【０００１】[0001]
【発明の属する技術分野】本発明は、室内、中でも密閉
空間容積の小さい乗用車等の自動車の車室、特にエアー
コンディショナーを備えた車室内用の据置き型消臭剤に
関するものである。本発明は、自動車、中でも密閉空間
容積の小さい乗用車の車室、特にエアーコンディショナ
ーを備えた車室内用の据置き型消臭剤に関するものであ
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a stationary type deodorant for use in a vehicle room, particularly for a vehicle room such as a passenger vehicle having a small enclosed space, particularly for a vehicle room equipped with an air conditioner. TECHNICAL FIELD The present invention relates to a stationary deodorant for automobiles, especially for passenger compartments having a small enclosed space, particularly for interiors of vehicles equipped with an air conditioner.
【０００２】[0002]
【従来の技術】従来、室内、中でも自動車の車室内の消
臭剤としては、活性炭、シリカゲルのような吸着性多孔
質物質を用いたものや、合成や天然の有機又は無機消臭
性物質を担持させたものが多用されている。しかしなが
ら、これらの消臭剤は吸着能力、量等に応じて、それら
の効果は限られており、初期は悪臭量が減じられるため
に、ある一定期間は消臭感が得られるが、継続的な悪臭
の主な発生源である細菌、カビの繁殖を抑えることはで
きないため、該繁殖に伴い次々と発生してくる悪臭量
が、その消臭能を超えると、再び感知される量に達して
臭気の再発生を感じさせるようになるのを免れない。ま
た、継続的な悪臭の主な発生源である細菌、カビの繁殖
を抑えるため、除菌剤をエアゾール、又は加熱蒸散によ
って処理する製品が市販されているが、装備等にコスト
がかかると同時に、その除菌剤の効果で処理直後の消臭
性は良好であるが、薬剤の単位時間当りの消費量が多く
残存量の減少度も高いため、作用の持続性に欠けるとい
う問題があった。2. Description of the Related Art Conventionally, as a deodorant in a room, especially in a vehicle cabin, an adsorbent porous material such as activated carbon or silica gel, or a synthetic or natural organic or inorganic deodorant is used. What is carried is often used. However, the effects of these deodorants are limited according to the adsorption capacity, amount, etc., and since the amount of malodor is initially reduced, a deodorant sensation can be obtained for a certain period of time. Since the growth of bacteria and mold, which are the main sources of unpleasant odors, cannot be suppressed, if the amount of odors generated one after another during the breeding exceeds its deodorizing ability, it will reach the amount perceived again. I can't help but feel the odor reappear. In addition, in order to suppress the growth of bacteria and mold, which are the main sources of continuous odors, products that treat the disinfectant by aerosol or heat evaporation are commercially available, but at the same time the cost of equipment etc. increases. Although the deodorant effect immediately after the treatment is good due to the effect of the disinfectant, there is a problem that since the consumption amount of the drug per unit time is large and the residual amount is reduced to a high degree, there is a lack of sustained action. .
【０００３】[0003]
【発明が解決しようとする課題】本発明は、このような
従来の消臭剤のもつ欠点を克服し、悪臭発生源となる細
菌、カビ等の微生物の繁殖を格別の装備を要さず簡単に
抑制し、悪臭の発生を長期間防止し、しかも安全である
消臭剤を提供することを目的としてなされたものであ
る。SUMMARY OF THE INVENTION The present invention overcomes the drawbacks of the conventional deodorant and makes it easy to propagate microorganisms such as bacteria and molds, which are sources of offensive odor, without requiring special equipment. The purpose of the present invention is to provide a deodorant which is safe, prevents the generation of offensive odor for a long time, and is safe.
【０００４】[0004]
【課題を解決するための手段】本発明者らは、前記した
好ましい特性を有する消臭剤を開発するために種々研究
を重ねた結果、常温で適度に蒸散される特定の除菌成分
を取り扱いやすい据置き形態に取り込んだものが、微生
物の繁殖を抑制し、悪臭の発生を長期間防止するととも
に、既に発生していた又は少量ながらも発生した悪臭を
捕捉しうることを見出し、この知見に基づいて本発明を
なすに至った。The inventors of the present invention have conducted various studies to develop a deodorant having the above-mentioned preferable characteristics. As a result, the present inventors have dealt with a specific sterilizing component which is appropriately evaporated at room temperature. It was found that what was incorporated in an easy-to-install configuration could suppress the growth of microorganisms, prevent the generation of foul odors for a long time, and capture the foul odor that was already generated or generated even in small quantities. Based on this, the present invention has been accomplished.
【０００５】すなわち、本発明は、（１）オルトフェニ
ルフェノール、４‐クロロ‐３，５‐ジメチルフェノー
ル、２‐メチル‐３‐クロロフェノール、メチルパラベ
ン、エチルパラベン、プロピルパラベン、ブチルパラベ
ン、イソプロピルメチルフェノール、８‐キノリノール
及び安息香酸ナトリウムの中から選ばれた少なくとも１
種の除菌成分を含有する粒状物を通気性包装体に収容し
たことを特徴とする据置き型消臭剤、を提供するもので
ある。That is, the present invention relates to (1) orthophenylphenol, 4-chloro-3,5-dimethylphenol, 2-methyl-3-chlorophenol, methylparaben, ethylparaben, propylparaben, butylparaben, and isopropylmethylphenol. At least one selected from quinolinol, 8-quinolinol and sodium benzoate
It is intended to provide a stationary deodorant characterized in that a granular material containing various kinds of bacteria-eliminating components is accommodated in a breathable package.
【０００６】[0006]
【発明の実施の形態】本発明の好ましい態様としては、
（２）粒状物がさらに消臭成分を含有する前記（１）記
載の据置き型消臭剤、（３）消臭成分が植物抽出物系の
ものである前記（１）又は（２）記載の据置き型消臭
剤、（４）消臭成分が合成物系のものである前記
（１）、（２）又は（３）記載の据置き型消臭剤、
（５）粒状物がさらに吸着成分を含有する前記（１）な
いし（４）のいずれかに記載の据置き型消臭剤、（６）
粒状物がさらに香料を含有する前記（１）ないし（５）
のいずれかに記載の据置き型消臭剤、（７）粒状物がさ
らに保持材を用いてなる前記（１）ないし（６）のいず
れかに記載の据置き型消臭剤、（８）保持材がタルク、
カオリン、粘土鉱物、ケイ酸塩、ガラス、ケイソウ土、
天然及び／又は合成樹脂、天然及び／又は合成ゴム、パ
ラフィンロウ、糖類、多糖類、小麦粉、デンプンからな
る前記（７）記載の据置き型消臭剤、（９）保持材が多
孔質材、被混練材及び被混合材の中から選ばれた少なく
とも１種である前記（７）又は（８）記載の据置き型消
臭剤、（１０）前記（１）ないし（９）のいずれかに記
載の粒状物と、消臭成分、吸着成分及び香料の中から選
ばれた少なくとも１種を含有する別の粒状物とを通気性
包装体に収容したことを特徴とする据置き型消臭剤、
（１１）消臭成分が植物抽出物系及び／又は合成物系の
ものである前記（１０）記載の据置き型消臭剤。（１
２）吸着成分が活性炭、シリカゲル、黒鉛、カーボンブ
ラック、金属酸化物及びゼオライトの中から選ばれた少
なくとも１種のものである前記（５）ないし（１１）の
いずれかに記載の据置き型消臭剤、が挙げられる。DESCRIPTION OF THE PREFERRED EMBODIMENTS Preferred embodiments of the present invention include:
(2) The stationary deodorant according to (1), wherein the granular material further contains a deodorant component, and (3) the (1) or (2), wherein the deodorant component is of a plant extract type. (4) The stationary deodorant according to (1), (2) or (3), wherein the deodorant component is of a synthetic type.
(5) The stationary deodorant according to any one of the above (1) to (4), wherein the granular material further contains an adsorption component, (6)
(1) to (5), wherein the granular material further contains a fragrance.
(7) The stationary deodorant according to any one of (1) to (6), wherein the granular material further comprises a holding material, (8) Talc,
Kaolin, clay minerals, silicates, glass, diatomaceous earth,
The stationary deodorant according to the above (7), comprising a natural and / or synthetic resin, natural and / or synthetic rubber, paraffin wax, saccharide, polysaccharide, flour, starch, (9) a porous material, The stationary deodorant according to the above (7) or (8), which is at least one member selected from a kneaded material and a mixed material, (10) any of the above (1) to (9). A stationary deodorant comprising a particulate material described above and another particulate material containing at least one selected from a deodorant component, an adsorbent component, and a fragrance in a gas-permeable package. ,
(11) The stationary deodorant according to the above (10), wherein the deodorant component is a plant extract type and / or a synthetic type. (1
2) The stationary type extinction device according to any one of (5) to (11), wherein the adsorption component is at least one selected from activated carbon, silica gel, graphite, carbon black, metal oxide, and zeolite. Odorants.
【０００７】本発明の据置き型消臭剤においては除菌成
分として オルトフェニルフェノール、メタクレゾー
ル、４‐クロロ‐３，５‐ジメチルフェノール、２‐メ
チル‐３‐クロロフェノール、メチルパラベン、エチル
パラベン、プロピルパラベン、ブチルパラベン、イソプ
ロピルメチルフェノール、８‐キノリノール、安息香酸
ナトリウムが用いられる。これらは分子量が２００以下
と低分子量で、適度な自然蒸散性を示し、しかも安全な
ものである。これらは単独で用いてもよいし、２種以上
を組み合わせて用いてもよい。これら以外の分子量が大
きく、常温における蒸散がほとんど期待できない物質で
は、悪臭を発生させる微生物が繁殖している場所まで到
達して、それらを抑制することがほとんど不可能なた
め、それらを用いることによる効果もほとんど期待でき
ない。また、逆に分子量が１００以下と小さいアルコー
ル等の液状物質では、液状であるため取り扱いにくく、
揮発性が速く、設置又は処理直後は効果が期待できるも
のの、薬剤が処理部に長くは残存しないため、持続性に
乏しく、そのため早くに微生物の再繁殖を招来し、悪臭
の再発生が起こるようになる。In the stationary deodorant of the present invention, ortho-phenylphenol, meta-cresol, 4-chloro-3,5-dimethylphenol, 2-methyl-3-chlorophenol, methylparaben, ethylparaben, Propylparaben, butylparaben, isopropylmethylphenol, 8-quinolinol, sodium benzoate are used. These have a low molecular weight of 200 or less, exhibit moderate spontaneous transpiration, and are safe. These may be used alone or in combination of two or more. Substances with a large molecular weight other than these, which can hardly be expected to evaporate at room temperature, reach the place where the odor-producing microorganisms are growing, and it is almost impossible to suppress them. Little effect can be expected. Conversely, liquid substances such as alcohols having a molecular weight as small as 100 or less are difficult to handle because they are liquid,
Although the volatility is fast and the effect can be expected immediately after installation or treatment, since the drug does not remain in the treatment section for a long time, it is poor in persistence, so that the microorganisms re-proliferate quickly and the odor reappears. become.
【０００８】本発明においては、除菌成分の効果を捕助
するために、さらに消臭成分、中でも発生した悪臭物質
（例えば含窒素又は硫黄化合物等）を選択的に捕捉し
て、中和等の反応を起こさせたり、包接させたりするよ
うな消臭成分を含有させるのが好ましい。このような消
臭成分としては、例えば植物抽出物系のものや、合成物
系のもの等が挙げられる。植物抽出物系消臭成分の例と
しては、お茶、フキ、ツワブキ、シダ、ベイ、ジャスミ
ン、シナモン、丁字、ユーカリ、ベルガモット、ドクダ
ミ、アビエス、竹、ヒノキ、ヒバ、松、椿、バラ、ヒイ
ラギモクセイ、ヤマナラシ、キリ、コナラ、レンギョ
ウ、ライラック、オレンジ、レモン、ペパーミント、リ
ンゴ又は柿の由来のものなどが挙げられ、中でも柿又は
緑茶の抽出物、例えば柿渋タンニンを主成分としたリリ
ース科学社製「パンシル」、緑茶フラボノイドを主成分
とした小川香料社製「ジュウヤクエキス」、松下電工化
研社製「ピュリエール」等の市販品などが挙げられる。
合成物系消臭成分の例としては、主に中和等の化学的処
理を行うものとして、ベタイン型両性化合物、イミダゾ
リウム化合物、四級アミン型化合物、クエン酸、乳酸、
リンゴ酸等の有機酸やその塩、グリオキサール、グルタ
ールアルデヒドなどが挙げられ、また、吸収等の物理的
処理を行うものとして、流動パラフィン、高級アルコー
ル、エチレングリコール、ジエチレングリコール、トリ
エチレングリコール、ポリエチレングリコール、プロピ
レングリコール、ジプロピレングリコール、ポリプロピ
レングリコール、シクロデキストリンなどが挙げられ、
中でもリシノール酸亜鉛（市販品として、ゴールドシュ
ミット社製「ＴＥＧＯＳＯＲＢ」がある）、２‐エチル
ヘキサン酸亜鉛（市販品として、大洋香料社製「オクト
ープ亜鉛」がある）などが挙げられる。これらの消臭成
分は一般に液状物質であるため、乳糖、デンプン、デン
プン糖、シクロデキストリン、粉末セルロース等の糖類
や多糖類、小麦ファイバー、アップルファイバー、オレ
ンジファイバー、トマトファイバー、シリカゲルなどの
含浸剤で吸着等の保持処理を施した粒状物の形で配合す
るのがよい。[0008] In the present invention, in order to capture the effect of the bacteria-eliminating component, deodorizing components, in particular, generated malodorous substances (eg, nitrogen-containing or sulfur compounds) are selectively captured to neutralize the components. It is preferable to include a deodorant component that causes the reaction described above or causes the reaction to be included. Such deodorizing components include, for example, those based on plant extracts and those based on synthetic substances. Examples of plant extract-based deodorant components include tea, butterbur, camellia, fern, bay, jasmine, cinnamon, choji, eucalyptus, bergamot, dokudami, abies, bamboo, hinoki, hiba, pine, camellia, rose, and holly , Porcupine, drill, oak, forsythia, lilac, orange, lemon, peppermint, apples or persimmons, etc., among others, extracts of persimmons or green tea, for example, Release Science Co., Ltd. Commercially available products such as "Pancil", "Juyaku Extract", which is mainly composed of green tea flavonoids, and "Purier", manufactured by Matsushita Electric Works, Ltd. are available.
Examples of the synthetic deodorant component include those mainly performing chemical treatment such as neutralization, betaine-type amphoteric compounds, imidazolium compounds, quaternary amine-type compounds, citric acid, lactic acid,
Organic acids such as malic acid and salts thereof, glyoxal, glutaraldehyde, and the like. Examples of physical treatments such as absorption include liquid paraffin, higher alcohols, ethylene glycol, diethylene glycol, triethylene glycol, and polyethylene glycol. , Propylene glycol, dipropylene glycol, polypropylene glycol, cyclodextrin and the like,
Among them, zinc ricinoleate (a commercially available product, "TEGOSORB" manufactured by Goldschmidt Co., Ltd.) and zinc 2-ethylhexanoate (a commercially available product, "Octop Zinc" manufactured by Taiyo Perfumery Co., Ltd.) are exemplified. Since these deodorizing components are generally liquid substances, they are impregnated with saccharides and polysaccharides such as lactose, starch, starch sugar, cyclodextrin, and powdered cellulose, and impregnating agents such as wheat fiber, apple fiber, orange fiber, orange fiber, tomato fiber, and silica gel. It is preferable to mix in the form of a granular material subjected to a holding treatment such as adsorption.
【０００９】本発明においては、悪臭物質の脱臭をより
向上させるため、吸着成分を含有させるのが好ましい。
吸着成分としては、例えば活性炭、黒鉛、カーボンブラ
ック、亜鉛華のような金属酸化物、ゼオライト等が挙げ
られる。これらは単独で用いてもよいし、２種以上を組
み合わせて用いてもよい。また、吸着成分は、後述の保
持材としても用いることができる。In the present invention, in order to further improve the deodorization of malodorous substances, it is preferable to contain an adsorbing component.
Examples of the adsorption component include activated carbon, graphite, carbon black, metal oxides such as zinc white, zeolite, and the like. These may be used alone or in combination of two or more. Further, the adsorption component can be used as a holding material described later.
【００１０】本発明においては、悪臭物質の臭気や場合
により上記各成分の臭気をマスキングするため、適宜香
料を含有させてもよい。香料の例としては、リモネン、
ゲラニオール、ピネン、シトロネラール、ミルセン、バ
ニリン、フェネチルアルコール、酢酸ゲラニル、サリチ
ル酸ベンジル、リナロール、ローズ油、レモン油、ジャ
スミン油、スペアミント油、酢酸イソペンチル、ターピ
ノレン、ターピネン、フェランドレン、カリオフィレ
ン、フェルネセン、ジフェニルメタン、ヘキセノール、
デセノール、ウンデセノール、ノナジエノール、ネロー
ル、ヒドロキシシトロネロール、ジヒドロミルセノー
ル、ボルネオール、イソプレゴール、ファルネソール、
ネロリドール、４‐イソプロピルシクロヘキサノール、
ジメチルベンジルカルビノール、１‐メチル‐１‐メト
キシシクロドデカン、ベンジルイソオイゲノール、トリ
メチルヘキシルアルデヒド、イソシクロシトラール、メ
チルノニルケトン、フラクトン、エチレンブラシレー
ト、６‐アセチルヘキサテトラリンなどが挙げられる。
中でも、香料と消臭成分の機能、すなわちマスキングと
消臭効果を併せ持つもの、例えばヒノキチオールのよう
な植物精油等を含有させるのがよい。In the present invention, a fragrance may be appropriately contained in order to mask the odor of the malodorous substance and, if necessary, the odor of each of the above components. Examples of fragrances are limonene,
Geraniol, pinene, citronellal, myrcene, vanillin, phenethyl alcohol, geranyl acetate, benzyl salicylate, linalool, rose oil, lemon oil, jasmine oil, spearmint oil, isopentyl acetate, terpinolene, terpinene, ferrandren, caryophyllene, fernesene, diphenylmethane, hexenol ,
Decenol, undecenol, nonadienol, nerol, hydroxycitronellol, dihydromyrcenol, borneol, isopulegol, farnesol,
Nerolidol, 4-isopropylcyclohexanol,
Examples include dimethylbenzylcarbinol, 1-methyl-1-methoxycyclododecane, benzylisoeugenol, trimethylhexylaldehyde, isocyclocitral, methylnonyl ketone, fractone, ethylene brassate, and 6-acetylhexatetralin.
Above all, it is preferable to contain a substance having both functions of a fragrance and a deodorant component, that is, a masking and deodorizing effect, for example, a plant essential oil such as hinokitiol.
【００１１】本発明においては、さらに上記各成分の保
持材を用いてもよい。保持材はその形状が粒状であり、
上記除菌成分や、それを主とする他成分との混合物や、
これらの成分の１種又は２種以上を吸着、接着、担持、
含浸、混練、混合等で保持しうるものであれば特に限定
されず、このようなものとしてはタルク、カオリン、粘
土鉱物、ケイ酸塩、ガラス、ケイソウ土、天然及び／又
は合成樹脂、天然及び／又は合成ゴム、パラフィンロ
ウ、糖類、多糖類、小麦粉、デンプンからなるもの、中
でも多孔質材や、被混練材又は被混合材すなわち所定成
分を混練又は混合等で保持しうるものが好ましい。In the present invention, a holding material for each of the above components may be used. The holding material is granular in shape,
The above-mentioned bacteria-eliminating component and a mixture with other components mainly containing it,
One, two or more of these components are adsorbed, adhered, carried,
There is no particular limitation as long as it can be retained by impregnation, kneading, mixing, and the like. Such materials include talc, kaolin, clay mineral, silicate, glass, diatomaceous earth, natural and / or synthetic resin, natural and / or synthetic resin. And / or synthetic rubber, paraffin wax, saccharides, polysaccharides, flour, and starch, among which a porous material, a material to be kneaded or a material to be mixed, that is, a material capable of holding a predetermined component by kneading or mixing is preferable.
【００１２】本発明において用いられる除菌成分を含有
する粒状物としては、除菌成分だけからなるものであっ
てもよいし、またそれを主とする他成分との混合物から
なるものであってもよいし、また除菌成分や、それを主
とする他成分との混合物や、これら複数の異種成分を保
持材に保持させたものであってもよい。また、除菌成分
を含有する粒状物とともに、消臭成分、吸着成分及び香
料の中から選ばれた少なくとも１種を含有する別の粒状
物を併用してもよい。これら粒状物は粒径が１〜５ｍ
ｍ、中でも２〜４ｍｍの範囲であるのが好ましい。The granular material containing a disinfecting component used in the present invention may be composed of only a disinfecting component or a mixture of the disinfecting component and other components mainly. It may be a bactericidal component, a mixture with another component mainly containing the bactericidal component, or a material in which a plurality of these different components are held by a holding material. In addition, another granular material containing at least one selected from a deodorant component, an adsorbing component, and a fragrance may be used in combination with the granular material containing the sterilizing component. These granules have a particle size of 1 to 5 m.
m, especially preferably in the range of 2 to 4 mm.
【００１３】本発明においては、除菌成分を含有する粒
状物だけを用いるかあるいは該粒状物と上記の別の粒状
物を併用し、これを通気性包装体に収容してなるが、こ
の通気性包装体については、除菌成分、消臭成分、香料
等の蒸発、揮発あるいは気化ガスを車室内に適度に、好
ましくは徐放的に常温で自然蒸散させるものであれば特
に制限されず、このようなものとしては、例えば紙、
布、樹脂フィルム又はシート、金属箔又はシート等、中
でも和紙や、アクリル系、レーヨン系、コットン系等の
不織布を素材とし、必要に応じ微小孔や、ハニカム構造
のような貫通孔を設けた方形や円形等の適当な形状の袋
状体などが挙げられる。また、通気性包装体には適当な
箇所に保持あるいは装着しうるように吸盤や粘着材や面
ファスナー〔マジックテープ（登録商標）〕等の係止具
あるいは装着具あるいは固着具を設けてもよい。In the present invention, only the granular material containing the bacteria-eliminating component is used, or the granular material is used in combination with the other granular material, and the granular material is contained in a gas-permeable package. No particular limitation is imposed on the sex packaging, as long as it allows the natural vaporization of the eradication, volatilization or vaporization gas of the bacteria-eliminating component, deodorant component, fragrance, etc. in the passenger compartment appropriately, preferably gradually and at room temperature in a controlled release manner. Such things include, for example, paper,
Cloth, resin film or sheet, metal foil or sheet, etc., among them, Japanese paper, acrylic, rayon, cotton, etc. non-woven fabrics, and if necessary, micro holes or squares with through holes such as honeycomb structure And a bag-shaped body having an appropriate shape such as a circle or the like. Further, the breathable package may be provided with a locking device such as a suction cup, an adhesive or a hook-and-loop fastener (Magic Tape (registered trademark)), a mounting device, or a fixing device so as to be held or mounted at an appropriate location. .
【００１４】[0014]
【実施例】次に、実施例により本発明を更に詳細に説明
するが、本発明はこれらの例によって何ら限定されるも
のではない。なお、各例において、試験品の各成分の配
合％は特に指示されない限り質量基準のものである。 実施例１〜４、比較例１〜３ 表１に示す配合あるいは単独処方の、平均粒径３ｍｍの
ビーズ状物を通気性布袋に入れた試験品を用意した。な
お、消臭成分はそれを含浸剤に含浸させた細粒物として
配合し、その配合割合を該細粒物中の消臭成分基準で表
示した。また、ビーズ状物における表示成分（香料を含
む）を除く残分はパラフィンロウである。ただし、比較
例１では活性炭入りゲル製剤のみを試験品として用い
た。これらの各試験品について以下の各種試験を行い、
評価した。その結果も表１に示す。Next, the present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples. In each of the examples, the percentage of each component of the test sample is based on mass unless otherwise specified. Examples 1 to 4 and Comparative Examples 1 to 3 Test articles were prepared in which a beaded material having an average particle diameter of 3 mm and contained in the air-permeable cloth bag was blended or independently formulated as shown in Table 1. The deodorant component was blended as fine particles impregnated with an impregnating agent, and the blending ratio was indicated based on the deodorant component in the fine particles. The remainder of the bead-like material other than the display components (including the fragrance) is paraffin wax. However, in Comparative Example 1, only the gel preparation containing activated carbon was used as a test product. Perform the following various tests on each of these test items,
evaluated. Table 1 also shows the results.
【００１５】[0015]
【表１】[Table 1]
【００１６】（１）除菌性 各試験品を、大腸菌を接種した普通寒天培地及び黒麹黴
胞子を接種したポテトデキストロース寒天培地とともに
密閉容器内に置き、３０℃で３日間放置した後、開封し
て微生物の繁殖状態を目視により両培地の全表面積に対
するコロニーの面積の割合で評価した。なお、各培地の
寸法形状は互いに全く同じである。 ○ コロニー面積３０％未満 △ コロニー面積３０％以上６０％未満 × コロニー面積６０〜１００％(1) Bactericidal property Each test product was placed in a closed container together with a normal agar medium inoculated with Escherichia coli and a potato dextrose agar medium inoculated with black koji mold spores, left at 30 ° C. for 3 days, and then opened. Then, the propagation state of the microorganisms was visually evaluated by the ratio of the area of the colony to the total surface area of both media. The dimensions and shape of each medium are exactly the same. ○ Colony area less than 30% △ Colony area 30% or more and less than 60% × Colony area 60-100%
【００１７】（２）除菌持続性 各試験品を予め２５℃の室内で２週間放置し、これを、
大腸菌を接種した普通寒天培地及び黒麹黴胞子を接種し
たポテトデキストロース寒天培地とともに密閉容器内に
置き、３０℃で３日間放置した後、開封して微生物の繁
殖状態を目視により両培地の全表面積に対するコロニー
の面積の割合で評価した。なお、各培地の寸法形状は互
いに全く同じである。 ○ コロニー面積３０％未満 △ コロニー面積３０％以上６０％未満 × コロニー面積６０〜１００％(2) Persistence of sterilization Each test product was left in a room at 25 ° C. for 2 weeks in advance.
Place it in a closed container together with a normal agar medium inoculated with Escherichia coli and a potato dextrose agar medium inoculated with black koji mold spores, leave at 30 ° C. for 3 days, open, and visually observe the propagation state of the microorganisms on the total surface area of both culture media. Was evaluated by the ratio of the area of the colony to the total. The dimensions and shape of each medium are exactly the same. ○ Colony area less than 30% △ Colony area 30% or more and less than 60% × Colony area 60-100%
【００１８】（３）消臭性 上記除菌性評価時、容器内に発生していた悪臭の濃度を
ガス検知管で測定し、この測定値を、試験品を用いなか
った以外は上記除菌性試験と同様にした場合の悪臭濃度
の測定値に対する割合（これを消臭率という）として出
し、以下の基準で評価した。 ○ 消臭率８０％以上 △ 消臭率４０％以上８０％未満 × 消臭率４０％未満(3) Deodorizing property At the time of the above-described evaluation of the sterilization property, the concentration of the malodor generated in the container was measured with a gas detector tube, and the measured value was used as the above-mentioned sterilization except that the test sample was not used. The ratio to the measured value of the malodor concentration in the same manner as in the sex test (this is referred to as a deodorization rate) was evaluated based on the following criteria. ○ Deodorization rate 80% or more △ Deodorization rate 40% or more and less than 80% × Deodorization rate less than 40%
【００１９】（４）消臭持続性 上記除菌持続性評価時、容器内に発生していた悪臭の濃
度をガス検知管で測定し、この測定値を、試験品を用い
なかった以外は上記除菌持続性試験と同様にした場合の
悪臭濃度の測定値に対する割合（これを消臭率という）
として出し、以下の基準で評価した。 ○ 消臭率８０％以上 △ 消臭率４０％以上８０％未満 × 消臭率４０％未満(4) Deodorant Persistence At the time of the above evaluation of the bacteria elimination persistence, the concentration of the malodor generated in the container was measured with a gas detector tube, and the measured value was measured as described above except that no test product was used. Percentage of measured odor concentration measured in the same manner as in the bacteria elimination persistence test (this is called the deodorization rate)
And evaluated according to the following criteria. ○ Deodorization rate 80% or more △ Deodorization rate 40% or more and less than 80% × Deodorization rate less than 40%
【００２０】実施例５〜１０ 実施例１のビーズ状物における除菌成分に代えて、オル
トフェニルフェノール、４‐クロロ‐３，５‐ジメチル
フェノール、エチルパラベン、プロピルパラベン、ブチ
ルパラベン及び安息香酸ナトリウムのそれぞれについ
て、各使用した以外は実施例１と同様にして試験品を用
意し、試験したところ、それぞれ実施例１と同様の評価
結果を得た。Examples 5 to 10 Orthophenylphenol, 4-chloro-3,5-dimethylphenol, ethylparaben, propylparaben, butylparaben and sodium benzoate were used in place of the bacteria-eliminating components in the beads in Example 1. For each of the above, a test product was prepared and tested in the same manner as in Example 1 except for using each, and the same evaluation results as in Example 1 were obtained.
【００２１】実施例１１ メチル‐パラベン２．５質量部とパラフィンロウ４７．
５質量部との混練物からなる平均粒径３ｍｍのビーズ状
物と、パンシル５．０質量部をシリカゲル４．７質量部
に含浸させて細粒化したもの、カーボンブラック０．３
質量部及びパラフィンロウ４０．０質量部の混練物から
なる平均粒径３ｍｍのビーズ状物とを互いに同質量で通
気性布袋に入れた試験品を用意し、実施例１と同様にし
て試験したところ、実施例１と同様の評価結果を得た。Example 11 2.5 parts by weight of methyl-paraben and paraffin wax
5 parts by mass of a kneaded product, a bead having an average particle diameter of 3 mm, 5.0 parts by mass of Pansil impregnated with 4.7 parts by mass of silica gel to obtain fine particles, carbon black 0.3
A bead having an average particle size of 3 mm and a bead comprising 40.0 parts by mass of paraffin wax and 40.0 parts by mass of paraffin wax was prepared in the same mass in a breathable cloth bag, and tested in the same manner as in Example 1. However, the same evaluation results as in Example 1 were obtained.
【００２２】実施例１２ ２‐メチル‐３‐クロロフェノール２．５質量部とパラ
フィンロウ４７．５質量部との混練物からなる平均粒径
３ｍｍのビーズ状物と、パンシル２質量部と柑橘系香料
３．０質量部とを小麦ファイバー４．７質量部に含浸さ
せて細粒化したもの、カーボンブラック０．３質量部及
びパラフィンロウ４０．０質量部の混練物からなる平均
粒径３ｍｍのビーズ状物とを互いに同質量で通気性布袋
に入れた試験品を用意し、実施例１と同様にして試験し
たところ、実施例１と同様の評価結果を得た。Example 12 Beads having an average particle size of 3 mm, comprising a mixture of 2.5 parts by mass of 2-methyl-3-chlorophenol and 47.5 parts by mass of paraffin wax, 2 parts by mass of pansil, and a citrus 3.0 parts by mass of a fragrance and 4.7 parts by mass of wheat fiber are impregnated and refined, and a kneaded product of 0.3 parts by mass of carbon black and 40.0 parts by mass of paraffin wax having an average particle size of 3 mm. A test article in which the beaded material and the same weight were put in a breathable cloth bag was prepared and tested in the same manner as in Example 1. As a result, the same evaluation results as in Example 1 were obtained.
【００２３】[0023]
【発明の効果】本発明の消臭剤は、悪臭発生源となる細
菌、カビ等の微生物の繁殖を格別の装備を要さず簡単に
抑制し、悪臭の発生を長期間防止し、しかも安全である
という顕著な効果を奏する。したがって、本発明の消臭
剤は、室内、中でも密閉空間容積の小さい乗用車等の自
動車の車室、特にエアーコンディショナーを備えた車室
内用として有効である。EFFECT OF THE INVENTION The deodorant of the present invention can easily suppress the growth of microorganisms such as bacteria and molds which are a source of offensive odor without requiring special equipment, prevent the generation of offensive odor for a long time, and be safe. Has a remarkable effect. Therefore, the deodorant of the present invention is effective for use indoors, especially for the interior of automobiles such as passenger cars having a small enclosed space volume, particularly for interiors equipped with an air conditioner.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） Ａ６１Ｌ 9/01 Ａ６１Ｌ 9/01 Ｒ 9/04 9/04 9/16 9/16 Ｄ Ｆターム(参考） 4C080 AA04 AA05 BB02 CC01 HH05 JJ03 KK02 LL03 MM01 MM02 MM04 MM05 MM06 MM12 MM18 MM31 NN01 NN04 NN22 QQ03──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl.7 Identification symbol FI theme coat ゛ (reference) A61L 9/01 A61L 9/01 R 9/04 9/04 9/16 9/16 DF term (reference) 4C080 AA04 AA05 BB02 CC01 HH05 JJ03 KK02 LL03 MM01 MM02 MM04 MM05 MM06 MM12 MM18 MM31 NN01 NN04 NN22 QQ03
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001066948AJP5155504B2 (en) | 2001-03-09 | 2001-03-09 | Deferred deodorant |
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001066948AJP5155504B2 (en) | 2001-03-09 | 2001-03-09 | Deferred deodorant |
| Publication Number | Publication Date |
|---|---|
| JP2002263178Atrue JP2002263178A (en) | 2002-09-17 |
| JP5155504B2 JP5155504B2 (en) | 2013-03-06 |
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001066948AExpired - Fee RelatedJP5155504B2 (en) | 2001-03-09 | 2001-03-09 | Deferred deodorant |
| Country | Link |
|---|---|
| JP (1) | JP5155504B2 (en) |
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003045449A1 (en)* | 2001-11-26 | 2003-06-05 | Yugen Kaisha Okada Giken | Deodorant and cosmetic shampoo preparation containing the same |
| JP2008029781A (en)* | 2006-07-28 | 2008-02-14 | Ishihara Chem Co Ltd | Antibacterial deodorant and antibacterial deodorant method using the same |
| WO2010073747A1 (en)* | 2008-12-25 | 2010-07-01 | 石原薬品株式会社 | Deodorizing material with sustained vaporization properties for use in automobiles |
| WO2018213975A1 (en)* | 2017-05-22 | 2018-11-29 | 南通启吾农产品有限公司 | Storeroom deodorant |
| JP2021010706A (en)* | 2019-07-08 | 2021-02-04 | 株式会社プラネット | Simple multifunctional deodorant |
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| JPS6395058A (en)* | 1986-10-09 | 1988-04-26 | ダイセル化学工業株式会社 | Deodorant composition |
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| JPH04132556A (en)* | 1990-09-25 | 1992-05-06 | Taiyo Chem Kk | Deodorant bag |
| JPH04354533A (en)* | 1991-05-30 | 1992-12-08 | Meiji Seika Kaisha Ltd | Deodorant porous granular material |
| JPH05279202A (en)* | 1992-04-02 | 1993-10-26 | Sumitomo Chem Co Ltd | Drug sustained-release resin composition |
| JPH1099175A (en)* | 1996-10-02 | 1998-04-21 | Hitachi Chem Co Ltd | Bedding with deodorizing function |
| JP2000319104A (en)* | 1999-05-11 | 2000-11-21 | Kyoto Karitasu:Kk | Slow release complex and its secondary product |
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003045449A1 (en)* | 2001-11-26 | 2003-06-05 | Yugen Kaisha Okada Giken | Deodorant and cosmetic shampoo preparation containing the same |
| JP2008029781A (en)* | 2006-07-28 | 2008-02-14 | Ishihara Chem Co Ltd | Antibacterial deodorant and antibacterial deodorant method using the same |
| WO2010073747A1 (en)* | 2008-12-25 | 2010-07-01 | 石原薬品株式会社 | Deodorizing material with sustained vaporization properties for use in automobiles |
| JP2010148736A (en)* | 2008-12-25 | 2010-07-08 | Ishihara Chem Co Ltd | Volatilization durability deodorizing material for automobile |
| WO2018213975A1 (en)* | 2017-05-22 | 2018-11-29 | 南通启吾农产品有限公司 | Storeroom deodorant |
| JP2021010706A (en)* | 2019-07-08 | 2021-02-04 | 株式会社プラネット | Simple multifunctional deodorant |
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| JP5155504B2 (en) | 2013-03-06 |
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