BACKGROUND OF THE INVENTION 1. Field of the Invention
The present invention relates generally to semiconductor devices and manufacturing methods thereof, and more particularly, to a semiconductor device including a plurality of field effect transistors and a manufacturing method thereof.
2. Description of the Background Art
In recent years, as semiconductor devices came to be more densely integrated and reduced in size, 2-power supply devices having external voltage of a conventional level and internal voltage of a lower level have been proposed.
FIG. 79 is a cross sectional view showing such a conventional 2-power supply semiconductor device including a plurality of field effect transistors.
Referring toFIG. 79, the conventional 2-power supply semiconductor device include a first field effect transistor supplied with first power supply voltage (low Vdd) and a second field effect transistor supplied with second power supply voltage (high Vdd) higher than low Vdd formed on a main surface of a ptype semiconductor substrate101 and spaced apart from each other. Anisolation oxide film102 is formed between the first and second field effect transistors.
In the low Vdd region, a pair of first source/drain regions110 and a pair of low concentrationimpurity diffusion regions108 are formed spaced apart from each other on the main surface ofsemiconductor substrate101 having a first channel region therebetween. Low concentration, n typeimpurity diffusion region108 formed adjacent to the first channel region and high concentration, n typeimpurity diffusion region110 formed adjacent to n typeimpurity diffusion region108 constitute an LDD (Lightly Doped Drain) structure. A first gateinsulating film106 is formed on the first channel region. Afirst gate electrode118 is formed on firstgate insulating film106. Asidewall oxide film109 is formed on a side offirst gate electrode118. The first field effect transistor supplied with low Vdd is formed of first source/drain regions110,impurity diffusion regions108, first gateinsulating film106, andfirst gate electrode118.
In the high Vdd region, a pair of second source/drain regions117 and a pair of low concentrationimpurity diffusion regions116 are formed on the main surface ofsemiconductor substrate101, spaced apart from each other and having a second channel region therebetween. Second source/drain region117 and low concentrationimpurity diffusion region116, in other words low concentration n typeimpurity diffusion region116 formed adjacent to the second channel region and high concentration, n typeimpurity diffusion region117 formed adjacent to n typeimpurity diffusion region116 constitute an LDD structure. A secondgate insulating film104 is formed on the second channel region. Firstgate insulating film106 is formed on secondgate insulating film104. Asecond gate electrode119 is formed on firstgate insulating film106. Asidewall oxide film120 is formed on a side ofsecond gate electrode119. Second source/drain regions117 andimpurity diffusion region116, second gateinsulating film104, first gateinsulating film106 andfirst gate electrode119 form the second field effect transistor supplied with high Vdd. Thegate insulating films104 and106 of the second field effect transistor supplied with high Vdd should be thicker than the first gateinsulating film106 of first field effect transistor supplied with low Vdd.
Referring to FIGS.80 to86, a method of manufacturing the conventional 2-power supply semiconductor device will be now described.
Isolation oxide film102 is formed on the main surface ofsemiconductor substrate101 to surround an active region. Secondgate insulating film104 is formed on the active region on the main surface ofsemiconductor substrate101. Aresist pattern105ais formed on secondgate insulating film104 positioned in the high Vdd region and onisolation oxide film102. The structure as shown inFIG. 80 is thus obtained.
An isotropic etching is performed usingresist pattern105aas a mask to remove secondgate insulating film104 positioned in the low Vdd region to obtain the structure as shown inFIG. 81.Resist pattern105ais then removed.
As shown inFIG. 82, first gateinsulating film106 is formed on the main surface ofsemiconductor substrate101 and on second gateinsulating film104.
A first doped polysilicon film103 (seeFIG. 83) is deposited on first gateinsulating film106 andisolation oxide film102.Resist patterns105band105care formed on the regions of first dopedpolysilicon film103 to be first andsecond gate electrodes118 and119 (seeFIG. 79). The structure as shown inFIG. 83 is thus obtained.
Then, usingresist patterns105band105cas masks, an anisotropic etching is performed to remove a part of first dopedpolysilicon film103, and first andsecond gate electrodes118 and119 are formed as a result.Resist patterns105band105care then removed. The structure as shown inFIG. 84 is thus obtained. The gate insulating film portion of the second field effect transistor formed of first and second gateinsulating films106 and104 can be made thicker than the firstgate insulating film106 of the first field effect transistor. Thus, the breakdown voltage of the second field effect transistor can be greater than the breakdown voltage of the first field effect transistor, so that the second field effect transistor may be supplied with voltage higher than the first field effect transistor.
As shown inFIG. 85, an n type impurity is introduced into a prescribed region of the main surface ofsemiconductor substrate101 to form low concentration n typeimpurity diffusion regions108 and116.
Sidewall oxide films109 and120 (seeFIG. 86) are formed on sides of first andsecond gate electrodes118 and119. An n type impurity is then introduced into a prescribed region of the main surface ofsemiconductor substrate101 to form high concentration n typeimpurity diffusion regions110 and117 as shown inFIG. 86.
The conventional 2-power supply semiconductor device is manufactured as described above.
In the manufacture of the 2-power supply semiconductor device,resist pattern105ais directly formed on second gateinsulating film104 positioned in the high Vdd region. In the following removal ofresist pattern105a, defects (local irregularities) are sometimes generated in the surface of second gateinsulating film104. A light etching processing for removingresist pattern105ais directly performed to the surface of secondgate insulating film104, second gateinsulating film104 may be reduced in thickness. The defects in the surface of secondgate insulating film104 and the reduction in thickness lead to a reduction in the breakdown voltage of secondgate insulating film104, and as a result electrical characteristics of the semiconductor device including the field effect transistor deteriorate.
As a countermeasure, a manufacturing method as shown in FIGS.87 to93 has been proposed.
Referring to FIGS.87 to93, the proposed conventional method of manufacturing a 2-power supply semiconductor device including a plurality of field effect transistors will be described.
Isolation oxide film102 is formed on the main surface of ptype semiconductor substrate101 to surround an active region. Secondgate insulating film104 is formed on the active region in the main surface of ptype semiconductor substrate101. First dopedpolysilicon film103 is formed on secondgate insulating film104 andisolation oxide film102.Resist pattern105ais formed on the region of firstdoped polysilicon film103 to be second gate electrode119 (seeFIG. 88) positioned in the high Vdd region to obtain the structure as shown inFIG. 87.
An anisotropic etching is performed usingresist pattern105aas a mask to etch away a part of first dopedpolysilicon film103, andsecond gate electrode119 as shown inFIG. 88 results.Resist pattern105ais then removed.Resist pattern105bis formed on second gateinsulating film104 positioned in the high Vdd region andsecond gate electrode119 to form the structure as shown inFIG. 88.
In the manufacture,second gate electrode119 is formed on second gateinsulating film104 and thenresist pattern105bis formed.Resist pattern105bis not directly formed on the region of the surface of secondgate insulating film104 in contact withsecond gate electrode119. Thus, defects in the surface of secondgate insulating film104 as in the manufacturing method shown in FIGS.80 to86 can be prevented.
Then, as shown inFIG. 89, second gateinsulating film104 positioned in the low Vdd region is removed by an isotropic etching. Then,resist pattern105bis removed.
As shown inFIG. 90, a silicon oxide film to be firstgate insulating film106 is formed on the main surface of ptype semiconductor substrate101 positioned in the low Vdd region and on second gateinsulating film104 andsecond gate electrode119.
Then, on first gateinsulating film106 andisolation oxide film102, a second doped polysilicon film107 (seeFIG. 91) is formed by means of CVD.Resist pattern105c(seeFIG. 91) is formed on the region of second dopedpolysilicon film107 to be first gate electrode118 (seeFIG. 93). The structure as shown inFIG. 91 is thus obtained.
An anisotropic etching is performed using resistpattern105cas a mask to remove a part of second dopedpolysilicon film107, and first gate electrode118 (seeFIG. 92) is formed as a result. After the anisotropic etching, a part of second dopedpolysilicon film107 also remains on a side ofsecond gate electrode119. Resistpattern105cis then removed. Resistpattern105d(seeFIG. 92) is formed on firstgate insulating film106 positioned in the low Vdd region and onfirst gate electrode118. Thus, the structure as shown inFIG. 92 results.
Second dopedpolysilicon film107 remaining on the side of second gate electrode is removed by an isotropic etching, and then resistpattern105dis removed. After low concentration, n typeimpurity diffusion regions108,116 (seeFIG. 93) are formed by introducing an impurity,sidewall oxide films109,120 (seeFIG. 93) are formed, followed by formation of high concentration n typeimpurity diffusion regions110,117 (seeFIG. 93), and the semiconductor device as shown inFIG. 93 results.
In the manufacture of the proposed conventional 2-power supply semiconductor device as shown in FIGS.87 to93,second gate electrode119 is formed before resistpattern105bis formed as shown inFIG. 88, in order to prevent defects from being formed in the surface of secondgate insulating film104. In the manufacture of the 2-power supply semiconductor device, however, in the step as shown inFIG. 90, during forming firstgate insulating film106,second gate electrode119 formed of doped polysilicon is oxidized in anend123 of the contact portion betweensecond gate electrode119 and secondgate insulating film104 as shown inFIG. 94. Therefore, asilicon oxide film124 grows along the contact surface between secondgate insulating film104 andsecond gate electrode119. Thus grown silicon oxide film is called “gate bird's beak”. Herein,FIG. 94 is an enlarged view ofregion110 shown inFIG. 90. The gate oxide film having a “gate bird's beak” formed of an oxide film is poor in quality and difficult to control in thickness. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors deteriorate.
SUMMARY OF THE INVENTION The present invention is directed to a solution to the above-described problems. It is one object of the invention to provide a semiconductor device which can prevent electrical characteristics of the device from deteriorating by preventing the deterioration of the quality of a gate insulating film.
Another object of the invention is to provide a semiconductor device which can prevent a gate bird's beak from being generated.
Yet another object of the invention is to provide a method of manufacturing a semiconductor device which can prevent the deterioration of the quality of a gate insulating film.
A semiconductor device according to one aspect of the invention having a plurality of field effect transistors includes first and second field effect transistors.
The first field effect transistor includes a pair of first source/drain regions, a first gate insulating film, and a first gate electrode. The second field effect transistor includes a pair of second source/drain regions, a second gate insulating film, and a second gate electrode. The first source/drain regions are formed, on a main surface of a semiconductor substrate, spaced apart from each other and having a first channel region therebetween. The first gate insulating film is formed on the first channel region in a first thickness. The second source/drain regions are formed on the main surface of the semiconductor substrate, spaced apart from each other and having a second channel region therebetween. The second gate insulating film is formed on the second channel region in a second thickness larger than the first thickness. The second gate electrode is formed on the second gate insulating film. An oxidation protection film to prevent one of the first and second gate electrodes from being oxidized is formed on a side of one of the gate electrodes. In the semiconductor device according to this aspect, the oxidation protection film to prevent the gate electrode from being oxidized is formed on a side of one of the first and second gate electrodes, and therefore an oxidizing step to form a gate insulating film of another field effect transistor may be performed while the oxidization protection film is formed on a side of that one gate electrode. As a result, the lower part of the side of the gate electrode can be prevented from being oxidized, and a gate bird's beak can be avoided. Thus, the threshold voltages of the field effect transistors can be prevented from increasing. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
A semiconductor device according to another aspect of the invention having a plurality of field effect transistors includes first and second field effect transistors.
The first field effect transistor includes a pair of first source/drain regions, a first gate insulating film, and a first gate electrode. The second field effect transistor includes a pair of second source/drain regions, a second gate insulating film, and a second gate electrode. The first source/drain regions are formed, on a main surface of a semiconductor substrate, spaced apart from each other and having a first channel region therebetween. The first gate insulating film has a first thickness and is formed on the first channel region to include an oxide nitride film. The first gate electrode is formed on the first gate insulating film. The second source/drain regions are formed, on the main surface of the semiconductor substrate, spaced apart from each other and having a second channel region therebetween. The second gate insulating film is formed on the second channel region and has a second thickness larger than the first thickness. The second gate electrode is formed on the second gate insulating film.
In the semiconductor device according to this aspect, since the first gate insulating film is formed to include the oxide nitride film, in the manufacturing process which will be described, in the presence of the second gate electrode, during forming the oxide nitride film to be the first gate insulating film, an end of the second gate electrode can be prevented from being excessively oxidized in the contact portion between a lower part of a side of the second gate electrode and the second gate insulating film. Thus, as a result, the lower part of the side of the gate electrode can be prevented from being oxidized, and a gate bird's beak can be avoided. Thus, the threshold voltages of the field effect transistors can be prevented from increasing. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating. Furthermore, since the first gate insulating film is formed to include the oxide nitride film, the first gate insulating film may be formed thinner with a prescribed breakdown voltage being maintained than the case of using a conventional silicon oxide film or the like. As a result, the driving voltage of the first field effect transistor may be reduced.
A semiconductor device according to another aspect of the invention having a plurality of field effect transistors includes first and second field effect transistors. The first field effect transistor includes a pair of first source/drain regions, a first gate insulating film, and a first gate electrode. The second field effect transistor includes a pair of second source/drain regions, a second gate insulating film, and a second gate electrode. The first source/drain regions are formed, on a main surface of a semiconductor substrate, spaced apart from each other and having a first channel region therebetween. The first gate insulating film is formed on the first channel region and has a first thickness. The first gate electrode is formed on the first gate insulating film. The second source/drain regions are formed, on the main surface of the semiconductor substrate, spaced apart from each other and having a second channel region therebetween. The gate insulating film is formed on the second channel region and has a second thickness larger than the first thickness. The second gate electrode is formed on the second gate insulating film. An anti-oxidation conductive film is formed on at least one of the first and second gate insulating films.
In the semiconductor device according to this aspect, the anti-oxidation conductive film is formed on at least one of the first and second gate insulating films, it is not necessary to form a resist pattern directly on the surface of one of the first and second gate insulating films in the following manufacturing steps. Furthermore, before forming one of the first and second gate electrodes, an oxidizing step to form the other one of the first and second gate insulating films may be performed using the anti oxidation conductive film. Thus, in the step of oxidizing the first gate insulating film, a lower part of the side of one of the first and second gate electrodes can be prevented from being oxidized, and a gate bird's beak can be avoided. Thus, the threshold voltages of the field effect transistors can be prevented from increasing. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
Furthermore, since the anti-oxidation conductive film is formed on one of the first and second gate insulating films, a resist pattern will not be formed directly on one of the first and second gate insulating films in the following manufacturing steps. As a result, defects such as local irregularities in the gate insulating film as formed during removing the resist pattern can be avoided. Therefore, the threshold voltages of the field effect transistors may be prevented from fluctuating. Electrical characteristics of the semiconductor device including the plurality of field effect transistors may be prevented from deteriorating.
In the semiconductor device according to this aspect, a semiconductor film having a conductive impurity may be formed at a position between the anti-oxidation conductive film and at least one of the first and second gate insulating films.
Thus, when voltage is supplied to one of the first and second gate electrodes having the semiconductor film including the conductive impurity, the formation of a depletion layer caused by a reduction in the concentration of the conductive impurity in the vicinity of one of the first and second gate insulating films may be prevented. As a result, the fluctuation of the threshold voltages of the field effect transistors caused by the formation of such a depletion layer can be prevented. Therefore, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
A semiconductor device according to another aspect of the invention having a plurality of field effect transistors includes first and second field effect transistors.
The first field effect transistor includes a pair of first source/drain regions, a first gate insulating film, and a first gate electrode. The second field effect transistor includes a pair of second source/drain regions, a second gate insulating film, and a second gate electrode. The first source/drain regions are formed, on a main surface of a semiconductor substrate, spaced apart from each other and having a first channel region therebetween. The first gate insulating film is formed on the first channel region and has a first thickness. The first gate electrode is formed on the first gate insulating film. The second source/drain regions are formed, on the main surface of the semiconductor substrate, spaced apart from each other and having a second channel region therebetween. The second gate insulating film is formed on the second channel region and has a second thickness. The second gate electrode is formed on the second gate insulating film. A semiconductor film having a conductive impurity is formed on and in contact with at least one of the first and second gate insulating films. An anti-oxidation insulating film for preventing the semiconductor film having the conductive impurity from being oxidized is formed on the semiconductor film.
Since the semiconductor film having the conductive impurity is thus formed on and in contact with one of the first and second gate insulating films, it is not necessary to form a resist pattern directly on a surface of one of the first and second gate insulating films in the manufacture of the semiconductor device. Furthermore, before one of the first and second gate electrodes is formed, an oxidizing step to form the other one of the first and second gate insulating films may be performed using the anti-oxidation insulating film as a mask. In the step of oxidizing the gate insulating films, a lower part of a side of the gate electrodes can be prevented from being oxidized as a result, and a gate bird's beak can be avoided. Thus, the threshold voltages of the field effect transistors can be prevented from increasing. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
Furthermore, the semiconductor film having the conductive impurity is formed on and in contact with one of the first and second gate insulating films, a resist pattern is not formed directly on one of the first and second gate insulating films. As a result, defects such as local irregularities in the gate insulating films as formed during removing the resist pattern can be avoided. Therefore, the threshold voltages of the field effect transistors may be prevented from fluctuating. Electrical characteristics of the semiconductor device including the plurality of field effect transistors may be prevented from deteriorating. Furthermore, when voltage is supplied to one of the first and second gate electrodes having the semiconductor film including the conductive impurity, the formation of a depletion layer caused by a reduction in the concentration of the conductive impurity in the vicinity of one of the first and second gate insulating films may be prevented. As a result, the fluctuation of the threshold voltages of the field effect transistors caused by the formation of such a depletion layer can be prevented. Therefore, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
A semiconductor device according to another aspect of the invention having a plurality of field effect transistors includes first and second field effect transistors.
The first field effect transistor includes a pair of first source/drain regions, a first gate insulating film, and a first gate electrode. The second field effect transistor includes a pair of second source/drain regions, a second gate insulating film, and a second gate electrode. The second gate electrode has a first conductive film, an insulating film and a second conductive film. The first source/drain regions are formed, on a main surface of a semiconductor substrate, spaced apart from each other and having a first channel region therebetween. The first gate insulating film is formed on the first channel region and has a first thickness. The first gate electrode is formed on the first gate insulating film. The second source/drain regions are formed, on the main surface of the semiconductor substrate, spaced apart from each other and having a second channel region therebetween. The second gate insulating film is formed on the second channel region and has a second thickness. The first conductive film to be a part of the second gate electrode is formed on the second gate insulating film. The insulating film to be a part of the second gate electrode is formed on the first conductive film. The second conductive film to be a part of the second gate electrode is formed on the insulating film.
Thus, the second gate electrode has the first conductive film, the insulating film, and the second conductive film, and therefore an oxidizing step for forming the first gate insulating film can be performed before forming the second gate electrode without forming a resist pattern directly on the surface of the second gate insulating film. As a result, a lower part of a side of the gate electrode can be prevented from being oxidized, and a gate bird's beak can be avoided. Thus, the threshold voltages of the field effect transistors can be prevented from increasing. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
A semiconductor device according to another aspect of the invention having a plurality of field effect transistors includes first and second field effect transistors.
The first field effect transistor includes a pair of first source/drain regions, a first gate insulating film, and a first gate electrode. The second field effect transistor includes a pair of second source/drain regions, a second gate insulating film, and a second gate electrode. The first source/drain regions are formed, on a main surface of a semiconductor substrate, spaced apart from each other and having a first channel region therebetween. The first gate insulating film is formed on the first channel region and has a first thickness. The first gate electrode is formed on the first gate insulating film. The second source/drain regions are formed, on the main surface of the semiconductor substrate, spaced apart from each other and having a second channel region therebetween. The second gate insulating film is formed on the second channel region and has a second thickness larger than the first thickness. The second gate electrode is formed on the second gate insulating film. A protection conductive film is formed on and in contact with at least one of the first and second gate insulating films.
Thus, the protection conductive film is formed on and in, contact with one of the first and second gate insulating films, it is not necessary to form a resist pattern directly on the surface of one of the first and second gate insulating films. Furthermore, before forming one of the first and second gate electrodes, an oxidizing step for forming the other one of the first and second gate insulating films can be performed using the protection conductive film. Thus, in the step of oxidizing the gate insulating films, a lower part of a side of one of the first and second gate electrodes can be prevented from being oxidized, and a gate bird's beak can be avoided. Thus, the threshold voltages of the field effect transistors can be prevented from increasing. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
In the semiconductor device according to this aspect, the protection conductive film includes first and second protection conductive films. The first protection conductive film may be formed on and in contact with the first gate insulating film, while the second protection conductive film may be formed on and in contact with the second gate insulating film. The first and second protection conductive films may be substantially equal in thickness.
Thus, during etching the first and second protection conductive films to form the first and second gate electrodes, the part of the thickness of the first and second protection conductive films to be removed by the etching can be made substantially equal in the regions to form the first and second gate electrodes. As a result, during the etching for forming the first and second gate electrodes, the amount of etching for forming the first gate electrode can be substantially the same as the amount of etching for forming the second gate electrode. Therefore, the amount of overetching during forming the first and second gate electrodes can be reduced. As a result, the semiconductor substrate or the like positioned under the protection conductive films to be etched away can be prevented from being damaged by overetching. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
The semiconductor device according to this aspect may further include a protection conductive film formed by depositing a film having an amorphous structure. Thus, the film having the amorphous structure is free from grain boundaries, and therefore during isotropically etching the protection conductive film in the manufacture of the semiconductor device, damages to the gate insulating film positioned under the protection conductive film caused by the isotropic etching agent running along grain boundaries can be prevented. As a result, the fluctuation of the threshold voltages of the field effect transistors can be prevented. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented.
In the semiconductor device according to this aspect, an anti-oxidation film may be formed on and in contact with the protection conductive film. Thus, in the manufacture of the semiconductor device, a natural oxide film difficult to control in thickness can be prevented from being formed on the protection conductive film. Thus, in an etching step to form the first and second gate electrodes, the variation of the thickness of the protection conductive film to be etched away caused by the formation of such a natural oxide film can be prevented. As a result, during etching for forming the first and second gate electrodes, the variation of the thickness of the protection conductive film to be etched away can be reduced, the amount of overetching, can be reduced. As a result, damages to the semiconductor substrate or the like positioned under the protection conductive film to be etched away, caused by overetching can be prevented.
In a method of manufacturing a semiconductor device according to another aspect of the invention, a first gate insulating film having a first thickness is formed on a main surface of a semiconductor device. A first gate electrode is formed on the first gate insulating film. Using the gate electrode as a mask, an impurity is introduced into the main surface of the substrate to form a pair of first source/drain regions, spaced apart from each other and having a first channel region therebetween. A second gate insulating film having a second thickness larger than the first thickness is formed on the main surface of the semiconductor substrate. Using the second gate electrode as a mask, an impurity is introduced into the main surface of the substrate to form a second pair of source/drain regions, spaced apart from each other and having a second channel region therebetween. An oxidation protection film to prevent a gate electrode from being oxidized is formed on a side of one of the first and second gate electrodes. After one of the first and second gate insulating films is formed, the other one of the first and second gate insulating films is formed with the oxidation protection film being present on the side of the gate electrode formed on that one of the first and second gate insulating films.
Thus, with the gate electrode being formed on one of the first and second gate insulating films, the other one of the first and second gate insulating films is formed, and therefore resist pattern is not directly formed on the gate insulating film. Therefore, during the following removal of the resist pattern, a direct light etching processing can be prevented on the surface of the gate insulating film. As a result, defects in the surface of the gate insulating film caused by such a light etching processing can be prevented. Furthermore, with the oxidation protection film for preventing a gate electrode from being oxidized being present on a side of one of the first and second gate electrodes, an oxidizing step to form the other one of the first and second gate insulating films is performed. As a result, a lower part of a side of the gate electrode can be prevented from being oxidized, and a gate bird's beak can be avoided. Thus, the threshold voltages of the field effect transistors can be prevented from increasing. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
In a method of manufacturing a semiconductor device according to another aspect of the invention, a first gate insulating film including an oxide nitride film and having a first thickness is formed on a main surface of a semiconductor substrate. A first gate electrode is formed on the first gate insulating film. Using the gate electrode as a mask, an impurity is introduced into the main surface of the substrate to form a pair of first source/drain regions, spaced apart from each other and having a first channel region therebetween. A second gate insulating film having a second thickness larger than the first thickness is formed on the main surface of the semiconductor substrate. Using the second gate electrode as a mask, an impurity is introduced into the main surface of the substrate to form a second pair of source/drain regions, spaced apart from each other and having a second channel region therebetween. The first gate insulating film is formed in the presence of the second gate electrode formed on the second gate insulating film.
Thus, while the second gate electrode has been formed on the second gate insulating film, the first gate insulating film is formed, and therefore resist pattern is not directly formed on the second gate insulating film. Therefore, during the following removal of the resist pattern, a direct light etching processing on the surface of the second gate insulating films can be prevented. Thus, defects in the surface of the second gate insulating film caused by such a light etching processing can be prevented.
Furthermore, since there is the step of forming the first gate insulating film to include the oxide nitride film, an end of the second gate electrode can be suppressed from being excessively oxidized at the joint of a lower part of a side of the second gate electrode and the second gate insulating film during forming the oxide nitride film to be the first gate insulating film while the second gate electrode has been formed. Thus, a gate bird's beak can be avoided. Therefore, the threshold voltages of the field effect transistors can be prevented increasing, and as a result electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating. Since the first gate insulating film is formed to include the oxide nitride film, the thickness of the first gate insulating film can be made smaller than the case of using a conventional silicon oxide film as a prescribed breakdown voltage is maintained. As a result, the driving voltage of the first field effect transistor can be reduced.
In a method of manufacturing a semiconductor device according to another aspect of the invention, a first gate insulating film having a first thickness is formed on a main surface of a semiconductor substrate. A first gate electrode is formed on the first gate insulating film. Using the first gate electrode as a mask, an impurity is introduced into the main surface of the substrate to form a pair of first source/drain regions, spaced apart from each other and having a first channel region therebetween. A second gate insulating film having a second thickness larger than the first thickness is formed on the main surface of the semiconductor substrate. Using the second gate electrode as a mask, an impurity is introduced into the main surface of the substrate to form a second pair of source/drain regions, spaced apart from each other and having a second channel region therebetween. An anti-oxidation conductive film is formed on at least one of the first and second gate insulating films. While the anti-oxidation conductive film has been formed on at least one of the first and second gate insulating films, the other one of the first and second gate insulating films is formed.
Since the anti-oxidation conductive film is formed on one of the first and second gate insulating films, it is not necessary to directly form a resist pattern on the surface of one of the first and second gate insulating films. In addition, before forming one of the first and second gate electrodes, an oxidizing step to form the other one of the first and second gate insulating films can be performed using the anti-oxidation conductive film as a mask. As a result, a lower part of a side of one of the first and second gate electrodes can be prevented from being oxidized, and a gate bird's beak can be avoided. Thus, the threshold voltages of the field effect transistors can be prevented from increasing. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
Furthermore, since the anti-oxidation conductive film is formed on one of the first and second gate insulating films, a resist pattern is not directly formed on that one of the first and second gate insulating films. As a result, defects such as local irregularities in the gate insulating film as formed during removing a resist pattern can be avoided. Therefore, the threshold voltages of the field effect transistors may be prevented from fluctuating. Electrical characteristics of the semiconductor device including the plurality of field effect transistors may be prevented from deteriorating.
The method of manufacturing the semiconductor device according to this aspect may further include the step of forming a semiconductor film including a conductive impurity at a position between the anti-oxidation conductive film and at least one of the first and second gate insulating films. Thus, when voltage is supplied to one of the first and second gate electrodes on the side having the semiconductor film including the conductive impurity, the formation of a depletion layer caused by a reduction in the concentration of the conductive impurity in the vicinity of one of the first and second gate insulating films can be restricted. As a result, the fluctuation of the threshold voltages of the field effect transistors caused by the formation of such a depletion layer can be prevented. Therefore, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
In the method of manufacturing the semiconductor device according to this aspect, a substrate protection film may be formed in the region on the main surface of the semiconductor substrate to form one of the first and second gate insulating films. With the substrate protection film being present, the other one of the first and second gate insulating films and the anti-oxidation conductive film may be formed.
Thus, with the presence of the substrate protection film, the other one of the first and second gate insulating films and the anti-oxidation conductive film are formed, the insulating film forming the other one of the first and second gate insulating film can be prevented from being formed in contact with the main surface of the semiconductor substrate positioned in the region to form one of the first and second gate insulating films.
As a result, during etching away the anti-oxidation conductive film and the insulating film from the region to form one of the first and second gate insulating films, the main surface of the semiconductor substrate positioned in the region to form that one of the first and second gate insulating films can be prevented from being directly etched. Thus, damages to the main surface of the semiconductor substrate caused by etching can be prevented. As a result, during forming one of the first and second gate insulating films, the deterioration of the quality of one of the first and second gate insulating films caused by the presence of damages by the etching on the main surface of the semiconductor substrate in which the gate insulating film is formed can be prevented. As a result, the fluctuation of the threshold voltage of the field effect transistors can be prevented. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented.
The method of manufacturing the semiconductor device according to this aspect may further include the step of removing a part of the main surface of the semiconductor substrate positioned in the region to form one of the first and second gate insulating films before forming that insulating film.
Thus, in the main surface of the semiconductor substrate positioned in the region to form one of the first and second gate insulating films by means of etching in the manufacture of the semiconductor device, a part of the main surface of the semiconductor substrate with damages such as local irregularities can be removed. Therefore, that one of the first and second gate insulating films can be formed on the main surface of the semiconductor substrate removed of the damaged part. Therefore, the quality of the gate insulating film can be prevented from deteriorating due to damages on the main surface of the semiconductor substrate. The fluctuation of the threshold voltages of the field effect transistors can be prevented. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented.
In a method of manufacturing a semiconductor device according to another aspect of the invention, a first gate insulating film having a first thickness is formed on a main surface of a semiconductor device. A first gate electrode is formed on the first gate insulating film. Using the gate electrode as a mask, an impurity is introduced into the main surface of the substrate to form a pair of first source/drain regions, spaced apart from each other and having a first channel region therebetween. A second gate insulating film having a second thickness larger than the first thickness is formed on the main surface of the semiconductor substrate. A first conductive film to be a part of a second electrode is formed on the second gate insulating film. An insulating film to be a part of the second gate electrode is formed on the first conductive film. A second conductive film to be a part of the second gate electrode is formed on the insulating film. The first and second insulating films and the insulating film are anisotropically etched to form the second gate electrode. Using the second gate electrode as a mask, an impurity is introduced into the main surface of the substrate to form a second pair of source/drain regions, spaced apart from each other and having a second channel region therebetween. Herein the first gate insulating film is formed in the presence of the first conductive film.
Thus, after forming the first conductive film to be a part of the second gate electrode on the second gate insulating film, the first gate insulating film is formed, and therefore an oxidizing step to form the first gate insulating film can be performed without forming a resist pattern directly on the surface of the second gate insulating film. Therefore, during the following removal of the resist pattern, a direct light etching processing to the surface of the second gate insulating film can be prevented. Thus, defects on the surface of the second gate insulating film caused by such a light etching processing can be prevented.
In the presence of the first conductive film, after the first gate insulating film is formed and then the insulating film and the second conductive films are formed, the first and second conductive films and the insulating film are anisotropically etched to form the second gate electrode, a side of the second gate electrode can be prevented from being oxidized in the oxidizing step to form the first gate insulating film. Thus, a gate bird's beak can be avoided. Thus, the threshold voltages of the field effect transistors can be prevented from increasing. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating. In the presence of the insulating film, when a voltage is supplied to the second gate electrode, the voltage drops in the insulating film, and voltage imposed on the second gate insulating film can be reduced.
In a method of manufacturing a semiconductor device according to another aspect of the invention, a first gate insulating film having a first thickness is formed on a main surface of a semiconductor substrate. A first gate electrode is formed on the first gate insulating film. Using the gate electrode as a mask, an impurity is introduced into the main surface of the substrate to form a pair of first source/drain regions, spaced apart from each other and having a first channel region therebetween. A second gate insulating film having a second thickness larger than the first thickness is formed on the main surface of the semiconductor substrate. A second gate electrode is formed on the second gate insulating film. Using the second gate electrode as a mask, an impurity is introduced into the main surface of the substrate to form a pair of second source/drain regions, spaced apart from each other and having a second channel region therebetween. A protection conductive film for protecting a gate insulating film is formed on and in contact with at least one of the first and second gate insulating films. While the protection conductive film has been formed, the other one of the first and second gate insulating films is formed.
Thus, the protection conductive film is formed on and in contact with one of the first and second gate insulating films, it is not necessary to directly form a resist pattern on that one of the first and second gate insulating films. Furthermore, before forming one of the first and second gate electrodes, an oxidizing step to form the other one of the first and second gate insulating films using the protection conductive film as a mask can be performed. As a result, a lower part of the side of one of the first and second gate electrodes can be prevented from being oxidized, and a gate bird's beak can be avoided. Thus, the threshold voltages of the field effect transistors can be prevented from increasing. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
In the method of manufacturing the semiconductor device according to this aspect, a conductive film may be formed on and in contact with the other one of the first and second gate insulating films. A resist pattern may be formed on and in contact with the conductive film and the protection conductive film. Using the resist pattern as a mask, part of the conductive film and the protection conductive film is anisotropically etched away to simultaneously form the first gate electrode and the second gate electrode.
Thus, the resist pattern is formed on and in contact with the protection conductive film and the conductive film, part of the conductive film and the protection conductive film is anisotropically etched away using the resist pattern as a mask, and therefore the first and second gate electrodes can be formed only of the conductive film and the protection conductive film. As a result, it is not necessary to further form a conductive film to be a part of the gate electrode on the protection conductive film, the process of manufacturing the semiconductor device can be simplified.
In a method of manufacturing a semiconductor device according to another aspect of the invention, an insulating film is formed on a main surface of a semiconductor substrate positioned in regions to form first and second field effect transistors. A resist pattern is formed on the insulating film positioned in the regions to form the second field effect transistor. Using the resist pattern as a mask, a part of the insulating film positioned in the region to form the first field effect transistor is isotropically etched away, followed by removal of the resist pattern. Thus a part of the surface of the insulating film is isotropically etched away to form first and second gate insulating films. A first gate electrode is formed on the first gate insulating film. Using the first gate electrode as a mask, an impurity is introduced into the main surface of the semiconductor substrate to form a pair of source/drain regions, spaced apart from each other and having a first channel region therebetween. A second gate electrode is formed on the second gate insulating film. Using the second gate electrode as a mask, an impurity is introduced into the main surface of the semiconductor substrate, to form a pair of second source/drain regions, spaced apart from each other and having a second channel region therebetween.
Thus, the first and second gate insulating films are formed of a single insulating film, only a single oxidizing step is necessary to form the first and second gate insulating films. Since the first and second gate electrodes are formed after forming the first and second gate insulating films, thus first and second gate electrodes are not oxidized during forming the first and second gate insulating films. As a result, a lower part of a side of the first and second gate electrodes can be prevented from being oxidized, and a gate bird's beak can be avoided. Thus, the threshold voltages of the field effect transistors can be prevented from increasing. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
Furthermore, since only a single oxidizing step is necessary to form the first and second gate insulating films, in other words the number of oxidizing steps to form insulating films is reduced by one as compared to the conventional method, the process of manufacturing the semiconductor device can be simplified.
Furthermore, the first and second gate insulating films are formed by means of isotropic etching, possible defects such as local irregularities caused by for example a step of ashing during removal of the resist pattern on the insulating film to be the first and second gate insulating films can be removed by the anisotropic etching. As a result, a defectless, highly reliable gate insulating film may be obtained, and the fluctuation of the threshold voltages of the field effect transistors can be prevented. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
The foregoing and other objects, features, aspects and advantages of the present invention will become more apparent from the following detailed description of the present invention when taken in conjunction with the accompanying drawings.
BRIEF DESCRIPTION OF THE DRAWINGSFIG. 1 is a cross sectional view showing a 2-power supply semiconductor device including a plurality of field effect transistors according to a first embodiment of the invention;
FIGS.2 to10 are cross sectional views for use in illustration of the first to ninth steps in the process of manufacturing the 2-power supply semiconductor device including the plurality of field effect transistors according to the first embodiment shown inFIG. 1;
FIG. 11 is a cross sectional view showing a 2-power supply semiconductor device including a plurality of field effect transistors according to a second embodiment of the invention;
FIGS.12 to21 are cross sectional views for use in illustration of the first to tenth steps in the process of manufacturing the 2-power supply semiconductor device including the plurality of field effect transistors according to the second embodiment shown inFIG. 11;
FIG. 22 is a cross sectional view showing a 2-power supply semiconductor device including a plurality of field effect transistors according to a third embodiment of the invention;
FIG. 23 is a cross sectional view showing a first variation of the 2-power supply semiconductor device including the plurality of field effect transistors according to the third embodiment;
FIG. 24 is a cross sectional view showing a second variation of the 2-power supply semiconductor device including the plurality of field effect transistors according to the third embodiment;
FIGS.25 to32 are cross sectional views showing the first to eighth steps in the process of manufacturing the 2-power supply semiconductor device including the plurality of field effect transistors according to the third embodiment shown inFIG. 22;
FIG. 33 is a cross sectional view showing a 2-power supply semiconductor device including a plurality of field effect transistors according to a fourth embodiment of the invention;
FIGS.34 to37 are cross sectional views for use in illustration of the first to fourth steps in the process of manufacturing the 2-power supply semiconductor device including the plurality of field effect transistors according to the fourth embodiment shown inFIG. 33;
FIGS.38 to41 are cross sectional views for use in illustration of a process of manufacturing a 2-power supply semiconductor device including a plurality of field effect transistor according to a first variation of the fourth embodiment;
FIGS. 42 and 43 are cross sectional views for use in illustration of the first and second steps in a process of manufacturing a 2-power supply semiconductor device including a plurality of field effect transistors according to a second variation of the fourth embodiment;
FIG. 44 is a cross sectional view showing a 2-power supply semiconductor device including a plurality of field effect transistors according to a third variation of the fourth embodiment;
FIGS. 45 and 46 are cross sectional views for use in illustration of the first and second steps in the process of manufacturing the 2-power supply semiconductor device including the plurality of field effect transistors according to the third variation of the fourth embodiment shown inFIG. 44;
FIG. 47 is a cross sectional view showing a 2-power supply semiconductor device including a plurality of field effect transistors according to a fifth embodiment of the invention;
FIG. 48 is a cross sectional view for use in illustration of the first step in the process of manufacturing the 2-power supply semiconductor device including the plurality of field effect transistors according to the fifth embodiment shown inFIG. 47;
FIG. 49 is a cross sectional view showing a 2-power supply semiconductor device including a plurality of field effect transistors according to a sixth embodiment of the invention;
FIGS.50 to55 are cross sectional views for use in illustration of the first to sixth steps in the process of manufacturing the 2-power supply semiconductor device including the plurality of field effect transistors according to the sixth embodiment shown inFIG. 49;
FIG. 56 is a cross sectional view showing a 2-power supply semiconductor device including a plurality of field effect transistors according to a seventh embodiment of the invention;
FIGS.57 to60 are cross sectional views for use in illustration of the first to fourth steps in the process of manufacturing the 2-power supply semiconductor device including the plurality of field effect transistors according to the seventh embodiment shown inFIG. 56;
FIG. 61 is a cross sectional view showing a 2-power supply semiconductor device including a plurality of field effect transistors according to a first variation of the seventh embodiment;
FIG. 62 is a view schematically showing how an isotropic etching agent runs along grain boundaries inside a dopedpolysilicon film32 to reach a secondgate insulating film4, when dopedpolysilicon film32 shown inFIG. 56 is isotropically etched;
FIG. 63 is a view schematically showing that an isotropic etching agent does not reach a secondgate insulating film4 because of the absence of grain boundaries in asilicon film34, when asilicon film34 having an amorphous structure as shown inFIG. 61 has its surface isotropically etched in the process of manufacture;
FIG. 64 is a cross sectional view showing a 2-power supply semiconductor device including a plurality of field effect transistors according to a second variation of the seventh embodiment;
FIGS.65 to70 are cross sectional views for use in illustration of the first to sixth steps in the process of manufacturing the 2-power supply semiconductor device including the plurality of field effect transistors according to the second variation of the seventh embodiment shown inFIG. 64;
FIG. 71 is a cross sectional view showing a 2-power supply semiconductor device including a plurality of field effect transistors according to an eighth embodiment of the invention;
FIG. 72 is a cross sectional view for use in illustration of the first step in the process of manufacturing the 2-power supply semiconductor device including the plurality of field effect transistors according to the eighth embodiment shown inFIG. 71;
FIG. 73 is a cross sectional view showing a 2-power supply semiconductor device including a plurality of field effect transistors according to a ninth embodiment of the invention;
FIGS.74 to78 are cross sectional views for use in illustration of the first to fifth steps in the process of manufacturing the 2-power supply semiconductor device including the plurality of field effect transistors according to the ninth embodiment shown inFIG. 73;
FIG. 79 is a cross sectional view showing a conventional 2-power supply semiconductor device including a plurality of field effect transistors;
FIGS.80 to86 are cross sectional views for use in illustration of the first to seventh steps in the process of manufacturing the conventional 2-power supply semiconductor device including the plurality of field effect transistors shown inFIG. 79;
FIGS.87 to93 are cross sectional views for use in illustration of the first to seventh steps in the process of manufacturing another conventional 2-power supply semiconductor device including a plurality of field effect transistors; and
FIG. 94 is an enlarged view ofregion100 inFIG. 90.
DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments of the invention will be now described in conjunction with the accompanying drawings.
First Embodiment
Referring toFIG. 1, in a 2-power supply semiconductor device including a plurality of field transistors according to a first embodiment of the invention, there are formed, on a main surface of a ptype semiconductor substrate1, a first field effect transistor supplied with a first power supply voltage (low Vdd) and a second field effect transistor supplied with a second voltage (high Vdd) higher than the first power supply voltage, spaced apart from each other. Anisolation oxide film2 is formed between the first and second field effect transistors.
In the low Vdd region, there are formed, on the main surface ofsubstrate1, a pair of first source/drain regions10, and a pair of low concentration,impurity diffusion regions8 adjacent thereto, spaced apart from each other and having a first channel region therebetween. Low concentration, n typeimpurity diffusion region8 formed adjacent to the first channel region and high concentration, n typeimpurity diffusion region10 formed adjacent to n typeimpurity region8 constitute an LDD structure. A firstgate insulating film6 is formed on the first channel region. Afirst gate electrode18 is formed on firstinsulating film6. Asidewall oxide film9 is formed on a side offirst gate electrode18. First source/drain regions10, low concentrationimpurity diffusion regions8 adjacent thereto, firstgate insulating film6, andfirst gate electrode18 form the first field effect transistor.
In the high Vdd region, there are formed, on the main surface ofsemiconductor substrate1, a pair of second source/drain regions17 and a pair of low concentrationimpurity diffusion regions16 adjacent thereto, spaced apart from each other and having a second channel therebetween. Low concentration, n typeimpurity diffusion region16 formed adjacent to the second channel region and high concentration, n typeimpurity diffusion region17 formed adjacent to n typeimpurity diffusion region16 constitute an LDD structure. A secondgate insulating film4 is formed on the second channel region. Asecond gate electrode19 is formed on the second gate insulating film. On a side ofsecond gate electrode19, asidewall nitride film21 formed of a silicon nitride film which serves as an oxidation protection film to preventsecond gate electrode19 from being oxidized is formed. On a side ofsidewall nitride film21, asidewall oxide film20 is formed. Second source/drain regions17, low concentrationimpurity diffusion regions16 adjacent thereto, secondgate insulating film4 andsecond gate electrode19 form the second field effect transistor. Herein, the thickness ofgate insulating film4 of the second field effect transistor supplied with high Vdd should be larger than the thickness of thegate insulating film6 of the first field effect transistor supplied with low Vdd.
Thus,sidewall nitride film21 serving as an oxidation protection film to preventsecond gate electrode19 from being oxidized is formed on a side ofsecond gate electrode19, and therefore an oxidizing step to form firstgate insulating film6 in the first field effect transistor can be performed withsidewall nitride film21 present on the side ofsecond gate electrode19. As a result, a lower part of a side of thesecond gate electrode19 can be prevented from being oxidized, and a gate bird's beak can be avoided. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
In addition, the sidewall is formed of a silicon nitride film, which has a higher ability of preventing diffusion of oxygen atoms than a silicon oxide film, can more surely preventsecond gate electrode19 from being oxidized.
Referring to FIGS.2 to10, a process of manufacturing the 2-power supply semiconductor device including the plurality of field effect transistors according to the first embodiment of the invention will be described.
As shown inFIG. 2,isolation oxide film2 is formed on the main surface of ptype semiconductor substrate1 to surround an active region. Secondgate insulating film4 is formed on the active region of the main surface of ptype semiconductor substrate1. A first dopedpolysilicon film3 is formed on secondgate insulating film4 and onisolation oxide film2. A resistpattern5ais formed on a region of first dopedpolysilicon film3 positioned in the high Vdd region to be second gate electrode19 (seeFIG. 1).
Using resistpattern5aas a mask, a part of first dopedpolysilicon film3 is anisotropically etched away to formsecond gate electrode19 as shown inFIG. 3, followed by removal of resistpattern5a(seeFIG. 2). Asilicon nitride film11 is formed on secondgate insulating film4,second gate electrode19 andisolation oxide film2.
Silicon nitride film11 is anisotropically etched to form, on a side ofsecond gate electrode19,sidewall nitride film21 formed of a silicon nitride film which serves as an oxidation protection film to preventsecond gate electrode19 from being oxidized. A resistpattern5bis formed on secondgate insulating film4,second gate electrode19 andsidewall nitride film21 to cover the high Vdd region.
Herein, resistpattern5bis formed aftersecond gate electrode19 is formed on secondgate insulating film4, resistpattern5bis not directly formed on the region—of the surface of secondgate insulating film4 in whichsecond gate electrode19 is positioned. As a result, during removing resistpattern5b, in the region of the surface of secondgate insulating film4, a resist removing processing or a light etching processing can be prevented. As a result, defects may be prevented from being generated in the region of the surface of secondgate insulating film4. The condition of the anisotropic etching tosilicon nitride film11 may be adjusted so thatsidewall nitride film21 serving as the oxidation protection film has an arbitrary thickness. Thus, during forming second source/drain regions17 (seeFIG. 1) and low concentration impurity diffusion regions16 (seeFIG. 1) in the manufacturing process which will be described, the distance between the source region and the drain region (the length of the channel region) can be adjusted, and second source/drain regions17 and low concentrationimpurity diffusion regions16 having an offset structure can be readily formed. Thus, a high electric field in the vicinity of the boundary region between the channel region, second source/drain regions17 and low concentrationimpurity diffusion regions16 can be reduced. Thus, the generation of electrons with high energy can be prevented. As a result, the fluctuation of the threshold voltage of the second field effect transistor caused by introduction of such high energy electrons into secondgate insulating film14 can be prevented, and as a result electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
After the step shown inFIG. 4, secondgate insulating film4 present in the low Vdd region is removed by means of isotropic etching, and the structure as shown inFIG. 5 results. Thereafter, resistpattern5bis removed.
Firstgate insulating film6 is formed on the portion of the main surface of ptype semiconductor substrate1 positioned in the low Vdd region, on the surface of secondgate insulating film4, and onsecond gate electrode19 by means of thermal oxidation. Thus, the structure as shown inFIG. 6 results. Herein, the thermal oxidation to form firstgate insulating film6 can be performed aftersidewall nitride film21 serving as the oxidation protection film is formed on the side ofsecond gate electrode19. As a result, a lower part of the side ofsecond gate electrode19 can be prevented from being oxidized, and a gate bird's beak can be avoided. Thus, the threshold voltages of the field effect transistors can be prevented from increasing. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
A second dopedpolysilicon film7 is formed to generally cover the entire surface. A resistpattern5cis formed on the region of second dopedpolysilicon film7 to be the first gate electrode18 (seeFIG. 1). As a result, the structure as shown inFIG. 7 results.
Then, using resistpattern5cas a mask, a part of second dopedpolysilicon film7 is anisotropically etched away to form first gate electrode18 (seeFIG. 1). Herein,silicon oxide film6 formed by the thermal oxidation during forming firstgate insulating film6 is onsecond gate electrode19. As a result, during the anisotropic etching for formingfirst gate electrode18,silicon oxide film6 serves as a stopper, so that damages such as partial removal ofsecond gate electrode19 by the anisotropic etching can be prevented. Furthermore, second dopedpolysilicon film7 is formed on firstgate insulating film6, resistpattern5d(seeFIG. 8) is not directly formed on first gate insulating film64 positioned under first gate electrode in the manufacturing process according to the first embodiment. Therefore, as is the case with secondgate insulating film4, defects caused by a processing of removing a resist pattern on the surface of firstgate insulating film6 can be prevented. Thereafter, resistpattern5c(seeFIG. 7) is removed. A resistpattern5d(seeFIG. 8) is formed to cover the low Vdd region. Thus, the structure as shown inFIG. 8 results. At the time, second dopedpolysilicon film7 also remains on a side ofsidewall nitride film21.
Second dopedpolysilicon film7 on the side ofsidewall nitride film21 is removed by means of isotropic etching. Thereafter, resistpattern5dis removed. An n type impurity is introduced into a prescribed region of the main surface of ptype semiconductor substrate1 to form low concentration, n typeimpurity diffusion regions8 and16 as shown inFIG. 9. The n type impurity may be phosphorous or arsenic.
Sidewall oxide films9 and20 are formed on sides offirst gate electrode18 andsidewall nitride film21. First and secondgate insulating films4 and6 in the region other than those positioned under first andsecond gate electrodes18 and19,sidewall oxide films9 and20 andsidewall nitride film21 are etched away. An n type impurity is introduced into a prescribed region of the main surface of ptype semiconductor substrate1 to form high concentration, n typeimpurity diffusion regions10 and17 as shown inFIG. 10.
The 2-power supply semiconductor device according to the first embodiment is thus manufactured.
Note that in the 2-power supply semiconductor device according to the first embodiment,sidewall nitride film21 serving as the oxidation protection film is formed on a side ofsecond gate electrode19, the same effects can be brought about by formingsidewall nitride film21 serving as the oxidation protection film on a side offirst gate electrode18.
Second Embodiment
Referring toFIG. 11, in a 2-power supply semiconductor device including a plurality of field transistors according to a second embodiment of the invention, there are formed, on a main surface of a ptype semiconductor substrate1, a first field effect transistor supplied with a first power supply voltage (low Vdd) and a second field effect transistor supplied with a second voltage (high Vdd) higher than the first power supply voltage, spaced apart from each other. Anisolation oxide film2 is formed between the first and second field effect transistors.
In the low Vdd region, there are formed, on the main surface ofsubstrate1, a pair of first source/drain regions10 and a pair ofimpurity diffusion regions26, spaced apart from each other and having a first channel region therebetween. Intermediate concentration, n typeimpurity diffusion region26 formed adjacent to the first channel region and high concentration, n typeimpurity diffusion region10 formed adjacent to n typeimpurity region26 constitute an LDD structure. A firstgate insulating film6 is formed on the first channel region. Afirst gate electrode18 is formed on firstinsulating film6. Asidewall oxide film9 is formed on a side offirst gate electrode18. First source/drain regions10,impurity diffusion regions26, firstgate insulating film6, andfirst gate electrode18 form the first field effect transistor.
In the high Vdd region, there are formed, on the main surface ofsemiconductor substrate1, a pair of second source/drain regions17, pairs ofimpurity diffusion regions16 and12 adjacent thereto, spaced apart from each other and having a second channel therebetween. Low concentration, n typeimpurity diffusion region16 formed adjacent to the second channel region, intermediate concentration, n typeimpurity diffusion region12 and high concentration, n type impurity-diffusion region17 formed adjacent to n typeimpurity diffusion region16 constitute an LDD structure. A secondgate insulating film4 is formed on the second channel region. Asecond gate electrode19 is formed on secondgate insulating film4. Asidewall nitride film21 serving as an oxidation protection film to preventsecond gate electrode19 from being oxidized is formed on a side ofsecond gate electrode19. Asidewall oxide film20 is formed on a side ofsidewall nitride film21. Second source/drain regions17,impurity diffusion regions16 and12, secondgate insulating film4, andsecond gate electrode19 form the second field effect transistor. Herein, the thickness of the secondgate insulating film4 of the second field effect transistor supplied with high Vdd should be larger than the thickness of the firstgate insulating film6 of the first field effect transistor supplied with low Vdd.
Thus, withsidewall nitride film21 serving as the oxidation protection film to prevent the oxidation ofsecond gate electrode19 being present on a side ofsecond gate electrode19, an oxidizing step to form the firstgate insulating film6 of first field effect transistor can be performed in the manufacturing process which will be described. As a result, as is the case with the first embodiment, a gate bird's beak can be prevented from being generated insecond gate electrode19. As a result, electric characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating. Furthermore, the second source/drain regions17 andimpurity diffusion regions12 and16 of the second field effect transistors which are supplied with high Vdd have a three-region LDD structure, a high electric field in the boundary region between the second channel region and second source/drain regions as well asimpurity diffusion regions12 and16 can be more effectively reduced. As a result, the fluctuation of the threshold voltage of the second field effect transistor can be prevented. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
Referring to FIGS.12 to21, a method of manufacturing the 2-power supply semiconductor device including the plurality of field effect transistors according to the second embodiment will be described.
As shown inFIG. 12,isolation oxide film2 to surround an active region is formed on the main surface of ptype semiconductor substrate1. Secondgate insulating film4 is formed on the active region of the main surface ofsemiconductor substrate1. A first dopedpolyslicon film3 is formed on secondgate insulating film4 andisolation oxide film2. A resistpattern5ais formed on the region of first dopedpolysilicon film3 positioned in the high Vdd region to be second gate electrode19 (seeFIG. 11).
Then, using resistpattern5aas a mask, a part of first dopedpolysilicon film3 is anisotropically etched away to formsecond gate electrode19. Thereafter, resistpattern5ais removed. A resistpattern5bis formed on secondgate insulating film4 andisolation oxide film2 positioned in the low Vdd region. An n type impurity is introduced into a prescribed region ofsemiconductor substrate1 to form a low concentration, n typeimpurity diffusion region16 as shown inFIG. 13. The n type impurity used is phosphorus, the introduction energy is 20 keV, and the dose is 2×1013cm−2. The introduction energy may be in the range from 10 to 30 keV. Herein, sincesecond gate electrode19 has been formed on secondgate insulating film4, a resist pattern is not directly formed in the region of the surface of secondgate insulating film4 in whichsecond gate electrode19 is positioned, in the process of manufacturing which will be described. Defects in the region of the surface of secondgate insulating film4 which are caused by a processing of removing the resist patterns or a light etching processing can be prevented. Resistpattern5bis thereafter removed.
Asilicon nitride film11 is formed on secondgate insulating film4,second gate electrode19 andisolation oxide film2. Thus, the structure as shown inFIG. 14 results.
Silicon nitride film11 is then anisotropically etched to form sidewall nitride film21 (seeFIG. 11) which serves as an oxidation protection film to preventsecond gate electrode19 from being oxidized on a sidewall ofsecond gate electrode19. Resistpattern5c(seeFIG. 15) is formed on secondgate insulating film4,second gate electrode19 andsidewall nitride film21 to cover the high Vdd region to obtain the structure as shown inFIG. 15.
Then, secondgate insulating film4 present in the low Vdd region is isotropically etched to obtain the structure as shown inFIG. 16. Resistpattern5cis then removed away.
Firstgate insulating film6 is formed by means of thermal oxidation on the portion of the main surface ofsemiconductor substrate1 positioned in the low Vdd region, on the surface of secondgate insulating film4, and onsecond gate electrode19. The structure as shown inFIG. 17 thus results. Herein, the thermal oxidation to form firstgate insulating film6 may be performed after formingsidewall nitride film21 serving as the oxidation protection film to preventsecond gate electrode19 from being oxidized on a side ofsecond gate electrode19. As a result, a lower part of a side ofsecond gate electrode19 can be prevented from being oxidized, and a gate bird's beak can be prevented.
A second doped polysilicon film7 (seeFIG. 18) is formed to generally cover the entire surface. A resistpattern5d(seeFIG. 18) is formed on the region of second dopedpolysilicon film7 to be the first gate electrode (seeFIG. 11). Thus, the structure as shown inFIG. 18 results.
Then, using resistpattern5das a mask, a part of second dopedpolysilicon film7 is anisotropically etched away to form first gate electrode18 (seeFIG. 11). Herein,silicon oxide film6 formed by the thermal oxidation during forming firstgate insulating film6 is present onsecond gate electrode19. Therefore, during the anisotropic etching for formingfirst gate electrode18,silicon oxide film6 serves as a stopper, so that damages such as partial removal ofsecond gate electrode19 by the anisotropic etching can be prevented. Thereafter, resistpattern5d(seeFIG. 18) is removed. A resistpattern5e(seeFIG. 19) is formed to generally cover the low Vdd region. Thus, the structure as shown inFIG. 19 results. At the time, second dopedpolysilicon film7 also remains on a side ofsidewall nitride film21.
Then, second dopedpolysilicon film7 on the side ofsidewall nitride film21 is isotropically etched away. Then, resistpattern5e(seeFIG. 19) is removed. An n type impurity is introduced into a prescribed region of the main surface ofsemiconductor substrate1, and thus intermediate concentration, n typeimpurity diffusion regions26 and12 are formed as shown inFIG. 20. The n type impurity is arsenic, the introduction energy is 60 keV, and the dose is 2×1013cm−2. The introduction energy may be in the range from 30 to 80 keV.
Sidewall oxide films9 and20 (seeFIG. 21) are then formed on a side offirst gate electrode18 andsidewall nitride film21. First and secondgate insulating films4 and6 in the region other than in the regions positioned under first andsecond gate electrodes18 and19,sidewall oxide films9 and20 andsidewall nitride film21 are etched away. An n type impurity is introduced into a prescribed region of the main surface of semiconductor substrate. As shown inFIG. 21, high concentration, n typeimpurity diffusion regions10 and17 are formed. Herein, the n type impurity is arsenic, the introduction energy is 40 keV, and the dose is 5×1013cm−2. The introduction energy may be in the range from 30 to 60 keV.
Thus, the 2-power supply semiconductor device including the plurality of field effect transistors according to the second embodiment is manufactured.
Third Embodiment
Referring toFIG. 22, in a 2-power supply semiconductor device including a plurality of field transistors according to a third embodiment of the invention, there are formed, on a main surface of a ptype semiconductor substrate1, a first field effect transistor supplied with a first power supply voltage (low Vdd) and a second field effect transistor supplied with a second voltage (high Vdd) higher than the first power supply voltage, spaced apart from each other. Anisolation oxide film2 is formed between the first and second field effect transistors.
In the low Vdd region, there are formed, on the main surface ofsubstrate1, a pair of first source/drain regions10, and a pair ofimpurity diffusion regions8, spaced apart from each other and having a first channel region. Low concentration, n typeimpurity diffusion region8 formed adjacent to the first channel region and high concentration, n typeimpurity diffusion region10 formed adjacent to n typeimpurity region8 constitute an LDD structure. Anoxide nitride film13 serving as a gate insulating film is formed on the first channel region. Afirst gate electrode18 is formed onoxide nitride film13. Asidewall oxide film9 is formed on a side offirst gate electrode18. First source/drain regions10 andimpurity diffusion regions8,oxide nitride film13, andfirst gate electrode18 form the first field effect transistor.
In the high Vdd region, there are formed, on the main surface ofsemiconductor substrate1, a pair of second source/drain regions17, and a pair ofimpurity diffusion regions16 spaced apart from each other and having a second channel therebetween. Low concentration, n typeimpurity diffusion region16 formed adjacent to the second channel region and high concentration, n typeimpurity diffusion region17 formed adjacent to n typeimpurity diffusion region16 constitute an LDD structure. A secondgate insulating film4 is formed on the channel region. Asecond gate electrode19 is formed on secondgate insulating film4. Anoxide nitride film13 is formed on a side ofsecond gate electrode19 and on secondgate insulating film4. Asidewall oxide film20 is formed onoxide nitride film13. Second source/drain regions17, andimpurity diffusion regions16, secondgate insulating film4, andsecond gate electrode19 form the second field effect transistor. Thus, thegate insulating film13 of the first field effect transistor is formed of an oxide nitride film, an end ofsecond gate electrode19 in the junction of a lower part of the side ofsecond gate electrode19 and secondgate insulating film4 can be prevented from being excessively oxidized. The generation of a gate bird's beak can be restricted. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating. Furthermore, since the first gate insulating film is formed ofoxide nitride film13, the driving capability of the transistor may be improved in terms of thickness as compared to a conventional silicon oxide film or the like.
Referring toFIG. 23, a first variation of the 2-power supply semiconductor device including the plurality of field effect transistors according to the third embodiment has basically the same structure as the 2-power supply semiconductor device according to the first embodiment shown inFIG. 1. However, in the first variation shown inFIG. 23, the firstgate insulating film13 is formed of oxide nitride film. A second variation of the third embodiment shown inFIG. 24 has basically the same structure as the device according to the second embodiment shown inFIG. 11. However, as shown inFIG. 24, in the device according to the second variation, as is the case with the examples shown inFIGS. 22 and 23, the firstgate insulating film13 is formed of oxide nitride film. Therefore, the driving capability of the transistor may be improved as compared to the case of using the conventional silicon oxide film in terms of thickness in addition to the effects brought about according to the first and second embodiments.
Referring to FIGS.25 to32, a process of manufacturing the 2-power supply semiconductor device including the plurality of field effect transistors shown inFIG. 22 according to the third embodiment will be described.
The manufacturing process shown inFIG. 25 is identical to the manufacturing process according to the first embodiment shown inFIG. 2.
Now, a part of first dopedpolysilicon film3 is anisotropically etched away, using a resistpattern5a(seeFIG. 25) as a mask, to form second gate electrode19 (seeFIG. 22), followed by removal of resistpattern5a(seeFIG. 25). A resistpattern5b(seeFIG. 26) is formed on secondgate insulating film4 and onsecond gate electrode19 to cover the high Vdd region, and the structure as shown inFIG. 26 results. Herein, resistpattern5bis formed aftersecond gate electrode19 is formed on secondgate insulating film4, resistpattern5bis not directly formed in the region of the surface of secondgate insulating film4 in whichsecond gate electrode19 is positioned. As a result, defects in the region of the surface of secondinsulating film4 caused by a processing of removing resistpattern5boralight etching processing can be prevented.
Secondgate insulating film4 present in the low Vdd region is isotropically etched away to obtain the structure as shown inFIG. 27. Thereafter, resistpattern5bis removed.
Then,oxide nitride film13 to be the first gate insulating film is formed at the position of the main surface ofsemiconductor substrate1 positioned in the low Vdd region, on the surface of secondgate insulating film4, and onsecond gate electrode19 by means of thermal oxidation using N2O or O2as a gas atmosphere. Thus, the structure as shown inFIG. 28 results. Herein,oxide nitride film13 is formed as the first gate insulating film, an end ofsecond gate electrode19 can be prevented from being excessively oxidized in the junction of a lower part of the side ofsecond gate electrode19 and secondgate insulating film4. Thus, a gate bird's beak can be prevented. Furthermore, sinceoxide nitride film13 is formed as the first gate insulating film, the thickness ofoxide nitride film13 as the first gate insulating film may be smaller than a conventional silicon oxide film, while maintaining a prescribed breakdown voltage. As a result, the driving voltage of the first field effect transistor can be reduced.
The manufacturing process as shown in FIGS.29 to32 is substantially identical to the manufacturing process according to the first embodiment shown in FIGS.7 to10.
Thus, the 2-power supply semiconductor device according to the third embodiment as shown inFIG. 22 is manufactured.
Fourth Embodiment
Referring toFIG. 33, in a 2-power supply semiconductor device including a plurality of field transistors according to a fourth embodiment of the invention, there are formed, on a main surface of a ptype semiconductor substrate1, a first field effect transistor supplied with a first power supply voltage (low Vdd) and a second field effect transistor supplied with a second power supply voltage (high Vdd) higher than the first power supply voltage, spaced apart from each other. Anisolation oxide film2 is formed between the first and second field effect transistors.
In the low Vdd region, there are formed, on the main surface ofsubstrate1, a pair of first source/drain regions10, and a pair ofimpurity diffusion regions8, spaced apart from each other and having a first channel region therebetween. Low concentration, n typeimpurity diffusion region8 formed adjacent to the first channel region and high concentration, n typeimpurity diffusion region10 formed adjacent to n typeimpurity region8 constitute an LDD structure. A firstgate insulating film6 is formed on the first channel region. Afirst gate electrode18 is formed on firstinsulating film6. Asidewall oxide film9 is formed on a side offirst gate electrode18. First source/drain regions10,impurity regions8, firstgate insulating film6, andfirst gate electrode18 form the first field effect transistor.
In the high Vdd region, there are formed, on the main surface ofsemiconductor substrate1, a pair of second source/drain regions17 and a pair ofimpurity diffusion regions16, spaced apart from each other and having a second channel therebetween. Low concentration, n typeimpurity diffusion region16 formed adjacent to the second channel region and high concentration, n typeimpurity diffusion region17 formed adjacent to n typeimpurity diffusion region16 constitute an LDD structure. A secondgate insulating film4 is formed on the second channel region. A nitrogen dopedpolysilicon film14 serving as an anti-oxidation conductive film is formed on secondgate insulating film4. A first dopedpolysilicon film13 doped with a p type or n type impurity is formed on nitrogen dopedpolysilicon film14. Nitrogen dopedpolysilicon film14 and first dopedpolysilicon film3 form asecond gate electrode19. Asidewall oxide film20 is form on a side ofsecond gate electrode19. Second source/drain regions17,impurity diffusion regions16, secondgate insulating film4, andsecond gate electrode19 form the second field effect transistor. Herein, the thickness of secondgate insulating film4 of the second field effect transistor should be larger than the thickness of the firstgate insulating film6 of the first field effect transistor in view of breakdown voltage.
As described above, since nitrogen dopedpolysilicon film14 serving as an anti-oxidation conductive film is formed on secondgate insulating film4, it is not necessary to form a resist pattern directly on the surface of secondgate insulating film4 in the following process of manufacturing. Furthermore, before formingsecond gate electrode19, firstgate insulating film6 is formed using nitrogen dopedpolysilicon film14 as a mask, an oxidizing step may be performed while hardly oxidizing the surface of nitrogen dopedpolysilicon film14. As a result, in the oxidizing step to form agate insulating film6, a lower part of a side ofsecond gate electrode19 is not oxidized, and a gate bird's beak can be prevented. Thus, the threshold voltage of the second field effect transistor can be prevented from increasing, and electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
In addition, since first and secondgate insulating films6 and4 are formed in the above-described manner, a conductive layer may be later formed in the region positioned above first and secondgate insulating films4 and6, and therefore first andsecond gate electrodes18 and19 may be formed in a single patterning processing. As a result, the number of steps included in the manufacture of the semiconductor device may be reduced.
In addition, nitrogen dopedpolysilicon film14 is formed on secondgate insulating film4, a resist pattern is not directly formed on secondgate insulating film4. As a result, defects such as local irregularities in the gate insulating film as formed during removing a resist pattern can be avoided. Therefore, the threshold voltages of the field effect transistors may be prevented from fluctuating. Electrical characteristics of the semiconductor device including the plurality of field effect transistors may be prevented from deteriorating.
Referring to FIGS.34 to37, a process of manufacturing the 2-power supply semiconductor device including the plurality of field effect transistors according to the fourth embodiment will be described.
Isolation oxide film2 is formed to surround an active region on the main surface of ptype semiconductor substrate1. Secondgate insulating film4 is formed on the active region of the main surface ofsemiconductor substrate1. Nitrogen dopedpolysilicon film14 to be the anti-oxidation conductive film is formed on secondgate insulating film4 andisolation oxide film2. Resistpattern5ais formed on nitrogen dopedpolysilicon film14 positioned in the high Vdd region. Thus the structure as shown inFIG. 34 is obtained. Since nitrogen dopedpolysilicon film14 is formed on secondgate insulating film4 and resistpattern5ais formed, resistpattern5ais not directly formed on the surface of second gate insulating film. As a result, defects caused by a processing of removing resistpattern5aoralight etching processing can be prevented on the surface of secondgate insulating film4. As a result, the fluctuation of the threshold voltages of the field effect transistors can be prevented. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from the deteriorating.
Nitrogen dopedpolysilicon film14 and secondgate insulating film4 present in the low Vdd region are removed by means of isotropic etching, and the structure as shown inFIG. 35 results. Resistpattern5ais thereafter removed.
As shown inFIG. 36, firstgate insulating film6 is formed on the main surface ofsemiconductor substrate1 positioned in the low Vdd region. At the time, the surface of nitrogen dopedpolysilicon film14 is little oxidized, because its surface had nitrogen introduced.
First dopedpolysilicon film3 is formed on firstgate insulating film6, nitrogen dopedpolysilicon film14 andisolation oxide film2. Resistpatterns5band5care formed on the regions of first dopedpolysilicon film3 to be first andsecond gate electrodes18 and19 (seeFIG. 33), and the structure as shown inFIG. 37 results.
Using resistpatterns5band5cas masks, a part of first dopedpolysilicon film3 is anisotropically etched away to form first andsecond gate electrodes18 and19 (seeFIG. 33). Since nitrogen dopedpolysilicon film14 serving as the anti-oxidation conductive film is formed on secondgate insulating film4, first andsecond gate electrodes18 and19 may be formed in a single etching processing after first and secondgate insulating films6 and4 are formed. In addition, sincefirst gate electrode18 andsecond gate electrode19 may be formed in a single anisotropic etching processing, the number of steps included in the manufacture of the semiconductor device may be reduced. Furthermore, since nitrogen dopedpolysilicon film14 is formed on secondgate insulating film4, nitrogen dopedpolysilicon film14 serves as a barrier against an impurity when the impurity is introduced to form second source/drain regions17 and impurity diffusion regions16 (seeFIG. 33). As a result, the impurity can be effectively prevented from being introduced into the second channel region. As a result, erroneous operations of the second field effect transistor caused by introduction of the impurity into the second channel region can be more effectively prevented.
Thereafter, an impurity is introduced into a prescribed region of the main surface ofsemiconductor substrate1, followed by formation ofsidewall oxide films9 and20 (seeFIG. 33) on sides of first andsecond gate electrodes18 and19 (seeFIG. 33), and the semiconductor device as shown inFIG. 33 is formed.
The 2-power supply semiconductor device including the plurality of field effect transistors according to the fourth embodiment is thus manufactured.
Referring to FIGS.38 to41, a process of manufacturing a 2-power supply semiconductor device including a plurality of field effect transistors according to a first variation of the fourth embodiment will be now described.
Isolation oxide film2 is formed on the main surface of ptype semiconductor substrate1 to surround an active region. An oxide film (not shown) is formed on the main surface ofsemiconductor substrate1. A resist pattern (not shown) is formed on the oxide film positioned in the low Vdd region. Using the resist pattern as a mask, an impurity is introduced into the main surface ofsemiconductor substrate1 positioned in the high Vdd region. Using the resist pattern as a mask, the oxide film positioned in the high Vdd region is isotropically etched away. Thereafter, the resist pattern is removed to form the structure as shown inFIG. 38.
The manufacturing steps shown inFIGS. 39 and 40 are substantially identical to the steps of manufacturing the 2-power supply semiconductor device including the plurality of field effect transistors according to the fourth embodiment. However, anoxide film28 serving as a substrate protection film is formed on the main surface of semiconductor substrate positioned in the low Vdd region as shown inFIG. 39. Thus, in the oxidizing step to form secondgate insulating film4, the main surface ofsemiconductor substrate1 positioned in the low Vdd region is not directly oxidized. Sinceoxide film4 and nitrogen dopedpolysilicon film14 are formed onoxide film28, during isotropically etching away nitrogen dopedpolysilicon film14 from the low Vdd region as shown inFIG. 40,oxide film28 having a sufficient thickness can prevent the main surface ofsemiconductor substrate1 positioned in the low Vdd region from being directly damaged by the isotropic etching. Thus, when first gate insulating film6 (seeFIG. 33) is formed in the low Vdd region, the deterioration of the quality of firstgate insulating film6 because of possible damages by etching on the main surface ofsemiconductor substrate1 can be prevented. As a result, the fluctuation of the threshold voltage of the first field effect transistor can be prevented. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
The manufacturing process according to the first variation of the fourth embodiment shown inFIG. 41 is substantially identical to the manufacturing process according to the fourth embodiment shown inFIG. 37. An impurity is thereafter introduced into a prescribed region of the main surface ofsemiconductor substrate1, followed by formation ofsidewall oxide films9 and20 (seeFIG. 33) on sides of first andsecond gate electrodes18 and19 (seeFIG. 33), to form the semiconductor device as shown inFIG. 33.
Referring toFIGS. 42 and 43, a process of manufacturing a 2-power supply semiconductor device including a plurality of field effect transistors according to a second variation of the fourth embodiment will be now described.
Among the steps of manufacturing the 2-power supply semiconductor device including the plurality of field effect transistors according to the fourth embodiment, after performing the steps shown inFIGS. 34 and 35, resistpattern5a(seeFIG. 35) is removed. Then, the entire surface ofsemiconductor substrate1 is oxidized to form anoxide film29 on the main surface ofsemiconductor substrate1 positioned in the low Vdd region to obtain the structure as shown inFIG. 42.
Then, as shown inFIG. 43, oxide film29 (seeFIG. 42) is isotropically etched away. In the manufacturing process according to the second variation of the fourth embodiment, after the main surface ofsemiconductor substrate1 positioned in the low Vdd region is oxidized, oxide film29 (seeFIG. 42) is thus isotropically etched away, possible damages generated by etching on the main surface positioned in the low Vdd region ofsemiconductor substrate1 caused by an etching processing to remove oxide film4 (seeFIG. 34) and nitrogen doped polysilicon film14 (seeFIG. 34) from the main surface ofsemiconductor substrate1 positioned in the low Vdd region can be removed by isotropically etching a part of the main surface ofsemiconductor substrate1 with the defects. As a result, during forming first gate insulating film6 (seeFIG. 33), the deterioration of the quality of firstgate insulating film6 because of damages by etching such as local irregularities on the surface ofsemiconductor substrate1 may be prevented. As a result, the fluctuation of the threshold voltages of the field effect transistors may be prevented, and as a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
After the step shown inFIG. 43, the steps to manufacture the 2-power supply semiconductor device including the plurality of field effect transistors according to the fourth embodiment shown inFIGS. 36 and 37 are performed to obtain the semiconductor device as shown inFIG. 33.
Referring toFIG. 44, a 2-power supply semiconductor device including a plurality of field effect transistors according to a third variation of the fourth embodiment of the invention has substantially the same structure as the 2-power supply semiconductor device according to the fourth embodiment shown inFIG. 33. However, as shown inFIG. 44, in the device according to the third variation, there is formed a dopedpolysilicon film32 having a conductive impurity between secondgate insulating film4 and nitrogen dopedpolysilicon film14. Therefore, in the 2-power supply semiconductor device according the third variation, in addition to the effects brought about by the device according to the fourth embodiment, the formation of a depletion layer caused by a reduction in the density of the conductive impurity in the vicinity of secondgate insulating film4 when a voltage is supplied togate electrode19 can be restrained. As a result, the fluctuation of the threshold voltages of the field effect transistors caused by the formation of such a depletion layer can be prevented. Therefore, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
Referring toFIGS. 45 and 46, a process of manufacturing the 2-power supply semiconductor device according to the third variation of the fourth embodiment of the invention will be now described.
As shown inFIG. 45,isolation oxide film2 is formed to surround an active region on the main surface of ptype semiconductor substrate1. Secondgate insulating film4 is formed on the active region of the main surface ofsemiconductor substrate1.Doped polysilicon film32 having a conductive impurity is formed between secondgate insulating film4 andisolation oxide film2. Nitrogen dopedpolysilicon film14 is formed on dopedpolysilicon film32.
After performing the steps substantially identical to the manufacturing steps according to the fourth embodiment of the invention as shown in FIGS.34 to36, apolysilicon film7 is formed to generally cover the entire semiconductor device as shown inFIG. 46. Resistpatterns5gand5hare formed onpolysilicon film7.
Using resistpatterns5gand5has masks, an anisotropic etching is performed to partially remove dopedpolysilicon film7, nitrogen dopedpolysilicon film14 and dopedpolysilicon film32 to form first andsecond gate electrodes18 and19 (seeFIG. 44).
Thereafter, an impurity is introduced into a prescribed region of the main surface ofsemiconductor substrate1, followed by formation of a sidewall oxide film9 (seeFIG. 44) on sides of first andsecond gate electrodes18 and19 (seeFIG. 44), and the semiconductor device as shown inFIG. 44 results.
In the 2-power supply semiconductor device including the plurality of field effect transistors according to the fourth embodiment, nitrogen dopedpolysilicon film14 is formed in the high Vdd region, the same effects can be brought about by forming nitrogen dopedpolysilicon film14 in the low Vdd region.
Fifth Embodiment
Referring toFIG. 47, In a 2-power supply semiconductor device including a plurality of field transistors according to a fifth embodiment of the invention, there are formed, on a main surface of a ptype semiconductor substrate1, a first field effect transistor supplied with a first power supply voltage (low Vdd) and a second field effect transistor supplied with a second voltage (high Vdd) higher than the first power supply voltage, spaced apart from each other. Anisolation oxide film2 is formed between the first and second field effect transistors.
In the low Vdd region, there are formed, on the main surface ofsubstrate1, a pair of first source/drain regions10, and a pair ofimpurity diffusion regions8 spaced apart from each other and having a first channel region therebetween. Low concentration, n typeimpurity diffusion region8 formed adjacent to the first channel region and high concentration, n typeimpurity diffusion region10 formed adjacent to n typeimpurity diffusion region8 constitute an LDD structure. A firstgate insulating film6 is formed on the first channel region. Afirst gate electrode18 is formed on firstinsulating film6. Asidewall oxide film9 is formed on a side offirst gate electrode18. First source/drain regions10,impurity diffusions8, firstgate insulating film6, andfirst gate electrode18 form the first field effect transistor.
In the high Vdd region, there are formed, on the main surface ofsemiconductor substrate1, a pair of second source/drain regions17, and a pair ofimpurity diffusion regions16, spaced apart from each other and having a second channel therebetween. Low concentration, n typeimpurity diffusion region16 formed adjacent to the second channel region and high concentration, n typeimpurity diffusion region17 formed adjacent to n typeimpurity diffusion region16 constitute an LDD structure. Secondgate insulating film4 is formed on the second channel region.Doped polysilicon film32 having a conductive impurity is formed on secondgate insulating film4. Anitride film27 is formed on a dopedpolysilicon film32. A dopedpolysilicon film7 is formed onnitride film27.Doped polysilicon film32,nitride film27 and dopedpolysilicon film7 form asecond gate electrode19. Asidewall oxide film9 is formed on a side ofsecond gate electrode19. Herein,nitride film27 is formed by nitriding the surface of dopedpolysilicon film32 by lamp annealing as in the manufacturing steps which will be described and is a tunnel insulating film through which a current may be passed when voltage is supplied togate electrode19. Second source/drain regions17,impurity diffusion regions16, secondgate insulating film4, andsecond gate electrode19 form the second field effect transistor.
Thus, dopedpolysilicon film32 andnitride film27 are formed on secondgate insulating film4, it is not necessary to form a resist pattern directly on the surface of secondgate insulating film4. An oxidizing step to form firstgate insulating film6 may be performed, usingnitride film27 as a mask before formingsecond gate electrode19. As a result, a lower part of a side ofsecond gate electrode19 is not oxidized in the step of oxidizing firstgate insulating film6, and therefore a gate bird's beak can be prevented. Therefore, the threshold voltages of the field effect transistors can be prevented from increasing. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
Furthermore, since dopedpolysilicon film32 is formed on secondgate insulating film4, a resist pattern is not formed directly on secondgate insulating film4. Therefore, as a result, defects such as local irregularities in the gate insulating film as formed during removing the resist pattern can be avoided. Therefore, the threshold voltages of the field effect transistors may be prevented from fluctuating. Electrical characteristics of the semiconductor device including the plurality of field effect transistors may be prevented from deteriorating.
In addition, before formingsecond gate electrode19,gate insulating films6 and4 are formed, first andsecond gate electrodes18 and19 may be formed in a single patterning processing by forming a conductive layer on the regions positioned on first and secondgate insulating films4 and6. As a result, the number of steps included in the manufacture of semiconductor device may be reduced.
Furthermore, since dopedpolysilicon film32 including a conductive impurity is formed on secondgate insulating film4, when a voltage is supplied togate electrode19, the formation of a depletion layer caused by a reduction in the density of the conductive impurity in the vicinity of secondgate insulating film4 may be restricted. As a result, the fluctuation of the threshold voltages of the field effect transistors caused by the formation of such a depletion layer can be prevented. Therefore, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
Referring toFIG. 48, a process of manufacturing the 2-power supply semiconductor device according to the fifth embodiment will be now described.
As shown inFIG. 48,isolation oxide film2 is formed to surround an active region on the main surface of ptype semiconductor substrate1. Secondgate insulating film4 is formed on the active region on the main surface ofsemiconductor substrate1.Doped polysilicon film32 including a conductive impurity is formed on secondgate insulating film4 andisolation oxide film2. The surface of dopedpolysilicon film32 is nitrided by means of lamp annealing to formnitride film27.
After the step shown inFIG. 48, the steps substantially the same as those shown in FIGS.34 to37 related to the 2-power supply semiconductor device according to the fourth embodiment are performed. Thus, semiconductor device as shown inFIG. 47 results.
In the step corresponding to the step shown inFIG. 36, dopedpolysilicon film32 andnitride film27 are formed on secondgate insulating film4, a resist pattern does not have to be formed directly on the surface of secondgate insulating film4. Furthermore, before formingsecond gate electrode19, an oxidizing step to form firstgate insulating film6 usingnitride film27 as a mask may be performed. Thus, in the step of oxidizing firstgate insulating film6, a lower part of a side ofsecond gate electrode19 is not oxidized, and as a result, a gate bird's beak can be prevented. As a result, the threshold voltages of the field effect transistors can be prevented from increasing. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
Furthermore, since first and secondgate insulating films6 and4 may be formed in the above-described manner, in the step corresponding to the step shown inFIG. 37, doped polysilicon film7 (seeFIG. 47) may be formed in the region positioned above first and secondgate insulating films6 and4, and first andsecond gate electrodes18 and19 may be formed in a single patterning processing. As a result, the number of steps included in the manufacture of the semiconductor device may be reduced.
Sixth Embodiment
Referring toFIG. 49, in a 2-power supply semiconductor device including a plurality of field transistors according to a sixth embodiment of the invention, there are formed, on a main surface of a ptype semiconductor substrate1, a first field effect transistor supplied with a first power supply voltage (low Vdd) and a second field effect transistor supplied with a second voltage (high Vdd) higher than the first power supply voltage, spaced apart from each other. Anisolation oxide film2 is formed between the first and second field effect transistors.
In the low Vdd region, there are formed, on the main surface ofsubstrate1, a pair of first source/drain regions10, and a pair ofimpurity diffusion regions8 spaced apart from each other and having a first channel region therebetween. Low concentration, n typeimpurity diffusion region8 formed adjacent to the first channel region and high concentration, n typeimpurity diffusion region10 formed adjacent to n typeimpurity diffusion region8 constitute an LDD structure. A firstgate insulating film6 is formed on the first channel region. Afirst gate electrode18 is formed on firstgate insulating film6. Asidewall oxide film9 is formed on a side offirst gate electrode18. First source/drain regions10,impurity diffusion regions8, firstgate insulating film6, andfirst gate electrode18 form the first field effect transistor.
In the high Vdd region, there are formed, on the main surface ofsemiconductor substrate1, a pair of second source/drain regions17, a pair ofimpurity diffusion regions16 spaced apart from each other and having a second channel therebetween. Low concentration, n typeimpurity diffusion region16 formed adjacent to the second channel region and high concentration, n typeimpurity diffusion region17 formed adjacent to n typeimpurity diffusion region16 constitute an LDD structure. A secondgate insulating film4 is formed on the second channel region. A first dopedpolysilicon film3 is formed on secondgate insulating film4. An insulatingfilm6 of the same material as that of firstgate insulating film6 is formed on first dopedpolysilicon film3. A second dopedpolysilicon film22 is formed on insulatingfilm6. First dopedpolysilicon film3, insulatingfilm6, and second dopedpolysilicon film22 formsecond gate electrode19. Asidewall oxide film20 is formed on a side ofsecond gate electrode19. Second source/drain regions17,impurity diffusion regions16, secondgate insulating film4, andsecond gate electrode19 form the second field effect transistor.
Thus,second gate electrode19 is formed to have first dopedpolysilicon3, insulatingfilm6 in the high Vdd region and second dopedpolysilicon film22, a resist pattern is not directly formed on the surface of secondgate insulating film4 in the step of manufacture which will be described, an oxidizing step to form firstgate insulating film6 in the low Vdd region may be performed before formingsecond electrode19. As a result, a gate bird's beak caused by oxidation of a side ofsecond electrode19 can be prevented. Furthermore, when high Vdd is supplied tosecond gate electrode19, a voltage imposed on secondgate insulating film4 can be reduced by a voltage drop at insulatingfilm6 in the high Vdd region.
Assuming that the thickness of firstgate insulating film6 in low Vdd region is t1, the thickness of second gate insulating film4 t2, the thickness of insulatingfilm6 in the high Vdd region t3, a voltage supplied to first gate electrode18 V1, and a voltage supplied to second gate electrode19 V2, the thicknesses of insulatingfilm6 in the high Vdd region, firstgate insulating film6 in the low Vdd region and secondgate insulating film4 may be adjusted such that t1/(t2+t3) is substantially equal to V1/V2, and the static characteristic of first and second field effect transistors can be adjusted to be substantially equal to each other.
Referring to FIGS.50 to55, a process of manufacturing the 2-power supply semiconductor device according to the fifth embodiment will be now described.
As shown inFIG. 50,isolation oxide film2 is formed on the main surface of ptype semiconductor substrate1 to surround an active region. Secondgate insulating film4 is formed on the active region of the main surface ofsemiconductor substrate1. First dopedpolysilicon film3 is formed on secondgate insulating film4 andisolation oxide film2. Thereafter, a resistpattern5ais formed on first dopedpolysilicon film3 positioned in the high Vdd region.
First dopedpolysilicon film3 and secondgate insulating film4 present in the low Vdd region are removed by isotropic etching. Thereafter, resistpattern5ais removed. Thus, the structure as shown inFIG. 51 results.
Firstgate insulating film6 is formed on the portion of the main surface ofsemiconductor substrate1 positioned in the low Vdd region and on first dopedpolysilicon film3 by means of thermal oxidation. Thus, the structure as shown inFIG. 52 results. Before forming second gate electrode19 (seeFIG. 49), an oxidizing step to form firstgate insulating film6 is performed, a gate bird's beak caused by oxidation of a side ofsecond gate electrode19 can be prevented. Furthermore, since first dopedpolysilicon film3 is formed on secondgate insulating film4, a resist pattern is not directly formed onto the surface of secondgate insulating film4. As a result, a processing of removing the resist pattern is not directly performed on the surface of secondgate insulating film4, and defects on the surface of secondgate insulating film4 can be prevented.
Then, second dopedpolysilicon film7 is formed on firstgate insulating film6 andisolation oxide film2. By forming resistpatterns5band5con the portion of second dopedpolysilicon film7 in the low Vdd region and on the region to be second gate electrode19 (seeFIG. 49), the structure as shown inFIG. 53 results.
Then, using resistpatterns5band5cas masks, anisotropic etching is performed to remove part of second dopedpolysilicon film7, firstgate insulating film6, and firstdoped polysilicon3 to form second gate electrode19 (seeFIG. 49). Thereafter, resistpatterns5band5c(seeFIG. 53) are removed. Resistpatterns5dand5eare formed on secondinsulating film4,second gate electrode19, and the region to be thegate electrode18 of doped polysilicon film7 (seeFIG. 49). Thus, the structure as shown inFIG. 54 results.
Then, using resistpatterns5dand5eas masks, anisotropic etching is performed to partially remove second dopedpolysilicon film7 and thus first gate electrode18 (seeFIG. 49) is formed. Thereafter, resistpatterns5dand5eare removed to obtain the structure as shown inFIG. 55. Then, an impurity is introduced into a prescribed region of the main surface ofsemiconductor substrate1, followed by formation ofsidewall oxide films9 and20 (seeFIG. 49) on sides of first andsecond gate electrodes18 and19, to form the semiconductor device as shown inFIG. 49.
Seventh Embodiment
Referring toFIG. 56, in a 2-power supply semiconductor device including a plurality of field transistors according to a seventh embodiment of the invention, there are formed, on a main surface of a ptype semiconductor substrate1, a first field effect transistor supplied with a first power supply voltage (low Vdd) and a second field effect transistor supplied with a second voltage (high Vdd) higher than the first power supply voltage, spaced apart from each other. Anisolation oxide film2 is formed between the first and second field effect transistors.
In the low Vdd region, there are formed, on the main surface ofsubstrate1, a pair of first source/drain regions10 and a pair ofimpurity diffusion regions8, spaced apart from each other and having a first channel region therebetween. Low concentration, n typeimpurity diffusion region8 formed adjacent to the first channel region and high concentration, n typeimpurity diffusion region10 formed adjacent to n typeimpurity region8 constitute an LDD structure. A firstgate insulating film6 is formed on the first channel region. A dopedpolysilicon film31 is formed on firstgate insulating film6.Doped polysilicon film31 has a relatively small thickness for example of about 500 Å. Anatural oxide film30 is formed on dopedpolysilicon film31. A dopedpolysilicon film7 is formed onnatural oxide film30.Doped polysilicon film31,natural oxide film30 and dopedpolysilicon film7 formfirst gate electrode18. Asidewall oxide film9 is formed on a side offirst gate electrode18. First source/drain regions10 andimpurity diffusion regions8, firstgate insulating film6 andfirst gate electrode18 form first field effect transistor.
In the high Vdd region, there are formed, on the main surface ofsemiconductor substrate1, a pair of second source/drain regions17, a pair ofimpurity diffusion regions16, spaced apart from each other and having a second channel therebetween. Low concentration, n typeimpurity diffusion region16 formed adjacent to the second channel region and high concentration, n typeimpurity diffusion region17 formed adjacent to n typeimpurity diffusion region16 constitute an LDD structure. A secondgate insulating film4 is formed on the second channel region. A dopedpolysilicon film32 is formed on secondgate insulating film4.Doped polysilicon film32 has a relatively small thickness for example of about 500 Å.Natural oxide film30 is formed on dopedpolysilicon film32.Doped polysilicon film7 is formed onnatural oxide film30.Doped polysilicon film32,natural oxide film30 and dopedpolysilicon film7 constitutesecond gate electrode19. Asidewall oxide film9 is formed on a side ofsecond gate electrode19. Second source/drain regions17,impurity diffusion regions16, secondgate insulating film4, andsecond gate electrode19 form the second field effect transistor.
Thus,doped polysilicon films31 and32 are formed on first and secondgate insulating films6 and4, it is not necessary to form a resist pattern directly on the surfaces of first and secondgate insulating films6 and4 in the following manufacturing steps. Furthermore, an oxidizing step to form firstgate insulating film6 can be performed using dopedpolysilicon film32 as a mask, before formingsecond gate electrode19. Thus, in the step of oxidizinggate insulating film6, as a result, a lower part of a side ofsecond gate electrode19 can be prevented from being oxidized, and a gate bird's beak can be avoided. Thus, the threshold voltages of the field effect transistors can be prevented from increasing. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
Furthermore, by makingdoped polysilicon films31 and32 formed on first and secondgate insulating films6 and4 substantially equal in thickness, the thicknesses of dopedpolysilicon films31 and32 to be etched away for forming first andsecond gate electrodes18 and19 can be made substantially equal in the regions to form first andsecond gate electrodes18 and19. As a result, during etching for forming first andsecond gate electrodes18 and19, the amount of etching to formfirst gate electrode18 can be almost the same as the amount of etching to formsecond gate electrode19. As a result, the amount of overetching in forming first andsecond gate electrodes18 and19 can be reduced. Therefore, damages caused by overetching ofsemiconductor substrate1 positioned under dopedpolysilicon films31 and32 to be etched away can be prevented. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented.
Furthermore, since dopedpolysilicon films31 and32 are formed on first and secondgate insulating films6 and4, a resist pattern is not formed directly on first and secondgate insulating films6 and4. As a result, defects such as local irregularities in the gate insulating film caused by the step of ashing to remove a resist pattern can be prevented from being generated in first and secondgate insulating films6 and4.
Referring to FIGS.57 to60, a method of manufacturing the 2-power supply semiconductor device according to the seventh embodiment of the invention will be described.
As shown inFIG. 57,isolation oxide film2 to surround an active region is formed on the main surface of ptype semiconductor substrate1. Secondgate insulating film4 is formed on the active region of the main surface ofsemiconductor substrate1.Doped polysilicon film32 is formed on secondgate insulating film4 andisolation oxide film2. Thereafter, a resistpattern5fis then formed on dopedpolysilicon film32 positioned in the high Vdd region.
Using resistpattern5fas a mask, secondgate insulating film4 and dopedpolysilicon film32 positioned in the low Vdd region are etched away, followed by removal of resistpattern5f. Since dopedpolysilicon film32 is formed on secondgate insulating film4, resistpattern5fis not directly formed on secondgate insulating film4. As a result, defects such as fine irregularities in the surface of secondgate insulating film4 caused by the removal of resistpattern5fcan be prevented.
As shown inFIG. 58, firstgate insulating film6 is formed on the main surface ofsemiconductor substrate1 positioned in the low Vdd region and on dopedpolysilicon film32.Doped polysilicon film31 is then formed on first gate insulating film andisolation oxide film2. A resistpattern5iis formed on dopedpolysilicon film31 in the low Vdd region.
Since dopedpolysilicon film32 is formed on secondgate insulating film4, an oxidizing step to form firstgate insulating film6 can be performed using dopedpolysilicon film32 as a mask before forming second gate electrode19 (seeFIG. 56). Thus, in the step of oxidizinggate insulating film6, a lower part of a side ofsecond gate electrode19 can be prevented from being oxidized, and a gate bird's beak can be avoided. Thus, the threshold voltages of the field effect transistors can be prevented from increasing. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
Furthermore, by makingdoped polysilicon films31 and32 substantially equal in thickness, in the step of etching to form first andsecond electrodes18 and19 (seeFIG. 56), the amount of etching to formfirst gate electrode18 can be substantially the same as the amount of etching to formsecond gate electrode19. As a result, the amount of overetching during forming first andsecond gate electrodes18 and19 can be reduced.
Then,doped polysilicon film31 andgate insulating film6 positioned in the high Vdd region are etched away, using resistpattern5ias a mask, followed by removal of resistpattern5i. Thus, the structure as shown inFIG. 59 results. Herein,polysilicon films31 and32 are laid out such that the films do not overlap on the main surface ofsemiconductor substrate1 andisolation oxide film2. Thus, in the manufacture of the semiconductor device, there is no such region having a thickness as large as the sum of the thicknesses of dopedpolysilicon films31 and32 to be etched away. As a result, the doped polysilicon film will not have a locally thick region, the etching margin during etching to formgate electrodes18 and19 can be improved.
A part of the surfaces of first and seconddoped polysilicon films31 and32 is isotropically etched away. A dopedpolysilicon film7 having for example a thickness of about 1500 Å is formed on the entire surface ofsemiconductor substrate1. At the time,natural oxide film30 has been formed on the surfaces of dopedpolysilicon films31 and32. Resistpatterns5gand5hare then formed on dopedpolysilicon film7. Thus, the structure as shown inFIG. 60 results.
Thereafter, using resistpatterns5gand5has masks, part of dopedpolysilicon films7,31 and32, andnatural oxide film30 is etched away to form first andsecond gate electrodes18 and19 (seeFIG. 56). An impurity is introduced into a prescribed region of the main surface ofsemiconductor substrate1, followed by formation of a sidewall oxide film9 (seeFIG. 56) on sides of first andsecond gate electrodes18 and19, and the semiconductor device as shown inFIG. 56 results. Herein, if the thickness of dopedpolysilicon films31 and32 is for example not less than 100 Å, during etching to form first andsecond gate electrodes18 and19, part of dopedpolysilicon films31 and32 having a sufficient thickness will not be removed during removingnatural oxide film30, and damages by the etching are not caused on first and secondgate insulating films6 and4 positioned under dopedpolysilicon films31 and32 and in the main surface ofsemiconductor substrate1. As a result, during etching to form first andsecond gate electrodes18 and19, the etching process to removenatural oxide film30 can be readily performed, and the etching margin can be improved as compared to the case of removingnatural oxide film30 by etching the doped polysilicon films.
Referring toFIG. 61, a 2-power supply semiconductor device including a plurality of field effect transistors according to a first variation of the seventh embodiment has basically the same structure as the 2-power supply semiconductor device according to the seventh embodiment shown inFIG. 56 with difference being thatsilicon films33 and34 having an amorphous structure are formed on first and secondgate insulating films6 and4. Sincesilicon films33 and34 formed on first and secondgate insulating films6 and4 have an amorphous structure, an isotropic etching agent used for isotropicallyetching silicon films33 and34 does not run insidesilicon films33 and34 to reach first and secondgate insulating films6 and4. This is in contrast to the case ofpolysilicon film32 having a large number of crystals as shown inFIG. 62 where the isotropic etching agent runs along grain boundaries to reachgate insulating film4. Meanwhile, as shown inFIG. 63, in the case ofsilicon film34, having an amorphous structure which is free from grain boundaries, the isotropic etching agent does not run along grain boundaries to reachgate insulating film4.
Therefore, damages caused by the isotropic etching agent can be prevented ingate insulating films4, and the fluctuation of the threshold voltages of field effect transistors caused by such damages in the gate insulating film can be prevented. As a result, electrical characteristics of the 2-power supply semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
Referring toFIG. 64, a 2-power supply semiconductor device including a plurality of field effect transistors according to a second variation of the seventh embodiment has basically the same structure as the 2-power supply semiconductor device according to the seventh embodiment shown inFIG. 56, with different being that thefirst gate electrode31ais formed only of doped polysilicon film as shown inFIG. 64, and that thesecond gate electrode32ais formed only of doped polysilicon film. Since the first andsecond gate electrodes31aand32aare formed of doped polysilicon films, respectively, the method of forming doped polysilicon film7 (seeFIG. 56) in the 2-power supply semiconductor device according to the seventh embodiment can be omitted. Thus, the manufacturing process can be simplified as compared to the 2-power supply semiconductor device according to the seventh embodiment.
Referring to FIGS.65 to70, a method of manufacturing the 2-power supply semiconductor device according to the second variation of the seventh embodiment will be now described.
As shown inFIG. 65,isolation oxide film2 is formed to surround an active region on the main surface of p type semiconductor substrate. Secondgate insulating film4 is formed on the active region of the main surface ofsemiconductor substrate1.Doped polysilicon film32 is formed on secondgate insulating film4 andisolation oxide film2. A resistpattern5fis formed on dopedpolysilicon film32 positioned in the high Vdd region.
Using resistpattern5fas a mask, part of dopedpolysilicon film32 and secondgate insulating film4 is removed, followed by removal of resistpattern5f. The structure as shown inFIG. 66 thus results. Herein, the thickness of dopedpolysilicon film32 has such a thickness to be used as a gate electrode.
First gate insulating film6 (seeFIG. 67) is formed on the main surface ofsemiconductor substrate1 and on dopedpolysilicon film32. Doped polysilicon film31 (seeFIG. 67) is formed on firstgate insulating film6. A resistpattern5j(seeFIG. 67) is formed in the portion positioned in the low Vdd region on dopedpolysilicon film31. Thus, the structure as shown inFIG. 67 results.
Since dopedpolysilicon film32 is formed on secondgate insulating film4, an oxidizing step to form firstgate insulating film6 may be performed using dopedpolysilicon film32 as a mask before formingsecond gate electrode32a(seeFIG. 64). Thus, in the step of oxidizinggate insulating film6, as a result, a lower part of a side ofsecond gate electrode32acan be prevented from being oxidized, and a gate bird's beak can be avoided. Thus, the threshold voltages of the field effect transistors can be prevented from increasing. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
Doped polysilicon film31 and firstgate insulating film6 positioned in the high Vdd region are etched away, using resistpattern5jas a mask, followed by removal of resistpattern5j, and the structure as shown inFIG. 68 thus results.
Then, as shown inFIG. 69, resistpatterns5gand5hare formed on dopedpolysilicon films31 and32.
As shown inFIG. 70, using resistpatterns5gand5h(seeFIG. 69) as masks, part of dopedpolysilicon films31 and32 (seeFIG. 69) is anisotropically etched away to form first andsecond gate electrodes31aand32a. Since first andsecond gate electrodes31aand32aare formed only of dopedpolysilicon films31 and32 (seeFIG. 69) serving as a protection conductive film, the number of steps for forming the doped polysilicon films can be reduced as compared to the process of manufacturing the 2-power supply semiconductor device according to the seventh embodiment shown in FIGS.57 to60.
An impurity is then introduced into a prescribed region of the main surface ofsemiconductor substrate1 followed by formation of a sidewall oxide film9 (seeFIG. 64) on sides of first andsecond gate electrodes31aand32a(seeFIG. 64), and the semiconductor device as shown inFIG. 64 results.
As an application of the second variation of the fourth embodiment, after oxidizing the main surface ofsemiconductor substrate1 positioned in the low Vdd region before forming firstgate insulating film6, a part of the surface is isotropically etched to prevent the quality ofgate insulating film6 from deteriorating. In addition, as applications of the first to third embodiment,doped polysilicon films31 and32 serving as a protection conductive film to protect the gate insulating films may be formed on first and secondgate insulating films6 and4 to bring about the same effect as the seventh embodiment.
Eighth Embodiment
Referring toFIG. 71 in a 2-power supply semiconductor device including a plurality of field effect transistors according to an eighth embodiment of the invention, there are formed, on a main surface of a ptype semiconductor substrate1, a first field effect transistors supplied with a first power supply voltage (low Vdd) and a second field effect transistor supplied with a second voltage (high Vdd) higher than the first power supply voltage, spaced apart from each other. Anisolation oxide film2 is formed between the first and second field effect transistors.
In the low Vdd region, there are formed, on the main surface ofsubstrate1, a pair of first source/drain regions10, a pair ofimpurity diffusion regions8, spaced apart from each other and having a first channel region therebetween. Low concentration, n typeimpurity diffusion region8 formed adjacent to the first channel region and high concentration n typeimpurity diffusion region10 formed adjacent to n typeimpurity diffusion region8 constitute an LDD structure. A firstgate insulating film6 is formed on the first channel region. A dopedpolysilicon film31 is formed on firstgate insulating film6. Anitride film27 is formed on dopedpolysilicon film31. A dopedpolysilicon film7 is formed onnitride film27.Doped polysilicon films31 and7, andnitride film27 form afirst gate electrode18. Asidewall oxide film9 is formed on a side offirst gate electrode18. The first source/drain regions10,impurity diffusion regions8, firstgate insulating film6, andfirst gate electrode18 form the first field effect transistor.
In the high Vdd region, there are formed, on the main surface ofsemiconductor substrate1, a pair of second source/drain regions17, and a pair ofimpurity diffusion regions16, spaced apart from each other and having a second channel region therebetween. Low concentration, n typeimpurity diffusion region16 formed adjacent to the second channel region and high concentration, n typeimpurity diffusion region17 formed adjacent to n typeimpurity diffusion region16 constitute an LDD structure. A secondgate insulating film4 is formed on the second channel region. A dopedpolysilicon film32 is formed on secondgate insulating film4.Nitride film27 is formed on dopedpolysilicon film32.Doped polysilicon films7 and32 andnitride film27 formsecond gate electrode19.Sidewall oxide film9 is formed on a side ofsecond gate electrode19. Second source/drain regions17,impurity diffusion regions16, secondgate insulating film4 andsecond gate electrode19 form the second field effect transistor.
Since dopedpolysilicon film32 is formed on secondgate insulating film4, an oxidizing step to form firstgate insulating film6, using dopedpolysilicon film32 as a mask can be performed before formingsecond gate electrode19. As a result, in the step of oxidizinggate insulating film6, a lower part of a side ofsecond gate electrode19 can be prevented from being oxidized, and a gate bird's beak can be avoided. Thus, the threshold voltages of the field effect transistors can be prevented from increasing. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
Furthermore,nitride film27 is formed on dopedpolysilicon films31 and32 serving as a protection conductive film, a natural oxide film difficult to control in thickness can be prevented from being formed on dopedpolysilicon films31 and32. As a result, the fluctuation of the thicknesses of dopedpolysilicon films31,32 and7 caused by such a natural oxide film can be prevented. As a result, the amount of overetching can be reduced in etching to form first andsecond gate electrodes18 and19. As a result, damages tosemiconductor substrate1 positioned under dopedpolysilicon films31 and32 to be etched away, caused by overetching can be prevented.
Referring toFIG. 72, a method of manufacturing the 2-power supply semiconductor device according to the eighth embodiment of the invention will be described.
After performing the steps in the manufacture of the 2-power supply semiconductor device according to the seventh embodiment shown in FIGS.57 to59, dopedpolysilicon films31 and32 are nitrided by lamp annealing as shown inFIG. 72, andnitride film27 serving as an oxidation protection film is formed. Herein,doped polysilicon film32 is formed on secondgate insulating film4, and therefore an oxidizing step to form firstgate insulating film6 can be performed using dopedpolysilicon film32 as a mask before formingsecond gate electrode19. Thus, in the step of oxidizinggate insulating film6, a lower part of a side ofsecond gate electrode19 can be prevented from being oxidized, and a gate bird's beak can be avoided. Thus, the threshold voltages of the field effect transistors can be prevented from increasing. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
Sincenitride film27 is formed on the surfaces of dopedpolysilicon films31 and32, a natural oxide film difficult to control in thickness can be prevented from being formed on dopedpolysilicon films31 and32. As a result, variations of the thicknesses of dopedpolysilicon films31,32 and7 caused by such a natural oxide film can be prevented. As a result, the amount of overetching during etching to form first andsecond gate electrodes18 and19 can be reduced. As a result, damages caused by overetching tosemiconductor substrate1 positioned under dopedpolysilicon films31 and32 to be etched away can be prevented.
As is the case with the 2-power supply semiconductor device according to the seventh embodiment shown inFIG. 60, dopedpolysilicon film7 is formed in the low Vdd region and the high Vdd region. Resist patterns are thereafter formed on dopedpolysilicon film7, anisotropic etching is performed using the resist patterns as a mask to form first andsecond gate electrodes18 and19 (seeFIG. 71). An impurity is introduced into the main surface ofsemiconductor substrate1, followed by formation of a sidewall oxide film9 (seeFIG. 71) on sides of first andsecond gate electrodes18 and19, and the semiconductor device as shown inFIG. 71 is thus obtained.
Ninth Embodiment
Referring toFIG. 73, In a 2-power supply semiconductor device including a plurality of field transistors according to a ninth embodiment of the invention, there are formed, on a main surface of a ptype semiconductor substrate1, a first field effect transistor supplied with a first power supply voltage (low Vdd) and a second field effect transistor supplied with a second voltage (high Vdd) higher than the first power supply voltage, spaced apart from each other. Anisolation oxide film2 is formed between the first and second field effect transistors.
In the low Vdd region, there are formed, on the main surface ofsubstrate1, a pair of first source/drain regions10, and a pair ofimpurity diffusion regions8, spaced apart from each other and having a first channel region therebetween. Low concentration, n typeimpurity diffusion region8 formed adjacent to the first channel region and high concentration, n typeimpurity diffusion region10 formed adjacent to n typeimpurity region8 constitute an LDD structure. A firstgate insulating film25 is formed on the first channel region. Afirst gate electrode18 is formed on first insulatingfilm25. Asidewall oxide film9 is formed on a side offirst gate electrode18. First source/drain regions10,impurity diffusion regions8, firstgate insulating film25, andfirst gate electrode18 form the first field effect transistor.
In the high Vdd region, there are formed, on the main surface ofsemiconductor substrate1, a pair of second source/drain regions17, and a pair ofimpurity diffusion regions16, spaced apart from each other and having a second channel therebetween. Low concentration, n typeimpurity diffusion region16 formed adjacent to the second channel region and high concentration, n typeimpurity diffusion region17 formed adjacent to n typeimpurity diffusion region16 constitute an LDD structure. A secondgate insulating film4 is formed on the second channel region. Asecond gate electrode19 is formed on secondgate insulating film4.Sidewall oxide film9 is formed on a side ofsecond gate electrode19. Second source/drain regions17,impurity diffusion regions16, secondgate insulating film4 andsecond gate electrode19 form the second field effect transistor.
Herein, in the 2-power supply semiconductor device according to the ninth embodiment, as will be described in connection with the following manufacturing steps, among first and secondgate insulating films25 and4 having substantially the same thickness, only a part of firstgate insulating film25 is isotropically etched to be reduced in thickness. Therefore, firstgate insulating film25 can be formed before formingsecond gate electrode19. As a result, a lower part of a side ofsecond gate electrode19 can be prevented from being oxidized in the step of oxidizing to form firstgate insulating film25, and a gate bird's beak caused by the oxidation can be prevented. Therefore, the threshold voltages of the field effect transistors can be prevented from increasing.
Referring to FIGS.74 to78, a method of manufacturing the 2-power supply semiconductor device according to the ninth embodiment will be now described.
As shown inFIG. 74,isolation oxide film2 is formed to surround an active region on the main surface of ptype semiconductor substrate1. Secondgate insulating film4 is formed on the active region of the main surface ofsemiconductor substrate1. A resistpattern5fis formed on secondgate insulating film4 andisolation oxide film2, positioned in the high Vdd region.
Using resistpattern5fas a mask, a part of the surface of secondgate insulating film4 positioned in the low Vdd region is isotropically etched away to form first gate insulating film25 (seeFIG. 75) thinner than secondgate insulating film4 positioned in the high Vdd region. First and secondgate insulating films25 and4 are formed thicker than their final thickness when used as the gate insulating films for the field effect transistors. The difference between secondgate insulating film4 and firstgate insulating film25 in thickness is set substantially identical to the final difference in thickness between the first and second gate insulating films used in the field effect transistors. Resistpattern5fis then removed to obtain the structure as shown inFIG. 75.
At the time, the surface of secondgate insulating film4 positioned in the high Vdd region may suffer from defects such as local irregularities caused by the process of removing the resist pattern. The surfaces of first and secondgate insulating films25 and4 are isotropically etched to remove the defects formed by the removal of the resist pattern. The first and secondgate insulating films25 and4 are isotropically etched to have the thicknesses of the gate insulating films used in the first and second field effect transistors.
Since first and secondgate insulating films25 and4 are formed of a single insulating film, only a single oxidizing step is necessary to form first and secondgate insulating films25 and4. As a result, as compared to the conventional case, the number of oxidizing steps can be reduced by one, and the process of manufacturing the semiconductor device can thus be simplified. Furthermore, the first and second gate insulating films are formed by means of isotropic etching, possible defects such as local irregularities caused by the removal of resistpattern5f(seeFIG. 74) present on the surface of secondgate insulating films4 can be removed by the isotropic etching process. As a result, the first and secondgate insulating films25 and4 will be highly reliable, and the fluctuation of the threshold voltages of the field effect transistors can be prevented.
As shown inFIG. 76, a dopedpolysilicon film3 is then formed on first and secondgate insulating films25 and4, and onisolation oxide film2. Resistpatterns5band5hare formed on dopedpolysilicon film3.
Using resistpatterns5gand5has masks, a part of dopedpolysilicon film3 is anisotropically etched away to form first andsecond gate electrodes18 and19 (seeFIG. 77), followed by removal of resistpatterns5gand5h. As shown inFIG. 77, an impurity is then introduced into the main surface ofsemiconductor substrate1, using first andsecond gate electrodes18 and19 as masks, n typeimpurity diffusion regions8 and16 are formed on the main surface ofsemiconductor substrate1.
Herein, the oxidizing step to form first and secondgate insulating films25 and4 can be performed before formingsecond gate electrode19, a lower part of a side of the gate electrode can be prevented from being oxidized, and a gate bird's beak can be avoided. Thus, the threshold voltages of the field effect transistors can be prevented from increasing. As a result, electrical characteristics of the semiconductor device including the plurality of field effect transistors can be prevented from deteriorating.
Asidewall oxide film9 is then formed on sides of first andsecond gate electrodes18 and19 as shown inFIG. 78. Using first andsecond gate electrodes18 and19 andsidewall oxide film9 as masks, impurity ions are introduced into the main surface ofsemiconductor substrate11 to form high concentration, n typeimpurity diffusion regions10 and17. The semiconductor device as shown inFIG. 73 is thus obtained.
Although the present invention has been described and illustrated in detail, it is clearly understood that the same is by way of illustration and example only and is not to be taken by way of limitation, the spirit and scope of the present invention being limited only by the terms of the appended claims.