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CN1687203A - Vegetable capsule of starch composition and preparation method - Google Patents

Vegetable capsule of starch composition and preparation method
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CN1687203A
CN1687203ACNA2005100132853ACN200510013285ACN1687203ACN 1687203 ACN1687203 ACN 1687203ACN A2005100132853 ACNA2005100132853 ACN A2005100132853ACN 200510013285 ACN200510013285 ACN 200510013285ACN 1687203 ACN1687203 ACN 1687203A
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starch
parts
gum
sodium
starch composition
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CN1333006C (en
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高建平
陈静远
虎桂芳
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Tianjin University
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Tianjin University
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本发明涉及一种淀粉组合物植物胶囊及制备方法。将淀粉或淀粉组合物混合均匀,分散在10-200份的蒸馏水中,在60-95℃下加热15-60分钟,使淀粉充分湖化,然后按配比加入增塑剂、凝胶、表面活性剂、遮光剂、食用色素、防腐剂、抗氧剂和增强剂,充分混合均匀后减压消泡,得到的胶液可用常规旋转冲模成囊法或滴液成囊法制得淀粉组合物植物软胶囊;或用蘸模法制得淀粉组合物植物空心硬胶囊,成囊温度在40-95℃。本发明的优点在于:以淀粉组合物为主要原料,系纯天然无污染,而且原料来源广泛,生产成本低。The invention relates to a starch composition vegetable capsule and a preparation method thereof. Mix the starch or starch composition evenly, disperse in 10-200 parts of distilled water, heat at 60-95°C for 15-60 minutes to make the starch fully lake, and then add plasticizer, gel and surfactant according to the proportion agent, opacifying agent, food coloring, preservative, antioxidant and enhancer, mixed well and then defoaming under reduced pressure, the obtained glue can be made into starch composition plant soft Capsules; or the starch composition plant hollow hard capsules are prepared by dipping mold method, and the capsule forming temperature is 40-95°C. The invention has the advantages that: the starch composition is used as the main raw material, which is pure natural and pollution-free, has wide sources of raw materials and low production cost.

Description

Vegetable capsule of starch composition and preparation method
Technical field
The invention belongs to medical and health, healthcare products, makeup and functional food field, particularly a kind of vegetable capsule of starch composition and preparation method.
Background technology
Capsule has very in medicine, healthcare products and functional food industry to be used widely.Conventional capsules to be utilized by the skin of animal, gelatin that the bone hydrolysis makes as capsule casing material.Yet, along with spreading of European mad cow disease and foot and mouth disease, and the transformation of consumption idea, people begin to query the security of animals products.Therefore, plant capsule is gone with the tide of historical development becomes the market of medicine, healthcare products, makeup and functional food new lover.At present the plant capsule demand of world market and is the trend that grows steadily at 15,000,000,000 according to estimates.The cellulose capsule Vcaps of U.S. exploitation has been used for the packing of some drugs, healthcare products, makeup, has just used the Vcaps plant capsule as the product of Sunrider (Sunrider) company.Domestic Harbin Hong Tai company utilizes the carrageenin that extract from marine alga to develop plant capsule for main raw material.But the said products still can not contend with traditional gelatine capsule on production cost or price.
Summary of the invention
In order to solve deficiency of the prior art, the invention provides a kind of vegetable capsule of starch composition prescription and preparation method.
The vegetable capsule of starch composition prescription is as follows:
A kind of vegetable capsule of starch composition prescription, component and content are as follows:
10 parts of starch,
1 ~ 6 part in polyalcohols, polyose or long-chain fat acids softening agent,
0.15 ~ 2 part of vegetable jelly and inorganic salts gel,
0 ~ 0.3 part of the esters surface active agent of negatively charged ion or non-ionic type,
0 ~ 2 part of natural or synthetic oxide compound or calcium salt opalizer,
0 ~ 0.3 part of food dye,
0 ~ 0.3 part in oxidation inhibitor of edible natural,
0 ~ 0.2 part of sanitas of food,
0 ~ 0.2 part of derivatived cellulose and water-soluble polymers toughener.
Described starch is common starch or modified starch: starch comprises wheat starch, W-Gum, arrowroot starch, Starch rice, yam starch and tapioca (flour); Modified starch mainly comprises starch acetate, starch-phosphate, Sumstar 190, pregelatinized Starch, hydroxypropylated starch, carboxymethyl starch, hydroxyethylamyle, hydrolyzed starch or dextrin; Above-mentioned starch is to select for use one or more to mix to use.
Described polyalcohols, polyose or long-chain fat acids softening agent are that one or more mixing of glycerine, polyoxyethylene glycol, sorbyl alcohol, N.F,USP MANNITOL, Xylitol, stearic acid, Palmiticacid, fructose, sucrose, maltose, Oligomeric maltose or triethyl citrate are used; For the hard film preparation, plasticizer dosage is 1 ~ 3 part; For the flexible film preparation, plasticizer dosage is 2 ~ 6 parts.
Described vegetable jelly and inorganic salts gel are Viscogum BE, and one or more of carrageenin, sodium alginate, carrageenin, tara gum, xanthan gum, ghatti gum, tragacanth gum, konjak mannan, gum gellan, araban, pectin, kuteera gum, Sudan Gum-arabic, salt of wormwood, yellow soda ash, Repone K, sodium bicarbonate, sodium-acetate or Potassium ethanoate mix use.
The esters surface active agent of described negatively charged ion or non-ionic type is sodium lauryl sulphate, dimethyl polysiloxane, Sodium dodecylbenzene sulfonate, glyceryl monooleate, sorbitan ester class, Yelkin TTS, Vinlub, dioctyl alkyl succinic acid sodium or sucrose fatty acid ester.
Described natural or synthetic oxide compound or calcium salt opalizer are that titanium dioxide, silicon-dioxide, ferric oxide, lime carbonate, natural algae soil are as diatomite or potter's clay.
Described food dye is that riboflavin, anthocyanidin, carotene, turmeric, cochineal extract, ponceau 4R, acid bright green BS, patent blue V, red iron oxide, iron oxide yellow, iron oxide black, carbon black, D+C are red 33, D+C is red 22, D+C is red 26, D+C is red 28, D+C Huang 10, yellow 2G, red 2G, FD+C are green 3, FD+C blue 1 or FD+C indigo plant 2.
Described edible natural oxidation inhibitor be gallic acid ester, Rosmarinus officinalis, carotene, phytic acid, xitix, tea-polyphenol, monascorubin, cacao color or phosphatide.
Described food sanitas is Sodium Benzoate, P-hydroxybenzoic acid sodium, potassium sorbate or propylparaben.
Described derivatived cellulose and water-soluble polymers toughener are polyvinyl alcohol, hydroxypropylcellulose, Walocel MT 20.000PV or Polyvinylpyrolidone (PVP).
The preparation method of vegetable capsule of starch composition prescription of the present invention, starch or starch composites are mixed, be dispersed in the distilled water of 10-200 part, heated 15-60 minute down at 60-95 ℃, make the abundant lakeization of starch, add softening agent, gel, tensio-active agent, opalizer, food dye, sanitas, oxidation inhibitor and toughener by proportioning then, thorough mixing is the back vacuum defoaming evenly, and the glue that obtains can rotate punch die encystation method or dropping method makes starch composites plant soft capsule with routine; Or making the starch composites plant hollow hard capsule with mode dunking method, the encystation temperature is at 40-95 ℃, preferred 50-85 ℃.
The invention has the advantages that: with the starch composites is main raw material, be that pure natural is pollution-free, and raw material sources is extensive, and production cost is low.
Embodiment
Example 1:
Get 10 parts of starch, wherein tapioca (flour) and pregelatinized Starch are each 5 parts, add in 140 parts the deionized water, stir 4min, 85 ℃ of following gelatinizations, treat that gelatinization adds 2 parts of glycerine, 0.3 part polyvinyl alcohol, 0.2 part sodium alginate in the back fully, stir and make its thorough mixing, utilize conventional capsular production unit and production technique to produce starch plant soft capsule and empty hard capsule after mixing.
Softening agent glycerine can change sorbyl alcohol, Xylitol, polyoxyethylene glycol, stearic acid, Palmiticacid, sucrose, triethyl citrate etc. in the body series.
The gel sodium alginate can change carrageenin, tara gum, xanthan gum, ghatti gum, tragacanth gum, konjak mannan, gum gellan, araban, pectin, kuteera gum, Sudan Gum-arabic etc. into.
Example 2:
Get 10 parts starch, wherein yam starch is 3 parts, 2 parts of 5 parts of tapioca (flour)s and hydrolyzed starches, the deionized water that adds 190 parts, stir 4min, 75 ℃ of following gelatinizations, treat that the complete back of gelatinization adds 3 parts softening agent, wherein glycerine is 2 parts, 1 part of polyoxyethylene glycol, 0.3 the sodium lauryl sulphate of part, 0.4 the gel of part, wherein carrageenin is 0.2 part, 0.1 part of xanthan gum, 0.1 part in salt of wormwood, 0.1 the titanium dioxide of part, 0.1 the acid bright green BS of part stirs and makes its thorough mixing, utilizes conventional capsular production unit and production technique to produce starch plant soft capsule and empty hard capsule after mixing.
In the body series gelling system salt of wormwood can yellow soda ash, Repone K, sodium bicarbonate, sodium-acetate, Potassium ethanoate etc.
Tensio-active agent sodium lauryl sulphate (SLS) can change dimethyl polysiloxane, Sodium dodecylbenzene sulfonate, glyceryl monooleate, sorbitan ester class, Yelkin TTS, dioctyl alkyl succinic acid sodium, sucrose fatty acid ester, Vinlub into.Opalizer titanium dioxide can change silicon-dioxide, ferric oxide, lime carbonate, natural algae soil into as diatomite, potter's clay etc.
The acid bright green BS of food dye can change riboflavin, anthocyanidin, carotene, turmeric, cochineal extract, ponceau 4R, patent blue V, red iron oxide, iron oxide yellow, iron oxide black etc. into.
Example 3:
Get 10 parts starch, wherein 3 parts of Sumstar 190s, 3 parts of hydroxypropylated starchs and konjak starch are 4 parts, add 150 parts deionized water, stir 5min, 90 ℃ of gelatinizations, after treating gelatinization fully, add 2 parts softening agent, wherein the hydroxypropylcellulose of 1.5 parts of glycerine, 0.5 part, 0.5 part of stearic acid, 0.4 the gelling system of part, wherein 0.2 part of carrageenin, 0.1 part of tragacanth gum, 0.1 part of Potassium ethanoate, 0.1 part titanium dioxide, 0.1 part acid bright green BS stir and make its thorough mixing.Like this starch solution homogeneous 4min under high-speed stirring of preparation, carry out the vacuum froth breaking again after, can utilize conventional capsular production unit and production technique to produce starch plant soft capsule and empty hard capsule then.
Opalizer titanium dioxide can change silicon-dioxide, ferric oxide, lime carbonate, natural algae soil into as diatomite, potter's clay etc. in the body series.
The toughener hydroxypropylcellulose can change polyvinyl alcohol, Walocel MT 20.000PV, Polyvinylpyrolidone (PVP) into.
Example 4:
Get 10 parts starch, wherein 6 parts of Sumstar 190s, 2 parts of W-Gums and wheat starch are 2 parts, the distilled water that adds 120 parts stirs 5min, at 90 ℃ of gelatinization 45min, treat that gelatinization fully adds 3 parts glycerine and 1 portion of maltose, 1 part sodium alginate, 0.1 part polyvinyl alcohol, 0.2 part dioctyl sodium sulphosuccinate, 0.1 part tea-polyphenol, 0.2 part acid bright green BS in the back, stirring mixes it.Like this preparation starch mixture solution homogeneous 4min under high-speed stirring, carry out the vacuum froth breaking again after, can utilize conventional capsular production unit and production technique to produce starch plant soft capsule and empty hard capsule then.
Example 5:
Get 10 parts starch, wherein 5 parts of yam starchs, 3 parts of starch acetates and 2 parts in dextrin,, the distilled water that adds 90 parts stirs 4min, at 95 ℃ of gelatinization 40min, treat that the complete back of gelatinization adds 3 parts softening agent, wherein 1.5 parts of stearic acid, 1.5 parts of Palmiticacid, 1 part gelling system, wherein 0.5 part of carrageenin, 0.2 part of sodium bicarbonate and konjak mannan are 0.3 part, and 0.1 part potassium sorbate, 0.3 part acid bright green BS fully stir it is mixed.So preparation starch mixture solution homogeneous 4min under high-speed stirring after carrying out the vacuum froth breaking, can utilize conventional capsular production unit and production technique to produce starch plant soft capsule and empty hard capsule then.
Example 6:
Get 10 parts starch, wherein 4 parts of arrowroot starchs, 4 parts of hydrolyzed starches and carboxymethyl starch are 2 parts, the distilled water that adds 140 parts stirs 4min, at 90 ℃ of gelatinization 45min, treat that the complete back of gelatinization adds 2 parts softening agent, wherein 1.5 parts of glycerine and polyoxyethylene glycol are 0.5 part, 1 part gelling system, wherein 0.7 part of carrageenin and Repone K are 0.3 part, 1 part diatomite, 0.3 part acid bright green BS, 0.1 part tea-polyphenol, and fully stirring mixes it.So preparation starch mixture solution homogeneous 4min under high-speed stirring after carrying out the vacuum froth breaking, can utilize conventional capsular production unit and production technique to produce starch plant soft capsule and empty hard capsule then.
The present invention is not limited to the technology described in the embodiment; its description is illustrative; and it is nonrestrictive; authority of the present invention is limited by claim; based on present technique field personnel according to the present invention can change, technology related to the present invention that method such as reorganization obtains, all within protection scope of the present invention.

Claims (7)

Translated fromChinese
1.一种淀粉组合物植物胶囊配方,组分和含量如下:1. A starch composition vegetable capsule formula, the components and content are as follows:淀粉                                        10份,Starch 10 parts,多元醇类、多糖类或长链脂肪酸类增塑剂        1~6份,1~6 parts of polyalcohols, polysaccharides or long-chain fatty acid plasticizers,植物胶和无机盐类凝胶                        0.15~2份,Vegetable gum and inorganic salt gel 0.15~2 parts,阴离子或非离子型的酯类表面活性剂            0~0.3份,Anionic or nonionic ester surfactants 0~0.3 parts,天然的或合成的氧化物或钙盐遮光剂            0~2份,Natural or synthetic oxide or calcium salt sunscreens 0~2 parts,食用色素                                    0~0.3份,Food coloring 0~0.3 parts,天然可食用抗氧剂                            0~0.3份,Natural edible antioxidant 0~0.3 parts,食品用防腐剂                                0~0.2份,Food preservatives 0~0.2 parts,纤维素衍生物及水溶性聚合物增强剂            0~0.2份。Cellulose derivatives and water-soluble polymer reinforcements 0~0.2 parts.2.如权利要求1所述的一种淀粉组合物植物胶囊配方,其特征是所述的淀粉为普通淀粉或变性淀粉:淀粉包括小麦淀粉、玉米淀粉、竹芋淀粉、大米淀粉、马铃薯淀粉及木薯淀粉;变性淀粉主要包括淀粉醋酸酯、淀粉磷酸酯、氧化淀粉、预胶化淀粉、羟丙基淀粉、羧甲基淀粉、羟乙基淀粉、水解淀粉或糊精;上述淀粉是选用一种或两种以上混合使用。2. a kind of starch composition vegetable capsule formula as claimed in claim 1 is characterized in that described starch is common starch or modified starch: starch comprises wheat starch, corn starch, arrowroot starch, rice starch, potato starch and Tapioca starch; modified starch mainly includes starch acetate, starch phosphate, oxidized starch, pregelatinized starch, hydroxypropyl starch, carboxymethyl starch, hydroxyethyl starch, hydrolyzed starch or dextrin; the above starch is selected Or a mixture of two or more.3.如权利要求1所述的一种淀粉组合物植物胶囊配方,其特征是所述的多元醇类、多糖类或长链脂肪酸类增塑剂为甘油、聚乙二醇、山梨醇、甘露醇、木糖醇、硬脂酸、软脂酸、果糖、蔗糖、麦芽糖、低聚麦芽糖或柠檬酸三乙酯的一种或两种以上混合使用;对于硬薄膜制剂,增塑剂的用量为1~3份;对于软薄膜制剂,增塑剂的用量为2~6份。3. a kind of starch composition vegetable capsule formula as claimed in claim 1 is characterized in that described polyhydric alcohols, polysaccharides or long-chain fatty acid plasticizer are glycerol, polyethylene glycol, sorbitol, One or more of mannitol, xylitol, stearic acid, palmitic acid, fructose, sucrose, maltose, maltose oligosaccharide or triethyl citrate are used in combination; for hard film preparations, the amount of plasticizer 1 to 3 parts; for soft film preparations, the amount of plasticizer is 2 to 6 parts.4.如权利要求1所述的一种淀粉组合物植物胶囊配方,其特征是所述的植物胶和无机盐类凝胶为刺槐豆胶,角叉菜胶、海藻酸钠、卡拉胶、塔拉胶、黄原胶、茄替胶、龙须胶、魔芋甘露聚糖、洁冷胶、阿聚糖、果胶、刺梧桐树胶、阿拉伯树胶、碳酸钾、碳酸钠、氯化钾、碳酸氢钠、醋酸钠或醋酸钾的一种或两种以上混合使用。4. a kind of starch composition vegetable capsule formula as claimed in claim 1 is characterized in that described vegetable gum and inorganic salts gel are locust bean gum, carrageenan, sodium alginate, carrageenan, tower Latex gum, xanthan gum, ghatti gum, asparagus gum, konjac mannan, gellan gum, araban, pectin, karaya gum, gum arabic, potassium carbonate, sodium carbonate, potassium chloride, bicarbonate Sodium, sodium acetate or potassium acetate or a mixture of two or more.5.如权利要求1所述的一种淀粉组合物植物胶囊配方,其特征是;5. a kind of starch composition vegetable capsule formula as claimed in claim 1, is characterized in that;所述的阴离子或非离子型的酯类表面活性剂为十二烷基硫酸钠、二甲基聚硅氧烷、十二烷基苯磺酸钠、甘油单油酸酯、脱水山梨糖醇酯类、卵磷脂、甘油硬脂酸酯、二辛基烷基琥珀酸钠或脂肪酸糖酯;The anionic or nonionic ester surfactants are sodium lauryl sulfate, dimethylpolysiloxane, sodium dodecylbenzenesulfonate, glycerol monooleate, sorbitan ester lecithin, glyceryl stearate, sodium dioctylalkyl succinate or fatty acid sugar ester;所述的天然的或合成的氧化物或钙盐遮光剂为二氧化钛、二氧化硅、氧化铁、碳酸钙、天然藻土如硅藻土或陶土;The natural or synthetic oxide or calcium salt sunscreen agent is titanium dioxide, silicon dioxide, iron oxide, calcium carbonate, natural alginate such as diatomaceous earth or clay;所述的食用色素为核黄素、花青素、胡萝卜素、姜黄、胭脂虫提取物、丽春红4R、酸性亮绿BS、专利蓝V、氧化铁红、氧化铁黄、氧化铁黑、炭黑、D+C红33、D+C红22、D+C红26、D+C红28、D+C黄10、黄2G、红2G、FD+C绿3、FD+C蓝1或FD+C蓝2;The food coloring is riboflavin, anthocyanin, carotene, turmeric, cochineal extract, Ponceau 4R, acid bright green BS, patent blue V, iron oxide red, iron oxide yellow, iron oxide black, Carbon black, D+C red 33, D+C red 22, D+C red 26, D+C red 28, D+C yellow 10, yellow 2G, red 2G, FD+C green 3, FD+C blue 1 or FD+C blue 2;所述的天然可食用抗氧剂为没食子酸酯、迷迭香、胡萝卜素、植酸、抗坏血酸、茶多酚、红曲红色素、可可色素或磷脂;The natural edible antioxidant is gallate, rosemary, carotene, phytic acid, ascorbic acid, tea polyphenols, monascus red pigment, cocoa pigment or phospholipid;所述的食品用防腐剂为苯甲酸钠、对羟基苯甲酸钠、山梨酸钾或对羟基苯甲酸丙酯;所述的纤维素衍生物及水溶性聚合物增强剂为聚乙烯醇、羟丙基纤维素、羟甲基纤维素或聚乙烯基吡咯烷酮。The food preservative is sodium benzoate, sodium p-hydroxybenzoate, potassium sorbate or propyl p-hydroxybenzoate; the cellulose derivative and water-soluble polymer reinforcing agent are polyvinyl alcohol, hydroxypropyl fiber hydroxymethylcellulose or polyvinylpyrrolidone.6.如权利要求1所述的一种淀粉组合物植物胶囊配方的制备方法,将淀粉或淀粉组合物混合均匀,分散在10-200份的蒸馏水中,在60-95℃下加热15-60分钟,使淀粉充分湖化,然后按配比加入增塑剂、凝胶、表面活性剂、遮光剂、食用色素、防腐剂、抗氧剂和增强剂,充分混合均匀后减压消泡,得到的胶液可用常规旋转冲模成囊法或滴液成囊法制得淀粉组合物植物软胶囊;或用蘸模法制得淀粉组合物植物空心硬胶囊,成囊温度在40-95℃。6. The preparation method of a starch composition vegetable capsule formula as claimed in claim 1, the starch or the starch composition is mixed uniformly, dispersed in 10-200 parts of distilled water, heated at 60-95°C for 15-60 Minutes to make the starch fully lake, then add plasticizer, gel, surfactant, opacifier, food coloring, preservative, antioxidant and enhancer according to the proportion, mix well and then decompress and defoam, the obtained The glue can be made into starch composition plant soft capsules by conventional rotary die encapsulation method or drop liquid encapsulation method; or the starch composition plant hollow hard capsules can be obtained by dipping mold method, and the encapsulation temperature is 40-95°C.7.如权利要求6所述的一种淀粉组合物植物胶囊配方的制备方法,其特征是所述的成囊温度为50-85℃。7. The preparation method of a starch composition vegetable capsule formulation according to claim 6, characterized in that the temperature for forming a capsule is 50-85°C.
CNB2005100132853A2005-04-072005-04-07Vegetable capsule of starch composition and preparation methodExpired - Fee RelatedCN1333006C (en)

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CN104056274A (en)*2013-03-212014-09-24中国科学院化学研究所Reinforcing and toughening agent for preparing starch hard capsule and application thereof
CN104072811A (en)*2014-06-272014-10-01浙江神能光降解材料有限公司Method for preparing hard capsule shells from plant-derived modified starch
CN104127877A (en)*2014-07-292014-11-05浙江益立胶囊有限公司Plant hollow capsule
CN104147607A (en)*2013-05-132014-11-19吉林文辉胶囊有限公司Disintegrating auxiliary agent used for preparation of starch hard capsule and use thereof
CN104146984A (en)*2014-08-072014-11-19陕西科技大学Method for preparing hollow plant capsules from celery and starch
EP2865374A1 (en)*2013-10-262015-04-29Zhongshan Capsule Starch Material Technology Co., Ltd.Mixing and extruding method for preparing starch softgel capsules
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CN104667288A (en)*2015-02-052015-06-03湖南尔康制药股份有限公司Instant starch soft capsule
CN104688711A (en)*2015-03-092015-06-10湖南尔康制药股份有限公司Hollow plant capsule and preparation method thereof
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CN104940163A (en)*2015-06-242015-09-30陈威宇Capsule shell
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CN105533610A (en)*2015-12-182016-05-04湖南尔康制药股份有限公司Spice capsule
CN105558818A (en)*2015-12-182016-05-11湖南尔康制药股份有限公司Convenient instant staple food with various flavors
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CN105769811A (en)*2016-05-052016-07-20夏放军Empty starch capsule and preparation method thereof
CN105801922A (en)*2016-05-112016-07-27湖南尔康制药股份有限公司Starch empty capsule applicable to edible packaging field and preparation method of starch empty capsule
CN105853388A (en)*2016-04-252016-08-17夏放军Health care hollow capsule and preparation method thereof
CN105885109A (en)*2016-05-112016-08-24湖南尔康制药股份有限公司Starch-base film-forming composition capable of being applied to edible packaging field
CN105997928A (en)*2016-05-202016-10-12夏放军Sweet hollow capsule and preparation method thereof
CN106074436A (en)*2016-07-122016-11-09吉林农业大学A kind of method utilizing starch matrix to make heat molten type capsule material
CN106420657A (en)*2016-08-292017-02-22浙江大学Production method and product of rice starch hollow capsule
CN104666275B (en)*2015-03-092017-04-26湖南尔康制药股份有限公司Starch-based plant empty capsule
CN107184562A (en)*2017-05-102017-09-22中象新材料(大连)有限公司A kind of corn bran starch hollow capsule and preparation method thereof
CN107549859A (en)*2017-09-192018-01-09太仓市林港农场专业合作社A kind of immune soft capsule of galic essential oil compound enhancing and preparation method thereof
CN109364038A (en)*2018-09-212019-02-22浙江中同科技有限公司A kind of Starch composite adhesive capsule and preparation method thereof
CN109364039A (en)*2018-09-212019-02-22浙江中同科技有限公司A kind of starch hollow capsule and preparation method thereof
CN109562184A (en)*2016-07-062019-04-02快力胶囊股份有限公司 Hard capsule with improved hardness and method for producing the same
CN110063496A (en)*2019-05-272019-07-30西北农林科技大学A kind of peony petal capsule and preparation method thereof
CN110063480A (en)*2019-05-282019-07-30西北农林科技大学A kind of peony pollen capsule and preparation method thereof
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CN113181135A (en)*2021-05-132021-07-30青岛益青生物科技股份有限公司Gelatin hollow capsule with new formula and preparation method thereof
CN114617264A (en)*2020-12-142022-06-14深圳市前海小藻科技有限公司Plant capsule preparation with high content of EPA
CN114788820A (en)*2022-04-182022-07-26陕西省动物研究所Starch matrix empty capsule with biological auxiliary function pharmacological action
CN116218043A (en)*2023-03-202023-06-06中国农业大学Natural pigment edible starch film and preparation method thereof
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CN104056274B (en)*2013-03-212016-12-28中国科学院化学研究所For preparing activeness and quietness agent and the purposes of starch hard capsule
CN104056274A (en)*2013-03-212014-09-24中国科学院化学研究所Reinforcing and toughening agent for preparing starch hard capsule and application thereof
CN104147607A (en)*2013-05-132014-11-19吉林文辉胶囊有限公司Disintegrating auxiliary agent used for preparation of starch hard capsule and use thereof
CN104147607B (en)*2013-05-132018-05-15吉林文辉胶囊有限公司It is used to prepare the disintegration auxiliary agent and purposes of starch hard shell capsules
CN103550065A (en)*2013-10-262014-02-05中山市凯博思淀粉材料科技有限公司 A method for producing starch-based soft capsules by composite extrusion
EP2865373A1 (en)*2013-10-262015-04-29Zhongshan Capsule Starch Material Technology Co., Ltd.Compounding and extruding method for producing starch softgel capsules
EP2865375A1 (en)*2013-10-262015-04-29Zhongshan Capsule Starch Material Technology Co., Ltd.Coating and extruding method for producing starch softgel capsules
EP2865374A1 (en)*2013-10-262015-04-29Zhongshan Capsule Starch Material Technology Co., Ltd.Mixing and extruding method for preparing starch softgel capsules
CN103768608B (en)*2014-02-052016-12-14石狮市新明食品科技开发有限公司A kind of plant capsule compositions of Sargassum colloid
CN103768608A (en)*2014-02-052014-05-07许自霖Plant capsule composition of seaweed colloid and preparation method thereof
CN103834066A (en)*2014-03-052014-06-04中国科学院青岛生物能源与过程研究所Low-viscosity starch glue for preparing starch capsules as well as preparation method and application of low-viscosity starch glue
CN103830736A (en)*2014-03-052014-06-04中国科学院青岛生物能源与过程研究所Production method of starch empty capsule
EP2937082A1 (en)*2014-04-212015-10-28Hunan Er-Kang Pharmaceutical Co., Ltd.Film-forming composite used to make starch softgel capsules and the method to prepare it
CN103937037B (en)*2014-04-282016-09-21北京崇尚科技开发有限公司For preparing modified starch glue and the starch matrix Capsules thereof of Capsules
CN103937037A (en)*2014-04-282014-07-23中国科学院化学研究所Modified starch adhesive for preparing hollow capsule and starch-base hollow capsule thereof
CN103937038A (en)*2014-04-282014-07-23中国科学院化学研究所Composition for preparing hollow capsule and starch-base hollow capsule thereof
CN103937038B (en)*2014-04-282016-08-17中国科学院化学研究所For preparing composition and the starch matrix Capsules thereof of Capsules
CN104000798A (en)*2014-06-112014-08-27青岛双鲸药业有限公司Vegetative soft capsule
CN103976974A (en)*2014-06-112014-08-13青岛双鲸药业有限公司Preparation method of vegetative soft capsule
CN103976974B (en)*2014-06-112016-03-09青岛双鲸药业有限公司A kind of preparation method of autonomic soft capsules
CN104000798B (en)*2014-06-112016-02-03青岛双鲸药业有限公司A kind of autonomic soft capsules
CN104042589B (en)*2014-06-202016-04-06刘杰Capsule of a kind of animal protein-free and preparation method thereof
CN104042589A (en)*2014-06-202014-09-17刘杰Capsule without animal proteins and preparation method thereof
CN104072811A (en)*2014-06-272014-10-01浙江神能光降解材料有限公司Method for preparing hard capsule shells from plant-derived modified starch
CN104127877A (en)*2014-07-292014-11-05浙江益立胶囊有限公司Plant hollow capsule
CN104146984A (en)*2014-08-072014-11-19陕西科技大学Method for preparing hollow plant capsules from celery and starch
CN104667288A (en)*2015-02-052015-06-03湖南尔康制药股份有限公司Instant starch soft capsule
CN104688711B (en)*2015-03-092017-08-29湖南尔康制药股份有限公司A kind of phyteral Capsules and preparation method thereof
CN104688711A (en)*2015-03-092015-06-10湖南尔康制药股份有限公司Hollow plant capsule and preparation method thereof
CN104666275B (en)*2015-03-092017-04-26湖南尔康制药股份有限公司Starch-based plant empty capsule
CN104784148A (en)*2015-04-172015-07-22湖南尔康制药股份有限公司Film formation composition for preparing plant capsules and preparation method of film formation composition
CN104784148B (en)*2015-04-172017-12-22湖南尔康制药股份有限公司A kind of film-forming composition for preparing plant capsule and preparation method thereof
CN104800852B (en)*2015-05-042017-12-22湖南尔康制药股份有限公司A kind of sol gel process for being used to prepare starch hollow capsule
CN104800852A (en)*2015-05-042015-07-29湖南尔康制药股份有限公司Method for melting gelatin for preparing starch hollow capsule
CN104873977A (en)*2015-05-082015-09-02浙江万里学院Special glue for composite starch and preparation method of empty capsule of special glue
CN104873977B (en)*2015-05-082018-01-30浙江万里学院The preparation method of composite starch special glue and its Capsules
CN104940163A (en)*2015-06-242015-09-30陈威宇Capsule shell
CN105030723B (en)*2015-07-132017-12-26湖南尔康制药股份有限公司A kind of starch capsule and preparation method thereof
CN104984355B (en)*2015-07-132017-12-29湖南尔康制药股份有限公司A kind of premixing auxiliary material and preparation method thereof
CN105030723A (en)*2015-07-132015-11-11湖南尔康制药股份有限公司Starch capsule and method for preparing same
CN104984355A (en)*2015-07-132015-10-21湖南尔康制药股份有限公司Premixing auxiliary material and preparing method of premixing auxiliary material
CN105580902A (en)*2015-12-182016-05-18湖南尔康制药股份有限公司Freeze-dried flavored milk capsule and preparation process thereof
CN105558818A (en)*2015-12-182016-05-11湖南尔康制药股份有限公司Convenient instant staple food with various flavors
CN105533610A (en)*2015-12-182016-05-04湖南尔康制药股份有限公司Spice capsule
CN105853388A (en)*2016-04-252016-08-17夏放军Health care hollow capsule and preparation method thereof
CN105769811A (en)*2016-05-052016-07-20夏放军Empty starch capsule and preparation method thereof
CN105885109A (en)*2016-05-112016-08-24湖南尔康制药股份有限公司Starch-base film-forming composition capable of being applied to edible packaging field
CN105801922A (en)*2016-05-112016-07-27湖南尔康制药股份有限公司Starch empty capsule applicable to edible packaging field and preparation method of starch empty capsule
CN105885109B (en)*2016-05-112017-07-07湖南尔康制药股份有限公司A kind of starch base film-forming composition that can be applied to edible packaging field
CN105997928A (en)*2016-05-202016-10-12夏放军Sweet hollow capsule and preparation method thereof
CN109562184A (en)*2016-07-062019-04-02快力胶囊股份有限公司 Hard capsule with improved hardness and method for producing the same
US11318101B2 (en)2016-07-062022-05-03Qualicaps Co., Ltd.Hard capsule having improved hardness, and method for manufacturing same
CN109562184B (en)*2016-07-062023-02-03快力胶囊股份有限公司 Hard capsule with improved hardness and manufacturing method thereof
CN106074436A (en)*2016-07-122016-11-09吉林农业大学A kind of method utilizing starch matrix to make heat molten type capsule material
CN106420657A (en)*2016-08-292017-02-22浙江大学Production method and product of rice starch hollow capsule
CN107184562A (en)*2017-05-102017-09-22中象新材料(大连)有限公司A kind of corn bran starch hollow capsule and preparation method thereof
CN107549859A (en)*2017-09-192018-01-09太仓市林港农场专业合作社A kind of immune soft capsule of galic essential oil compound enhancing and preparation method thereof
CN107549859B (en)*2017-09-192019-11-01太仓市林港农场专业合作社A kind of galic essential oil compound enhances immune soft capsule and preparation method thereof
CN109364039A (en)*2018-09-212019-02-22浙江中同科技有限公司A kind of starch hollow capsule and preparation method thereof
CN109364038A (en)*2018-09-212019-02-22浙江中同科技有限公司A kind of Starch composite adhesive capsule and preparation method thereof
CN110063496A (en)*2019-05-272019-07-30西北农林科技大学A kind of peony petal capsule and preparation method thereof
CN110063480A (en)*2019-05-282019-07-30西北农林科技大学A kind of peony pollen capsule and preparation method thereof
CN110589255B (en)*2019-09-192021-03-16苏州纽特食品科技有限公司Packaging water and preparation method thereof
CN110589255A (en)*2019-09-192019-12-20苏州纽特食品科技有限公司Packaging water and preparation method thereof
CN112480482A (en)*2020-11-302021-03-12河北华北制药华恒药业有限公司Fermentation gel homogenizing agent and preparation method and application thereof
CN112400642A (en)*2020-12-042021-02-26宿州碧康农业科技有限公司Planting method of selenium-rich carrots without pesticide residues
CN114617264A (en)*2020-12-142022-06-14深圳市前海小藻科技有限公司Plant capsule preparation with high content of EPA
CN113181135A (en)*2021-05-132021-07-30青岛益青生物科技股份有限公司Gelatin hollow capsule with new formula and preparation method thereof
CN114788820A (en)*2022-04-182022-07-26陕西省动物研究所Starch matrix empty capsule with biological auxiliary function pharmacological action
CN116218043A (en)*2023-03-202023-06-06中国农业大学Natural pigment edible starch film and preparation method thereof
CN116869957A (en)*2023-07-312023-10-13上海春芝堂生物制品有限公司Plant capsule shell material, plant soft capsule, and preparation methods and applications thereof
CN119547854A (en)*2024-12-032025-03-04广州市威伦食品有限公司 A preparation method of natural plant pigment composition and its application in food

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