本發明係有關一種矽橡膠黏土材料,特別是指一種可解決傳統黏土容易乾掉、產生沾黏問題之矽橡膠黏土組成物及使用於矽橡膠黏土的製作方法。The invention relates to a enamel rubber clay material, in particular to a ruthenium rubber clay composition which can solve the problem that the traditional clay is easy to dry and cause sticking problems, and a manufacturing method for the ruthenium rubber clay.
黏土因為材料的可塑性及價格便宜、容易取得的優點,是極受歡迎的創作媒材之一。市面上的黏土種類眾多,常見有超輕土、樹脂黏土、紙黏土、油土及兒童專用的安全黏土等等,而每一種黏土具有不同的特性,呈現出的效果也不盡相同,選擇上可根據使用需求及價格差異而定。Clay is one of the most popular creation media because of its plasticity and its advantages of being cheap and easy to obtain. There are many types of clay on the market, such as ultra-light soil, resin clay, paper clay, oil soil and safety clay for children. Each clay has different characteristics and the effect is not the same. Can be based on usage needs and price differences.
其中,超輕土的質感輕柔,延展性非常好,色彩也很鮮豔,其乾燥後不像樹脂黏土般堅硬,因為它的密度低且具有彈性,就算掉在地上也不易摔壞。但超輕土在使用上很容易沾手,製作動作要快,否則容易乾燥,而且一旦沾黏在其他物品或衣服上就很難清理,不適合初學者或孩童重複捏玩使用。Among them, the ultra-light soil has a soft texture, very good ductility and bright color. It is not as hard as resin clay after drying. Because of its low density and elasticity, it is not easy to break even if it falls on the ground. However, ultra-light soil is easy to touch, easy to make, or easy to dry, and it is difficult to clean once it is stuck on other items or clothes. It is not suitable for beginners or children to play with.
樹脂黏土的顏色相當多樣,韌性強,可塑性高且材質細緻,作品風乾後會呈透明感。樹脂黏土容易保存,可長期收藏也不會損壞,其延展性好,乾了之後質地硬,又不會像輕質土那樣容易黏手,可是樹脂黏土的土質容易乾燥,乾燥後則很難恢復軟度,其成品較重且容易龜裂,而且樹脂黏土主要是由澱粉和樹脂製成,易被蟲啃蝕,放在太潮濕的地方可能會發臭、發霉。Resin clay is quite diverse in color, strong in toughness, high in plasticity and meticulous in texture, and it will be transparent after drying. Resin clay is easy to store and can be stored for a long time without damage. It has good ductility. After drying, it has a hard texture and is not as easy to stick as light soil. However, the soil of resin clay is easy to dry, and it is difficult to recover after drying. Softness, the finished product is heavier and prone to cracking, and the resin clay is mainly made of starch and resin, which is easily eroded by insects, and may be stinky and moldy when placed in a place that is too humid.
紙黏土是由紙漿、石粉、樹脂等素材組成,由於紙黏土的纖維較粗,容易塑型,半乾燥後只需用水搓揉即可恢復軟度;然而,紙黏土的土質硬,易黏手,乾燥後容易有龜裂現象,也較難保存。Paper clay is composed of pulp, stone powder, resin and other materials. Because the paper clay is thicker and easier to shape, it can be softened after only half-drying. However, the soil of paper clay is hard and easy to stick. It is prone to cracking after drying and is also difficult to store.
另外,油土 不會乾,但較為油膩,材質硬, 不容易塑型。而強調天然無毒的兒童用安全黏土通常成分包含麵粉、水及食用色素,其缺點為容易乾掉,塑型力差、容易散開,同時也較為沾手或沾黏其他物品,故不易清潔,善後比較麻煩,而且其保存期限短,容易有臭味。In addition, the oil and soil will not dry, but it is more greasy, the material is hard, and it is not easy to shape. The natural non-toxic children's safety clay usually contains flour, water and food coloring. Its shortcomings are easy to dry, poor plasticity, easy to spread, and also more sticky or sticky, so it is not easy to clean. And its shelf life is short and it is easy to smell.
有鑑於此,本發明乃提出一種嶄新的矽橡膠黏土組成物,並將此矽橡膠黏土組成物使用於矽橡膠黏土的製作方法中,用以改善目前市面上的黏土所產生之各種缺點。In view of the above, the present invention proposes a novel ruthenium rubber clay composition, and the ruthenium rubber clay composition is used in the production method of ruthenium rubber clay to improve various disadvantages of clay currently on the market.
本發明的主要目的在於提供一種矽橡膠黏土組成物及使用於矽橡膠黏土的製作方法,藉由在以甲基乙烯基矽橡膠為主要原料的組成物中,添加二甲基矽油來提供良好的潤滑及化學穩定性,可以用以排除了習知黏土材料的缺點,比如容易乾燥、不易保存、易沾黏等等,尤其能夠讓初學者或孩童對於黏土捏塑有更多重複練習的機會,且沒有惱人的善後及保存問題。The main object of the present invention is to provide a enamel rubber clay composition and a method for preparing the ruthenium rubber clay, which is provided by adding dimethyl hydrazine oil to a composition containing methyl vinyl ruthenium rubber as a main raw material. Lubrication and chemical stability can be used to eliminate the shortcomings of conventional clay materials, such as easy drying, difficult to store, easy to stick, etc., especially for beginners or children to have more opportunities for repeated practice of clay molding. There are no annoying aftertastes and preservation problems.
本發明的另一目的在於提供一種矽橡膠黏土組成物及使用於矽橡膠黏土的製作方法,其矽橡膠黏土可重複捏塑,且只要進一步添加食品級白金架橋劑,即可藉由沸水加熱方式,使之硬化成型,且仍保有材料的彈性。Another object of the present invention is to provide a ruthenium rubber clay composition and a method for preparing the ruthenium rubber clay, wherein the ruthenium rubber clay can be repeatedly kneaded, and as long as the food grade white gold bridging agent is further added, the boiling water heating method can be adopted. , it is hardened and still retains the elasticity of the material.
為達上述之目的,本發明提供一種矽橡膠黏土組成物,其由100重量份的甲基乙烯基矽橡膠、6~10重量份的二甲基矽油、1重量份的抗菌劑及1重量份的食用色素等成份所混合調配而成。In order to achieve the above object, the present invention provides a ruthenium rubber clay composition comprising 100 parts by weight of methyl vinyl ruthenium rubber, 6 to 10 parts by weight of dimethyl hydrazine oil, 1 part by weight of an antibacterial agent, and 1 part by weight. The food coloring ingredients are mixed and blended.
此矽橡膠黏土亦可加入2~5重量份的白金架橋劑,以便再透過煮沸方式予以硬化成型;但是白金架橋劑之衰減期大概為三個月,建議在此期間之內使其固化。The enamel rubber clay may also be added with 2 to 5 parts by weight of a platinum bridging agent for hardening by boiling; however, the white gold bridging agent has a decay period of about three months, and it is recommended to cure it during this period.
本發明也提供一種矽橡膠黏土的製作方法,其步驟是先提供前述成份混合組成之矽橡膠黏土組成物,再將此矽橡膠黏土組成物於常溫下以滾輪混煉,即製得一種無臭、無味且不易沾黏的矽橡膠黏土。The invention also provides a method for preparing a ruthenium rubber clay, which comprises the steps of: providing a ruthenium rubber clay composition of the foregoing composition, and then kneading the ruthenium rubber clay composition at a normal temperature to obtain an odorless, An odorless and non-sticky rubber clay.
根據本發明所提供的矽橡膠黏土組成物及使用於矽橡膠黏土的製作方法,可以提昇矽橡膠黏土的使用特性,方便使用者可以重複捏塑,不會有容易乾燥的情形,也不會產生臭味及發生掉屑、沾黏,易於清理及善後。而當使用者有定型需求時,也可再混入2~5重量份的白金架橋劑,藉由煮沸方式,即可使作品硬化定型但仍保有彈性,其組成及製作方法相當簡易、安全,能夠有效推廣至大眾成為理想的黏土材料。According to the enamel rubber clay composition provided by the invention and the manufacturing method of the ruthenium rubber clay, the use characteristics of the ruthenium rubber clay can be improved, and the user can repeat the molding without repeated drying or the like. Odor and spoilage, sticky, easy to clean and aftercare. When the user has a stereotyped requirement, 2 to 5 parts by weight of a platinum bridging agent can be further mixed, and the boiled method can make the work hardened and set but still retains elasticity, and the composition and manufacturing method thereof are relatively simple and safe. Effectively promoted to the public to become the ideal clay material.
底下藉由具體實施例詳加說明,當更容易瞭解本發明之目的、技術內容、特點及其所達成之功效。The purpose, technical content, features and effects achieved by the present invention will be more readily understood by the detailed description of the embodiments.
為清楚揭露本發明所揭露的矽橡膠黏土組成物及使用於矽橡膠黏土的製作方法的技術特徵,以下將提出具體實施例以詳細說明本發明的技術特徵,更同時佐以圖式俾使該些技術特徵得以彰顯。In order to clearly disclose the technical features of the enamel rubber clay composition disclosed in the present invention and the manufacturing method for the ruthenium rubber clay, specific embodiments will be hereinafter described to explain the technical features of the present invention in detail, and at the same time, These technical features are highlighted.
請參照第1圖,為本發明之實施例所提供之一種矽橡膠黏土組成物的組成結構示意圖。根據本發明所提供之矽橡膠黏土組成物,主要是以甲基乙烯基矽橡膠為主要原料,並於每100重量份的甲基乙烯基矽橡膠中混合添加6~10重量份的二甲基矽油,以及1重量份的食品級抗菌劑、1重量份的食用色素。圖中以重量百分比簡單表示,甲基乙烯基矽橡膠、二甲基矽油、抗菌劑及食用色素分別約佔89~93%、6~9%、1%及、1%;且圖中各成份所占面積比例並非實際比例。Please refer to FIG. 1 , which is a schematic structural diagram of a composition of a sputum rubber clay composition according to an embodiment of the present invention. The ruthenium rubber clay composition provided by the present invention mainly comprises methyl vinyl ruthenium rubber as a main raw material, and 6 to 10 parts by weight of dimethyl group is added and mixed per 100 parts by weight of the methyl vinyl ruthenium rubber. Emu oil, 1 part by weight of food grade antibacterial agent, 1 part by weight of food coloring. In the figure, it is simply expressed by weight percentage, and methyl vinyl fluorene rubber, dimethyl hydrazine oil, antibacterial agent and food coloring account for about 89 to 93%, 6 to 9%, 1% and 1%, respectively; The proportion of the area is not the actual ratio.
其中,甲基乙烯基矽橡膠為一種無色透明的彈性體,具有良好的電絕緣性、耐氧抗老化性、耐光抗老化性以及防霉性,而且表面不容易沾黏,可作為良好的緩衝材;而二甲基矽油無味無毒,具有生理惰性及良好的化學穩定性,疏水性能好,並具有很高的抗剪能力,廣泛用做絕緣、潤滑、防震、油漆和日用化妝品的添加劑等。Among them, methyl vinyl fluorene rubber is a colorless and transparent elastomer with good electrical insulation, oxygen and aging resistance, light and aging resistance and mildew resistance, and the surface is not easy to stick, which can be used as a good buffer. Dimethyl eucalyptus oil is odorless, non-toxic, physiologically inert and has good chemical stability, good hydrophobic properties, and high shear resistance. It is widely used as an additive for insulation, lubrication, shockproof, paint and daily cosmetics. .
必須注意的是,如同本說明書中所用,各種材料之使用量係以「重量份」為計數的單位,根據本實施例內容,其中矽橡膠黏土組成物包含有比率為100:6~10:1:1(重量份/重量份/重量份/重量份)之甲基乙烯基矽橡膠:二甲基矽油:抗菌劑:食用色素,也就是每100重量份的甲基乙烯基矽橡膠,二甲基矽油的使用量為6~10重量份,抗菌劑的使用量為1重量份,食用色素的使用量為1重量份,如將重量份轉換為以公克為計數單位,則相當於每使用100公克的甲基乙烯基矽橡膠,二甲基矽油的使用量為6~10公克,抗菌劑的使用量為1公克,食用色素的使用量為1公斤。以下描述亦是此等情形,故不再贅述。It should be noted that, as used in the present specification, the amounts of various materials used are in units of "parts by weight", according to the present embodiment, wherein the 矽 rubber clay composition contains a ratio of 100:6 to 10:1. : 1 (parts by weight / part by weight / part by weight / part by weight) of methyl vinyl oxime rubber: dimethyl oxime oil: antibacterial agent: food coloring, that is, every 100 parts by weight of methyl vinyl ruthenium rubber, dimethyl The amount of the base oil used is 6 to 10 parts by weight, the amount of the antibacterial agent used is 1 part by weight, and the amount of the food coloring matter used is 1 part by weight. If the weight portion is converted to the unit of counting in grams, it is equivalent to 100 per used. The gram of methyl vinyl ruthenium rubber, dimethyl eucalyptus oil is used in an amount of 6 to 10 grams, the antibacterial agent is used in an amount of 1 gram, and the edible coloring matter is used in an amount of 1 kg. The following description is also the case and will not be described again.
此矽橡膠黏土組成物是應用於矽橡膠黏土的製作,可藉由二甲基矽油的惰性及潤滑作用,讓矽橡膠黏土具有不容易乾燥之特性,讓使用者可以最大自由度的創意發想重複捏塑,同時,此矽橡膠黏土無臭無味,也不會發生掉屑、沾黏等情況,非常容易清理及方便善後。The enamel rubber clay composition is applied to the manufacture of 矽 rubber clay. The inertness and lubrication of dimethyl eucalyptus oil can make 矽 rubber clay have characteristics that are not easy to dry, so that users can think creatively with maximum freedom. Repeated kneading, at the same time, this rubber clay is odorless and tasteless, and it will not cause chipping, sticking, etc. It is very easy to clean and convenient.
進一步地,請參照第2圖,為本發明之實施例所提供之另一種矽橡膠黏土組成物的組成結構示意圖;若使用者有將矽橡膠黏土予以定型的需求,可再混入2~5重量份的白金架橋劑,並藉由煮沸方式,即可使作品硬化定型但仍保有彈性。圖中以重量百分比簡單表示,甲基乙烯基矽橡膠、二甲基矽油、抗菌劑、食用色素及白金架橋劑分別約佔87~91%、5~9%、1%、1%及3~4%;且圖中各成份所占面積比例並非實際比例。Further, please refer to FIG. 2 , which is a schematic structural diagram of another composition of a ruthenium rubber clay provided by an embodiment of the present invention; if the user has a need to shape the 矽 rubber clay, 2 to 5 weights may be mixed. The white gold bridging agent, by boiling, can make the work harden and set but still retains its elasticity. In the figure, it is simply expressed by weight percentage. methyl vinyl fluorene rubber, dimethyl hydrazine oil, antibacterial agent, food coloring agent and platinum bridging agent account for about 87-91%, 5-9%, 1%, 1% and 3~, respectively. 4%; and the proportion of the area occupied by each component in the figure is not the actual ratio.
以下請參照第3圖,對於本發明如何使用此矽橡膠黏土組成物於本發明之矽橡膠黏土的製作方法之流程步驟進行詳述。Hereinafter, please refer to Fig. 3 for a detailed description of the process steps of the method for producing the crucible rubber clay of the present invention using the crucible rubber clay composition of the present invention.
首先,如步驟S100,提供如前述第1圖之組成比例的矽橡膠黏土組成物,其包含有100重量份的甲基乙烯基矽橡膠、6~10重量份的二甲基矽油、1重量份的食品級抗菌劑和1重量份的食用色素。First, in step S100, a ruthenium rubber clay composition having a composition ratio of the above-mentioned FIG. 1 is provided, which comprises 100 parts by weight of methyl vinyl ruthenium rubber, 6 to 10 parts by weight of dimethyl hydrazine oil, and 1 part by weight. Food grade antibacterial agent and 1 part by weight of food coloring.
然後,如步驟S110,將矽橡膠黏土組成物於常溫下以滾輪混煉,即製得矽橡膠黏土。此矽橡膠黏土具有彈性,且不容易乾燥,不易沾手,使用者可以隨心所欲的用它來捏塑成任意形狀,亦可利用模具製成單一形狀的作品。Then, in step S110, the crucible rubber clay composition is kneaded at a normal temperature by a roller to obtain a crucible rubber clay. The 矽 rubber clay is elastic and not easy to dry, and is not easy to touch. The user can use it to mold into any shape as desired, and can also use the mold to make a single shape.
後續,若有成型需求,如步驟S120,再於矽橡膠黏土中加入2~5重量份的食品級白金架橋劑,充分混合之後,再予以捏塑為預定成型之形狀。Subsequently, if there is a molding requirement, in step S120, 2 to 5 parts by weight of a food grade platinum bridging agent is added to the crucible rubber clay, and after fully mixing, it is kneaded into a shape to be formed.
最後,如步驟S130,取上述已捏塑好的矽橡膠黏土,置入約100℃的沸水中煮3~5分鐘,即可使矽橡膠黏土固化成型但仍保有彈性。Finally, in step S130, the above-mentioned kneaded enamel rubber clay is taken and placed in boiling water of about 100 ° C for 3 to 5 minutes to cure the enamel rubber clay but still retain elasticity.
另外要注意的是,只要在未經煮沸之前,使用者都可以任意將矽橡膠黏土重新塑型,但是白金架橋劑之衰減期大概為三個月,建議在此期間之內使其固化。而加入白金架橋劑的矽橡膠黏土若在水中煮超過一定時間時,黏土將會膨脹變形,所以水煮時間控制於3~5分鐘內較為適當。It should also be noted that the user can reshape the enamel rubber clay without any boiling, but the white gold bridging agent has a decay period of about three months. It is recommended to cure it during this period. If the enamel rubber clay added with the platinum bridging agent is boiled in water for more than a certain period of time, the clay will expand and deform, so it is appropriate to control the boiling time within 3 to 5 minutes.
根據本發明所提供之矽橡膠黏土組成物,藉由在以甲基乙烯基矽橡膠為主要原料的組成物中,添加二甲基矽油來提供良好的潤滑及化學穩定性,並可於實務上搭配食品級抗菌劑和食用色素,以及食品級白金架橋劑,使黏土的成份除了無臭無味之外,更是非常環保安全。According to the present invention, the ruthenium rubber clay composition provides good lubrication and chemical stability by adding dimethyl hydrazine oil to the composition containing methyl vinyl ruthenium rubber as a main raw material, and can be practically used. With food-grade antibacterial agents and food coloring, as well as food-grade white gold bridging agents, the clay ingredients are environmentally safe and safe, in addition to being odorless and tasteless.
再者,有別於習知黏土材料的缺點,比如容易乾燥、沾黏,而不利重複塑型,或是容易發臭、發霉,而難以保存,不易清潔及善後等等;本發明所製得之矽橡膠黏土的優勢在於具有不容易乾之特性,可重複捏塑,特別對於初學者或孩童來說,可以提供更多重複練習或者捏玩的機會;同時,此矽橡膠黏土不僅不會發出臭味,且使用上不易掉屑、不易沾手,更由於不會沾黏衣物或地板,相當容易清潔,也沒有惱人的善後問題,而製作好的成品仍具有彈性,不易龜裂或摔壞,有利於長期保存。Moreover, it is different from the disadvantages of the conventional clay materials, such as being easy to dry, sticking, unsatisfactory to reshape, or easily stinky, moldy, difficult to store, difficult to clean and aftercare, etc.; The advantage of the rubber clay is that it has the characteristics of not easy to dry, and can be repeatedly molded, especially for beginners or children, it can provide more opportunities for repeated practice or pinching; at the same time, this rubber clay will not not be issued. It has a odor, and it is not easy to be used for chipping, it is not easy to touch hands, and it is easy to clean because it does not stick to clothes or the floor, and there is no annoying problem of aftercare. The finished product is still elastic and not easy to crack or break. Conducive to long-term preservation.
總的來說,本發明的矽橡膠黏土組成物及使用於矽橡膠黏土的製作方法,可以相當程度地提昇矽橡膠黏土的使用特性,方便使用者可以重複捏塑,不會有容易乾燥、掉屑及沾黏等問題,同時也易於清理、善後及保存。而當使用者有定型需求時,可以藉由混入白金架橋劑,再透過簡單的水煮方式,即可使作品硬化定型但仍保有彈性,其組成及製作方法皆相當簡易、安全,能夠有效地推廣至大眾成為理想的黏土材料。In general, the enamel rubber clay composition of the present invention and the method for preparing the ruthenium rubber clay can considerably improve the use characteristics of the ruthenium rubber clay, and the user can repeat the molding without repeated drying and dropping. Problems such as shavings and stickiness are also easy to clean, rehabilitate and preserve. When the user has a stereotyped requirement, the work can be hardened and set by using a simple white boiled agent, but the composition and the manufacturing method are relatively simple and safe. Promote to the public to become the ideal clay material.
唯以上所述者,僅為本發明之較佳實施例而已,並非用來限定本發明實施之範圍。故即凡依本發明申請範圍所述之特徵及精神所為之均等變化或修飾,均應包括於本發明之申請專利範圍內。The above is only the preferred embodiment of the present invention and is not intended to limit the scope of the present invention. Therefore, any changes or modifications of the features and spirits of the present invention should be included in the scope of the present invention.
無no
第1圖為本發明之實施例所提供之一種矽橡膠黏土組成物的組成結構示意圖。 第2圖為本發明之實施例所提供之另一種矽橡膠黏土組成物的組成結構示意圖。 第3圖為本發明之實施例所提供之矽橡膠黏土的製作方法之流程圖。Fig. 1 is a schematic view showing the composition and structure of a ruthenium rubber clay composition according to an embodiment of the present invention. Fig. 2 is a schematic view showing the composition and structure of another enamel rubber clay composition according to an embodiment of the present invention. Fig. 3 is a flow chart showing a method of manufacturing a rubber clay according to an embodiment of the present invention.
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW105118461ATWI626267B (en) | 2016-06-13 | 2016-06-13 | Silicon rubber clay and manufacturing method thereof |
| CN201710239869.5ACN107254173A (en) | 2016-06-13 | 2017-04-13 | Silicone rubber clay composition and preparation method thereof |
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW105118461ATWI626267B (en) | 2016-06-13 | 2016-06-13 | Silicon rubber clay and manufacturing method thereof |
| Publication Number | Publication Date |
|---|---|
| TW201742885Atrue TW201742885A (en) | 2017-12-16 |
| TWI626267B TWI626267B (en) | 2018-06-11 |
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW105118461ATWI626267B (en) | 2016-06-13 | 2016-06-13 | Silicon rubber clay and manufacturing method thereof |
| Country | Link |
|---|---|
| CN (1) | CN107254173A (en) |
| TW (1) | TWI626267B (en) |
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114958003A (en)* | 2022-06-28 | 2022-08-30 | 广东省仟甫新材料有限公司 | Preparation method of room temperature curable silica gel clay for DIY of children |
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1176175C (en)* | 2002-12-18 | 2004-11-17 | 浙江久立耐火电缆有限公司 | Putty cable sealing insulative material and its manufacture |
| EP2319889B1 (en)* | 2006-06-16 | 2012-09-19 | Nok Corporation | Silicone rubber composition |
| TW200825139A (en)* | 2006-12-15 | 2008-06-16 | Formosan Rubber Group Inc | The composition of producing electrostatic-dispersed silicone plate with continuous width, and the manufacturing method thereof |
| US8443840B2 (en)* | 2007-03-09 | 2013-05-21 | Asahi Rubber Inc. | Excessive pressure release valve and release valve unit having the release valve |
| KR101012314B1 (en)* | 2010-06-08 | 2011-02-09 | 대일소재(주) | A rubber clay |
| TWI471380B (en)* | 2012-09-13 | 2015-02-01 | Daeil Advanced Materials Co Ltd | Thermocurable rubber clay for handicrafts |
| CN104492094B (en)* | 2014-11-28 | 2017-02-01 | 龚䶮 | A kind of nontoxic plasticine and preparation method thereof |
| Publication number | Publication date |
|---|---|
| CN107254173A (en) | 2017-10-17 |
| TWI626267B (en) | 2018-06-11 |
| Publication | Publication Date | Title |
|---|---|---|
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| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |