【0001】[0001]
【産業上の利用分野】本発明は水の電気分解及び電気浸
透作用によってイオン水を生成する装置に関する。FIELD OF THE INVENTION The present invention relates to a device for producing ionic water by electrolysis and electroosmosis of water.
【0002】[0002]
【従来の技術】イオン水生成装置は、電解槽内に隔膜を
介して陰陽極電極を設け、供給される水を前記電極間の
通電によって電気分解及び電気浸透作用によって陰極室
にアルカリイオン水を陽極室に酸性イオン水を生成す
る。しかして水道水等の供給される原水中にはカルシウ
ム,マグネシウム,その他の硬度分が含まれており、連
続して使用すると時間と共に陰極電極に水酸化カルシウ
ムとか炭酸カルシウム等のスケールが付着堆積し、電解
能力を次第に低下させる。このため従来は所定の使用時
間毎に通電極性を反転して逆洗することが行なわれてい
るが、スケール付着量に対して逆洗時間が短いと汚れを
充分に除去することができず、又、逆洗時間が長くなる
と陽極溶解によって電極が消耗し、又、この洗浄時間中
は所要のイオン水生成ができないため洗浄時間が長くな
るとそれだけ装置の稼働率が低下するといった欠点があ
った。2. Description of the Related Art An ionized water producing apparatus is provided with a negative and positive electrode in a electrolytic cell through a diaphragm, and the supplied water is electrolyzed and electroosmotically activated by energizing the electrodes to supply alkaline ionized water to a cathode chamber. Generate acidic ionized water in the anode chamber. However, the raw water supplied, such as tap water, contains calcium, magnesium, and other hardness components, and if used continuously, scales such as calcium hydroxide or calcium carbonate will adhere and accumulate on the cathode electrode over time. , Electrolytic capacity is gradually reduced. For this reason, conventionally, the back polarity is reversed by reversing the energizing polarity at every predetermined use time, but if the back wash time is short with respect to the scale adhesion amount, the stain cannot be sufficiently removed. Also, when the backwashing time becomes long, the electrode is consumed due to anodic dissolution, and since the required ionized water cannot be generated during this washing time, there is a drawback that the operating rate of the apparatus decreases as the washing time becomes longer. .
【0003】[0003]
【発明が解決しようとする課題】本発明はイオン水生成
中に電極等に付着するスケールが少なくなるよう、又、
スケール付着時に通電極性を反転して溶解洗浄させると
き等の洗浄時に洗浄効果を高め短時間に電解能力を回復
できるように改良するものである。DISCLOSURE OF THE INVENTION The present invention aims to reduce the scale attached to electrodes and the like during the generation of ionized water.
It is intended to improve the cleaning effect during cleaning such as when the energization polarity is reversed and the solution is cleaned when the scale is attached, so that the electrolytic ability can be restored in a short time.
【0004】[0004]
【課題を解決するための手段】電解イオン水生成装置の
陰極電極,陽極電極,もしくは隔膜を振動させる振動装
置を設けたことを特徴とする。A vibrating device for vibrating the cathode electrode, the anode electrode, or the diaphragm of the electrolytic ionized water generator is provided.
【0005】[0005]
【作用】本発明は前記のように陰極電極,陽極電極,も
しくは隔膜を振動させる振動装置を設けたから、正極性
通電して電解イオン水の生成中に振動させれば電極にス
ケールの付着するのを少なくすることができ、電解能力
を落さずに長時間の連続したイオン水生成を、続けるこ
とができる。又、通電極性を反転して付着スケールの逆
洗除去を行なうとき、又は通電を中断して洗浄するとき
に振動させれば洗浄効果を高め短時間で電解能力を回復
させることができ、洗浄時間を短かくすることができ
る。Since the present invention is provided with the vibrating device for vibrating the cathode electrode, the anode electrode, or the diaphragm as described above, the scale adheres to the electrode if the positive electrode is energized and vibrated during the generation of electrolytic ion water. Can be reduced, and continuous generation of ionized water for a long time can be continued without lowering the electrolysis capacity. Also, when the polarity of electricity is reversed to remove the adhered scale by backwashing, or when the electricity is interrupted and the washing is performed, vibration can be enhanced to enhance the washing effect and restore the electrolytic ability in a short time. The time can be shortened.
【0006】[0006]
【実施例】以下図面の一実施例により本発明を説明す
る。図1において、1は電解槽で、給水口1aから原水
が供給され、アルカリイオン水が吐出口1bから吐出
し、酸性イオン水が吐出口1cから吐出する。2は電解
槽1を2分する隔膜(浸透膜)で、分割された陰極室に
は陰極電極3が陽極室には陽極電極4が挿入配置され
る。陰極電極3は可振状態に設けられ、超磁歪材5をソ
レノイド6によって励磁する振動装置により超音波振動
が与えられる。7は交流電源を整流した直流出力電源
で、出力電圧を極性切換器8を経て前記陰陽極電極3,
4間に通電する。9は振動装置のコイル6を励磁する高
周波発振器である。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below with reference to an embodiment of the drawings. In FIG. 1, reference numeral 1 denotes an electrolytic cell, to which raw water is supplied from a water supply port 1a, alkaline ionized water is discharged from a discharge port 1b, and acidic ionized water is discharged from a discharge port 1c. Reference numeral 2 is a diaphragm (permeation membrane) that divides the electrolytic cell 1 into two parts. The cathode electrode 3 is inserted into the divided cathode chamber, and the anode electrode 4 is inserted into the anode chamber. The cathode electrode 3 is provided in a vibrating state, and ultrasonic vibration is applied by a vibration device that excites the giant magnetostrictive material 5 with a solenoid 6. Reference numeral 7 is a direct current output power source obtained by rectifying an alternating current power source.
Energize between four. Reference numeral 9 is a high frequency oscillator for exciting the coil 6 of the vibration device.
【0007】以上において、図示極性で電源8より陰陽
極電極3,4間に通電し、給水口1aから電解槽1内に
供給される水を電気分解すると共に隔膜2を通して電気
浸透作用を行なわせることによって陰極室にアルカリイ
オン水,陽極室に酸性イオン水を生成することができ、
各々吐出口1b,1cから取出して利用することができ
る。電解作用中、陰極電極3はコイル6の高周波励磁に
より振動する超磁歪材5の振動が伝播振動し、電極3は
常に超音波振動しながら電解作用する。このため水の電
解によってイオン水を生成中に電極3面にスケールの付
着が防止され、電解効率を低下することなく、長時間に
亘って活性状態を維持し連続して能率の良いイオン水を
生成することができる。In the above, a power source 8 having the polarity shown in the figure applies electricity between the negative and positive electrodes 3, 4 to electrolyze the water supplied from the water supply port 1a into the electrolytic cell 1 and to perform electroosmotic action through the diaphragm 2. As a result, alkaline ionized water can be generated in the cathode chamber and acidic ionized water can be generated in the anode chamber.
Each can be taken out from the discharge ports 1b and 1c and used. During the electrolytic action, the vibration of the giant magnetostrictive material 5 that vibrates by the high frequency excitation of the coil 6 propagates and vibrates in the cathode electrode 3, and the electrode 3 performs electrolytic action while constantly vibrating ultrasonically. For this reason, scale is prevented from adhering to the surface of the electrode 3 during generation of ionized water by electrolysis of water, and the active state is maintained for a long period of time without lowering electrolysis efficiency to continuously produce highly efficient ionized water. Can be generated.
【0008】振動素子の超磁歪材5には、例えばTb
0.3、Dy0.7、Fe1.95を用い、振動数30
0〜2000Hz程度の磁歪振動を容易に作用することが
できる。磁歪はロッドの寸法によって異なるが20〜3
0μm程度は容易に得られ、この振動により電極3にス
ケールが付着するのを防止することができる。なお超磁
歪材は他の素子を用いることができ、磁歪材以外に電歪
材とか、磁石,その他の振動素子を用いることができ、
振動数は更に高く10から30KHz の超音波振動を与え
ることができる。The giant magnetostrictive material 5 of the vibrating element is, for example, Tb.
0.3, Dy0.7, Fe1.95, frequency 30
Magnetostrictive vibration of about 0 to 2000 Hz can be easily applied. Magnetostriction varies depending on the size of the rod, but it is 20 to 3
A thickness of about 0 μm can be easily obtained, and this vibration can prevent the scale from adhering to the electrode 3. Other elements can be used as the giant magnetostrictive material, and in addition to the magnetostrictive material, an electrostrictive material, a magnet, or another vibrating element can be used.
The frequency is higher, and ultrasonic vibrations of 10 to 30 KHz can be applied.
【0009】又、イオン水生成の電解中に陰極電極3に
スケールが堆積して電解能力が低下したときは極性切換
器8により通電極性を反転させて逆洗処理する。この洗
浄処理は陰極電極3を正極性として通電することにより
付着するスケールを陽極溶解により溶出して除去するの
であるが、このとき電極3に超磁歪材5の振動を作用す
ることによりスケールの溶出連度を高めて短時間洗浄す
ることができ、又、電解能力を充分回復する完全清浄を
することができる。Further, when scale is deposited on the cathode electrode 3 during electrolysis for producing ionized water and the electrolysis capacity is lowered, the polarity is switched by the polarity switcher 8 to carry out backwashing treatment. In this cleaning treatment, the scale that adheres when the cathode electrode 3 is positively charged is eluted and removed by anodic dissolution. At this time, the scale is dissolved by applying the vibration of the giant magnetostrictive material 5 to the electrode 3. It is possible to perform cleaning for a short time by increasing the continuity, and to perform complete cleaning that sufficiently restores the electrolytic ability.
【0010】この通電極性を反転して洗浄するとき、陰
極電極3の溶解による消耗をともなう。勿論陽極電極4
はイオン水生成中の正極通電により陽極溶解するが、こ
れらの電極としてTi−Pt、Ti基材にPt,Au等
の貴金属コーティング、又はPt系焼成電極を用いるこ
とによって消耗させることなく永久使用することができ
る。When cleaning is performed by reversing the polarity of energization, the cathode electrode 3 is consumed due to dissolution. Of course the anode electrode 4
Is dissolved by anodic current application during the generation of ionized water, but it is used permanently without being consumed by using Ti-Pt as these electrodes, coating of a precious metal such as Pt, Au on a Ti base material, or a Pt-based firing electrode. be able to.
【0011】なお電極3の洗浄は、前記のように通電極
性を反転して行なう以外に、通電電流を中断して行なう
場合、イオン水生成を中止して薬液の供給により、行な
う場合等があるが、いずれの場合でも電極3の振動を行
なうことによって洗浄効果を高めることができ、高能率
に洗浄をすることができる。The cleaning of the electrode 3 may be carried out by reversing the energizing polarity as described above, by interrupting the energizing current, or by stopping the production of ionized water and supplying the chemical solution. However, in any case, the cleaning effect can be enhanced by vibrating the electrode 3, and cleaning can be performed with high efficiency.
【0012】図2は他の実施例で、隔膜2を介する陰極
電極3及び陽極電極4を、支持枠10によって上下端を
一体に固定支持した一体電極構成体を設け、この構成体
に振動装置11によって振動を作用させるようにしたも
のである。この場合は陰陽両電極3,4,及び隔膜2の
全体に同期的に超音波振動等を作用させることができ
る。FIG. 2 shows another embodiment, in which the cathode electrode 3 and the anode electrode 4 via the diaphragm 2 are integrally fixed and supported by the support frame 10 at the upper and lower ends thereof, and an integrated electrode structure is provided to this structure. The vibration is applied by 11. In this case, ultrasonic vibration or the like can be applied to the entire positive and negative electrodes 3, 4, and the diaphragm 2 synchronously.
【0013】勿論、隔膜2,陰極電極3,及び陽極電極
4に各々独立した振動装置で振動を作用させることがで
き、この場合は各々に最良に振動数,振幅を制御した振
動を与えることができる。又、各電極等への振動の作用
は、電解によるイオン水生成中は停止しておき、スケー
ル除去の洗浄時のみに振動作用することができる。又、
イオン水生成中は小さい微細な振動を与え、洗浄時に振
幅の大きい強い振動を与えて洗浄効果を高める等の制御
を発振器9によって行なうことができる。Of course, the diaphragm 2, the cathode electrode 3, and the anode electrode 4 can be vibrated by independent vibrating devices, and in this case, the vibration whose frequency and amplitude are controlled is best applied to each. it can. Further, the action of vibration on each electrode or the like can be stopped during the generation of ionized water by electrolysis, and the action of vibration can be performed only during cleaning for scale removal. or,
The oscillator 9 can perform control such that a small minute vibration is given during the generation of ionized water and a strong vibration having a large amplitude is given at the time of washing to enhance the washing effect.
【0014】[0014]
【発明の効果】以上のように本発明は、陰極電極,陽極
電極,もしくは隔膜を振動させる振動装置を設けたか
ら、正極性通電をして電解イオン水の生成中に振動させ
れば、電極等に付着するスケールの付着量を少なくする
ことができ、電解能力を落とさずに長時間の連続したイ
オン水生成を続けることができる。又、通電極性を反転
して付着スケールの逆洗とか、通電を中断して洗浄する
ときに振動を行なわせば、洗浄効果を高め短時間で電解
能力を回復させることができ、洗浄時間を短縮すること
ができる。As described above, according to the present invention, the vibrating device for vibrating the cathode electrode, the anode electrode, or the diaphragm is provided. It is possible to reduce the amount of scale that adheres to the surface and to continue the generation of ionized water for a long time without lowering the electrolysis capacity. In addition, by reversing the polarity of energization and backwashing the adhered scale, or by suspending energization and performing vibration during washing, it is possible to enhance the washing effect and restore the electrolytic capacity in a short time. It can be shortened.
【図1】本発明の一実施例の構成図である。FIG. 1 is a configuration diagram of an embodiment of the present invention.
【図2】本発明の他の実施例の一部構成図である。FIG. 2 is a partial configuration diagram of another embodiment of the present invention.
1 電解槽 2 隔膜 3 陰極電極 4 陽極電極 5 超磁歪材 6 励磁コイル 7 通電電源 8 極性切換器 9 高周波発振器 DESCRIPTION OF SYMBOLS 1 Electrolyzer 2 Diaphragm 3 Cathode electrode 4 Anode electrode 5 Giant magnetostrictive material 6 Excitation coil 7 Energizing power source 8 Polarity switch 9 High frequency oscillator
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP32046192AJPH06165985A (en) | 1992-11-30 | 1992-11-30 | Ionized water forming device |
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP32046192AJPH06165985A (en) | 1992-11-30 | 1992-11-30 | Ionized water forming device |
| Publication Number | Publication Date |
|---|---|
| JPH06165985Atrue JPH06165985A (en) | 1994-06-14 |
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP32046192APendingJPH06165985A (en) | 1992-11-30 | 1992-11-30 | Ionized water forming device |
| Country | Link |
|---|---|
| JP (1) | JPH06165985A (en) |
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6007686A (en)* | 1994-08-26 | 1999-12-28 | Medical Discoveries, Inc. | System for elctrolyzing fluids for use as antimicrobial agents |
| US6117285A (en)* | 1994-08-26 | 2000-09-12 | Medical Discoveries, Inc. | System for carrying out sterilization of equipment |
| KR100890604B1 (en)* | 2008-07-03 | 2009-03-25 | 아쿠아셀 주식회사 | Drinking water production equipment rich in dissolved oxygen and hydrogen |
| US8182656B2 (en) | 2007-09-11 | 2012-05-22 | Sanyo Electric Co., Ltd. | Electrolyzing device |
| JP2012196643A (en)* | 2011-03-23 | 2012-10-18 | Yoshihisa Ishii | Apparatus for producing hypochlorous acid water or the like |
| CN111268770A (en)* | 2020-03-31 | 2020-06-12 | 浙江工业大学 | Electric flocculation reactor |
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6007686A (en)* | 1994-08-26 | 1999-12-28 | Medical Discoveries, Inc. | System for elctrolyzing fluids for use as antimicrobial agents |
| US6117285A (en)* | 1994-08-26 | 2000-09-12 | Medical Discoveries, Inc. | System for carrying out sterilization of equipment |
| US8182656B2 (en) | 2007-09-11 | 2012-05-22 | Sanyo Electric Co., Ltd. | Electrolyzing device |
| KR100890604B1 (en)* | 2008-07-03 | 2009-03-25 | 아쿠아셀 주식회사 | Drinking water production equipment rich in dissolved oxygen and hydrogen |
| JP2012196643A (en)* | 2011-03-23 | 2012-10-18 | Yoshihisa Ishii | Apparatus for producing hypochlorous acid water or the like |
| CN111268770A (en)* | 2020-03-31 | 2020-06-12 | 浙江工业大学 | Electric flocculation reactor |
| Publication | Publication Date | Title |
|---|---|---|
| RU2264894C2 (en) | Electrochemical working process | |
| JPH10328669A5 (en) | ||
| US20070131543A1 (en) | Electro plate vibration structure of oxygen/hydrogen mixture gas generator | |
| JPH06165985A (en) | Ionized water forming device | |
| EP2300059A1 (en) | Atomization apparatus | |
| JP3680096B2 (en) | Electrolytic ozone water production method and apparatus, and method for regenerating solid polymer electrolyte membrane | |
| JP2008150665A (en) | Method for producing ozone water | |
| WO2006057204A1 (en) | Spraying device-use piezoelectric vibrator and drive control method thereof | |
| JPH06328071A (en) | Electrode life determination device for electrolyzed ionic water generation device | |
| JPH0648886U (en) | Water purifier with vibration function | |
| JP2011110453A (en) | Atomizer for forming film | |
| JPH0631277A (en) | Cleaning device for electrolytic water preparation device | |
| JP2607326Y2 (en) | Electrode type water reformer | |
| JPH06277668A (en) | Water preparation device | |
| JPH09143780A (en) | Electrode cleaner | |
| TWI668338B (en) | Metal surface processing apparatus | |
| JPH0671265A (en) | Continuous electrolytic water generator | |
| JP2000117256A (en) | Device for production of electrolytic water | |
| JP3061490B2 (en) | Electrolytic ionic water generator | |
| JPH06178980A (en) | Electrolytically ionized water forming device | |
| JPH09220577A (en) | Electrolyzing apparatus | |
| JPH01242405A (en) | Ozonizer | |
| JP2005296878A (en) | Electrolytic ion water generator | |
| JP3286900B2 (en) | Plating method and plating equipment | |
| JPH078954A (en) | Diaphragm washing method of electrolytic water making apparatus, electrolytic diaphragm used therein and electrolytic water making apparatus equipped with mechanism performing diaphragm whasing method |