US20060077367A1 - Exposure apparatus and method for producing device - Google Patents

Abstract

There is provided an exposure apparatus capable of forming a desirable device pattern by removing unnecessary liquid when performing exposure by projecting a pattern onto the substrate via a projection optical system and the liquid. The exposure device projects an image of the pattern onto the substrate P via the projection optical system and the liquid so as to expose the substrate P. The exposure device includes a liquid removing mechanism40which removes the liquid remaining on a part7arranged in the vicinity of the image plane of the projection optical system.

Description

CROSS-REFERENCE
• This application is a Continuation Application of International Application No. PCT/JP2004/007417 which was filed on May 24, 2004 claiming the conventional priority of Japanese patent Application Nos. 2003-146423 filed on May 23, 2003; 2003-305280 filed on Aug. 28, 2003; and 2004-049231 filed on Feb. 25, 2004.
BACKGROUND OF THE INVENTION
• 1. Field of the Invention
• The present invention relates to an exposure apparatus and a method for producing a device in which a substrate is exposed with a pattern via a projection optical system and a liquid.
• 2. Description of the Related Art
• Semiconductor devices and liquid crystal display devices are produced by the so-called photolithography technique in which a pattern formed on a mask is transferred onto a photosensitive substrate. The exposure apparatus, which is used in the photolithography step, includes a mask stage for supporting the mask and a substrate stage for supporting the substrate. The pattern on the mask is transferred onto the substrate via a projection optical system while successively moving the mask stage and the substrate stage. In recent years, it is demanded to realize the higher resolution of the projection optical system in order to respond to the further advance of the higher integration of the device pattern. As the exposure wavelength to be used is shorter, the resolution of the projection optical system becomes higher. As the numerical aperture of the projection optical system is larger, the resolution of the projection optical system becomes higher. Therefore, the exposure wavelength, which is used for the exposure apparatus, is shortened year by year, and the numerical aperture of the projection optical system is increased as well. The exposure wavelength, which is dominantly used at present, is 248 nm of the KrF excimer laser. However, the exposure wavelength of 193 nm of the ArF excimer laser, which is shorter than the above, is also practically used in some situations. When the exposure is performed, the depth of focus (DOF) is also important in the same manner as the resolution. The resolution R and the depth of focus δ are represented by the following expressions respectively.
  R=k₁·λ/NA  (1)
  δ=±k₂·λ/NA²  (2)
• In the expressions, λ represents the exposure wavelength, NA represents the numerical aperture of the projection optical system, and k₁and k₂represent the process coefficients. According to the expressions (1) and (2), the following fact is appreciated. That is, when the exposure wavelength λ is shortened and the numerical aperture NA is increased in order to enhance the resolution R, then the depth of focus δ is narrowed.
• If the depth of focus δ is too narrowed, it is difficult to match the substrate surface with respect to the image plane of the projection optical system. It is feared that the margin is insufficient during the exposure operation. Accordingly, the liquid immersion method has been suggested, which is disclosed, for example, in International Publication No. 99/49504 as a method for substantially shortening the exposure wavelength and widening the depth of focus. In this liquid immersion method, the space between the lower surface of the projection optical system and the substrate surface is filled with a liquid such as water or any organic solvent so that the resolution is improved and the depth of focus is magnified about n times by utilizing the fact that the wavelength of the exposure light beam in the liquid is 1/n as compared with that in the air (n represents the refractive index of the liquid, which is about 1.2 to 1.6 in ordinary cases).
• However, the conventional technique as described above involves the following problem. The exposure apparatus, which is disclosed in International Publication No. 99/49504, is constructed such that the liquid is supplied and recovered to form the liquid immersion area on a part of the substrate. In the case of this exposure apparatus, for example, when the substrate stage is moved to the load/unload position in order to unload the substrate having been placed on the substrate stage and load a new substrate in a state in which the liquid in the liquid immersion area is not recovered sufficiently after the completion of the liquid immersion exposure, there is such a possibility that the liquid, which remains on (adheres to) the end portion of the projection optical system, the liquid supply nozzle, and/or the liquid recovery nozzle, may fall onto surrounding units and members including, for example, the guide surface of the stage and the reflecting surface for the interferometer for the stage.
• Further, when the liquid remains on the optical element disposed at the end portion of the projection optical system, the remaining liquid leaves any adhesion trace (so-called water mark) on the optical element disposed at the end portion of the projection optical system after the evaporation of the remaining liquid. There is such a possibility that any harmful influence may be exerted on the pattern to be formed on the substrate during the exposure process to be subsequently performed. It is also assumed that the liquid immersion area is formed during any process other than the exposure process, i.e., when the reference mark member and/or the reference plane member arranged around the substrate on the substrate stage is used. In such a situation, there is such a possibility that the liquid in the liquid immersion area cannot be recovered sufficiently, the adhesion trace may remain on the member as described above, and the liquid remaining on the member as described above may be scattered.
SUMMARY OF THE INVENTION
• The present invention has been made taking the foregoing circumstances into consideration, an object of which is to provide an exposure apparatus capable of forming a desired device pattern on a substrate by sufficiently removing any unnecessary liquid when the pattern is projected onto the substrate to perform the exposure via a projection optical system and the liquid, and a method for producing a device based on the use of the exposure apparatus.
• In order to achieve the object as described above, the present invention adopts the following constructions corresponding to FIGS.1 to27 as illustrated in embodiments. However, parenthesized symbols affixed to respective elements merely exemplify the elements by way of example, with which it is not intended to limit the respective elements.
• According to a first aspect of the present invention, there is provided an exposure apparatus (EX) which projects an image of a pattern onto a substrate (P) through a liquid (1) to expose the substrate therewith; the exposure apparatus comprising a projection optical system (PL) which projects the image of the pattern onto the substrate; and a liquid-removing mechanism (40,60,160,174,178,180,183,251,257) which removes the liquid remaining on a part (27,13,14,31,32,151,152) arranged in the vicinity of an image plane of the projection optical system.
• According to the present invention, any unnecessary liquid, which remains on the part arranged in the vicinity of the image plane of the projection optical system, including, for example, an optical element disposed at the end portion of the projection optical system, a reference member for positioning the shot area, various sensors, a light-transmitting optical member, and a nozzle of the liquid supply and/or the liquid recovery mechanism, is removed by the liquid-removing mechanism. Accordingly, it is possible to avoid the scattering and the falling of the remaining liquid and the occurrence of the adhesion trace (water mark) on the part as described above. Therefore, it is possible to form the desired pattern accurately on the substrate.
• According to a second aspect of the present invention, there is provided an exposure apparatus (EX) which exposes a substrate (P) by forming a liquid immersion area (AR2) on a part of the substrate (P) and projecting an image of a pattern onto the substrate (P) through a liquid (1) in the liquid immersion area, the exposure apparatus comprising:
• a projection optical system (PL) which projects the image of the pattern onto the substrate;
• a substrate stage (PST) which is movable while holding the substrate;
• a liquid supply mechanism (10) which supplies the liquid onto the substrate to form the liquid immersion area;
• a first liquid recovery mechanism (30) which recovers the liquid from a surface of the substrate; and
• a second liquid recovery mechanism (20) which has a recovery port (23) provided on the substrate stage and which recovers the liquid after completion of the exposure for the substrate.
• According to the present invention, the liquid in the liquid immersion area on the substrate is recovered by not only the first liquid recovery mechanism but also the second liquid recovery mechanism having the recovery port on the stage after the completion of the liquid immersion exposure. Accordingly, it is possible to avoid the scattering and the falling of the remaining liquid and the occurrence of the adhesion trace of the remaining liquid. Therefore, it is possible to form the desired pattern accurately on the substrate.
• According to a third aspect of the present invention, there is provided an exposure apparatus (EX) which exposes a substrate by projecting an image of a pattern onto the substrate through a liquid; the exposure apparatus comprising a projection optical system (PL) which projects the image of the pattern onto the substrate; and a detection unit (100,198) which detects a state of a surface of a part (for example,2,151,152) arranged in the vicinity of an image plane side of the projection optical system (PL).
• According to the present invention, the detection unit can be used to detect the surface state of the part arranged in the vicinity of the image plane of the projection optical system (whether or not any foreign matter such as the liquid is adhered). Therefore, it is possible to perform an appropriate treatment including, for example, the removal of the foreign matter from the surface of the part by the washing, depending on an obtained result.
• According to a fourth aspect of the present invention, there is provided a method for producing a device, wherein the exposure apparatus (EX) as defined in any one of the aspects described above is used. According to the present invention, it is possible to produce the device having desired performance in a state in which the environmental change and the occurrence of the adhesion trace on the optical element disposed in the vicinity of the image plane of the projection optical system are suppressed.
BRIEF DESCRIPTION OF THE DRAWINGS
• FIG. 1 shows a schematic arrangement illustrating an embodiment of an exposure apparatus of the present invention.
• FIG. 2 shows a schematic arrangement illustrating a liquid recovery mechanism and a liquid supply mechanism for forming a liquid immersion area.
• FIG. 3 shows a plan view illustrating a substrate stage.
• FIG. 4 shows an example of a second liquid recovery unit.
• FIGS. 5A and 5B show a schematic arrangement illustrating an example of a first liquid-removing unit as a liquid-removing mechanism.
• FIG. 6 shows a schematic arrangement illustrating an example of a first liquid-removing unit as a liquid-removing mechanism.
• FIG. 7 shows a schematic arrangement illustrating an example of a first liquid-removing unit as a liquid-removing mechanism.
• FIG. 8 shows a schematic arrangement illustrating an example of a second liquid-removing unit as a liquid-removing mechanism.
• FIG. 9 schematically illustrates a situation of movement of the substrate stage.
• FIG. 10 shows a schematic arrangement illustrating an example of a second liquid-removing unit as a liquid-removing mechanism.
• FIG. 11 shows a schematic arrangement illustrating an example of a second liquid-removing unit as a liquid-removing mechanism.
• FIG. 12 shows a schematic arrangement illustrating an example of a second liquid-removing unit as a liquid-removing mechanism.
• FIG. 13 schematically shows an example of a washing mechanism.
• FIG. 14 schematically shows an example of a washing mechanism.
• FIG. 15 schematically shows an example of a foreign matter-detecting system.
• FIG. 16 shows a plan view illustrating another embodiment of a substrate stage.
• FIG. 17 schematically shows an example of a first liquid-removing unit.
• FIG. 18 schematically shows another embodiment of an exposure apparatus of the present invention.
• FIG. 19 schematically shows another embodiment of the operation for removing the liquid according to the present invention.
• FIGS. 20A and 20B show the relationship between the gas nozzle and the optical element.
• FIG. 21 schematically shows another embodiment of an exposure apparatus of the present invention.
• FIG. 22 schematically shows another embodiment of an exposure apparatus of the present invention.
• FIG. 23 schematically shows another embodiment of an exposure apparatus of the present invention.
• FIG. 24 schematically shows another embodiment of an exposure apparatus of the present invention.
• FIG. 25 shows a plan view illustrating major parts of a substrate stage shown inFIG. 24 as viewed from an upper position.
• FIG. 26 shows a flow chart illustrating exemplary steps of producing a semiconductor device.
• FIG. 27 shows a flow chart illustrating an exemplary exposure procedure with the exposure apparatus according to the present invention.
DESCRIPTION OF THE PREFERRED EMBODIMENTS OF THE INVENTION
• An explanation will be made below about embodiments of the exposure apparatus according to the present invention with reference to the drawings. However, the present invention is not limited thereto.
Embodiment of Exposure Apparatus Based on Use of First and Second Liquid-Removing Units
• FIG. 1 shows a schematic arrangement illustrating an embodiment of the exposure apparatus of the present invention. With reference toFIG. 1, an exposure apparatus EX includes a mask stage MST which supports a mask M, a substrate stage PST which supports a substrate P, an illumination optical system IL which illuminates, with an exposure light beam EL, the mask M supported by the mask stage MST, a projection optical system PL which performs projection exposure for the substrate P supported by the substrate stage PST with an image of a pattern of the mask M illuminated with the exposure light beam EL, and a control unit CONT which collectively controls the overall operation of the exposure apparatus EX.
• The exposure apparatus EX of this embodiment is a liquid immersion exposure apparatus to which the liquid immersion method is applied in order that the exposure wavelength is substantially shortened to improve the resolution and the depth of focus is substantially widened. The exposure apparatus EX includes aliquid supply mechanism10 which supplies theliquid1 onto the substrate P, and a liquid recovery mechanism (first liquid recovery mechanism)30 which recovers the liquid1 from the surface of the substrate P. In this embodiment, pure water is used as theliquid1. The exposure apparatus EX forms a liquid immersion area AR2 on at least a part of the substrate P including a projection area AR1 of the projection optical system PL by theliquid1 supplied from theliquid supply mechanism10 at least during the period in which the pattern image of the mask M is transferred onto the substrate P. Specifically, the exposure apparatus EX is operated as follows. That is, the space between the surface (exposure surface) of the substrate P and theoptical element2 disposed at the end portion of the projection optical system PL is filled with theliquid1. The pattern image of the mask M is projected onto the substrate P to expose the substrate P therewith via the projection optical system PL and the liquid1 disposed between the projection optical system PL and the substrate P.
• The embodiment of the present invention will now be explained as exemplified by a case of the use of the scanning type exposure apparatus (so-called scanning stepper) as the exposure apparatus EX in which the substrate P is exposed with the pattern formed on the mask M while synchronously moving the mask M and the substrate P in mutually different directions (opposite directions) in the scanning directions. In the following explanation, the X axis direction is the synchronous movement direction (scanning direction) for the mask M and the substrate P in the horizontal plane, the Y axis direction (non-scanning direction) is the direction which is perpendicular to the X axis direction in the horizontal plane, and the Z axis direction is the direction which is perpendicular to the X axis direction and the Y axis direction and which is coincident with the optical axis AX of the projection optical system PL. The directions about the X axis, the Y axis, and the Z axis are designated as θX, θY, and θZ directions respectively. The term “substrate” referred to herein includes substrates obtained by coating a semiconductor wafer surface with a resist, and the term “mask” includes a reticle formed with a device pattern to be subjected to the reduction projection onto the substrate.
• The illumination optical system IL is used so that the mask M, which is supported on the mask stage MST, is illuminated with the exposure light beam EL. The illumination optical system IL includes, for example, an exposure light source, an optical integrator which uniformizes the illuminance of the light flux radiated from the exposure light source, a condenser lens which collects the exposure light beam EL supplied from the optical integrator, a relay lens system, and a variable field diaphragm which sets the illumination area on the mask M illuminated with the exposure light beam EL to be slit-shaped. The predetermined illumination area on the mask M is illuminated with the exposure light beam EL having a uniform illuminance distribution by the illumination optical system IL. Those usable as the exposure light beam EL radiated from the illumination optical system IL include, for example, emission lines (g-ray, h-ray, i-ray) in the ultraviolet region radiated, for example, from a mercury lamp, far ultraviolet light beams (DUV light beams) such as the KrF excimer laser beam (wavelength: 248 nm), and vacuum ultraviolet light beams (VUV light beams) such as the ArF excimer laser beam (wavelength: 193 nm) and the F₂laser beam (wavelength: 157 nm). In this embodiment, the ArF excimer laser beam is used. As described above, theliquid1 is pure water in this embodiment, through which the exposure light beam EL is transmissive even when the exposure light beam EL is the ArF excimer laser beam. The emission line (g-ray, h-ray, i-ray) in the ultraviolet region and the far ultraviolet light beam (DUV light beam) such as the KrF excimer laser beam (wavelength: 248 nm) are also transmissive through pure water.
• The mask stage MST supports the mask M. The mask stage MST is two-dimensionally movable in the plane perpendicular to the optical axis AX of the projection optical system PL, i.e., in the XY plane, and it is finely rotatable in the θZ direction. The mask stage MST is driven by a mask stage-driving unit MSTD such as a linear motor. The mask stage-driving unit MSTD is controlled by the control unit CONT. Amovement mirror50 is provided on the mask stage MST. Alaser interferometer51 is provided at a position opposed to themovement mirror50. The position in the two-dimensional direction and the angle of rotation of the mask M on the mask stage MST are measured in real-time by thelaser interferometer51. The result of the measurement is outputted to the control unit CONT. The control unit CONT drives the mask stage-driving unit MSTD on the basis of the result of the measurement obtained by thelaser interferometer51 to thereby position the mask M supported on the mask stage MST.
• The projection optical system PL projects the pattern on the mask M onto the substrate P at a predetermined projection magnification β to perform the exposure. The projection optical system PL includes a plurality of optical elements including the optical element (lens)2 provided at the end portion on the side of the substrate P. The optical elements are supported by a barrel PK. In this embodiment, the projection optical system PL is the reduction system having the projection magnification β which is, for example, ¼ or ⅕. The projection optical system PL may be any one of the 1× magnification system and the magnifying system. Theoptical element2, which is disposed at the end portion of the projection optical system PL of this embodiment, is provided detachably (exchangeably) with respect to the barrel PK. Theoptical element2, which is disposed at the end portion, is exposed (protrudes) from the barrel PK. The liquid1 in the liquid immersion area AR2 makes contact with only theoptical element2. Accordingly, the barrel PK formed of metal can be prevented from any corrosion or the like.
• Theoptical element2 is formed of fluorite. Fluorite has a high affinity for water. Therefore, theliquid1 is successfully allowed to make tight contact with the substantially entire surface of theliquid contact surface2aof theoptical element2. That is, in this embodiment, the liquid (pure water)1, which has the high affinity for theliquid contact surface2aof theoptical element2, is supplied. Therefore, the highly tight contact is effected between the liquid1 and theoptical element2. Quartz having a high affinity for water may be used as theoptical element2 as well. A water-attracting (lyophilic or liquid-attracting) treatment may be applied to theliquid contact surface2aof theoptical element2 to further enhance the affinity for theliquid1.
• The exposure apparatus EX further includes a focus-detectingsystem4. The focus-detectingsystem4 has a light-emittingsection4aand a light-receivingsection4b. The detecting light beam is projected obliquely from an upper position onto the surface (exposure surface) of the substrate P via the liquid1 from the light-emittingsection4a. The reflected light beam from the surface of the substrate P is received by the light-receivingsection4b. The control unit CONT controls the operation of the focus-detectingsystem4. Further, the position (focus position) in the Z axis direction of the surface of the substrate P with respect to a predetermined reference surface is detected on the basis of a light-receiving result obtained by the light-receivingsection4b. Respective focus positions at a plurality of respective points on the surface of the substrate P are determined by using the focus-detectingsystem4. Accordingly, it is also possible to detect the posture of the substrate P in an inclined direction. Those usable for the arrangement or the structure of the focus-detectingsystem4 may include, for example, one disclosed in Japanese Patent Application Laid-open No. 8-37149.
• The substrate stage PST supports the substrate P. The substrate stage PST includes aZ stage52 which holds the substrate P by the aid of a substrate holder, anXY stage53 which supports theZ stage52, and a base54 which supports theXY stage53. The substrate stage PST is driven by a substrate stage-driving unit PSTD such as a linear motor. The substrate stage-driving unit PSTD is controlled by the control unit CONT. It goes without saying that the Z stage and the XY stage may be provided as an integrated body. When theXY stage53 of the substrate stage PST is driven, the substrate P is subjected to the control of the position in the XY directions (position in the direction substantially parallel to the image plane of the projection optical system PL).
• Amovement mirror55, which is movable together with the substrate stage PST with respect to the projection optical system PL, is provided on the substrate stage PST (Z stage52). Alaser interferometer56 is provided at a position opposed to themovement mirror55. The angle of rotation and the position in the two-dimensional direction of the substrate P on the substrate stage PST are measured in real-time by thelaser interferometer56. The result of the measurement is outputted to the control unit CONT. The control unit CONT drives theXY stage53 by the aid of the substrate stage-driving unit PSTD on the basis of the result of the measurement of thelaser interferometer56 to thereby position the substrate P supported on the substrate stage PST in the X axis direction and the Y axis direction.
• The control unit CONT drives theZ stage52 of the substrate stage PST by the aid of the substrate stage-driving unit PSTD. Accordingly, the control unit CONT controls the position (focus position) in the Z axis direction of the substrate P held by theZ stage52 and the position in the θX direction and the θY direction. That is, theZ stage52 is operated on the basis of the instruction from the control unit CONT based on the result of the detection performed by the focus-detectingsystem4. The focus position (Z position) and the angle of inclination of the substrate P are controlled so that the surface (exposure surface) of the substrate P is adjusted to the image plane formed via the projection optical system PL and theliquid1.
• Anauxiliary plate57 having a flat surface is provided on the substrate stage PST (Z stage52) so that the substrate P is surrounded thereby. Theauxiliary plate57 is installed so that the surface has approximately the same height as that of the surface of the substrate P held by the substrate holder. In this arrangement, a gap of about 0.1 to 2 mm is formed between theauxiliary plate57 and the edge of the substrate P. However, theliquid1 scarcely flows into the gap owing to the surface tension of theliquid1. Even when the vicinity of the circumferential edge of the substrate P is subjected to the exposure, theliquid1 can be retained under the projection optical system PL by the aid of theauxiliary plate57.
• Asubstrate alignment system5, which detects the alignment mark on the substrate P or the reference mark provided on theZ stage52, is provided in the vicinity of the end portion of the projection optical system PL. Amask alignment system6, which detects the reference mark provided on theZ stage52 via the mask M and the projection optical system PL, is provided in the vicinity of the mask stage MST. Those usable for the arrangement of thesubstrate alignment system5 include, for example, one disclosed in Japanese Patent Application Laid-open No. 4-65603. Those usable for the arrangement of themask alignment system6 include, for example, one disclosed in Japanese Patent Application Laid-open No. 7-176468.
• A first liquid-removingunit40, which removes theliquid1 remaining on the reference member having the reference mark provided on theZ stage52, is provided in the vicinity of thesubstrate alignment system5. The substrate stage PST is provided with a secondliquid recovery unit20 which recovers theliquid1.
• Theliquid supply mechanism10 supplies thepredetermined liquid1 onto the substrate P in order to form the liquid immersion area AR2. Theliquid supply mechanism10 includes a firstliquid supply section11 and a secondliquid supply section12 which are capable of feeding theliquid1, afirst supply nozzle13 which is connected to the firstliquid supply section11 through asupply tube11A having a flow passage and which has a supply port for supplying theliquid1 fed from the firstliquid supply section11 onto the substrate P, and asecond supply nozzle14 which is connected to the secondliquid supply section12 through asupply tube12A having a flow passage and which has a supply port for supplying theliquid1 fed from the secondliquid supply section12 onto the substrate P. The first andsecond supply nozzles13,14 make contact with the liquid1 in the liquid immersion area AR2 during the liquid immersion exposure. The first andsecond supply nozzles13,14 are arranged closely to the surface of the substrate P, and they are provided at mutually different positions in the surface direction of the substrate P. Specifically, thefirst supply nozzle13 of theliquid supply mechanism10 is provided on one side (−X side) in the scanning direction with respect to the projection area AR1. Thesecond supply nozzle14 is provided on the other side (+X side) in the scanning direction so that thesecond supply nozzle14 is opposed to thefirst supply nozzle13.
• Each of the first and secondliquid supply sections11,12 includes, for example, a tank for accommodating the liquid1, and a pressurizing pump. The first and secondliquid supply sections11,12 supply theliquid1 onto the substrate P through thesupply tubes11A,12A and thesupply nozzles13,14 respectively. The operation of the first and secondliquid supply sections11,12 for supplying the liquid is controlled by the control unit CONT. The control unit CONT is capable of controlling the liquid supply amounts per unit time onto the substrate P by the first and secondliquid supply sections11,12 independently respectively. Each of the first and secondliquid supply sections11,12 includes a temperature-adjusting mechanism for theliquid1. Theliquid1, which has approximately the same temperature of 23° C. as the temperature in the chamber for accommodating the apparatus therein, is supplied onto the substrate P.
• It is preferable that the pure water (liquid), which is supplied from theliquid supply sections11,12, has a transmittance of not less than 99%/mm. In this case, it is desirable that the value of TOC (total organic carbon), which indicates the total amount of carbon contained in organic compounds, is less than 3 ppb in relation to carbon compounds dissolved in the pure water.
• The liquid recovery mechanism (first liquid recovery unit)30 recovers the liquid1 from the surface of the substrate P. Theliquid recovery mechanism30 includes first andsecond recovery nozzles31,32 each of which has a recovery port arranged closely to the surface of the substrate P, and first and secondliquid recovery sections33,34 which are connected to the first andsecond recovery nozzles31,32 throughrecovery tubes33A,34A having flow passages respectively. The first andsecond recovery nozzles31,32 make contact with the liquid1 in the liquid immersion area AR2 during the liquid immersion exposure. Each of the first and secondliquid recovery sections33,34 includes, for example, a sucking unit such as a vacuum pump, and a tank for accommodating the recoveredliquid1. The first and secondliquid recovery sections33,34 recover the liquid1 from the surface of the substrate P through the first andsecond recovery nozzles31,32 and therecovery tubes33A,34A. The operation of each of the first and secondliquid recovery sections33,34 for recovering the liquid is controlled by the control unit CONT. The control unit CONT is capable of controlling the liquid recovery amounts per unit time by the first and secondliquid recovery sections33,34 independently respectively.
• FIG. 2 shows a plan view illustrating a schematic arrangement of theliquid supply mechanism10 and theliquid recovery mechanism30. As shown inFIG. 2, the projection area AR1 of the projection optical system PL is designed to have a slit shape (rectangular shape) in which the Y axis direction (non-scanning direction) is the longitudinal direction. The liquid immersion area AR2, which is filled with theliquid1, is formed on a part of the substrate P so that the projection area AR1 is included therein. As described above, thefirst supply nozzle13 of theliquid supply mechanism10, which is used to form the liquid immersion area AR2 for the projection area AR1, is provided on one side (−X side) in the scanning direction with respect to the projection area AR1, and thesecond supply nozzle14 is provided on the other side (+X side) in the scanning direction on the opposite side. The first andsecond supply nozzles13,14 are formed to be linear as viewed in a plan view in which the Y axis direction is the longitudinal direction respectively. The supply ports of the first andsecond supply nozzles13,14 are formed to be slit-shaped while the Y axis direction is the longitudinal direction respectively, and they are directed to the surface of the substrate P. Theliquid supply mechanism10 simultaneously supplies the liquid1 from the ± sides in the X direction of the projection area AR1 from the supply ports of the first andsecond supply nozzles13,14.
• As appreciated fromFIG. 2, each of the first andsecond recovery nozzles31,32 of theliquid recovery mechanism30 has a recovery port which is formed continuously to be circular arc-shaped so that the recovery port is directed to the surface of the substrate P. A substantially annular recovery port is formed by the first andsecond recovery nozzles31,32 which are arranged so that they are opposed to one another. The respective recovery ports of the first andsecond recovery nozzles31,32 are arranged to surround the projection area AR1 and the first andsecond supply nozzles13,14 of theliquid supply mechanism10. A plurality ofpartition members35 are provided in the recovery port formed continuously to surround the projection area AR1.
• Theliquid1, which is supplied onto the substrate P from the supply ports of the first andsecond supply nozzles13,14, is supplied so that theliquid1 is spread while causing the wetting between the substrate P and the lower end surface of the end portion (optical element2) of the projection optical system PL. Theliquid1, which is supplied from the first andsecond supply nozzles13,14, is recovered from the recovery ports of the first andsecond recovery nozzles31,32.
• FIG. 3 shows a schematic plan view illustrating theZ stage52 of the substrate stage PST as viewed from an upper position. The movement mirrors55 are arranged on the mutually perpendicular two side surfaces of therectangular Z stage52. The substrate P is held at a substantially central portion of theZ stage52 by the aid of an unillustrated holder. As described above, theauxiliary plate57, which has the flat surface of substantially the same height as that of the surface of the substrate P, is provided around the substrate P. A liquid-absorbingmember21, which constitutes a part of the secondliquid recovery unit20 for recovering theliquid1, is provided around theauxiliary plate57. The liquid-absorbingmember21 is an annular member having a predetermined width, which is arranged in a groove (recovery port)23 formed annularly on theZ stage52. The liquid-absorbingmember21 is formed of a porous material including, for example, a porous ceramics. Alternatively, a sponge as a porous material may be used as the material for forming the liquid-absorbingmember21. When the liquid-absorbingmember21 formed of the porous material is used as described above, a predetermined amount of the liquid1 can be retained by the liquid-absorbingmember21.
• FIG. 4 shows a sectional view illustrating the secondliquid recovery unit20. The secondliquid recovery unit20 includes the liquid-absorbingmember21 which is arranged in the groove (recovery port)23 formed annularly on theZ stage52 as described above, aflow passage22 which is formed in theZ stage52 and which is communicated with thegroove23, atube passage26 which is provided outside theZ stage52 and which has one end connected to theflow passage22, atank27 which is connected to the other end of thetube passage26 and which is provided outside theZ stage52, and apump29 as a sucking unit which is connected to thetank27 via avalve28. Theliquid recovery unit20 drives thepump29 to suck theliquid1 recovered by the liquid-absorbingmember21 so that theliquid1 is collected in thetank27. Thetank27 is provided with adischarge flow passage27A. When a predetermined amount of theliquid1 is pooled in thetank27, theliquid1 contained in thetank27 is discharged to the outside via thedischarge flow passage27A.
• With reference toFIG. 3 again, areference member7 is provided in the vicinity of one corner of theZ stage52. A reference mark PFM which is to be detected by thesubstrate alignment system5 and a reference mark MFM which is to be detected by themask alignment system6 are provided on thereference member7 in a predetermined positional relationship. The surface of thereference member7 is substantially flat, which also functions as a reference surface for the focus-detectingsystem4. The reference surface for the focus-detectingsystem4 may be provided on theZ stage52 separately from thereference member7. Thereference member7 and theauxiliary plate57 may be provided as an integrated body.
• A liquid-absorbingmember42, which constitutes a part of the first liquid-removingunit40 for removing theliquid1 remaining on thereference member7, is provided in the vicinity of thereference member7 on theZ stage52. Further, a second liquid-removingunit60, which removes theliquid1 remaining on theoptical element2 disposed at the end portion of the projection optical system PL and/or the barrel PK disposed in the vicinity of the end portion, is provided in the vicinity of another corner of theZ stage52.
• Next, an explanation will be made with reference to a flow chart shown inFIG. 27 about a procedure for exposing the substrate P with the pattern on the mask M by using the exposure apparatus EX described above. The position information about the alignment mark is determined in a state in which theliquid1 is absent on the substrate P before supplying the liquid1 from theliquid supply mechanism10. The control unit CONT moves theXY stage53 while monitoring the output of thelaser interferometer56 so that the portion corresponding to the optical axis AX of the projection optical system PL is advanced along abroken line arrow43 shown inFIG. 3. During the movement, thesubstrate alignment system5 detects a plurality of alignment marks (not shown) formed on the substrate P corresponding to the shot areas S1 to S11 without passing through the liquid1 (Step SA1,FIG. 27). The alignment marks are detected by thesubstrate alignment system5 in a state in which theXY stage53 is stopped. As a result, the position information about the respective alignment marks is determined in the coordinate system prescribed by thelaser interferometer56. When the alignment marks are detected by thesubstrate alignment system5, all of the alignment marks on the substrate P may be detected, or only a part thereof may be detected.
• Further, during the movement of theXY stage53, the surface information of the substrate P is detected by the focus-detectingsystem4 without passing through the liquid1 (Step SA2,FIG. 27). The surface information is detected by the focus-detectingsystem4 for all of the shot areas S1 to S11 on the substrate P respectively. The result of the detection is stored in the control unit CONT while corresponding to the position of the substrate P in the scanning direction (X axis direction). The surface information may be detected by the focus-detectingsystem4 for only a part of the shot areas.
• When the detection of the alignment mark of the substrate P and the detection of the surface information of the substrate P are completed, the control unit CONT moves theXY stage53 so that the detection area of thesubstrate alignment system5 is positioned on thereference member7. Thesubstrate alignment system5 detects the reference mark PFM on thereference member7 to determine the position information of the reference mark PFM in the coordinate system prescribed by the laser interferometer56 (Step SA3,FIG. 27).
• As a result of the completion of the detection process for the reference mark PFM, the positional relationships between the reference mark PFM and the plurality of alignment marks on the substrate P, i.e., the positional relationships between the reference mark PFM and the plurality of shot areas S1 to S11 on the substrate P are determined respectively. Further, the reference mark PFM and the reference mark MFM are in the predetermined positional relationship. Therefore, the positional relationships between the reference mark MFM and the plurality of shot areas S1 to S11 on the substrate P in the XY plane are determined respectively.
• The control unit CONT detects the surface information of the surface (reference surface) of thereference member7 by using the focus-detectingsystem4 before or after the detection of the reference mark PFM by the substrate alignment system5 (Step SA4,FIG. 27). When the detection process for the surface of thereference member7 is completed, the relationship between the surface of thereference member7 and the surface of the substrate P is determined.
• Subsequently, the control unit CONT moves theXY stage53 so that the reference mark MFM on thereference member7 can be detected by themask alignment system6. In this situation, the end portion of the projection optical system PL is opposed to thereference member7. The control unit CONT starts the supply and the recovery of theliquid1 by theliquid supply mechanism10 and theliquid recovery mechanism30, respectively. The space between the projection optical system PL and thereference member7 is filled with the liquid1 to form the liquid immersion area. The size of thereference member7 in the XY direction is sufficiently larger than the sizes of thesupply nozzles13,14 and therecovery nozzles31,32. The liquid immersion area AR2 is smoothly formed on thereference member7.
• Subsequently, the control unit CONT detects the reference mark MFM via the mask M, the projection optical system PL, and theliquid1 by using the mask alignment system6 (Step SA5,FIG. 27). Accordingly, the position of the mask M in the XY plane, i.e., the projection position information of the image of the pattern of the mask M is detected by using the reference mark MFM via the projection optical system PL and theliquid1.
• When the detection process is completed as described above, the control unit CONT stops the operation for supplying theliquid1 onto thereference member7 by theliquid supply mechanism10. On the other hand, the control unit CONT continues, for a predetermined period of time, the operation for recovering the liquid1 from the surface of thereference member7 by the liquid recovery mechanism30 (Step SA5.1). After the predetermined period of time has elapsed, the control unit CONT stops the recovery operation having been performed by theliquid recovery mechanism30. Further, in order to remove theliquid1 which is unsuccessfully recovered by theliquid recovery mechanism30 and which remains on thereference member7, the substrate stage PST is moved in a direction directed to ablow unit41 of the first liquid-removingunit40 as described later on.
• FIG. 5 shows such a situation that theliquid1, which remains on thereference member7 provided on the substrate stage PST (Z stage52), is removed by the first liquid-removingunit40 which constitutes a part of the liquid-removing mechanism.FIG. 5A shows a schematic perspective view, andFIG. 5B shows a sectional view. With reference toFIG. 5, the first liquid-removingunit40 includes theblow unit41 which blows the gas against thereference member7, and the liquid-absorbingmember42 which is provided adjacently to thereference member7. Theblow unit41 includes agas supply section41A which is capable of feeding the gas, and anozzle section43 which is connected to thegas supply section41A. Ablow port43A of thenozzle section43 is formed to be slit-shaped so that theblow port43A is parallel to the in-plane direction of the surface of thereference member7, which is arranged closely to thereference member7. The liquid-absorbingmember42 is provided at the position opposed to theblow port43A of thenozzle section43 with thereference member7 intervening therebetween. Thegas supply section41A and thenozzle section43 are supported by an unillustrated support section which is provided independently from the projection optical system PL. The liquid-absorbingmember42 is arranged in agroove44 as a recovery port provided in theZ stage52. The liquid-absorbingmember42 is formed of, for example, a porous material such as a porous ceramics and a sponge, in the same manner as the liquid-absorbingmember21 of the secondliquid recovery unit20, which is capable of retaining a predetermined amount of theliquid1. The gas is fed from thegas supply section41A, and thus the high speed gas is allowed to blow against thereference member7 obliquely from an upper position via the slit-shapedblow port43A of thenozzle section43. The control unit CONT allows the gas to blow against thereference member7 from thenozzle section43 of the first liquid-removingunit40. Accordingly, theliquid1 remaining on thereference member7 is blown off and removed (Step SA5.2). In this procedure, the control unit CONT allows the gas to blow against thereference member7 from thenozzle section43 while moving the substrate stage PST (i.e., the reference member7) with respect to thenozzle section43 of the first liquid-removingunit40. Accordingly, the gas is blown uniformly against the entire surface of thereference member7. The blown offliquid1 is retained (recovered) by the liquid-absorbingmember42 which is arranged at the position opposed to theblow port43A of thenozzle section43.
• As shown inFIG. 5B, aflow passage45, which is continued to thegroove44, is formed in theZ stage52. The bottom of the liquid-absorbingmember42 arranged in thegroove44 is connected to theflow passage45. Theflow passage45, which is connected to thegroove44 arranged with the liquid-absorbingmember42, is connected to one end of atube passage46 which is provided outside theZ stage52. On the other hand, the other end of thetube passage46 is connected to apump49 as a sucking unit via avalve48 and atank47 provided outside theZ stage52. The first liquid-removingunit40 drives thegas supply section41A and drives thepump49 so that the liquid1 recovered by the liquid-absorbingmember42 is sucked to collect the liquid1 in thetank47. Thetank47 is provided with adischarge flow passage47A. When a predetermined amount of theliquid1 is pooled in thetank47, theliquid1 contained in thetank47 is discharged to the outside via thedischarge flow passage47A.
• Subsequently, the control unit CONT moves theXY stage53 so that the substrate P is arranged under the projection optical system PL in order to expose the respective shot areas S1 to S11 on the substrate P (Step SA6,FIG. 27). The control unit CONT drives theliquid supply mechanism10 to start the operation for supplying the liquid onto the substrate P in the state in which the substrate P is arranged under the projection optical system PL. Theliquid1, which is fed from the first and secondliquid supply sections11,12 of theliquid supply mechanism10 respectively in order to form the liquid immersion area AR2, flows through thesupply tubes11A,12A, and then theliquid1 is supplied onto the substrate P via the first andsecond supply nozzles13,14 to form the liquid immersion area AR2 between the projection optical system PL and the substrate P. In this situation, the supply ports of the first andsecond supply nozzles13,14 are arranged on the both sides in the X axis direction (scanning direction) of the projection area AR1. The control unit CONT simultaneously supplies theliquid1 onto the substrate P on the both sides of the projection area AR1 from the supply ports of theliquid supply mechanism10. Accordingly, theliquid1, which is supplied onto the substrate P, forms, on the substrate P, the liquid immersion area AR2 in a range wider than at least the projection area AR1. Further, the control unit CONT controls the first and secondliquid recovery sections33,34 of theliquid recovery mechanism30 to perform the operation for recovering the liquid from the surface of the substrate P concurrently with the operation for supplying theliquid1 performed by theliquid supply mechanism10. In other words, the control unit CONT simultaneously performs the liquid supply by theliquid supply mechanism10 and the liquid recovery by the liquid recovery mechanism (first liquid recovery mechanism)30 in order to form the liquid immersion area AR2 during the exposure for the substrate P (Step SA7,FIG. 27). Accordingly, theliquid1 on the substrate P, which flows to the outside of the projection area AR1 from the supply ports of the first andsecond supply nozzles13,14, is recovered by the recovery ports of the first andsecond recovery nozzles31,32. As described above, theliquid recovery mechanism30 recovers the liquid1 from the surface of the substrate P through the recovery ports provided to surround the projection area AR1.
• The respective shot areas S1 to S11 on the substrate P are subjected to the scanning exposure by using the respective pieces of information determined during the detection process as described above (Step SA8,FIG. 27). That is, the respective shot areas S1 to S11 on the substrate P and the mask M are subjected to the positional adjustment during the scanning exposure for the respective shot areas respectively on the basis of the information about the positional relationships between the reference mark PFM and the respective shot areas S1 to S11 determined before the supply of theliquid1, and the information about the projection position of the image of the pattern of the mask M determined by using the reference mark MFM after the supply of theliquid1.
• The positional relationship is adjusted between the surface of the substrate P and the image plane formed via theliquid1 during the scanning exposure for the respective shot areas S1 to S11 on the basis of the surface information of the substrate P determined before the supply of theliquid1 and the surface information of the surface of the substrate P detected by using the focus-detectingsystem4 during the scanning exposure.
• In this embodiment, when theliquid1 is supplied to the substrate P from the both sides of the projection area AR1 in the scanning direction, the control unit CONT controls the liquid supply operation of the first and secondliquid supply sections11,12 of theliquid supply mechanism10 so that the liquid supply amount per unit time, which is to be supplied in front of the projection area AR1 in relation to the scanning direction, is set to be larger than the liquid supply amount to be supplied on the side opposite thereto. For example, when the exposure process is performed while moving the substrate P in the +X direction, the control unit CONT is operated so that the liquid amount from the −X side with respect to the projection area AR1 (i.e., from the first supply nozzle13) is made larger than the liquid amount from the +X side (i.e., from the second supply nozzle14). On the other hand, when the exposure process is performed while moving the substrate P in the −X direction, the liquid amount from the +X side with respect to the projection area AR1 is made larger than the liquid amount from the −X side.
• When the scanning exposure is completed for the respective shot areas S1 to S11 on the substrate P, then the control unit CONT stops the supply of the liquid by theliquid supply mechanism10, and the substrate stage PST is moved so that therecovery port23 of the secondliquid recovery unit20 provided for the substrate stage PST is opposed to the projection optical system PL. The control unit CONT uses, in combination, the liquid recovery mechanism (first liquid recovery mechanism)30 and the secondliquid recovery unit20 to recover theliquid1 existing under the projection optical system PL (Step SA9). In this manner, theliquid1 of the liquid immersion area AR2 is recovered simultaneously by using the liquid recovery mechanism (first liquid recovery unit)30 having the recovery port arranged over the substrate stage PST and the secondliquid recovery unit20 having the recovery port arranged on the substrate stage PST. Therefore, it is possible to suppress the liquid1 from remaining on the substrate P and the end portion of the projection optical system PL.
• The secondliquid recovery unit20 recovers theliquid1 of the liquid immersion area AR2 after the completion of the exposure for the substrate P. However, theliquid1, which outflows to the outside of the substrate P (auxiliary plate57), may be recovered during the liquid immersion exposure. Therecovery port23 of the secondliquid recovery unit20 is provided in the zonal (annular) form around the substrate P. However, therecovery port23 may be provided partially at a predetermined position in the vicinity of the substrate P (auxiliary plate57) considering the movement direction of the substrate stage PST after the completion of the exposure for the substrate P. The liquid immersion exposure itself is not affected even when the vibration, which is accompanied by the recovery operation, is increased before and after the liquid immersion exposure. Therefore, in this period, the recovery power of theliquid recovery mechanism30 may be increased as compared with the power brought about during the liquid immersion exposure.
• When theliquid1 on the substrate P is unsuccessfully recovered after the completion of the liquid immersion exposure, the substrate P may be dealt with as follows, although the substrate P is not a part. That is, for example, the substrate stage PST, which supports the substrate P, is moved to arrange the substrate P at a position separated from the projection optical system PL, specifically at a position under theblow unit41 of the first liquid-removingunit40. The gas is blown against the substrate P to remove the liquid. The blown offliquid1 can be collected in thetank47 by effecting the suction with thepump42 by the aid of the liquid-absorbing member. Alternatively, the blown off liquid1 may be recovered by the secondliquid recovery unit20 of course, the gas blow operation can be performed not only for the substrate P but also for the surfaces of theauxiliary plate57 and theZ stage52 disposed outside theauxiliary plate57.
• As described above, the firstliquid recovery unit40 removes theliquid1 remaining on thereference member7. However, it is also possible to remove theliquid1 remaining on any part (area) other than thereference member7 on the substrate stage PST. For example, when theliquid1 is subjected to the outflow and/or the scattering to the outside of the substrate P during the liquid immersion exposure, and theliquid1 is adhered onto the substrate stage PST (Z stage52), then theliquid1 on the substrate stage PST can be recovered by the first liquid-removingunit40 after the completion of the exposure for the substrate P. In this case, theliquid1, which has been blown off by theblow unit41 of the first liquid-removingunit40, may be recovered by the liquid-absorbingmember21 arranged in the groove (recovery port)23 of the secondliquid recovery unit20.
• Thenozzle section43 of theblow unit41 may be previously provided movably with respect to the substrate stage PST. Theliquid1, which has flown out to the outside of the substrate P, may be recovered during the exposure and/or after the completion of the exposure for the substrate P.
• As explained above, the first liquid-removingunit40 is provided, which removes theliquid1 remaining on thereference member7 provided on the substrate stage PST (Z stage52). Therefore, it is possible to prevent the liquid1 from remaining on thereference member7. Further, theliquid1 is recovered by using the recovery port on the substrate stage PST as well after the completion of the exposure for the substrate P. Therefore, it is possible to prevent the liquid1 from remaining on the substrate P and/or at the end portions of the nozzle and the projection optical system PL, and it is possible to prevent the liquid1 from falling and scattering to the substrate or the like. In the embodiment described above, the first liquid-removingunit40 has the liquid-absorbingmember42 arranged in the vicinity of thereference member7. However, the liquid-absorbingmember42 may be omitted. In this case, theliquid1, which has been removed from the surface of thereference member7, may be allowed to remain in a predetermined area on the substrate stage PST at which the exposure operation and the measuring operation are not affected thereby as well.
• FIG. 6 shows another embodiment of the first liquid-removingunit40. In the following description, the same or equivalent constitutive portions as those of the embodiment described above will be designated by the same reference numerals, any explanation of which will be simplified or omitted. With reference toFIG. 6, the first liquid-removingunit40 is provided with a suckingunit81 which sucks the liquid1 adhered onto thereference member7. The suckingunit81 is arranged at a position opposed to theblow unit41 to interpose thereference member7 therebetween. The suckingunit81 includes a suckingsection81A which includes a tank and a pump, and a suckingnozzle82 which is connected to the suckingsection81A. A suckingport82A of the suckingnozzle82 is arranged closely to thereference member7. When theliquid1 remaining on thereference member7 is removed, then theblow unit41 blows the gas against thereference member7, and the suckingunit81 sucks the liquid1 from the surface of thereference member7.
• In the illustrative embodiment explained with reference toFIG. 6, the first liquid-removingunit40 is provided with both of theblow unit41 and the suckingunit81. However, it is also allowable to adopt an arrangement in which only the suckingunit81 is provided. The suckingunit81 sucks theliquid1 remaining on thereference member7 from the suckingport82A, and thus theliquid1 can be removed (recovered). Thenozzle section82 of the suckingunit81 may be provided movably with respect to the substrate stage PST to recover theliquid1 flown out to the outside of the substrate P during the exposure and/or after the completion of the exposure for the substrate P. In the embodiment shown inFIG. 6, the first liquid-removingunit40 has the liquid-absorbingmember42 arranged in the vicinity of thereference member7. However, the liquid-absorbingmember42 may be omitted.
• FIG. 7 shows a sectional view illustrating still another embodiment of the first liquid-removingunit40. As shown inFIG. 7, the first liquid-removingunit40 includes acover member84 which covers thereference member7, and a drygas supply section85 which supplies the dry gas to the internal space of thecover member84. The drygas supply section85 supplies the dry gas to the internal space of thecover member84 arranged over thereference member7 via atube passage86. Accordingly, the vaporization of theliquid1 remaining on thereference member7 is facilitated, and thus theliquid1 is removed. The first liquid-removingunit40 removes the liquid on the part such as thereference member7 carried on the substrate stage PST. However, when the exposure apparatus EX carries a stage provided with a reference section and/or a measuring member separately from the substrate stage PST as disclosed in Japanese Patent Application Laid-open No. 11-135400, the liquid on the part on the stage can be also removed.
• Next, an explanation will be made with reference toFIG. 8 about the second liquid-removingunit60 for removing theliquid1 or the like remaining on the barrel PK disposed in the vicinity of the end portion and/or theoptical element2 disposed at the end portion of the projection optical system PL. With reference toFIG. 8, the second liquid-removingunit60 includes ablow unit61 which blows the gas against theoptical element2 for constructing the part disposed at the end portion of the projection optical system PL and the barrel PK disposed in the vicinity thereof, and a recovery unit (sucking unit)62 which recovers the fallen liquid blown off by the gas blow effected by theblow unit61. Theblow unit61 includes agas supply section63, and anozzle section64 which is connected to thegas supply section63 and which is provided in arecess64B of theZ stage52. Thenozzle section64 has ablow port64A which is directed upwardly and which is capable of being arranged in the vicinity of the end portion of the projection optical system PL. On the other hand, therecovery unit62 includes a recovery port (groove)65 which is provided in theZ stage52, a liquid-absorbingmember66 which is formed of a porous material arranged in therecovery port65, aflow passage67 which is arranged in theZ stage52 and which is communicated with thegroove66, atube passage68 which is provided outside theZ stage52 and which has one end connected to theflow passage67, atank69 which is connected to the other end of thetube passage68 and which is provided outside theZ stage52, and apump71 as a sucking unit which is connected to thetank69 via avalve70. Therecovery unit62 drives thepump71 to suck theliquid1 recovered by the liquid-absorbingmember66 so that theliquid1 is collected in thetank69. Thetank69 is provided with adischarge flow passage69A. When a predetermined amount of theliquid1 is pooled in thetank69, theliquid1 contained in thetank69 is discharged to the outside via thedischarge flow passage69A.
• In this embodiment, theblow port64A of thenozzle section64 of theblow unit61 is slit-shaped, in which the Y axis direction is the longitudinal direction (seeFIG. 3). Therecovery port65 of therecovery unit62 is formed to have a rectangular shape in which the Y axis direction is the longitudinal direction at the position adjoining on the +X side of theblow port64A. The second liquid-removingunit60 removes theliquid1 remaining on the end portion of the projection optical system PL allowed to make contact with the liquid1 in the liquid immersion area AR2 during the exposure for the substrate P as well as on the supply nozzles (parts)13,14 of theliquid supply mechanism10 and the recovery nozzles (parts)31,32 of theliquid recovery mechanism30 after the completion of the exposure for the substrate P. Of course, it is also possible to remove the liquid from only the end portion of the projection optical system PL or from only the nozzles.
• As described above, the control unit CONT recovers the liquid1 from the surface of the substrate P (Step SA9,FIG. 27) by using the liquid recovery mechanism (first liquid recovery unit)30 after the completion of the liquid immersion exposure for the substrate P (after the completion of Step SA8). After the completion of the recovery of the liquid1 from the surface of the substrate P by theliquid recovery mechanism30, the control unit CONT moves the substrate stage PST so that the second liquid-removingunit60 is arranged under the projection optical system PL. The second liquid-removingunit60 allows the gas to blow from thenozzle section64 of theblow unit61 arranged obliquely downwardly with respect to the end portion of the projection optical system PL. Theliquid1, which remains on the end portion of the projection optical system PL, is blown off and removed (Step SA10,FIG. 27). The blown offliquid1 falls onto the liquid-absorbingmember66 disposed adjacently to thenozzle section64. Theliquid1 is recovered by therecovery port65 arranged with the liquid-absorbingmember66 of therecovery unit62. In this embodiment, the control unit CONT drives the second liquid-removingunit60 while moving the substrate stage PST, for example, in the X axis direction perpendicular to the longitudinal direction (Y axis direction) of therecovery port65 and theblow port64A. Accordingly, the gas is allowed to blow against the end portion of the projection optical system PL as a matter of course, as well as against therecovery nozzles31,32 of theliquid recovery mechanism30 and thesupply nozzles13,14 of theliquid supply mechanism10 disposed therearound. It is possible to remove theliquid1 remaining on thesupply nozzles13,14 and therecovery nozzles31,32 as well.
• As explained above, theliquid1, which remains on the end portion of the projection optical system PL allowed to make contact with the liquid1 in the liquid immersion area AR2 during the exposure as well as on thesupply nozzles13,14 and therecovery nozzles31,32, is removed. Accordingly, as schematically shown inFIG. 9, even when the substrate stage PST is moved from the position under the projection optical system PL (exposure process position A) to the position (load/unload position B) at which the substrate P is loaded and/or unloaded, it is possible to suppress the occurrence of any inconvenience which would be otherwise caused such that theliquid1, which remains, for example, on the end portion of the projection optical system PL, falls to affect the surrounding equipment and brings about the environmental change. In particular, it is possible to suppress the occurrence of the adhesion trace (water mark) by preventing the liquid1 from remaining on theoptical element2 disposed at the end portion of the projection optical system PL.
• Further, the second liquid-removingunit60 is provided for the substrate stage PST. Accordingly, when the second liquid-removingunit60 is driven while moving the substrate stage PST, the gas can be allowed to blow against the projection optical system PL, the supply nozzles, and the recovery nozzles while scanning the second liquid-removingunit60, even when any actuator is not provided. Further, for example, as shown inFIG. 9, the operation for blowing the gas is performed by the second liquid-removingunit60 during the period of the movement from the exposure process position A to the load/unload position B after the completion of the liquid immersion exposure. Accordingly, it is possible to simultaneously perform the liquid-removing operation (gas-blowing operation) and the stage-moving operation. It is possible to improve the time efficiency of the series of the exposure process. Therefore, it is preferable that the second liquid-removingunit60 is previously provided at the position to pass under the projection optical system PL during the movement of the substrate stage PST from the exposure process position A to the load/unload position B.
• FIGS. 10 and 11 show modified embodiments of the second liquid-removingunit60. As shown inFIG. 10, alarge groove72 is formed on theZ stage52 beforehand. Thenozzle section64 of theblow unit61 and the flow passage (recovery port)67 of therecovery unit62 may be arranged in thegroove72. In the illustrative embodiment shown inFIG. 10, the liquid-absorbingmember66 is not provided. As described above, it is also possible to adopt the arrangement in which the liquid-absorbingmember66 is not provided. Alternatively, as shown inFIG. 11, a plurality of nozzle sections64 (twonozzle sections64, in the illustrative embodiment shown inFIG. 11) of theblow unit61 may be provided in the groove. Further, as exemplified in the illustrative embodiments shown inFIGS. 10 and 11, thegroove72, which is larger than the size (width) of the end portion of the projection optical system PL, is provided, and thenozzle section64 and therecovery port67 are arranged in thegroove72. Accordingly, all of theliquid1, which falls as a result of the blow of the gas, can be recovered by thegroove72. Therefore, it is possible to suppress the scattering of the liquid1 to the surroundings.
• Alternatively, as shown inFIG. 12, acover member73, which prevents the liquid1 subjected to the gas blow from being scattered to the surroundings, can be provided around therecovery port65 and theblow port64A of thenozzle section64. Thecover member73 shown inFIG. 12 is formed to be U-shaped as viewed in a plan view so that thecover member73 can be arranged to surround the end portion of the projection optical system PL. Thecover member73 is formed so that theblow port64A of thenozzle section64 is arranged on the side of the opening of the U-shaped form. Further, thecover member73 is formed so that the side of the opening of the U-shaped form of thecover member73 faces the movement direction of the substrate stage PST (X axis direction). The end portion of the projection optical system PL enters and exists the inside of thecover member73 on the side of the opening of the U-shaped form. Theblow port64A and therecovery port65, for each of which the Y axis direction is the longitudinal direction, are provided inside thecover member73. Accordingly, the liquid can be efficiently removed, for example, from the end portion of the projection optical system PL while avoiding the scattering of theliquid1 by one time of the scanning movement of the substrate stage PST.
• Theliquid1, which outflows to the outside of the substrate P, can be also recovered during the exposure for the substrate P by the aid of therecovery port65 of therecovery unit62 of the second liquid-removingunit60. In this arrangement, it is preferable that a plurality ofrecovery ports65 of therecovery unit62 are provided at predetermined intervals around the substrate P.
• In the embodiments shown in FIGS.8 to12, the second liquid-removingunit60 is provided with therecovery unit62 in the vicinity of thenozzle section64. However, therecovery unit62 may be omitted. In this arrangement, theliquid1, which is removed from the end portion of the projection optical system PL, can be also allowed to remain in a predetermined area on the substrate stage PST in which no influence is exerted on the exposure operation and the measuring operation.
• In the embodiments shown in FIGS.8 to12, the second liquid-removingunit60 is arranged on the substrate stage PST. However, the second liquid-removingunit60 may be arranged on a portion or a member different from the substrate stage PST. For example, a stage, which is movable on the side of the image plane of the projection optical system PL, may be further provided independently from the substrate stage PST, and the second liquid-removingunit60 may be arranged on the stage.
• A sucking port may be provided in the vicinity of the projection optical system PL, the supply nozzle, the recovery nozzle, and/or theblow port64A of thenozzle section64 of the second liquid-removingunit60. Alternatively, a sucking port may be provided in place of theblow port64A to recover the liquid adhered to the forward end surface of the projection optical system PL, the supply nozzle, and/or the recovery nozzle.
• Even when theliquid1 is removed from the end portion of the projection optical system PL, then impurities and/or foreign matters, which are contained in theliquid1, may adhere to theoptical element2 disposed at the end portion of the projection optical system PL, and theoptical element2 may be contaminated therewith in some cases. The impurities and/or foreign matters herein include, for example, broken pieces of the photoresist and deposits of the electrolyte contained in the photoresist. Accordingly, it is preferable to wash theoptical element2 before or after removing (blowing off or sucking) theliquid1 remaining on theoptical element2 disposed at the end portion of the projection optical system PL.
• FIG. 13 schematically shows a state in which the end portion of the projection optical system PL is washed. In an embodiment shown inFIG. 13, awashing station90 is provided at a position different from that of the substrate P held by the substrate holder, on the substrate stage PST (Z stage52). Awashing plate91 is provided for thewashing station90. Thewashing plate91 is, for example, a plate member having substantially the same size as that of the substrate P.
• In order to wash theoptical element2 disposed at the end portion of the projection optical system PL after (or before) the completion of the liquid immersion exposure, the control unit CONT moves the substrate stage PST to arrange the washing plate91 (washing station90) under the projection optical system PL. The control unit CONT drives theliquid supply mechanism10 and theliquid recovery mechanism30 to form the liquid immersion area AR2 between the projection optical system PL and thewashing plate91. Theoptical element2, which is disposed at the end portion of the projection optical system PL, is washed with the liquid1 in the liquid immersion area AR2 formed on thewashing plate91. After the washing process comes to an end, the second liquid-removingunit60 is used as described above to remove theliquid1 remaining on theoptical element2 disposed at the end portion of the projection optical system PL.
• In the case of thewashing station90 shown inFIG. 13, theliquid supply mechanism10 and theliquid recovery mechanism30 are used to form the liquid immersion area AR2 on thewashing plate91, and theoptical element2 disposed at the end portion of the projection optical system PL is washed with the liquid1 in the liquid recovery amount AR2. However, as shown inFIG. 14, awashing mechanism95 may be provided for thewashing station90, and thewashing mechanism95 can be used to wash theoptical element2 disposed at the end portion of the projection optical system PL. Thewashing mechanism95 of thewashing station90 shown inFIG. 14 includes a washingliquid supply section96, a jettingsection97 which is connected to the washingliquid supply section96 and which has a jettingport97A for jetting or spouting the washing liquid fed from the washingliquid supply section96 to theoptical element2 disposed at the end portion of the projection optical system PL, arecovery tube98 which has arecovery port98A for recovering the waste liquid after washing theoptical element2, and arecovery section99 which is connected to therecovery tube98 and which includes, for example, a pump and a tank. The jettingport97A and therecovery port98A are arranged in agroove94 formed on the substrate stage PST (Z stage52). After the completion of the liquid immersion exposure, thewashing station90 is arranged under the projection optical system PL, and the washing liquid is jetted or spouted toward theoptical element2 disposed at the end portion of the projection optical system PL by using thejetting section97 of thewashing mechanism95. Accordingly, theoptical element2 is washed. In this arrangement, the washing liquid is prevented from the scattering to the surroundings by arranging the jettingport97A and therecovery port98A in thegroove94.
• The washing station90 (washing plate91) is arranged on the substrate stage PST. However, the washing station90 (washing plate91) may be arranged on a member different from the substrate stage PST. For example, a stage, which is movable on the side of the image plane of the projection optical system PL, may be further provided independently from the substrate stage PST, and the washing station may be arranged on the stage.
• It is preferable to confirm whether or not any foreign matter is adhered to theoptical element2 disposed at the end portion of the projection optical system PL by using a foreign matter-detecting system after the washing operation and the liquid removal operation.FIG. 15 schematically shows an example of the foreign matter-detectingsystem100. The foreign matter referred to herein includes the remaining liquid (liquid droplet)1, for example, as well as the broken pieces of the photoresist and the deposits of the electrolyte contained in the photoresist as described above.
• With reference toFIG. 15, the foreign matter-detectingsystem100 includes a light-emittingsection118 which is provided on the substrate stage PST (Z stage52) and which radiates a predetermined radiation light beam from an obliquely downward position onto the surface of theoptical element2 disposed at the end portion of the projection optical system PL, a branchingmirror119 which is arranged on the optical path for connecting the surface of theoptical element2 and the light-emittingsection118, a first light-receivingsection120 which is provided on the substrate stage PST and which receives the reflected light beam from the surface of theoptical element2 on the basis of the radiation from the light-emittingsection118, and a second light-receivingsection121 which is arranged at a position over the substrate stage PST and which receives the branched light beam from the branchingmirror119 on the basis of the radiation from the light-emittingsection118. In this embodiment, for example, the light-emittingsection118 and the first light-receivingsection120, which constitute the foreign matter-detectingsystem100, are provided at the positions other than those of the substrate holder and the washing station on the substrate stage PST. The light-receiving results obtained by the first and second light-receivingsections120,121 are outputted as photoelectric signals to the control unit CONT which constitutes a part of the foreign matter-detectingsystem100. The control unit CONT is constructed to calculate, as the real reflectance, the light reflectance of the surface of theoptical element2 on the basis of the photoelectric signals outputted from the first and second light-receivingsections120,121 so that the degree of contamination of the surface of theoptical element2 is measured on the basis of the result of comparison between the calculated real reflectance and the previously stored predetermined reflectance. In other words, if any foreign matter adheres to theoptical element2, then any scattered light is generated due to the foreign matter to change the reflectance, and the receiving amount of light received by the first light-receivingsection120 is changed. The control unit CONT previously stores, as the predetermined reflectance, the light reflectance of the surface of theoptical element2 measured upon the completion of the production of this apparatus in which it is assumed that the surface of theoptical element2 is not contaminated to such an extent that the optical characteristics are affected.
• As explained with reference toFIGS. 13 and 14, the control unit CONT moves the substrate stage PST to arrange the foreign matter-detectingsystem100 under the projection optical system PL after completing the washing process for theoptical element2 disposed at the end portion of the projection optical system PL. When the predetermined radiation light beam is radiated from the light-emittingsection118, then the radiation light beam, which is transmitted through the branchingmirror119, is radiated onto the surface of theoptical element2, and the radiation light beam is reflected by the surface. The reflected light beam is received by the first light-receivingsection120. On the other hand, the radiation light beam (branched light beam), which is branched by the branchingmirror119, does not arrive at the surface of theoptical element2, and the radiation light beam is received by the second light-receivingsection121. The photoelectric signals, each of which is subjected to the photoelectric conversion by one of the light-receivingsections120,121, are outputted to the control unit CONT respectively. The control unit CONT calculates the reflectance of the surface of theoptical element2 on the basis of the photoelectric signal supplied from the first light-receivingsection120 and the photoelectric signal supplied from the second light-receivingsection121. That is, in general, when the light beam comes, at a certain angle of incidence, into the boundary surface between two media, the reflectance R is represented by R=Ir/I₀provided that I₀represents the intensity of the energy of the incoming light flux, and Ir represents the intensity of the energy of the reflecting light flux. Therefore, the control unit CONT determines the real reflectance Rr assuming that the intensity of the energy based on the photoelectric signal from the first light-receivingsection120 is Ir, and the intensity of the energy based on the photoelectric signal from the second light-receivingsection121 is I₀. Subsequently, the control unit CONT reads the predetermined reflectance R₀which is previously stored in order to calculate the difference ΔR (=R₀−Rr) between the predetermined reflectance R₀and the real reflectance Rr. The display signal, which is based on the determined difference ΔR between the both reflectances R₀and Rr, is outputted to thedisplay unit126. Thedisplay unit126 numerically displays the degree of contamination of the surface of theoptical element2 on the basis of the display signal. If the degree of contamination exceeds a predetermined allowable value, then the control unit CONT judges that the foreign matter is present in an amount of not less than an allowable amount on the surface of theoptical element2, and the control unit CONT controls the washing unit so that the washing process is performed again.
• This embodiment is constructed such that the radiation light beam is radiated onto theoptical element2, and the scattered light on the surface of theoptical element2 is detected. However, when any foreign matter adheres to theoptical element2, the uneven illuminance or the telecentric deviation is observed on the side of the image plane of the projection optical system PL. Therefore, it is possible to detect whether or not any foreign matter adheres by measuring the illuminance at the focus plane and the defocus plane respectively by using an illuminance sensor provided on the substrate stage PST.
• In the embodiment shown inFIG. 15, the liquid and the foreign matter (impurity) adhered to the surface of theoptical element2 are detected by radiating the light beam onto theoptical element2 and receiving the scattered light therefrom. However, the detecting method is not limited thereto. For example, the detection may be performed by using themask alignment system6 described above. Further, the foreign matter-detecting system may be used to confirm whether or not any foreign matter adheres to theoptical element2 disposed at the end portion of the projection optical system PL not only after the washing of the surface of theoptical element2 but also at a predetermined timing during the exchange of the substrate P or the like. When any foreign matter is detected, the washing operation may be performed. The foreign matter-detectingsystem100 detects the foreign matter on theoptical element2 disposed at the end portion of the projection optical system PL. However, it is also allowable to detect the foreign matter on the surface of any other part to make contact with the liquid on the side of the image plane of the projection optical system PL.
Another Embodiment of Exposure Apparatus Based on Use of First Liquid-Removing Unit
• FIG. 16 shows another embodiment of the exposure apparatus provided with the first liquid-removing unit. In this embodiment, theZ stage52 is provided with a plate member (upper plate)138A which constitutes a part of an uneven illuminance sensor (measuring system)138 for receiving the light beam radiated onto the side of the image plane (side of the substrate P) via the projection optical system PL, and a liquid-absorbingmember142, which recovers the liquid removed from theplate member138A, is further provided in the vicinity thereof. The liquid-absorbingmember142 is arranged in agroove144 formed in theZ stage52. Theplate member138A is formed such that the surface of the glass plate is subjected to the patterning with a thin film including a light-shielding material such as chromium, and apinhole138P is provided at a central portion thereof. The upper surface of theplate member138A has the liquid repellence. In this embodiment, the surface of theplate member138A is coated with a material having the liquid repellence such as a fluorine-based compound.
• FIG. 17 shows a situation in which the adhered liquid is removed from theplate member138A which is provided on the substrate stage PST and which constitutes a part of theuneven illuminance sensor138. In this embodiment, theuneven illuminance sensor138 measures, at a plurality of positions, the illuminance (intensity) of the exposure light beam radiated onto the side of the image plane by the aid of the projection optical system PL to measure the uneven illuminance (illuminance distribution) of the exposure light beam radiated onto the side of the image plane of the projection optical system PL, as disclosed in Japanese Patent Application Laid-open No. 57-117238 (corresponding to U.S. Pat. No. 4,465,368). Theuneven illuminance sensor138 includes theplate member138A which is provided on the substrate stage PST (Z stage52), which has the light-shielding film subjected to the patterning on the surface of the glass plate, and which has thepinhole138P formed at the central portion thereof, anoptical system138C which is embedded in theZ stage52 and which is illuminated with the light beam passed through thepinhole138P, and a light-receiving element (light-receiving system)138B which receives the light beam passed through theoptical system138C. For example, a relay optical system may be provided between theoptical system138C and the light-receivingelement138B, and the light-receivingelement138B may be arranged outside theZ stage52 as well. The disclosure of U.S. Pat. No. 4,465,368 is incorporated herein by reference within a range of permission of the domestic laws and ordinances of the designated state or the selected state designated or selected in this international application.
• When the illuminance distribution is measured by using theuneven illuminance sensor138, the space between the projection optical system PL and theplate member138A is filled with the liquid in a state in which the projection optical system PL is opposed to theplate member138A of theuneven illuminance sensor138. Subsequently, thepinhole138P is successively moved to a plurality of positions in the radiation area onto which the exposure light beam is radiated to determine (measure) the illuminance distribution (uneven illuminance) by measuring the illuminance of the exposure light beam at the respective positions as described above. After the illuminance distribution is determined, the control unit CONT moves the substrate stage PST to arrange theplate member138A of theuneven illuminance sensor138 under thenozzle section43 of the first liquid-removingunit40.
• As described above, the liquid-absorbingmember142, which recovers the liquid removed from theplate member138A by the first liquid-removingunit40, is provided at the position adjacent to theplate member138A on theZ stage52. The liquid-absorbingmember142 is formed of, for example, a porous material such as a porous ceramics and a sponge in the same manner as the liquid-absorbingmember42 described above, which is capable of retaining a predetermined amount of the liquid.
• The control unit CONT blows the gas against theplate member138A from thenozzle section43 of the first liquid-removingunit40, and thus the liquid adhered to theplate member138A is blown off and removed. The blown off liquid is retained (recovered) by the liquid-absorbingmember142 arranged at the position opposed to theblow port43A of thenozzle section43 of the first liquid-removingunit40. The liquid-repelling treatment is applied to the surface of theplate member138A. Therefore, it is possible to avoid any invasion of the liquid into thepinhole138P. Additionally, it is possible to satisfactorily remove the liquid from theplate member138A by allowing the gas to blow thereagainst.
• Aflow passage145, which is communicated with thegroove144, is formed in theZ stage52. The liquid-absorbingmember142 is arranged in thegroove144 so that the bottom thereof makes contact with theflow passage145. Theflow passage145 is connected to one end of atube passage146 which is provided outside theZ stage52. On the other hand, the other end of thetube passage146 is connected to apump149 via atube passage148 having avalve148A and atank147 provided outside theZ stage52. The control unit CONT drives thegas supply section41A of the first liquid-removingunit40, and the control unit CONT drives thepump149. Accordingly, the liquid, which is recovered by the liquid-absorbingmember142, is sucked and collected in thetank147. Thetank147 is provided with adischarge flow passage147A. When a predetermined amount of theliquid1 is pooled in thetank147, theliquid1 is discharged to the outside from thetank147 via thedischarge flow passage147A.
• For example, the suction of the liquid and the blowing of the dry air may be used, or they may be appropriately combined and used, as explained in the foregoing embodiment in relation to the method for removing the liquid from theplate member138A by the first liquid-removingunit40. It is unnecessary that the entire surface of theplate member138A is liquid-repellent. It is also allowable that only a part of theplate member138A, for example, only the surrounding of thepinhole138P may be liquid-repellent. Not only the upper surface of theplate member138A of theuneven illuminance sensor138 but also the surface of another part on the substrate stage PST may be liquid-repellent. It is also allowable that the coating of the liquid-repelling material may be omitted when the ability of the first liquid-removingunit40 to remove the liquid is sufficiently high.
• Other sensors, which are not limited to the uneven illuminance sensor and which receive the exposure light beam passed via the projection optical system PL and the liquid through the light-transmitting portion, are also arranged on the substrate stage PST, including, for example, a radiation amount monitor as disclosed in Japanese Patent Application Laid-open No. 11-16816 (corresponding to United States Patent Application Publication No. 2002/0061469) and a spatial image-measuring sensor for measuring, for example, the image characteristics as disclosed in Japanese Patent Application Laid-open No. 2002-14005 (corresponding to United States Patent Application Publication No. 2002/0041377). The sensors as described above also have such a possibility that the liquid may remain on and adhere to the surface of the flat portion formed with the light-transmitting portion. Therefore, it is also allowable to apply, to the sensors, the method for removing the liquid based on the use of the first liquid-removingunit40 as described above. When a reflecting member is arranged on the substrate stage PST as disclosed in Japanese Patent Application Laid-open No. 62-183522 (corresponding to U.S. Pat. No. 4,780,747), it is also allowable to remove the liquid remaining on and adhered to the surface thereof by using the first liquid-removingmechanism40. The contents of United States Patent Application Publication No. 2002/0061469, United States Patent Application Publication No. 2002/0041377, and U.S. Pat. No. 4,780,747 are incorporated herein by reference within a range of permission of the domestic laws and ordinances of the designated state or the selected state designated or selected in this international application.
• When a sensor, which is detachable with respect to the substrate stage PST, is used as disclosed in Japanese Patent Application Laid-open Nos. 11-238680 and 2000-97616 and International Publication WO 02/063664 (corresponding to United States Patent Application Publication No. 2004/0041377), the sensor may be detached from the substrate stage PST after removing the liquid remaining on and adhered to the surface of the sensor by using the first liquid-removingunit40. The disclosure of United States Patent Publication No. 2004/0041377 is incorporated herein by reference within a range of permission of the domestic laws and ordinances of the designated state or the selected state designated or selected in this application.
Embodiment of Exposure Apparatus Based on Use of Third Liquid-Removing Unit
• FIG. 18 schematically shows an exposure apparatus based on the use of a third liquid-removing unit. With reference toFIG. 18, a focus-detectingsystem4 includes a light-emittingsection4aand a light-receivingsection4b. In this embodiment, those provided in the vicinity of the end portion of the projection optical system PL are a firstoptical member151 through which a detecting light beam is transmissive, the detecting light beam being radiated from the light-emittingsection4aof the focus-detectingsystem4, and a secondoptical member152 through which the detecting light beam reflected on the substrate P is transmissive. The firstoptical member151 and the secondoptical member152 are supported in a state of being separated from theoptical element2 disposed at the end portion of the projection optical system PL. The firstoptical member151 is arranged on the −X side of theoptical element2, and the secondoptical member152 is arranged on the +X side of theoptical element2. The first and secondoptical members151,152 are provided at the positions at which they are capable of making contact with the liquid1 in the liquid immersion area AR2 and at which the optical path for the exposure light beam EL and the movement of the substrate P are not inhibited.
• As shown inFIG. 18, for example, during the exposure process for the substrate P, theliquid1 is supplied and recovered by theliquid supply mechanism10 and theliquid recovery mechanism30 so that all of the optical path of the exposure light beam EL passed through the projection optical system PL, i.e., all of the optical path of the exposure light beam EL between theoptical element2 and the substrate P (projection area AR1 on the substrate P) is filled with theliquid1. Further, when all of the optical path of the exposure light beam EL between theoptical element2 and the substrate P is filled with theliquid1, and the liquid immersion area AR2 is formed in a desired state on the substrate P to cover all of the projection area AR1, then theliquid1, which forms the liquid immersion area AR2, makes tight contact (contact) with the end surfaces of the firstoptical member151 and the secondoptical member152 respectively. In the state in which the liquid immersion area AR2 is formed on the substrate P and theliquid1 makes tight contact with the end surfaces of the firstoptical member151 and the secondoptical member152 respectively, all of the optical path between the firstoptical member151 and the secondoptical member152, which is included in the optical path for the detecting light beam radiated from the light-emittingsection4aof the focus-detectingsystem4 and the reflected light beam thereof from the surface of the substrate P, is filled with theliquid1. The setting is made such that the detecting light beam, which is radiated from the light-emittingsection4aof the focus-detectingsystem4, is radiated onto the projection area AR1 of the projection optical system PL on the substrate P in the state in which all of the optical path for the detecting light beam is filled with theliquid1.
• The liquid contact surfaces, which are the end surfaces of the first and secondoptical members151,152, are subjected to, for example, the liquid-attracting treatment to have the lyophilicity or liquid-attracting property. Accordingly, theliquid1 in the liquid immersion area AR2 tends to easily make tight contact with the liquid contact surfaces of the first and secondoptical members151,152. Therefore, it is easy to maintain the shape of the liquid immersion area AR2.
• InFIG. 18, theliquid supply mechanism10 and theliquid recovery mechanism30 are simplified and illustrated in the drawing. Theliquid supply mechanism10 shown inFIG. 18 includes aliquid supply section171 which is capable of feeding theliquid1, and asupply tube172 which connects asupply nozzle173 and theliquid supply section171. Theliquid1, which is fed from theliquid supply section171, passes through thesupply tube172, and then theliquid1 is supplied onto the substrate P from aliquid supply port174 of thesupply nozzle173. Theliquid recovery mechanism30 shown inFIG. 18 includes aliquid recovery section175 which is capable of recovering theliquid1, and arecovery tube176 which connects arecovery nozzle177 and theliquid recovery section175. Theliquid1 on the substrate P is recovered from arecovery port178 of therecovery nozzle177, and then theliquid1 is recovered to theliquid recovery section175 through therecovery tube176.
• This embodiment has been explained assuming that the firstoptical member151 and the secondoptical member152 are mutually independent members. However, for example, an annular optical member may be arranged to surround theoptical element2 disposed at the end portion of the projection optical system PL. The detecting light beam may be radiated onto a part of the annular optical member. The detecting light beam, which has passed through the liquid immersion area AR2 and along the surface of the substrate P, may be received via a part of the annular optical member. When the optical member is provided in the annular form, and the liquid1 in the liquid immersion area AR2 is allowed to make tight contact with the inner side surface of the annular optical member, then it is possible to satisfactorily maintain the shape of the liquid immersion area AR2. In this embodiment, the firstoptical member151 and the secondoptical member152 are separated from each other with respect to the projection optical system PL. However, it is also allowable to integrally provide the firstoptical member151, the secondoptical member152, and theoptical element2 of the projection optical system PL.
• After performing the liquid immersion exposure process in the state shown inFIG. 18, the control unit CONT arranges the washing plate (or a dummy substrate) under the projection optical system PL, for example, as explained with reference toFIG. 13. Theliquid supply mechanism10 and theliquid recovery mechanism30 are used to form the liquid immersion area AR2 on the washing plate. The liquid1 in the liquid immersion area AR2 is used to wash theoptical element2 disposed at the end portion of the projection optical system PL, the first and secondoptical members151,152, those disposed in the vicinity of thesupply port174 of thesupply nozzle173, and those disposed in the vicinity of therecovery port178 of therecovery nozzle177. After completing the washing, the control unit CONT uses, for example, theliquid recovery mechanism30 to recover theliquid1 of the liquid immersion area AR2.
• After recovering theliquid1 of the liquid immersion area AR2, the control unit CONT arranges a gas nozzle160 (third liquid-removing unit) for blowing the gas, under the projection optical system PL as shown inFIG. 19 by the aid of an unillustrated driving unit. In this situation, the substrate stage PST is moved to the load/unload position (seeFIG. 9) in order to unload the substrate P. A liquid-receivingmember280, which receives theliquid1 fallen, for example, from theoptical element2, is arranged under the projection optical system PL. In a situation in which thegas nozzle160 is not used, thegas nozzle160 is arranged at a predetermined position in the exposure apparatus (EX) to make no interference with the substrate stage PST. Thegas nozzle160 may be provided at a position other than the position of the substrate holder on the substrate stage PST.
• The control unit CONT blows the gas from ablow port161 of thegas nozzle160, and the blown liquid is used to move the position of the liquid1 adhered to theoptical element2, the first and secondoptical members151,152, thesupply nozzle173, and/or therecovery nozzle177. For example, as shown inFIG. 19, the control unit CONT firstly moves theblow port161 of thegas nozzle160 in parallel to the substrate surface (in the X direction) to arrive at the position opposed to the area of thelower surface2aof theoptical element2 through which the exposure light beam EL passes. After that, the gas is blown from theblow port161. Thegas nozzle160 is moved toward the outside of the area through which the exposure light beam EL passes, in a state in which the gas is being blown. Accordingly, it is possible to move, to the outside of the area, the liquid (liquid droplet)1 adhered to the area of thelower surface2aof theoptical element2 through which the exposure light beam EL passes, i.e., the area of thelower surface2aof theoptical element2 corresponding to the projection area AR1. In this embodiment, the area, through which the exposure light beam EL passes, is a substantially central portion of thelower surface2aof theoptical element2. Therefore, the method as described above can be used to move, toward the end of thelower surface2a, theliquid1 adhered to (remaining on) the central portion of thelower surface2a(seereference numeral1′ shown inFIG. 19). In other words, the control unit CONT removes the liquid adhered to the area through which the exposure light beam EL passes, by moving the liquid to the outside of the area by using the blowing gas without drying theliquid1 adhered to the area through which the exposure light beam EL passes. Accordingly, it is possible to avoid the inconvenience which would be otherwise caused such that the water mark is formed in at least the area of thelower surface2aof theoptical element2 through which the exposure light beam EL passes. In this embodiment, thegas nozzle160 and the unit equipped therewith function as the third liquid-removing unit.
• In this embodiment, the liquid is moved aside (removed) from the area through which the exposure light beam EL passes. However, there is no limitation thereto. It is appropriate to move aside the liquid from a desired area, if necessary.
• FIG. 20A shows an example of theblow port161. As shown inFIG. 20A, theblow port161 is formed to be slit-shaped in which the Y axis direction is the longitudinal direction in this embodiment.FIG. 20B shows thelower surface2aof theoptical element2. The projection area AR1 is slit-shaped (rectangular) in which the Y axis direction is the longitudinal direction. Theblow port161 is formed to have a size smaller than thelower surface2aof theoptical element2. When theliquid1, which is adhered to the central portion of thelower surface2aof theoptical element2, is moved aside as described above, the control unit CONT firstly allows the gas to blow from theblow port161 in a state in which theblow port161 of thegas nozzle160 is opposed to the substantially central portion of thelower surface2aof theoptical element2. Thegas nozzle160 is moved toward the +X side (or the −X side) while maintaining the gas blowing state. In other words, the control unit CONT moves thegas nozzle160 in the X axis direction. Accordingly, the control unit CONT can smoothly move (move aside) theliquid1 to the outside of the area of thelower surface2aof theoptical element2 corresponding to the projection area AR1. When theliquid1, which is adhered to the central portion of thelower surface2aof the optical element2 (central portion of the area corresponding to the projection area AR1), is moved in the Y axis direction in order to exclude theliquid1 to the outside of the area corresponding to the projection area AR1, the movement distance is long, because the Y axis direction is the longitudinal direction for the projection area AR1. When the movement distance is long, the movement time is long as well. Therefore, when much weight is given to the time efficiency, it is desirable that theliquid1, which is adhered to the central portion of thelower surface2aof the optical element2 (central portion of the area corresponding to the projection area AR1), is moved in the X axis direction. Accordingly, theliquid1 can be moved smoothly to the outside of the area corresponding to the projection area AR1.
• In this embodiment, the gas, which is blown from theblow port161 of thegas nozzle160, is the clean gas obtained after passing through a filter unit (not shown) including a chemical filter and a particle-removing filter. Accordingly, theoptical element2 or the like can be prevented from being contaminated. As for the gas, it is preferable to use a gas which is substantially the same as the gas contained in the environment in which the exposure apparatus EX is installed, specifically a gas which is substantially the same as the gas contained in the chamber in which the exposure apparatus EX is accommodated. In this embodiment, the air (dry air) is used. Alternatively, the nitrogen gas (dry nitrogen) may be used as the gas which is to be blown. If any gas, which is different from the gas contained in the environment in which the exposure apparatus EX is installed, is used, there is such a possibility that any inconvenience such as any measurement error or the like may be caused, for example, due to the variation or fluctuation of the optical path for the measuring light beam of the interferometer which measures the stage position on account of the difference in refractive index between the mutually different gases. However, when the gas, which is blown from theblow port161, is substantially the same gas as the gas contained in the installation environment for the exposure apparatus EX, it is possible to avoid the inconvenience as described above.
• Theliquid1, which has been moved (moved aside) to the outside of the area through which the exposure light beam EL passes, is vaporized (dried) and removed, for example, by a predetermined drying unit and/or the gas blown from thegas nozzle160.
• Even when the liquid, which has been moved to the outside of the area through which the exposure light beam EL passes, is dried, it is possible to suppress the adhesion of any impurity or the like to the portion at which the liquid has been dried at the outside of the area through which the exposure light beam EL passes, because the washing operation has been performed for thelower surface2aof theoptical element2 before allowing the gas to blow from thegas nozzle160.
• In this embodiment, the liquid, which has been moved to the outside of the area through which the exposure light beam EL passes, may be sucked (recovered).
• Similarly, the control unit CONT moves (move aside) the liquid (liquid droplet) adhered to at least the area of each of the end surfaces of the first and secondoptical members151,152 on the liquid contact surface side through which the detecting light beam of the focus-detectingsystem4 passes, by using the gas blown from thegas nozzle160. Accordingly, it is possible to avoid the inconvenience which would be otherwise caused such that the water mark is formed in (any impurity adheres to) at least the area of each of the end surfaces of the first and secondoptical members151,152 through which the detecting light beam passes.
• Similarly, the control unit CONT moves aside theliquid1 adhered to (remaining on) thesupply nozzle173 and therecovery nozzle177 by using the gas blown from thegas nozzle160. Accordingly, it is possible to avoid the inconvenience of the formation of the water mark on thesupply nozzle173 and therecovery nozzle177. The water mark acts as the foreign matter (impurity). Therefore, if the water mark is formed, for example, on the supply nozzle173 (supply port174) and/or the recovery nozzle177 (recovery port178), there is such a possibility that the foreign matter (impurity), which results from the water mark, may invade the liquid immersion area AR2 when the liquid immersion area AR2 is formed. In such a situation, the exposure accuracy and/or the measuring accuracy is consequently deteriorated. Further, it is considered that the recovery ability of theliquid recovery mechanism30 is changed depending on the contact angle (affinity) of the recovery nozzle177 (recovery port178) with respect to theliquid1. If the water mark is formed on therecovery nozzle177, and the contact angle with respect to theliquid1 is changed, then there is such a possibility that the recovery ability of theliquid recovery mechanism30 may be deteriorated. However, the inconvenience as described above can be avoided by removing theliquid1 adhered to thenozzles173,177 as described in this embodiment.
• As explained above, the liquid, which adheres to the predetermined area of theoptical element2 and the first and secondoptical members151,152 (area irradiated with the exposure light beam and/or the detecting light beam), is moved (moved aside) to the outside of the predetermined area by blowing the gas thereagainst while moving the gas nozzle160 (blow port161) relative to the predetermined area. Accordingly, it is possible to avoid the inconvenience of the formation of the water mark in the predetermined area.
• This embodiment is constructed such that the gas is firstly blown against the central portion of thelower surface2a, and then thegas nozzle160 is moved substantially linearly toward the end of thelower surface2ain the state in which the blow of the gas is maintained, when the liquid1 adhered to thelower surface2aof theoptical element2 is moved aside to the end. However, thegas nozzle160 may be moved so that theblow port161 depicts a spiral locus with respect to thelower surface2a. The shape of theblow port161 is not limited to the slit-shaped form. It is also allowable to use any arbitrary shape including, for example, circular shapes. Further, a porous member may be arranged at theblow port161.
• In this embodiment, one gas nozzle160 (blow port161) is provided. It is a matter of course that a plurality of gas nozzles160 (blow ports161) may be provided, and they may be used simultaneously. Further, a plurality ofgas nozzles160 may be used, for example, as follows. That is, theliquid1 adhered to theoptical element2 is removed by using the gas blown from thefirst gas nozzle160, and the liquid1 adhered to the firstoptical member151 or the secondoptical member152 is removed by using the gas blown from asecond gas nozzle160. The removing operations as described above may be used concurrently. When the liquid-removing operations are performed concurrently for a plurality of predetermined areas by using a plurality ofgas nozzles160 respectively, it is possible to efficiently perform the liquid-removing operations.
• In order to move (move aside) theliquid1 adhered to the end surfaces of the first and secondoptical members151,152 and theoptical element2, for example, it is also allowable to use, for example, the gas blown from theblow port64A of the second liquid-removingunit60 explained with reference toFIG. 8.
• The embodiment described above is constructed such that the gas is blown from the lower position against theoptical element2 and the first and secondoptical members151,152. However, the gas may be blown from an upper position. For example, as shown inFIG. 21, ablow port161 of thegas nozzle162 may be installed so that theblow port161 is directed downwardly or obliquely downwardly to remove (move aside) theliquid1 adhered to the end surface of the secondoptical member152 on the liquid contact surface side. It is a matter of course that thegas nozzle160 can be also used to remove theliquid1 adhered to the end surface of the firstoptical member151. Alternatively, aflow passage163 may be formed through a part of the first optical member151 (or the second optical member152). Agas nozzle164, which is connected to theflow passage163, may be provided on the end surface of the firstoptical member151 on the liquid contact surface side. The gas, which passes through theflow passage163 and thegas nozzle164, can be also blown against the end surface of the firstoptical member151 from an upper position. Theflow passage163 is formed at a position at which the optical path for the detecting light beam of the focus-detectingsystem4 is not inhibited.
• In the embodiment described above, the liquid is removed by using thegas nozzle160 after washing theoptical element2 disposed at the end portion of the projection optical system PL, the first and secondoptical members151,152, those disposed in the vicinity of thesupply port174 of thesupply nozzle173, and those disposed in the vicinity of therecovery port178 of therecovery nozzle177. However, the washing step may be omitted. Thegas nozzle160 may be provided on the substrate stage PST in the same manner as in the embodiment described above, and thegas nozzle160 may be moved by moving the substrate stage PST. Alternatively, as disclosed in Japanese Patent Application Laid-open No. 11-135400, a stage, which is movable on the image plane side of the projection optical system PL, may be further provided independently from the substrate stage PST to arrange thegas nozzle160 on the stage.
• In the embodiment described above, the gas is blown from theblow port161 to move theliquid1 adhered to theoptical element2, the first and secondoptical members151,152, and/or thenozzles173,177. However, it is also possible to move theliquid1 remaining on (adhered to) the substrate stage PST by using the gas blown from theblow port161. For example, theblow port161 may be arranged to be opposed to the upper surface of the substrate stage PST. The gas may be blown from theblow port161 against thereference member7 as explained, for example, with reference toFIG. 3. The liquid1 adhered onto thereference member7 can be moved (moved aside) to the outside of the reference member7 (or to the outside of the detection objective area on the reference member7) without drying theliquid1. Similarly, the gas can be blown from theblow port161 to move (move aside), without performing the drying, theliquid1 adhered onto theupper plate138A of theuneven illuminance sensor138 as explained, for example, with reference toFIG. 16, and the liquid1 adhered to a radiation amount monitor as disclosed, for example, in Japanese Patent Application Laid-open No. 11-16816 and to an upper plate of a spatial image-measuring sensor as disclosed, for example, in Japanese Patent Application Laid-open No. 2002-14005.
Embodiment of Exposure Apparatus Based on Use of Fourth Liquid-Removing Unit
• FIG. 22 shows an embodiment of an exposure apparatus provided with a liquid-removing unit (fourth liquid-removing unit) different from the first to third liquid-removing units. With reference toFIG. 22, one end of agas supply tube181 is connected to an intermediate portion of asupply tube172, for example, by the aid of a flow passage-switchingunit182 such as a three-way valve. On the other hand, the other end of thegas supply tube181 is connected to agas supply section180. The flow passage-switchingunit182 closes the flow passage which connects thegas supply section180 and asupply port174 when the flow passage, which connects theliquid supply section171 and thesupply port174, is opened. On the other hand, the flow passage-switchingunit182 opens the flow passage which connects thegas supply section180 and thesupply port174 when the flow passage, which connects theliquid supply section171 and thesupply port174, is closed. Similarly, one end of agas supply tube184 is connected to an intermediate portion of arecovery tube176 by the aid of a flow passage-switchingunit185. The other end of thegas supply tube184 is connected to agas supply section183. The flow passage-switchingunit185 closes the flow passage which connects thegas supply section183 and arecovery port178 when the flow passage, which connects theliquid recovery section175 and therecovery port178, is opened. On the other hand, the flow passage-switchingunit185 opens the flow passage which connects thegas supply section183 and therecovery port178 when the flow passage, which connects theliquid recovery section175 and therecovery port178, is closed. In this embodiment, for example, thegas supply sections180,183, thesupply port174, therecovery port178, and the flow passage-switchingunit182 function as the fourth liquid-removing unit (liquid-removing mechanism) for removing the remaining liquid.
• For example, when the liquid immersion area AR2 is formed on the substrate P, the control unit CONT drives the flow passage-switchingunits182,185 so that the flow passage, which connects theliquid supply section171 and thesupply port174, is opened, and the flow passage, which connects theliquid recovery section175 and therecovery port178, is opened. In this situation, the flow passage for connecting thegas supply section180 and thesupply port174, and the flow passage for connecting thegas supply section183 and therecovery port178 are closed.
• After the completion of the liquid immersion exposure for the substrate P, the control unit CONT stops the liquid supply operation performed by theliquid supply mechanism10. Further, the liquid recovery operation is continued by theliquid recovery mechanism30 for a predetermined period of time after the stop of the liquid supply operation to recover theliquid1 with which the liquid immersion area AR2 has been formed. When the liquid supply operation performed by theliquid supply mechanism10 is stopped, the control unit CONT drives the flow passage-switchingunit182 to close the flow passage for connecting theliquid supply section171 and thesupply port174 and open the flow passage for connecting thegas supply section180 and thesupply port174. After theliquid1 of the liquid immersion area AR2 substantially disappears, the control unit CONT drives thegas supply section180 to start the supply of the gas. The gas, which is supplied from thegas supply section180, is blown from thesupply port174 of thesupply nozzle174 through thegas supply tube181 and the flow passage-switchingunit182. Accordingly, theliquid1, which remains in the flow passage between the flow passage-switchingunit182 and thesupply port174, is successfully blown to the outside via thesupply port174 so that theliquid1 can be removed. The gas, which is supplied from thegas supply section180 and which is blown from thesupply port174, can be used to remove, for example, theliquid1 adhered to the end surfaces of the first and secondoptical members151,152 and the liquid1 adhered onto the substrate stage PST (including, for example, the measuring member).
• Similarly, the control unit CONT drives the flow passage-switchingunit185 after the completion of the recovery operation for the liquid1 in the liquid immersion area AR2 by theliquid recovery mechanism30 to close the flow passage for connecting theliquid recovery section175 and therecovery port178 and open the flow passage for connecting thegas supply section183 and therecovery port178. The control unit CONT uses the gas supplied from thegas supply section183 so that theliquid1, which remains in the flow passage between the flow passage-switchingunit185 and therecovery port178, is blown off to the outside and removed through therecovery port178. The gas, which is blown from therecovery port178, can be also used to remove (move aside) theliquid1 adhered to the end surfaces of the first and secondoptical members151,152 and the liquid1 adhered onto the substrate stage PST (including, for example, the measuring member).
• As explained above, the clean gas is supplied from thegas supply sections180,183 when theliquid1 is neither supplied nor recovered. Accordingly, it is possible to avoid the inconvenience of the formation of the water mark in the internal flow passages of thesupply tube172 and thesupply nozzle173, those disposed in the vicinity of thesupply port174, the internal flow passages of therecovery tube176 and therecovery nozzle177, and those in the vicinity of therecovery port178. In this embodiment, the supply port (discharge port) is commonly used for the liquid and the gas for removing the liquid. Therefore, the structure can be simplified in the vicinity of the liquid supply port, and it is possible to obtain the compact exposure apparatus.
Another Embodiment of Exposure Apparatus Based on Use of Third Liquid-Removing Unit
• FIG. 23 shows a modified embodiment of the exposure apparatus based on the use of the third liquid-removing unit shown inFIG. 19. With reference toFIG. 23, agas nozzle160, which has ablow port161, is attached to a liquid-receivingmember190. The liquid-receivingmember190 is a dish-shaped member which is formed to be larger than the occupied area occupied by theoptical element2, thenozzles173,177, and the first and secondoptical members151,152. Theliquid1, which drips from the respective members, can be received by the upper surface of the liquid-receivingmember190. A liquid-absorbingmember199, which is formed of a porous member or a sponge-like member, is exchangeably provided on the upper surface of the liquid-receivingmember190. Accordingly, theliquid1, which drips from the respective members, can be satisfactorily recovered (collected) and retained. Acircumferential wall section191 is formed for the liquid-receivingmember190. Therefore, it is possible to prevent the collected liquid1 from any outflow from the liquid-receivingmember190.
• The liquid-receivingmember190 is provided movably by the aid of adriving mechanism193. Thedriving mechanism193 includes anarm section194, anactuator section195, and ashaft section196. One end of thearm section194 is connected to the side surface of the liquid-receivingmember190, and the other end is connected to theactuator section195. Theactuator section195 is attached so that theactuator section195 is hung, for example, by a predetermined support section CL such as a column for supporting the projection optical system PL and the body of the exposure apparatus EX by the aid of theshaft section196. When theactuator section195 is driven, the liquid-receivingmember190, which is attached to one end of thearm section194, makes swinging movement in the θZ direction about the swinging center of theshaft section196. The control unit CONT can move the liquid-receivingmember190 back and forth with respect to the area under the projection optical system PL by driving theactuator section195 of thedriving mechanism193 to cause the swinging movement of the liquid-receivingmember190. Further, theactuator section195 is capable of moving the liquid-receivingmember190 in the Z axis direction by the aid of thearm section194, and theactuator section195 is capable of moving the liquid-receivingmember190 in the XY directions as well.
• The liquid-receivingmember190 is provided with animage pickup unit198 including, for example, CCD. Theimage pickup unit198 is capable of outputting, as an image, the surface information about theoptical element2 and the first and secondoptical members151,152.
• When the control unit CONT moves (removes) theliquid1 adhered, for example, to theoptical element2 and the first and secondoptical members151,152, then theactuator section195 is driven so that theoptical element2 is opposed to the liquid-receivingmember190, and the gas is blown against theoptical element2 while moving thegas nozzle160 together with the liquid-receivingmember190 with respect to theoptical element2. Theliquid1, which adheres to the area of theoptical element2 corresponding to the optical path for the exposure light beam EL, is moved by the blown gas, and then the liquid1 falls. Theliquid1, which has fallen from theoptical element2, is retained by the liquid-receivingmember190. Accordingly, for example, even when the substrate stage PST is arranged under the projection optical system PL and the liquid-receivingmember190, then theliquid1 is received by the liquid-receivingmember190, and thus it is possible to avoid the inconvenience which would be otherwise caused such that theliquid1, which is removed, for example, from theoptical element2, adheres to the substrate stage PST.
• The control unit CONT controls the gas blow operation of thegas nozzle160 on the basis of the image pickup result obtained by theimage pickup unit198. For example, the control unit CONT determines the position of the adhesion of theliquid1 on the basis of the image pickup result obtained by theimage pickup unit198 to successfully perform the control such that the position of the adhesion of theliquid1 and thegas nozzle160 are subjected to the positional adjustment to allow the gas to blow thereagainst. Accordingly, it is possible to remove theliquid1 more reliably. When it is judged that theliquid1 is removed from theoptical element2, the control unit CONT completes the gas blow operation having been performed by thegas nozzle160.
• It is also appropriate to provide a positioning mechanism which positions, for example, the liquid-receivingmember190 and the first and secondoptical members151,152. Aleaf spring member192 as shown by broken lines inFIG. 23 can be used as the positioning mechanism. In the illustrative embodiment shown inFIG. 23, theleaf spring member192 is provided on theupper surface191A of thecircumferential wall section191 of the liquid-receivingmember190. When the liquid-receivingmember190 is moved in the +Z direction in accordance with the driving of theactuator section195 to approach the first and secondoptical members151,152, the leaf spring member (positioning mechanism)192 interposes the outer portions of the first and secondoptical members151,152. Accordingly, the first and secondoptical members151,152 and the liquid-receivingmember190 are positioned. In this state, the gas, which is discharged from thegas nozzle160, is blown against a desired area of the optical element2 (in this case, the area corresponding to the projection area AR1). Accordingly, it is possible to satisfactorily remove (move aside) theliquid1 adhered to the area.
Still Another Embodiment of Exposure Apparatus Based on Use of Third Liquid-Removing Unit
• FIG. 24 shows another modified embodiment of the exposure apparatus provided with the third liquid-removing unit. In this modified embodiment, the gas for removing the liquid is jetted or spouted not from the nozzle but from suction holes for sucking and attracting the substrate. With reference toFIG. 24, the substrate stage PST is provided with a center table250 which is provided at a substantially central portion of the substrate stage PST as viewed in a plan view and which is movable in the Z axis direction. The center table250 is movable in the Z axis direction by the aid of an unillustrated driving mechanism, which is provided to be capable of protruding from the upper surface of the substrate stage PST (Z stage52). The suction holes251 are provided on theupper surface250A of the center table250. The suction holes251 are connected to one end of aflow passage252 which is provided in the substrate stage PST. On the other hand, the other end of theflow passage252 is capable of making communication with any one of one end of afirst flow passage254 and one end of asecond flow passage255 by the aid of a flow passage-switchingunit253. The other end of thefirst flow passage254 is connected to avacuum system256, and the other end of thesecond flow passage255 is connected to agas supply section257. When the flow passage-switchingunit253 connects theflow passage252 and thefirst flow passage254 to open the flow passage which connects thevacuum system256 and the suction holes251, the flow passage-switchingunit253 closes the flow passage which connects thegas supply section257 and the suction holes251. On the other hand, when the flow passage-switchingunit253 connects theflow passage252 and thesecond flow passage255 to open the flow passage which connects thegas supply section257 and the suction holes251, the flow passage-switchingunit253 closes the flow passage which connects thevacuum system256 and the suction holes251.
• When the substrate P is loaded on the substrate stage PST, then the control unit CONT moves the center table250 upwardly to place the substrate P on the center table250, and thevacuum system256 is driven to attract and hold the back surface of the substrate P by the aid of the suction holes251. The control unit CONT moves the center table250 downwardly in a state in which the substrate P is attracted and held, and the substrate P is held on the substrate holder on theZ stage52. The substrate holder is provided, for example, with a pin-chuck mechanism. The substrate holder attracts and holds the substrate P by the pin-chuck mechanism. On the other hand, when the substrate P is unloaded from the substrate stage PST, then the control unit CONT releases the substrate P from being attracted and held by the substrate holder, and the center table250 is moved upwardly while attracting and holding the substrate P. When the center table250 is moved upwardly in a state in which the substrate P is attracted and held thereby, then the substrate P is separated from the Z stage, and the unload operation can be performed.
• In this embodiment, the gas is blown from the suction holes251 provided for the center table250. The blown gas is used to move (move aside) theliquid1 adhered to thelower surface2aof theoptical element2 and the first and secondoptical members151,152. When the liquid1 adhered to theoptical element2 and/or the first and secondoptical members151,152 is removed, the control unit CONT drives the flow passage-switchingunit253 to open the flow passage for connecting thegas supply section257 and the suction holes251. The control unit CONT moves the substrate stage PST along the XY plane, while the gas is blown from the suction holes251. When the gas is blown, then theliquid1, which has been adhered, for example, to the area of thelower surface2aof theoptical element2 corresponding to the optical path for the exposure light beam EL, is moved, and then the liquid1 falls.
• In this embodiment, a liquid-receiving-member DP, which is capable of collecting theliquid1, is installed on the Z stage52 (substrate holder). The liquid-receiving member DP is a dish-shaped member in the same manner as the liquid-receivingmember190 shown inFIG. 23, which is formed to have a circular shape with a size substantially equivalent to that of the substrate P. The liquid-receiving member DP can be installed on the substrate holder. Theliquid1, which has fallen from theoptical element2, is retained by the liquid-receiving member DP installed for the substrate holder. A liquid-retainingmember261 is provided on the upper surface of the liquid-receiving member DP. Theliquid1 is recovered and retained by the liquid-retainingmember261. The liquid-receiving member DP has acircumferential wall section262 which prevents the retained liquid1 from any outflow from the liquid-receiving member DP.
• FIG. 25 shows the liquid-receiving member DP held by the substrate holder as viewed from an upper position. With reference toFIG. 25, a plurality of the suction holes251 are provided on theupper surface250A of the center table250. In this embodiment, the three suction holes are provided. A plurality of (three)openings264, which correspond to the plurality of suction holes251, are provided for the liquid-receiving member DP. That is, the suction holes251 are exposed even in a state in which the liquid-receiving member DP is held by the substrate holder. Therefore, the gas, which is discharged or spouted from the suction holes251, is successfully blown against theoptical element2 or the like. A plurality of (three)grooves258, which extend in the radial direction from the central portion of theupper surface250A, are formed on theupper surface250A of the center table250. The plurality ofgrooves258 are continued to one another at the central portion of theupper surface250A. The suction holes251 are arranged inside thegrooves258. When the back surface of the substrate P as the exposure process objective is attracted and held by theupper surface250A of the center table250, then thevacuum system256 is driven in a state in which the back surface of the substrate P abuts against theupper surface250A, and the space, which is formed by the back surface of the substrate P and thegrooves258, is allowed to have a negative pressure. Accordingly, the substrate P can be attracted and held by the center table250. When the liquid-receiving member DP is held by the center table250, the liquid-receiving member DP can be also held by the center table250 by appropriately setting, for example, the shapes and the sizes of theopening264 and thegroove258 and/or the size and the position of thesuction hole251. Alternatively, suction holes and grooves corresponding thereto, which are different from the suction holes251 and which are exclusively used to attract and hold the liquid-receiving member DP, may be previously provided on theupper surface250A of the center table250 (seereference numerals251′ and258′ shown inFIG. 25). The suction holes251′ may be used to attract and hold the liquid-receiving member DP with respect to theupper surface250A. The center table250 can be used to load/unload the liquid-receiving member DP with respect to the substrate stage PST, in the same manner as the substrate P as the exposure process objective. When the liquid removal operation is performed for theoptical element2 or the like, the liquid-receiving member DP is loaded on the substrate stage PST. When the liquid removal operation is completed, the liquid-receiving member DP is unloaded from the substrate stage PST. When the liquid-receiving member DP is attracted and held by the pin-chuck mechanism of the substrate holder, the following arrangement is adopted in order to form a substantially tightly closed space with respect to the back surface of the liquid-receiving member DP other than theopenings264. That is, for example, the area, which is allowed to have a negative pressure by the pin-chuck mechanism, may be divided into a plurality of pieces. The negative pressure is selectively applied in the area other than the area corresponding to theopenings264. Accordingly, the liquid-receiving member DP can be attracted and held with respect to the substrate holder.
• There is such a possibility that theliquid1, which is retained by the liquid-receiving member DP, may invade the space between the back surface of the liquid-receiving member DP and theupper surface250A of the center table250 (as well as the upper surface of the substrate holder) via theopenings264. Therefore, it is preferable to provide a seal member, for example, in the vicinity of theopenings264 and/or the back surface of the liquid-receiving member DP in order to avoid the invasion of theliquid1.
• It is preferable that the substrate stage PST is moved to any position away from the projection optical system PL, for example, to the load/unload position B (seeFIG. 9) to blow the gas beforehand from the suction holes251 at the position before blowing the gas discharged from the suction holes251 against theoptical element2 or the like. There is such a possibility that any foreign matter (dust) may be present in the suction holes251 and/or in the vicinity of thereof. However, when the gas is blown against theoptical lens2 or the like after the gas blow operation is previously performed to remove the foreign matter at the position separated from the projection optical system PL, it is possible to avoid the inconvenience such as the pollution of theoptical element2 or the like.
• Also in the embodiment shown inFIG. 24, theblow port64A as explained, for example, with reference toFIG. 8 may be provided at any position other than the position of the substrate holder for holding the substrate P on the substrate stage PST, and the gas blown from theblow port64A can be used to move theliquid1 adhered to theoptical element2 or the like.
• In the embodiments described above, the first to fourth liquid-removing units have been explained. However, each of the removing units as described above may be provided on the exposure apparatus EX singly. Alternatively, the removing units as described above may be appropriately combined and provided on the exposure apparatus EX.
• As described above, pure water is used as theliquid1 in the embodiments of the present invention. Pure water is advantageous in that pure water is available in a large amount with ease, for example, in the semiconductor production factory, and pure water exerts no harmful influence, for example, on the optical element (lens) and the photoresist on the substrate P. Further, pure water exerts no harmful influence on the environment, and the content of impurity is extremely low. Therefore, it is also expected to obtain the function to wash the surface of the substrate P and the surface of the optical element provided at the end surface of the projection optical system PL.
• It is approved that the refractive index n of pure water (water) with respect to the exposure light beam EL having a wavelength of about 193 nm is approximately in an extent of 1.44. When the ArF excimer laser beam (wavelength: 193 nm) is used as the light source of the exposure light beam EL, then the wavelength is shortened on the substrate P by 1/n, i.e., to about 134 nm, and a high resolution is obtained. Further, the depth of focus is magnified about n times, i.e., about 1.44 times as compared with the value obtained in the air. Therefore, when it is enough to secure an approximately equivalent depth of focus as compared with the case of the use in the air, it is possible to further increase the numerical aperture of the projection optical system PL. Also in this viewpoint, the resolution is improved.
• In this embodiment, theoptical element2 is attached to the end portion of the projection optical system PL. The lens can be used to adjust the optical characteristics of the projection optical system PL, including, for example, the aberration (for example, spherical aberration and comatic aberration). Theoptical element2, which is attached to the end portion of the projection optical system PL, may be an optical plate to adjust the optical characteristic of the projection optical system PL. Alternatively, theoptical element2 may be a plane parallel plate through which the exposure light beam EL is transmissive. When theoptical element2 to make contact with theliquid1 is the plane parallel plate which is cheaper than the lens, it is enough that the plane parallel plate is merely exchanged immediately before supplying theliquid1 even when any substance (for example, any silicon-based organic matter), which deteriorates the transmittance of the projection optical system PL, the illuminance of the exposure light beam EL on the substrate P, and the uniformity of the illuminance distribution, is adhered to the plane parallel plate, for example, during the transport, the assembling, and/or the adjustment of the exposure apparatus EX. An advantage is obtained such that the exchange cost is lowered as compared with the case in which the optical element to make contact with theliquid1 is the lens. That is, the surface of the optical element to make contact with theliquid1 is dirtied, for example, due to the adhesion of scattered particles generated from the resist by being irradiated with the exposure light beam EL or any adhered impurity contained in theliquid1. Therefore, it is necessary to periodically exchange the optical element. However, when the optical element is the cheap plane parallel plate, then the cost of the exchange part is low as compared with the lens, and it is possible to shorten the time required for the exchange. Thus, it is possible to suppress the increase in the maintenance cost (running cost) and the decrease in the throughput.
• When the pressure, which is generated by the flow of theliquid1, is large between the substrate P and the optical element disposed at the end portion of the projection optical system PL, it is also allowable that the optical element is tightly fixed so that the optical element is not moved by the pressure, rather than allowing the optical element to be exchangeable.
• The embodiment of the present invention is constructed such that the space between the projection optical system PL and the surface of the substrate P is filled with theliquid1. However, for example, another arrangement may be adopted such that the space is filled with the liquid1 in a state in which a cover glass constructed of a plane parallel plate is attached to the surface of the substrate P.
• Theliquid1 is water in the embodiment of the present invention. However, theliquid1 may be any liquid other than water. For example, when the light source of the exposure light beam EL is the F₂laser, the F₂laser beam is not transmitted through water. Therefore, in this case, those preferably usable as theliquid1 may include, for example, a fluorine-based fluid such as fluorine-based oil and perfluoropolyether (PFPE) through which the F₂laser beam is transmissive. In this case, the portion to make contact with theliquid1 is subjected to the liquid-attracting treatment by forming a thin film, for example, with a substance having a molecular structure of small polarity including fluorine. Alternatively, other than the above, it is also possible to use, as theliquid1, liquids (for example, cedar oil) which have the transmittance with respect to the exposure light beam EL, which have the refractive index as high as possible, and which are stable against the photoresist coated on the surface of the substrate P and the projection optical system PL. Also in this case, the surface treatment is performed depending on the polarity of the liquid1 to be used.
• When the liquid immersion method is used as described above, the numerical aperture NA of the projection optical system is 0.9 to 1.3 in some cases. When the numerical aperture NA of the projection optical system is increased as described above, the image formation performance is sometimes deteriorated by the polarization effect with the random polarized light beam having been hitherto used as the exposure light beam. Therefore, it is desirable to use the polarized illumination. In this case, the following procedure is preferred. That is, the linear polarized illumination is effected, which is adjusted to the longitudinal direction of the line pattern of the line-and-space pattern of the mask (reticle) so that a large amount of diffracted light of the S-polarized component (TE-polarized component), i.e., the component in the polarization direction along the longitudinal direction of the line pattern is allowed to outgo from the pattern of the mask (reticle). When the space between the projection optical system PL and the resist coated on the surface of the substrate P is filled with the liquid, the diffracted light of the S-polarized component (TE-polarized component), which contributes to the improvement in the contrast, has the transmittance through the resist surface that is raised to be high as compared with a case in which the space between the projection optical system PL and the resist coated on the surface of the substrate P is filled with the air (gas). Therefore, even when the numerical aperture NA of the projection optical system exceeds 1.0, it is possible to obtain the high image formation performance. It is more effective to make appropriate combination, for example, with the phase shift mask and/or the oblique incidence illumination method (especially the dipole illumination method) adjusted to the longitudinal direction of the line pattern as disclosed in Japanese Patent Application Laid-open No. 6-188169. For example, when a phase shift mask of the half tone type having a transmittance of 6% (pattern having a half pitch of about 45 nm) is illuminated by using the linear polarized illumination method and the dipole illumination method in combination, the depth of focus (DOF) can be increased by about 150 nm as compared with a case in which any random polarized light beam is used, assuming that the illumination σ, which is prescribed by circumscribed circles of two light fluxes for forming the dipole on the pupil plane of the illumination system, is 0.95, the radii of the respective light fluxes on the pupil plane are 0.125σ, and the numerical aperture of the projection optical system PL is NA=1.2.
• Further, for example, when the ArF excimer laser beam is used as the exposure light beam, and the substrate P is exposed with a fine line-and-space pattern (for example, line-and-space of about 25 to 50 nm) by using the projection optical system PL having a reduction magnification of about ¼, then the mask M functions as a polarizing plate on account of the Wave Guide effect depending on the structure of the mask M (for example, the pattern fineness and the chromium thickness), and a large amount of the diffracted light beam of the S-polarized component (TE-polarized component) is radiated from the mask M as compared with the diffracted light beam of the P-polarized component (TM-component) which lowers the contrast. In such a situation, it is desirable that the linear polarized illumination is used as described above. However, the high resolution performance can be obtained even when the numerical aperture NA of the projection optical system PL is large, for example, 0.9 to 1.3 even when the mask M is illuminated with the random polarized light beam.
• When the substrate P is exposed with an extremely fine line-and-space pattern on the mask M, there is also such a possibility that the P-polarized component (TM-polarized component) may be larger than the S-polarized component (TE-polarized component) on account of the Wire Grid effect. However, when the ArF excimer laser beam is used as the exposure light beam, and the substrate P is exposed with a line-and-space pattern larger than 25 nm by using the projection optical system PL having a reduction magnification of about ¼, then a large amount of the diffracted light beam of the S-polarized component (TE-polarized component) is radiated from the mask M as compared with the P-polarized component (TM-polarized component). Therefore, the high resolution performance can be obtained even when the numerical aperture NA of the projection optical system PL is large, for example, 0.9 to 1.3.
• Further, it is also effective to use a combination of the oblique incidence illumination method and the polarized illumination method in which the linear polarization is effected in a tangential (circumferential) direction of a circle having a center of the optical axis as disclosed in Japanese Patent Application Laid-open No. 6-53120 as well as the linear polarized illumination (S-polarized illumination) adjusted to the longitudinal direction of the line pattern of the mask (reticle). In particular, when the pattern of the mask (reticle) includes not only the line pattern which extends in a predetermined one direction but the pattern also includes line patterns which extend in a plurality of directions in a mixed manner, then the high image formation performance can be obtained even when the numerical aperture NA of the projection optical system is large, by using, in combination, the zonal illumination method and the polarized illumination method in which the linear polarization is effected in a tangential direction of a circle having a center of the optical axis as disclosed in Japanese Patent Application Laid-open No. 6-53120 as well. For example, when a phase shift mask of the half tone type (pattern having a half pitch of about 63 nm) having a transmittance of 6% is illuminated by using, in combination, the zonal illumination method (zonal ratio: 3/4) and the polarized illumination method in which the linear polarization is effected in a tangential direction of a circle having a center of the optical axis, the depth of focus (DOF) can be increased by about 250 nm as compared with a case in which any random polarized light beam is used, assuming that the illumination σ is 0.95, and the numerical aperture of the projection optical system PL is NA=1.00. When the numerical aperture of the projection optical system is NA=1.2 with a pattern having a half pitch of about 55 nm, it is possible to increase the depth of focus by about 100 nm.
• The substrate P, which is usable in the respective embodiments described above, is not limited to the semiconductor wafer for producing the semiconductor device. Those applicable include, for example, the glass substrate for the display device, the ceramic wafer for the thin film magnetic head, and the master plate (synthetic quartz, silicon wafer) for the mask or the reticle to be used for the exposure apparatus.
• As for the exposure apparatus EX, the present invention is also applicable to the scanning type exposure apparatus (scanning stepper) based on the step-and-scan system for performing the scanning exposure for the pattern of the mask M by synchronously moving the mask M and the substrate P as well as the projection exposure apparatus (stepper) based on the step-and-repeat system for performing the full field exposure for the pattern of the mask M in a state in which the mask M and the substrate P are allowed to stand still, while successively step-moving the substrate P. The present invention is also applicable to the exposure apparatus based on the step-and-stitch system in which at least two patterns are partially overlaid and transferred on the substrate P.
• The present invention is also applicable to a twin-stage type exposure apparatus. The structure and the exposure operation of the twin-stage-type exposure apparatus are disclosed, for example, in Japanese Patent Application Laid-open Nos. 10-163099 and 10-214783 (corresponding to U.S. Pat. Nos. 6,341,007, 6,400,441, 6,549,269, and 6,590,634), Published Japanese Translation of PCT International Publication for Patent Application No. 2000-505958 (corresponding to U.S. Pat. No. 5,969,441), and U.S. Pat. No. 6,208,407, contents of which are incorporated herein by reference within a range of permission of the domestic laws and ordinances of the state designated or selected in this international application.
• The embodiments described above adopt the exposure apparatus in which the space between the projection optical system PL and the substrate P is locally filled with the liquid. However, the present invention is also applicable to a liquid immersion exposure apparatus wherein a stage, which holds the substrate as the exposure objective, is moved in a liquid bath. For example, Japanese Patent Application Laid-open No. 6-124873 discloses the structure and the exposure operation of the liquid immersion exposure apparatus wherein the stage, which holds the substrate as the exposure objective, is moved in the liquid bath. For example, U.S. Pat. No. 5,825,043 (Japanese Patent Application Laid-open No. 10-303114) discloses an exposure apparatus wherein a liquid bath is formed on a substrate stage to hold the substrate therein. The contents of the description in U.S. Pat. No. 5,825,043 are incorporated herein by reference within a range of permission of the domestic laws and ordinances of the state designated or selected in this international application.
• As for the type of the exposure apparatus EX, the present invention is not limited to the exposure apparatus for the semiconductor device production apparatus for exposing the substrate P with the semiconductor device pattern. The present invention is also widely applicable, for example, to the exposure apparatus for producing the liquid crystal display device or for producing the display as well as the exposure apparatus for producing, for example, the thin film magnetic head, the image pickup device (CCD), the reticle, or the mask.
• When the linear motor is used for the substrate stage PST and/or the mask stage MST, it is allowable to use any one of those of the air floating type based on the use of the air bearing and those of the magnetic floating type based on the use of the Lorentz's force or the reactance force. Each of the stages PST, MST may be either of the type in which the movement is effected along the guide or of the guideless type in which no guide is provided. An example of the use of the linear motor for the stage is disclosed in U.S. Pat. Nos. 5,623,853 and 5,528,118, contents of which are incorporated herein by reference within a range of permission of the domestic laws and ordinances of the state designated or selected in this international application.
• As for the driving mechanism for each of the stages PST, MST, it is also allowable to use a plane motor in which a magnet unit provided with two-dimensionally arranged magnets and an armature unit provided with two-dimensionally arranged coils are opposed to one another, and each of the stages PST, MST is driven by the electromagnetic force. In this arrangement, any one of the magnet unit and the armature unit is connected to the stage PST, MST, and the other of the magnet unit and the armature unit is provided on the side of the movable surface of the stage PST, MST.
• The reaction force, which is generated in accordance with the movement of the substrate stage PST, may be mechanically released to the floor (ground) by using a frame member so that the reaction force is not transmitted to the projection optical system PL. The method for handling the reaction force is disclosed in detail, for example, in U.S. Pat. No. 5,528,118 (Japanese Patent Application Laid-open No. 8-166475), contents of which are incorporated herein by reference within a range of permission of the domestic laws and ordinances of the state designated or selected in this international application.
• The reaction force, which is generated in accordance with the movement of the mask stage MST, may be mechanically released to the floor (ground) by using a frame member so that the reaction force is not transmitted to the projection optical system PL. The method for handling the reaction force is disclosed in detail, for example, in U.S. Pat. No. 5,874,820 (Japanese Patent Application Laid-open No. 8-330224), contents of which are incorporated herein by reference within a range of permission of the domestic laws and ordinances of the state designated or selected in this international application.
• As described above, the exposure apparatus EX according to the embodiment of the present invention is produced by assembling the various subsystems including the respective constitutive elements as defined in claims so that the predetermined mechanical accuracy, the electric accuracy, and the optical accuracy are maintained. In order to secure the various accuracies, those performed before and after the assembling include the adjustment for achieving the optical accuracy for the various optical systems, the adjustment for achieving the mechanical accuracy for the various mechanical systems, and the adjustment for achieving the electric accuracy for the various electric systems. The steps of assembling the various subsystems into the exposure apparatus include, for example, the mechanical connection, the wiring connection of the electric circuits, and the piping connection of the air pressure circuits in correlation with the various subsystems. It goes without saying that the steps of assembling the respective individual subsystems are performed before performing the steps of assembling the various subsystems into the exposure apparatus. When the steps of assembling the various subsystems into the exposure apparatus are completed, the overall adjustment is performed to secure the various accuracies as the entire exposure apparatus. It is desirable that the exposure apparatus is produced in a clean room in which, for example, the temperature and the cleanness are managed.
• As shown inFIG. 26, the microdevice such as the semiconductor device is produced by performing, for example, astep201 of designing the function and the performance of the microdevice, astep202 of manufacturing a mask (reticle) based on the designing step, astep203 of producing a substrate as a base material for the device, anexposure process step204 of exposing the substrate with a pattern of the mask by using the exposure apparatus EX of the embodiment described above, astep205 of assembling the device (including a dicing step, a bonding step, and a packaging step), and aninspection step206.
• According to the present invention, it is possible to avoid the occurrence of the rust or the like on the apparatus and the environmental change in the exposure apparatus caused by the falling of the remaining liquid, by removing the unnecessary liquid remaining on the part arranged in the vicinity of the image plane of the projection optical system. In particular, it is possible to avoid the occurrence of the adhesion trace (water mark) on the optical element, by removing the liquid remaining on the optical element disposed at the end portion of the projection optical system. Therefore, it is possible to accurately form a desired pattern on the substrate.

Claims (41)

1. An exposure apparatus which projects an image of a pattern onto a substrate through a liquid to expose the substrate therewith, the exposure apparatus comprising:

a projection optical system which projects the image of the pattern onto the substrate; and

a liquid-removing mechanism which removes the liquid remaining on a part arranged in the vicinity of an image plane of the projection optical system.

2. The exposure apparatus according toclaim 1, wherein the liquid-removing mechanism includes a liquid-sucking unit which sucks the liquid adhered to the part.

3. The exposure apparatus according toclaim 1, wherein the liquid-removing mechanism includes a unit which blows a gas against the part.

4. The exposure apparatus according toclaim 1, wherein the part includes a part disposed at an end portion of the projection optical system.

5. The exposure apparatus according toclaim 1, further comprising a liquid supply mechanism which supplies the liquid, wherein the part includes a supply nozzle of the liquid supply mechanism.

6. The exposure apparatus according toclaim 1, further comprising a liquid recovery mechanism which recovers the liquid, wherein the part includes a recovery nozzle of the liquid recovery mechanism.

7. The exposure apparatus according toclaim 1, wherein the part makes contact with the liquid during the exposure for the substrate.

8. The exposure apparatus according toclaim 1, further comprising a stage which is movable on a side of the image plane of the projection optical system.

9. The exposure apparatus according toclaim 8, wherein the part includes a part of the stage or a measuring member provided on the stage.

10. The exposure apparatus according toclaim 9, wherein the measuring member includes a reference member provided on the stage.

11. The exposure apparatus according toclaim 9, further comprising a measuring system including an upper plate which has a light-transmitting portion which transmits an exposure light beam from the projection optical system therethrough, and a light-receiving system which receives the light beam having passed through the light-transmitting portion of the upper plate, wherein the part includes the upper plate of the measuring system.

12. The exposure apparatus according toclaim 8, wherein at least a part of the liquid-removing mechanism is provided on the stage.

13. The exposure apparatus according toclaim 1, wherein a surface of the part is liquid-repellent.

14. The exposure apparatus according toclaim 1, wherein the liquid-removing mechanism moves the liquid remaining in a predetermined area on a surface of the part to outside of the predetermined area.

15. The exposure apparatus according toclaim 1, wherein the liquid-removing mechanism removes the liquid by using a clean gas or a dry gas.

16. The exposure apparatus according toclaim 15, wherein the clean gas is nitrogen gas.

17. The exposure apparatus according toclaim 1, further comprising a washing mechanism which washes the part.

18. The exposure apparatus according toclaim 1, further comprising a detection unit which detects a state of a surface of the part.

19. The exposure apparatus according toclaim 1, wherein the liquid-removing mechanism removes the liquid remaining on the part arranged in the vicinity of the image plane of the projection optical system before the exposure or after the exposure.

20. The exposure apparatus according toclaim 19, further comprising a liquid recovery mechanism which recovers the liquid from a surface of the substrate during the exposure.

21. The exposure apparatus according toclaim 8, wherein the liquid-removing mechanism includes a first liquid-removing mechanism which removes the liquid remaining on the part provided on the stage, and a second liquid-removing mechanism which removes the liquid remaining at an end portion of the projection optical system.

22. The exposure apparatus according toclaim 8, wherein the liquid-removing mechanism includes a gas blow nozzle which is provided for the stage and which spouts a gas upwardly from the stage.

23. The exposure apparatus according toclaim 1, further comprising a control unit which controls the liquid-removing mechanism, wherein the control unit controls the liquid-removing mechanism to execute liquid removal operation by the liquid-removing mechanism when the substrate is unloaded.

24. The exposure apparatus according toclaim 1, further comprising an optical member which makes contact with the liquid in a liquid immersion area, and a focus-detecting system, wherein a light beam, which is radiated from the focus-detecting system, is transmitted through the optical member and the liquid, and the light beam arrives at the substrate.

25. The exposure apparatus according toclaim 1, wherein the liquid-removing mechanism includes a gas-spouting section which is movable in a substrate surface direction.

26. The exposure apparatus according toclaim 1, wherein the liquid-removing mechanism is a unit which is provided with a nozzle which selectively spouts the liquid and a gas.

27. The exposure apparatus according toclaim 26, further comprising a liquid supply mechanism which supplies the liquid, and a flow passage-switching unit which switches flow passages for the liquid to be supplied from the liquid supply mechanism and the gas to be supplied from the nozzle of the liquid-removing mechanism.

28. The exposure apparatus according toclaim 25, further comprising a liquid-receiving member which is provided with a nozzle which spouts the gas, and an actuator which moves the liquid-receiving member relative to the projection optical system.

29. The exposure apparatus according toclaim 25, further comprising a system which selectively applies a positive or negative pressure to the substrate and which is provided for the gas-spouting section.

30. An exposure apparatus which exposes a substrate by forming a liquid immersion area on a part of the substrate and projecting an image of a pattern onto the substrate through a liquid in the liquid immersion area, the exposure apparatus comprising:

a projection optical system which projects the image of the pattern onto the substrate;

a substrate stage which is movable while holding the substrate;

a liquid supply mechanism which supplies the liquid onto the substrate to form the liquid immersion area;

a first liquid recovery mechanism which recovers the liquid from a surface of the substrate; and

a second liquid recovery mechanism which has a recovery port provided on the substrate stage and which recovers the liquid after completion of the exposure for the substrate.

31. The exposure apparatus according toclaim 30, wherein both of the first and second liquid recovery mechanisms recover the liquid after the completion of the exposure for the substrate.

32. The exposure apparatus according toclaim 30, wherein the first liquid recovery mechanism recovers the liquid simultaneously with the supply of the liquid by the liquid supply mechanism to form the liquid immersion area during the exposure for the substrate.

33. The exposure apparatus according toclaim 30, wherein the second liquid recovery mechanism recovers the liquid outflowed to outside of the substrate during the exposure for the substrate.

34. The exposure apparatus according toclaim 30, further comprising a liquid-removing mechanism which is different from the first and second liquid recovery mechanisms.

35. An exposure apparatus which exposes a substrate by projecting an image of a pattern onto the substrate through a liquid, the exposure apparatus comprising:

a projection optical system which projects the image of the pattern onto the substrate; and

a detection unit which detects a state of a surface of a part arranged in the vicinity of an image plane side of the projection optical system.

36. The exposure apparatus according toclaim 35, wherein the detection unit detects a foreign matter adhered to the surface of the part.

37. The exposure apparatus according toclaim 35, wherein the surface of the part includes a surface of an optical element disposed most closely to the image plane side of the projection optical system.

38. The exposure apparatus according toclaim 37, further comprising a washing unit which washes the surface of the optical element, and a control unit which controls the washing unit, wherein the control unit operates the washing unit in response to a result of the detection performed by the detection unit.

39. A method for producing a device, comprising using the exposure apparatus as defined inclaim 1.

40. A method for producing a device, comprising using the exposure apparatus as defined inclaim 30.

41. A method for producing a device, comprising using the exposure apparatus as defined inclaim 35.

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