US20130075244A1 - Method and system for the torrefaction of lignocellulosic material - Google Patents

Abstract

A method for torrefaction of biomass using a torrefaction reactor vessel having stacked trays including: feeding the biomass to an upper inlet of the vessel; cascading the biomass down through the trays by passing the biomass through an opening in each of the trays to deposit the biomass on a lower tray; heating the biomass material with an oxygen deprived gas; extracting moisture from below each of the upper trays; as the biomass undergoes torrefaction in the lower trays retaining the gas with the biomass until the biomass falls from the stacked trays to a pile of biomass in the reactor vessel; exhausting gases containing organic compounds through a gas outlet at an elevation between the stacked trays and the pile of biomass, and discharging torrefied biomass from the torrefaction reactor vessel.

Description

RELATED APPLICATION
• This application claims priority to U.S. Provisional Patent Application Ser. No. 61/537,413 filed on Sep. 21, 2011 and 61/551,932 filed Oct. 27, 2011, respectively, the entirety of which are incorporated by reference.
BACKGROUND OF THE INVENTION
• The present invention generally relates to systems and methods for torrefaction of biomass material, such as wood, other lignocellulosic material, and biomass containing fossil based materials such as plastic fractions and refuse-derived fuel (RDF) (these materials are collectively referred to as “biomass material”). The invention more particularly relates to a pressurized reactor vessel for the torrefaction of biomass material.
• Torrefaction refers to the thermal treatment of biomass, usually in an oxygen deprived atmosphere at relatively low temperatures of 200 degrees Celsius (° C.) to 400° C., or 200° C. to 350° C., temperatures outside the range used for the process known as pyrolysis. An oxygen deprived atmosphere may have a low percentage of oxygen as compared to the percentage of oxygen in atmospheric air. A torrefaction process is described in U.S. Patent Application Publication US 2011/0041392. Torrefaction converts biomass material to an efficient fuel having increased energy density relative to the input biomass. Torrefaction removes moisture and volatile components from the biomass material. In torrefaction, the hemicellulose fraction of the biomass material is largely destructed producing moisture and volatile organic compounds (VOCs), while the cellulose fraction is depolymerized to produce a hydrophobic solid combustible fuel product with a higher energy density (on a mass basis) that the unprocessed biomass material. Further, the torrefied biomass material may be suited for grinding.
• Torrefaction changes the chemical structure of the biomass. Torrefied biomass may be burned in coal fired facilities (torrefied wood or biomass has the characteristics that resemble those of low rank coals) and can be compacted to high grade fuel pellets.
• Unpressurized reactor vessels with multiple trays have been used for torrefaction, as is described in U.S. Patent Application Publication 2010/0083530 (the '530 Application). The '530 Application recommends that torrefaction be performed in a reactor vessel operating at atmospheric pressure. In view of this recommendation, the '530 Application teaches that vessels should not be operated at above-atmospheric pressures. See '530 Application, para. 0061.
• Pressurized reactor vessels with multiple trays have been used in pulp mills to delignify pulp by oxidation. Examples of a pulping reactor vessel with multiple trays are disclosed in U.S. Pat. Nos. 3,742,735 ('735 Patent) and 3,660,225 ('225 Patent). Multiple tray vessels allow pulp to cascade through the vertical arrangement trays in the reactor. The trays allow the pulp to cascade in discrete batches down through the vessel. An oxygen rich environment in the pulping reactor promotes delignification and bleaching of the pulp. The '735 Patent and '225 Patent do not suggest using a pulping reactor vessel having an oxygen deprived environment for torrefaction of wood or other biomass material.
BRIEF DESCRIPTION OF THE INVENTION
• The vessel heats biomass on each tray such that the biomass is uniformly heated at each elevation in the vessel. To achieve uniform heating of the material on each tray the flow of oxygen deprived gas may be regulated in a range of 1 to 24 kilograms (kg) of gas per kilogram of dry biomass material being treated on the tray. The flow of the oxygen deprived gas through the trays may be continuous.
• The oxygen deprived gas is a heat transfer media that may add or remove heat from the biomass material for drying and torrefaction. The gas flows through the biomass material and the trays.
• The continuous flow of oxygen deprived gas through the material heats the biomass material, provided that the gas is at a higher temperature than the material. The constant flow of gas may also cool the material where the torrefaction reaction, which is exothermic, causes the material to become hotter than the gas. If the material overheats, the torrefaction reaction may over-react. The continuous flow of gas regulates the temperature of the biomass material in the vessel to be in a range of about the same temperature as the gas, or hotter, such as 20° C. to 30° C. hotter, than the biomass material.
• The biomass material may have a total retention period in the reactor vessel of 15 to 60 minutes. The retention period in the pressurized reactor vessel may be selected based on the type of biomass material processed in the vessel. For example, the total retention period in the vessel may be 15 to 25 minutes when wood is used as the biomass material.
• To achieve this retention period, the vessel includes a stack of trays through which includes the biomass. The biomass is dried in upper trays, and undergoes torrefaction in lower trays and in a lower chamber of the vessel. The torrefied biomass may be cooled in a lowermost portion of the vessel or in a screw conveyor or other device downstream of the outlet to the vessel.
• The stacked trays effectively form a succession of moving beds for the biomass in a compact vertical pressurized reactor vessel. Each tray may have a pie-segment shaped opening through which biomass material falls to the tray at the next lower elevation in the vessel. The biomass material falls through the opening after traveling around the tray. A scraper may slide the material around the tray toward the opening. The rotational speed of the scraper is selected to provide the desired retention period on each tray. The retention period may be uniform for each of the trays in the vessel. The retention period may be achieved by the selection of number of trays for each of drying and optionally torrefaction and the period necessary to perform each of these processes. Trays may not be needed for cooling or the torrefaction process as these processes may be performed on a pile of the biomass in an open interior chamber of the vessel. Cooling may be performed after discharging the torrefied biomass from the vessel. Alternatively, the trays may be used for the torrefaction or cooling processes within the vessel.
• The torrefaction process volatilizes mainly hemicellulose organic compounds in the biomass material. These compounds become entrained in the hot gases passing through the material and will condense in tar like deposits on cooler surfaces in the torrefaction reactor and in the conduits for the torrefaction gas. To reduce these deposits of organic compounds, the surfaces in the torrefaction reactor and gas exhaust conduits have been minimized. Further, the torrefaction gas is exhausted from regions of the reactor which have high temperatures to minimize the risk of organic compounds condensing on the surfaces of the exhaust conduits. In addition, the reactor and conduits may be insulated, such as with an insulation coating, to assist in maintaining high internal surface temperatures in the reactor and conduits. Further, the trays and inside surfaces of outer walls in the reactor vessel and associated gas conduits may be heated such as with heat traced elements.
• A pressurized vessel configured for subjecting biomass to a torrefaction process has been conceived, the vessel including: a cylindrical vessel wall extending substantially vertically, wherein the vessel wall is may be insulated; an insulated top plate to the vessel wall, forming a pressure seal between the wall and the plate; a rotatable shaft extending vertically down from the top plate, wherein the shaft includes an insulated upper coupling configured to connect to a motor drive system; a plurality of scraper devices each at a different elevation within the vessel and mounted to the shaft; a plurality of tray assemblies wherein each tray assembly is associated with one of the scraper devices such that the scraper device is immediately above a tray of the tray assembly; the tray is perforated, an open mesh or otherwise permeable to gas flow and impermeable to biomass, and each tray includes a discharge opening to transfer biomass from the tray and to a tray of a lower one of the tray assemblies; a chamber of the vessel below the tray assemblies is for subjecting the biomass to a torrefaction reaction; and a bottom discharge port of the vessel through which the torrefied biomass is discharged.
• Alternatively, the vessel may contain a cooling zone in a lower portion of the vessel below the tray assemblies and the chamber for torrefaction. The cooling zone may be configured to retain and cool the torrefied biomass before the biomass is discharged from the torrefaction reactor vessel. A lower zone of the vessel may also serve for passivation of active sites in the biomass by injecting atmospheric air or oxygen (O₂) generated by a nitrogen gas generator. The lower zone for passivation may be below or in place of a cooling zone in the vessel.
• A method has been conceived for torrefaction of biomass using a pressurized torrefaction reactor vessel having stacked trays including: feeding the biomass to an upper inlet of the vessel such that the biomass material is deposited on an upper tray of a vertical stack of trays in the reactor; as the biomass moves in the vessel on each of the stacked trays, heating and drying the biomass material with an oxygen deprived gas injected into the vessel under a pressure of at least 3 bar gauge (such as 3 to 20 bar gauge, or 3 to 15 bar gauge, or 3 to bar gauge); cascading the biomass down through the trays by passing the biomass through an opening in each of the trays to deposit the biomass on a lower tray; below the lowermost tray, depositing the biomass in a pile of biomass within the vessel; subjecting the biomass to torrefaction in the pile; discharging torrefied biomass from a lower outlet of the torrefaction reactor vessel; removing volatized organic compounds by exhausting gas from the stack of trays; cleaning the exhausted gas to remove the volatized organic compounds, and feeding the cleaned gas to the vessel.
• The oxygen deprived gas may be superheated steam, a gas with substantially less oxygen than in atmospheric air (such as 75% less) or a gas composed of about two percent (2%) or less of oxygen and 98% or more of other gases. The other gases may be a substantial portion of nitrogen with some reaction products from the torrefaction reactor, such reaction produces include carbon monoxide (CO), carbon dioxide (CO₂) and methane (CO₄). The biomass may be pressurized before being fed to the vessel with a pressure transfer device. The trays may be a mesh, screen or have perforations and the heating and drying of the biomass includes passing the gas through the biomass and the trays. A scraper device may rotate to move the biomass material across the tray in an arch-shaped path. Alternatively, the trays may rotate while the scraper device and biomass do not rotate about the vessel. The opening in each tray may be a triangular shaped section extending from the shaft in the vessel to the wall of the vessel.
• The gas may be injected into the stack of trays at multiple elevations wherein the gas is hotter when injected at a lower elevation than the gas injected at an upper elevation. The gases for drying the biomass may be injected at multiple elevations of the vessel, whereas the gases for torrefaction may only be injected at a single elevation of stack of trays such as at the uppermost tray used for torrefaction. At an elevation of the vessel below from which the gas is extracted, the biomass may continue to cascade down through the trays.
• A method for torrefaction of lignocellulosic biomass using a torrefaction reactor vessel having stacked tray assemblies has been conceived comprising: continuously feeding the biomass to an upper inlet to the torrefaction reactor vessel such that the biomass material is deposited on an upper tray assembly of a plurality of tray assemblies stacked vertically within the reactor; as the biomass moves in the vessel while supported by a tray of each tray assembly, heating and drying the biomass material with a gas injected into the vessel, wherein the gas is substantially non-oxidizing of the biomass, under a pressure of at least 3 bar gauge and at least a temperature in a range of 200° C. to 400° C. (such as 200° C. to 300° C. or 200° C. to 250° C. for drying gases and torrefaction gases that are hotter, such as 5° C. to 100° C. hotter, than the drying gases), and cascading the biomass down through the trays by passing the biomass through an opening in each of the trays to deposit the biomass on the tray of the next lower tray assembly; subjecting the biomass to a torrefaction reaction on the lower tray assembly and in a chamber of the vessel below the trays for drying, and discharging torrefied biomass from a lower outlet of the torrefaction reactor.
• The trays of each of the tray assemblies have a mesh, screen or have perforations, and the heating and drying of the biomass includes passing the gas through the biomass and the trays. In addition, each tray assembly may include a scraper device above the tray and an extraction gas chamber below the tray. The scraper device or tray rotates to move the biomass across the upper surface of the tray.
• The gas injected for torrefaction may be hotter, e.g., by 5° C. to 100° C., than the gas injected to the upper tray assemblies which are used for drying the biomass. Further, a cooling zone for the biomass may be below all of the tray assemblies and below the torrefaction chamber of the vessel, such in a discharge portion of the vessel. The cooling gas injected into the cooling zone may be cooler than the gas injected to the cooling tray assemblies, wherein the cooling zone cools the torrefied biomass to below a temperature at which the biomass auto-combusts when exposed to the atmosphere and the cooling tray assemblies cool the torrefied biomass to stop or suppress the torrefaction reaction.
• Gases extracted from the vessel may be circulated back to the vessel by blowers or compressors. The gases to be circulated may pass through a cyclone, condenser or filter to separate particles and condensable byproducts, such as organic compounds, before the gas flows to the compressor or blower. The gases circulated back to the torrefaction tray assemblies or torrefaction chamber may be heated before being injected into the vessel. A portion of the gases extracted from the tray assemblies may be directed to a combustor to generate heat energy to be added to the gases circulated back to the torrefaction tray assemblies. The extracted gases may also be used in other process steps associated with the torrefaction plant or facility.
• A pressurized reactor vessel has been conceived for subjecting biomass to a torrefaction process includes: a cylindrical vessel wall extending substantially vertically, wherein the vessel wall may be insulated; an insulated top plate to the vessel wall, forming a pressure seal between the wall and the plate; inlet nozzles injecting an oxygen deprived gas into the vessel, wherein the gas temperature of the oxygen deprived gas injected through the nozzles at upper elevations in the vessel is lower than the gas temperature of the oxygen deprived gas injected through the inlet nozzles at lower elevations; a rotatable shaft extending vertically down into the vessel from the top plate, wherein the shaft includes an insulated upper coupling configured to connect to a motor drive system; a stack of scrapers and trays extending into the vessel from the top plate, wherein each scraper is fixed to and rotates with the shaft and is immediately above an associated stationary tray, each tray is perforated to allow passage of gas and block passage of biomass and has an opening through which biomass falls; the stack includes a gas extraction chamber at an elevation below one of the trays and above one of the scrapers, wherein the gas extraction chamber receives the gas passing through the one of the trays and includes a gas extraction port to exhaust gas passing through the tray; the stack includes a plurality of lower scrapers and trays which are below the gas extraction chamber and have no gas extraction chamber between the lower scrapers and trays; a torrefaction chamber in the vessel below the stack, wherein the torrefaction chamber is receives a pile of biomass discharged from the stack; a torrefaction gas exhaust outlet on the vessel and at an elevation below the stack and above an upper surface of the pipe of biomass, and a biomass outlet at a lower region of the vessel. Torrefaction gases also may be injected into lower regions of the reactor vessel and specifically directly into the biomass pile in the vessel. Torrefaction gases injected into these lower regions may be at temperatures cooler, e.g., 5° C. to 20° C. cooler, than in the reactor vessel where gas is injected in the lower portion of the vessel, the lower torrefaction section, the gas temperature of the inert gas injected through the nozzles at a lower elevation in the vessel is lower than the gas temperature of the inert gas injected through the inlet nozzles at upper elevations. Also as an alternative in the reactor vessel, the trays may rotate while the scraper device and biomass do not rotate about the vessel.
• A method has been conceived for torrefaction of biomass using a torrefaction reactor vessel having stacked trays including: feeding the biomass to an upper inlet of the vessel such that the biomass material is deposited on an upper tray of a vertical stack of trays in the reactor; cascading the biomass down through the trays by passing the biomass through an opening in each of the trays to deposit the biomass on a lower tray; as the biomass moves through each of the stacked trays, heating and drying the biomass material with an oxygen deprived gas; extracting moisture containing gas having passed through the biomass on the upper trays wherein the extraction is immediately below each of the upper trays; as the biomass undergoes torrefaction in the lower trays of the stacked trays, retaining the gas with the biomass until the biomass falls from the stacked trays to a pile of biomass in the reactor vessel; exhausting gases containing organic compounds volatized by the torrefaction of the biomass through a gas outlet on the vessel at an elevation between the stacked trays and the pile of biomass, and discharging torrefied biomass from a lower outlet of the torrefaction reactor vessel.
• The torrefaction and optional cooling of the biomass material may occur in a pile of biomass in a lower region of the reactor vessel. To promote torrefaction in the pile, hot oxygen deprived gases may be injected into the vessel at the elevation of the pile such that the gasses rise through the pile to the region of the vessel between the pile and stack of trays. To allow for the torrefaction and optional cooling within the pile of biomass in the reactor vessel, gas nozzles in the wall of the vessel inject the oxygen deprived gas into the pile. The nozzles may be arranged on a center column in the vessel or extend through the sidewall of the vessel. To provide cooling of the biomass materials, a gas well below the torrefaction temperature, such as a gas at 200° C. or cooler, is injected through nozzles at the lowermost region of the vessel. This cool gas flows in a direction with the biomass material out the bottom of the vessel.
BRIEF DESCRIPTION OF THE DRAWINGS
• FIG. 1 is a side view of a pressurized torrefaction reactor.
• FIG. 2 is a perspective view of the top and side of the torrefaction reactor shown inFIG. 1.
• FIG. 3 is a cross-sectional, side view of the torrefaction reactor shown inFIG. 1.
• FIG. 4 is a perspective view of the top and side of the torrefaction reactor shown inFIG. 1, wherein a quarter section of the reactor has been removed to show internal components for illustrative purposes.
• FIG. 5 is a side view of a stack of tray assemblies, a top plate for the reactor and motor gear box assembly, which are inserted into an upper opening of the reactor shown inFIG. 1.
• FIG. 6 is a top and side view of the stack of tray assemblies shown inFIG. 5.
• FIG. 7 is a perspective view of a spoke wheel scraper component of a tray assembly.
• FIG. 8 is a perspective view of a top and side of tray plate component of a tray assembly.
• FIG. 9 is a perspective view of the bottom and side of the tray shown inFIG. 8.
• FIG. 10 is an isolation plate which is a component of the stack of tray assemblies, wherein the plate segments have been remove for illustrative purposes to show the chute and support frame of the isolation plate.
• FIG. 11 is a side view of the isolation plate shown inFIG. 10.
• FIG. 12 is a top down view of the isolation plate shown inFIG. 10.
• FIG. 13 is a perspective view showing the top and sides of a section of the support frame of the isolation plate shown inFIG. 10.
• FIG. 14 is a perspective view showing the bottom and side of a top plate for the torrefaction reactor.
• FIG. 15 is a cross-sectional view of an insulated coupling between a drive gearbox and a shaft for the stack of tray assemblies.
• FIG. 16 is a cross-sectional view of a bottom end of the shaft in the stack of tray assemblies.
• FIG. 17 is a cross-sectional view of a torrefaction reactor showing schematically the gas flows in and out of the reactor.
• FIG. 18 is a cross-sectional view of an upper portion of the torrefaction reactor and illustrates the drying of biomass in the reactor.
• FIG. 19 is a top down view of a mesh tray plate illustrated inFIG. 18 and used for drying biomass.
• FIG. 20 is a top down view of an isolation plate illustrated inFIG. 18 and having an enlarged portion showing the seal between the reactor and the isolation plate.
• FIG. 21 is a cross-sectional view of a portion of the torrefaction reactor corresponding to the lower section of the stack of tray assemblies and illustrates the torrefaction process in the stack.
• FIG. 22 is a top down view of a mesh tray plate illustrated inFIG. 21 and having an enlarged portion showing a seal between the tray plate and the reactor.
• FIG. 23 is a process flowchart illustrating the flow of biomass material and gases through a plant for torrefaction of the biomass.
• FIG. 24 is a process flowchart illustrating the torrefaction gas processing unit shown inFIG. 23.
DETAILED DESCRIPTION OF THE INVENTION
• FIGS. 1 to 4 illustrate an embodiment of apressurized treatment vessel10 for receiving, drying, treating by torrefaction, and cooling biomass material from a supply ofbiomass12 through anupper inlet14. The biomass may be wood chips, wood pulp or other comminuted cellulosic material. The biomass is dried, subjected to a torrefaction process and cooled to produce torrefied biomass.
• The biomass may be fully or partially dried in anexternal dryer15 before entering the vessel. After passing through the upper inlet, the biomass enters an upper tray in astack16 of trays. The trays provide a cascade of moving beds to dry and treat the biomass. The upper trays may be used to dry the biomass. Lower trays may be used to subject the biomass to a torrefaction treatment. An insulating tray may divide the drying trays from each other and the torrefaction trays.
• Theupper inlet14 to the pressurized vessel may be coupled to a continuous feed, pressure isolation device, such as a conventional rotary valve or plug screw feeder, to feed thebiomass12 to the pressurized vessel from a source of biomass at atmospheric pressure. The source ofbiomass12 may provide lignocellulose material that has been chipped or cut to have chip dimensions of a length between 10 to 50 millimeters (mm), a width of 10 to 50 mm, and a thickness of 5 to 20 mm. The chip thickness may be in other ranges, such as 20 to 30 mm, 15 to 25 mm, and 3 to 10 mm. These chip dimensions may be most suitable for wood. Other chip dimensions may be suitable depending on the type of wood or the non-wood material being used for the biomass.
• As an alternative, the vessel may be operated with an internal pressure at or near atmospheric pressure. A vessel operating at or near atmospheric pressure may not require the rotary valve or other type of airlock that is needed for pressurized vessels.
• Thebiomass12 may be fed to theinlet14 to the vessel at a temperature of 80° C. to 120° C., for example, or higher if adryer15 heats the biomass before entering the vessel. If there is no dryer, the biomass material may enter the vessel at ambient temperature. The biomass is heated in the vessel by a pressurized, hot and oxygen starved gas. The gases entering the vessel may be at a temperature in a range of 200° C. to 400° C. and used to dry the biomass and promote the torrefaction reaction. To promote the torrefaction reaction the gas may particularly be in any of the ranges of 250° C. to 400° C., 250° C. to 300° C., and 300° C. to 380° C. The gas entering to dry the biomass may be cooler than the gas temperature that promotes torrefaction. Gas temperature for drying may be in a range of 200° C. to 250° C. The volume of oxygen deprived gas supplied to the vessel may be in ranges of 1 to 8 kilogram (kg), 1 to 12 kg or 1 to 24 kg of gas to kg of dry biomass.
• Immediately below theupper inlet14 in thevessel10 may be a channel that receives the biomass from the inlet and directs the biomass to theupper tray18. The biomass falls on the upper tray and is moved in an arc path across the tray until the biomass passes over a leading edge of an opening in the upper tray. The biomass falls through the opening to the next lower tray. The process of moving the biomass over the surface of a tray, falling through an opening in the tray and depositing on the next lower tray is repeated for each tray in the stack of tray assemblies.
• The biomass falls from the stack of tray assemblies and forms a pile in thechamber20 of the pressurized vessel. While in the pile, the biomass remains an oxygen deprived gas atmosphere and continues its conversion to torrefied biomass. Below thechamber20, the vessel may converge in aconvergence zone22 in a manner to promote uniform downward flow of the biomass through the chamber and bottom of the vessel, and to abottom biomass outlet24 of the vessel.
• A large access orobservation port26 in the wall of the vessel provides access to the pile of biomass in thechamber20. In addition sensor ports, e.g., temperature and pressure probes may be arranged at various elevations and angular positions throughout the vessel.
• Hot oxygen deprivedgas28 may be injected into the vessel, such as through atop input manifold30 and throughgas injection nozzles32 arranged at the various elevations of thestack16 of tray assemblies. Agas extraction port34 below corresponding injection nozzles allows gases passing through the biomass to be discharged from the stack of trays and vessel.
• In the embodiment shown inFIGS. 1 to 4, thegas inlets30,32 for the oxygen deprived gas are at the top of the vessel and at two elevations corresponding to the tray assemblies for drying the biomass, and the upper tray assembly for the torrefaction process. Similarly, there are threegas extraction ports34 each below a corresponding as inlet. Two of the gas extraction ports are adjacent the tray assemblies for drying. The third is at an upper region of thechamber20. The number ofgas outlets34 may be minimized to reduce metallic surface area exposed to gases with organic compounds from the biomass material.
• The oxygen deprived gases flowing to multiple elevations in the vessel may be at temperatures and compositions that vary for different elevations in the stack oftrays16 andchamber20. For example, the hot oxygen deprived gas introduced to the uppermost elevation of the vessel, e.g.,top inlet port30, may be at a temperature hotter than the temperature of thebiomass12 entering the vessel. The hot oxygen deprived gases introduced throughnozzles32 on the cylindrical wall of the vessel may vary in temperature at different elevations of the vessel. The temperature of the gases may become increasingly hotter at lower elevations of the stack of trays and be slightly above the temperature of the biomass as it moves down through the stack. The biomass increases in temperature as it moves down through the stack of tray assemblies and falls into a pile in the chamber. At the lower elevations of the vessel, the temperature of the gases introduced through thenozzles32 may be cooler than the biomass in the corresponding elevation of the vessel. The temperature of the gases injected at the different elevations may be selected to create a temperature profile along a vertical direction of the biomass in the vessel. The gases may also be injected through thenozzles32 to maintain a uniform temperature across a cross-section of the vessel at each elevation of the vessel.
• By injecting the oxygen deprived gas at a temperature slightly above the temperature of the biomass being heated by the gas, the efficiency of heating can be increased as compared to injecting gas at all elevations of the vessel at a single temperature which may be substantially hotter than the incoming biomass to the vessel. Alternatively, the oxygen deprivedgases28 injected for drying and torrefaction may be at substantially similar temperatures and compositions.
• The torrefaction reaction may occur in the lower trays of the stack of trays and in thechamber20 and optionally just in thechamber20. Aconvergence zone22 at the bottom of the vessel may be configured to promote a uniform downward flow of the biomass material to anoutlet24 of the vessel. Thelower chamber20 may be a hollow region of the pressure reactor vessel below the stack of trays. The lower chamber and convergence zone may span the lower one-half or lower two-thirds of the height of the pressure vessel. Theconvergence zone22 may be a DIAMONDBACK® single convergence section sold by the Andritz Group and described in U.S. Pat. Nos. 5,500,083; 5,617,975 and 5,628,873. The convergence zone alternatively be a straight drop tube and include a multiple screw conveyor or moving grate at the bottom of the zone and at the outlet of the vessel. Theconvergence zone22 may be maintained at a cooler temperature than the stack of tray assemblies used for torrefaction and cooler than the temperature of the biomass material in thechamber20.
• Thepressure vessel10 may have dimensions, such as diameter and height, based on the desired operational conditions, such as the composition of the biomass material and the volumetric rate of biomass to flow through the vessel. In general, for industrial scale units, the pressure vessel may have a height of over 100 feet (30 meters) and a diameter of over 9 feet (2.7 meters). The vessel may have a length to diameter (L/D) ratio in ranges of 5 to 1 (5:1) to 12:1, or 6:1 to 11:1, or 7:1 to 10:1.
• The volume of hot oxygen deprived gas needed for the vessel is dramatically reduced in apressurized reaction vessel10 as compared to a vessel operating at atmospheric pressure. Pressurizing thetreatment vessel10 the volume of hot gas needed to heat the biomass is decreased by a factor of two (2) to thirty-five (35) as compared to a vessel at atmospheric pressure. The reduction factor for the vessel depends on the pressure in the vessel.
• Because of the reduced volume of hot gas needed in the pressurized reactor, the volume, size and cost of thevessel10 may be significantly reduced as compared to a vessel operating at atmospheric pressure. A pressurized vessel in which a hot gas is injected provides effective and economical heat transfer from the gas to the biomass in the vessel.
• The oxygen deprivedgas28 injected to thevessel10 is a hot, clean gas (as compared to the gas extracted from the torrefaction reaction in the vessel) that is substantially free of organic compounds and other chemicals that may accumulate on the surfaces of the vessel. As the gas passes through the biomass, organic compounds become entrained with the gas and may condense on relatively cool surfaces of the vessel. In view of the potential of condensation, the gas passages downstream of the biomass may be large and substantially free of small passage nozzles and other surfaces that could become clogged if organic compounds condense on the surfaces.
• In the embodiment shown inFIGS. 1 to 4, theuppermost gas inlet30 may be a single inlet for drying gas. Thenozzles32 on the side wall of the vessel may be limited to a small number, e.g., two to four, of nozzles that directly inject hot gas through the wall of the vessel.
• The flow of heated gas into, through and from the pressure reaction vessel may be configured to promote the flow of hot, pressurized gases through the tray assemblies in the upper elevations of the vessel where the biomass is being heated to the desired temperature for torrefaction and thereafter cooled. As shown inFIG. 1, the hot oxygen deprived gas may be injected into the upper section of thevessel10 through atop input manifold86 andgas injection nozzles34 arranged at the various elevations of thetray assemblies16,18 and20 in the upper portion of the vessel.
• The gases flowing to multiple elevations in the vessel may be at temperatures and compositions that vary for each of the tray assemblies. For example, the hot oxygen deprivedgas28 introduced to the uppermost elevation of the vessel may be at a temperature slightly, e.g., 5° C. to 100° C., hotter than the temperature of the driedbiomass12 being fed to the vessel. The hot oxygen deprived gases introduced at succeeding lower elevations of the vessel may be increasingly hotter to be slightly above the temperature of the biomass in the vessel that is proximate to the injected hot gas. By injecting the oxygen deprived gas at a temperature slightly above the biomass being heated by the gas, the efficiency of heating can be increased as compared to injecting gas at a single temperature which may be substantially hotter than the incoming biomass to the vessel. Alternatively, the gases injected for drying and torrefaction may be at substantially similar temperatures and compositions, and the gases for cooling the biomass may be recirculated gases extracted from other cooler elevations in the vessel. For example the exhaust gas from the drying trays will be cooler than that from the torrefaction levels and will be below temperatures required for torrefaction.
• Before the torrefaction reaction occurs in the vessel, the biomass may be dried and heated in an oxygen deprived environment to a temperature of 200° C., or in a range of 180° C. to 250° C. or 200° C. to 300° C. The drying may occur partially or fully in adryer15 upstream of thevessel10 or in the drying tray assemblies in the upper portion of thestack16. The biomass may be directly heated with an oxygen deprived gas, e.g., super-heated steam, nitrogen or a mixture of both, injected into the top of the vessel or dryer. The drying process may be conducted at a lower temperature than the temperature used to cause torrefaction of the biomass and at a temperature that does not cause the biomass to release large amounts of organic compounds.
• The compounds released in the drying tray assemblies are primarily water and highly volatile (lighter weight) organic compounds. Water condensation does not cause fouling. Similarly, light weight organic compounds tend not to leave tar-like deposits in the vessel and the conduits for the extracted torrefaction gases. The exhaust gases from the drying tray assemblies may be removed from the vessel without resulting in large deposits on the surfaces of the vessel. The water and light organic compounds may be separated from the gas after the gas has been extracted from the vessel or circulated as surplus gas to the torrefaction portion of the vessel.
• The gasses exhausted from the torrefaction process are rich in organic compounds that may condense on surfaces of the vessel or on the biomass material if the surfaces or material cool below the torrefaction temperatures, e.g., 250° C. to 200° C. or 160° C. These condensed compounds may deposit on surfaces of equipment and conduits in the form of tar like substances which can cause plugging and improper operation of the vessel.
• To prevent or minimize condensation, the vessel, piping, tanks and other equipment having surfaces in contact with the organic rich gas are insulated and heat traced so that cooler surfaces are minimized. Another technique to minimize condensation on surfaces is to minimize surfaces exposed to the organic rich gases. Using anopen chamber20 for some or all of the torrefaction process minimizes the surfaces, especially surfaces of small passages, exposed to gases rich with organic compounds. Eliminating some or all exhaust chambers between the trays for torrefaction also minimizes the surfaces that may receive the tar deposits of organic compounds.
• The gases from the torrefaction of the biomass, which include heavier organic compounds, are extracted from the vessel through the lower gas extraction port(s)34. After being removed from the vessel, the gasses from torrefaction are cooled to cause a portion of the organic compounds to condense but are maintained at a temperature above the dew-point of water or above a temperature at which lighter organic compounds condense. Upon condensing, the organic compounds form an aerosol, mist or droplets in the gas stream. A cyclone, drop out tank or other separator device separates the condensed organic compounds from the gas stream. Once separated from the organic compounds, these gases pass through a blower or other pressure increasing device, are heated to above the torrefaction temperature and are injected back into the vessel such as at the tray assemblies.
• A circulation flow of condensed liquid organics may be circulated and sprayed into the aerosol laden gas discharging from the condenser, prior to a cyclone separator. This provides a flow of larger droplets of liquid organics which collect some portion of the aerosols and enhance the removal of organics from the gas stream. A condenser may be used to cool the torrefaction gases from the reactor. The condenser may be cooled with a suitable heat exchange fluid. The energy acquired by the heat exchange fluid may be used to re-heat the circulating gases after the heavier organic components have been removed.
• If cooling gases are injected into theconvergence zone22 at the lower region of the vessel, the cooling gases may be cooler than thegases28 injected for drying and torrefaction. The cooling gases may reduce the temperature of the biomass to below a temperature that causes torrefaction. The cooling gases may be circulated gases extracted from upper elevations in the vessel, such as exhaust gas from the stack oftrays16 orchamber20.
• The temperature in theconvergence zone22 may be cooler than the temperature needed for torrefaction, such as below 265° C., 240° C. or 200° C. The torrefaction temperature will depend on the pressure in thevessel10 and the composition of the biomass material. The temperature in theconvergence zone22 may be at least 15° C. to 40° C. lower than the temperature ofchamber20. To control and maintain the temperature in the convergence zone gas may be injected to thechamber20 through injection nozzle21 (FIGS. 1-4) to provide cooling or heating of the biomass. Cooling or heating gas may be injected into the converging zone throughnozzles23. The injection and extraction of cooling gases may occur at several elevations in theconvergence zone22. The temperature of the cooling gases may be controlled to be at a temperature below that which the biomass material auto-combusts.
• FIG. 5 is a side view of the stack oftrays16 withcover plate36 andsleeve38.FIG. 6 is a perspective view of the top and side of the stack oftrays16. The stack of trays is vertically aligned and coaxial with theshaft38 and the circulartop plate36.
• The stack oftrays16 may be supported in the vessel by a centervertical shaft42 that is rotatably mounted to thecover plate36 at the top of the vessel. Thecover plate16 may be a flat plate, a hemispherical plate, an elliptical plate or other plate providing a sealable cover to the top of the reactor vessel. The cover plate may have a wide annular flange that bolts, is welded or otherwise fixed to a matching flange on the vertical cylindrical wall to the vessel. A wide flange may assist in the removal and reattachment of the cover plate when the stack oftrays16 is being repaired or replaced.
• Immediately above the cover plate are a gearbox andelectric motor assembly40 that drives theshaft42 to turn the scrapper or trays of the stack of trays. Avertical sleeve38 provides a cylindrical housing for the upper end of the shaft and at least a lower portion of the gearbox and motor assembly.
• The stack of trays with shaft may be removed as a stacked unit from the vessel by removing the upper cover plate. A crane may be used to pull out the stack of trays from the vessel. The stack of trays can be cleaned, repaired and otherwise serviced outside of the vessel. The removal of the stack of trays allows easy access to the interior of the vessel for service and cleaning. The crane can be used to insert the stack of trays back into the vessel, attach the cover plate to the top of the tray and attach the motor and gearbox to the upper end of the shaft.
• Theshaft42 extends down through the stack of trays and is supported by abottom bracket44. The bottom bracket includes a lower bearing which receives a lower end of theshaft42. The bottom bracket may include acylindrical bottom plate46 that provides a bottom support to the stack of trays and shaft. Metallic straps or bars47 extend vertically between the bottom plate and thecover plate36. These straps or bars form an outer cage for the trays and assist in maintaining the alignment of the trays in the stack. The straps or bars may connect to the periphery of each of the non-rotating tray assemblies and isolation plates in the stack. These connections assist in holding the horizontal alignment of the tray assemblies and isolation plates.
• Thestack16 of trays may include tray assemblies each of which includes anannular scraper48 and acircular tray plate50. The scraper is coaxial with and fixed to theshaft42. The scraper rotates with the shaft and moves the biomass in an arched shaped path over the plate immediately below the scraper. Thetray plate50 is coaxial with the shaft and is stationary. Eachtray plate50 has an opening through which biomass falls from the plate down to the next tray plate.
• Anisolation plate52 separates an upperexhaust gas chamber54 from a lowerinlet gas chamber56. The isolation plate isolates adjacent tray assemblies, and particularly isolates the gas streams in adjacent tray assemblies. The gas chambers, especially the lower chamber may be substantially open and free of structural surfaces. Achute58 provides a vertical passage for biomass flowing from an upper tray assembly, through an isolation plate and to a lower tray assembly. The chute has sidewalls that separate the biomass falling down through the chute from the gases in thegas chambers54,56. A gas extraction port34 (FIGS. 1 to 4) is aligned with theexhaust chamber54. Similarly, thegas injection nozzles32 are aligned with the lowerinlet gas chamber56.
• Theupper tray assemblies60 may be used to dry the biomass material. These dryingassemblies60, two of which are shown inFIGS. 5 and 6, may be each separated bygas chambers54,56. Drying causes moisture to be released from the biomass and become entrained with the gases. Having the moisture landed gases enter agas exhaust chamber54 below each drying tray plate allows these gases to exhaust through a gas extraction port below each drying tray plate and improves the drying process of the biomass. Further, the biomass tends not to release significant amounts of organic compounds during the drying process provided that the biomass does not reach torrefaction temperatures. With limited amounts of organic compounds, the exhaust gases from the dryingtray assemblies60 tend not to coat thechamber54 andexhaust port34 with tar like organic deposits.
• Thelower tray assemblies62 may be used for torrefaction by operating at higher temperatures than the dryingtray assemblies60. Due to the torrefaction process, organic compounds are released by the biomass and become entrained in the gas passing through the biomass. The organic compounds may condense on cooler surfaces and can clog narrow passages and moving parts. Further, a relatively small amount of moisture released into the gases by the biomass in the lower tray assemblies as only a small amount of moisture remains in the biomass after the dryingtray assemblies60. To avoid having organic compounds condense on surfaces and in view of the small amount of moisture being released, the gases pass through two or more of thelower tray assemblies62 without being extracted immediately below each tray assembly. In the example shown inFIGS. 5 and 6 the gases pass down through threetray assemblies62 and are discharged through thebottom plate46 and into thechamber20. By eliminating the gas chambers between thelower tray assemblies62, the surfaces which may be coated with tar are reduced.
• On the tray assemblies, especially thelower tray assemblies62, where there is a large temperature change between the biomass and the surface of the tray or other surfaces of the vessel, the biomass directly on the surface of the tray and near the biomass entrance for the tray may be relatively cool. To avoid condensation of organic compounds in the biomass at the tray inlet, additional heating may be provided at the tray inlet to avoid condensation. The additional heating may be achieved by baffles directing a portion of the hot inlet gases directly at the inlet section of the tray or other section of the tray or vessel surface where there is a risk of cooler temperatures and condensation.
• The net flow of gas down through thestack16 is downward and toward thechamber20. To prevent condensation, aerosol formation and fouling of surfaces in the vessel, the gases from torrefaction are extracted at an elevation in the vessel corresponding to a peak gas temperature in the vessel. This elevation may be in thechamber20. Thelower gas outlet34 is at the upper region of thechamber20 and corresponds to the hottest region in the vessel. By extracting gases from the torrefaction process only while the biomass is at its hottest in the vessel or above a threshold temperature, e.g., 280° C., the risk is reduced of excessive tar deposits on the surfaces of the vessel as the gas is exhausted from the vessel. Similarly, by reducing or eliminating the gas chambers between the lower tray assemblies minimizes the surfaces of the tray assemblies and vessel that are exposed to the gases with organic compounds.
• The torrefied biomass material is discharged under pressure from thevessel10. The biomass material is discharged to a pressure transfer device which reduces the pressure of the material to atmospheric pressure. From the pressure transfer device, the torrefied biomass is moved to other processes such as using a screw conveyor, as is shown inFIG. 23.
• The number of tray assemblies in thestack16 will depend on the design requirements for the vessel, and particularly the retention time desired for drying and for torrefaction. For example, the total number of tray assemblies in thevessel10 may be in any of the ranges of 3 to 10 and 4 to 6. The proportion of drying tray assemblies may be 20 to 100% or 20% to 50% or 40%, with the remainder and tray assemblies for torrefaction. These ranges are exemplary and do not define limits on the numbers of tray assemblies.
• FIG. 7 is perspective view of ascraper48 in each of thetray assemblies60,62. Thescraper48, as shown in this embodiment, has a shape similar to a wagon wheel with a centeraxial collar64 which slides over and is keyed to the shaft. Anannular ring66 is at the outer periphery of the scraper, andvertical vanes68 extend generally radially from the collar to the ring. The vanes may be at an angle, e.g., at 5 to 15 degrees, offset from a radial line if desired to promote the movement of the biomass material that fills the pie-shapedchamber72 between the vanes. Arib70 may be used for aligning the tray assemblies in the stack, or aligning the stack when being inserted down into the vessel. Further, therib70 may dislodge deposits on the straps or bars47 or other surfaces as the scraper rotates. The height (h) of a scraper is sufficient to ensure that the biomass moves across the tray and may extend substantially the entire gap between plates especially in thelower tray assemblies62.
• FIGS. 8 and 9 are perspective views of anexemplary tray plate50. The tray plate includes a substantiallycircular screen plate82 which is perforated, a mesh, or otherwise permeable to gas flow and impervious to the biomass material. The plate may be supported byribs84 extending radially from acollar86 and anouter ring88. The arrangement of ribs, collar and ring provide structural support for the tray plate and minimize the surface area of the plate, especially for the tray plates used for torrefaction. Theouter ring88 may include an arch90 of the circle that may be slanted radially inwardly in a downward direction. The arch90 is aligned with a pie-shapedopening92 and deflects the biomass inwardly and away from the wall of the vessel. Thecollar86 is coaxial with the vertical shaft of the vessel which rotates within the collar. Alternatively the collar may be fixed to the shaft such that thetray plate50 rotates as the scraper remains stationary.
• The pie shapedopening92 in thetray plate50 allows the biomass material on thecircular screen plate82 to pass down to the next tray assembly. Thescreen plate50 may also have a pie shapedsolid plate94 which is aligned with the pie-shaped opening in the tray assembly immediately above thesolid plate94 or the biomass inlet chute at the top to the vessel, if the tray is the uppermost tray. Thesolid plate94 may have a larger area than the area of theopening92. The solid plate provides a solid pad to receive the falling biomass material. As the biomass material flows from one plate to a lower plate another it lands on the lower plate at a slightly cooler temperature than temperature of the biomass already moving on the lower tray. The solid plate may include electrical heating elements to assist in heating the biomass. Further, the solid plate prevents the organic rich torrefaction gas falling with the biomass from passing straight through the screen plate and condensing on the tray support structure for the tray.
• Theopening92 in each tray plate is at the furthermost region of the plate with respect to the path of the biomass on the plate. Thesolid plate94 is at the start of the path of the biomass on the plate and is aligned with the trailing edge (in the direction of biomass movement) of theopening92. The alignment of the solid plate and opening ensures that the biomass entering each tray assembly is retained on the tray plate for nearly a full rotational period of the scraper or tray plate.
• Eachopening92 may be vertically staggered such that each opening is over the solid plate of the tray plate immediately below the opening. By aligning theopenings92 over a solid plate, the biomass falls through the opening and onto the solid plate. As the plate or tray turns, the biomass slides from the solid plate, around the entire upper surface of the tray plate in an arc-shaped path to the openings in the plate. Maintaining the biomass on the upper surface of each tray maximizes the retention period of the biomass on tray plate and, thus, allows the biomass to be heated, dried and promotes torrefaction.
• FIGS. 10 to 13 illustrate anisolation plate52 for the stack of tray assemblies. The isolation plate forms a solid, insulating and substantially impervious horizontal wall within the vessel. Theisolation plate52 may be used to separate thegas chambers54,56 within thestack16 of tray assemblies. Theisolation plate52 may be used to define a bottom wall of anexhaust gas chamber54 and an upper wall of aninlet gas chamber56.
• Achute58 extends through theisolation plate52 to provide a passage. The chute may be oriented generally vertically and having a cross-sectional shape conforming to the shape of the pie-shapedopenings92 in the tray assemblies immediately above and below theisolation plate52. The chute may have vertical walls extending entirely around the chute and having a cross-sectional shape conforming to theopenings92 of the plate trays. The walls of the chute confine the biomass to the chute area and prevent the biomass from entering thegas chambers54,56. The walls may be solid or meshed to confine the biomass material. Further, the walls may be bracketed, such as with vertical ribs, to provide structural support for the walls.
• Theisolation plate52 may be formed as an assembly of pie-shapedsections98 each of which has a horizontal plate, support ribs and arch-shaped inner and outer supports. The isolation plate may be solid, such as formed of steel or other metal material. An insulating layer may be applied to the lower or upper surface of the metal plate in the isolation plate. The insulating layer may be alternatively sandwiched between upper and lower metal sheets to form the isolation plate. The pie-shapedsections98 of the isolation plate may be joined by bracket I-beam strips100.
• Theisolation plate52 is stationary due to the chute associated with the plate that allows biomass to flow down through the plate. The isolation plate is supported by the vertical strips47 (FIGS. 5 and 6) at the outer periphery of thestack16 of tray assemblies. The isolation plate is fixed to remain in angular alignment with the trays to ensure that the biomass material falls through the opening in the isolation plate from an upper plate to a lower plate. The isolation plate has acollar102 formed by the assembly of the chute and pie-shapedsections98. The collar is coaxial with and surrounds the shaft. Because the isolation plate is stationary, the collar remains stationary as the shaft rotates.
• FIG. 14 is a perspective view showing the bottom and side of thecover plate36. The cover plate may be formed of a metal plate with an optional insulating layer. The insulating layer may be sandwiched between metal sheets forming the plate or applied to the outer or inner surface of the metal plate. Theupper inlet14 for the biomass extends through thecover plate36, opens to the interior of the vessel and is aligned with asolid plate94 of the uppermost tray assembly. The gas inlet(s)30 in the cover plate may be relatively small as compared to theinlet14 for the biomass material.
• Achannel104 may be aligned with theinlet14 and extend downward from the cover plate. The channel directs biomass material to the uppermost tray assembly and may assist in distributing the biomass in the chambers of the scraper of the uppermost tray assembly. The channel may be a pair of L-shaped walls on opposite sides of theinlet14. A bearing106 in a center opening of the cover plate receives the shaft for the stack of tray assemblies. Thecylindrical sleeve38 for the gearbox is coaxial with the center opening with thebearing106. The sleeve may have a large open area to allow access to the gearbox for service.
• FIG. 15 is an enlarged cross-sectional view of acoupling108 between theshaft42 for the stack of tray assemblies and adrive shaft110 of the gearbox assembly in thecylindrical sleeve38 on the top of the cover plate. Thecoupling108 is insulated to avoid excessive heat loss from the interior of the vessel through theshaft42 and to the exterior of the vessel. The coupling includes an insulatingdisc112 between the respective ends of theshaft42 for thestack16 and thedrive shaft110. The insulatingdisc112 is sandwiched between the shafts. Theinsulated disc112 may be a lamination of outer steel discs with an insulation layer between the discs.
• Theshafts42,112 are coupled together by a pair ofannular collars116, anannular flange114 on each collar is bolted together to ensure that the torsion of thedrive shaft110 turns theshaft42 of the stack. Aring118 between thecollars116 maintains an appropriate spacing between the shafts and ensures that the insulatingdisc112 is not crushed.
• FIG. 16 is an enlarged cross-sectional view of the lower end of theshaft42 for the stack of tray assemblies. Thebottom plate46 supports thestack16 and provides structural support for a spindle bearing120 shown inFIG. 17. Avertical bracket121 may provide structural rigidity to the bottom plate and support theshaft42.
• Thecollar64 of each of thescrapers48 are fixed, e.g., keyed, to theshaft48 such that the scrapers rotate with the shaft. Aslip ring122 maintains alignment between thelowermost scrapper48 and theshaft48. Between each of the scrapers, the shaft may have abushing124 that is adjacent thecollar86 of each of thetray plates46. The collar forms a bushing to allow its respective tray plate to remain stationary.
• FIG. 17 is a schematic diagram of thepressurized vessel10 showing the flow of biomass material, such as wood chips that are shown by a pattern of dots in the vessel. The shaft for the stack of tray assemblies is supported by the spindle bearing120 that is fixed to thebottom plate46 by abracket121. The scrapers are not shown inFIG. 17 for purposes of illustration.
• The twoupper tray assemblies60 are configured for drying of the biomass material. These upper tray assemblies have an upper oxygen deprivedgas chamber56 that is immediately above the scrapers for each of the tray assemblies. The oxygen deprived dryinggas126 for drying enters throughgas nozzles32 that may be arranged to uniformly distribute gases over the scraper and biomass being moved by the scraper. The dryinggas126 may be provided from the same source of gases that provides the oxygen deprivedgases128 for torrefaction, such as is illustrated bygas source28 inFIG. 1. Alternatively, the source of the dryinggas126 may differ from the source oftorrefaction gas128. The temperature of the oxygen deprived dryinggas126 for drying may be raised for the drying gas injected at lower elevations of the upper tray assemblies.
• As the biomass moves over the tray, the oxygen deprived gas flows down through the biomass and the trays of the tray assemblies and into anexhaust chamber54 below each tray.Isolation plates52 separate the upper tray assemblies from each other and from thelower tray assemblies62 that promote torrefaction.
• Thelower tray assemblies62 are configured for torrefaction. These tray assemblies do not have an exhaust gas chamber below each assembly. There may also be a single inlet gas assembly above theuppermost tray assembly62. Hot torrefaction oxygen deprivedgas128 for torrefaction enters throughnozzles32 above the scrapper for the uppermost one of thelower tray assemblies62. The hot torrefaction oxygen deprivedgas128 may be at a temperature to promote torrefaction, such as 10 to 30° C. hotter than the hottest of the dryinggases126. The hot torrefaction oxygen deprivedgas128 enters the vessel and passes down through all of thelower tray assemblies62 and through thebottom plate42 of the stack of tray assemblies. The hot torrefaction oxygen deprivedgas130 is exhausted through anoutlet34 below the stack and above the pile ofbiomass132 in thechamber20 of thevessel10. The hot torrefaction oxygen deprivedgas130 is exhausted from the hottest region of the vessel. The exhausted torrefaction oxygen deprived gas may be cleaned, heated and as the oxygen deprived dryinggas126 and the hot torrefaction oxygen deprivedgas128.
• Additional hot torrefaction oxygen deprivedgas128 may be injected directly into thechamber20 and into the pile of biomass. Additional hot torrefaction gas may be injected through nozzles on or in the convergence zone of the vessel, such as at the mid-point of a convergence. The additional hot torrefaction oxygen deprived gas may flow upward through the biomass in a manner counter-current to the downward movement of the biomass. The counter-current flow may exhaust through thegas outlet34 and with the torrefaction gas being exhausted from the stack of tray assemblies. Other torrefaction gas may exhaust from or be injected into the vessel through adischarge port132 at the bottom of the vessel.
• FIG. 18 is a schematic diagram of the upper portion of thepressurized vessel10 and particularly theupper tray assemblies60. The oxygen deprived gas enters theupper inlet30 through the cover plate at a temperature comparatively cooler than the oxygen deprived gas injected in lower elevations of the vessel. The oxygen deprived gas may be distributed by abaffle136 that disperses the gas uniformly over the biomass. A gap (G) above the biomass material provides sufficient volume to uniformly distribute the gas. The gap (G) may be a few inches, such as 5 to 8 inches or 150 mm to 200 mm. The hot oxygen deprived gas flows down through the biomass material (shown by the pattern of dots) and through the meshed or screenedtray plate82 and into theexhaust chamber54 and out through thesingle exhaust outlet34. Theexhaust outlet34 may be positioned adjacent the chute for theisolation tray52 immediately below theoutlet34. Thegas inlet32 for the next lower tray assembly may also be located adjacent the chute.
• Theisolation tray52 is shown inFIG. 18 as a lamination of metal and insulating layers. The tray may include upper and lower layers of steel and a middle layer of a non-metallic insulating layer. Insulating the isolation tray assists with the thermal efficiency in the vessel and allows for substantially large, e.g., greater than 10° C., between adjacent tray assemblies used for drying.
• FIG. 19 shows atray plate82 for an upper tray assembly used to dry biomass material. The tray plate is formed as a mesh. Immediately below theplate82 are heatingelements138 which are illustrated by dotted radial lines. The heating elements may be electrical resistive elements, conduits with steam or another hot oxygen deprived gas, or other devices that add heat energy to the tray plate, and particularly to thesolid plate94 which receives the cooler, wet biomass as it is deposited on the plate. The heating elements add heat to the tray plate to avoid having deposits of organic compounds and other material on cooler portions of the screen plate. Alternatively, hot gas may be blown on a underside of the tray structure. The rotation direction of the scraper is shown as clockwise.
• FIG. 20 is a top down view of anisolation tray plate52. An annular brass or softglass fiber ring140 may form a seal between the perimeter of thetray plate52 and the wall of the vessel. Thetray plate52 may include heating elements to prevent cooling of the plate and thereby prevent condensation of organic and other compounds on the metal surfaces.
• The external wall(s) of the vessel may be insulated, such as by applying an insulating coating to the outer surface of themetal walls142. The insulation of the walls may extend over the entire outer surface of the vessel. The insulation of the outer wall of the vessel increases the heat efficiency of the vessel and assists in maintaining uniform temperature levels across each elevation of the vessel.
• The enlarged portion shown inFIG. 20 illustrates the brass orglass fiber seal140 between the periphery of theisolation tray plate52 and the inside surface of thecylindrical metal wall142 of the torrefaction reactor vessel. Thewall142 may be coated with an insulatingmaterial144, such as a ceramic coating, a glass fiber coating or high-temperature polymer coating.
• FIG. 21 is a schematic diagram of the upper portion of thepressurized vessel10 and particularly thelower tray assemblies62. The scrapers are not shown to better illustrate the gas flow (see arrows) and movement of the biomass material (see pattern of dotted lines). The oxygen deprived gas enters theuppermost tray assembly62 through, for example, twonozzles32 arranged at opposite sides of the vessel, e.g., 180 degrees apart. The gas entering theuppermost tray assembly62 is hot, e.g., above a temperature in a range of 240° C. to 300° C. to promote torrefaction of the biomass in thetray assemblies62 andchamber20. The temperature needed to promote torrefaction is dependent on the biomass material and the pressure in the vessel. The oxygen deprived gas injected at theuppermost tray assembly62 may be hotter, e.g., 5° C. to 100° C. hotter, than the oxygen deprived gases added to theupper tray assemblies60 used for drying the biomass.
• A gap above the biomass material and scraper on theuppermost tray assembly62 provides sufficient volume to uniformly distribute the gas. Similar gaps, but possibly shorter, are between the lower surface of thetray plates82 and the top of the scraper/biomass level in each of thelower tray assemblies82. The initial gap above theuppermost tray assembly62 may be a few inches, such as 5 to 8 inches or 125 mm to 200 mm, and the lower gaps may be 3 to 5 inches. The hot oxygen deprived gas flows down through the biomass material (shown by the pattern of dots) and through the meshed or screenedtray plate82 and directly into the gap immediately above the biomass and scraper on the nextlower tray assembly62.
• The hot gas passes down through each of thelower tray assemblies62 and out anoutlet34, e.g., a single outlet, which is below the stack of tray assemblies and above the pile of biomass in thechamber20 of the vessel. Thesingle outlet34 may be aligned with the elevation of the vessel having the hottest gas, or gases at a temperature substantially hotter than the condensation temperature of the organic compounds in the gas. By extracting the gas while very hot through theoutlet34 the risk is reduced of organic compounds depositing on the surfaces of the vessel and the outlet.
• There may be asingle outlet34 for the gases passing through the biomass material undergoing the torrefaction process. A single outlet minimizes the surfaces of the outlet that are exposed to the exhaust gases with the organic compounds that are volatilized during torrefaction. Minimizing the surfaces of the outlet and associated outlet conduits reduces the surface area which may become clogged with deposits, e.g., organic tar like substances, from the exhaust gas.
• FIG. 22 is a top down view of atray plate82 for a lower tray assembly that is used for torrefaction of the biomass. The tray plate may be a metallic mesh having substantially the same sized mesh openings as the tray plates of the upper tray assemblies. Alternatively, openings of the mesh of the plate may be smaller that the openings in the mesh of the plates in the upper tray assemblies. Thetray plate82 of the lower tray assemblies has the pie-shapedopening92 and the solid pie-shapedplate94 below the chute or opening92 of the next higher isolation plate or tray assembly. Theplate94 is adjacent theopening92 such that the biomass falls on theplate94, moves around the entirety of theplate82 before falling through theopening92.
• Astationary seal144, such as an L-shaped vertical wall, may be vertically aligned with the leading edge of the pie-shapedplate94 and include a flange attached to the interior wall of the vessel. The stationary seal is between the upper edge of the scraper and below the bottom on the next higher tray plate. Theseal144 directs gases flowing with the biomass falling from the above tray assembly into the biomass and away from the opening in the tray plate.
• FIG. 23 is a flow diagram of a plant, e.g., factory, for producingtorrefied biomass material151 frombiomass material150. Abucket elevator152 anddrag conveyor154 may transport thebiomass material150 to afeed bin156 that provides a continuous feed of biomass material at a flow rate determined by a meter screw at the bottom of the feed bin. Asecond bucket elevator158 transports the biomass moving at a uniform flow rate to aninlet rotary valve160 at the top inlet of atorrefaction reactor162. The rotary valve may be a high pressure transfer device that transfers the unpressurized biomass material to thepressurized torrefaction reactor162, without loss of pressure from the vessel. The torrefaction reactor may be a cylindrical pressurized vessel having a height of 30 to 50 meters and a diameter of 3 to 10 meters. These dimensions are exemplary. The actual dimensions of the torrefaction vessel will depend on various factors including the type of biomass material, the desired flow rate of the material and the pressure in the vessel.
• Adischarge conveying screw164 removes the torrefied biomass material from the bottom of the torrefaction reactor at a metered flow rate. Acooling screw166 conveys the torrefied biomass material while removing heat energy from the material such as by cooling vanes on the outer surface of thescrew166 or cooling water flowing over the outer surface of the screw. Other cooling devices may be used in addition to or substitution for the cooling screw. These other cooling devices may include a fluid bed cooler.
• The cooled torrefied biomass material passes through adischarge rotary valve168 which reduces the pressure of the material to an atmospheric pressure and exposes the material to atmospheric air. The torrefied biomass material is cooled before being exposed to air to minimize the risk that the material spontaneously combusts.
• Athird bucket elevator170 andsecond drag conveyor172 transports the cooled torrefied biomass material to astorage bin174. A metering screw discharges thebiomass material151 from the storage bin for further processing or to be used as a combustible fuel.
• Heat orthermal energy176 for a dryinggas processing unit178 and a torrefiedgas processing unit180 may be provided by steam, combustion or other energy source. Theheat energy176 provides a means to increase the temperatures of the gases that are to be injected into thetorrefaction reactor vessel162. The gas processing unit for the dryinggas178 removes dust and other particles from the circulating drying gases and re-heats the gas to the temperatures needed for drying. The torrefiedgas processing unit180 removes the dust and other particles from the circulating torrefaction gases, removes the heavier organic compounds to allow the recovery of heat, and re-heats the gas to the required temperature for reuse as torrefaction gases.
• The gases circulating through thegas processing units178 and180 are at substantially the same pressures as in the torrefaction reactor. The pressurization of the gases may be achieved by adding or relieving the oxygen deprived gases to the reactor or gas processing units.
• The oxygen deprived gases are circulated through the torrefaction reactor in a substantially closed gas loop system. The gases may be used to dry the biomass, apply heat to sustain torrefaction and cool the torrefied biomass. The temperature of the oxygen deprived gas entering a tray may be set to achieve the desired function of the tray. For example, the gas flowing to a top inlet may be cooler than the oxygen deprived gases flowing to the torrefaction tray assemblies.
• The dryinggas processing unit178 provides oxygen deprived heated gases for the drying process occurring in the torrefaction reactor to dry the biomass material. The drying gas may provide a source of oxygen depleted gas such as nitrogen or dry steam. The drying gas from the drying gas processing unit flows to thegas nozzles32 aligned with the upper tray assemblies in the torrefaction reactor.Exhaust outlets34 extract the oxygen deprived gas from the torrefaction reactor after the gas has passed through the biomass material to dry the material. The temperature of the drying gas may be in a range of 180° C. to 240° C. or at other temperatures below the temperature threshold, e.g., 205° C., for causing a torrefaction reaction in the biomass material. The temperature of the drying gas may be coolest at the top inlet and be hotter, e.g., an increase of 5 to 10° C., atlower gas nozzles34. The exhausted drying gas may be processed to remove the moisture and other entrained liquids or solids from the gas, reheated and returned for use as a drying gas in the torrefaction reactor.
• The torrefiedgas processing unit180 provides an oxygen deprived gas, which may be the same gas composition as provided by the drying gas processing unit, to the lower regions of the torrefaction reactor where the biomass material undergoes torrefaction. The torrefiedgas processing unit180 supplies an oxygen deprived gas at temperatures above the threshold temperature, e.g., 250° C. to 300° C., required to promote a torrefaction reaction. The torrefaction gases are added throughnozzles32 aligned with the uppermost tray assembly configured for torrefaction.Additional inlet nozzles32 for torrefaction gases may be at the lower region of the vessel. These lower nozzles add hot gases to ensure that the pile of biomass material in the vessel remains at or above a temperature to promote the torrefaction reaction.
• In the embodiment of the torrefaction reactor shown inFIG. 23 there is no cooling zone and the torrefaction process may continue as the biomass material flows down to the outlet of thereactor162. Some cooling gases may flow in a counter-current direction from thecooling screw162 into the bottom of thereactor162. Further, thecooling screw162 may have a small flow of nitrogen gas at its discharge end. The nitrogen gas displaces torrefaction gas containing organic compounds which may be carried with the torrefied biomass material from the discharge of the reactor and into the cooling screw. The organic compounds in the torrefaction gases, if not removed, might deposit on the cool surfaces of the cooling screw. Additionally, the cooling screw may have an outer water jacket and a water passage through a center of the shaft of the screw. These water jacket and passage transfer heat away from the biomass material and cool the material. Warm water exiting the cooling screw may be circulated to a cooling tower and returned to the cooling screw as cooling water.
• The gases extracted from the torrefaction process may be removed from asingle outlet34 that flows directly and through insulated conduits into the torrefiedgas processing unit180. The extracted gas may include entrained organic compounds that will deposit on surfaces that are cooler than the gas. By flowing the extracted gas directly and quickly into the torrefied gas processing unit, the risk that the organic compounds deposit on conduit surfaces is reduced because the gas remains at a relatively hot temperature during the short passage to thegas processing unit180. Also from the gas processing unit180 astream181 is sent to a combustor for further processing of the torrefaction gases and particularly the condensed organic compounds removed from the torrefaction gases. Agenerator182 of the oxygen deprived gas for the dryinggas processing unit178 and the torrefiedgas processing unit180 may be a nitrogen PSA plant which are conventional and commercially available. These plants may generate sufficient amounts of nitrogen gas to supply the drying and torrefied gas processing units.
• FIG. 24 is a process flow chart showing an exemplary torrefiedgas processing unit180. The compounds released from the biomass during the torrefaction process include various molecular weight organic components evolved during the torrefaction reaction. These organic components will cause significant fouling of equipment due to tar-like deposits when condensation occurs, particularly in an un-controlled manner. In the torrefiedgas processing unit180 the gases extracted from the torrefaction reactor are reduced in temperature so that heavier organic compounds are condensed but the gas is maintained above the dew point temperature of water and lighter organic compounds. The condensed organic components may be formed into an aerosol, mist or droplets in the gas stream. The gas stream with the condensed organic components flows to one or more drop out tank(s) or cyclone separator(s)204 where the heavier weight components are separated from the gas stream. The heavier weight components fall to the bottom of the drop out tank(s) or cyclone separator(s) and flow to acollection tank206. Thecomponents181 from thecollection tank206 may flow to a recovery boiler or other chemical recovery system.
• Torrefaction gas200 extracted from thetorrefaction reactor162 is cooled in aheat exchanger202 to cause organic volatile materials in the gas to condense such as into aerosols or droplets. The cooled torrefied gas enters acyclone separator204 in which condensed liquid droplets are separated from the gas. Other examples ofseparators204 include devices that oxidize the byproducts, catalytically convert the byproducts, filter the byproducts from the gas flow and flow separators, such as cyclones that use centrifugal forces to separate particles from the gas stream. Theseparators204 may be used singularly or in combination in the torrefactiongas processing system180. The byproducts separated by these components may be further processed by being separated, concentrated or purified into usable products.
• The separated gases flow to asecond heat exchanger212 and the separated droplets flow as a liquid to acondensate tank206. A portion of the liquid from the condensate tank is sprayed into the gas flowing from theheat exchanger202 to theseparator204. The liquid droplets sprayed in the gases promote the condensation of gaseous organic compounds from the gas flow. Aliquid pump208 may pressurize the condensed liquid to be sprayed into the gas flow. Adroplet spray nozzle209 breaks the liquid into droplets and sprays them into the gas stream.
• The torrefaction gas flows from the cyclone separator to asecond heat exchanger212 and athird heat exchanger214 both of which increase the temperature of the gas such as to 250° C. to 300° C. The third heat exchanger may receive thermal energy from a gas fired combustor.
• Ablower216 increases the pressure of the torrefaction gas, such as by 0.5 bar gauge, as thegas218 flows to the torrefaction reactor. The torrefaction gas flows through the torrefactiongas processing unit180 while pressurized to the pressure in the torrefaction reactor vessel.
• Thermal oil or condensed liquids, such as organic compounds, circulate through the torrefaction gas processing unit, to cool inheat exchanger202 the torrefaction gas exhausted from the torrefaction reactor and heat the gas in thesecond heat exchanger212 after the gas has been cleaned in theseparator204. The thermal oil or condensed liquid is cooled in aheat exchanger220 by cooling water that flows from224 and to226 a cooling tower. The cooled liquid is temporality stored in afluid tank222. Aliquid pump210 moves the liquid through the liquid circulation in thetorrefaction processing unit180.
• The gases extracted from the drying portion of the torrefaction reactor, such as from the upper tray assemblies, tend not to have large amounts of higher molecular weight organic compounds. The gases from the drying section include the oxygen deprived gas, steam and water, and volatile, lighter weight, organic compounds which tend not to condense on surfaces in the vessel. The gases extracted from the drying section need not flow through the torrefiedgas processing unit180. The dryinggas processing unit178 may include separators and condensers to remove water from the gas stream, a heat exchanger to increase the temperature of the gas to the temperature(s) desired for the drying portion of the torrefaction and a blower to transfer the drying gas to the reactor.
• The steam produced during drying may be exhausted to a combustor, an exhaust stack or a heat recovery system. The torrefaction gas produced during torrefaction may be burned in a combustor, for instance in combination with the steam from the drying section and the heat produced might be used for instance for pre-drying the biomass.
• While the invention has been described in connection with what is presently considered to be the most practical and preferred embodiment, it is to be understood that the invention is not to be limited to the disclosed embodiment, but on the contrary, is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the appended claims.

Claims (23)

What is claimed is:

1. A torrefaction reactor vessel configured for subjecting biomass to a torrefaction process, the reactor comprising:

inlet nozzles injecting an oxygen deprived gas into the vessel, wherein the gas temperature of the oxygen deprived gas injected through the nozzles at upper elevations in the vessel is lower than the gas temperature of the oxygen deprived gas injected through the inlet nozzles at lower elevations;

a rotatable shaft extending vertically down into the vessel;

a stack of scrapers and trays extending into the vessel from the top plate, wherein each scraper is fixed to and rotates with the shaft and is immediately above an associated stationary tray, each tray is perforated to allow passage of gas and block passage of biomass and has an opening through which biomass falls;

the stack includes a gas extraction chamber at an elevation below one of the trays and above one of the scrapers, wherein the gas extraction chamber receives the gas passing through the one of the trays and includes a gas extraction port to exhaust gas passing through the tray;

the stack includes a plurality of lower scrapers and trays which are below the gas extraction chamber and have no gas extraction chamber between the lower scrapers and trays;

a torrefaction chamber in the vessel and below the stack, wherein the torrefaction chamber holds a pile of biomass discharged from the stack;

a torrefaction gas exhaust outlet on the vessel and at an elevation below the stack and above an upper surface of the pile of biomass, and

a biomass outlet at a lower region of the vessel.

2. The reactor vessel ofclaim 1 wherein the shaft includes an insulated upper coupling configured to connect to a motor drive system external to the vessel.

3. The reactor vessel ofclaim 1 wherein each of the scrapers and trays are strapped together, and the strapped tray assemblies and scraper devices are coaxial with the shaft of the vessel.

4. The reactor vessel ofclaim 1 wherein each of the trays are coaxial and coextensive with each other, each of the scrapers are coaxial and coextensive with each other, and the trays and scrapers are coaxial.

5. The reactor vessel ofclaim 1 further comprising an isolation plate below the gas extraction chamber, wherein the isolation plate is coaxial and coextensive with the trays and includes a walled chute extending through the gas extraction chamber and to the scraper immediately below the isolation plate.

6. The reactor vessel ofclaim 5 wherein immediately below the isolation plate and above the immediately below scraper is a gas distribution chamber having an inlet nozzle in a wall of the vessel to receive an oxygen deprived drying gas.

7. The reactor vessel ofclaim 1 wherein the torrefaction gas exhaust outlet is a single outlet through which substantially torrefaction gas exhausts from the vessel except for the gas which flows with biomass through the biomass outlet.

8. The torrefaction vessel ofclaim 1 further comprising an oxygen deprived gas inlet nozzle on an outer wall of the vessel and at an elevation below the upper surface of the pile of biomass.

9. A method for torrefaction of biomass using a torrefaction reactor vessel having stacked trays including:

feeding the biomass to an upper inlet of the vessel such that the biomass material is deposited on an upper tray of a vertical stack of trays in the reactor;

cascading the biomass down through the trays by passing the biomass through an opening in each of the trays to deposit the biomass on a lower tray;

as the biomass moves around each of the stacked trays, heating the biomass material with an oxygen deprived gas injected into the vessel;

as the biomass is dried in upper trays of the stacked trays, extracting moisture containing gas having passed through the biomass on the upper trays wherein the extraction is immediately below each of the upper trays;

as the biomass undergoes torrefaction in the lower trays of the stacked trays, retaining the gas with the biomass until the biomass falls from the stacked trays to a pile of biomass in the reactor vessel;

exhausting gases containing organic compounds volatized by the torrefaction of the biomass through a gas outlet on the vessel at an elevation between the stacked trays and the pile of biomass, and

discharging torrefied biomass from a lower outlet of the torrefaction reactor vessel.

10. The method ofclaim 9 further comprising circulating extracted gas from the vessel, removing the volatized organic compounds from the extracted gas to clean the gas, and feeding the cleaned gas to one or more of the stacked trays.

11. The method ofclaim 10 wherein the cleaning of the gas includes cooling the gas to condense the organic compounds and separating the condensate from the gas.

12. The method ofclaim 10 wherein the feeding of the biomass and the discharge of the torrefied biomass are continuous.

13. The method ofclaim 8 wherein the oxygen deprived gas includes nitrogen gas.

14. The method ofclaim 8 further comprising moving the biomass around each tray by a scraper device associated with each tray.

15. The method ofclaim 8 wherein the oxygen deprived gas is injected under a pressure of at least 3 bar gauge and the interior of the vessel is under the pressure of at least 3 bar gauge.

16. A method for torrefaction of lignocellulosic biomass using a torrefaction reactor having stacked tray assemblies comprising:

continuously feeding the biomass to the torrefaction reactor such that the biomass material is deposited on a first tray assembly of a plurality of tray assemblies stacked vertically within the reactor;

as the biomass cascades down through drying trays in the tray assemblies, heating the biomass material with an oxygen deprived gas injected at a temperature below a threshold torrefaction temperature, wherein the oxygen deprived gas.

extracting from the vessel gases flowing through each of the drying trays before the gas flows to the biomass on a next lower tray;

as the biomass cascades down through torrefaction trays in the tray assemblies, wherein the torrefaction trays are below the drying trays, heating the biomass material with an oxygen deprived gas injected at a temperature above the threshold torrefaction temperature to promote a torrefaction reaction in the biomass on the torrefaction trays;

containing the oxygen deprived gas passing through the torrefaction trays in the vessel as the oxygen deprived gas and biomass pass through a plurality of torrefaction trays, and exhausting the oxygen deprived gas having passed through the torrefaction tray from the vessel, and

discharging torrefied biomass from a lower outlet of the torrefaction reactor.

17. The method ofclaim 16 wherein the threshold torrefaction temperature is in a range of 230° C. to 280° C.

18. The method ofclaim 16 further comprising cleaning the exhausted gas by removing volatized organic compounds and feeding the cleaned gas to the vessel.

19. The method ofclaim 18 wherein the cleaning of the gas includes cooling the gas to condense the organic compounds and separating the condensate from the gas.

20. The method ofclaim 16 wherein the oxygen deprived gas includes a substantial portion of nitrogen gas.

21. The method ofclaim 16 further comprising moving the biomass around each tray by a scraper device associated with each tray.

22. The method ofclaim 16 wherein the biomass is retained in the reactor vessel for a period of 15 to 60 minutes.

23. The method ofclaim 16 wherein the oxygen deprived gas is injected under a pressure of at least 3 bar gauge and the interior of the vessel is under the pressure of at least 3 bar gauge.

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