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SU505637A1 - The method of obtaining -acyl derivatives of the substituted imidazolidine - Google Patents

The method of obtaining -acyl derivatives of the substituted imidazolidine

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Publication number
SU505637A1
SU505637A1SU2086702ASU2086702ASU505637A1SU 505637 A1SU505637 A1SU 505637A1SU 2086702 ASU2086702 ASU 2086702ASU 2086702 ASU2086702 ASU 2086702ASU 505637 A1SU505637 A1SU 505637A1
Authority
SU
USSR - Soviet Union
Prior art keywords
obtaining
acyl derivatives
alkyl
substituted imidazolidine
formaldehyde
Prior art date
Application number
SU2086702A
Other languages
Russian (ru)
Inventor
Елена Яковлевна Борисова
Наталья Валентиновна Кропотова
Елена Михайловна Черкасова
Original Assignee
Московский Ордена Трудового Красного Знамени Институт Тонкой Химической Технологии Им.М.В.Ломоносова
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Московский Ордена Трудового Красного Знамени Институт Тонкой Химической Технологии Им.М.В.ЛомоносоваfiledCriticalМосковский Ордена Трудового Красного Знамени Институт Тонкой Химической Технологии Им.М.В.Ломоносова
Priority to SU2086702ApriorityCriticalpatent/SU505637A1/en
Application grantedgrantedCritical
Publication of SU505637A1publicationCriticalpatent/SU505637A1/en

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Translated fromRussian

3 Пример 3. К раствору 0,6 г 1-трет-бутиламино-2-фенил - 2 - акрилоиламиноэтана в 7 мл спирта добавл ют 1,1 мл 20%-.ного водного формальдегида и 0,3 г поташа, нагревают 30 мин ири 100° С, /концентрируют в вакууме досуха, экстрагируют продукт 5x50 мл эфира, сушат экстракт сульфатом , отгон ют растворитель, перегон ют остаток в вакууме и получают 0,51 г (80,5%) 1-трет-бутил-З-аКрилоил-4-феннлимидазолидина . Свойства синтезир01ванных 1-г/9ет-бутил-3ацил-4-фенилимидазолидинов приведены в та-блице.3 Example 3. To a solution of 0.6 g of 1-tert-butylamino-2-phenyl-2-acryloylaminoethane in 7 ml of alcohol is added 1.1 ml of 20% aqueous formaldehyde and 0.3 g of potash, heated for 30 minutes Irie 100 ° C, / are concentrated in vacuo to dryness, the product is extracted with 5x50 ml of ether, the extract is dried with sulphate, the solvent is distilled off, the residue is distilled in vacuum and 0.51 g (80.5%) of 1-tert-butyl-3 is obtained aCryloyl-4-phennlimidazolidine. The properties of the synthesized 1-g / 9et-butyl-3 acyl-4-phenylimidazolidines are given in the table.

Использована окись алюмини  II степени активности.Used alumina II degree of activity.

Claims (2)

Translated fromRussian
Формула изобретени Invention Formula. 1. Способ получени  Ы-ацильных .производных замеш,ен1ных имидазолидинов общей формулы. 1. The method of obtaining N-acyl derivatives, mixed imid imidazolidines of the general formulaK{vK {v. В,Г-М. V, GM.4.fourSsSsгде R - ал кил, алкенил, арил или аралкил; RI - алкил, арил; Rs-RS - водород, алкил, на основе формальдегида, отличаюш,ийс   тем, что, с целью повышени  выхода целевого продукта и упрощени  процесса, формальдегид подвергают взаимодействию с соответствующим р-аминоаМИ1дом в среде органического растворител , например спирта, диаксана , лри 50-10,0° С.where R is alkyl, alkenyl, aryl or aralkyl; RI is alkyl, aryl; Rs-RS - hydrogen, alkyl, based on formaldehyde, is different from the fact that, in order to increase the yield of the target product and simplify the process, formaldehyde is reacted with the corresponding p-amino-IM1 in an environment of an organic solvent, for example, alcohol, dioxane, LR 50- 10.0 ° C.2. Способ по -п. 1, отличающийс  тем, что (Процесс ведут в лрисутст1вии щелочных агентов, например едкого кали, поташа.2. Method p. 1, characterized in that (The process is carried out in the alkaline agent supply, for example caustic potash, potash.
SU2086702A1974-12-241974-12-24 The method of obtaining -acyl derivatives of the substituted imidazolidineSU505637A1 (en)

Priority Applications (1)

Application NumberPriority DateFiling DateTitle
SU2086702ASU505637A1 (en)1974-12-241974-12-24 The method of obtaining -acyl derivatives of the substituted imidazolidine

Applications Claiming Priority (1)

Application NumberPriority DateFiling DateTitle
SU2086702ASU505637A1 (en)1974-12-241974-12-24 The method of obtaining -acyl derivatives of the substituted imidazolidine

Publications (1)

Publication NumberPublication Date
SU505637A1true SU505637A1 (en)1976-03-05

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Family Applications (1)

Application NumberTitlePriority DateFiling Date
SU2086702ASU505637A1 (en)1974-12-241974-12-24 The method of obtaining -acyl derivatives of the substituted imidazolidine

Country Status (1)

CountryLink
SU (1)SU505637A1 (en)

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