US20060076272A1

Movatterモバイル変換

Info

Publication number: US20060076272A1
Application number: US10/520,400
Authority: US
Inventors: Jacob Stil
Original assignee: Individual
Current assignee: Shell USA Inc
Priority date: 2002-07-02
Filing date: 2002-07-02
Publication date: 2006-04-13
Also published as: CN1639306A; JP2005531673A; GB2405603A; EP1532229A1; GB0428282D0; WO2004005438A1; AU2002368080A1

Abstract

A method for gasification of a solid carboneous feed, wherein the gasification is performed in an elongated gasification reactor vessel having a gasifier unit, a co-axial positioned cooled channel through which the dust-loaded hot-gaseous product of the gasifier unit is discharged from the reactor, and means to supply a quench gas to the dust-loaded hot gaseous product at a position downstream of the gasifier unit, wherein to an annular space between the reactor vessel wall and the cooled channel a dust-free gas is supplied at a rate sufficient to ensure that no dust-loaded hot gas will flow from the cooled channel to the annular space.

Description

The invention is directed to a method for gasification of a solid carboneous feed, wherein said gasification is performed in an elongated gasification reactor vessel comprising a gasifier unit, a co-axial positioned cooled channel through which the dust-loaded hot-gaseous product of the gasifier unit is discharged from the reactor, and means to supply a quench gas to the dust-loaded hot gaseous product at a position downstream of said gasifier unit.
Such a process is described in U.S. Pat. No. 4,859,213. This publications describes a typical coal gasification process as performed in an elongated gasification reactor vessel comprising a gasifier unit, a co-axial positioned cooled channel through which the dust-loaded hot-gaseous product of the gasifier unit is discharged from the reactor, and means to supply a quench gas to the dust-loaded hot gaseous product at a position downstream of said gasifier unit. Pulverized coal from a coal feed system is fed into the gasifier unit via burners along with an oxygen containing gas. In the gasifier pulverized coal is partially oxidized with oxygen to a carbon monoxide-hydrogen comprising gas (syngas), further also referred to as product gas. Ash, in the form of slag, gravitates in the cooled channel into a slag bath tank located at the lower end of the elongated reactor. Product gas, containing dust and entrained liquid slag droplets, rises in the cooled channel to a quench section. The quenched product gas exits the gasification reactor via a duct into a waste heat boiler or syngas cooler. Solids are removed from the resultant cooled product gas in a so-called solids removal section. A portion of cleaned and cooled gas from the solids removal section is then fed back, by means of a recycle gas compressor, into the cooled channel as quench gas. The quench gas entering the cooled channel cools the product gas such that entrained fly slag particles are solidified and will not stick to the duct or waste heat boiler surfaces as the solids and gas pass through.
In the carbon gasification process, as for example disclosed in U.S. Pat. No. 4,859,213, a carboneous feed is transformed under high temperature and pressure into a hot product gas. Inert ash components contained in the carbon are partly discharged with the hot product gas stream from the gasification reactor in form of fine dust. Since the gasification pressures are up to 50 bar and higher, the components used in the gasification process, such as the gasification reactor, quench means, cooled channel, duct and the downstream heat exchanger heating surfaces, must be operated within a pressure wall which can be realized by one or more pressure containers or pressure mantles. To protect the pressure mantles of the reactor against the high syngas temperatures of over 1500° C., the quench tube and the cooled channel are provided with water-cooled cooling surfaces. The dust-loaded hot product gas is cooled with cold quench gas supplied from a quench gas supply unit to a temperature of approx. 900° C. A further cooling takes place in one or more heat exchanger surfaces downstream said quench unit whereby steam is produced.
Between the gasifier unit, the quench unit, and the cooled channel and the pressure wall of the gasification reactor an annular space is created as is also shown in U.S. Pat. No. 4,859,213.
The cooling surfaces of the cooled channel can only withstand small gas-side pressure differences. The pressure between the interior of the cooled channel and the annular space has therefore substantially to be compensated. Openings which fluidly connect the cooled channel and the annular space are for example sliding points in the wall of the cooled channel for compensating thermal expansions and the openings at the quench unit.
To this end it is known from the speech “Criteria for Design of Gasifier and Syngas Cooler” of Dr. G. Keintzel and Dipl.-Ing. Gawlowski, held at the conference EPOS 2000—International Conferencce on Efficiency, Cost, Optimisation, Simulation and Environmental Aspects of Energy and Process Systems, Jul. 5-7, 2000, University of Twente, Enschede, The Netherlands, Figure “Heating Surfaces in the Syngas Cooler”, to make the sliding point associated with the cooled channel open or to provide it with gas-permeable plugs, in order to thereby achieve a pressure compensation at least at a hot-gas guiding channel segment separated from the pressure wall by gas barriers. Therefore, during pressure compensation dust-loaded hot-product gas enter the annular space. In a carbon gasification plant of industrial scale it has been found that an undesired flow on the gas side occurs in the annular space charged with gas, i.e. a so-called secondary flow, since the hot-gas can cool down at the side of the cooling surface oriented towards the annular space and at the pressure wall, and cooled gas can flow back via the sliding point into the cooled channel. In this way an undesired heating up of regions of the respective pressure wall and setting of dust occurs. This can lead to operation failures.
It is an objective of the present to provide a gasification process as generally described above wherein dust loaded product gas cannot enter the annular space and therefore dust depositions are avoided.
The following process achieves this object. A method for gasification of a solid carbonaceous feed, wherein said gasification is performed in an elongated gasification reactor vessel comprising a gasifier unit, a co-axial positioned cooled channel through which the dust-loaded hot-gaseous product of the gasifier unit is discharged from the reactor, and means to supply a quench gas to the dust-loaded hot gaseous product at a position downstream of said gasifier unit, wherein to an annular space between the reactor vessel wall and the cooled channel a dust-free gas is supplied at a rate sufficient to ensure that no dust-loaded hot gas will flow from the cooled channel to said annular space.
Applicants have found that by supplying such a dust free gas to said annular space no dust loaded hot product gas will pass via the openings, such as at the cited sliding points and at the quench supply means, in the wall of the cooled channel. A so-called positive flow of dust-free gas will exist from the annular space into the cooled channel. To arrive at such a positive flow the rate of dust-free gas as supplied to said annular space is preferably such that the pressure in said annular space is at least equal or just higher than the pressure in said cooled channel. The above is also referred to as a method for pressure compensation.
Also here an inadmissible heating up of the pressure wall cannot take place since a secondary flow is effectively suppressed. Therefore no substantial quantities of dust can settle in the annulus surrounding the heat exchanger heating surfaces.
While with the earlier proposed charging of the annulus with the dust-loaded hot gas the pressure within the annulus is kept somewhat lower than in the gas interior, the method of the invention intends to charge the annulus with the quench gas in such a way that the gas pressure within the annulus is equal to or somewhat higher than the gas pressure in the gasifier unit and channel.
The temperature of the dust-free gas is preferably between 200 and 350° C. and more preferably below 300° C.
The dust-free gas is preferably part of the gaseous product of the gasifier unit from which dust has been removed downstream of said gasification reactor, for example the dust free product gas as obtained in the solids removal section. Because this dust-free product gas is also preferably used as quench gas it has been found advantageous to combine the supply of the dust-free gas to the annular space with the supply of quench gas to the cooled channel. In this preferred embodiment the means to supply quench gas is preferably provided with gas discharge openings to supply quench gas to the cooled channel and gas discharge openings to supply quench gas to the annular space. It has been found that by providing sufficient openings in said means to supply quench gas a robust and reliable operation is achieved. One skilled in the art will be able to easily determine the area of these openings given the pressure level of the quench gas and the pressure level in the cooled channel.
In a preferred embodiment any sliding points present in the cooled channel are rendered gas-tight with respect to the hot-product gas guided in the cooled channel. With the method of the invention the pressure compensation function is separated from the function of the sliding point, since the quench gas used for pressure compensation is introduced from the quench unit between the gasification reactor and the quench tube into the annulus.
In this way the pressure compensation function is also separated from the other two functions attributable to the sliding point, i.e. is the expansion function and the assembling separation function. Preferably one or more gas barriers can be situated in the area of small differential expansions between the respective pressure wall and the respective cooled component so that the secondary function of compensating substantial differential expansions in the axial direction of the components at the sliding point is omitted.
Furthermore, it is useful that the annulus present in the syngas cooler, which is confined by the at least one heat exchanger surface and the pressure wall surrounding it and which is closed against the annulus charged with quench gas, is charged with cooled hot-gas.
The present invention is also directed to an elongated gasification reactor vessel, which may be used in the above described process, comprising a gasifier unit, a co-axial positioned cooled channel through which the dust-loaded hot-gaseous product of the gasifier unit is discharged from the reactor, and means to supply a quench gas to the dust-loaded hot gaseous product at a position downstream of said gasifier unit, wherein also means to supply a dust-free gas to an annular space between the reactor vessel wall and the cooled channel is present. Preferably the means to supply quench gas is provided with gas discharge openings to supply the majority of the quench gas to the cooled channel and gas discharge openings to supply a minor amount of quench gas to the annular space. The means for supplying the quench gas are usually holes (exit openings), the size of which determining the quantity of gas passing to the quench tube and the annulus, respectively.
Preferably the cooled channel is provided with sliding points which are rendered gas-tight with respect to the hot-gas guided in the cooled channel.
Preferably, there is one or more sliding points in the cooled channel downstream of said quench gas supply unit. Such sliding points are present between two cooled channel segments and/or at the end of the cooled channel. Preferably an annular barrier for closing the annular space is situated downstream of said sliding points.
It is useful that a further sliding point is provided in the area of the connection path and this sliding point is preferably associated with an enlargement of the pressure mantle in order to be able to better use the function of the assembling separation in the area of the sliding point.
As said before, in known carbon gasification plants at least one heat exchanger heating surface surrounded by a pressure wall is connected downstream of the cooled channel in order to further cool down the gas (product gas). In this connection it is useful that a sliding point is provided between the cooled channel and the heat exchanger heating surface and that the annular barrier for closing the annulus downstream of the sliding point is situated upstream or downstream of the heat exchanger heating surface.
Usually several heating surfaces connected one after the other at the gas side are used, which are surrounded by the same pressure wall. Preferably, the pressure compensation takes place between the gas interior in the heat exchanger heating surfaces and the surrounding annulus with dust-loaded hot-gas previously cooled down in the heat exchanger heating surfaces. Due to the substantially lower temperatures as compared to the temperatures in the area of the hot-gas guiding channel secondary flows and hence massive dust settlement in the annulus cannot occur anymore.
In case of a plurality of heat exchanger heating surfaces it is useful to insert a gas-tight sliding point between at least two adjacent heating surfaces.
The invention will now be described in connection with the enclosed drawings. In the drawings:
FIG. 1 shows an embodiment of the carbon gasification plant wherein the gasifier unit is situated in a first pressure container (gasification reactor) and the heat exchanger heating surfaces are situated in a second pressure container (syngas cooler), wherein the two pressure containers are connected through a rising connection path (so-called duct); and
FIG. 2 shows a representation of a further embodiment comparable toFIG. 1, with an inclined connection path (duct).
The gasification plant depicted inFIG. 1 consists of agasification reactor1, aconnection duct2 and asyngas cooler3. Thegasification reactor1 comprises a vertically orientedelongated pressure container4 in which a cooledchannel5,7 and a quench gas supply unit6 are located. Thegasifier unit8 is supplied with a carboneous feed, for example pulverized coal. The quench gas supply unit6 is fed with quench gas Q at9. Quenched hot-product gas HG flows in the cooledchannel part7 downstream the quench gas supply unit6. The cooled channel is provided with cooling surfaces. Preferably these cooling surfaces are bundles of conduits through which cooling water flows. A preferred cooling surface is the membrane wall as disclosed in for example U.S. Pat. No. 4,859,213.
The lower end of thegasification reactor1 is provided with a gas barrier10. Furthermore, slag S is discharged at thelower end11 of thegasification reactor1. Thepressure container4 consists of a lower part4aand an upper part4bwith an angled flange4c. Thepressure mantle12 connects thereto. Thesyngas cooler3 comprises a pressure container13 consisting of threecontainer parts13a,13b,13c. The pressure container part13 comprises anangled flange13doriented downwards which defines, together with flange4candpressure mantle12, theconnection path2. Within thegas cooler3 there are e.g. three heat exchanger heating surfaces14 situated one above the other, as seen in the direction of flow of the hot-gases HG. The heating surfaces are only shown schematically and can be e.g. in the form of heating surfaces with a cooled gas guiding mantle14aand straight or winding tube interiors14b. In the embodiment shown the gas guiding mantles14aof the two upper heating surfaces are connected together to form agas guiding mantle15 which is connected to thegas guiding mantle17 of the lower heating surface via a gas-tight slidingpoint16.
The connection between the cooledchannel part7 and thegas guiding mantle15 is made via a hot-gas guiding channel18 which extends in a curved portion18ainto thepressure container4, in a straight portion18bthrough thepressure mantle12 and theflange13d, and which is formed in its last portion as agas deflection chamber18c.
The gas-guidingchannel18 is provided at its entrance end with a slidingpoint19, which allows a sliding movement relative to the quenchtube7, which is provided with an enlargement7aat its exit end. This enlargement is schematically shown as a simple cone.
The opposing ends of cooledchannel part7 andgas guiding channel18 are provided withcompensator holders20 and21 between which aring compensator22 extends so that the slidingpoint19 is gas-tight with respect to the hot hot-gas exiting from the quench tube. In theconnection path2 in the area of thepressure mantle12 there is provided a further sliding point23 between two portions S1 and S2 of the gas-guidingchannel18, the portion S1 having an enlargement at its exit end. The sliding point23 corresponds in its design to the slidingpoint19.
Between the exit end of thegas guiding channel18 situated in thegas cooler3 and the entrance to thegas guiding mantle15 there is provided a further slidingpoint24 which differs in design from the slidingpoints19 and23 in that the enlargement15a, as seen in the direction of gas flow, is not disposed at the exit end of thegas guiding channel18 but at the entrance end of the guidingmantle15. The slidingpoint15 corresponds in its design to the slidingpoint24.
It is possible to dispose the enlargement for the slidingpoints19 and23 also at the other gas-guiding element. Equally, at the slidingpoints16 and24 the enlargement can be provided at the downstream entrance end of the gas guiding section.
As shown inFIG. 1, thegasification reactor5, the cooledchannel part7, thegas guiding channel18, thegas guiding mantle15 and thegas guiding mantle17 are surrounded by an annulus25 defined by thepressure container4, thepressure mantle12 and the pressure container13. This annulus is confined on the one hand by the annular barrier10 in thegasifier unit1 and is subdivided by anannular barrier26, which is situated between the slidingpoint24 and theupper heating surface14, into twopartial annulus25aand25b.
Since the slidingpoints19,23, and24 are gas-tight with respect to the dust-loaded hot-gases guided within the gas interior, in regular operation no dust-loaded hot-gas can enter theannulus25a.
For pressure compensation between the gas interior ofgasification reactor1, cooledchannel part7, andgas guiding channel18, theannulus25ais charged with quench gas Q which exits via exit openings27 from the quench gas supply unit6 into theannulus25a. The geometry of the exit openings27 is selected in correspondence with the pressures such that the pressure inannulus25ais equal to or somewhat higher than the gas pressure of the hot-gas in the gas interior. Since the quench gas enters the annulus with a substantially lower temperature (e.g. 250° C.) than the temperature of the hot-gases in the gas-guiding channel18 (e.g. 900° C.) a critical heating up of the respective pressure walls cannot take place. Since the quench gas is free of dust, dust settlement cannot occur.
The annulus25bdownstream of theannular barrier26 is charged backwards and upwards by the already partly cooled down hot-gas exiting the lower end of thegas guiding mantle17 which is cooled down e.g. to 300-250° C.
Since the annulus25bis charged with still dust-loaded but substantially cooler gas, secondary flows due to rising and subsequently cooling down hot-gas streams cannot occur.
As shown inFIG. 1 in broken lines thepressure mantle12 can have an enlargement12a, which allows entering the sliding point23 via an entrance opening12bfor inspection purposes.
It is also possible to dispose theannular barrier26 downstream of one of the heating surfaces14 and thus to enlarge theannulus25a. It is also conceivable to dispose theannular barrier26 above the slidingpoint24.
The embodiment ofFIG. 2 differs from the embodiment ofFIG. 1 in that the connection path between thegasifier1 and thegas cooler3 is not rising, but falling. The two general designs according toFIGS. 1 and 2 with rising or fallingconnection path12 are also known from theFIGS. 1 and 2 of U.S. Pat. No. 4,859,214. Also in the embodiment ofFIG. 2 an enlargement12acan be provided for. Other connection paths are also possible, for instance horizontal or curved paths.
Thus, in both embodiments the annulus25 confined between the components and the pressure walls is not charged with hot-gas exiting from the quench tube at any point but with cold gas, i.e. on the one hand in form of the quench gas Q and on the other hand with already cooled down hot-gas. The charged spaces are separated by a barrier from one another in order to avoid a short-circuit between quench gas and cooled-down hot-gas. The position of the annular barrier, as seen in the direction of flow of the hot-gas, can be variable.
FIG. 3 shows the quench supply unit6 in more detail. The quench supply unit is an modified quench supply unit as described inFIGS. 3 and 3aof U.S. Pat. No. 4,859,213. The modification lies in that openings27 are added through which quench gas can enter the annular space25.FIG. 3 also shows part of themembrane wall45 of cooledchannel5,7, openings53 to supply quench gas into the cooledchannel5,7 and part of thesupply conduit9.

Claims

1. A method for gasification of a solid carboneous feed, wherein said gasification is performed in an elongated gasification reactor vessel comprising: a gasifier unit;

a co-axial positioned cooled channel through which the dust-loaded hot-gaseous product of the gasifier unit is discharged from the reactor; and,

means to supply a quench gas to the dust-loaded hot gaseous product at a position downstream of said gasifier unit, wherein to an annular space between the reactor vessel wall and the cooled channel a dust-free gas is supplied at a rate sufficient to ensure that no dust-loaded hot gas will flow from the cooled channel to said annular space.

2. The method ofclaim 1, wherein the pressure in the annular space is equal or higher than the pressure in the cooled channel.

3. The method ofclaim 2, wherein the temperature of the dust-free gas is between 200 and 350° C.

4. The method ofclaim 3, wherein the dust-free gas is part of the gaseous product of the gasifier unit from which dust has been removed downstream said gasification reactor.

5. The method ofclaim 4, wherein the dust-free gas is part of the quench gas.

6. The method ofclaim 5, wherein the means to supply quench gas is provided with gas discharge openings to supply quench gas to the cooled channel and gas discharge openings to supply quench gas to the annular space.

7. An elongated gasification reactor vessel comprising:

a gasifier unit;

means to supply a quench gas to the dust-loaded hot gaseous product at a position downstream of said gasifier unit, wherein also means to supply a dust-free gas to an annular space between the reactor vessel wall and the cooled channel is present

8. The reactor ofclaim 7, wherein the means to supply quench gas is provided with gas discharge openings to supply quench gas to the cooled channel and gas discharge openings to supply quench gas to the annular space.