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US1666488A - Apparatus for extracting oil from shale - Google Patents

Apparatus for extracting oil from shale
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Publication number
US1666488A
US1666488AUS166223AUS16622327AUS1666488AUS 1666488 AUS1666488 AUS 1666488AUS 166223 AUS166223 AUS 166223AUS 16622327 AUS16622327 AUS 16622327AUS 1666488 AUS1666488 AUS 1666488A
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shale
unit
oil
pipe
tube
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US166223A
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Crawshaw Richard
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April 17, 1928.
R. cRAwsHAw APHKRATUS FOR EXTRACTING OIL FROM SHALE s Sheets-Sheet 1 Filed Feb. 5. 1927 V w I April 17' 1928.
1,666,488 R. CRAWSHAW APPARATUS FOR EXTRACTING OIL FROM SHALE Filed Feb. 5. 1927 5 Sheets-Sheet 2 F/r wrd d'mwJ/zaw, Zlwowntoz l/w'fnesses R. CRAWSHAW APPARATUS FOR EXTRACTING OIL FROM SHALE April 17, 1928.
3 Sheets-Sheet 3 Filed Feb. 5. 1927 Patented Apr. 17, 1928.
PATENT OFFICE.
RICHARD CRAWSHAW, OF DRUMRIGHT, OKLAHOMA.
APPARATUS FOR EXTBACTING OIL FROM SHALE.
Application filed February 5, 1927. Serial No. 166,223.
The present invention relates to an improved apparatus for extracting oil and byproducts from shale and has for its primary object to provide means whereby the oil extraction can be effected on a practical commercial basis.
A further object of the invention is the provision of an apparatus whereby oil may be extracted from shale at a minimum, expenditure of time and labor.
Another object of the invention is the provision of an apparatus designed to be operated directly in contact with the shale in situ so that the oil and gas may be extracted directly without mining of the shale.
Still another object of the invention is the provision of an apparatus which is comparatively simple and durable of construction and which will be efficient for the purpose intended.
Other objects and advantages of the invention will become apparent as the description progresses.
In the accompanying drawings forming a part of this specification and in which like reference characters are employed to designate corresponding parts throughout the same; 1
Figure 1 is a side elevational view of a portion of the apparatus,
Figure 2 is a similar view of the remaining portion,
Figure 3 is a vertical longitudinal sectional view through the portion of the apparatus shown in Figure 1,
Figure 4: is a similar view through the portion of the apparatus shown in Figure 2,
Figure 5 is an enlarged vertical longitudinal sectional view through the heating unit,
Figure 6 is an end elevational View of the unit, V
Figure ,7 is an end elevational view of the unit looking at the inner end,
Figure 8 is a transverse sectional view taken on the line 88 of Figure 5,
Figure 9 is a similar view taken on the line 9-9 of Figure 3, and
Figure 10 is a transverse sectional view taken on the line 1010 of Figure 4.
As is well known to those familiar with the present method of extracting oil from tion resides in the provision of a method and apparatus-whereby the oil will be directly extracted from the shale in situ so as to obviate the mining and transportation of the shale from the mines to the heating retorts.
WVith this in mind, my improved apparatus embodies a series of conducting pipes arranged in concentric position extending to and in communication with a heating unit embedded in the shale strata. The heating unit is arranged to sufficiently heat the immediate shale so as to separate the oil and gases therefrom, the oil and gas being conducted through suitable conducting pipes to a suitable reservoir.
Referring particularly to the drawings, thenumeral 15 generally designates a longitudinal tube section threaded at its ends. Connected with one end of thetube 15 and arranged to be embedded in the shale is a cylindrical heater 16 provided on its inner end with a reduced interiorly and exteriorly screw threadednipple 17 The interior threads of thenipple 17 threadedly engage thetube 15.
The heating unit 16 is formed with a central longitudinal bore tapered adjacent the outer end as at 18 and terminating in a reducedcentral bore 19 opening through the end of the heating unit. The exterior surface of the unit is formed with a plurality of annularcircumferential grooves 19 communicating a series ofradial bores 20. Theradial bores 20 communicate at their inner ends with a series of longitudinal bores 21 extending longitudinally. through the unit and opening through the inner end thereof. Formed longitudinally within the unit between the longitudinal bores 21 arebores 22 having their inner ends directed angularly toward the center of the unit. The present illustration embodies six such bores, three of thebores 24 extending in a straight line and opening through the outer end of the unit, while the remaining three are in communication withangular bores 23 opening through the rear end of the unit near thecenter thereof. The ends ofthebores 22 are closed byplugs 25. Fitted into the large their inner extremities connected with the.
heating element 26. The outer end of thecasing 27 is formed with an enlargedsleeve portion 29 held in position by apacking gland 30 connected with thetube 15.
Arranged concentrically about the major portion of thetube 15 and having its inner end threadedly connected with thenipple 17 of the unit is a conductingpipe 31 provided withapertures 32 adjacent its inner extremity, the longitudinal bores 21 communicating with saidpipe 31 as shown in Fig.
- 5. The outer end of the conductingpipe 31 is threadedly connected with apacking gland 33, this gland being provided with an annular recess in which is compressedpacking 34 tightly maintained in position by the gland 35 carried by acompanion flange 36 bolted to thepacking flange 33. From this construction it is apparent that the conductingpipe 31 is concentric to and spaced from thetube 15 so as to provide an annular passage between the interior of thepipe 31 and the exterior of the tube. 'Threadedly associated with the conductingpipe 31 adjacent its outer end is a cross fitting 37 embodying a central interiorly screw threadedsleeve 38 threadedly connected with the conducting pipe and formed with fourradial outlets 39. Threadedly connected with theoutlets 39 and adapted to control the discharge of matter therethrough arevalves 40 of any preferred type, preferably embodying rotatable taperedplugs 41 operable by a key.
As shown in the Figures 2 and 4 of the drawings, the heating unit 16 is of greater diameter than the exterior diameter of the conductingpipe 31. During the use of the apparatus, the heating unit is gradually driven into the shale strata and thus forms a passage between the exterior wall of the conducting pipe and the bore in the shale.
Acasing 42 is positioned concentrically about the intermediate portion of the conductingpipe 31 and is spaced therefrom, the inner end of thecasing 42 being snu ly fitted in the shale strata and securely held in position by means offlanges 43 threadedly con nected to the casing and secured to the shale by longitudinal bolts 44. The outer end of thecasing 42 is attached to the conductingpipe 31 by means of astuffing box 45 snugly embracing the connecting pipe and threadedly engaging the outer end of the casing.
Threadedly" connected with the exterior caspassage is formed between theconductingpipe 31 and theiutcriortube 15 forming a conduit for the passage of oil and gas extracted from the shale and communicating with the outlets of the cross fitting 37. The interiorcentral tube 15 provides a conduit for the conducting wires and also connects with a T fitting 48 threadedly connected with theinterior tube 15 adjacent its outer end. The fitting 48'is provided with a right angularlateral outlet 49 which is connected with a high pressure air tank or pump and in which a control Valve 50 is mounted to control the passage of compressed air. Thus, my improved method of extracting oil from shale embodies the projection of a heating unit into the natural shale strata designed to sufliciently heat the shale to extract the oil. The heating unit is gradually driven into the shale by periodic blasts of air projected through the unit de signed to readily disintegrate the burnt shale immediately forward of the unit. The oil and gas extracted from the shale is also removed under suitable air pressure.
In the application of the apparatus, the heating unit 16 and conduits connected thereto are periodically driven into the shale by intermittently discharging a compressed air charge through thevalve 50 and the central interior tube of the apparatus. The compressed air is discharged through the unit by passage through the longitudinalconcentric bores 22, 23 and 24 so as to escape at the forward end of the unit and disintegrate the shale. During the operation of the apparatus-the unit is heated to a suitable temperature, preferably about 500 degrees Fahrenheit, by means of the electric 1heating element 26 which is supplied with current by the conductingwires 28. The inner ends of thewires 28 are connected with a suitable source ofelectricity, preferably with a water driven generator. lVhen the shale has been sufficiently heated by means of the heating unit, the oil and gas extracted therefrom will be discharged through theradial bores 20 of the unit and theopenings 32 ofthepipe 31 into the intermediate passage between thepipe 31 and theinterior tube 15. The oil and gas is driven through the passage by means of compressed air admitted into the exterior passage through one of thebranches 47 of the cross fitting 46, and is discharged through thebranches 39 of the cross fitting 37, the oil flowing downwardly through the lower branch into a suitable receptacle, while the ga's will rise through the upper branch into a suitable container. Occasionally, during the use of the apparatus, it is desirable to admit air under relatively high pressure through the outlet of the fitting 46 so as to clear the radial bores 20 andopenings 32 and prevent obstruction thereof.
It will thus be apparent, that the present invention provides a relatively simple apparatus for the extraction of oil and gas from shale, producing means whereby this operation may be accomplished at a minimum expense so as to effect acommercially practical oil producing method.
It is to be understood that the form of my invention herewith shown'and described is tobe taken as the preferred example of the same, and that various changes asto the shape, size and arrangement of parts may be resorted to without departing from the spirit of the invention or the scope of the subjoined claims;
Having thus described my invention, I
claim:
1. An apparatus for extracting oil from shale comprising a heating unit adapted to be projected into the shale, a series of conducting pipes conncted with the unit, one of the pipes forming a.conduit for the oil accumulating about the unit, a compressed air line connected with one of the pipes and adapted to force the oil from the shale outwardly into a suitable container, and means for periodically cleaning the pipes and outlets.
2. An apparatus for extracting oil from shale including a heating unit formed with a central bore and a series of longitudinally extending bores, an electric heating element mounted in the central bore ofthe-heating unit, conductor wires connected to the heating element and with a source of electric energy for supplying current to the said heating element, an interior tube connected with the inner end of the heating unit and forming a housing forthe conductor wires, a compressed air pipe connected with the said tube and adapted to permit periodic dischargeof compressed air through the pipe and heating unit,a conducting pipe arranged concentrically about the interior tube and connected with the inner end of the heating unit, the said conducting pipe being provided with series of apertures adjacent its outer end, a fitting connected with the conducting pipe for the connection therewith of an oil delivery pipe, an exterior casing arranged concentrically with respect to and spaced from the conducting pipe and communicating with the cavity formed in the shale, a fitting connected to and communicating with the said exterior casing, a compressed air pipe line connected with the said exterior casing for the delivery of compressed air into the exterior casing and through the conducting line to force the oil therethrough, and means for connecting the said pipes with the shale formation.
3. An apparatus for extracting oil from shale comprising a heating unit provided with a central bore extending therethrough and having a plurality of longitudinal bores, the outer surface of the unit being formed with circnmferential grooves communicating with radial bores in the wall of the unit, an electric heating element positioned in the central bore of the unit, a tube threadedly connected with the inner end of the unit, conductor wires extending through the tube and connected with the heating element, a conducting pipe arranged concentrically about the tube and spaced therefrom having its inner end threadedly connected with the unit, the exterior diameter of the unit being greater "than the diameter of the said conducting pipe to provide an exterior pas- 9 sage between the cavity in the shale and the exterior wall of the conducting pipe, an exterior/casing arranged concentrically about the intermediate portion of the conducting pipe and spaced therefrom to form an annular passage, several of the bores of the unit communicating with the interior of the central tube and others with the passage formed between the tube and the conducting pipe, and pipe fittings connecting the said interior pipe and exterior casing with a compressed air supply line for periodically admitting air therein for clearance of a passage for the unit and the extraction of the o1 4. In apparatus for extracting oil from shale in situ, a heating unit adapted to enter the shale, concentric conducting pi es connected with the unit, means for supp ying air under pressure to one of said pipes, the shell of the unit having passage ways communicating with the said pipe and open ing through the end of the said shell of the unit, the other pipe constituting a conduit for oil extracted from the shale and the said shell of the unit having other passage ways therein in communication with the last mentioned pipe and opening through the exterior surface ofthe shell.
5. In apparatus for extracting oil from shale in situ, a heating unit comprising a shell having an axial bore, an electrical resistance unit within the shell, a. pipe fitted to one end of the shell, the shell having an opening in its outer end communicating with the bore of the shell, the resistance unit having a longitudinal opening 'therethrough, means for supplying air under pressure to the said pipe, a second pipe fitted at one end 5 to'the shell of concentric with respect to the first'mentio'ned pipe to provide a passage way between-the the unit and surrounding and pipes, and-an oil delivery pipe leading from the last-mentioned pipe and communicating With the said passage Way, the shell of the 10 heating unit having oil passages communieating With said passage Way between the first and last mentioned pipes.
RICHARD GRAWSHAW.
US166223A1927-02-051927-02-05Apparatus for extracting oil from shaleExpired - LifetimeUS1666488A (en)

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Cited By (68)

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US2688464A (en)*1949-12-091954-09-07Socony Vacuum Oil Co IncProcess for thermally working oil shale
US2786660A (en)*1948-01-051957-03-26Phillips Petroleum CoApparatus for gasifying coal
US2914309A (en)*1953-05-251959-11-24Svenska Skifferolje AbOil and gas recovery from tar sands
US3396806A (en)*1964-07-281968-08-13Physics Internat CompanyThermal underground penetrator
US20020040778A1 (en)*2000-04-242002-04-11Wellington Scott LeeIn situ thermal processing of a hydrocarbon containing formation with a selected hydrogen content
US20030079877A1 (en)*2001-04-242003-05-01Wellington Scott LeeIn situ thermal processing of a relatively impermeable formation in a reducing environment
US20030080604A1 (en)*2001-04-242003-05-01Vinegar Harold J.In situ thermal processing and inhibiting migration of fluids into or out of an in situ oil shale formation
US20030098149A1 (en)*2001-04-242003-05-29Wellington Scott LeeIn situ thermal recovery from a relatively permeable formation using gas to increase mobility
US6588504B2 (en)2000-04-242003-07-08Shell Oil CompanyIn situ thermal processing of a coal formation to produce nitrogen and/or sulfur containing formation fluids
US20030155111A1 (en)*2001-04-242003-08-21Shell Oil CoIn situ thermal processing of a tar sands formation
US20030173081A1 (en)*2001-10-242003-09-18Vinegar Harold J.In situ thermal processing of an oil reservoir formation
US20030173085A1 (en)*2001-10-242003-09-18Vinegar Harold J.Upgrading and mining of coal
US20030196810A1 (en)*2001-10-242003-10-23Vinegar Harold J.Treatment of a hydrocarbon containing formation after heating
US6698515B2 (en)2000-04-242004-03-02Shell Oil CompanyIn situ thermal processing of a coal formation using a relatively slow heating rate
US6715546B2 (en)2000-04-242004-04-06Shell Oil CompanyIn situ production of synthesis gas from a hydrocarbon containing formation through a heat source wellbore
US6715548B2 (en)2000-04-242004-04-06Shell Oil CompanyIn situ thermal processing of a hydrocarbon containing formation to produce nitrogen containing formation fluids
US20040144541A1 (en)*2002-10-242004-07-29Picha Mark GregoryForming wellbores using acoustic methods
US20050269089A1 (en)*2004-04-232005-12-08Sandberg Chester LTemperature limited heaters using modulated DC power
US7011154B2 (en)2000-04-242006-03-14Shell Oil CompanyIn situ recovery from a kerogen and liquid hydrocarbon containing formation
US7090013B2 (en)2001-10-242006-08-15Shell Oil CompanyIn situ thermal processing of a hydrocarbon containing formation to produce heated fluids
US7096953B2 (en)2000-04-242006-08-29Shell Oil CompanyIn situ thermal processing of a coal formation using a movable heating element
US7104319B2 (en)2001-10-242006-09-12Shell Oil CompanyIn situ thermal processing of a heavy oil diatomite formation
US7121342B2 (en)2003-04-242006-10-17Shell Oil CompanyThermal processes for subsurface formations
US7165615B2 (en)2001-10-242007-01-23Shell Oil CompanyIn situ recovery from a hydrocarbon containing formation using conductor-in-conduit heat sources with an electrically conductive material in the overburden
US20070045267A1 (en)*2005-04-222007-03-01Vinegar Harold JSubsurface connection methods for subsurface heaters
US20070095536A1 (en)*2005-10-242007-05-03Vinegar Harold JCogeneration systems and processes for treating hydrocarbon containing formations
US20070108201A1 (en)*2005-04-222007-05-17Vinegar Harold JInsulated conductor temperature limited heater for subsurface heating coupled in a three-phase wye configuration
US20080035346A1 (en)*2006-04-212008-02-14Vijay NairMethods of producing transportation fuel
US20080087426A1 (en)*2006-10-132008-04-17Kaminsky Robert DMethod of developing a subsurface freeze zone using formation fractures
US20080087420A1 (en)*2006-10-132008-04-17Kaminsky Robert DOptimized well spacing for in situ shale oil development
US20080128134A1 (en)*2006-10-202008-06-05Ramesh Raju MudunuriProducing drive fluid in situ in tar sands formations
US20080173443A1 (en)*2003-06-242008-07-24Symington William AMethods of treating a subterranean formation to convert organic matter into producible hydrocarbons
US20080207970A1 (en)*2006-10-132008-08-28Meurer William PHeating an organic-rich rock formation in situ to produce products with improved properties
US20080230219A1 (en)*2007-03-222008-09-25Kaminsky Robert DResistive heater for in situ formation heating
US20080271885A1 (en)*2007-03-222008-11-06Kaminsky Robert DGranular electrical connections for in situ formation heating
US20080290719A1 (en)*2007-05-252008-11-27Kaminsky Robert DProcess for producing Hydrocarbon fluids combining in situ heating, a power plant and a gas plant
US20080289819A1 (en)*2007-05-252008-11-27Kaminsky Robert DUtilization of low BTU gas generated during in situ heating of organic-rich rock
US20090050319A1 (en)*2007-05-152009-02-26Kaminsky Robert DDownhole burners for in situ conversion of organic-rich rock formations
US20090071652A1 (en)*2007-04-202009-03-19Vinegar Harold JIn situ heat treatment from multiple layers of a tar sands formation
US20090145598A1 (en)*2007-12-102009-06-11Symington William AOptimization of untreated oil shale geometry to control subsidence
US20090189617A1 (en)*2007-10-192009-07-30David BurnsContinuous subsurface heater temperature measurement
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US20090260823A1 (en)*2008-04-182009-10-22Robert George Prince-WrightMines and tunnels for use in treating subsurface hydrocarbon containing formations
US7669657B2 (en)2006-10-132010-03-02Exxonmobil Upstream Research CompanyEnhanced shale oil production by in situ heating using hydraulically fractured producing wells
US20100089586A1 (en)*2008-10-132010-04-15John Andrew StaneckiMovable heaters for treating subsurface hydrocarbon containing formations
US20100089575A1 (en)*2006-04-212010-04-15Kaminsky Robert DIn Situ Co-Development of Oil Shale With Mineral Recovery
US20100101793A1 (en)*2008-10-292010-04-29Symington William AElectrically Conductive Methods For Heating A Subsurface Formation To Convert Organic Matter Into Hydrocarbon Fluids
US20100258291A1 (en)*2009-04-102010-10-14Everett De St Remey EdwardHeated liners for treating subsurface hydrocarbon containing formations
US20100282460A1 (en)*2009-05-052010-11-11Stone Matthew TConverting Organic Matter From A Subterranean Formation Into Producible Hydrocarbons By Controlling Production Operations Based On Availability Of One Or More Production Resources
US8151877B2 (en)2007-05-152012-04-10Exxonmobil Upstream Research CompanyDownhole burner wells for in situ conversion of organic-rich rock formations
US8151884B2 (en)2006-10-132012-04-10Exxonmobil Upstream Research CompanyCombined development of oil shale by in situ heating with a deeper hydrocarbon resource
US8230929B2 (en)2008-05-232012-07-31Exxonmobil Upstream Research CompanyMethods of producing hydrocarbons for substantially constant composition gas generation
US8616280B2 (en)2010-08-302013-12-31Exxonmobil Upstream Research CompanyWellbore mechanical integrity for in situ pyrolysis
US8616279B2 (en)2009-02-232013-12-31Exxonmobil Upstream Research CompanyWater treatment following shale oil production by in situ heating
US8622127B2 (en)2010-08-302014-01-07Exxonmobil Upstream Research CompanyOlefin reduction for in situ pyrolysis oil generation
US8631866B2 (en)2010-04-092014-01-21Shell Oil CompanyLeak detection in circulated fluid systems for heating subsurface formations
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US9016370B2 (en)2011-04-082015-04-28Shell Oil CompanyPartial solution mining of hydrocarbon containing layers prior to in situ heat treatment
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Cited By (487)

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US2786660A (en)*1948-01-051957-03-26Phillips Petroleum CoApparatus for gasifying coal
US2688464A (en)*1949-12-091954-09-07Socony Vacuum Oil Co IncProcess for thermally working oil shale
US2914309A (en)*1953-05-251959-11-24Svenska Skifferolje AbOil and gas recovery from tar sands
US3396806A (en)*1964-07-281968-08-13Physics Internat CompanyThermal underground penetrator
US6789625B2 (en)2000-04-242004-09-14Shell Oil CompanyIn situ thermal processing of a hydrocarbon containing formation using exposed metal heat sources
US20020040778A1 (en)*2000-04-242002-04-11Wellington Scott LeeIn situ thermal processing of a hydrocarbon containing formation with a selected hydrogen content
US20020046883A1 (en)*2000-04-242002-04-25Wellington Scott LeeIn situ thermal processing of a coal formation using pressure and/or temperature control
US20020076212A1 (en)*2000-04-242002-06-20Etuan ZhangIn situ thermal processing of a hydrocarbon containing formation producing a mixture with oxygenated hydrocarbons
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US8225866B2 (en)2000-04-242012-07-24Shell Oil CompanyIn situ recovery from a hydrocarbon containing formation
US8485252B2 (en)2000-04-242013-07-16Shell Oil CompanyIn situ recovery from a hydrocarbon containing formation
US8789586B2 (en)2000-04-242014-07-29Shell Oil CompanyIn situ recovery from a hydrocarbon containing formation
US7096941B2 (en)2000-04-242006-08-29Shell Oil CompanyIn situ thermal processing of a coal formation with heat sources located at an edge of a coal layer
US7096953B2 (en)2000-04-242006-08-29Shell Oil CompanyIn situ thermal processing of a coal formation using a movable heating element
US7086468B2 (en)2000-04-242006-08-08Shell Oil CompanyIn situ thermal processing of a hydrocarbon containing formation using heat sources positioned within open wellbores
US6581684B2 (en)2000-04-242003-06-24Shell Oil CompanyIn Situ thermal processing of a hydrocarbon containing formation to produce sulfur containing formation fluids
US7036583B2 (en)2000-04-242006-05-02Shell Oil CompanyIn situ thermal processing of a hydrocarbon containing formation to increase a porosity of the formation
US6588504B2 (en)2000-04-242003-07-08Shell Oil CompanyIn situ thermal processing of a coal formation to produce nitrogen and/or sulfur containing formation fluids
US7017661B2 (en)2000-04-242006-03-28Shell Oil CompanyProduction of synthesis gas from a coal formation
US6591907B2 (en)2000-04-242003-07-15Shell Oil CompanyIn situ thermal processing of a coal formation with a selected vitrinite reflectance
US6591906B2 (en)2000-04-242003-07-15Shell Oil CompanyIn situ thermal processing of a hydrocarbon containing formation with a selected oxygen content
US7011154B2 (en)2000-04-242006-03-14Shell Oil CompanyIn situ recovery from a kerogen and liquid hydrocarbon containing formation
US6997255B2 (en)2000-04-242006-02-14Shell Oil CompanyIn situ thermal processing of a hydrocarbon containing formation in a reducing environment
US6994161B2 (en)2000-04-242006-02-07Kevin Albert MaherIn situ thermal processing of a coal formation with a selected moisture content
US6994160B2 (en)2000-04-242006-02-07Shell Oil CompanyIn situ thermal processing of a hydrocarbon containing formation to produce hydrocarbons having a selected carbon number range
US6994168B2 (en)2000-04-242006-02-07Scott Lee WellingtonIn situ thermal processing of a hydrocarbon containing formation with a selected hydrogen to carbon ratio
US6991031B2 (en)2000-04-242006-01-31Shell Oil CompanyIn situ thermal processing of a coal formation to convert a selected total organic carbon content into hydrocarbon products
US6973967B2 (en)2000-04-242005-12-13Shell Oil CompanySitu thermal processing of a coal formation using pressure and/or temperature control
US6966372B2 (en)2000-04-242005-11-22Shell Oil CompanyIn situ thermal processing of a hydrocarbon containing formation to produce oxygen containing formation fluids
US6959761B2 (en)2000-04-242005-11-01Shell Oil CompanyIn situ thermal processing of a coal formation with a selected ratio of heat sources to production wells
US6953087B2 (en)2000-04-242005-10-11Shell Oil CompanyThermal processing of a hydrocarbon containing formation to increase a permeability of the formation
US6948563B2 (en)2000-04-242005-09-27Shell Oil CompanyIn situ thermal processing of a hydrocarbon containing formation with a selected hydrogen content
US6923258B2 (en)2000-04-242005-08-02Shell Oil CompanyIn situ thermal processsing of a hydrocarbon containing formation to produce a mixture with a selected hydrogen content
US6607033B2 (en)2000-04-242003-08-19Shell Oil CompanyIn Situ thermal processing of a coal formation to produce a condensate
US6913078B2 (en)2000-04-242005-07-05Shell Oil CompanyIn Situ thermal processing of hydrocarbons within a relatively impermeable formation
US6609570B2 (en)2000-04-242003-08-26Shell Oil CompanyIn situ thermal processing of a coal formation and ammonia production
US6910536B2 (en)2000-04-242005-06-28Shell Oil CompanyIn situ thermal processing of a hydrocarbon containing formation using a natural distributed combustor
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