US20230124496A1 - Continuous Spray Dispenser For Highly Corrosive and Other Low Compatibility Products - Google Patents

Abstract

A spray dispensing device including a first chamber defined by a container, a bladder contained within the first chamber that houses a fluid composition (e.g., a bleach composition), and an actuator in fluid communication with the first chamber so as to allow dispensing of the fluid composition from the bladder when the actuator is actuated (e.g., pressed). A pressurized composition may be contained within a second chamber, which acts as a pressure control device. The pressure of the pressurized composition may be in a range of from about 70 psi to about 150 psi. An outlet valve may provide selective fluid communication between the pressure control device (i.e., the second chamber) and the first chamber.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS
• This application is a continuation of co-pending United States Pat. Application No. 17/343,527, filed on Jun. 9, 2021, which is a continuation of United States Pat. Application No. 16/590,811, filed on Oct. 2, 2019, which is a continuation of United States Pat. Application No. 15/261,766 filed on Sep. 9, 2016, which is now granted U.S. Pat. No. 10,472,162, issued Nov. 12, 2019. The entire disclosures of the above application and patent are incorporated herein by reference.
FIELD OF THE INVENTION
• The present disclosure relates to dispensing devices, particularly to handheld dispensing containers for spraying cleaning compositions. e.g., such as bleach. Although particularly suitable for dispensing compositions including an oxidant or other corrosive and/or low compatibility component, other fluid compositions could also be dispensed from the device.
DESCRIPTION OF RELATED ART
• Currently, bleach compositions are typically provided in jugs or similar containers that require the user to pour the desired amount of bleach. Some bleach containing products (e.g., toilet bowl cleaners) are packaged in squeezable containers that allow a user to squirt a desired amount of the product by squeezing the sides of the container. While bleach compositions are highly efficacious at cleaning, and killing microbes (e.g., sanitizing, disinfecting, and sterilizing), there continues to be a need for alternative, more convenient modes of dispensing such compositions. Previous attempts to dispense such compositions through alternative mechanisms have been hampered by the presence of oxidizing agents (e.g., typically hypochlorites and/or peroxides) within the composition, which are highly corrosive and/or otherwise incompatible with many materials.
BRIEF SUMMARY
• One aspect of the present invention relates to a spray dispensing device that may dispense a fluid composition. In some embodiments, the fluid composition may be a cleaning or other composition including an oxidizing agent, or other corrosive agent that may corrode or otherwise compromise components typically employed in spray mechanisms, containers, and the like. According to one embodiment, a spray dispensing device may include a first chamber defined by a container having contoured sidewalls (e.g., a non-cylindrical container, e.g., which may include a wide variety of shapes for ornamental purposes, enhanced gripping, or the like). The device may further include a bladder contained within the first chamber, which bladder houses a fluid composition to be dispensed (e.g., an oxidizing bleach composition). An actuator may be provided in fluid communication with the first chamber configured to dispense the fluid composition from the bladder upon actuation of the actuator. A second chamber may also be provided, which acts as a pressure control device. A pressurized composition may be contained in the second chamber, e.g., at a pressure in a range of about 70 psi to about 150 psi. An outlet valve may be provided, which provides selective fluid communication between the pressure control device and the first chamber.
• Such an outlet valve may be configured to provide a substantially constant pressure within the first chamber, so as to apply a substantially constant pressure against the bladder over the life of the spray dispensing device (which device may typically be disposable after the contents have been spent). Such a configuration may allow for continuous dispensing of the fluid composition so long as the actuator remains actuated. Where substantially constant pressure is provided within the first chamber, the spray stream or aerosol of dispensed fluid may advantageously be maintained at a substantially constant flow rate and pattern over the life of the spray dispensing device. In other words, the last portion of fluid composition dispensed from the container may be dispensed with similar spray pattern and other characteristics as compared to the first portion of fluid composition dispensed from the container. In addition, the described configuration may also allow the container to be inverted, or rotated to any desired orientation, while still maintaining the same dispensing characteristics (i.e., dispensing is not gravity dependent).
• Another spray dispensing device may include a first chamber defined by a container, a bladder contained within the first chamber and housing a fluid composition, and an actuator in fluid communication with the first chamber configured to dispense the fluid composition from the bladder upon actuation thereof. A second chamber (e.g., also disposed within the container) may be provided which acts as a pressure control device, and a pressurized composition may be contained within the second chamber. The pressurized composition may be selected from the group consisting of: air, nitrogen, carbon dioxide, nitrogen, inert components (e.g. argon) and combinations thereof. Any components of the pressurized composition may be in solid, liquid or gaseous phases and any combinations thereof (e.g. liquid nitrogen, carbon dioxide gas, solid carbon dioxide, etc.). An outlet valve may provide selective fluid communication between the pressure control device and the first chamber, e.g., so as to selectively permit the pressurized composition to flow from the second chamber (i.e.. the pressure control device) into the first chamber as the fluid composition is dispensed, in order to maintain a substantially constant pressure within the first chamber. The spray dispensing device may be free of hydrocarbon propellants.
• The elimination of the use of any hydrocarbon propellants reduces or eliminates the detrimental environmental effects associated with use of such propellants in existing dispensing systems. In addition, in the present system the composition which may contain corrosive or strong oxidizing agents does not require being filled under pressure. Not working with or handling a pressurized corrosive and/or oxidizing composition is a significant advantage during manufacturing because it is much safer to work with and reduces manufacturing complexity. The present system instead provides a “bag-on-valve” or “bag-in-bottle” (used interchangeably herein) type dispensing system combined with a separate second chamber that serves as a pressure control device, so as to provide the non-hydrocarbon pressurized composition into the first chamber as needed. The pressurized composition employed may advantageously be air, nitrogen, carbon dioxide, or other relatively environmentally inert component (e.g. in gaseous or liquid phase), which is able to drive the fluid composition from the bladder upon the user actuating the actuator, as this pressurized composition flows through the outlet valve and into the first chamber.
• Another embodiment is directed to a spray dispensing device that does not include an internal piston. The device may include a first chamber defined by a container having non-linear sidewalls (e.g., where the chamber is non-cylindrical), in which the chamber has a transverse cross-section that varies along a vertical axis of the first chamber. The lack of an internal piston allows the chamber to have any desired shape, e.g., which may include contouring or other features for ornamentation, improved grip, or other purposes within the central body portion of the sidewall of the container defining the first chamber. By way of example, the central body portion of the sidewall of the container and the first chamber may be narrowed in its central portion, and wider towards the top and bottom ends. Numerous other contoured shapes are also possible. Such a shape in the interior of the first chamber is possible where the spray dispensing device does not rely on a piston movable within the first chamber to drive dispensing of the fluid composition from the dispensing device.
• The device may further include a bladder contained within the first chamber, housing a fluid composition, an actuator in fluid communication with the first chamber, a second chamber which acts as a pressure control device, and a pressurized composition contained within the second chamber. The pressurized composition may comprise: air, nitrogen, carbon dioxide, inert components (e.g. argon) and any combinations thereof. The pressurized composition may be in solid, liquid or gaseous phases and any combinations thereof. Any of the forgoing pressurized composition materials may be in liquid or gaseous phase. An outlet valve may provide selective communication between the second chamber (i.e., the pressure control device) and the first chamber.
• Further features and advantages of the present invention will become apparent to those of ordinary skill in the art in view of the detailed description of preferred embodiments below.
BRIEF DESCRIPTION OF THE DRAWINGS
• To further clarify the above and other advantages and features of the present invention, a more particular description of the invention will be rendered by reference to specific embodiments thereof which are illustrated in the drawings located in the specification. It is appreciated that these drawings depict only typical embodiments of the invention and are therefore not to be considered limiting of its scope. The invention will be described and explained with additional specificity and detail through the use of the accompanying drawings in which:
• FIG.1 is a perspective view of an exemplary spray dispensing device;
• FIG.2 is a cut-away view of the spray dispensing device ofFIG.1;
• FIG.3 shows a user actuating the actuator on the spray dispensing device, so that the fluid composition is dispensed from the spray dispensing device onto a shower wall;
• FIG.4 is a cross-sectional view through the spray dispensing device ofFIG.3, with arrows showing flow of pressurized composition from the second chamber into the first chamber, and additional arrows showing application of forces that result in dispensing of the fluid composition from the bladder and actuator as an aerosol;
• FIG.5 is a cross-sectional view similar to that ofFIG.4, but showing an alternative configuration.
• FIG.6 is a block diagram showing an aspect of the present invention.
• FIG.7 is a block diagram showing another aspect of the present invention.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTSI. Definitions
• Before describing the present invention in detail, it is to be understood that this invention is not limited to particularly exemplified systems or process parameters that may, of course, vary. It is also to be understood that the terminology used herein is for the purpose of describing particular embodiments of the invention only, and is not intended to limit the scope, of the invention in any manner.
• All publications, patents and patent applications cited herein, whether supra or infra, are hereby incorporated by reference in their entirety to the same extent as if each individual publication, patent or patent application was specifically and individually indicated to be incorporated by reference.
• The term “comprising” which is synonymous with “including,” “containing,” or “characterized by,” is inclusive or open-ended and does not exclude additional, unrecited elements or method steps.
• The term “consisting essentially of” limits the scope of a claim to the specified materials or steps “and those that do not materially affect the basic and novel characteristic(s)” of the claimed invention.
• The term “consisting of” as used herein, excludes any element, step, or ingredient not specified in the claim.
• It must be noted that, as used in this specification and the appended claims, the singular forms “a,” “an” and “the” include plural referents unless the content clearly dictates otherwise. Thus, for example, reference to a “surfactant” includes one, two or more surfactants.
• The compositions described herein may provide sanitization, disinfection, or sterilization. As used herein, the term “sanitize” shall mean the reduction of contaminants in the inanimate environment to levels considered safe according to public health ordinance, or that reduces the bacterial population by significant numbers where public health requirements have not been established. By way of example, an at least 99% reduction in bacterial population within a 24 hour time period is deemed “significant” Greater levels of reduction are possible, as are faster treatment times (e.g., within 1 minute), when sanitizing. As used herein, the term “disinfect” shall mean the elimination of many or all pathogenic microorganisms on surfaces with the exception of bacterial endospores As used herein, the term “sterilize” shall mean the complete elimination or destruction of all forms of microbial life and which is authorized under the applicable regulatory laws to make legal claims as a “sterilant” or to have sterilizing properties or qualities. Some embodiments of the present compositions provide for at least a 3 or more log reduction in bacterial population within a designated time period. A 3-log reduction is equivalent to at least a 99.9% reduction, a 4-log reduction is equivalent to at least a 99.99% reduction, a 5-log reduction is equivalent to at least a 99.999% reduction, etc.
• Unless otherwise stated, all percentages, ratios, parts, and amounts used and described herein are by weight.
• Numbers, percentages, ratios, or other values stated herein may include that value, and also other values that are about or approximately the stated value, as would be appreciated by one of ordinary skill in the art. A stated value should therefore be interpreted broadly enough to encompass values that are at least close enough to the stated value to perform a desired function or achieve a desired result, and/or values that round to the stated value. The stated values include at least the variation to be expected in a typical manufacturing or formulation process, and may include values that are within 10%, within 5%, within 1%, etc. of a stated value. Furthermore, the terms “substantially”, “similarly”, “about” or “approximately” as used herein represent an amount or state close to the stated amount or state that still performs a desired function or achieves a desired result. For example, the term “substantially” “about” or “approximately” may refer to an amount that is within 10% of, within 5% of, or within 1% of, a stated amount or value.
• Some ranges may be disclosed herein. Additional ranges may be defined between any values disclosed herein as being exemplary of a particular parameter. All such ranges are contemplated and within the scope of the present disclosure.
• In the application, effective amounts are generally those amounts listed as the ranges or levels of ingredients in the descriptions, which follow hereto. Unless otherwise stated, amounts listed in percentage (“%′s”) are in weight percent (based on 100% active) of the fluid composition.
• Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which the invention pertains. Although a number of methods and materials similar or equivalent to those described herein can be used in the practice of the present invention, the preferred materials and methods are described herein.
II. Introduction
• In an aspect, the present invention is directed to a spray dispensing device including a first chamber defined by a container (e.g., which may include contoured, non-cylindrical sidewalls), a bladder contained within the first chamber that houses a fluid composition (e.g.. a bleach composition), and an actuator in fluid communication with the first chamber (e.g., or more particularly, in fluid communication with the interior of the bladder) so as to allow dispensing of the fluid composition from the bladder when the actuator is actuated (e.g., pressed). A pressurized composition may be contained within a second chamber, which acts as a pressure control device. The pressure of the pressurized composition may be in a range of from about 70 psi to about 150 psi. An outlet valve may provide selective fluid communication between the pressure control device (i.e., the second chamber) and the first chamber.
• The present spray dispensing devices advantageously provide the ability to deliver a fluid composition including an oxidizing agent, or other fluid composition which may include a corrosive agent, or other component exhibiting other incompatibility issues, as a continuous spray aerosol. Such aerosol dispensing of bleach and similar compositions has not previously been possible as a practical matter. The claimed spray dispensing devices may provide the fluid composition prepackaged within the spray dispensing device (e.g., within the bladder thereof). The disclosed configuration ensures that the bleach or other fluid composition does not contact the interior of the container of the spray dispensing device, which provides several advantages, making delivery of such a bleach aerosol or similar low compatibility fluid composition possible. In addition to providing a configuration where the fluid composition does not contact the interior of the container, there is no contact between any propellant employed in dispensing the fluid composition and the fluid composition itself. Thus, dispensing of the pure fluid composition itself is possible.
• In addition, in one embodiment of the invention no hydrocarbon propellants (e.g., isopentane, propane, isobutane, pentane, butane, fluorinated hydrocarbons, and the like) are needed. For example, the employed pressurized component (rather than a conventional propellant), as stored in the second chamber, may comprise: air, nitrogen, carbon dioxide, nitrogen, inert components (e.g. argon) and any combinations thereof. The pressurized composition may be in solid, liquid or gaseous phases and any combinations thereof. As the pressurized component does not contact the fluid composition itself (rather only the bladder), there is no risk of reactions, contamination, degradation, or the like that may otherwise occur with traditional aerosol systems in which a propellant and fluid composition being dispensed are mixed with or one another or otherwise contact one another.
• The disclosed dispensing devices also advantageously allow dispensing the fluid composition even when the container is in an inverted position, or any position in between inverted and a normal upright orientation. Where dispensing does not rely on the inclusion of any internal piston, the sidewalls of the container may be other than cylindrical. For example, various contours are possible for ornamentation, for enhanced grip, or for other purposes. Such configurations also allow the second chamber which acts as the pressure control device to be oriented as desired, and not necessarily in axial alignment with the longitudinal axis of the device, or with the bladder. In other words, in previous configurations, there has always been axial alignment with the various components in the spray dispensing system (i.e., all aligned with the longitudinal axis). In another embodiment of the invention, the pressure control device could be provided outside of or separate from the dispensing device and could be attached/coupled to the device immediately prior to use. Alternatively, the pressure control device may be coupled to the dispensing device and still be outside or separate from the dispensing device. Alternatively, the pressure control device maybe inside the spray dispensing system, but not attached to the interior of the dispensing device such that it may be created and/or filled externally prior to being placed in the dispensing device. In this embodiment, the pressure control device may have an outlet valve attached to it so that is fully functionally prior to being placed into the dispensing device. When the pressure control device has an outlet valve attached to the pressure control device, the container may be created without an outlet valve attached to any of the container walls. The present configurations allow for the alignment and non-separable arrangement requirements to be eliminated, freeing the configuration from such necessary alignment and detachment/separation problems between the dispensing container, the outlet valve and the pressure control device.
III. Exemplary Dispensing Systems
• FIGS.1-4 show an exemplaryspray dispensing device100 which may be prefilled (e.g.. during manufacture) with any desired fluid composition. In some embodiments, the fluid composition may include an oxidizing agent (e.g., one or more of hypochlorites, halogens, peroxides, hypochlorous acid, or the like). Examples of hypochlorites include, but are not limited to alkali metal hypochlorites (e.g.. sodium hypochlorite, potassium hypochlorite, and the like, alkali earth metal hypochlorites (e.g., calcium hypochlorite, magnesium hypochlorite, and the like). Combinations of hypochlorites may of course be employed. An example of a peroxide is hydrogen peroxide, although other peroxides may also be employed.
• The spray dispensing device configurations disclosed herein may also be used for dispensing fluid compositions that include other components that are corrosive or otherwise exhibit poor compatibility with metals or other materials typically employed in an aerosol dispenser. The spray dispensing devices may also be used for dispensing fluid compositions that do not include any such low-compatibility or corrosive components.FIG.2 is a cut-away view into thedispensing device100, better showing how thefluid composition102 may be stored within aninternal bladder104 disposed withinfirst chamber106 defined bycontainer108. Anactuator110 may be provided, configured to selectively provide fluid communication with the interior of thebladder104 withinfirst chamber106.Actuator110 may be configured to dispense thefluid composition102 frombladder104 upon pressing or otherwise actuatingactuator110.
• Actuator110 may be any of a wide variety of mechanisms configured to dispensefluid composition102 frombladder104, as will be appreciated by those of skill in the art. Such actuator may be capable of selectively dispensing thefluid composition102 frombladder104 upon the consumer pressing a button or the like onactuator110 to initiate dispensing. Such actuators will be apparent to those of skill in the art, and may be available from GUALA (Spinetta Marengo. Italy), AIROPACK (Waalwijk Netherlands), and other suppliers.
• As perhaps best seen inFIG.2, asecond chamber112 may also be provided, e.g., withincontainer108. separated fromfirst chamber106.Second chamber112 acts as a pressure control device by which apressurized composition114 contained withinsecond chamber112 may be released as needed intofirst chamber106 throughoutlet valve116, which provides fluid communication between thesecond chamber112 and thefirst chamber106 when a pressure infirst chamber106 drops below a predetermined threshold value at which theoutlet valve116 is configured to permit one-way passage ofpressurized composition114. For example, thepressurized composition114 withinsecond chamber112 may be at a first pressure that is higher than the pressure withinfirst chamber106. Theoutlet valve116 may be configured to regulate flow of thepressurized composition114 fromsecond chamber112 intofirst chamber106. so as to maintain a given second pressure withinfirst chamber106 over the life of thespray dispensing device100, until allfluid composition102 has been dispensed. For example, by substantially constant, it is meant that the pressure within the first chamber may remain within 25%, within 20%, within 10%, or within 5% of a desired target value (e.g., about 40 psi).
• By way of example, theoutlet valve116 may be configured as a one-way valve that automatically allows flow of thepressurized composition114 fromsecond chamber112 when the pressure within thefirst chamber106 drops below a specified threshold value. In this way,pressurized composition114 fromsecond chamber112 is automatically delivered intofirst chamber106 as needed to maintainfirst chamber106 at the desired pressure, without any input by the consumer. Such pressure in thefirst chamber106 may be selected by the manufacturer to provide a desired spray or aerosol pattern when dispensingfluid composition102, as the pressure of thefirst chamber106 drives dispensing of thefluid composition102 inbladder104 upon actuation ofactuator110.
• One advantage of providing the configuration with a pressurizedfirst chamber106, and aninternal bladder104 connected toactuator110, through whichfluid composition102 is dispensed is thatfluid composition102 may be dispensed even when thecontainer108 is in an inverted position, or any position in between inverted and a normal upright orientation as shown in the drawings. Furthermore, as will be appreciated, there is no requirement for a dip tube as is often found within many spray dispensing devices. For example, in at least some embodiments, no dip tube that typically extends from theactuator110 into the reservoir offluid composition102, e.g., down to a bottom of the reservoir offluid102 is needed. This is becauseflexible bladder104 progressively collapses aboutfluid composition102 andactuator110 asfluid composition102 is dispensed, and the volume thereof inbladder104 decreases. Thus, even without such a dip tube, the configuration may allow a very high fraction offluid composition102 to be dispensed over the life of the spray dispensing container (e.g.. at least 90%, at least 95%, at least 97%, at least 98%, or at least 99%.
• In addition, the configuration may allow a relatively high fraction of the volume defined withincontainer108 to actually be filled withfluid composition102 which can be dispensed therefrom. For example, the dispensable volume of fluid composition may be at least 50%, at least 55%, at least 60%, at least 65%, at least 70%, at least 75%, at least 80%, at least 85%, or at least 90% of the volume defined withincontainer108. Such a configuration prevents a situation undesirable to consumers, where a large appearingcontainer108 only holds for dispensing a relatively small volume of fluid composition. Such can be frustrating to consumers.
• By way of example, the pressure withinfirst chamber106 may be maintained at a pressure above atmospheric pressure (in order to provide the driving force needed to dispense the fluid composition frombladder104, out of device100). Pressure infirst chamber106 may be in a range from about 20 psi to about 70 psi, from about 25 psi to about 60 psi, or from about 30 psi to about 50 psi. In an embodiment, such pressures may be relative to atmospheric pressure (i.e., psig).
• The pressure withinsecond chamber112 may be provided as manufactured at an initial value that is greater than the pressure maintained withinfirst chamber106. For example, in an embodiment, the initial pressure (i.e., before dispensing any fluid composition102) withinsecond chamber112 may be from about 70 psi to about 150 psi, from about 80 psi to about 150 psi, from about 80 psi to about 120 psi, or from about 100 psi to 120 psi. As described above, the pressure values in the second chamber may be psig.
• In embodiments where a liquid pressurized composition is provided within the second chamber, substantially higher pressures may be needed to maintain the liquid phase at temperatures typical for use and storage of the spray dispensing devices. Where a liquid pressurized component is employed, thepressurized component114 may be in the liquid phase as stored in the second chamber, and may undergo a phase change to gaseous form after or as it passes through theoutlet valve116 into the first chamber (which is at a lower pressure). Such gaseous form of thepressurized component114 will advantageously apply the desired pressure against the flexiblecollapsible bladder104 storingfluid composition102 so as to drive dispensing offluid composition102 upon actuation ofactuator110.
• It will be apparent that the second chamber acts as a pressure control device, such that the actual pressure within thesecond chamber112 may progressively decrease over the life ofdevice100, as pressurized composition withinsecond chamber112 is released throughoutlet valve116 intofirst chamber106. Thus, as thefluid composition102 is dispensed, the pressure withinsecond chamber112 may progressively decrease aspressurized composition114 is passed throughoutlet valve116 intofirst chamber106, e.g., to maintainfirst chamber106 at a desired pressure sufficient to forcefluid composition102 withinbladder104 out ofdevice100 throughactuator110 in a desired spray pattern. The dispensing pattern may dispense thefluid composition102 as an aerosol of very small droplets. Dispensing a liquid bleach composition as such an aerosol is particularly advantageous, as no such product has been commercially available to date.
• By way of example, thepressurized composition114 may include air, nitrogen, carbon dioxide, or combinations thereof. In an embodiment, thepressurized composition114 may be provided in the second chamber in liquid phase. In other embodiments, it may be provided in gaseous phase. In one embodiment, no hydrocarbon propellants (e.g., isopentane, propane, isobutane, pentane, butane, fluorinated hydrocarbons, and the like) are needed, and no direct contact of thefluid composition102 with thepressurized composition114 need occur. In addition, it will be apparent from the above described structure that thepressurized composition114 remains within thecontainer108. and is not required to be dispensed at all from thecontainer108. Such a configuration of course also prevents release of thepressurized composition114 into the atmosphere at all, as it remains sealed within thecontainer108, even after thespray dispensing device100 has reached the end of its useful life. If desired, such pressurized composition could be recovered and reused by collecting the spent spray dispensing devices, and recovering the pressurized component for reuse, or recycling, if desired. That said, because in this embodiment no hydrocarbon propellants having questionable environmental safety are employed, such will not typically be necessary, as the spent pressurized composition may be: air, nitrogen, carbon dioxide, nitrogen, inert components (e.g. argon) and any combinations thereof. The pressurized composition may be in solid, liquid or gaseous phases and any combinations thereof (e.g. liquid nitrogen, carbon dioxide gas, solid carbon dioxide, etc.). As described, thefluid composition102 may advantageously be stored withinbladder104, which may be formed from a material that is specifically selected to be compatible with the particular fluid composition. For example, where the fluid composition includes an oxidizing agent, such as a halogen, a hypochlorite, hypochlorous acid, hydrogen peroxide, another peroxide, or combinations thereof, the bladder may be formed from an ethylene vinyl alcohol (EVA) material configured as a thin barrier film. Such EVA material may also be suitable for use with other fluid compositions stored inbladder104. Other bladder materials may of course also be employed, so long as care is taken to ensure that the selected bladder material is compatible with thespecific fluid composition102 stored therein. In some embodiments, the interior surface of thebladder104 could be coated with a barrier layer to allow an otherwise less compatible material to be used for thebladder104. By “compatible”, it is meant that the bladder material contacting thefluid composition102 does not result in significant degradation, corrosion, dissolution, or other attack of the bladder material by thefluid composition102 to be dispensed. Similarly, it is meant that the bladder material does not contaminate or otherwise alter the desired properties of thefluid composition102 stored within thebladder104. For example, a bladder material that inactivates a hypochlorite or other bleach composition would be undesirable where thefluid composition102 being dispensed is a hypochlorite or other bleach.
• Because the configuration of thespray dispensing device100 ensures that thefluid composition102 does not directly contact the interior ofcontainer108, the container may be fabricated from materials that are attacked or otherwise incompatible with the fluid composition102 (e.g., one or more metals). In an embodiment, the container may be made from a plastic material, such as polypropylene, polyethylene (including HDPE), polycarbonate, or combinations thereof. In another embodiment, the container may be made from one or more metal materials. Both metal and plastic materials could also be employed (e.g., for different parts of container108). Similarly, the actuator may be made from suitable plastic materials, including, but not limited to those identified above. Such may be preferred as the fluid composition will come into contact with the at least some of the components ofactuator110, particularly where the fluid composition includes an oxidizing agent or corrosive or low compatibility agent. Where there are not compatibility concerns with the fluid composition and metal, at least some of the actuator components could be made of metal.
• As is apparent from the structure described in conjunction with the Figures, no internal piston is needed withincontainer108. Because no internal piston is needed (dispensing instead relies on the bag-on-valve configuration ofbladder104,actuator110. and pressurized first chamber106), the container itself can have a contoured configuration not possible with containers that rely on an internal piston for dispensing. For example, as seen inFIGS.1-4, thesidewalls118 ofcontainer108 may be non-linear, including a contoured, curved configuration within the central body portion (or elsewhere) insidewall118.FIGS.1-4 show a configuration where thecentral body portion120 may be narrower in width than the adjacent upper and/orlower portions122,124. respectively, ofsidewall118 ofcontainer108.FIG.4 shows how such contoured configurations allow the transverse cross-section of thefirst chamber106 to vary along the vertical axis A of the chamber, due to thenon-linear sidewall118. Numerous other contoured shapes will be apparent to those of skill in the art that may be employed, because no internal piston is needed. For example, a contour may be provided which facilities improved ergonomic gripping ofcontainer108 within the hand of a consumer (e.g., seeFIG.3) facilitating easier dispensing.
• As seen inFIGS.2 and4, a plug orvalve126 may be provided inbottom wall128. or elsewhere withinsecond chamber112. in order to allow charging of thepressurized composition114 intosecond chamber112 during manufacture. Thepressurized composition114 may thus be filled intosecond chamber112 during manufacture through a valve (e.g., a one-way valve), or a hole which is subsequently stopped with a plug. Alternatively, a solid carbon dioxide composition could be added to the second chamber and then sealed on the bottom to create a pressurized composition without the need for filling the second chamber through a valve. Various other techniques for fillingsecond chamber112 will be apparent to those of skill in the art, and are within the scope of the present disclosure.
• An alternative embodiment is shown inFIG.5. For example, as shown inFIG.5,bottom128 may be sealed, e.g.. with no inlet forpressurized composition114. Rather, the composition (e.g.. liquid nitrogen and/or liquid carbon dioxide) could be introduced intosecond chamber112 during manufacture, followed by sealing ofsecond chamber112, as shown. For example,bottom wall128 could be provided separate fromsidewall118, to be welded or otherwise secured thereto in a sealed arrangement. In another embodiment, aplug126′ (e.g., elastomeric, plastic, metal, or other material) could be inserted into an associated opening throughbottom wall128. Where the plug is plastic or metal, theplug126′ (e.g., similar to plug126) could be welded or otherwise permanently sealed in place.
• Such a configuration may be particularly suited for apressurized composition114 that is initially charged intosecond chamber112 in liquid a liquid form (e.g., liquid nitrogen and/or liquid carbon dioxide). A solid form ofsuch composition114 may also be suitable (e.g., placement of dry ice (i.e., solid CO₂) or solid nitrogen into second chamber112) for initial charging intosecond chamber112. Once charged, thechamber112 may be sealed (e.g., weldingbottom wall128 and/or plug126′ into place). Once charged, the composition114 (e.g., which may initially be in a solid or liquid phase) may undergo a phase transition to the gaseous phase, providing the desiredpressurized composition114 for regulated release throughoutlet valve116 intofirst chamber106. Wherecomposition114 is initially in solid or liquid phase, care should of course be taken to ensure the charged amount is appropriate to provide the desired pressure withinsecond chamber112 once the initially solid orliquid composition114 undergoes a phase change to be in gaseous phase.
• Referring toFIG.6, in one embodiment, the pressure control device210 is provided outside of or separate from thedispensing device200. The pressure control device could be attached/coupled to the device immediately prior to use. Alternatively, the pressure control device210 may be coupled to thedispensing device200 and still be outside or separate from thedispensing device200. Referring toFIG.7, the spray dispensing system ordevice300 includes awall310 defining an interior. Apressure control device320 maybe inside thespray dispensing system300, but not attached to the interior of thedispensing device300 such that it may be created and/or filled externally prior to being placed in thedispensing device300. In one embodiment, thepressure control device320 may have anoutlet valve330 attached to it so that it is fully functional prior to being placed into thedispensing device300. When thepressure control device320 has anoutlet valve330 attached to thepressure control device320, the container may be created without an outlet valve attached to any of the container walls.
• Several suppliers would have the capability to manufacture the device as described herein (or components thereof), in light of the present disclosure. For example, AIROPACK, GUALA, and other suppliers would have the capability to produce the container, bladder, actuator, outlet valve, and other components described herein, if presented with the present disclosure. Additional details of exemplary bag-on- valve and pressure control devices, features of which may be incorporated herein are described in U.S. Pat. No. 8.292.121 and U.S. Publication Nos. 2001/0002598 and 2014/0183229, each of which is herein incorporated by reference in its entirety.
• Thefluid composition102 to be dispensed may be any conceivable composition capable of being dispensed through the described structure. In some embodiments, the fluid composition may be a cleaning composition that may include an oxidizing agent. Such compositions may often include one or more surfactants. An organic or mineral acid (e.g.. to aid in cleaning) may be included. One or more of a chelating agent, or one or more other adjuncts selected from the group consisting of fragrances, dyes, preservatives, humectants, solvents, polymers, pH adjusters, solubilizers, and combinations thereof may also be provided.
• The composition may have a viscosity so that it may readily be dispensed as described herein. Liquid compositions may have a viscosity of less than 10,000 cps, or less than 1,000 cps. It may also be possible to dispense gel or foam compositions from the spray dispensing devices described herein, and such is within the scope of the disclosure. In one embodiment, the foam or gel may be dispensed without the need for a propellant or with a very small amount of propellant (e.g less than 20% propellant by weight, less than 15% propellant by weight, less than 10% propellant by weight, less than 5% propellant by weight, less than 2% propellant by weight, etc.)
• In an embodiment, e.g.. where the composition contains a hypochlorite component, the pH may be from about 8 to about 14. from about 9 to about 13, or from about 10 to about 13 (about 8, about 9, about 10, about 11, about 12, about 13. or about 14. or any range defined between any such values). A hypochlorite oxidizing agent may have increased stability at such elevated pH values. In other embodiments, and depending on the particular components included in the fluid composition, the composition may have a pH from about 1 to about 8. or from about 4 to about 8 (about 1, about 2, about 3, about 4, about 5, about 6. about 7, or about 8, or any range defined between any such values).
• In one embodiment, the fluid composition may include one or more surfactants. Examples include, but are not limited to sulfates, sulfonates, betaines, alkyl polysaccharides, (e.g., alkyl polyglycosides, also known as alkyl polyglucosides), amine oxides, tweens, alcohol ethoxylates, and combinations thereof. One or more of the selected surfactants may provide foam building characteristics. The surfactant concentration may be any desired concentration. Examples may include up to 80%, up to 50%, up to 30%, up to 20%, or less than 10%, less than 5%, less than 4%, less than 3%, or less than 2% by weight, depending on the characteristics desired.
• The surfactant(s) may include nonionic, anionic, cationic, ampholytic, amphoteric, zwitterionic surfactants, and mixtures thereof. A typical listing of anionic, ampholytic, and zwitterionic classes, and species of these surfactants, is given in U.S. Pat. No. 3.929.678 to Laughlin. A list of cationic surfactants is given in U.S. Pat. No. 4.259.217 to Murphy. Various alkyl polysaccharide surfactants are disclosed in U.S. Pat. No. 5.776.872 to Giret et al.; U.S. Pat. No. 5,883,059 to Furman et al.; U.S. Pat. No. 5,883,062 to Addison et al.; and U.S. Pat. No. 5.906.973 to Ouzounis et al. U.S. Pat. No. 4,565,647 to Llenado. Various nonionic surfactants can be found in U.S. Pat. No. 3,929,678 to Laughlin. Each of the above patents is incorporated by reference.
• An organic acid (e.g.. citric acid), or relatively weaker mineral acid (e.g., phosphoric acid) may be included for cleaning. Where included, such an acid may be included in an amount of less than 5%, less than 4%, less than 3%, less than 2% (e.g., from 1% to 2%, or from greater than 0.5% to about 1.5%).
• Exemplary organic acid may include 2-hydroxycarboxylic acids or mixtures of two or more acids. Examples of such acids include, but are not limited to, tartaric acid, citric acid, malic acid, mandelic acid, oxalic acid, glycolic acid, lactic acid, and acetic acid.
• pH adjusters (e.g., sodium hydroxide, or another hydroxide), if present, may typically be included in an amount of less than 3%, less than 2%, less than 1% (e.g., from about 0.5% or greater than 0.5% to 1%). For adjusting pH downward, any of the above described acids may also be suitable for use.
• Solubilizers (e.g., to solubilize a fragrance or other oil), if present, may typically be included in an amount of less than 1%, less than 0.5%, less than 0.3% (e.g.. from about 0.01 % to 0.5%).
• Dyes, fragrances, and/or preservatives, if present, may typically be included in an amount of less than 1%, or less than 0.5%, Oxidizing agents, or any other components mentioned herein may be present in amounts of less than 10%, less than 5%, less than 4%, less than 3%, less than 2%, less than 1%, less than 0.5%, or less than 0.25%. The fluid composition may be formulated as a ready-to-use composition (e.g., with less than 1%, less than 0.5%, or less than 0.25% oxidizing agent), although a concentrate formulation intended to be diluted (e.g., with water) may also be possible.
• Specific compositions may be provided for kitchen use, for bathroom use, or for other specific or general uses. In some embodiments, the compositions may be effective at cleaning, and removing soils typically present in showers and bathtubs, such as, but not limited to soap scum, hard water stains, mildew, etc. The composition could also be used in other cleaning environments, e.g.. such as kitchens, bathroom sinks, walls, etc. In a kitchen environment, the composition may be effective at cleaning and removing kitchen grease. The composition could be sprayed on bathroom countertops, kitchen countertops, sinks, tables, stovetops, dishes, windows, mirrors, or floors, to name just a few.
• Without departing from the spirit and scope of this invention, one of ordinary skill can make various changes and modifications to the invention to adapt it to various usages and conditions. As such, these changes and modifications are properly, equitably, and intended to be, within the full range of equivalence of the following claims.

Claims (22)

1. A spray dispensing device, comprising:

(a) a container having a side wall, the container comprising:

(i) a first chamber defined by the side wall; and

(ii) a second chamber fluidly coupled to the first chamber, the second chamber being inside of the container and not attached to an interior of the spray dispensing device;

(b) a flexible bladder contained within the first chamber and configured to hold a fluid composition, wherein the flexible bladder is formed of a material compatible with the fluid composition;

(c) an actuator, formed of a material that is compatible with the fluid composition, in fluid communication with the flexible bladder and configured to dispense the fluid composition from the flexible bladder upon actuation of the actuator; and

(d) an outlet valve coupled to the second chamber so that the second chamber is fully functional prior to being placed into the dispensing device;

wherein the fluid composition does not directly contact an interior surface of the container;

wherein the first chamber is configured to have a first pressure and the second chamber is configured to have a second pressure, the second pressure being greater than the first pressure; and

wherein upon actuation of the actuator, the container is configured to dispense the fluid composition from the flexible bladder while the second chamber fluidly communicates with the first chamber through the outlet valve.

2. The spray dispensing device ofclaim 1, wherein the second chamber houses a pressurized composition at a pressure in the range from about 70 psi to about 150 psi.

3. The spray dispensing device ofclaim 2, wherein the pressurized composition is selected from the group consisting of air, nitrogen, carbon dioxide, argon and combinations thereof.

4. The spray dispensing device ofclaim 1, wherein the first chamber maintains a substantially constant pressure of about 25 psi to about 60 psi while the fluid composition is dispensed from the flexible bladder over a life of the spray dispensing device.

5. The spray dispensing device ofclaim 1, wherein a constant pressure within the first chamber is maintained in the range of about 20 psi to about 70 psi.

6. The spray dispensing device ofclaim 1, wherein the outlet valve is configured to allow a pressurized composition in the second chamber to flow to the first chamber, wherein the pressurized composition remains in the container.

7. The spray dispensing device ofclaim 1, wherein the fluid composition comprises an oxidant and the interior surface of the container comprises a metal.

8. The spray dispensing device ofclaim 1, wherein the fluid composition includes one or more oxidizing agents selected from the group consisting of halogens, hypochlorites, hypochlorous acid, hydrogen peroxide, other peroxides, and combinations thereof.

9. The spray dispensing device ofclaim 1, wherein the interior surface of the container is incompatible with the fluid composition disposed within the flexible bladder.

10. The spray dispensing device ofclaim 1, wherein the second chamber contains a pressurizing composition.

11. (canceled)

12. The spray dispensing device ofclaim 10, wherein the pressurized composition comprises a liquid phase or a solid phase.

13. The spray dispensing device ofclaim 1, wherein the container is made from a plastic material selected from the group consisting of polypropylene, polyethylene, polycarbonate, and combinations thereof.

14. The spray dispensing device ofclaim 1, wherein the flexible bladder comprises an ethylene vinyl alcohol barrier film.

15. A spray dispensing device, comprising:

(a) a container having a non-linear side wall that has a curved exterior surface spanning along at least a portion of the longitudinal axis of the container, wherein a transverse cross-section of the container varies along the longitudinal axis of the container, the container comprising:

(i) a first chamber having a first pressure; and

(ii) a second chamber fluidly coupled to the first chamber and configured to hold a pressurized composition having a second pressure, the second chamber being provided separate from the dispensing device and coupled to the dispensing device prior to use; and

(b) a flexible bladder housed within the first chamber and configured to contain a fluid composition;

(c) an actuator in fluid communication with the flexible bladder and configured to dispense the fluid composition from the flexible bladder upon activation; and

(d) an outlet valve positioned between the first chamber and the second chamber;

wherein the second pressure is greater than the first pressure;

wherein the pressurized composition does not contact the fluid composition as the pressurized composition flows into the first chamber from the second chamber through the outlet valve;

wherein upon actuation of the actuator, the container is configured to dispense the fluid composition from the flexible bladder while the second chamber fluidly communicates with the first chamber through the outlet valve.

16. (canceled)

17. The spray dispensing device ofclaim 15, wherein the pressurized composition comprises a liquid phase or a solid phase.

18. The spray dispensing device ofclaim 15, wherein the fluid composition includes a bleach composition and the flexible bladder is formed of a material compatible with the bleach composition.

19. The spray dispensing device ofclaim 15, wherein the first chamber maintains a substantially constant pressure of about 25 psi to about 60 psi while the fluid composition is dispensed from the flexible bladder over a life of the spray dispensing device.

20. A spray dispensing device, comprising:

(a) a container having a side wall, the container comprising:

(i) a first chamber having a first pressure; and

(ii) a second chamber fluidly coupled to the first chamber and configured to hold a pressurized composition having a second pressure, the second chamber being inside of the container and not attached to an interior of the spray dispensing device; and

(b) a flexible bladder housed within the first chamber and configured to contain a fluid composition, the fluid composition including an organic acid;

(c) an actuator in fluid communication with the flexible bladder and configured to dispense the fluid composition from the flexible bladder upon activation; and

(d) an outlet valve positioned between the first chamber and the second chamber;

wherein the second pressure is greater than the first pressure;

wherein the pressurized composition does not contact the fluid composition as the pressurized composition flows into the first chamber from the second chamber through the outlet valve; and

wherein upon actuation of the actuator, the container is configured to dispense the fluid composition from the flexible bladder while the second chamber fluidly communicates with the first chamber through the outlet valve.

21. The spray dispensing device ofclaim 20, wherein the organic acid is selected from the group comprising tartaric acid, citric acid, malic acid, mandelic acid, oxalic acid, glycolic acid, lactic acid, and acetic acid.

22. The spray dispensing device ofclaim 1, wherein the fluid composition includes an organic acid selected from the group comprising tartaric acid, citric acid, malic acid, mandelic acid, oxalic acid, glycolic acid, lactic acid, and acetic acid.

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