US20070199705A1 - Enhanced hydrocarbon recovery by vaporizing solvents in oil sand formations - Google Patents

Abstract

The present invention involves a method and apparatus for enhanced recovery of petroleum fluids from the subsurface by injecting a hydrocarbon solvent vapor in contact with the oil sand formation and the heavy oil and bitumen in situ. Multiple propped vertical hydraulic fractures are constructed from the well bore into the oil sand formation. The hydrocarbon solvent vapor and a non-condensing diluent gas are injected into the well bore, fill the hydraulic fractures, and thus contact and diffuse into the in situ bitumen. The hydrocarbon solvent vapors diffuse into the bitumen from the vertical faces of the propped fractures. The bitumen softens and flows by gravity to the well bore, exposing fresh surface of bitumen for the process to progressively soften and mobilizes the bitumen in a predominantly circumferentially, i.e. orthogonal to the propped fracture, diffusion direction at a nearly uniform rate into the oil sand deposit. The mobile oil may be deasphalted by the condensed solvent, leaving the heavy asphaltenes behind in the oil sand pore space with little loss of inherent fluid mobility in the processed oil sands. The processed product is produced with the dissolved solvent along with a tail diluent gas. The tail diluent gas is enriched with hydrocarbon solvent and re-injected into the process zone and the cycle repeated.

Description

RELATED APPLICATION
• This application is a continuation-in-part of copending U.S. patent application Ser. No. 11/363,540, filed Feb. 27, 2006, U.S. patent application Ser. No. 11/277,308, filed Mar. 27, 2006, U.S. patent application Ser. No. 11/277,775, filed Mar. 29, 2006, U.S. patent application Ser. No. 11/277,815, filed Mar. 29, 2006, U.S. patent application Ser. No. 11/277,789, filed Mar. 29, 2006, U.S. patent application Ser. No. 11/278,470, filed Apr. 3, 2006, and U.S. patent application Ser. No. 11/379,123, filed Apr. 18, 2006.
TECHNICAL FIELD
• The present invention generally relates to enhanced recovery of petroleum fluids from the subsurface by vaporized solvents placed in the oil sand formation contacting the viscous heavy oil and bitumen in situ, and more particularly to a method and apparatus to extract a particular fraction of the in situ hydrocarbon reserve by controlling the access to the in situ bitumen, the solvent composition, and operating temperatures and pressures of the in situ process, resulting in increased production of petroleum fluids from the subsurface formation as well as limiting water inflow into the process zone.
BACKGROUND OF THE INVENTION
• Heavy oil and bitumen oil sands are abundant in reservoirs in many parts of the world such as those in Alberta, Canada, Utah and California in the United States, the Orinoco Belt of Venezuela, Indonesia, China and Russia. The hydrocarbon reserves of the oil sand deposit is extremely large in the trillions of barrels, with recoverable reserves estimated by current technology in the 300 billion barrels for Alberta, Canada and a similar recoverable reserve for Venezuela. These vast heavy oil (defined as the liquid petroleum resource of less than 20° API gravity) deposits are found largely in unconsolidated sandstones, being high porosity permeable cohesionless sands with minimal grain to grain cementation. The hydrocarbons are extracted from the oils sands either by mining or in situ methods.
• The heavy oil and bitumen in the oil sand deposits have high viscosity at reservoir temperatures and pressures. While some distinctions have arisen between tar and oil sands, bitumen and heavy oil, these terms will be used interchangeably herein. The oil sand deposits in Alberta, Canada extend over many square miles and vary in thickness up to hundreds of feet thick. Although some of these deposits lie close to the surface and are suitable for surface mining, the majority of the deposits are at depth ranging from a shallow depth of 150 feet down to several thousands of feet below ground surface. The oil sands located at these depths constitute some of the world's largest presently known petroleum deposits. The oil sands contain a viscous hydrocarbon material, commonly referred to as bitumen, in an amount that ranges up to 15% by weight. Bitumen is effectively immobile at typical reservoir temperatures. For example at 15° C., bitumen has a viscosity of ˜1,000,000 centipoise. However, at elevated temperatures the bitumen viscosity changes considerably to ˜350 centipoise at 100° C. down to ˜10 centipoise at 180° C. The oil sand deposits have an inherently high permeability ranging from ˜1 to 10 Darcy, thus upon heating, the heavy oil becomes mobile and can easily drain from the deposit.
• Solvents applied to the bitumen soften the bitumen and reduce its viscosity and provide a non-thermal mechanism to improve the bitumen mobility. Hydrocarbon solvents consist of vaporized light hydrocarbons such as ethane, propane, or butane or liquid solvents such as pipeline diluents, natural condensate streams, or fractions of synthetic crudes. The diluent can be added to steam and flashed to a vapor state or be maintained as a liquid at elevated temperature and pressure, depending on the particular diluent composition. While in contact with the bitumen, the saturated solvent vapor dissolves into the bitumen. This diffusion process is due to the partial pressure difference between the saturated solvent vapor and the bitumen. As a result of the diffusion of the solvent into the bitumen, the oil in the bitumen becomes diluted and mobile and will flow under gravity. The resultant mobile oil may be deasphalted by the condensed solvent, leaving the heavy asphaltenes behind within the oil sand pore space with little loss of inherent fluid mobility in the oil sands due to the small weight percent (5-15%) of the asphaltene fraction to the original oil in place. Deasphalting the oil from the oil sands produces a high grade quality product by 3°-5° API gravity. If the reservoir temperature is elevated the diffusion rate of the solvent into the bitumen is raised considerably being two orders of magnitude greater at 100° C. compared to ambient reservoir temperatures of ˜15° C.
• In situ methods of hydrocarbon extraction from the oil sands consist of cold production, in which the less viscous petroleum fluids are extracted from vertical and horizontal wells with sand exclusion screens, CHOPS (cold heavy oil production system) cold production with sand extraction from vertical and horizontal wells with large diameter perforations thus encouraging sand to flow into the well bore, CSS (cyclic steam stimulation) a huff and puff cyclic steam injection system with gravity drainage of heated petroleum fluids using vertical and horizontal wells, stream flood using injector wells for steam injection and producer wells on 5 and 9 point layout for vertical wells and combinations of vertical and horizontal wells, SAGD (steam assisted gravity drainage) steam injection and gravity production of heated hydrocarbons using two horizontal wells, VAPEX (vapor assisted petroleum extraction) solvent vapor injection and gravity production of diluted hydrocarbons using horizontal wells, and combinations of these methods.
• Cyclic steam stimulation and steam flood hydrocarbon enhanced recovery methods have been utilized worldwide, beginning in with the discovery of CSS, huff and puff or steam-soak in Mene Grande field in Venezuela and for steam flood in the early 1960s in the Kern River field in California. These steam assisted hydrocarbon recovery methods including a combination of steam and solvent are described, see U.S. Pat. No. 3,739,852 to Woods et al., U.S. Pat. No. 4,280,559 to Best, U.S. Pat. No. 4,519,454 to McMillen, U.S. Pat. No. 4,697,642 to Vogel, and U.S. Pat. No. 6,708,759 to Leaute et al. The CSS process raises the steam injection pressure above the formation fracturing pressure to create fractures within the formation and enhance the surface area access of the steam to the bitumen. Successive steam injection cycles reenter earlier created fractures and thus the process becomes less efficient over time. CSS is generally practiced in vertical wells, but systems are operational in horizontal wells, but have complications due to localized fracturing and steam entry and the lack of steam flow control along the long length of the horizontal well bore.
• Descriptions of the SAGD process and modifications are described, see U.S. Pat. No. 4,344,485 to Butler, and U.S. Pat. No. 5,215,146 to Sanchez and thermal extraction methods in U.S. Pat. No. 4,085,803 to Butler, U.S. Pat. No. 4,099,570 to Vandergrift, and U.S. Pat. No. 4,116,275 to Butler et al. The SAGD process consists of two horizontal wells at the bottom of the hydrocarbon formation, with the injector well located approximately 10-15 feet vertically above the producer well. The steam injection pressures exceed the formation fracturing pressure in order to establish connection between the two wells and develop a steam chamber in the oil sand formation. Similar to CSS, the SAGD method has complications, albeit less severe than CSS, due to the lack of steam flow control along the long section of the horizontal well and the difficulty of controlling the growth of the steam chamber.
• A thermal steam extraction process referred to a HASDrive (heated annulus steam drive) and modifications thereof are described to heat and hydrogenate the heavy oils in situ in the presence of a metal catalyst, see U.S. Pat. No. 3,994,340 to Anderson et al., U.S. Pat. No. 4,696,345 to Hsuch, U.S. Pat. No. 4,706,751 to Gondouin, U.S. Pat. No. 5,054,551 to Duerksen, and U.S. Pat. No. 5,145,003 to Duerksen. It is disclosed that at elevated temperature and pressure the injection of hydrogen or a combination of hydrogen and carbon monoxide to the heavy oil in situ in the presence of a metal catalyst will hydrogenate and thermal crack at least a portion of the petroleum in the formation.
• Thermal recovery processes using steam require large amounts of energy to produce the steam, using either natural gas or heavy fractions of produced synthetic crude. Burning these fuels generates significant quantities of greenhouse gases, such as carbon dioxide. Also, the steam process uses considerable quantities of water, which even though may be reprocessed, involves recycling costs and energy use. Therefore a less energy intensive oil recovery process is desirable.
• Solvent assisted recovery of hydrocarbons in continuous and cyclic modes are described including the VAPEX process and combinations of steam and solvent plus heat, see U.S. Pat. No. 4,450,913 to Allen et al., U.S. Pat. No. 4,513,819 to Islip et al., U.S. Pat. No. 5,407,009 to Butler et al., U.S. Pat. No. 5,607,016 to Butler, U.S. Pat. No. 5,899,274 to Frauenfeld et al., U.S. Pat. No. 6,318,464 to Mokrys, U.S. Pat. No. 6,769,486 to Lim et al., and U.S. Pat. No. 6,883,607 to Nenniger et al. The VAPEX process generally consists of two horizontal wells in a similar configuration to SAGD; however, there are variations to this including spaced horizontal wells and a combination of horizontal and vertical wells. The startup phase for the VAPEX process can be lengthy and take many months to develop a controlled connection between the two wells and avoid premature short circuiting between the injector and producer. The VAPEX process with horizontal wells has similar issues to CSS and SAGD in horizontal wells, due to the lack of solvent flow control along the long horizontal well bore, which can lead to non-uniformity of the vapor chamber development and growth along the horizontal well bore.
• Direct heating and electrical heating methods for enhanced recovery of hydrocarbons from oil sands have been disclosed in combination with steam, hydrogen, catalysts and/or solvent injection at temperatures to ensure the petroleum fluids gravity drain from the formation and at significantly higher temperatures (300° to 400° range and above) to pyrolysis the oil sands. See U.S. Pat. No. 2,780,450 to Ljungström, U.S. Pat. No. 4,597,441 to Ware et al., U.S. Pat. No. 4,926,941 to Glandt et al., U.S. Pat. No. 5,046,559 to Glandt, U.S. Pat. No. 5,060,726 to Glandt et al., U.S. Pat. No. 5,297,626 to Vinegar et al., U.S. Pat. No. 5,392,854 to Vinegar et al., and U.S. Pat. No. 6,722,431 to Karanikas et al. In situ combustion processes have also been disclosed see U.S. Pat. No. 5,211,230 to Ostapovich et al., U.S. Pat. No. 5,339,897 to Leaute, U.S. Pat. No. 5,413,224 to Laali, and U.S. Pat. No. 5,954,946 to Klazing a et al.
• In situ processes involving downhole heaters are described in U.S. Pat. No. 2,634,961 to Ljungström, U.S. Pat. No. 2,732,195 to Ljungström, U.S. Pat. No. 2,780,450 to Ljungström. Electrical heaters are described for heating viscous oils in the forms of downhole heaters and electrical heating of tubing and/or casing, see U.S. Pat. No. 2,548,360 to Germain, U.S. Pat. No. 4,716,960 to Eastlund et al., U.S. Pat. No. 5,060,287 to Van Egmond, U.S. Pat. No. 5,065,818 to Van Egmond, U.S. Pat. No. 6,023,554 to Vinegar and U.S. Pat. No. 6,360,819 to Vinegar. Flameless downhole combustor heaters are described, see U.S. Pat. No. 5,255,742 to Mikus, U.S. Pat. No. 5,404,952 to Vinegar et al., U.S. Pat. No. 5,862,858 to Wellington et al., and U.S. Pat. No. 5,899,269 to Wellington et al. Surface fired heaters or surface burners may be used to heat a heat transferring fluid pumped downhole to heat the formation as described in U.S. Pat. No. 6,056,057 to Vinegar et al. and U.S. Pat. No. 6,079,499 to Mikus et al.
• The thermal and solvent methods of enhanced oil recovery from oil sands, all suffer from a lack of surface area access to the in place bitumen. Thus the reasons for raising steam pressures above the fracturing pressure in CSS and during steam chamber development in SAGD, are to increase surface area of the steam with the in place bitumen. Similarly the VAPEX process is limited by the available surface area to the in place bitumen, because the diffusion process at this contact controls the rate of softening of the bitumen. Likewise during steam chamber growth in the SAGD process the contact surface area with the in place bitumen is virtually a constant, thus limiting the rate of heating of the bitumen. Therefore both methods (heat and solvent) or a combination thereof would greatly benefit from a substantial increase in contact surface area with the in place bitumen. Hydraulic fracturing of low permeable reservoirs has been used to increase the efficiency of such processes and CSS methods involving fracturing are described in U.S. Pat. No. 3,739,852 to Woods et al., U.S. Pat. No. 5,297,626 to Vinegar et al., and U.S. Pat. No. 5,392,854 to Vinegar et al. Also during initiation of the SAGD process over pressurized conditions are usually imposed to accelerated the steam chamber development, followed by a prolonged period of under pressurized condition to reduce the steam to oil ratio. Maintaining reservoir pressure during heating of the oil sands has the significant benefit of minimizing water inflow to the heated zone and to the well bore.
• Hydraulic fracturing of petroleum recovery wells enhances the extraction of fluids from low permeable formations due to the high permeability of the induced fracture and the size and extent of the fracture. A single hydraulic fracture from a well bore results in increased yield of extracted fluids from the formation. Hydraulic fracturing of highly permeable unconsolidated formations has enabled higher yield of extracted fluids from the formation and also reduced the inflow of formation sediments into the well bore. Typically the well casing is cemented into the borehole, and the casing perforated with shots of generally 0.5 inches in diameter over the depth interval to be fractured. The formation is hydraulically fractured by injecting fracture fluid into the casing, through the perforations and into the formation. The hydraulic connectivity of the hydraulic fracture or fractures formed in the formation may be poorly connected to the well bore due to restrictions and damage due to the perforations. Creating a hydraulic fracture in the formation that is well connected hydraulically to the well bore will increase the yield from the well, result in less inflow of formation sediments into the well bore and result in greater recovery of the petroleum reserves from the formation.
• Turning now to the prior art, hydraulic fracturing of subsurface earth formations to stimulate production of hydrocarbon fluids from subterranean formations has been carried out in many parts of the world for over fifty years. The earth is hydraulically fractured either through perforations in a cased well bore or in an isolated section of an open bore hole. The horizontal and vertical orientation of the hydraulic fracture is controlled by the compressive stress regime in the earth and the fabric of the formation. It is well known in the art of rock mechanics that a fracture will occur in a plane perpendicular to the direction of the minimum stress, see U.S. Pat. No. 4,271,696 to Wood. At significant depth, one of the horizontal stresses is generally at a minimum, resulting in a vertical fracture formed by the hydraulic fracturing process. It is also well known in the art that the azimuth of the vertical fracture is controlled by the orientation of the minimum horizontal stress in consolidated sediments and brittle rocks.
• At shallow depths, the horizontal stresses could be less or greater than the vertical overburden stress. If the horizontal stresses are less than the vertical overburden stress, then vertical fractures will be produced; whereas if the horizontal stresses are greater than the vertical overburden stress, then a horizontal fracture will be formed by the hydraulic fracturing process.
• Hydraulic fracturing generally consists of two types, propped and unpropped fracturing. Unpropped fracturing consists of acid fracturing in carbonate formations and water or low viscosity water slick fracturing for enhanced gas production in tight formations. Propped fracturing of low permeable rock formations enhances the formation permeability for ease of extracting petroleum hydrocarbons from the formation. Propped fracturing of high permeable formations is for sand control, i.e. to reduce the inflow of sand into the well bore, by placing a highly permeable propped fracture in the formation and pumping from the fracture thus reducing the pressure gradients and fluid velocities due to draw down of fluids from the well bore. Hydraulic fracturing involves the literally breaking or fracturing the rock by injecting a specialized fluid into the well bore passing through perforations in the casing to the geological formation at pressures sufficient to initiate and/or extend the fracture in the formation. The theory of hydraulic fracturing utilizes linear elasticity and brittle failure theories to explain and quantify the hydraulic fracturing process. Such theories and models are highly developed and generally sufficient for the art of initiating and propagating hydraulic fractures in brittle materials such as rock, but are totally inadequate in the understanding and art of initiating and propagating hydraulic fractures in ductile materials such as unconsolidated sands and weakly cemented formations.
• Hydraulic fracturing has evolved into a highly complex process with specialized fluids, equipment and monitoring systems. The fluids used in hydraulic fracturing vary depending on the application and can be water, oil or multi-phased based gels. Aqueous based fracturing fluids consist of a polymeric gelling agent such as solvatable (or hydratable) polysaccharide, e.g. galactomannan gums, glycomannan gums, and cellulose derivatives. The purpose of the hydratable polysaccharides is to thicken the aqueous solution and thus act as viscosifiers, i.e. increase the viscosity by 100 times or more over the base aqueous solution. A cross-linking agent can be added which further increases the viscosity of the solution. The borate ion has been used extensively as a cross-linking agent for hydrated guar gums and other galactomannans, see U.S. Pat. No. 3,059,909 to Wise. Other suitable cross-linking agents are chromium, iron, aluminum, and zirconium (see U.S. Pat. No. 3,301,723 to Chrisp) and titanium (see U.S. Pat. No. 3,888,312 to Tiner et al). A breaker is added to the solution to controllably degrade the viscous fracturing fluid. Common breakers are enzymes and catalyzed oxidizer breaker systems, with weak organic acids sometimes used.
• Oil based fracturing fluids are generally based on a gel formed as a reaction product of aluminum phosphate ester and a base, typically sodium aluminate. The reaction of the ester and base creates a solution that yields high viscosity in diesels or moderate to high API gravity hydrocarbons. Gelled hydrocarbons are advantageous in water sensitive oil producing formations to avoid formation damage, that would otherwise be caused by water based fracturing fluids.
• The method of controlling the azimuth of a vertical hydraulic fracture in formations of unconsolidated or weakly cemented soils and sediments by slotting the well bore or installing a pre-slotted or weakened casing at a predetermined azimuth has been disclosed. The method disclosed that a vertical hydraulic fracture can be propagated at a pre-determined azimuth in unconsolidated or weakly cemented sediments and that multiple orientated vertical hydraulic fractures at differing azimuths from a single well bore can be initiated and propagated for the enhancement of petroleum fluid production from the formation. See U.S. Pat. No. 6,216,783 to Hocking et al., U.S. Pat. No. 6,443,227 to Hocking et al., U.S. Pat. No. 6,991,037 to Hocking, U.S. patent application Ser. No. 11/363,540 and U.S. patent application Ser. No. 11/277,308. The method disclosed that a vertical hydraulic fracture can be propagated at a pre-determined azimuth in unconsolidated or weakly cemented sediments and that multiple orientated vertical hydraulic fractures at differing azimuths from a single well bore can be initiated and propagated for the enhancement of petroleum fluid production from the formation. It is now known that unconsolidated or weakly cemented sediments behave substantially different from brittle rocks from which most of the hydraulic fracturing experience is founded.
• Accordingly, there is a need for a method and apparatus for enhancing the extraction of hydrocarbons from oil sands by direct heating, steam and/or solvent injection, or a combination thereof and controlling the subsurface environment, both temperature and pressure to optimize the hydrocarbon extraction in terms of produced rate, efficiency, and produced product quality, as well as limit water inflow into the process zone.
SUMMARY OF THE INVENTION
• The present invention is a method and apparatus for enhanced recovery of petroleum fluids from the subsurface by injection of a hydrocarbon vaporized solvent in contact with the oil sand formation and the heavy oil and bitumen in situ. Multiple propped hydraulic fractures are constructed from the well bore into the oil sand formation and filled with a highly permeable proppant. A hydrocarbon solvent and a non-condensing diluent gas are injected in a vaporized state into the well bore and the propped fractures. The injected gas flows upwards and outwards in the propped fractures contacting the oil sands and in situ bitumen on the vertical faces of the propped fractures. The hydrocarbon solvent vapors diffuse into the bitumen from the vertical faces of the propped fractures. The bitumen softens and flows by gravity to the well bore, exposing fresh surface of bitumen for the process to progressively soften and mobilize the bitumen in a predominantly circumferential, i.e. orthogonal to the propped fracture, diffusion direction at a nearly uniform rate into the oil sand deposit. To limit upward growth of the process, a light non-condensing gas can be injected to remain in the uppermost portions of the propped fractures. The mobile oil may be deasphalted by the condensed solvent, leaving the heavy asphaltenes behind in the oil sand pore space with little loss of inherent fluid mobility in the processed oil sands. The processed product is produced with the dissolved solvent along with a tail diluent gas. The tail diluent gas is enriched with hydrocarbon solvent and re-injected into the process zone and the cycle repeated.
• The processes active at the contact of the diluent with the bitumen in the oil sand are predominantly diffusive, being driven by partial pressure gradients, resulting in the diffusion of hydrocarbon solvent into the bitumen. Upon softening of the bitumen, the oil will become mobile and flow under gravity and exposed contact with fresh bitumen in situ for an every larger expanding zone of mobile oil in the native oil sand formation. The mobile oil flows by gravity with the dissolved solvent back to the well bore and pumped to the surface.
• The hydrocarbon solvent would preferably be one of ethane, propane, or butane or a mixture thereof, and be mixed with a non-condensing diluent gas being either methane, nitrogen, carbon dioxide, natural gas, or a mixture thereof, to ensure that the selected composition of the injected gas is such that: 1) the solvent mixture has a dew point that substantially corresponds with the operating process temperature and pressure in situ, 2) the solvent mixture is substantially more soluble in the bitumen than the diluent gas, 3) the solvent mixture is liquefied but vaporizable in the process zone, and 4) solvent mixture has a vapor/liquid envelop that encompasses the process operating temperatures and pressures. The solvent and diluent gas are injected into the well bore and the process zone, with the solvent primarily as a vapor state contacting and diffusing into the bitumen. By selecting the appropriate solvent and diluent gas mixture, the process can operate close to ambient reservoir pressures, so that water inflow into the process zone can be minimized. The selected range of temperatures and pressures to operate the process will depend on reservoir depth, ambient conditions, quality of the in place heavy oil and bitumen, composition of the solvent diluent gas mixture, and the presence of nearby water bodies. The process can be operated at elevated temperatures, which will result in greater diffusion rates of the solvent diffusing into the bitumen.
• As the injected mixture is injected and contacts the in situ bitumen, the injected gas tends to remain saturated with vaporized solvent. As the gas mixture contacts the bitumen, the oil becomes diluted with solvent and softens and flows by gravity to the well bore. The flowing oil contains dissolved solvent. The solvent in the injected mixture should be such that injected gas becomes saturated with solvent vapor with minimal liquid solvent present, otherwise asphaltene precipitation may occur. To maintain the flow, additional solvent is injected and the process area is either continuously circulated or pressure pulsed to distribute the solvent throughout the process zone. The produced product of oil and dissolved solvent is pumped to the surface where the solvent can be recycled for further injection.
• Although the present invention contemplates the formation of fractures which generally extend laterally away from a vertical or near vertical well penetrating an earth formation and in a generally vertical plane, those skilled in the art will recognize that the invention may be carried out in earth formations wherein the fractures and the well bores can extend in directions other than vertical.
• Therefore, the present invention provides a method and apparatus for enhanced recovery of petroleum fluids from the subsurface by vaporized solvents placed in the oil sand formation contacting the viscous heavy oil and bitumen in situ, and more particularly to a method and apparatus to extract a particular fraction of the in situ hydrocarbon reserve by controlling the access to the in situ bitumen, the solvent composition, and operating temperatures and pressures of the in situ process, resulting in increased production of petroleum fluids from the subsurface formation as well as limiting water inflow into the process zone.
• Other objects, features and advantages of the present invention will become apparent upon reviewing the following description of the preferred embodiments of the invention, when taken in conjunction with the drawings and the claims.
BRIEF DESCRIPTION OF THE DRAWINGS
• FIG. 1 is a horizontal cross-section view of a well casing having dual fracture winged initiation sections prior to initiation of multiple azimuth controlled vertical fractures.
• FIG. 2 is a cross-sectional side elevation view of a well casing having dual fracture winged initiation sections prior to initiation of multiple azimuth controlled vertical fractures.
• FIG. 3 is an isometric view of a well casing having dual propped fractures with downhole solvent and diluent gas injection for a pulsed pressure injection system.
• FIG. 4 is a horizontal cross-sectional side elevation view of a well casing and propped fracture showing flow of the injected gas and oil with progressive growth of the mobile oil zone.
• FIG. 5 is an isometric view of a well casing having dual propped fractures with downhole solvent and diluent gas injection for a continuous injection system.
• FIG. 6 is a horizontal cross-section view of a well casing having multiple fracture dual winged initiation sections after initiation of all four controlled vertical fractures.
• FIG. 7 is an isometric view of a well casing having four propped fractures with downhole solvent and diluent gas injection for a pulsed pressure injection system.
• FIG. 8 is an isometric view of a well casing having dual multi-stage propped fractures with downhole solvent and diluent gas injection for a continuous injection system.
DETAILED DESCRIPTION OF THE DISCLOSED EMBODIMENT
• Several embodiments of the present invention are described below and illustrated in the accompanying drawings. The present invention is a method and apparatus for enhanced recovery of petroleum fluids from the subsurface by injection of a hydrocarbon vaporized solvent in contact with the oil sand formation and the heavy oil and bitumen in situ. Multiple propped hydraulic fractures are constructed from the well bore into the oil sand formation and filled with a highly permeable proppant. A hydrocarbon solvent and a non-condensing diluent gas are injected in a vaporized state into the well bore and the propped fractures. The injected gas flows upwards and outwards in the propped fractures contacting the oil sands and in situ bitumen on the vertical faces of the propped fractures. The hydrocarbon solvent vapors diffuse into the bitumen from the vertical faces of the propped fractures. The bitumen softens and flows by gravity to the well bore, exposing fresh surface of bitumen for the process to progressively soften and mobilize the bitumen in a predominantly circumferential, i.e. orthogonal to the propped fracture, diffusion direction at a nearly uniform rate into the oil sand deposit. The solvent in the injected mixture should be such that injected gas becomes saturated with solvent vapor with minimal liquid solvent present, otherwise asphaltene precipitation may occur. To maintain the flow, additional solvent is injected and the process area is either continuously circulated or pressure pulsed to distribute the solvent throughout the process zone. The produced product of oil and dissolved solvent is pumped to the surface where the solvent can be recycled for further injection.
• Referring to the drawings, in which like numerals indicate like elements,FIGS. 1 and 2 illustrate the initial setup of the method and apparatus for forming either an in situ pressure pulsed or continuous injection of solvent and diluent into the oil sand deposit and for the extraction of the processed hydrocarbons.Conventional bore hole5 is completed by wash rotary or cable tool methods into theformation8 to apredetermined depth7 below theground surface6.Injection casing1 is installed to thepredetermined depth7, and the installation is completed by placement of agrout4 which completely fills the annular space between the outside theinjection casing1 and thebore hole5.Injection casing1 consists of fourinitiation sections21,22,23, and24 to produce two fractures one orientated alongplane2,2′ and one orientated alongplane3,3′.Injection casing1 must be constructed from a material that can withstand the pressures that the fracture fluid exerts upon the interior of theinjection casing1 during the pressurization of the fracture fluid. Thegrout4 can be any conventional material (if elevated temperatures are contemplated a steam injection casing cementation system is preferred) that preserves the spacing between the exterior of theinjection casing1 and thebore hole5 throughout the fracturing procedure, preferably a non-shrink or low shrink cement based grout that can withstand the imposed temperature and differential strains.
• The outer surface of theinjection casing1 should be roughened or manufactured such that thegrout4 bonds to the injection casing1 with a minimum strength equal to the down hole pressure required to initiate the controlled vertical fracture. The bond strength of thegrout4 to the outside surface of thecasing1 prevents the pressurized fracture fluid from short circuiting along the casing-to-grout interface up to theground surface6.
• Referring toFIGS. 1, 2, and3, theinjection casing1 comprises two fracture dualwinged initiation sections21,22,23, and24 installed at apredetermined depth7 within thebore hole5. Thewinged initiation sections21,22,23, and24 can be constructed from the same material as theinjection casing1. The position below ground surface of thewinged initiation sections21,22,23, and24 will depend on the required in situ geometry of the induced hydraulic fractures and the reservoir formation properties and recoverable reserves.
• The hydraulic fractures will be initiated and propagated by an oil based fracturing fluid consisting of a gel formed as a reaction product of aluminum phosphate ester and a base, typically sodium aluminate. The reaction of the ester and base creates a solution that yields high viscosity in diesels or moderate to high API gravity hydrocarbons. Gelled hydrocarbons are advantageous in water sensitive oil producing formations to avoid formation damage, that would otherwise be caused by water based fracturing fluids. The oil based gel provides the added advantage of injecting the solvent diluent gas mixture into the propped fracture, without the inherent problems of injecting a hydrocarbon fluid into a water saturated proppant fracture if water based fracturing fluids were used.
• The pumping rate of the fracturing fluid and the viscosity of the fracturing fluids needs to be controlled to initiate and propagate the fracture in a controlled manner in weakly cemented sediments such as oil sands. The dilation of the casing and grout imposes a dilation of the formation that generates an unloading zone in the oil sand, and such dilation of the formation reduces the pore pressure in the formation in front of the fracturing tip. The variables of interest are v the velocity of the fracturing fluid in the throat of the fracture, i.e. the fracture propagation rate, w the width of the fracture at its throat, being the casing dilation at fracture initiation, and μ the viscosity of the fracturing fluid at the shear rate in the fracture throat. The Reynolds number is Re=ρvw/μ. To ensure a repeatable single orientated hydraulic fracture is formed, the formation needs to be dilated orthogonal to the intended fracture plane, and the fracturing fluid pumping rate needs to be limited so that the Re is less than 1.0 during fracture initiation and less than 2.5 during fracture propagation. Also if the fracturing fluid can flow into the dilated zone in the formation ahead of the fracture and negate the induce pore pressure from formation dilation then the fracture will not propagate along the intended azimuth. In order to ensure that the fracturing fluid does not negate the pore pressure gradients in front of the fracture tip, its viscosity at fracturing shear rates within the fracture throat of ˜1-20 sec-1 needs to be greater than 100 centipoise.
• The fracture fluid forms a highly permeable hydraulic fracture by placing a proppant in the fracture to create a highly permeable fracture. Such proppants are typically clean sand for large massive hydraulic fracture installations or specialized manufactured particles (generally resin coated sand or ceramic in composition) which are designed also to limit flow back of the proppant from the fracture into the well bore. The fracture fluid-gel-proppant mixture is injected into the formation and carries the proppant to the extremes of the fracture. Upon propagation of the fracture to the requiredlateral31 andvertical extent32, the predetermined fracture thickness may need to be increased by utilizing the process of tip screen out or by re-fracturing the already induced fractures. The tip screen out process involves modifying the proppant loading and/or fracture fluid properties to achieve a proppant bridge at the fracture tip. The fracture fluid is further injected after tip screen out, but rather then extending the fracture laterally or vertically, the injected fluid widens, i.e. thickens, and fills the fracture from the fracture tip back to the well bore.
• Referring toFIG. 3 for the intermittent pressure pulsed solvent and diluent gas injection system, thecasing1 is washed clean of fracturing fluids and ascreen25 is present in the casing as abottom screen25 for hydraulic connection from the casing well bore1 to the proppedfractures30. A downholeelectric pump17 is placed inside the casing, connected to a power andinstrumentation cable18, withdownhole packer19 and droptube16 for solvent diluent gas injection, andpiping9 for production of the produced hydrocarbons to the surface. The solvent and diluent gas are injected at just below or very close to reservoir ambient pressure through thedrop tube16, through thescreen25, and into the proppedfractures30. The solvent and diluent gas contact the bitumen from the propped fracture faces and the solvent diffuses into the bitumen. The mobile oil from the bitumen includes dissolved solvents and flows by gravity along with any in place water as shown by11, to form a pool ofoil10 which flows15 into thescreen25 and13 into the pump, and is pumped14 through thetubing9 to the surface. The pressure of the injected gas in the propped fractures drops slightly as the solvent diffuses into the bitumen, and further solvent and diluent gas is injected through thedrop tube16 to continue the cycle of progressively mobilizing the in place bitumen by maintaining a saturated vaporized state of solvent in the propped fractures and mobilized oil sand region. The slight pressure cycling will encourage the gravity flow of the oil towards the well bore.
• Referring toFIGS. 3 and 4, the injected solvent and diluent gas flow as shown byvectors12 from thescreen25 into the proppedfractures30 with proppant shown34 and mobilizedoil sand zone35 adjacent to the proppedfractures34. The mobilized oil sand zone extends into thebitumen oil sands36 bydiffusive processes33 due to the partial pressure gradients. The mixture of solvent and produced bitumen results in a modified hydrocarbon that flows from thebitumen36 into the mobilizedoil sand zone35 and the proppedfracture34. The modified hydrocarbon eventually flows as11 down to a pool ofoil10 and asflow15 into thelower screen25 of the well bore. The process zone includes the proppedhydraulic fractures30, themobile zone35 in the oil sands of the formation, and the fluid contained therein. In some cases, the well borecasing1 may be considered part of the process zone when a part of the process for recovering hydrocarbons from the formation is carried out in the well casing.
• The mobilizedoil sand zone35 grows circumferentially33, i.e. orthogonal to the proppedfractures30, and becomes larger with time until eventually the bitumen within the lateral31 and vertical32 extent of the propped fracture system is completely mobilized by the injected solvent. Upon growth of the mobilized oil sand zone circumferentially to the lateral31 and vertical32 extent of the proppedfractures30, the contact area of the in place bitumen available for solvent diffusion drops dramatically from eight fracture surfaces each of an area oflateral extent31 timesvertical extent32 plus virtually a cylindrical shape of area 2π times the lateral andvertical extents31 and32, down to a cylindrical shape of area 2π times the lateral andvertical extents31 and32, i.e. from 8 plus 2π down to 2π, i.e. a drop of 65% in surface contact area, assuming vertical growth of the process zone has been inhibited by placing a light non-condensing gas in the uppermost portions of the fractures. At this stage if the process is continued, the growth of the mobile oil zone will become radial, and the mobilized oil will need to flow radially from the mobilized oil zone towards the fractures and well bore. It is at this stage that the process slows down and economics will determine if the injection/production process continues.
• Another embodiment of the present invention is shown onFIG. 5, for a continuous solvent diluent gas injection system, consisting of a similar arrangement ofhydraulic fractures30, injection casing1, abottom screen25 for hydraulic connection from the casing well bore1 to the proppedfractures30, but also atop screen26 for connection of upper portions of the propped fractures to the casing well bore1. A downholeelectric pump17 is placed inside the casing, connected to a power andinstrumentation cable18, withdownhole packer19 and droptube16 for solvent diluent gas injection, andpiping9 for production of the produced hydrocarbons to the surface. The solvent and diluent gas are injected at just below or very close to reservoir ambient pressure through thedrop tube16, through thescreen25, and into the proppedfractures30. The spent gas, now devoid or lowered in solvent content flows into the casing well bore1 through theupper screen27, with additional solvent and diluent gas injected through thedrop pipe16 and the spent tail gas removed through the casing well bore1. This system involves a continuous injection of solvent and diluent gas, compared to the earlier system which was an intermittent process.
• Another embodiment of the present invention is shown onFIGS. 6 and 7, consisting of aninjection casing38 inserted in abore hole39 and grouted in place by agrout40. Theinjection casing38 consists of eight symmetricalfracture initiation sections41,42,43,44,45,46,47, and48 to install a total of four hydraulic fractures on thedifferent azimuth planes31,31′,32,32′,33,33′,34, and34′. The process results in four hydraulic fractures installed from a single well bore at different azimuths as shown onFIG. 7. Thecasing1 is washed clean of fracturing fluids andscreen25 is present in the casing as abottom screen25 for hydraulic connection of the casing well bore1 to the proppedfractures30. A downholeelectric pump17 is placed inside the casing, connected to a power andinstrumentation cable18, withdownhole packer19 and droptube16 for solvent diluent gas injection, andpiping9 for production of the produced hydrocarbons to the surface. The solvent and diluent gas are injected at just below or very close to reservoir ambient pressure through thedrop tube16, through thescreen25 and into the proppedfractures30. The solvent and diluent gas contact the bitumen from the propped fracture faces, and the solvent diffuses into the bitumen. The mobile oil from the bitumen includes dissolved solvent and flows by gravity along with any in place water as shown by11, to form a pool ofoil10 which flows15 into thescreen25 and13 into the pump, and is pumped14 through thetubing9 to the surface. This configuration is for a pressure pulsed intermittent injection of solvent and diluent gas and could be configured similar toFIG. 5 for continuous solvent and diluent gas injection.
• Another embodiment of the present invention is shown onFIG. 8, similar toFIG. 5 except that the hydraulic fractures are constructed by a multi-stage process with various proppant materials of differing permeability. Multi-stage fracturing involves first injecting aproppant material50 to form ahydraulic fracture30. Prior to creation of the full fracture extent, adifferent proppant material51 is injected into the fracture over a reduced central section of the well bore53 to create an area of the hydraulic fracture loaded with thedifferent proppant material51. Similarly the multi-stage fracturing could consist of a third stage by injecting a thirddifferent proppant material52. By the appropriate selection of proppants with differing permeability, the circulation of the vaporized solvent in the formed fracture can be extended laterally a greater distance compared to a hydraulic fracture filled with a uniform permeable proppant, as shown earlier inFIG. 5. The proppant materials are selected so that theproppant material50 has the highest proppant permeability, withproppant material51 being lower, and withproppant material52 having the lowest proppant permeability. The different permeability of the proppant materials thus optimizes the lateral extent of the fluids flowing within the hydraulic fractures and controls the geometry and propagation rate of the transfer of heat and solvent to the oil sand formation. The permeability of the proppant materials will typically range from 1 to 100 Darcy for theproppant material50 in the fracture zone, i.e. generally being at least 10 times greater than the oil sand formation permeability. Theproppant material51 in fracture zone is selected to be lower than theproppant material50 in fracture zone by at least a factor of 2, andproppant material52 in fracture zone close to the well borecasing1 is selected to be in the milli-Darcy range thus limiting fluid flow in the fracture zone containing theproppant material52.
• Finally, it will be understood that the preferred embodiment has been disclosed by way of example, and that other modifications may occur to those skilled in the art without departing from the scope and spirit of the appended claims.

Claims (48)

1. A method for in situ recovery of hydrocarbons from a hydrocarbon containing formation having an ambient reservoir pressure and temperature, comprising:

a. drilling a bore hole in the formation to a predetermined depth to define a well bore with a casing;

b. installing one or more vertical hydraulic fractures from the bore hole to create a process zone within the formation by injecting a fracture fluid at a reservoir fracturing pressure into the casing, wherein the hydraulic fractures contain a proppant;

c. injecting a vaporized hydrocarbon solvent, having a hydrocarbon solvent vapor phase, at a solvent pressure into a section of the well casing connected to the hydraulic fractures;

d. recovering a mixture of solvent and hydrocarbons from the formation.

2. The method ofclaim 1, wherein the hydrocarbon solvent is one of a group of ethane, propane, butane, or a mixture thereof.

3. The method ofclaim 1, wherein the hydrocarbon solvent vapor is dry.

4. The method ofclaim 1, wherein the hydrocarbon solvent is injected at ambient reservoir temperature.

5. The method ofclaim 1, wherein the hydrocarbon solvent pressure is close to the ambient reservoir pressure but substantially below the reservoir fracturing pressure.

6. The method ofclaim 1, wherein the hydrocarbon solvent is mixed with a diluent gas.

7. The method ofclaim 6, wherein the diluent gas is non-condensable under the process conditions in the process zone.

8. The method ofclaim 6, wherein the non-condensable diluent gas has a lower solubility in the hydrocarbons in the formation than the saturated hydrocarbon solvent.

9. The method ofclaim 6, wherein the diluent gas is one of a group of methane, nitrogen, carbon dioxide, natural gas, or a mixture thereof.

10. The methodclaim 6, wherein the diluent gas is dry.

11. The method ofclaim 11, wherein the hydrocarbon solvent vapor is maintained saturated at or near its dew point.

12. The method ofclaim 1, wherein the dew point of the hydrocarbon solvent vapor in the injection gas is adjusted to the downhole conditions by injecting additional solvent at depth to add additional solvent to the injected gas.

13. The method ofclaim 1, wherein the hydrocarbon solvent injection is sufficient to maintain a saturated state of the hydrocarbon solvent vapor in the process zone.

14. The method ofclaim 1, wherein the hydraulic fractures are filled with proppants of differing permeability.

15. The method ofclaim 1, wherein the hydrocarbon solvent injection is a pressure pulsed cyclic intermittent injection.

16. The method ofclaim 1, wherein the hydrocarbon solvent injection is a continuous injection.

17. The method ofclaim 1, wherein the hydrocarbons produced from the formation are replaced volume for volume with the hydrocarbon solvent.

18. The method ofclaim 1, wherein the hydrocarbon solvent vapor saturation within a mixture of the hydrocarbon solvent and a diluent gas is monitored and adjusted, based on the dew point of the mixture of the hydrocarbon solvent and the diluent gas.

19. The method ofclaim 1, wherein the temperature of the hydrocarbon solvent is raised above the ambient reservoir temperature.

20. The method ofclaim 1, further comprising controlling the temperature and pressure in the majority of the part of the process zone, wherein the temperature is controlled as a function of pressure, or the pressure is controlled as a function of temperature.

21. The method ofclaim 1, wherein the pressure in the majority of the part of the process zone is at ambient reservoir pressure.

22. The method ofclaim 1, wherein at least two vertical fractures are installed from the bore hole at approximately orthogonal directions.

23. The method ofclaim 1, wherein at least three vertical fractures are installed from the bore hole.

24. The method ofclaim 1, wherein at least four vertical fractures are installed from the bore hole.

25. A hydrocarbon production well in a formation of unconsolidated and weakly cemented sediments having an ambient reservoir pressure and temperature, comprising:

a. a bore hole in the formation to a predetermined depth;

b. an injection casing grouted in the bore hole at the predetermined depth, the injection casing including multiple initiation sections separated by a weakening line and multiple passages within the initiation sections and communicating across the weakening line for the introduction of a fracture fluid to dilate the casing and separate the initiation sections along the weakening line;

c. a fracture fluid source for delivering the fracture fluid into the injection casing with sufficient reservoir fracturing pressure to dilate the injection casing and the formation and initiate a vertical hydraulic fracture, having a fracture tip, at an azimuth orthogonal to the direction of dilation to create a process zone within the formation, for controlling the propagation rate of each individual opposing wing of the hydraulic fracture, and for controlling the flow rate of the fracture fluid and its viscosity so that the Reynolds Number Re is less than 1 at fracture initiation and less than 2.5 during fracture propagation and the fracture fluid viscosity is greater than 100 centipoise at the fracture tip;

d. a source injecting a hydrocarbon solvent, having a hydrocarbon solvent vapor phase, into the casing, the hydraulic fractures and the formation; and

e. recovering a mixture of the hydrocarbon solvent and hydrocarbons from the formation through the casing.

26. The well ofclaim 26, wherein the hydrocarbon solvent is one of a group of ethane, propane, butane, or a mixture thereof.

27. The well ofclaim 26, wherein the hydrocarbon solvent vapor is dry.

28. The well ofclaim 26, wherein the hydrocarbon solvent is injected at ambient reservoir temperature.

29. The well ofclaim 26, wherein the hydrocarbon solvent is injected close to the ambient reservoir pressure but substantially below the reservoir fracturing pressure.

30. The well ofclaim 26, wherein the hydrocarbon solvent is mixed with a diluent gas.

31. The well ofclaim 31, wherein the diluent gas is non-condensable under the process conditions.

32. The well ofclaim 31, wherein the non-condensable diluent gas has a lower solubility in the hydrocarbons in the formation than the saturated hydrocarbon solvent.

33. The well ofclaim 31, wherein the diluent gas is one of a group of methane, nitrogen, carbon dioxide, natural gas, or a mixture thereof.

34. The wellclaim 31, wherein the diluent gas is dry.

35. The well ofclaim 36, wherein the hydrocarbon solvent vapor is maintained saturated at or near its dew point.

36. The well ofclaim 26, wherein the dew point of the hydrocarbon solvent vapor is adjusted to the downhole conditions by employing a solvent injector at depth to add additional hydrocarbon solvent to the process zone.

37. The well ofclaim 26, wherein the hydrocarbon solvent injection is sufficient to maintain a saturated state of the hydrocarbon solvent vapor in the process zone.

38. The well ofclaim 26, wherein the hydraulic fractures are filled with proppants of differing permeability.

39. The well ofclaim 26, wherein the hydrocarbon solvent injection is a pressure pulsed cyclic intermittent injection.

40. The well ofclaim 26, wherein the hydrocarbon solvent injection is a continuous injection.

41. The well ofclaim 26, wherein the hydrocarbons produced from the formation are replaced volume for volume with the hydrocarbon solvent and a diluent gas.

42. The well ofclaim 26, wherein the hydrocarbon solvent vapor saturation within the injection gas is monitored and adjusted, based on the dew point of the hydrocarbon solvent and a diluent gas.

43. The well ofclaim 26, wherein the temperature of the hydrocarbon solvent is raised above the ambient reservoir temperature.

44. The well ofclaim 26, further comprising controlling the temperature and pressure in the majority of the part of the process zone, wherein the temperature is controlled as a function of pressure, or the pressure is controlled as a function of temperature.

45. The well ofclaim 26, wherein the pressure in the majority of the part of the process zone is at ambient reservoir pressure.

46. The well ofclaim 26, wherein at least two vertical fractures are installed from the bore hole at approximately orthogonal directions.

47. The well ofclaim 26, wherein at least three vertical fractures are installed from the bore hole.

48. The well ofclaim 26, wherein at least four vertical fractures are installed from the bore hole.

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