US20060207178A1

Movatterモバイル変換

Info

Publication number: US20060207178A1
Application number: US10/544,737
Authority: US
Inventors: Michael Hsu
Original assignee: ZTEK Corp
Current assignee: ZTEK Corp
Priority date: 2003-02-06
Filing date: 2004-02-06
Publication date: 2006-09-21
Also published as: EP1606216A2; WO2004071947A3; CA2515321A1; WO2004071947A2

Abstract

An application applying mixed use of conventional hydrocarbon fuel with renewable energy sources for hydrogen production presents an optimal balance between economics and environmental benefits for any long-range implementations. A hydrogen production system incorporates the use of electricity from renewable sources in hydrogen reforming plants for various functions to achieve better environmental performance. The hydrogen production system includes the compression of hydrogen for high-pressure storage and an electrical heating supply for an endothermic reforming process of producing hydrogen from an input fuel. The compressed hydrogen, produced using renewable energy sources, also provides a means of stored mechanical energy, Another hydrogen production system utilizes a conventional chemical reforming process to provide leveled hydrogen generation together with electrolysis from the fluctuating renewable energy sources, which also provides low cost hydrogen generation, good environmental performance and commercial dependability.

Description

RELATED APPLICATIONS

The present invention claims priority to U.S. Provisional Patent Application Serial Number 60/449,131 entitled “RENEWABLE ENERGY OPERATED HYDROGEN PRODUCTION SYSTEM”, filed Feb. 21, 2003 and U.S. Provisional Patent Application Ser. No. 60/445,485 entitled “RENEWABLE ENERGY OPERATED HYDROGEN PRODUCTION SYSTEM”, filed Feb. 6, 2003, the contents of which are herein incorporated by reference.

FIELD OF THE INVENTION

The present invention relates to a hydrogen reforming plant for producing hydrogen. More particularly, the present invention relates to a hydrogen production plant that utilizes a renewable energy source for hydrogen compression and energy storage.

BACKGROUND OF THE INVENTION

Hydrogen is an ideal candidate for replacing fossil fuel because it can be readily made available from domestic renewable resources. Hydrogen is also nonpolluting, storable, transportable and clean, making it a valuable fuel. However, the lack of cost-effective hydrogen storage and transport particularly for an onboard vehicular system, is a major impediment to its widespread use. Improvements in the energy densities of hydrogen storage systems, reductions in cost, and increased compatibility with available and forecasted systems are required before viable hydrogen energy use will be realized.

One traditional means for generating hydrogen involves electrolysis. In this process, an electrical current is applied to split water into hydrogen at a cathode and oxygen at an anode. However, hydrogen production using electricity by electrolysis is expensive.

The storage of hydrogen fuel also poses many problems. To store hydrogen, the hydrogen must be stored under pressure, at low temperature, or both, which may require a significant amount of energy to create sufficiently high pressures and low temperatures. The requirement of additional energy for storage reduces the efficiency and effectiveness of producing and storing hydrogen.

SUMMARY OF THE INVENTION

The present invention provides a system and method for utilizing a renewable resource, such as wind energy or solar energy, for the compression or refrigeration of hydrogen as means for energy storage. The compressed hydrogen may comprise a form of mechanical energy storage and furthermore gains an added value as a transportable fuel for vehicle use.

According to one aspect of the invention, a hydrogen production system is provided. The hydrogen production system includes a reformer for producing hydrogen from a hydrocarbon fuel, a compressor for compressing the hydrogen produced by the reformer into a compressed state, a renewable energy source for converting a renewable resource into electricity for powering the compressor and a storage device for storing the compressed hydrogen from the compressor.

According to another aspect of the invention, a hydrogen production system comprising a catalytic reformer, an electric source, a compressor and a storage device is provided. The catalytic reformer produces hydrogen from a hydrocarbon fuel using one of an endothermic reforming process and steam generation. The electric source provides thermal energy for at least one of the endothermic reforming process and the steam generation. The compressor compresses the hydrogen produced by the reformer. The storage device stories the compressed or liquefied hydrogen from the compressor.

According to another aspect of the invention, a hydrogen production system comprising a catalytic reformer, a compressor and a storage device is provided. The catalytic reformer produces hydrogen from a hydrocarbon fuel and the compressor compresses the hydrogen produced by the reformer into one of a compressed and a liquefied state. The storage device stores the compressed or liquefied hydrogen from the compressor. The compressed hydrogen is pumped to a hydrogen tank of a vehicle and stored as a mechanical energy source and a chemical energy source.

According to yet another aspect of the invention, a hydrogen production system comprising a reformer, an electrolyser, one or more compressors, one or more renewable energy sources and one or more storage devices is provided. The reformer produces hydrogen from a hydrocarbon fuel. The electrolyser produces additional hydrogen by electrolysis. The compressors compress the hydrogen produced by the reformer and the electrolyser and the renewable energy sources convert a renewable resource to electricity for powering the electrolyser and the compressor. The storage devices store the compressed hydrogen from the compressor.

BRIEF DESCRIPTION OF THE FIGURES

FIG. 1 is a schematic view of a hydrogen production system according to an illustrative embodiment of the invention.

FIG. 2 illustrates the on-board components of a hydrogen powered vehicle suitable for implementing an illustrative embodiment of the invention.

FIG. 3 is a schematic view of a hydrogen production system providing levered production of hydrogen using the combination of a chemical reformer and electrolysis according to one embodiment of the present invention.

DETAILED DESCRIPTION OF THE INVENTION

The present invention provides an efficient, low cost hydrogen production system that utilizes renewable energy sources. The invention will be described below relative to an illustrative embodiment. Those skilled in the art will appreciate that the present invention may be implemented in a number of different applications and embodiments and is not specifically limited in its application to the particular embodiment depicted herein.

As used herein, the term “renewable source” or “renewable energy source” refers to any energy source with a natural replenishment rate that augments its own stock (or biomass) at a non-negligible rate. Renewable resources are generally capable of being replenished at least as fast as the renewable resource is used, although this need not be the case. Renewable sources include, but are not limited to, wind, solar energy, geothermal energy, biomass, waste, wave energy and hydro energy. In contrast, nonrenewable energy sources draw on finite resources that will eventually dwindle.

The term “renewable energy converter” refers to a system or device that converts a renewable resource to another form of energy, such as electricity.

The term “reforming”, and the like, refers to a chemical process that reacts hydrogen-containing fuels in the presence of steam, oxygen or both into a hydrogen-rich gas stream.

The term “electrolysis”, and the like, refers to an electrochemical process that dissociates water into hydrogen and oxygen using electricity.

The term “compress”, and the like, refers to a process of increasing the pressure of hydrogen ton make the hydrogen suitable for storage. The term “liquefy”, and the like, refers to a process of compressing hydrogen, which may incorporate refrigeration to reach a lower temperature, into a liquefied state and is intended to be included in the term “compress”.

FIG. 1 illustrates ahydrogen production system100 according to an illustrative embodiment of the invention. Thesystem100 comprises afuel reformer10 for producing hydrogen by converting an input fuel, fed from aninput fuel supply15, into a hydrogen gas in a process known as “reforming”. The system includes ahydrogen compressor20 for compressing the hydrogen gas produced by thereformer10 into a compressed or liquefied state by increasing the pressure and/or reducing the temperature of the hydrogen. Thesystem100 further includes ahydrogen storage device30 for storing the hydrogen after compression. Thestorage device30 can include any appropriate storage media suitable for storing or transporting hydrogen.

A renewable energy converter, such as awindmill40, photovoltaic cell or other source known in the art, is used to convert a renewable source, such as wind, solar energy, a geothermal resource, biomass, waste, wave energy and hydro energy, to electricity to power thehydrogen compressor20. The use of a renewable source to provide the necessary energy for compressing the hydrogen into a state suitable for storage and transport in accordance with the teachings of the invention, coupled with use of thermal reforming for the hydrogen production, significantly reduces the overall cost involved in producing and storing hydrogen. The illustrativehydrogen production system100 further produces hydrogen with little or no emission produced as a byproduct. Thehydrogen production system100 is further capable of at least partial or total sequestration of carbon dioxide (CO₂), which provides additional environmental benefits.

The rate of hydrogen generation from thesystem100 may be regulated according to the power available from therenewable energy converter40, resulting in a more efficient, cost effective and capacity augmented hydrogen generation andstorage system100 based on renewable energy.

Thereformer10 may comprise catalytic reformer that produces hydrogen from a hydrocarbon fuel using one of an endothermic reforming process and steam generation. For example, the reformer may be a steam reformer, autothermal reformer, partial oxidation reformer or other suitable device known in the art for separating hydrogen from hydrocarbons, for example, in a hydrocarbon fuel, to produce hydrogen, such as the autothermal cyclic reforming (ACR) process developed by General Electric Energy and Environmental. The input fuel that thereformer10 uses to produce hydrogen may comprise a hydrocarbon fuel, such as, but not limited to, natural gas (methane), liquid and gaseous hydrocarbon fuels, and carbonous fuels, such as coal.

In an illustrative embodiment of the present invention, the hydrogen can be inexpensively produced by a thermal reforming process using natural gas at less than half of the price of producing hydrogen by electrolysis. Another advantage of the use of areformer10 using natural gas to produce hydrogen is that the natural gas may be already available on site. In the present invention, the on-site generation of hydrogen using a continuous pipeline supply of natural gas, or by other known means for delivering available hydrocarbon fuel using existing infrastructure, reduces the needs for massive on-site storage and fleets of hydrogen trucks, which tend to impose sensitive safety considerations and inhibit wide adoptions of the bulk usage of hydrogen.

According to one embodiment, thereformer10 comprises a steam reformer, which converts methane (and other hydrocarbons in natural gas) into hydrogen and carbon monoxide by reaction with steam over a nickel catalyst. Conventional steam reformers currently in wide commercial use comprise a reformer section consisting of a catalyst material, which promotes the reforming reaction and a burner to supply heat for the endothermic reforming reaction. A steam source is typically connected to the reformer section to provide steam by vaporizing water.

For improved environmental performance of the system, the renewable energy converter may function as an electric source for providing thermal energy for an endothermic reforming process and/or steam generation. The heating requirement for the thermal reforming process can be supplied with the electricity derived from a source using therenewable energy converter40 or the heating derived by consuming hydrogen produced by thehydrogen production system100. According to one embodiment, the thermal energy for the endothermic reforming process performed by thereformer10 may also be supplied from a renewable energy converter, such as therenewable energy converter40 shown inFIG. 1, in electrical or thermal forms. For example, electricity derived from the renewable energy source may be used to supply heat to produce steam for a steam reforming process. The use of renewable energy to supply heat to the thermal reforming process also presents advantages over electrolysis, including increased efficiency.

In another embodiment, the reforming process can also be carried out utilizing renewable energy in an electrical discharge plasma process, such as that marketed by Wangtec of New Jersey. In such as process thereformer10 produces hydrogen using electricity derived from the renewable energy source by performing an electric discharge plasma process to reform a hydrocarbon fuel into hydrogen.

According to another embodiment, thereformer10 comprises a tubular reformer containing multiple tubes, which are normally made of refractory metal alloys. Each tube contains a packed granular or pelletized material having a suitable reforming catalyst as a surface coating. The tube diameter typically varies from between 9 cm and 16 cm, and the heated length of the tube is normally between 6 and 12 meters. A combustion zone is provided external to the tubes, and is typically formed in the burner. The tube surface temperature is maintained by the burner in the range of 900° C. to ensure that the hydrocarbon fuel flowing inside the tube is properly catalyzed with steam at a temperature of between about 500° C. and about 700° C. This traditional tube reformer relies upon conduction and convection heat transfer within the tube to distribute heat for reforming. Examples of suitable plate-type reformers for thermal enhancement are also described in U.S. Pat. Nos. 5,858,314, 5,693,201 and 6,183,703, the contents of which are herein incorporated by reference.

Thecompressor20 may comprise any suitable device known in the art for compressing hydrogen gasp into a compressed or liquefied state suitable for storage, using energy derived from a renewable source. According to one embodiment, thecompressor20 operates by increasing the pressure of the hydrogen gas. The compressor may comprise a mechanical compressor, a thermal hydride compressor, a magnetic compressor, a magneto-caloric compressor or other suitable device known in the art. Powered by energy produced by therenewable energy converter40, theillustrative compressor20 compresses and stores the hydrogen at a pressure of up to 50,000 psi. The hydrogen gas may also be liquefied for bulk storage under a cryogenic state at a temperature of between about 15-35° K.

In one application, the compressed hydrogen formed using a renewable-source and therenewable energy converter40 is a form of mechanical energy storage and furthermore gains an added value as a transportable fuel for vehicle use. In addition to providing a source of chemical energy, the compressed hydrogen may also provide a source of mechanical power that is stored in the hydrogen during the compression process. The energy content of the high-pressure hydrogen state of 10,000 psi can reach a ratio of 1:2 between the compression energy and the chemical component. Mechanical energy for compression, if utilized and recovered thermodynamically or electrochemically, represents a significant increase of energy density in the hydrogen fuel for transportation use.

Therenewable energy converter40 may comprise any suitable device that converts a renewable source, such as wind energy, solar energy, a geothermal resource, biomass, waste, wave energy, hydro energy and so on, into electricity for use by thecompressor20. According to the present invention, the electricity derived by therenewable energy converter40 may also be supplied to thereformer10 to enhance the reforming process. Suitable renewable energy converters include, but are not limited to, windmills, which convert wind energy to electricity and photovoltaic devices, which convert solar energy to electricity.

The hydrogen gas can be dispensed from thestorage tank30 through a dispenser or from the tank itself to any suitable device or system, such as a hydrogen consumption device. The thus produced hydrogen may be used as a mechanical energy source and/or a chemical energy source for the hydrogen consumption device.

According to one practice, as illustrated inFIG. 2, the hydrogen consumption device is a hydrogen-poweredfuel cell vehicle200 having an on-board fuel cell250 that produces electricity to power the vehicle from the electrochemical reaction between a hydrogen-containing fuel and oxygen from the air. The mobile vehicle may be a truck, bus, automobile, marine vessel, submarine, airplane and spacecraft, train or the like. According to one embodiment, the hydrogen formed according to the teachings of the invention may be pipe transported to users. Alternatively, the hydrogen from thehydrogen storage tank30 of thehydrogen production system100 may be vehicle transported to users.

The renewable energy provided by therenewable energy converter40 can also be used for hydrogen liquefaction for an increased range of commercial distribution. This economically viable model is applicable for the size of a filling station or for the central hydrogen production with proper siting considerations. An area with ample wind, solar or hydropower, in addition to a supply of readily available natural gas, liquid hydrocarbons or other carbonous solid fuels, provides a desirable location for the renewable energy poweredhydrogen reformer station100 of the present invention.

Referring again toFIG. 2, in one embodiment, the compressed hydrogen formed using renewable energy sources may be pumped to thehydrogen tank210 of thevehicle200 in the form of stored mechanical energy, which can then be converted to shaft power. The converted shaft power may be used for direct propulsion of the vehicle or for electrical generation using anelectrical generator220 and in turn to provide propulsion to the vehicle. The stored high-pressure hydrogen produced according to the teachings of the present invention can also be used for direct electrical power generation in a high-pressure fuel cell for the full utilization of the mechanical and chemical energies associated with the stored hydrogen. As the compression pressure increases for improved energy density for hydrogen storage, the mechanical energy related to the pressure becomes comparable to the chemical energy of the fuel. An efficient vehicle design therefore utilizes the mechanical energy stored in the fuel due to compression. Asmall size expander240, of turbo or reciprocating machinery, can be used to generate shaft power that in turn can provide mechanical or electrical energy to supplement the propulsion of thevehicle200.

The use of renewable energy in hydrogen production for hydrogen reforming and/or compression according to the teachings of the invention provides an economic, clean and transportable hydrogen fuel with enhanced energy density in storage.

According to another application, shown inFIG. 3, the present invention provides ahydrogen production system300 for mixed used of conventional hydrocarbon fuel with one or morerenewable energy converters340. For example, according to one embodiment, conventional chemical reforming may be used for leveled hydrogen generation capacity, together with electrolysis using electricity derived from renewable energy sources. As shown, thehydrogen production system300 ofFIG. 3 includes an input fuel,supply315 for providing a hydrocarbon fuel to areformer310, which reforms the hydrocarbon fuel into hydrogen. Therenewable energy converter340 converts a renewable energy source into electricity to power anelectrolyser350, which produces hydrogen using the electricity generated by therenewable energy converter340. The hydrogen from both thereformer310 and theelectrolyser350 are provided to ahydrogen compressor320 which compresses the hydrogen gas provided by thereformer310 and theelectrolyser350 into a compressed state. As shown, thecompressor320 may be powered using additional electricity derived from therenewable energy converter340. Thesystem300 further includes ahydrogen storage device330 for storing the hydrogen after compression. Thestorage device330 can include any appropriate storage media suitable for storing or transporting hydrogen.

In an illustrative embodiment, thereformer310 contributes over 50% of the hydrogen produced by thesystem300 on an average time basis, while theelectrolyser350 produces, on average, less than about 50% of the hydrogen produced by thesystem300. However, one skilled in the art will recognize that the invention is not limited to this allotments and that theelectrolyser350 and thereformer310 may produce any suitable portion of the hydrogen produced by thesystem300.

Thehydrogen production system300 ofFIG. 3 compensates for the natural fluctuations of the availability of the renewable energy supply, i.e. the daily, seasonal or weather variations of wind and solar intensity. As shown, thesystem300 improves the plant utilization, efficiency and the associated economics, by supplementing a hydrogen reforming operation using conventional hydrocarbon fuels. The mixed use of conventional hydrocarbon fuel together with a renewable energy sources provides an optimal balance among economic, environmental benefits, and commercial dependability.

The present invention has been described relative to an illustrative embodiment. Since certain changes may be made in the above constructions without departing from the scope of the invention, it is intended that all matter contained in the above description or shown in the accompanying drawings be interpreted as illustrative and not in a limiting sense.

It is also to be understood that the following claims are to cover all generic and specific features of the invention described herein, and all statements of the scope of the invention which, as a matter of language, might be said to fall therebetween.

Claims

1. A hydrogen production system comprising:

a reformer for producing hydrogen from a hydrocarbon fuel;

a compressor for compressing the hydrogen produced by the reformer into a compressed state;

a renewable energy source for converting a renewable resource into electricity for powering the compressor; and

a storage device for storing the compressed hydrogen from the compressor.

2. The hydrogen production system ofclaim 1, wherein the reformer is one of a steam reformer, an autothermal reformer, and a partial oxidation reformer.

3. The hydrogen production system ofclaim 1, wherein the hydrocarbon fuel is selected from the group consisting of coal, liquid and gaseous hydrocarbon fuel.

4. The hydrogen production system ofclaim 1, wherein the renewable resource comprises one of wind, solar, a geothermal resource, biomass, waste, wave energy and hydropower.

5. The hydrogen production system ofclaim 1, wherein the compressor is selected from the group consisting of a mechanical compressor, a thermal hydride compressor, a magnetic compressor and a magneto-caloric compressor.

6. The hydrogen production system ofclaim 1, wherein the hydrogen is compressed and stored at a pressure of up to 50,000 psi.

7. The hydrogen production system ofclaim 1, wherein the compressor liquefies the hydrogen for bulk storage under a cryogenic state.

8. The hydrogen production system ofclaim 1, wherein the hydrogen is pipe transported from the storage device to users.

9. The hydrogen production system ofclaim 1, wherein the hydrogen is vehicle transported from the storage device to users.

10. The hydrogen production system ofclaim 1, wherein the hydrogen is consumed on-site.

11. The hydrogen production system ofclaim 1, wherein the hydrogen is used for fueling a hydrogen powered vehicle.

12. The hydrogen production system ofclaim 1, wherein the system produces substantially zero emission from the production of hydrogen and is capable of the total sequestration of CO₂.

13. The hydrogen production system ofclaim 1, wherein the reformer uses thermal energy derived from the renewable resource in one of electrical form and thermal form.

14. The hydrogen production system ofclaim 1, wherein the reformer uses thermal energy derived from hydrogen produced by the said hydrogen production plant.

15. The hydrogen production system ofclaim 1, wherein the reformer uses electricity derived from renewable source to perform electric discharge plasma process for reforming hydrocarbon fuel for hydrogen production.

16. The hydrogen production system ofclaim 1, wherein the compressed hydrogen is pumped to a hydrogen tank of a vehicle and stored as a mechanical energy source and a chemical energy source.

17. The hydrogen production system ofclaim 16, wherein the stored mechanical energy is converted to shaft power for direct propulsion of the vehicle.

18. The hydrogen production system ofclaim 16, wherein the stored mechanical energy is converted to shaft power for electrical generation using an electrical generator and in turn to provide propulsion to the vehicle.

19. The hydrogen production system ofclaim 16, wherein the stored compressed hydrogen is used for direct electrical power generation in a high pressure fuel cell for the full utilization of the mechanical and chemical energies associated with the stored hydrogen.

20. The hydrogen production system ofclaim 1, wherein electricity derived from the renewable energy source is used to supply heat for the endothermic reforming process of the reformer.

21. The hydrogen production system ofclaim 1, wherein electricity derived from renewable energy source is used to supply heat to produce steam for the reforming process of the reformer.

22. A hydrogen production system, comprising:

a catalytic reformer for producing hydrogen from a hydrocarbon fuel using one of an endothermic reforming process and steam generation;

an electric source for providing thermal energy for at least one of the endothermic reforming process and the steam generation;

a compressor for compressing the hydrogen produced by the reformer; and

a storage device for storing the compressed or liquefied hydrogen from the compressor.

23. A hydrogen production system comprising:

a catalytic reformer for producing hydrogen from a hydrocarbon fuel;

a compressor for compressing the hydrogen produced by the reformer into one of a compressed and a liquefied state; and

a storage device for storing the compressed or liquefied hydrogen from the compressor, wherein the compressed hydrogen is pumped to a hydrogen tank of a vehicle and stored as a mechanical energy source and a chemical energy source.

24. The hydrogen production system ofclaim 23, wherein the stored mechanical energy is converted to shaft power for direct propulsion of the vehicle.

25. The hydrogen production system ofclaim 23, wherein the stored mechanical energy is converted to shaft power for electrical generation using an electrical generator and in turn to provide propulsion to the vehicle.

26. The hydrogen production system ofclaim 23, wherein the stored compressed hydrogen is used for direct electrical power generation in a high pressure fuel cell for the full utilization of the mechanical and chemical energies associated with the stored hydrogen.

27. A hydrogen production system comprising:

a reformer for producing hydrogen from a hydrocarbon fuel;

an electrolyser for producing additional hydrogen by electrolysis;

one or more compressors for compressing the hydrogen produced by the reformer and the electrolyser;

one or more renewable energy sources for converting a renewable resource to electricity for powering the electrolysis and the compressor; and

one or more storage devices for storing the compressed hydrogen from the compressor.

28. The hydrogen production system ofclaim 27, wherein the reformer is selected, from the group consisting of: a steam reformer, an autothermal reformer and a partial oxidation reformer.

29. The hydrogen production system ofclaim 27, wherein the reformer operates to achieve leveled production of hydrogen as the electrolysis operates at a capacity depending on the availability of renewable energy supplies.

30. The hydrogen production system ofclaim 27, wherein the reformer contributes on a time average basis over 50% of the hydrogen production of the system and the electrolysis contributes less than 50% of the hydrogen production of the system.