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GB1069168A - Composite coated aluminium articles - Google Patents

Composite coated aluminium articles

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Publication number
GB1069168A
GB1069168AGB4446764AGB4446764AGB1069168AGB 1069168 AGB1069168 AGB 1069168AGB 4446764 AGB4446764 AGB 4446764AGB 4446764 AGB4446764 AGB 4446764AGB 1069168 AGB1069168 AGB 1069168A
Authority
GB
United Kingdom
Prior art keywords
aluminium
acid
fluorinated hydrocarbon
polymer
electrolyte
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4446764A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Magnaplate Corp
Original Assignee
General Magnaplate Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Magnaplate CorpfiledCriticalGeneral Magnaplate Corp
Publication of GB1069168ApublicationCriticalpatent/GB1069168A/en
Expiredlegal-statusCriticalCurrent

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Abstract

A process for producing a composite coated aluminium article having an aluminium base, an intermediate layer of aluminium oxide and an outer layer of a fluorinated hydrocarbon polymer comprises (1) cleaning the surface of an aluminium substrate, (2) anodically oxidizing the cleaned substrate in an aqueous electrolyte containing from 15 to 18 ounces per gallon of sulphuric acid at a temperature from 25 DEG to 40 DEG F., at least 1 cubic foot of air per gallon of electrolyte per minute being passed through the electrolyte, the impressed voltage between the cathode and the aluminium anode being from 24 to 90 volts and the anode current density from 25 to 60 amps per square foot, the oxidation being continued until the oxide layer is at least 0.0005 ins. thick, (3) immersing the oxidized aluminium in an aqueous suspension of a fluorinated hydrocarbon polymer, the particles of said polymer being up to 2 microns in diameter, the suspension being at a temperature of at least 140 DEG F., until the polymer fills the interstices of the oxide layer and forms an outer coating at least 0.0001 in. thick. The cleaning step may comprise immersion in a hot sodium hydroxide solution followed by immersion in a chromic acid-nitric acid aqueous solution followed by rinsing. The anodizing bath may also contain a carboxylic acid, such as oxalic acid, malonic acid or succinic acid. A sugar, for example, sucrose, may also be added. The fluorinated hydrocarbon polymer may be polytetrafluoroethylene or tetrafluoropolyethylenehexafluoropolypropylene copolymer. The coated article is air dried and may subsequently be baked. Additional thicknesses of the fluorinated hydrocarbon may then be applied by spraying. Examples are given of coating an aluminium plate and an aluminium frying pan.ALSO:A process for producing a composite coated aluminium article having an aluminium base, an intermediate layer of aluminium oxide and an outer layer of a fluorinated hydrocarbon polymer comprises (1) cleaning the surface of an aluminium substrate, (2) anodically oxidising the cleaned substrate in an aqueous electrolyte containing from 15 to 18 ounces per gallon of sulphuric acid at a temperature from 25 DEG to 70 DEG F., at least 1 cubic foot of air per gallon of electrolyte per minute being passed through the electrolyte, the impressed voltage between the cathode and the aluminium anode being from 24 to 90 volts and the anode current density from 25 to 60 amps perr square foot, the oxidation being continued until the oxide layer is at least 0.0005 ins. thick, (3) immersing the oxidised aluminium in an aqueous suspension of a fluorinated hydrocarbon polymer, the particles of said polymer being up to 2 microns in diameter, the suspension being at a temperature of at least 140 DEG F., until the polymer fills the interstices of the oxide layer and forms an outer coating at least 0.0001 in. thick. the cleaning step may comprise immersion in a hot sodium hydroxide solution followed by immersion in a chromic acid-nitric acid aqueous solution followed by rinsing. The anodising bath may also contain a carboxylic acid, such as oxalic acid, malonic acid or succinic acid. A sugar, for example, sucrose, may also be added. The fluorinated hydrocarbon polymer may be polytetrafluoroethylene or tetrafluoropolyethylenehexafluoropolypropylene copolymer. The caoted article is air dried and may subsequently be baked. Additional thicknesses of the fluorinated hydrocarbon may then be applied by spraying. Examples are given of coating an aluminium plate and an aluminium frying pan.
GB4446764A1964-07-231964-10-30Composite coated aluminium articlesExpiredGB1069168A (en)

Applications Claiming Priority (1)

Application NumberPriority DateFiling DateTitle
US38461564A1964-07-231964-07-23

Publications (1)

Publication NumberPublication Date
GB1069168Atrue GB1069168A (en)1967-05-17

Family

ID=23518031

Family Applications (1)

Application NumberTitlePriority DateFiling Date
GB4446764AExpiredGB1069168A (en)1964-07-231964-10-30Composite coated aluminium articles

Country Status (3)

CountryLink
JP (1)JPS5239059B1 (en)
DE (1)DE1546966A1 (en)
GB (1)GB1069168A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
JPS5049567U (en)*1973-09-031975-05-15
JPS5162598U (en)*1974-11-111976-05-17
GB2140277A (en)*1983-05-261984-11-28Meyer Manuf Co LtdCooking vessel
WO1996018333A1 (en)*1994-12-161996-06-20Fissler GmbhMethod of producing a kitchen utensil provided with a nonstick coating
RU2122605C1 (en)*1996-06-041998-11-27Самарский государственный аэрокосмический университет им.С.П.КоролеваMethod of filling anode oxide coatings based on aluminum alloys
GB2328447A (en)*1997-08-161999-02-24British AerospaceA desmutting solution for use prior to anodising
WO1999032234A1 (en)*1997-12-221999-07-01E.I. Du Pont De Nemours And CompanyProcess for sealing coatings
FR2789334A1 (en)*1999-02-102000-08-11JfceSurface treatment of anodized aluminum and anodized aluminum alloy items to prevent graffiti adhesion, comprises mechanically compressing silicone oil coating against surface during application
CN103417126A (en)*2013-08-192013-12-04徐红春Metal base non-sticking cooker and production method
EP2677068A4 (en)*2011-02-182016-10-05Aisin Keikinzoku Co LtdSurface treatment method for metal member and metal member obtained by same

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
DE10335668A1 (en)*2003-08-042005-03-03Webasto Ag Guide arrangement for adjustable parts of vehicle roofs and production method thereof
JP2012182137A (en)*2012-04-092012-09-20Central Research Institute Of Electric Power IndustryGas insulated switchgear

Cited By (11)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
JPS5049567U (en)*1973-09-031975-05-15
JPS5162598U (en)*1974-11-111976-05-17
GB2140277A (en)*1983-05-261984-11-28Meyer Manuf Co LtdCooking vessel
WO1996018333A1 (en)*1994-12-161996-06-20Fissler GmbhMethod of producing a kitchen utensil provided with a nonstick coating
US5989631A (en)*1994-12-161999-11-23Fissler GmbhProcess for equipping a kitchenware object with an anti-adhesion coating
RU2122605C1 (en)*1996-06-041998-11-27Самарский государственный аэрокосмический университет им.С.П.КоролеваMethod of filling anode oxide coatings based on aluminum alloys
GB2328447A (en)*1997-08-161999-02-24British AerospaceA desmutting solution for use prior to anodising
WO1999032234A1 (en)*1997-12-221999-07-01E.I. Du Pont De Nemours And CompanyProcess for sealing coatings
FR2789334A1 (en)*1999-02-102000-08-11JfceSurface treatment of anodized aluminum and anodized aluminum alloy items to prevent graffiti adhesion, comprises mechanically compressing silicone oil coating against surface during application
EP2677068A4 (en)*2011-02-182016-10-05Aisin Keikinzoku Co LtdSurface treatment method for metal member and metal member obtained by same
CN103417126A (en)*2013-08-192013-12-04徐红春Metal base non-sticking cooker and production method

Also Published As

Publication numberPublication date
JPS5239059B1 (en)1977-10-03
DE1546966A1 (en)1970-10-22

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