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GB597144A - Improvements in or relating to synthetic resinous adhesive compositions - Google Patents

Improvements in or relating to synthetic resinous adhesive compositions

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Publication number
GB597144A
GB597144AGB24103/45AGB2410345AGB597144AGB 597144 AGB597144 AGB 597144AGB 24103/45 AGB24103/45 AGB 24103/45AGB 2410345 AGB2410345 AGB 2410345AGB 597144 AGB597144 AGB 597144A
Authority
GB
United Kingdom
Prior art keywords
per cent
resorcinol
formaldehyde
catalyst
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB24103/45A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WESTINGHOUSE ELECTRIC INT CO
Original Assignee
WESTINGHOUSE ELECTRIC INT CO
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WESTINGHOUSE ELECTRIC INT COfiledCriticalWESTINGHOUSE ELECTRIC INT CO
Publication of GB597144ApublicationCriticalpatent/GB597144A/en
Expiredlegal-statusCriticalCurrent

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Abstract

A resinous binder for bonding wood, laminated plastics and metal plates, comprises from 10 to 100 parts by weight of a soluble partial reaction product of 1 mol. of a polyhydroxybenzene having at least two hydroxyl groups in the 1-, 3-, 5-positions and from 1 to 1.17 mols. of formaldehyde in the form of a solid polymer, combined with 100 parts by weight of a vinyl thermoplastic resin. The partial reaction product is prepared by refluxing the polyhydroxybenzene and solid polymer of formaldehyde in substantially anhydrous methanol or ethanol in the presence of a catalyst in an amount of less than 1 per cent of the weight of the polyhydroxybenzene, the catalyst being neutralized after the reaction. The vinyl resin may be vinyl acetate, vinyl acetate-butyrate, polyvinyl alcohols, particularly those produced from a vinyl ester hydrolysed less than 50 per cent, polyvinyl formal, polyvinyl acetal, polyvinyl butyral and simple substituted vinyls such as acrylates, methyl- and propyl-methacrylates. Suitable polyhydroxybenzenes are resorcinol and phloroglucinol, 1,3-polyhydroxybenzenes with one methyl, ethyl or other group attached to the benzene ring. The catalyst may be a mineral acid, a strongly acid-reacting salt, such as ferric chloride or a basic substance. In the preparation of the phenol-formaldehyde resin, resorcinol, paraformaldehyde, anhydrous methyl or ethyl alcohol and hydrochloric acid are heated at about the reflux temperature of the alcohol until a clear viscous resin results, when the viscosity is adjusted by the addition of alcohol and the acid catalyst neutralized with alkali. In the examples: (1) a resorcinol resin solution in methanol having a 60 per cent solids content was mixed with polyvinylacetate of medium molecular weight dissolved in acetone; (2) a similar resin solution was combined with a high molecular weight polyvinyl acetate in acetone, in (3) low molecular weight polyvinyl acetate dissolved in benzene/ethanol solution was mixed with a 60 per cent solid content resorcinol formaldehyde resin in ethanol. Up to 10 per cent of a basic hardening catalyst such as ammonium hydroxide, ethylene diamine and hexamethylenetetramine can be added to the above compositions. In example (4) 15 per cent hydrolysed polyvinylacetate of medium molecular weight dissolved in a mixture of equal parts of acetone and ethyl acetate to yield a 20 per cent solution was combined with a 50 per cent resorcinol-formaldehyde resin solution in ethanol. In the Specification as open to inspection under Sect. 91, acetaldehyde or butyraldehyde may be used in the condensation in place of formaldehyde. This subject-matter does not appear in the Specification as accepted.
GB24103/45A1944-09-291945-09-18Improvements in or relating to synthetic resinous adhesive compositionsExpiredGB597144A (en)

Applications Claiming Priority (1)

Application NumberPriority DateFiling DateTitle
US255973XA1944-09-291944-09-29

Publications (1)

Publication NumberPublication Date
GB597144Atrue GB597144A (en)1948-01-19

Family

ID=21826977

Family Applications (1)

Application NumberTitlePriority DateFiling Date
GB24103/45AExpiredGB597144A (en)1944-09-291945-09-18Improvements in or relating to synthetic resinous adhesive compositions

Country Status (6)

CountryLink
BE (1)BE474432A (en)
CH (1)CH255973A (en)
DE (1)DE805721C (en)
FR (1)FR916537A (en)
GB (1)GB597144A (en)
NL (1)NL61397C (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
US2602785A (en)*1950-09-301952-07-08Shell DevCompositions containing glycidyl polyethers of dihydric phenols and polyvinyl acetate
US2713567A (en)*1952-04-141955-07-19Shell DevComposition containing glycidyl polyether and a polyvinyl acetal resin
EP1559732A4 (en)*2002-10-042007-04-18E Tec Co Ltd AMBIENT TEMPERATURE HARDENING BINDER AND PROCESS FOR PRODUCING MOLDING WITH THIS BINDER

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
US6008287A (en)*1996-11-261999-12-28Sumitomo Chemical Co., Ltd.Adhesive composition

Cited By (3)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
US2602785A (en)*1950-09-301952-07-08Shell DevCompositions containing glycidyl polyethers of dihydric phenols and polyvinyl acetate
US2713567A (en)*1952-04-141955-07-19Shell DevComposition containing glycidyl polyether and a polyvinyl acetal resin
EP1559732A4 (en)*2002-10-042007-04-18E Tec Co Ltd AMBIENT TEMPERATURE HARDENING BINDER AND PROCESS FOR PRODUCING MOLDING WITH THIS BINDER

Also Published As

Publication numberPublication date
FR916537A (en)1946-12-09
DE805721C (en)1951-05-28
CH255973A (en)1948-07-31
NL61397C (en)1900-01-01
BE474432A (en)1900-01-01

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