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US3451827A - Method of coating the interior of a sausage casing - Google Patents

Method of coating the interior of a sausage casing
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US3451827A
US3451827AUS509117AUS3451827DAUS3451827AUS 3451827 AUS3451827 AUS 3451827AUS 509117 AUS509117 AUS 509117AUS 3451827D AUS3451827D AUS 3451827DAUS 3451827 AUS3451827 AUS 3451827A
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casing
shirring
mandrel
coating
tubing
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US509117A
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Douglas J Bridgeford
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Continental Group Inc
Teepak Investments Inc
Tee Pak Inc
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Tee Pak Inc
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Assigned to BUFPAK CORPORATION A DE CORP.reassignmentBUFPAK CORPORATION A DE CORP.ASSIGNMENT OF ASSIGNORS INTEREST.Assignors: CONTINENTAL GROUP, INC., THE A NY CORP. OF NY
Assigned to CONTINENTAL GROUP, INC., A CORP. OF N.Y.reassignmentCONTINENTAL GROUP, INC., A CORP. OF N.Y.ASSIGNMENT OF ASSIGNORS INTEREST.Assignors: TEEPAK INC.
Assigned to TEEPAK, INC., A DE CORP.reassignmentTEEPAK, INC., A DE CORP.ASSIGNMENT OF ASSIGNORS INTEREST. EFFECTIVE JULY 1, 1983.Assignors: BUFPAK CORPORATION A DE CORP
Assigned to TEEPAK INVESTMENTS, INC.reassignmentTEEPAK INVESTMENTS, INC.ASSIGNMENT OF ASSIGNORS INTEREST.Assignors: TEEPAK, INC.
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24; 19619 D. J. BRIDGEFORD 7 METHOD OF COAT INC THE INTERIOR OF A SAUSAGE CASING Filed Nov. 22, 1965 Sheet of 4 FIG.-
DOUGLAS J BRIDGEFORD INVENIDR.
3,451,827 METHOD OF COATiNG THE INTERIOR OFA SAUSAGE CASING sheet 2 014 June 24,1969 D. J. BRIDGEFORD Filed Nov. 22, 1965 1 v w m 3 n 2 on 9. Na 2 o k A z n \Q\.\\\ J N a fi mm am I DOUGLAS J BRIDGEFORD INVENTOR.
June 24, 19 69 o. 1. BRIDGEFORD 3,451,827 METHOD OF COATING THE vINTERIOR OT" A SAUSAGE CASI G 7 Filed Nov. 22, 1965 Sheet DOUGLAS J amoEFoRo' kn n UUUT Filed Nov; 22, 1.965
June 24, 1969 METHOD OF COATING THE INTERIOR OF ASAUSAGE CASING Sheet 4 of 4 INVENTOR.
D. J. BRIDGEFORD 3,451,827
DOUGLAS J, BRIDGE FORD United States Patent U.S. Cl. 99-176 4 Claims ABSTRACT OF THE DISCLOSURE A thin-walled continuous tube of indefinite lengths is coated internally by shirring said tube on a mandrel having a longitudinal passage while introducing a solution, emulsion, or dispersion of an adherent coating material in a liquid carrier through said mandrel to coat the interior of the tube.
This invention relates to new and useful improvements in methods and apparatus for coating the inside of small diameter thin-walled flexible tubes.
Thin-walled small diameter tubes of plastic are made for a variety of purposes. Thin-walled small diameter tubes of regenerated cellulose (with or without fibrous reinforcement), cellulose derivatives, amylose, alginates, collagen, etc., are Well known for use as flexible molds or casings for the formation of sausages. In many applica- .tions it is desirable to provide inside coatings to thin- Walled hollow tubes, especially casings, such as, moistureproofing or anti-blocking materials, release agents, synthetic smokes, antibiotics, bacteristats, perfumes, dyes, pigments, etc. In larger diameter tubes it is possible to coat the inside of a tube by filling a portion of the tube with the desired coating material and then moving the tube so that the slug of coating material confined within the tube is moved in relation to the tube wall and thus coats the inside wall of the tube over an extended distance. This internal coating technique is theoretically capable of application to tubes of all sizes. However, in commercial practice it has been uneconomical to apply the internal coating technique above described to small size tubings and casings.
Accordingly, it is one object of this invention to provide a new and improved method for the internal coating of thin-walled tubes.
Another object of this invention is to provide a new and improved method for coating the inside of thin walled flexible tubes of relatively small diameter.
Another object of this invention is to provide a new and improved apparatus for coating the inside of thin- Walled flexible tubes.
A feature of this invention is the provision of an improved method for coating the inside of flexible wall tubes while shirring or pleating a predetermined length of the tube.
Another feature of this invention is the provision of a new and improved apparatus for coating the inside wall of thin-walled tubes, especially tubes of small diameter, while shirring or pleating a predetermined length of the tube.
Other objects and features of this invention will become apparent from time to time throughout the specification and claims as hereinafter related.
This invention comprises a new and improved method for the internal coating of thin-walled tubes while shirring or pleating a predetermined length of the tube. Many years ago, thin-walled tubes such as natural or artifical sausage casings were shirred or pleated into relatively short easily handled lengths by moving the tube over a hollow mandrel, inflating the tube around the mandrel, and shirring or pleating the tube by hand on the mandrel.
3,451,827 Patented June 24, 1969 Later, machines were designed, such as that shown in Dietrich U.S. Patent 2,010,626, which replaced the fingers of a hand shirring operator with mechanically operated dogs or lugs which would engage an inflated tubing and move it to form an accordion pleated or shirred product. Improved forms of shirring machines and the products produced thereby are shown in Korsgaard U.S. Patent 2,583,654; Blizzard et a1. U.S. Patents 2,722,714, 2,722,715, and 2,723,201; Gimbel U.S. Patent 2,819,488; and, Matecki U.S. Patents 2,983,949 and 2,984,574. This invention is based upon the discovery that a variety of coating materials, viz. any material which will form a coherent continuous coating, can be applied uniformly on the internal surface of a hollow tube by application through a hollow mandrel onto which the hollow tubing or casing is shirred. The coating material may be applied through the hollow mandrel of any of the several shirring machines described in the various patents mentioned above, or through a hollow mandrel onto which a casing is shirred by hand. Generally, the coating material must be introduced with the air or other gas which is blown into the hollow tube to keep it inflated during the shitring process.
In the accompanying drawings, to be taken as a part of this specification, there are clearly and fully illustrated several preferred embodiments of this invention, in which drawings,
FIG. 1 is a view in side elevation of a shirring machine (with much detail omitted) of the type shown in Blizzard et al. U.S. Patents 2,722,714, 2,722,715 and 2,723,201, which may be used for internal coating of hollow tubing or casings in accordance with this invention,
FIG. 2 is a view in cross section of a mandrel used in the shirring machine shown in FIG. 1 or in any of the other figures illustrating the application of an internal coating material therethrough,
FIG. 3 is a detail sectional view of a modified form of a mandrel shown in FIG. 2,
FIG. 4 is still another detail sectional view of another modified form of the mandrel shown in FIG. 2,
FIG. 5 is a view in side elevation of a shirring machine of the type shown in FIG. 1, with wheels performing the shirring function, arranged for internal coating of the tube or casing which is to be shirred in the machine,
FIG. 6 is a view in perspective of the shirring wheels shown in FIG. 5, and
FIG. 7 is a detail view of a strand of shirred casing.
Referring to the drawings by numerals of reference and more particularly to FIG. 1, the improved process of this invention is illustrated as applied to an apparatus of the type shown in Blizzard et al. U.S. Patents 2,722,- 714, 2,722,715, and 2,723,201. In comparing the apparatus of FIG. 1 with the corresponding figure in the Blizzard et al. patents, the same reference numerals are not used for the same parts shown in that patent, but the correspondence of parts and manner of operation will be apparent. In FIG. 1, the reference numeral 1 is applied generally to an angle iron welded frame which includes a rear bottom longitudinal angle 2, a rearintermediate angle 3, a rear toplongitudinal angle 4, and rearupright angles 5. The remaining portions of frame 1 are disclosed in more detail in Korsgaard U.S. Patent 2,583,654, to which reference is made for a more complete understanding of the same.
Frame 1 also includes transversely extendingangles 6. Mounted on therear top angle 4 and on a corresponding angle on the opposite side is plate 7 which carries a measuring roll 8. Measuring roll 8 is rotatably mounted between support plates 9 which also supports a rotatable squeeze roll 10. Cooperating with the measuring roll 8 is a metering disc 11. It is arranged to operate a measuring limit switch 12 for stopping further operation of the shirring head when a predetermined length of casing has been shirred.
In the Blizzard et al. and Korsgaard patents, there is explained in greater detail the employment of a tear limit switch for stopping further operation of the shirring head in the event that the casing or tubing handled in the apparatus is torn. The tear limit switch is operated by roller 13 which engages the upper side of the tubing or casing handled in the apparatus.
On the angle iron frame 1 there are mounted shirring head side plates 14 which consitute the framework for the shirring head. A shirring head motor 15 is mounted on plates 14 and is suitably controlled for starting, driving, and stopping the shirring head which is generally referred to as 16.
Shirring head 16 is arranged to receive a relatively thin-walled flexible tubing, such as, sausage casing 17, from reel 18 mounted on shaft 19. The casing 17 which is fed from reel 18 is initially in a flat condition and sometimes referred to reelstock. Casing 17 passes between metering roll 8 and squeeze roll 10 and is inflated as shown at 20. Just beyond the inflatedportion 20 the casing is broken away to show more detail of the shirring apparatus and particularly the portion of the apparatus which is used for coating the inside of the casing or tubing. Immediately below roller 13 which operates the tear limit switch and on the underside of inflatedcasing 20 is roller 22 carried on arm 23. Roller arm 23 is employed to limit the downward movement of roller 13 when the casing is deflated. The casing is drawn overmandrel 50 which has a central longitudinal aperture through which air flows under a slight pressure to inflate the casing to its full diameter and thus facilitate the shirring operation. The mandrel and central aperture are shown in more detail in FIGS. 2 to 4. The central aperture in the shirring mandrel provides an opening for introduction of a coating material and a lubricant, if necessary, into the interior of the casing.
Theinflated casing 20 passes over themandrel 50 into the shirring head 16 between guide rollers 24 which are mounted onvertical supports 25 that are in turn mounted on the ends of arms 26 secured to and extending from plate 7. Using the shirring head 16, constructed as herein disclosed, and with appropriate changes in the openings in the shirring dogs or lugs, it is possible to shirr a wide range of sizes of thin-walled tubes or synthetic sausage casings. Casings or tubings with which this invention can be employed range in thickness from 0.00101O in. and in length from about to 200 feet. While real 18 contains an indeterminate length of easing, the casing wound therearound is cut into lengths of the order from 30 to 200 feet, depending upon the end use requirements of the casing or tubing. The resulted lengths of casing are shirred onto the mandrel by shirring head 16 and the shirred casing cut off in predetermined desired lengths. The internal diameter of the casing with which this apparatus can be employed ranges from about /2 to about 2 in. While the apparatus is primarily used in the shirring of thin-walled cellulosic casing, it may be used in the shirring of fibrous casing, amylose or starch film casing, collagen film casing, alginate film casing, thinwalled tubes of various thermo-plastic materials, etc. The shirring head shown in this figure can be used in conjunction with a turret as described in the Korsgaard patent, where a floating mandrel construction as described in th Dietrich patent or other similar arrangement is used.
Shirring head 16 includes upper andlower shirring belts 27 which have a plurality of staggered spaced shirring lugs 28 which are offset or staggered in relation to each other.Belts 27 are supported on pulleys orwheels 29, 30, 31 and 32. Motor 15 is connected by a drive pulley or other suitable drive mechanism (not shown) to one of the wheels supportingshirring belt 27 and is operable to drive the belts to shirr the tubing orcasing 20. Thelower shirring belt 27 is driven by a motor and pulley arrangement which is not shown but which can be seen in FIG. 1 of the Blizzard et al. patent. Upper andlower shirring belts 27 are driven in coordination, with the shirring lugs 28 arranged to engage andshirr casing 20 onshirring mandrel 50. The shirred casing is eventually severed and compressed on a storage mandrel or on the outer end ofmandrel 50 where a floating construction is used. After compression, the shirred casing is discharged to a suitable storage hopper where the shirred strand is removed and placed in a box for shipment.
An oil (or other lubricant)storage tank 33 is supported byplates 34 and secured to shirring head plate 14.Storage tank 33 has an inlet opening 35- and a bottom outlet opening connected totubing 36 which is in turn connected to amanifold 37.Manifold 37 is connected to valve 38 andoutlet tubes 39 which are arranged to supply lubricant tobrushes 40 positioned for engagement withshirring belts 27. The oil or other lubricant which is placed instorage tank 33 is supplied tobrushes 40 for contact withshirring belts 27 and provides lubrication for the external surface of the tubing or casing being shirred to prevent mechanical damage due to shirring abrasion.
Shirringmandrel 50 is provided with collar 42 and actuating arm 43 for reciprocal movement of the mandrel into and out of the shirring head. Actuating member 43 is operated in association with the movement of turret 44 consisting of a plurality of separately actuated and rotatable mandrels as described in Korsgaard Patent 2,583,- 654.Mandrel 50 is provided with suitable correction indicated at 45 which is connected through flexible tubing 46 to valve 47 for supply of compressed air and liquid for coating the inside surface of tubing or casing being shirred in the machine. Valve 47 is arranged to meter a small amount of a liquid coating material which is to be applied to the inner surface of the tubing or casing being shirred. Valve 47 meters the coating liquid into the stream of air which is used to inflate the casing or tubing during shirring.
In FIG. 2, there is shown a detailed sectional view ofmandrel 50 illustrating the introduction of a coating material through the mandrel to coat the inside surface of tubing or casing being shirred in the apparatus.Mandrel 50 comprises hollowtubular portions 48 and 49. Tubular portion 49 is threadedly connected, withintubular portion 48 as indicated at 51. Tubular portion 49 is surrounded bysleeve 52 of plastic and abuts against cup shaped cap assembly 53 (also made of plastic). Thecap assembly 53 is constructed of two parts and is provided withpassages 54 for spraying a coating material. The mandrel is also provided withoutlet tube 55 which extends throughcap assembly 53 and mandrel portion 49 intooutlet passage 56.Tubular mandrel portion 48 is closed by a suitable plug closure 57 and is provided with inlet opening 58 for introduction of air and coating fluid. In the assembly shown in FIG. 1inlet opening 58 is connected to flexible tubing 46 for introduction of compressed air and the coating fluid.
In operation, the apparatus functions as a shirring machine as described in the Blizzard et al. and Korsgaard patents. Tubular material or casing 17 is drawn from reel 18 and inflated as indicated at 20 by compressed air introduced into the interior of the casing through the hollow interior ofmandrel 50. Theshirring belts 27 grip the inflated tubing or casing and form it into an accordion pleated or shirred strand. The pleated strand of tubing or casing may be compressed and severed from the unshirred portion of the casing in preparation for storage and shipment. Compressed air is introduced into the interior of the casing throughinlet 58 and the passages intubular mandrel portions 48 and 49 andopenings 54 incap assembly 53. Any desired coating material which is to be applied to the interior surface of the tubing or casing is admixed with the air stream at valve 47 and is blown into the interior of the casing in the form of a spray issuing fromopenings 54 in the cup shapedcap assembly 53 onmandrel 50. The excess air introduced into the casing is withdrawn, substantially denuded of coating material, throughtubes 55 and released to atmosphere throughoutlet 56. Any of a large variety of coating materials may be admixed with the compressed air introduced through themandrel 50 as will be subsequently described.
FIGS. 3 and 4 disclose alternate forms of theshirring mandrel 50 designed for improved efiiciency in spraying the coating material for application to the entire surface of tubing or casing being shirred in this apparatus. In FIG. 3, the mandrel shown in FIG. 2 is modified by application of a flexible washer member 59 which is of a size and shape suitable for wiping the internal surface of the casing and for restricting the flow of coating material beyond the point of contact with the casing. The operation of the modified mandrel shown in FIG. 3 is identical to that of the mandrel shown in FIG. 2 except that washer 59 restricts the flow of coating material beyond the point of contact with the casing.
In FIG. 4, there is shown a modified form of the mandrel for spraying a coating material within the tubes or casing being shirred in the machine.Mandrel 50 comprisestubular parts 48 and 49 andsleeve member 52 as shown in FIGS. 2 and 3. Thecap member 53, however, is provided with tubular extension 59 which is composed of threeparts 60, 61 and 62 which are threadedly connected together. Tube 55a extends from inlet opening 56a through the interior oftubular mandrel portions 48 and 49 into the tubular interior of member 60. Member 62 is provided with aspray opening 63 for application of a coating material to the interior of the tubing orcasing 20. The mandrel may be provided with a flexible washer 64 shown in dotted lines for lighting the inner surface oftubing 20 to provide an even coating of material therein. The tubular extension 59 is provided withair return openings 65 which permit the withdrawal of air through the bore oftubular mandrel portions 48 and 49 and outlet opening 58a.
The operation of the shirring device for coating the internal surface of a tubing or casing is essentially the same with this modified mandrel as with the mandrel shown in FIGS. 2 and 3. The compressed air and coating material is introduced through inlet opening 56a and tube 55a and sprayed into contact with the inner wall of the tubing or casing throughspray outlet 63. Excess air is withdrawn throughopening 65 and outlet opening 58a.
In FIG. there is shown a different type of shirring machine for shirring tubing or casing and simultaneously coating the interior thereof. The machine shown in FIG. 5 is substantially the same as that described in FIG. 1 except that shirring wheels have been substituted for theshirring belts 27 and feed belts have been provided for assisting in the conveyance of the inflated tubing or casing to the shirring wheels. In FIG. 5 all of the parts which are the same as in FIG. I bear the same reference numerals and the description of the arrangement of such parts will not be repeated. The apparatus is provided with feed-inbelts 27a which are supported on and driven by wheels 29a 30a, 31a and 32a. The feed-inbelts 27a are positioned in about the same location as theshirring belts 27 shown in FIG. 1. The apparatus is provided with a set of three shirring wheels 67 (two wheels or four or more wheels could be used, if desired) which are mounted on drive gears 68 which are in turn supported on avertical support plate 69. In FIG. 6, theshirring wheels 67 are shown in more detail in relation tomandrel 50. Theshirring wheels 67 have a plurality of lugs orteeth 70 of different configurations which cooperate to grip the casing and shirr it in essentially the same manner as thelugs 28 and theshirring belts 27 in FIG. 1. FIG. 6
also provides an isometric view of the end ofmandrel 50 showing thespray outlets 54 andair return tube 55.
In this apparatus, the tubing or casting reelstock 17 is fed from reel 18 and inflated as indicated at 20'. The inflated casing passes overmandrel 50 and is conveyed by feed-inbelts 27a toshirring wheels 67. Compressed air and the coating material for applicaation to the inner surface of tubing or casing 17 is introduced through valve 47 and inlet tubing 46 to the interior ofmandrel 50 as described in connection with FIG. 1 to 4. The casing is lubricated externally by 'oil or other lubricant supplied fromreservoir 33 throughmanifold 37 tobrushes 40 which apply lubricant to the feed-in belts and to the shirring wheels. The casing is shirred into a tightly compacted accordion pleated form as shown by a section of shirred casing 20a in FIG. 7. The casing in this form is provided with a uniform inner coating of whatever coating material was introduced with the compressed air through the shirring mandrel. As described in connection with FIG. 1, the casing is severed after shirring to a predetermined length and is transferred to other receiving mandrels on aturret 34 where the casing is further compressed and eventually discharged to a storage hopper in preparation for packaging.
In carrying out the novel process of this invention, the desired coating material is introduced into the interior of the thin-walled tubing or casing with compressed air introduced through a shirring mandrel. The casing is shirred into an accordion pleated form as shown in FIG. 7 and has a uniform coherent coating on the entire internal surface thereof. The types of coatings which may be applied in this manner include such materials as synthetic smokes (for applying a smoke flavor to sausages prepared in the casings), antibiotics or bacteristats (for preservative purposes), perfumes, dyes, pigments, release agents, etc. The coating materials may be applied as is, where liquid coatings are used, or in the form of aqueous or nonaqueous solutions, emulsions, latices, dispersions, and the like. tReactive materials may also be applied as internal coatings in this process. Suitable materials include fatty ketene dimers in the form of emulsions or mineral oil solutions or suspensions, isocyanates, ethylene imine, etc. In evaluating the effectiveness of this internal coating process, a large variety of coating materials were used.
Example I Solutions or suspensions in a concentration range from 0.2 to 2% were prepared in (1) food grade mineral oil, (2) an edible vegetable oil, and (3) twelve percent glycerol solution in water, using the following materials as the solute or dispersed phase for coating the inside of casing or tubing:
and vegetable fats These solutions or suspensions were introduced into the interior of regenerated cellulose casings during the shirring of the casing on shirring machines as described in FIGS. 1 to 5. The coating solutions were introduced through the interior of the shirring mandrel along with the compressed air used to inflate the casings during shirring. In each case a shirred casing was obtained having a coherent uniformly dispersed coating over the entire inner surface of this casing. The casings which were coated in this manner were with cetyl alcohol, lecithin, fatty ketene dimers, methocel, silicone oil, or stearato chromyl chloride and were found to be more easily peeled from sausages which were stuffed into the casing.
Example 11 It has been found that reactive materials such as tolylenediisocyanate, octadecylisocyanate, and fatty ketene dimers can be coated on the inside of cellulose tubes (casings) to provide hydrophobic coatings which reduce the rate of water uptake by the cellulose. In the case of cellulose casing, the reduced rate of water uptake provides a substantial increase in strength during the time that the casing is stuffed with sausage emulsion.
Solutions or dispersions were prepared of (l) octadecyl isocyanate in mineral oil, (2) 5% tolylene diisocyanate emulsified in water with lauryl sodium sulfate, and (3) C1548 fatty ketene dimer in mineral oil. These solutions were used to coat the inside of cellulose casings using the apparatus shown in FIG. 5.
The coated casings were rewet and inflated with compressed air until they burst. It required 18 seconds inflation to burst the coated samples as compared to 10 sec. to burst an uncoated, rewet, control.
Example III A mandrel as shown in FIG. 4 was used in the apparatus of FIG. 5 for coating cellulose casing with octadecyl isocyanate. A solution of 10% octadecyl isocyanate in mineral oil was applied at the rates of (1) 30 drops per 84 ft. strand and (2) 90 drops per 84 ft. strand. Control strands were also prepared by applying mineral oil without the isocyanate to casing at the same rates, i.e. 30 drops and 90 drops per '84 ft. strand. The strands were rewet by application of water internally and tested in the inflation burst test of a 20 in. length, as follows:
TABLE Burst, p.s.i.
Control Isocyanate coating 30 drops/strand. 9 .6 12 .7 90 drops/strand-.. 10.2 15 .8
It was further noted that the application of water to the exterior of the isocyanate coated casings resulted in a substantial reduction in strength.
Example IV An experiment similar to Example III was carried out in which celulose casing was coated with 10% C1648 fatty ketene dimer in mineral oil at a rate of 90 drops per 84 ft. strand. The rewet burst strength was 12.0 p.s.i., compared to 10.2 p.s.i. for the control.
Example V scribed. The diisocyanate reacts with the inner surface to form an inner coating or sheath which is hydrophobic and slows down the wet out rate for the cellulose.
While the operation of this invention has been described using various solutions as coating materials, it will be obvious to those skilled in the art that any liquid coating material could be applied to the inner surface of the casing using this process. Likewise, it would be possible to apply a solid particulate material to the inner surface of the casing or tubing to provide an anti-blocking coating. The process has been described as being carried out in several different shirring machines. It will be obvious to those skilled in the art that the process could be carried out in any shirring machine having a hollow mandrel through which the coating material could be applied. Likewise, the process could be carried out by application through a hollow shirring mandrel where the tubing or casing as shirred by hand onto the mandrel. The process was described as one in which the coating material is sprayed into the interior of the tubing or casing in advance of or during shirring. It will be obvious to those skilled in the art that the coating material may be applied by any suitable method of application through the hollow shirring mandrel. Thus, the coated material may be sprayed into the interior of the casing or tubing or may be applied througha wick or suitable wiping member which would apply the coating to the inner wall of the tubing.
What is claimed is:
1. A method of coating the interior of a sausage casing of indefinite length which comprises shirring the casing on a mandrel having a longitudinal passage while introducing a coating composition comprising a solution, emulsion, or dispersion of an adherent coating material in a liquid carrier through said passage to coat the interior of the casing.
2. A method in accordance with claim 1 in which said tube is inflated by gas introduced through said mandrel, and said coating composition is introduced in admixture with said gas.
3. A method in accordance with claim 2 in which the coating material is sprayed into the tube through the mandrel.
4. A method in accordance with claim 1 in which said adherent coating material is lactic acid, calcium lactate, trisodium hexametaphosphate, aluminum sulfate, potassium aluminum sulfate, lecithin diammonium phosphate, carboxy methyl celulose, silicone oil, calcium phytate, inositol, glycero-phosphoric acid, C C fatty ketene dimers, acetylated monoglycerides of animal or vegetable fats, methyl cellulose, cetyl alcohol, or an organic isocyanate and said liquid carrier is a good grade mineral oil or an edible vegetable oil.
References Cited UNITED STATES PATENTS 3,097,393 7/1963 Matccki.
3,209,398 10/1965 Ziolko 99-176 X 3,222,192 12/1965 Arnold et al. 99-176 3,266,911 8/1966 Clement 99176 3,360,383 12/1967 Rose et a1. 99-l76 3,361,577 1/1968 Simon et al 99176 X HYMAN LORD, Primary Examiner.
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US3658561A (en)*1969-09-221972-04-25Henry J RoseTreatment of sausage casing for easy peeling
US3658560A (en)*1969-08-201972-04-25Tee Pak IncEasily peeled synthetic casing
US3661621A (en)*1968-06-081972-05-09Wolff & Co AgProcess for producing tubular structures coated on both sides
FR2141324A5 (en)*1971-06-101973-01-19Union Carbide Corp
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DE2322049A1 (en)*1972-05-051973-11-15Union Carbide Corp PROCESS FOR MANUFACTURING MOISTURIZED, SHIRRED, TUBE-SHAPED CELLULOSE SHELLS
US3813731A (en)*1969-12-191974-06-04Steigerwald StrahltechFinely perforated artifical gas and water vapor pervious wrapping for foodstuffs
US3818947A (en)*1972-01-261974-06-25Tee Pak IncEasily peelable sausage casing
US3886979A (en)*1972-08-011975-06-03Union Carbide CorpShirred tubular food casings having a barrier coating
US3898348A (en)*1971-06-101975-08-05Union Carbide CorpFood casing and method of preparing same
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FR2342664A1 (en)*1976-03-011977-09-30Tee Pak Inc PROCESS FOR WETTING AND PLEASING ARTIFICIAL SAUSAGE CASINGS
DE2828296A1 (en)1977-06-281979-01-04Union Carbide Corp FOOD COVER AND METHOD FOR THEIR PRODUCTION
US4137947A (en)*1977-09-281979-02-06Teepak, Inc.Internally coated sausage casing with improved meat release composition
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EP0015622A1 (en)*1979-03-051980-09-17Herbert Dipl.-Ing. NiedeckerMethod for the preparatory treatment of shirred artificial sausage skins
US4287217A (en)*1977-08-051981-09-01Hoechst AktiengesellschaftMultiple-layer tubing
EP0041149A1 (en)*1980-05-311981-12-09Kollross, GünterMethod and apparatus for oiling the inside surface of a packing tubing
US4353939A (en)*1980-03-281982-10-12Hoechst AktiengesellschaftProcess for the manufacture of tubing based on cellulose hydrate having a coating on its inside and apparatus for carrying out the process
DE3237955A1 (en)*1981-10-161983-06-30Union Carbide Corp., 06817 Danbury, Conn. METHOD FOR PRODUCING AN AQUEOUS LIQUID COMBUSTION COMPOSITION AND USE FOR TREATING FOOD SHELLS
US4431032A (en)*1981-10-161984-02-14Union Carbide CorporationTar-depleted liquid smoke treatment of food casings
EP0118784A1 (en)*1983-02-141984-09-19Viskase CorporationInhibition of discoloration on cellulose food casings
US4489114A (en)*1983-03-141984-12-18Teepak, Inc.Arabinogalactans as release additives for cellulose containing casings
US4504500A (en)*1982-08-171985-03-12Red Arrow Products Company Inc.Method of coating a shirred casing strand with smoke flavor
US4505939A (en)*1982-09-141985-03-19Union Carbide CorporationTar-depleted liquid smoke treated food casing
US4511613A (en)*1983-02-141985-04-16Union Carbide CorporationMethod for inhibiting discoloration on cellulose food casings
US4518619A (en)*1983-02-151985-05-21Union Carbide CorporationPreparation of smoke treated, stuffed food casings
US4525397A (en)*1979-07-311985-06-25Union Carbide CorporationLiquid smoke treated cellulosic food casings
DE3447026A1 (en)*1984-01-041985-07-11Hoechst Ag, 6230 FrankfurtSausage casing having improved peelability
US4532141A (en)*1982-09-141985-07-30Union Carbide CorporationMethod for preparing a smoke colored food product
US4540613A (en)*1983-02-141985-09-10Union Carbide CorporationTar-depleted, concentrated, liquid smoke compositions
US4543282A (en)*1982-11-181985-09-24Hoechst AktiengesellschaftTubular food casing having improved peeling properties
US4657765A (en)*1983-02-141987-04-14Viskase CorporationMethod for imparting smoke color and flavor to food
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US4818551A (en)*1986-08-051989-04-04Viskase CorporationMethod of making a liquid smoke impregnated shirred casing stick
US4834993A (en)*1979-07-311989-05-30Viskase CorporationMethod for external liquid smoke treatment of cellulosic food casings
EP0502431A1 (en)*1991-03-071992-09-09Hoechst AktiengesellschaftTubular casings for foodstuffs with an improved peel-off ability
EP0528374A1 (en)*1991-08-211993-02-24Hoechst AktiengesellschaftTubular casing for foodstuffs with improved bonding properties for the filling
US5230933A (en)*1990-07-111993-07-27Viskase CorporationAcid resistant peelable casing
EP0559456A1 (en)1992-03-041993-09-08Viskase CorporationCellulosic articles and their manufacture
US5256458A (en)*1990-09-181993-10-26Viskase CorporationShirred thermoplastic casing having external non-oil based lubricating coating
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WO1998008390A3 (en)*1996-08-271998-06-18Alfacel S ACold temperature shirring
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US20030207002A1 (en)*2002-05-062003-11-06Merritt Frederick M.Process for improving smoky color of food
US20040062834A1 (en)*2002-09-262004-04-01Casematic, S.A. De C.V.Polyamide-based sausage casing
US20040202762A1 (en)*2003-04-082004-10-14Ducharme Paul ESmoked nonfibrous casing
US6991836B1 (en)*1999-01-112006-01-31Teepak Properties, LlcFood casing release coating comprising polyglyceryl esters
US20060234611A1 (en)*2003-08-272006-10-19Ulrich DeliusIntrinsically stable shirred plastic food casing
US20060269705A1 (en)*2003-08-272006-11-30Walter NiederstaetterIntrinsically stable shirred stick
US20070014947A1 (en)*2004-04-022007-01-18Curwood, Inc.Packaging inserts with myoglobin blooming agents, packages and methods for packaging
US20070148294A1 (en)*2003-04-082007-06-28Ducharme Paul E JrSmoked nonfibrous casing
EP1857270A1 (en)2006-05-172007-11-21Curwood, Inc.Myoglobin blooming agent, films, packages and methods for packaging
EP2095942A1 (en)2006-05-172009-09-02Curwood, Inc.Method that Promotes or Preserves the Desirable Color of Meat
US8545950B2 (en)2004-04-022013-10-01Curwood, Inc.Method for distributing a myoglobin-containing food product
US8668969B2 (en)2005-04-042014-03-11Curwood, Inc.Myoglobin blooming agent containing shrink films, packages and methods for packaging
US8709595B2 (en)2004-04-022014-04-29Curwood, Inc.Myoglobin blooming agents, films, packages and methods for packaging
US8741402B2 (en)2004-04-022014-06-03Curwood, Inc.Webs with synergists that promote or preserve the desirable color of meat
CN105087128A (en)*2015-06-302015-11-25北京秋实农业发展有限公司Lubricant for natural casings and preparation method thereof
WO2019079038A1 (en)*2017-10-162019-04-25Nitta Casings Inc.Methods of flavoring collagen casings
WO2021202682A1 (en)2020-03-312021-10-07Viskase Companies, Inc.Rigid shirred food casing articles, and related methods and compositions

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US3653928A (en)*1969-06-301972-04-04Tee Pak IncEasily peeled synthetic casing
US3658560A (en)*1969-08-201972-04-25Tee Pak IncEasily peeled synthetic casing
US3658561A (en)*1969-09-221972-04-25Henry J RoseTreatment of sausage casing for easy peeling
US3813731A (en)*1969-12-191974-06-04Steigerwald StrahltechFinely perforated artifical gas and water vapor pervious wrapping for foodstuffs
US3753740A (en)*1969-12-231973-08-21Tee Pak IncEasily peelable sausage casing
FR2141324A5 (en)*1971-06-101973-01-19Union Carbide Corp
US3898348A (en)*1971-06-101975-08-05Union Carbide CorpFood casing and method of preparing same
US3818947A (en)*1972-01-261974-06-25Tee Pak IncEasily peelable sausage casing
FR2184297A5 (en)*1972-05-051973-12-21Union Carbide Corp
DE2322049A1 (en)*1972-05-051973-11-15Union Carbide Corp PROCESS FOR MANUFACTURING MOISTURIZED, SHIRRED, TUBE-SHAPED CELLULOSE SHELLS
US3981046A (en)*1972-05-051976-09-21Union Carbide CorporationProcess for production of shirred moisturized food casings
US3886979A (en)*1972-08-011975-06-03Union Carbide CorpShirred tubular food casings having a barrier coating
US4026985A (en)*1972-08-011977-05-31Union Carbide CorporationShirred tubular food casings having a barrier coating
DK152956B (en)*1972-08-011988-06-06Viskase Corp Wrinkled and compressed, agitated foodstuffs for the production of the same
FR2342664A1 (en)*1976-03-011977-09-30Tee Pak Inc PROCESS FOR WETTING AND PLEASING ARTIFICIAL SAUSAGE CASINGS
DE2828296A1 (en)1977-06-281979-01-04Union Carbide Corp FOOD COVER AND METHOD FOR THEIR PRODUCTION
US4287217A (en)*1977-08-051981-09-01Hoechst AktiengesellschaftMultiple-layer tubing
US4137947A (en)*1977-09-281979-02-06Teepak, Inc.Internally coated sausage casing with improved meat release composition
US4207353A (en)*1977-11-031980-06-10Union Carbide CorporationFood casing and method of preparing same
US4161968A (en)*1977-11-031979-07-24Union Carbide CorporationFood casing and method of preparing same
EP0015622A1 (en)*1979-03-051980-09-17Herbert Dipl.-Ing. NiedeckerMethod for the preparatory treatment of shirred artificial sausage skins
US4834993A (en)*1979-07-311989-05-30Viskase CorporationMethod for external liquid smoke treatment of cellulosic food casings
US4525397A (en)*1979-07-311985-06-25Union Carbide CorporationLiquid smoke treated cellulosic food casings
US4353939A (en)*1980-03-281982-10-12Hoechst AktiengesellschaftProcess for the manufacture of tubing based on cellulose hydrate having a coating on its inside and apparatus for carrying out the process
EP0041149A1 (en)*1980-05-311981-12-09Kollross, GünterMethod and apparatus for oiling the inside surface of a packing tubing
DE3237955A1 (en)*1981-10-161983-06-30Union Carbide Corp., 06817 Danbury, Conn. METHOD FOR PRODUCING AN AQUEOUS LIQUID COMBUSTION COMPOSITION AND USE FOR TREATING FOOD SHELLS
US4431033A (en)*1981-10-161984-02-14Union Carbide CorporationTar-depleted liquid smoke treatment of food casings
US4431032A (en)*1981-10-161984-02-14Union Carbide CorporationTar-depleted liquid smoke treatment of food casings
US4504500A (en)*1982-08-171985-03-12Red Arrow Products Company Inc.Method of coating a shirred casing strand with smoke flavor
US4505939A (en)*1982-09-141985-03-19Union Carbide CorporationTar-depleted liquid smoke treated food casing
US4532141A (en)*1982-09-141985-07-30Union Carbide CorporationMethod for preparing a smoke colored food product
US4543282A (en)*1982-11-181985-09-24Hoechst AktiengesellschaftTubular food casing having improved peeling properties
US4511613A (en)*1983-02-141985-04-16Union Carbide CorporationMethod for inhibiting discoloration on cellulose food casings
US4500576A (en)*1983-02-141985-02-19Union Carbide CorporationInhibition of discoloration on cellulose food casings
US4540613A (en)*1983-02-141985-09-10Union Carbide CorporationTar-depleted, concentrated, liquid smoke compositions
US4657765A (en)*1983-02-141987-04-14Viskase CorporationMethod for imparting smoke color and flavor to food
US4717576A (en)*1983-02-141988-01-05Viskase CorporationTar-depleted, concentrated, liquid smoke compositions and method for producing
EP0118784A1 (en)*1983-02-141984-09-19Viskase CorporationInhibition of discoloration on cellulose food casings
US4518619A (en)*1983-02-151985-05-21Union Carbide CorporationPreparation of smoke treated, stuffed food casings
US4489114A (en)*1983-03-141984-12-18Teepak, Inc.Arabinogalactans as release additives for cellulose containing casings
DE3447026A1 (en)*1984-01-041985-07-11Hoechst Ag, 6230 FrankfurtSausage casing having improved peelability
US4818551A (en)*1986-08-051989-04-04Viskase CorporationMethod of making a liquid smoke impregnated shirred casing stick
US5230933A (en)*1990-07-111993-07-27Viskase CorporationAcid resistant peelable casing
US5256458A (en)*1990-09-181993-10-26Viskase CorporationShirred thermoplastic casing having external non-oil based lubricating coating
US5304385A (en)*1990-09-181994-04-19Viskase CorporationMethod for making a cooked food using shirred casing having an ethylenic polymer outer layer with an external non-oil based lubricant
US5358784A (en)*1991-03-071994-10-25Hoechst AktiengesellschaftTubular food casing with improved peelability
EP0502431A1 (en)*1991-03-071992-09-09Hoechst AktiengesellschaftTubular casings for foodstuffs with an improved peel-off ability
US5370914A (en)*1991-03-071994-12-06Hoechst AktiengesellschaftTubular food casing with improved peelability
US5736179A (en)*1991-08-211998-04-07Hoechst AktiengesellschaftTubular foodstuff casing having a chitosan coating
EP0528374A1 (en)*1991-08-211993-02-24Hoechst AktiengesellschaftTubular casing for foodstuffs with improved bonding properties for the filling
EP0559456A1 (en)1992-03-041993-09-08Viskase CorporationCellulosic articles and their manufacture
WO1998008390A3 (en)*1996-08-271998-06-18Alfacel S ACold temperature shirring
US5782683A (en)*1996-08-271998-07-21Alfacel S.A.Cold temperature shirring
US5914141A (en)*1997-03-111999-06-22Alfacel S.A.Easy peeling wiener casings via use of enzymes
US6086929A (en)*1998-09-152000-07-11Alfacel S.A.Shirring solution for cellulosic sausage casings
US6991836B1 (en)*1999-01-112006-01-31Teepak Properties, LlcFood casing release coating comprising polyglyceryl esters
US20030207002A1 (en)*2002-05-062003-11-06Merritt Frederick M.Process for improving smoky color of food
US7001635B2 (en)2002-05-062006-02-21Viskase CorporationProcess for improving smoky color of an encased food product
US20040062834A1 (en)*2002-09-262004-04-01Casematic, S.A. De C.V.Polyamide-based sausage casing
US20040062888A1 (en)*2002-09-262004-04-01Casematic, S.A. De C.V.Polymer-based sausage casing
US7833594B2 (en)2002-09-262010-11-16Casematic, S.A. De C.V.Polymer based sausage casing
US20070148294A1 (en)*2003-04-082007-06-28Ducharme Paul E JrSmoked nonfibrous casing
US20040202762A1 (en)*2003-04-082004-10-14Ducharme Paul ESmoked nonfibrous casing
US7803437B2 (en)2003-08-272010-09-28Kalle GmbhIntrinsically stable shirred plastic food casing
US20060269705A1 (en)*2003-08-272006-11-30Walter NiederstaetterIntrinsically stable shirred stick
US20060234611A1 (en)*2003-08-272006-10-19Ulrich DeliusIntrinsically stable shirred plastic food casing
US8440277B2 (en)2003-08-272013-05-14Kalle GmbhIntrinsically stable shirred stick
US8802204B2 (en)2004-04-022014-08-12Curwood, Inc.Packaging inserts with myoglobin blooming agents, packages and methods of packaging
US8741402B2 (en)2004-04-022014-06-03Curwood, Inc.Webs with synergists that promote or preserve the desirable color of meat
US8709595B2 (en)2004-04-022014-04-29Curwood, Inc.Myoglobin blooming agents, films, packages and methods for packaging
US8470417B2 (en)2004-04-022013-06-25Curwood, Inc.Packaging inserts with myoglobin blooming agents, packages and methods for packaging
US8530012B2 (en)2004-04-022013-09-10Curwood, Inc.Packaging articles, films and methods that promote or preserve the desirable color of meat
US8545950B2 (en)2004-04-022013-10-01Curwood, Inc.Method for distributing a myoglobin-containing food product
US8623479B2 (en)2004-04-022014-01-07Curwood, Inc.Packaging articles, films and methods that promote or preserve the desirable color of meat
US20070014947A1 (en)*2004-04-022007-01-18Curwood, Inc.Packaging inserts with myoglobin blooming agents, packages and methods for packaging
US8668969B2 (en)2005-04-042014-03-11Curwood, Inc.Myoglobin blooming agent containing shrink films, packages and methods for packaging
EP2095942A1 (en)2006-05-172009-09-02Curwood, Inc.Method that Promotes or Preserves the Desirable Color of Meat
EP1857270A1 (en)2006-05-172007-11-21Curwood, Inc.Myoglobin blooming agent, films, packages and methods for packaging
CN105087128A (en)*2015-06-302015-11-25北京秋实农业发展有限公司Lubricant for natural casings and preparation method thereof
CN105087128B (en)*2015-06-302018-02-09北京秋实农业股份有限公司A kind of natural casing lubricant and preparation method thereof
WO2019079038A1 (en)*2017-10-162019-04-25Nitta Casings Inc.Methods of flavoring collagen casings
CN111447833A (en)*2017-10-162020-07-24韦斯康芬胶原蛋白美国有限公司Method for seasoning casing of collagen
JP2020536584A (en)*2017-10-162020-12-17ビスコファン・コラーゲン・ユーエスエー・インコーポレイテッド How to flavor the collagen casing
RU2769984C2 (en)*2017-10-162022-04-12ВИСКОФЭН КОЛЛАГЕН ЮЭсЭЭй ИНК.Methods for introducing flavoring substances into collagen shells
JP7603446B2 (en)2017-10-162024-12-20ビスコファン・コラーゲン・ユーエスエー・インコーポレイテッド Method for flavoring collagen casing
WO2021202682A1 (en)2020-03-312021-10-07Viskase Companies, Inc.Rigid shirred food casing articles, and related methods and compositions

Also Published As

Publication numberPublication date
FR1506619A (en)1967-12-22
GB1124180A (en)1968-08-21

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Owner name:BUFPAK CORPORATION A DE CORP.

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Effective date:19811214

ASAssignment

Owner name:CONTINENTAL GROUP, INC., A CORP. OF N.Y.

Free format text:ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:TEEPAK INC.;REEL/FRAME:004089/0312

Effective date:19811214

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Owner name:TEEPAK, INC., A DE CORP.

Free format text:ASSIGNMENT OF ASSIGNORS INTEREST. EFFECTIVE JULY 1, 1983.;ASSIGNOR:BUFPAK CORPORATION A DE CORP;REEL/FRAME:004185/0588

Effective date:19830922

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Owner name:TEEPAK INVESTMENTS, INC., 103 SPRINGER BUILDING, 3

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