本發明涉及一種毛髮調理組合物，更詳細而言，涉及一種含有高分子聚二甲基矽氧烷醇以及直鏈型矽氧烷類化合物作為有效成分，並提高毛髮的光澤度、柔順度以及光滑度的持久力的毛髮調理組合物，較佳為涉及一種受損毛髮的調理組合物。The present invention relates to a hair conditioning composition, and more particularly to a polymer containing a polydimethyl methoxyalkanol and a linear siloxane compound as an active ingredient, and improving the gloss and suppleness of the hair and A smoothing, long-lasting hair conditioning composition, preferably a conditioning composition involving damaged hair.
通常，賦予毛髮調理感（改善毛髮狀態）的產品可以分為需要清洗類型的產品（沖洗類產品）和不需要清洗類型的產品（免洗類產品）。需要清洗的產品可以分為護髮素、焗油劑、護髮膜(hair pack)、髮膜(hair mask)、頭髮精華素等，主要藉由在乳化劑型中含有四級陽離子表面活性劑以及少量的矽油或者合成油、天然油類等調理成分，對毛髮賦予光澤度和光滑度。In general, products that impart hair conditioning (improving hair condition) can be classified into products requiring a cleaning type (rinsing products) and products requiring no cleaning type (a disposable product). Products that need to be cleaned can be divided into hair conditioners, oil eliminants, hair packs, hair masks, hair serums, etc., mainly by containing a quaternary cationic surfactant and a small amount in the emulsifier type. The oyster sauce or synthetic oil, natural oils and other conditioning ingredients impart gloss and smoothness to the hair.
免洗類產品可以分為頭髮噴霧、亮髮素、護髮精華液、髮油等，藉由多種劑型賦予毛髮調理效果。The disposable products can be divided into hair spray, radiance, hair care essence, hair oil, etc., and the hair conditioning effect is imparted by various dosage forms.
對免洗類的毛髮調理組合物中使用的矽油而言，根據其種類或者分子量而具有多種功能，由此，即便具有相同化學結構的矽油，也會顯示出多種使用感特性。根據分子量以及黏度，矽顯示出多種形態，從分子量以及黏度最低的揮發性形態到分子量以及黏度增大的順序顯示為液體、有黏性的液體、黏膠(Gum)、凝膠、彈性體及樹脂的形態。即，矽的分子量增加時，黏性也會增加。The eucalyptus oil used in the disposable hair conditioning composition has various functions depending on its kind or molecular weight, and thus, even if it has the same chemical structure, eucalyptus oil exhibits various use sensibility characteristics. Depending on the molecular weight and viscosity, 矽 shows a variety of forms, from the molecular weight and the lowest viscosity of the volatile form to the molecular weight and the order of increasing viscosity is shown as liquid, viscous liquid, glue (Gum), gel, elastomer and The form of the resin. That is, when the molecular weight of cerium increases, the viscosity also increases.
在所述免洗類產品中，尤其護髮精華液是過量的矽油被分散的劑型，當用在毛髮上時，可以立即賦予光澤度和光滑度，但是存在因過量的矽油導致使用上的黏膩感、毛髮的黏糊感等缺點的問題。In the disposable product, in particular, the hair care essence is an excessive amount of the eucalyptus oil dispersed type, and when used on the hair, the gloss and smoothness can be immediately imparted, but there is a stickiness due to excessive eucalyptus oil. The problem of shortcomings such as greasy feeling and sticky feeling of hair.
另外，習知毛髮調理組合物（劑型）雖然可以立即賦予毛髮光澤度和光滑度，但是其持久力短且在手和毛髮上會感覺到油膩（Oily）的殘留感。習知技術為了完善所述問題，使用了過量的矽油以及揮發性矽油、清爽使用感的潤滑劑等，然而其效果不能持續很久，而且引起使用上的黏膩感以及毛髮的厚重下垂等問題（參考專利文獻1和2）。Further, the conventional hair conditioning composition (dosage form) can impart a glossiness and smoothness to the hair immediately, but has a short lasting force and a feeling of greasy (Oily) on the hands and hair. In order to improve the above-mentioned problems, an excessive amount of eucalyptus oil, a volatile eucalyptus oil, a lubricant for refreshing use, and the like are used, but the effect cannot be sustained for a long time, and causes a problem of stickiness in use and heavy sagging of the hair ( Reference is made to Patent Documents 1 and 2).
習知技術文獻
專利文獻
（專利文獻1）韓國公開專利第10-2013-0049305號（2013.05.14）
（專利文獻2）韓國公開專利特2001-0024126（2001.03.26）Conventional Technical Document Patent Literature (Patent Document 1) Korean Patent Publication No. 10-2013-0049305 (2013.05.14)
(Patent Document 2) Korean Patent Publication 2001-0024126 (2001.03.26)
本發明的目的在於，提供一種顯著提高毛髮的光澤度、柔順度以及光滑度的持久力的毛髮調理組合物，較佳為提供一種受損毛髮的調理組合物。It is an object of the present invention to provide a hair conditioning composition which remarkably enhances the gloss, suppleness and smoothness of hair, and preferably provides a conditioning composition for damaged hair.
本發明的其他目的在於，提供一種由所述組合物製造的化妝品。Another object of the present invention is to provide a cosmetic manufactured from the composition.
在上述技術背景之下，為了達成所述目的，本說明書的發明人為了開發提高毛髮調理功效（提高毛髮的光澤度、柔順度、光滑度等）的持久力的組合物而不懈努力的結果，確認到在毛髮調理組合物中，如果使用低含量的高分子聚二甲基矽氧烷醇和直鏈型矽氧烷類化合物（較佳為三矽氧烷）作為有效成分，則可以顯著提高毛髮的光澤度、柔順度以及光滑度的持久力，由此完成了本發明。Under the above technical background, in order to achieve the object, the inventors of the present specification have made unremitting efforts to develop a composition for improving the hair conditioning effect (improving the gloss, smoothness, smoothness, and the like of hair). It has been confirmed that in the hair conditioning composition, if a low content of high molecular weight polydimethyl methoxy stanol and a linear siloxane compound (preferably trioxane) are used as an active ingredient, the hair can be remarkably improved. The glossiness, the smoothness, and the durability of the smoothness, thereby completing the present invention.
為此，本發明提供毛髮調理組合物，其為含有聚二甲基矽氧烷醇以及直鏈型矽氧烷類化合物作為有效成分的毛髮調理組合物，其特徵在於：所述聚二甲基矽氧烷醇的平均分子量（莫耳質量（molar mass, M））為60萬~130萬g/mol，較佳為70萬~120萬g/mol，最佳為80萬~110萬g/mol。To this end, the present invention provides a hair conditioning composition which is a hair conditioning composition containing a polydimethyl methoxyalkanol and a linear siloxane compound as an active ingredient, characterized in that the polydimethyl group The average molecular weight (molar mass (M)) of the methoxyalkanol is from 600,000 to 1.3 million g/mol, preferably from 700,000 to 1.2 million g/mol, and most preferably from 800,000 to 1.1 million g/ Mol.
另外，本發明提供一種聚二甲基矽氧烷醇以及直鏈型矽氧烷類化合物的混合物在毛髮調理化妝料組合物或者化妝品的製造中的應用，更加準確而言，作為毛髮調理增進劑的應用。所述聚二甲基矽氧烷醇的平均分子量為60萬~130萬g/mol。In addition, the present invention provides a use of a mixture of a polydimethyl methoxyalkanol and a linear siloxane compound in the manufacture of a hair conditioning cosmetic composition or a cosmetic, more precisely as a hair conditioning enhancer. Applications. The polydimethyl methoxyalkanol has an average molecular weight of 600,000 to 1.3 million g/mol.
根據本發明的毛髮調理組合物向毛髮（尤其，受損毛髮）賦予光澤度和柔順度的同時，黏膩感少，具有清爽和塗抹光潤的特性，可以向使用者提供優秀的使用感。The hair conditioning composition according to the present invention imparts glossiness and suppleness to hair (especially, damaged hair), has less stickiness, and has refreshing and smearing properties, and can provide an excellent feeling of use to the user.
未作其他定義時，本說明書中使用的所有技術以及科學術語具有與所屬技術領域具有通常知識者通常所理解的含義相同的含義。通常，本說明書中使用的命名法是在本技術領域中所熟知且通常使用的。In the absence of other definitions, all of the technical and scientific terms used in this specification have the same meaning as commonly understood by those of ordinary skill in the art. Generally, the nomenclature used in this specification is well known and commonly used in the art.
以下，針對本發明進行更加詳細的說明。Hereinafter, the present invention will be described in more detail.
在本說明書中，在表示濃度、含量、長度、面積、體積、溫度、角度、時間（期間）等中使用的術語“約”是指在該數值或者數值範圍中最大存在10%的容許誤差。In the present specification, the term "about" used in terms of concentration, content, length, area, volume, temperature, angle, time (period), and the like means that there is a maximum allowable error of 10% in the numerical value or range of values.
本發明的一思想在於，One idea of the invention is that
涉及一種毛髮調理組合物，較佳為涉及一種受損毛髮的調理組合物，其為含有聚二甲基矽氧烷醇（dimethiconol）以及直鏈型矽氧烷類化合物作為有效成分的毛髮調理組合物，其特徵在於，所述聚二甲基矽氧烷醇的平均分子量為60萬~130萬g/mol。The invention relates to a hair conditioning composition, preferably a conditioning composition for damaged hair, which is a hair conditioning combination containing dimethiconol and a linear siloxane compound as an active ingredient. The polydimethylsiloxane oxyalcohol has an average molecular weight of 600,000 to 1.3 million g/mol.
在本發明中，所述聚二甲基矽氧烷醇的平均分子量較佳為70萬~120萬g/mol，最佳為80萬~110萬g/mol。如果所述聚二甲基矽氧烷醇的平均分子量不足60萬g/mol，則具有毛髮塗層的持久力低下的問題，如果所述聚二甲基矽氧烷醇的平均分子量超過130萬g/mol，則在毛髮塗層的持久效果上沒有大的增加，反而使用感降低，因此，較佳為在所述範圍內適當使用。In the present invention, the average molecular weight of the polydimethyl methoxyalkanol is preferably from 700,000 to 1,200,000 g/mol, and most preferably from 800,000 to 1,110,000 g/mol. If the average molecular weight of the polydimethyl methoxyalkanol is less than 600,000 g/mol, there is a problem that the durability of the hair coating is low if the average molecular weight of the polydimethyl methoxyalkanol exceeds 1.3 million. When g/mol, there is no large increase in the long-lasting effect of the hair coating, and the feeling of use is lowered, so that it is preferably used within the above range.
在本發明中，所述直鏈型矽氧烷類化合物可以選自由三矽氧烷（trisiloxane）、二矽氧烷（disiloxane）以及聚二甲基矽氧烷（dimethicone）而成的群中的一種以上，但是並不局限於此，較佳為三矽氧烷以及聚二甲基矽氧烷。In the present invention, the linear siloxane compound may be selected from the group consisting of trisiloxane, disiloxane, and dimethicone. One or more, but not limited thereto, are preferably trioxane and polydimethyl siloxane.
在本發明中，所述聚二甲基矽氧烷醇以及直鏈型矽氧烷類化合物的混合比按照重量基準為5.1~34.9:1.0~27.5，較佳為12.0~32.0：5.0~25.0，最佳為16.0~24.0：6.0~10.0。In the present invention, the mixing ratio of the polydimethyl methoxyalkanol and the linear siloxane compound is 5.1 to 34.9: 1.0 to 27.5, preferably 12.0 to 32.0: 5.0 to 25.0, based on the weight. The best is 16.0~24.0: 6.0~10.0.
當超過所述聚二甲基矽氧烷醇以及直鏈型矽氧烷類化合物（例如，三矽氧烷）的混合比（重量比）範圍時，所述組合物其毛髮的光澤度、柔順度以及光滑度的持久力改善效果有可能會降低。When the mixing ratio (weight ratio) of the polydimethyl methoxyalkanol and the linear siloxane compound (for example, trioxane) is exceeded, the composition has glossiness and suppleness of the hair. Degree and smoothness of the endurance improvement effect may be reduced.
在本發明中，在保持所述聚二甲基矽氧烷醇以及直鏈型矽氧烷類化合物的重量比的狀態下，所述組合物中所含的聚二甲基矽氧烷醇的含量為5.1~34.9重量%，較佳為12.0~32.0重量%，最佳為16.0~24.0重量%。如果所述聚二甲基矽氧烷醇的含量不足5.1重量%，則具有毛髮調理效果低下的問題，如果所述聚二甲基矽氧烷醇的含量超過34.9重量%，則在毛髮調理效果上沒有大的增加，反而使用感降低，因此，較佳為在所述範圍內適當使用。In the present invention, the polydimethyl methoxyalkanol contained in the composition is maintained in a state in which the weight ratio of the polydimethyl methoxyalkanol and the linear siloxane compound is maintained. The content is from 5.1 to 34.9% by weight, preferably from 12.0 to 32.0% by weight, most preferably from 16.0 to 24.0% by weight. If the content of the polydimethyl methoxyalkanol is less than 5.1% by weight, there is a problem that the hair conditioning effect is low, and if the content of the polydimethyl methoxyalkanol exceeds 34.9% by weight, the hair conditioning effect is obtained. There is no large increase in the above, but the feeling of use is lowered. Therefore, it is preferable to use it appropriately within the above range.
在本發明中，在保持所述聚二甲基矽氧烷醇以及直鏈型矽氧烷類化合物的重量比的狀態下，所述組合物中所含的直鏈型矽氧烷類化合物的含量為1.0~27.5重量%，較佳為5.0~25.0重量%，最佳為6.0~10.0重量%。如果所述直鏈型矽氧烷類化合物的含量不足1.0重量%，則具有黏膩感改善效果低下的問題，如果所述直鏈型矽氧烷類化合物的含量超過27.5重量%，則在黏膩感改善效果上沒有大的增加，反而使用感降低，因此，較佳在所述範圍內適當使用。In the present invention, the linear siloxane compound contained in the composition is maintained in a state in which the weight ratio of the polydimethyl methoxyalkanol and the linear siloxane compound is maintained. The content is 1.0 to 27.5% by weight, preferably 5.0 to 25.0% by weight, most preferably 6.0 to 10.0% by weight. If the content of the linear siloxane compound is less than 1.0% by weight, there is a problem that the effect of improving the feeling of stickiness is low, and if the content of the linear siloxane compound exceeds 27.5% by weight, it is sticky. There is no large increase in the effect of improving the greasy feeling, but the feeling of use is lowered. Therefore, it is preferable to use it appropriately within the above range.
在本發明中，所述組合物可以進一步包括選自由2-辛基十二醇肉豆蔻酸酯（2-Octyldodecyl Myristate）、肉豆蔻酸異丙酯（Isopropyl Myristate）、C12-15烷基苯甲酸酯（C12-15 Alkyl Benzoate）、棕櫚酸異丙酯（Isopropyl Palmitate）、丁基辛醇水楊酸酯（Butyloctyl Salicylate）、鯨蠟醇乙基己酸酯（Cetyl Ethylhexanoate）、棕櫚酸乙基己酯（Ethylhexyl Palmitate）、碳酸二辛酯（Dicaprylyl Carbonate）以及椰油醇-辛酸酯/葵酸酯（Coco-Caprylate/Caprate）而成的群中的一種以上的酯類油（Ester Oil），但並不局限於此，優選為進一步包括碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物。In the present invention, the composition may further comprise a surfactant selected from the group consisting of 2-Octyldodecyl Myristate, Isopropyl Myristate, and C12-15 alkyl benzoate. Acid ester (C12-15 Alkyl Benzoate), Isopropyl Palmitate, Butyloctyl Salicylate, Cetyl Ethylhexanoate, ethyl palmitate Ester Oil of more than one ester group of Ethylhexyl Palmitate, Dicaprylyl Carbonate, and Coco-Caprylate/Caprate However, it is not limited thereto, and preferably further comprises a mixture of dioctyl carbonate and coco alcohol-caprylate/acetate.
在本發明中，所述組合物中所含的酯類油的含量為3.0~25.0重量%，較佳為4.0~22.0重量%，最佳為18.0~22.0重量%。如果所述酯類油的含量不足3.0重量%，則具有毛髮調理保持效果低下的問題，如果所述酯類油的含量超過25.0重量%，則在毛髮調理保持效果上沒有大的增加，反而使用感降低，因此，較佳為在所述範圍內適當使用。In the present invention, the content of the ester oil contained in the composition is from 3.0 to 25.0% by weight, preferably from 4.0 to 22.0% by weight, most preferably from 18.0 to 22.0% by weight. When the content of the ester oil is less than 3.0% by weight, there is a problem that the hair conditioning and maintenance effect is lowered. When the content of the ester oil exceeds 25.0% by weight, there is no large increase in the hair conditioning and maintenance effect, and instead, it is used. The feeling is lowered, and therefore, it is preferably used within the above range as appropriate.
在本發明中，所述組合物可以進一步包括選自由荷荷巴油（Jojoba oil）、葵花籽油、蓖麻油、橄欖油、椰子油、深海兩節薺籽油（Crambe Abyssinica seed oil）以及豆油（例如，黑豆油）而成的群中的一種以上的植物油，但並不局限於此，較佳為荷荷巴油、椰子油、深海兩節薺籽油以及黑豆油，最佳為進一步含有荷荷巴油。In the present invention, the composition may further comprise a material selected from the group consisting of jojoba oil, sunflower oil, castor oil, olive oil, coconut oil, Crambe Abyssinica seed oil, and soybean oil. One or more vegetable oils in the group of (for example, black soybean oil), but are not limited thereto, and are preferably jojoba oil, coconut oil, deep sea sorghum seed oil, and black soybean oil, and are preferably further contained. Jojoba oil.
在本發明中，所述組合物中所含的植物油的含量為0.05~7.0重量%，較佳為0.1~6.5重量%，最佳為4.0~6.0重量%。如果所述植物油的含量不足0.05重量%，則具有毛髮調理保持效果低下的問題，如果所述植物油的含量超過7.0重量%，則在毛髮調理保持效果上沒有大的增加，反而增加劑型的不穩定性，因此，較佳為在所述範圍內適當使用。In the present invention, the content of the vegetable oil contained in the composition is 0.05 to 7.0% by weight, preferably 0.1 to 6.5% by weight, most preferably 4.0 to 6.0% by weight. If the content of the vegetable oil is less than 0.05% by weight, there is a problem that the hair conditioning and maintenance effect is lowered. If the content of the vegetable oil exceeds 7.0% by weight, there is no large increase in the hair conditioning and maintenance effect, and the dosage form is unstable. Therefore, it is preferred to use it appropriately within the above range.
在本發明中，所述組合物可以進一步含有環狀矽氧烷類化合物，所述環狀矽氧烷類化合物可以是環聚二甲基矽氧烷（Cyclomethicone），優選為環三聚二甲基矽氧烷（Cyclotrisiloxane）、環四聚二甲基矽氧烷（Cyclotetrasiloxane）、環五聚二甲基矽氧烷（Cyclopentasiloxane）、環己矽氧烷（Cyclohexasiloxane）、環庚矽氧烷（Cycloheptasiloxane）或者其混合物，但並不局限於此，最佳為環五聚二甲基矽氧烷以及環己矽氧烷的混合物。In the present invention, the composition may further contain a cyclic oxoxane compound, which may be cyclomethicone, preferably cyclotrimethyl dimethyl Cyclotrisiloxane, cyclotetrasiloxane, cyclopentasiloxane, cyclohexasiloxane, cycloheptasiloxane Or a mixture thereof, but is not limited thereto, and is preferably a mixture of cyclopenta-dimethyl methoxyoxane and cyclohexyloxane.
在本發明中，所述組合物中所含的環狀矽氧烷類化合物的含量為21.5~78.5重量%，較佳為22.0~38.0重量%，最佳為24.0~26.0重量%。如果所述環狀矽氧烷類化合物的含量不足21.5重量%，則具有清爽的使用感低下的問題，如果所述環狀矽氧烷類化合物的含量超過78.5重量%，則在效果上沒有大的增加，反而柔順使用感的持久力會降低，因此，較佳為在所述範圍內適當使用。In the present invention, the content of the cyclic siloxane compound contained in the composition is 21.5 to 78.5 wt%, preferably 22.0 to 38.0 wt%, most preferably 24.0 to 26.0 wt%. When the content of the cyclic siloxane compound is less than 21.5 wt%, there is a problem that the feeling of use is low, and if the content of the cyclic siloxane compound exceeds 78.5 wt%, the effect is not large. The increase in the sturdy feeling of use is reduced, and therefore, it is preferably used within the range as appropriate.
在本發明中，所述聚二甲基矽氧烷醇的黏度為6萬~16萬cs，較佳為6萬5千~15萬cs，最佳為7萬7千~14萬cs。如果所述聚二甲基矽氧烷醇的黏度不足6萬cs，則具有毛髮塗層的持久力低下的問題，如果所述聚二甲基矽氧烷醇的黏度超過16萬cs，則在效果上沒有大的增加，反而增加劑型的不穩定性，因此，較佳為在所述範圍內適當使用。In the present invention, the polydimethyl methoxyalkanol has a viscosity of 60,000 to 160,000 cs, preferably 65,000 to 150,000 cs, and most preferably 77,000 to 140,000 cs. If the viscosity of the polydimethyl methoxyalkanol is less than 60,000 cs, there is a problem that the durability of the hair coating is low, and if the viscosity of the polydimethyl methoxyalkanol exceeds 160,000 cs, then There is no large increase in the effect, but the dosage form is unstable, and therefore, it is preferably used within the above range.
在本發明中，所述直鏈型矽氧烷類化合物的黏度可以為0.5~2.5cs，較佳為0.65~2.0cs，最佳為1.0~1.5cs。所述直鏈型矽氧烷類化合物的黏度範圍為用於保持直鏈型矽氧烷類化合物的揮發性的黏度範圍，較佳為在所述範圍內適當使用。In the present invention, the linear siloxane compound may have a viscosity of 0.5 to 2.5 cs, preferably 0.65 to 2.0 cs, and most preferably 1.0 to 1.5 cs. The viscosity range of the linear siloxane compound is a viscosity range for maintaining the volatility of the linear siloxane compound, and it is preferably used within the above range.
在本發明中，所述環狀矽氧烷類化合物的黏度可以為3.0~5.0cs，較佳為3.2~4.8cs，最佳為3.5~4.5cs。所述環狀矽氧烷類化合物的黏度範圍為用於保持環狀矽氧烷類化合物的揮發性的黏度範圍，較佳為在所述範圍內適當使用。In the present invention, the cyclic siloxane derivative may have a viscosity of 3.0 to 5.0 cs, preferably 3.2 to 4.8 cs, and most preferably 3.5 to 4.5 cs. The viscosity range of the cyclic siloxane compound is a viscosity range for maintaining the volatility of the cyclic siloxane compound, and it is preferably used within the above range.
所述聚二甲基矽氧烷醇、直鏈型矽氧烷類化合物（例如，三矽氧烷等）以及環狀矽氧烷類化合物（例如，環聚二甲基矽氧烷等）各自的黏度是基於如下結果的黏度，即用LVT模型黏度計（博勒飛工程實驗室：Brookfield Engineering Laboratories, Inc.）在30rpm的轉速下利用4號轉子杆（Spindle bar）在常溫下測定1分鐘的結果。The polydimethyl methoxyalkanol, a linear siloxane compound (for example, trioxane, etc.), and a cyclic siloxane compound (for example, cyclopolydimethyloxane, etc.) are each The viscosity is based on the viscosity of the following results, using an LVT model viscometer (Böller Engineering Laboratory: Brookfield Engineering Laboratories, Inc.) at 30 rpm using a No. 4 rotor rod (Spindle bar) for 1 minute at room temperature. the result of.
所述聚二甲基矽氧烷醇、直鏈型矽氧烷類化合物（例如，三矽氧烷等）以及環狀矽氧烷類化合物（例如，環聚二甲基矽氧烷）各自的穩定度是基於如下評價結果的穩定度，即為了在惡劣環境下進行評價，在60℃的恆溫槽條件或者將溫度範圍以-15℃~45℃每12小時進行變更的溫度循環條件下，一周期間觀察乳化穩定度，確認穩定、稍微不穩定、水相部分/油相部分的分離與否，從而評價乳化穩定度（數據未圖示）。Each of the polydimethylhydriolanol, a linear siloxane compound (for example, trioxane, etc.) and a cyclic siloxane compound (for example, cyclopolydimethyloxane) The stability is based on the stability of the evaluation results, that is, in the case of evaluation in a harsh environment, under a temperature bath condition of 60 ° C or a temperature range of -15 ° C to 45 ° C every 12 hours, one week. The emulsification stability was observed during the period, and it was confirmed that the stability was stable, slightly unstable, and the separation of the aqueous phase portion/oil phase portion was evaluated to evaluate the emulsion stability (data not shown).
在本發明中，所述組合物考慮到化妝品安全有關規則中的使用限量，可以進一步包括保濕劑（多元醇等）、蠟、黏度調節劑、增黏劑、pH調節劑、脂肪、有機溶劑、溶解劑、濃縮劑、凝膠劑、軟化劑、抗氧化劑、懸浮劑、穩定劑、發泡劑（foaming agent）、芳香劑、表面活性劑、水、離子型乳化劑、非離子型乳化劑、填充劑、金屬離子封鎖劑、螯合劑、保存劑、維生素、潤濕劑、染料、顏料、親水性活性劑、親油性活性劑、脂囊泡或者與化妝品中通常使用的任意其他成分相同的化妝品學或者皮膚科學領域中通常使用的助劑。另外，本發明的組合物為了增加皮膚狀態改善效果，可以進一步包括皮膚吸收促進物質。In the present invention, the composition may further include a humectant (polyol, etc.), a wax, a viscosity modifier, a tackifier, a pH adjuster, a fat, an organic solvent, in consideration of a use limit in the relevant rules of cosmetic safety. Solvents, concentrates, gels, softeners, antioxidants, suspending agents, stabilizers, foaming agents, fragrances, surfactants, water, ionic emulsifiers, nonionic emulsifiers, Filler, metal ion blocker, chelating agent, preservative, vitamin, wetting agent, dye, pigment, hydrophilic active agent, lipophilic active agent, lipid vesicle or any other cosmetic ingredient commonly used in cosmetics Additives commonly used in the field of physiology or dermatology. Further, the composition of the present invention may further include a skin absorption promoting substance in order to increase the skin condition improving effect.
在本發明中，所述組合物為了向皮膚以及/或者毛髮賦予有用的功能性，進一步包括適當含量的甘油等保濕成分、抗氧化劑等抗氧化/抗老化成分、酪氨酸酶抑制劑、角質再生促進劑等美白成分、紫外線遮擋劑等保護成分、透明質酸、膠原蛋白、彈性蛋白等傷口治療成分、消炎劑等含鹽成分等，從而能夠向皮膚以及/或者毛髮賦予保濕、抗老化、美白、保護、傷口治療等功效，但並不局限於此。In the present invention, in order to impart useful functions to the skin and/or hair, the composition further includes an appropriate amount of a moisturizing component such as glycerin, an antioxidant/anti-aging component such as an antioxidant, a tyrosinase inhibitor, and a keratin. A protective component such as a whitening component such as a regenerative accelerator or an ultraviolet ray shielding agent, a salt-containing component such as a hyaluronic acid, collagen, or elastin, and a salt-containing component such as an anti-inflammatory agent, thereby imparting moisturizing and anti-aging properties to the skin and/or hair. Whitening, protection, wound treatment, etc., but not limited to this.
在本發明中，所述組合物的特徵在於，可以提高毛髮，較佳為提高受損毛髮的調理（毛髮的光澤度、柔順度以及光滑度的程度以及持續期間等）。In the present invention, the composition is characterized in that hair can be improved, and it is preferred to improve conditioning of the damaged hair (degree of gloss, smoothness, smoothness, duration, and the like of the hair).
在本發明中，所述毛髮可以是包括人類的哺乳類身體中任意的毛髮或者毛，例如頭髮、眉毛、睫毛、髭、須、胸毛、後背毛、胳膊毛、腿毛、生殖器毛、鼻毛或者耳毛，但並不局限於此。In the present invention, the hair may be any hair or hair including a human mammalian body such as hair, eyebrows, eyelashes, moles, whiskers, chest hair, arm hair, leg hair, genital hair, nose hair or ear. Mao, but not limited to this.
在本發明中，所述受損毛髮可以是因選自由染色以及燙髮而成的群中的一種以上的化學處理、物理損傷、壓力或者缺乏營養導致的受損毛髮，但並不局限於此。In the present invention, the damaged hair may be damaged hair resulting from one or more chemical treatments, physical damage, stress, or lack of nutrition selected from the group consisting of dyeing and perming, but is not limited thereto.
在本發明中，所述組合物在劑型方面並未有特別限定，可以是具有軟膏、護髮水、護髮霜、護髮膜、頭髮營養液、護髮乳、焗油劑、頭皮護理劑、洗髮水、護髮素、髮蠟（pomade）等劑型的具有化妝品學用途的組合物。所述各個劑型的組合物根據所述各種劑型或者為了符合最終目的，可以包括在通常的化妝料組合物中調配的各種成分，所述成分的種類和劑量可以由所屬技術領域具有通常知識者容易選定。例如，作為在所述組合物中調配的成分，可以使用油脂成分、保濕劑、潤滑劑、表面活性劑、有機以及無機顏料、有機粉體、紫外線吸收劑、防腐劑、殺菌劑、防氧化劑、植物萃取物、pH調節劑、乙醇、色素、香料、血液循環促進劑、涼爽劑、止汗劑、淨化水等。In the present invention, the composition is not particularly limited in terms of dosage form, and may be an ointment, a hair lotion, a hair cream, a hair care film, a hair nutrient solution, a hair lotion, an emu oil agent, a scalp care agent, A cosmetic composition for use in a dosage form such as shampoo, conditioner, or pomade. The compositions of the respective dosage forms may comprise, depending on the various dosage forms or for the ultimate purpose, various ingredients formulated in a typical cosmetic composition, the types and dosages of which may be readily available to those of ordinary skill in the art. Selected. For example, as a component to be formulated in the composition, a fat or oil component, a moisturizer, a lubricant, a surfactant, an organic and inorganic pigment, an organic powder, an ultraviolet absorber, a preservative, a bactericide, an antioxidant, or the like can be used. Plant extracts, pH adjusters, ethanol, pigments, flavors, blood circulation promoters, cooling agents, antiperspirants, purified water, and the like.
以下，藉由實施例更加詳細說明本發明。所述實施例僅用於示例本發明，所屬技術領域具有通常知識者應理解本發明的範圍並不由所述實施例而受限。Hereinafter, the present invention will be described in more detail by way of examples. The embodiments are merely illustrative of the invention, and those skilled in the art should understand that the scope of the invention is not limited by the embodiments.
參考例：毛髮調理組合物的製造Reference example: manufacture of hair conditioning composition
製造出具有下表1以及表2的組成和含量的毛髮調理組合物。其中，高分子聚二甲基矽氧烷醇具有80萬~110萬g/mol的平均分子量，低分子聚二甲基矽氧烷醇具有45萬~59萬g/mol的平均分子量。Hair conditioning compositions having the compositions and levels of Tables 1 and 2 below were made. Among them, the high molecular weight polydimethyl methoxyalkanol has an average molecular weight of 800,000 to 1.1 million g/mol, and the low molecular weight polydimethyl methoxyalkanol has an average molecular weight of 450,000 to 590,000 g/mol.
下列表1以及表2顯示毛髮調理組合物的組成（單位：重量%）。Table 1 and Table 2 below show the composition (unit: % by weight) of the hair conditioning composition.
表1
表2
實驗例1：毛髮的光澤度持久力評價Experimental Example 1: Evaluation of gloss durability of hair
向毛髮塗抹在上述參考例中製造的各個毛髮調理組合物（實施例1~6以及比較例1~8），然後如下測定毛髮的光澤度持久力（塗層力）進行了評價。Each of the hair conditioning compositions (Examples 1 to 6 and Comparative Examples 1 to 8) produced in the above Reference Example was applied to the hair, and then the gloss endurance (coating force) of the hair was measured as follows.
＜毛髮的光澤度持久力測定方法＞<Method for measuring the gloss endurance of hair>
實驗對象：test subject:
（1）正常毛髮：標準毛髮，約10cm長度的正常黑毛（髮辮，BM-B10，Beaulax公司，日本）(1) Normal hair: standard hair, normal black hair of about 10 cm length (hairpin, BM-B10, Beaulax, Japan)
（2）受損的乾燥毛髮：將所述正常毛髮用脫色劑進行脫色處理約30分鐘，然後用洗髮水進行處理後，在約30℃的溫度下用水沖洗3分鐘，進行乾燥準備的受損的乾燥毛髮。(2) Damaged dry hair: The normal hair was subjected to decolorization treatment with a decolorizing agent for about 30 minutes, and then treated with shampoo, and then rinsed with water at a temperature of about 30 ° C for 3 minutes to prepare for drying. Dry hair.
實驗中使用的髮辮（正常毛髮或者受損的乾燥毛髮）是利用沒有調理功效的基本洗髮水進行洗滌後，用水沖洗約1分鐘，然後乾燥約5分鐘後，塗抹組合物（實施例1~6以及比較例1~8），然後利用SAMBA儀器（SAMBA毛髮系統（SAMBA Hair system），Bossa Nova Technologies公司），隨時間（塗抹後即刻，經過1、2、3小時之後）測定毛髮表面的光澤度程度。其中，毛髮的光澤度持久力是藉由隨時間測定毛髮基於光照射角度（-45°~+45°）的光的最大反射量而得出的。The bun (normal hair or damaged dry hair) used in the experiment was washed with a basic shampoo having no conditioning effect, rinsed with water for about 1 minute, and then dried for about 5 minutes, and then applied to the composition (Example 1~) 6 and Comparative Examples 1 to 8), and then using a SAMBA instrument (SAMBA Hair system, Bossa Nova Technologies), the gloss of the hair surface was measured over time (after 1, 2, 3 hours after application). Degree of degree. Among them, the gloss endurance of the hair is obtained by measuring the maximum reflection amount of the light based on the light irradiation angle (-45° to +45°) over time.
其結果，如下表3以及第1圖中所示，確認到：As a result, as shown in the following Table 3 and FIG. 1, it was confirmed that:
①比起作為主成分含有低分子聚二甲基矽氧烷醇的組合物（比較例1），作為主成分含有高分子聚二甲基矽氧烷醇的組合物（比較例3）其在塗抹後即刻，毛髮的光澤度程度較高，1 is a composition containing a low molecular weight polydimethyl methoxyalkanol as a main component (Comparative Example 1), and a composition containing a polymer polydimethyl methoxyalkanol as a main component (Comparative Example 3) Immediately after application, the gloss of the hair is higher.
②比起作為主成分含有低分子聚二甲基矽氧烷醇，並且不含有碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例1），作為主成分含有低分子聚二甲基矽氧烷醇，並且作為組成成分含有作為酯類油的碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和作為植物油的荷荷巴油的組合物（比較例2）其在塗抹後即刻，毛髮的光澤度程度較高，2 compared to a composition containing a low molecular weight polydimethyl methoxyalkanol as a main component, and containing no mixture of dioctyl carbonate and coco alcohol-caprylate/stearic acid ester and jojoba oil (Comparative Example) 1) containing, as a main component, a low molecular weight polydimethyl methoxyalkanol, and as a constituent component, a mixture of dioctyl carbonate as an ester oil and a mixture of coco alcohol-caprylate/acetate and as a vegetable oil The composition of jojoba oil (Comparative Example 2) has a high degree of glossiness of the hair immediately after application.
③比起作為主成分含有高分子聚二甲基矽氧烷醇，並且不含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例3），作為主成分含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（實施例1、5以及6）其在塗抹後即刻，毛髮的光澤度程度長時間較高。3 compared to a polymer containing a polydimethyl methoxyalkanol as a main component, and containing no mixture of trioxane, dioctyl carbonate, and coco alcohol-caprylate/salt and jojoba oil The composition (Comparative Example 3) contains a polymer polydimethyl methoxyalkanol as a main component, and contains trioxane, dioctyl carbonate, and coco alcohol-octanoate/acetate as a constituent. The composition of the mixture and jojoba oil (Examples 1, 5 and 6) had a high degree of gloss on the hair for a long time immediately after application.
一方面，確認到比起實施例1、5以及6的組合物，作為主成分含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油，而且不含有三矽氧烷的組合物（比較例4）其在塗抹後即刻，毛髮的光澤度程度較低（未提供數據）。On the other hand, it was confirmed that the composition of Examples 1, 5, and 6 contained a polymer polydimethyl methoxyalkanol as a main component, and contained dioctyl carbonate and coco alcohol-octanoate as a constituent component. The mixture of /alcoholic acid and jojoba oil, and the composition containing no trioxane (Comparative Example 4), had a low degree of gloss after application (data not provided).
與此不同地，作為主成分含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（實施例2、3以及4）與基於實施例1的組合物類似，在塗抹後即刻，毛髮的光澤度程度長時間顯示較高（未提供數據）。In contrast, a polymer containing a polydimethyl methoxyalkanol as a main component and containing a mixture of trioxane, dioctyl carbonate, and coco alcohol-octanoate/acetate as a constituent component The composition of the joba oil (Examples 2, 3 and 4) was similar to the composition based on Example 1, and the degree of gloss of the hair was high for a long time immediately after application (data not provided).
另外，將受損的乾燥毛髮作為對象，評價塗抹基於實施例1、2、3、4、5以及6的組合物時的毛髮的光澤度持久力的結果，可以獲得如下表3以及與基於第1圖的實施例1的組合物的結果類似的結果（未提供數據）。In addition, as a result of evaluating the gloss endurance of the hair based on the compositions of Examples 1, 2, 3, 4, 5, and 6 on the damaged dry hair, the following Table 3 and the The results of the composition of Example 1 of Figure 1 are similar results (data not provided).
綜合所述結果，確認到一同含有本發明中規定的含量作為主成分的高分子聚二甲基矽氧烷醇和作為組成成分的三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物，其顯示最佳的毛髮光澤度持久力。In view of the results, it was confirmed that the polymer polydimethyl methoxyalkanol containing the content specified in the present invention as a main component and the trioxane, dioctyl carbonate, and cocoyl octanoate as constituent components were confirmed. A combination of a mixture of sunflower acid ester and jojoba oil which exhibits an optimum hair gloss endurance.
以下表3是顯示在毛髮塗抹毛髮調理組合物前後，隨著時間測定正常毛髮的光澤度持久力的結果（單位：%）。Table 3 below shows the results (unit: %) of the gloss endurance of normal hair measured over time before and after the hair application of the hair conditioning composition.
表3
實驗例2：毛髮的柔順度評價Experimental Example 2: Evaluation of hair suppleness
向毛髮塗抹在上述參考例中製造的各個毛髮調理組合物（實施例1~6以及比較例1~8），然後如下測定毛髮的柔順度（柔軟性）程度進行了評價。Each of the hair conditioning compositions (Examples 1 to 6 and Comparative Examples 1 to 8) produced in the above Reference Example was applied to the hair, and the degree of softness (softness) of the hair was measured as follows.
＜毛髮的柔順度程度測定方法＞<Method for measuring the degree of compliance of hair>
實驗中使用的髮辮（正常毛髮或者受損的乾燥毛髮；參考實驗例1）是利用沒有調理功效的基本洗髮水進行洗滌後，用水沖洗約1分鐘，然後乾燥約5分鐘後，塗抹組合物（實施例1~6以及比較例1~8），然後利用MTT175儀器（小型拉伸試驗儀器（Miniature Tensile Tester）,Dia-Stron公司），測定毛髮的柔順度程度。其中，毛髮的柔順度程度是將相對於對照組試料的毛髮梳理時的阻力用gmf值進行數值化而得出的，毛髮的阻力值越小，代表毛髮沒有亂成一團而保持柔順狀態。The hairpin (normal hair or damaged dry hair used in the experiment; refer to Experimental Example 1) was washed with a basic shampoo having no conditioning effect, rinsed with water for about 1 minute, and then dried for about 5 minutes, and then applied to the composition. (Examples 1 to 6 and Comparative Examples 1 to 8), and the degree of compliance of the hair was measured using an MTT175 instrument (Miniature Tensile Tester, Dia-Stron). Among them, the degree of compliance of the hair is obtained by numerically calculating the resistance at the time of combing the hair of the control sample with the gmf value, and the smaller the resistance value of the hair, the more the hair is not tangled and remains compliant.
其結果，如下表4以及第2圖所示，確認到：As a result, as shown in Table 4 and Figure 2 below, it was confirmed that:
①比起作為主成分含有低分子聚二甲基矽氧烷醇的組合物（比較例1），作為主成分含有高分子聚二甲基矽氧烷醇的組合物（比較例3）其在塗抹後即刻，毛髮的柔順度程度較高，1 is a composition containing a low molecular weight polydimethyl methoxyalkanol as a main component (Comparative Example 1), and a composition containing a polymer polydimethyl methoxyalkanol as a main component (Comparative Example 3) Immediately after application, the hair is more flexible.
②比起作為主成分含有低分子聚二甲基矽氧烷醇，並且不含有碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例1），作為主成分含有低分子聚二甲基矽氧烷醇，並且作為組成成分含有碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例2）其在塗抹後即刻，毛髮的柔順度程度較高，2 compared to a composition containing a low molecular weight polydimethyl methoxyalkanol as a main component, and containing no mixture of dioctyl carbonate and coco alcohol-caprylate/stearic acid ester and jojoba oil (Comparative Example) 1) a composition containing a low molecular weight polydimethyl methoxyalkanol as a main component, and containing, as a constituent component, a mixture of dioctyl carbonate and coco alcohol-caprylate/ethyl ester and jojoba oil ( Comparative Example 2), immediately after application, the degree of flexibility of the hair is high,
③比起作為主成分含有高分子聚二甲基矽氧烷醇，並且不含有碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例3），作為主成分含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例4）其在塗抹後即刻，毛髮的柔順度程度較高，3 compared to a composition containing a high molecular weight polydimethyl methoxyalkanol as a main component and containing no mixture of dioctyl carbonate and coco alcohol-caprylate/stearic acid ester and jojoba oil (Comparative Example) 3) A composition containing a high molecular weight polydimethyl methoxyalkanol as a main component and containing a mixture of dioctyl carbonate and coco alcohol-caprylate/stealate as a constituent component and jojoba oil ( Comparative Example 4) Immediately after application, the degree of flexibility of the hair is high,
④比起作為主成分含有高分子聚二甲基矽氧烷醇，並且不含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例3），作為主成分含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（實施例1以及2）其在塗抹後即刻，毛髮的柔順度程度較高，4 compared to a polymer containing a polydimethyl methoxyalkanol as a main component, and containing no mixture of trioxane, dioctyl carbonate, and cocoyl-caprylate/stearic acid ester and jojoba oil The composition (Comparative Example 3) contains a polymer polydimethyl methoxyalkanol as a main component, and contains trioxane, dioctyl carbonate, and coco alcohol-octanoate/acetate as a constituent. The composition of the mixture and jojoba oil (Examples 1 and 2) has a higher degree of suppleness of the hair immediately after application.
⑤比起作為主成分含有高分子聚二甲基矽氧烷醇，並且不含有碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例4），作為主成分含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（實施例1）其在塗抹後即刻，毛髮的柔順度程度較高。5 compared to a composition containing a high molecular weight polydimethyl methoxyalkanol as a main component and containing no mixture of dioctyl carbonate and coco alcohol-caprylate / oleic acid ester and jojoba oil (Comparative Example) 4), as a main component, contains a high molecular weight polydimethyl methoxyalkanol, and as a constituent component, a mixture containing trioxane, dioctyl carbonate, and coco alcohol-caprylate/coumate, and jojoba The composition of the oil (Example 1) had a higher degree of suppleness of the hair immediately after application.
一方面，確認到即便是作為主成分含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物，當組合物中高分子聚二甲基矽氧烷醇的含量顯著降低時（基於比較例8的組合物），毛髮的柔順度程度顯示為較低。On the other hand, it was confirmed that even a high molecular weight polydimethyl methoxyalkanol is contained as a main component, and a mixture containing trioxane, dioctyl carbonate, and coco alcohol-octanoate/acetate as a constituent component is confirmed. In the composition with jojoba oil, when the content of the high molecular weight polydimethyl methoxyalkanol in the composition was remarkably lowered (based on the composition of Comparative Example 8), the degree of compliance of the hair was shown to be low.
與此不同地，確認到作為主成分含有高含量的高分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（實施例3、4、5以及6）與基於實施例1以及2的組合物類似，毛髮的柔順度程度顯示為較高。In contrast, it was confirmed that a high content of high molecular weight polydimethyl methoxyalkanol was contained as a main component, and trioxane, dioctyl carbonate, and coco alcohol-caprylate/salt were contained as constituent components. The composition of the mixture of esters and jojoba oil (Examples 3, 4, 5 and 6) was similar to the compositions based on Examples 1 and 2, and the degree of compliance of the hair was shown to be higher.
另外，將受損的乾燥毛髮作為對象，評價塗抹基於實施例1、2、3、4、5以及6的組合物時的毛髮的柔順度程度的結果，可以獲得與基於如下表4的實施例1的組合物的結果類似的結果（未提供數據）。Further, as a result of evaluating the degree of compliance of the hairs based on the compositions of Examples 1, 2, 3, 4, 5, and 6 on the damaged dry hair, the examples based on the following Table 4 were obtained. The results of the composition of 1 were similar (data not provided).
綜合所述結果，確認到一同含有本發明中規定的含量的作為主成分的高分子聚二甲基矽氧烷醇和作為組成成分的三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物，其顯示最佳的毛髮柔順度程度。In view of the results, it was confirmed that the high molecular weight polydimethyl methoxyalkanol containing the content specified in the present invention and the trioxane, dioctyl carbonate, and coco alcohol-octanoic acid as constituent components are contained together. A combination of an ester/geranate mixture and jojoba oil which exhibits an optimum degree of hair softness.
以下表4是顯示藉由柔順度增加率（對比塗抹前）換算測定在毛髮塗抹毛髮調理組合物前後，正常毛髮的柔順度程度的結果（單位：%）。Table 4 below shows the results (unit: %) of the degree of compliance of normal hair before and after the hair application of the hair conditioning composition by the compliance increase rate (before contrast application).
【表4】
實驗例3：毛髮的光滑度持久力評價Experimental Example 3: Smoothness evaluation of hair smoothness
向毛髮塗抹在上述參考例中製造的各個毛髮調理組合物（實施例1~6以及比較例1~8），然後如下測定毛髮的光滑度持久力（摩擦力）進行了評價。Each of the hair conditioning compositions (Examples 1 to 6 and Comparative Examples 1 to 8) produced in the above Reference Example was applied to the hair, and then the smoothness endurance (frictional force) of the hair was measured as follows.
＜毛髮的光滑度持久力測定方法＞<Method for measuring the smoothness of hair's smoothness>
試驗中使用的髮辮（正常毛髮或者受損的乾燥毛髮；參考實驗例1）是利用沒有調理功效的基本洗髮水進行洗滌後，用水沖洗約1分鐘，然後乾燥約5分鐘後，塗抹組合物（實施例1~6以及比較例1~8），然後利用MTT175儀器（小型拉伸試驗儀器（Miniature Tensile Tester）,Dia-Stron公司），隨著時間（塗抹後即刻、經過1、2、3小時後）測定了毛髮的光滑度程度。其中，毛髮的光滑度程度是將相對於對照組試料的毛髮的表面摩擦力用gmf值進行數值化而得出的光滑度，毛髮的摩擦力值越小，代表毛髮的表面保持光潤狀態。The hairpin (normal hair or damaged dry hair used in the test; refer to Experimental Example 1) was washed with a basic shampoo having no conditioning effect, rinsed with water for about 1 minute, and then dried for about 5 minutes, and then applied to the composition. (Examples 1 to 6 and Comparative Examples 1 to 8), and then using an MTT175 instrument (Miniature Tensile Tester, Dia-Stron), over time (immediately after application, 1, 2, 3) The degree of smoothness of the hair was measured after hours. Here, the degree of smoothness of the hair is a smoothness obtained by numerically calculating the surface frictional force of the hair of the control sample with a gmf value, and the smaller the frictional value of the hair, the surface of the hair is kept moist.
其結果，如下表5以及第3圖所示，確認到：As a result, as shown in Table 5 and Figure 3 below, it was confirmed that:
①比起作為主成分含有低分子聚二甲基矽氧烷醇的組合物（比較例1），作為主成分含有高分子聚二甲基矽氧烷醇的組合物（比較例3）其在塗抹後即刻，毛髮的光滑度程度較高，1 is a composition containing a low molecular weight polydimethyl methoxyalkanol as a main component (Comparative Example 1), and a composition containing a polymer polydimethyl methoxyalkanol as a main component (Comparative Example 3) Immediately after application, the smoothness of the hair is higher.
②比起作為主成分含有高分子聚二甲基矽氧烷醇，並且不含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例3），作為主成分含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（實施例1~6）其在塗抹後即刻，毛髮的光滑度程度長時間較高。2 compared to a mixture containing a polymer polydimethyl methoxyalkanol as a main component, and containing no mixture of trioxane, dioctyl carbonate, and coco alcohol-caprylate/coumate and jojoba oil The composition (Comparative Example 3) contains a polymer polydimethyl methoxyalkanol as a main component, and contains trioxane, dioctyl carbonate, and coco alcohol-octanoate/acetate as a constituent. The composition of the mixture and jojoba oil (Examples 1 to 6) had a smoothness of hair for a long time immediately after application.
另外，將受損的乾燥毛髮作為對象，評價塗抹基於實施例1、2、3、4、5以及6的組合物時的毛髮的光滑度持久力的結果，可以獲得與基於如下表5的實施例1的組合物的結果類似的結果（未提供數據）。Further, as a result of the damaged dry hair, the results of applying the smoothness of the hair based on the compositions of Examples 1, 2, 3, 4, 5, and 6 were evaluated, and the results based on the following Table 5 were obtained. The results of the composition of Example 1 were similar (data not provided).
綜合所述結果，確認到一同含有本發明中規定的含量的作為主成分的高分子聚二甲基矽氧烷醇和作為組成成分的三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物，其顯示最佳的毛髮光滑度持久力。In view of the results, it was confirmed that the high molecular weight polydimethyl methoxyalkanol containing the content specified in the present invention and the trioxane, dioctyl carbonate, and coco alcohol-octanoic acid as constituent components are contained together. A combination of an ester/geranate mixture and jojoba oil which exhibits optimal hair smoothness and endurance.
以下表5是顯示藉由光滑度增加率（對比塗抹前）換算隨著時間測定在毛髮塗抹毛髮調理組合物前後，正常毛髮的光滑度持久力的結果（單位：%）。Table 5 below shows the results (unit: %) of the smoothness of the normal hair before and after the hair application of the hair conditioning composition by the smoothness increase rate (before the comparison).
表5
試驗例4：使用感評價Test Example 4: Evaluation of use feeling
以11名感官評價專家小組為對象，在毛髮以及皮膚上塗抹在上述參考例中製造的各個毛髮調理組合物（實施例1~6以及比較例1~8）後，以15分標準，對使用感進行了如下所示的感官評價（15分標準的評價分數基準被確認為是，[1分]非常低-[5分]很一般-[10分]較高-[15]非常高）。For each of the 11 sensory evaluation expert groups, each of the hair conditioning compositions (Examples 1 to 6 and Comparative Examples 1 to 8) produced in the above Reference Example was applied to the hair and the skin, and then used for 15 minutes. The senses were evaluated as follows (15 points of the standard evaluation scores were confirmed as yes, [1 points] very low - [5 points] very general - [10 points] higher - [15] very high).
＜毛髮的使用感感官評價方法＞<Method of sensory evaluation of hair use>
試驗中使用的髮辮（正常毛髮或者受損的乾燥毛髮；參考實驗例1）是利用沒有調理功效的基本洗髮水進行洗滌後，用水沖洗約1分鐘，然後乾燥約5分鐘後，塗抹組合物（實施例1~6以及比較例1~8），然後11名感官評價專家小組針對七種項目（手塗抹性（用手塗抹時的容易性）、手清爽度、柔順度、毛髮塗抹性、毛髮吸收性、毛髮擰團、毛髮光澤度）進行了評價。The hairpin (normal hair or damaged dry hair used in the test; refer to Experimental Example 1) was washed with a basic shampoo having no conditioning effect, rinsed with water for about 1 minute, and then dried for about 5 minutes, and then applied to the composition. (Examples 1 to 6 and Comparative Examples 1 to 8), and then 11 sensory evaluation expert groups for seven items (hand spreadability (easiness when applied by hand), hand refreshing degree, suppleness, hair spreadability, Hair absorption, hair twisting, and hair gloss were evaluated.
其結果，如表6以及第4圖所示，根據由11名感官評價專家小組的評價分數的感官評價，基於實施例1以及實施例3~6的組合物相比基於比較例3以及比較例4的組合物，在七種項目（手塗抹性（用手塗抹時的容易性）、手清爽度、柔順度、毛髮塗抹性、毛髮吸收性、毛髮擰團、毛髮光澤度）的綜合評價上，其效果顯示優勢，從而被評價為有利於毛髮調理。As a result, as shown in Table 6 and FIG. 4, based on the sensory evaluation of the evaluation scores of the 11 sensory evaluation expert groups, the compositions based on Example 1 and Examples 3 to 6 were compared with Comparative Example 3 and Comparative Example. The composition of 4, in seven items (hand spread (easiness when applied by hand), hand refreshing, suppleness, hair spreadability, hair absorption, hair twisting, hair gloss) The effect shows an advantage and is thus evaluated as being beneficial for hair conditioning.
具體地，相比作為主成分含有高分子聚二甲基矽氧烷醇，並且不含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例3）或者作為主成分含有高分子聚二甲基矽氧烷醇，並且含有碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例4），作為主成分含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物中的實施例1、3、4、5、6的組合物的感官評價綜合分數（合計）顯示較高。Specifically, it contains a high molecular weight polydimethyl methoxyalkanol as a main component, and does not contain a mixture of trioxane, dioctyl carbonate, and coco-octanoate/acetate, and jojoba. The oil composition (Comparative Example 3) or as a main component contains a high molecular weight polydimethyl methoxyalkanol, and contains a mixture of dioctyl carbonate and coco alcohol-caprylate/acetate and jojoba oil. The composition (Comparative Example 4) contains, as a main component, a high molecular weight polydimethyl methoxyalkanol, and as a constituent component, a trioxane, a dioctyl carbonate, and a coco alcohol-caprylate/acetate. The sensory evaluation composite score (total) of the compositions of Examples 1, 3, 4, 5, and 6 in the composition of the mixture and jojoba oil showed higher.
另外，作為主成分含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（實施例2）與基於實施例1的組合物類似，確認到毛髮的光滑度程度顯示較高（未提供數據）。Further, the main component contains a high molecular weight polydimethyl methoxyalkanol, and as a constituent component, a mixture containing trioxane, dioctyl carbonate, and coco alcohol-octanoate/acetate, and jojoba oil The composition (Example 2) was similar to the composition based on Example 1, and it was confirmed that the degree of smoothness of the hair was high (data not provided).
另外，將受損的乾燥毛髮作為對象，評價塗抹基於實施例1、2、3、4、5以及6的組合物時的使用感的結果，可以獲得與基於如下表6的實施例1的組合物的結果類似的結果（未提供數據）。In addition, as a result of evaluating the feeling of use when the compositions based on Examples 1, 2, 3, 4, 5, and 6 were applied, the damaged dry hair was evaluated, and the combination with Example 1 based on the following Table 6 was obtained. The results of the results are similar (data not provided).
一方面，含有高分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物中，基於比較例5的組合物由於低含量的高分子聚二甲基矽氧烷醇，而顯示組合物的黏度非常低，且缺乏柔順度，含有低分子聚二甲基矽氧烷醇，並且作為組成成分含有三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物（比較例7）顯示毛髮黏膩感和油膩感（oily）強，而使用感低下（未提供數據）。In one aspect, a combination comprising a high molecular weight polydimethyl methoxyalkanol and comprising as a constituent a trioxane, a dioctyl carbonate, and a mixture of coco alcohol-caprylate/geranate and jojoba oil The composition based on Comparative Example 5 showed a very low viscosity and lack of flexibility due to a low content of high molecular weight polydimethyl methoxyalkanol, and contained a low molecular weight polydimethyl oxysterol. And a composition containing trioxane, dioctyl carbonate, and a mixture of coco alcohol-caprylate/eroke ester and jojoba oil as a constituent component (Comparative Example 7) showed a sticky feeling of greasy hair and a greasy feeling (oily) is strong, and the sense of use is low (data is not provided).
綜合所述結果，確認到一同含有本發明中規定的含量的作為主成分的高分子聚二甲基矽氧烷醇和作為組成成分的三矽氧烷、碳酸二辛酯以及椰油醇-辛酸酯/葵酸酯的混合物和荷荷巴油的組合物，其顯示最佳的毛髮光滑度持久力。In view of the results, it was confirmed that the high molecular weight polydimethyl methoxyalkanol containing the content specified in the present invention and the trioxane, dioctyl carbonate, and coco alcohol-octanoic acid as constituent components are contained together. A combination of an ester/geranate mixture and jojoba oil which exhibits optimal hair smoothness and endurance.
以下表6是顯示以11名感官評價專家小組為對象，在正常毛髮以及皮膚上塗抹根據本發明的毛髮調理組合物後，以15分標準，對使用感進行感官評價的結果。Table 6 below shows the results of sensory evaluation of the feeling of use by applying the hair conditioning composition according to the present invention to normal hair and skin for 11 sensory evaluation expert groups.
表6
以上針對本發明內容的特定部分進行了詳細說明，然而所屬技術領域具有通常知識者應明確所述具體技術說明僅是較佳的實施形態，並不由此限定本發明的範圍。因此，本發明的實際範圍應由所附的申請專利範圍及其等價物而定。The specific details of the present invention have been described in detail above, and it is to be understood that Therefore, the actual scope of the invention should be determined by the scope of the appended claims and their equivalents.
無no
第1圖是示出隨著時間測定在毛髮塗抹根據本發明的毛髮調理組合物之前和之後，毛髮的光澤度持久力的結果的圖表。Fig. 1 is a graph showing the results of the gloss endurance of the hair before and after the application of the hair conditioning composition according to the present invention to the hair over time.
第2圖是示出藉由柔順度增加率（對比塗抹前）換算在毛髮塗抹根據本發明的毛髮調理組合物之前和之後，毛髮的柔順度程度的結果的圖表。Fig. 2 is a graph showing the results of the degree of compliance of the hair before and after the application of the hair conditioning composition according to the present invention by the rate of increase in softness (before the comparison).
第3圖是示出藉由柔順度增加率（對比塗抹前）換算隨著時間測定在毛髮塗抹根據本發明的毛髮調理組合物之前和之後，毛髮的柔順度持久力的結果的圖表。Fig. 3 is a graph showing the results of the suppleness of the hair before and after the application of the hair conditioning composition according to the present invention by the conversion of the compliance rate (before the comparison).
第4圖是示出以11名感官評價專家小組為對象，在毛髮以及皮膚上塗抹根據本發明的毛髮調理組合物後，以15分標準，對使用感進行感官評價的結果的圖表。Fig. 4 is a graph showing the results of sensory evaluation of the feeling of use by applying the hair conditioning composition according to the present invention to hair and skin for 11 sensory evaluation expert groups.
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR20180024814 | 2018-02-28 | ||
| KR10-2018-0024814 | 2018-02-28 | ||
| KR10-2019-0013496 | 2019-02-01 | ||
| KR1020190013496AKR102684249B1 (en) | 2018-02-28 | 2019-02-01 | Hair Conditioning Composition |
| Publication Number | Publication Date |
|---|---|
| TW201936168Atrue TW201936168A (en) | 2019-09-16 |
| TWI776023B TWI776023B (en) | 2022-09-01 |
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW108106349ATWI776023B (en) | 2018-02-28 | 2019-02-25 | Hair conditioning composition |
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| KR (1) | KR102684249B1 (en) |
| TW (1) | TWI776023B (en) |
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| KR101763870B1 (en) | 2011-11-04 | 2017-08-02 | 애경산업(주) | Self-exothermic hair conditioning composition |
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| Publication number | Publication date |
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| KR102684249B1 (en) | 2024-07-11 |
| KR20190103949A (en) | 2019-09-05 |
| TWI776023B (en) | 2022-09-01 |
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