Disclosure of Invention
In view of the shortcomings of the prior art, an object of the present specification is to provide a full-color melt slice spinning device capable of automatically identifying and precisely mixing colors, which can automatically detect the color of a sample and color the spinning main material in a primary color, so that the color of the spinning main material is consistent with the color of the sample, and can color the full color by three color master batches, and has an automatic cleaning function.
To achieve the above object, embodiments of the present disclosure provide a full-color spectrum melt-chip spinning apparatus capable of automatic identification and precise color matching, comprising:
 The first material conveying mechanism is used for conveying the spinning main material to be colored, and is provided with a first metering pump and a first outlet, wherein the first metering pump is used for metering the conveying amount of the spinning main material;
 The three second material conveying mechanisms are respectively used for conveying color master batches of red, yellow and blue, and are provided with a second metering pump and a second outlet, wherein the three second metering pumps are respectively used for metering the conveying amount of the color master batches of the red, yellow and blue;
 The cleaning agent conveying device comprises a cleaning agent conveying mechanism, a cleaning agent conveying mechanism and a cleaning agent conveying mechanism, wherein the cleaning agent conveying mechanism is provided with a third metering pump and a third outlet, and the third metering pump is used for metering the conveying amount of the cleaning agent;
 The material mixing mechanism is communicated with the first material conveying mechanism, the second material conveying mechanism and the third material conveying mechanism, is provided with a material inlet, and is connected with the first outlet, the second outlet and the third outlet;
 the spectrocolorimeter is used for analyzing and confirming the color number of the target production color sample;
 The control mechanism is electrically connected with the light-splitting color measuring instrument, the first metering pump, the three second metering pumps, the three first material level sensors and the third metering pump and is used for receiving color number information of the light-splitting color measuring instrument and controlling the rotating speeds of the three second metering pumps;
 And the spinning box body is connected with the fourth outlet.
As a preferable implementation mode, the mixing mechanism comprises a mixing bin, wherein the mixing bin is provided with the feeding hole, the feeding hole is in an inverted cone shape, and a conical part opposite to the feeding hole is arranged in the mixing bin.
As a preferred implementation mode, the mixing mechanism further comprises a mixing pipe arranged below the mixing bin, and a plurality of folding baffles are arranged in the mixing pipe in a staggered mode.
As a preferred implementation mode, the material mixing mechanism further comprises a material level monitoring bin arranged below the material mixing pipe, a second material level sensor is arranged in the material level monitoring bin and is electrically connected with the control mechanism, and the second material level sensor is a rotation-resistant material level sensor.
As a preferred embodiment, the mixing mechanism further comprises a screw extruder arranged below the material level monitoring bin, the screw extruder comprises a screw and a first motor, the first motor is used for driving the screw to rotate, and the screw is horizontally arranged and used for conveying mixed materials.
As a preferable implementation mode, the mixing mechanism further comprises a dynamic mixer connected to the outlet of the screw extruder, the dynamic mixer is connected with a second motor, the inlet of the dynamic mixer is communicated with the outlet of the screw extruder, and the fourth outlet is arranged at the outlet of the dynamic mixer.
The first material conveying mechanism comprises a wet storage bin, a pre-crystallizer and a first drying tower which are sequentially connected, wherein a first sight glass is arranged in the wet storage bin, a wet material discharging metering valve is arranged between the wet storage bin and the pre-crystallizer, a second sight glass is arranged in the first drying tower, a first discharging valve is arranged above the first outlet at the bottom of the first drying tower, and the first metering pump is arranged between the first discharging valve and the first outlet.
As a preferred embodiment, the second feeding mechanism comprises a second drying tower, a second discharging valve is arranged above the second outlet at the bottom of the second drying tower, and the second metering pump is arranged between the second discharging valve and the second outlet.
As a preferable implementation mode, the second metering pump is a positive displacement metering pump, and the control mechanism determines the blanking proportion of the color master batches of the three colors of red, yellow and blue according to the color number information, so as to control the rotating speeds of the three positive displacement metering pumps.
In a preferred embodiment, the third feeding mechanism comprises a third drying tower, a third discharging valve is arranged at the bottom of the third drying tower above the third outlet, the third metering pump is arranged between the third discharging valve and the third outlet, when the third feeding mechanism works, the three second discharging valves are closed, the first discharging valve and the third discharging valve are opened, and the spinning main material and the cleaning agent are discharged according to a preset proportion.
Advantageous effects
According to the full-color spectrum melt slice spinning device capable of automatically identifying and accurately mixing colors, through the arrangement of the three second material conveying mechanisms, color master batches of red, yellow and blue (namely three primary colors) can be respectively conveyed, and the three second metering pumps, the light-splitting color measuring instrument and the control mechanism are arranged, so that full-color spectrum polyester melt can be blended for spinning, market color master batches are not needed, free color mixing and full-color spectrum color mixing can be realized, the occupied area is small, and full-color spectrum spinning can be realized only through the three color master batches. By arranging the light-splitting color meter and the control mechanism, the color number of the target production color sample can be automatically identified, the color is accurately matched, and the error is small. Through setting up the third conveying mechanism that carries the cleaner, can set for procedure cleaning pipeline and equipment voluntarily, need not manual operation, convenient and fast shortens the colour changing flow, reduces the colour changing cost.
Specific embodiments of the invention are disclosed in detail below with reference to the following description and drawings, indicating the manner in which the principles of the invention may be employed. It should be understood that the embodiments of the invention are not limited in scope thereby.
Features that are described and/or illustrated with respect to one embodiment may be used in the same way or in a similar way in one or more other embodiments in combination with or instead of the features of the other embodiments.
It should be emphasized that the term "comprises/comprising" when used herein is taken to specify the presence of stated features, integers, steps or components but does not preclude the presence or addition of one or more other features, integers, steps or components.
Drawings
In order to more clearly illustrate the embodiments of the invention or the technical solutions of the prior art, the drawings which are used in the description of the embodiments or the prior art will be briefly described, it being obvious that the drawings in the description below are only some embodiments of the invention, and that other drawings can be obtained from these drawings without inventive faculty for a person skilled in the art.
FIG. 1 is a schematic diagram of a full-color melt-slice spinning device capable of automatic identification and precise color matching according to the present embodiment;
 Fig. 2 is a schematic structural diagram of a mixing bin provided in the present embodiment;
 Fig. 3 is a schematic structural diagram of a mixing tube according to the present embodiment;
 fig. 4 is a schematic structural diagram of a material level monitoring bin provided in the present embodiment;
 fig. 5 is a schematic structural diagram of a dynamic mixer according to the present embodiment.
Reference numerals illustrate:
 1. The device comprises a first conveying mechanism, 11, a wet storage bin, 111, a first sight glass, 12, a wet material blanking metering valve, 13, a pre-crystallizer, 14, a first drying tower, 141, a second sight glass, 15, a first blanking valve, 16, a first metering pump, 17 and a first outlet;
 2. A second material conveying mechanism; 21, a second drying tower, 22, a second blanking valve, 23, a second metering pump, 24, a second outlet;
 3. a third material conveying mechanism; 31, a third drying tower, 32, a third blanking valve, 33, a third metering pump, 34, a third outlet;
 4. Mixing mechanism 41, mixing bin 411, feed inlet 412, taper part 42, mixing tube 421, folding baffle, 43, material level monitoring bin 431, second material level sensor 44, screw extruder 441, first motor 45, dynamic mixer 451, second motor 452, fourth outlet;
 5. a spectroscopic colour meter; 6, a control mechanism, 7, a spinning box, 71, a spinning component and 8, a mounting platform.
Detailed Description
In order to make the technical solution of the present invention better understood by those skilled in the art, the technical solution of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention, and it is apparent that the described embodiments are only some embodiments of the present invention, not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, shall fall within the scope of the invention.
It will be understood that when an element is referred to as being "disposed on" another element, it can be directly on the other element or intervening elements may also be present. When an element is referred to as being "connected" to another element, it can be directly connected to the other element or intervening elements may also be present. The terms "vertical," "horizontal," "left," "right," and the like are used herein for illustrative purposes only and are not meant to be the only embodiment.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used herein in the description of the invention is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. The term "and/or" as used herein includes any and all combinations of one or more of the associated listed items.
Please refer to fig. 1 to 5. The embodiment of the application provides a full-color-spectrum melt slice spinning device capable of automatically identifying and accurately mixing colors, which comprises a first material conveying mechanism 1, a second material conveying mechanism 2, a third material conveying mechanism 3, a material mixing mechanism 4, a light-splitting color measuring instrument 5, a control mechanism 6 and a spinning box 7.
Wherein the first feeding mechanism 1 is used for conveying spinning main materials to be colored, such as polyester chips. The first feeding mechanism 1 is provided with a first metering pump 16 and a first outlet 17, and the first metering pump 16 is used for metering the feeding amount of the spinning main material. The second material conveying mechanisms 2 are three and are respectively used for conveying color master batches of red, yellow and blue. The second material conveying mechanism 2 is provided with a second metering pump 23 and a second outlet 24, and the three second metering pumps 23 are respectively used for metering the conveying amount of the color master batch of red, yellow and blue. A first level sensor (not shown) is provided upstream of the second metering pump 23 for detecting the level of the fluid before the second metering pump 23. The third material conveying mechanism 3 is used for conveying cleaning agents. The third delivery mechanism 3 is provided with a third metering pump 33 and a third outlet 34, the third metering pump 33 being used for metering the delivery of cleaning agent. The material mixing mechanism 4 is communicated with the first material conveying mechanism 1, the second material conveying mechanism 2 and the third material conveying mechanism 3. The mixing mechanism 4 is provided with a feeding hole 411, and the feeding hole 411 is connected with the first outlet 17, the second outlet 24 and the third outlet 34. The mixing mechanism 4 is provided with a fourth outlet 452. The spectrocolorimeter 5 is used for analyzing and confirming the color number of the target production color sample. The control mechanism 6 is electrically connected with the spectrocolorimeter 5, the first metering pump 16, the three second metering pumps 23, the three first level sensors and the third metering pump 33. The control mechanism 6 is used for receiving the color number information of the spectrocolorimeter 5 and controlling the rotating speeds of the three second metering pumps 23. The spinning beam 7 is connected to the fourth outlet 452. After the spinning main material and the color master batch are fully mixed by the mixing mechanism 4, the mixture is discharged to the spinning manifold 7 from the fourth outlet 452.
According to the full-color spectrum melt slice spinning device capable of automatically identifying and accurately mixing colors, through the arrangement of the three second material conveying mechanisms 2, color master batches of red, yellow and blue (namely three primary colors) can be respectively conveyed, and the three second metering pumps 23, the spectrocolorimeter 5 and the control mechanism 6 are arranged, so that full-color spectrum polyester melt can be blended for spinning, market color master batches are not required, free color mixing is achieved, the occupied area of the full-color spectrum melt slice spinning device is small, and full-color spectrum spinning can be achieved only through the three color master batches. By arranging the spectrocolorimeter 5 and the control mechanism 6, the color number of the target production color sample can be automatically identified, the color is accurately matched, and the error is small. Through setting up the third material conveying mechanism 3 that carries the cleaner, can set for procedure cleaning pipeline and equipment voluntarily, need not manual operation, convenient and fast shortens the colour changing flow, reduces the colour changing cost.
In the present embodiment, as shown in fig. 2, the mixing mechanism 4 includes a mixing hopper 41. The mixing bin 41 is provided with the feed inlet 411, and the feed inlet 411 is in an inverted cone shape, so that the spinning main material and the color master batch of each color can be conveniently gathered. The inside of the mixing bin 41 is provided with a conical part 412 opposite to the feeding hole 411, and the spinning main material and the color master batch of each color drop to the conical part 412 from the reverse conical feeding hole 411, so that the primary mixing is realized.
As shown in fig. 3, the mixing mechanism 4 further includes a mixing pipe 42 disposed below the mixing bin 41, and a plurality of folding baffles 421 inclined downward are staggered in the mixing pipe 42, and the spinning main material and the color master batch of each color fall through dead weight, flow back and forth between the folding baffles 421, and mix, so as to realize secondary mixing. The mixing pipe 42 adopts a structure principle similar to a rectifying tower to fully mix the master batch.
As shown in fig. 4, the mixing mechanism 4 further includes a level monitoring bin 43 disposed below the mixing pipe 42, and a second level sensor 431 is disposed in the level monitoring bin 43. The second level sensor 431 is preferably a rotation-resistant level sensor, because the rotation-resistant level sensor has a mixing and stirring effect on the master batch, and realizes the third mixing and increases the mixing of the master batch of each component. The second level sensor 431 is electrically connected to the control mechanism 6, and the control mechanism 6 controls the device to stop operation once the second level sensor 431 detects a shortage of material.
As shown in fig. 1, the compounding mechanism 4 further includes a screw extruder 44 disposed below the level monitoring bin 43. The screw extruder 44 includes a screw and a first motor 441, and the first motor 441 is for driving the screw to rotate. The screw rod is horizontally arranged and used for conveying the mixed materials. And conveying the mixed master batch into a screw with partition heating through a rotating screw for melt mixing, so as to realize fourth mixing.
As shown in fig. 5, the compounding mechanism 4 further includes a dynamic mixer 45 connected to the outlet of the screw extruder 44. A second motor 451 is connected to the dynamic mixer 45 for driving the rotation of the structure within the dynamic mixer 45. The inlet of the dynamic mixer 45 communicates with the outlet of the screw extruder 44, and a fourth outlet 452 is provided at the outlet of the dynamic mixer 45. The melt coming out of the screw extruder 44 enters the dynamic mixer 45 to be stirred uniformly, and is mixed for the fifth time, so that pure coloring of the stock solution is ensured. The spinning device provided by the embodiment of the application is skillfully provided with five times of mixing, and can ensure that the color of the blended stock solution is uniform.
In the present embodiment, the spinning beam 7 is provided with a spinning assembly 71, and the spinning assembly 71 includes a fourth metering pump and a spinning die. The melt discharged from the outlet of the dynamic mixer 45 enters a fourth metering pump in the spinning beam 7, reaches a spinning die head through metering, and ejects polyester filaments with a specific shape, a specific number and a specific fineness.
Specifically, as shown in fig. 1, the first material conveying mechanism 1 comprises a wet storage bin 11, a pre-crystallizer 13 and a first drying tower 14 which are sequentially connected. The wet silo 11 is provided with a first sight glass 111 for checking the internal conditions. A wet material discharging metering valve 12 is arranged between the wet material bin 11 and the pre-crystallizer 13 and is used for metering the discharging amount of the wet material. The first drying tower 14 is used for drying the spinning main material, and the first drying tower 14 is provided with a second sight glass 141 for checking the internal condition. The bottom of the first drying tower 14 is provided with a first blanking valve 15 above the first outlet 17, so that whether the first material conveying mechanism 1 inputs spinning main materials into the material mixing mechanism 4 can be controlled. The first metering pump 16 is arranged between the first blanking valve 15 and the first outlet 17, and after the first blanking valve 15 is opened, the first metering pump 16 works to meter the amount of the spinning main material input to the mixing mechanism 4 by the first material conveying mechanism 1.
Specifically, the second feeding mechanism 2 includes a second drying tower 21 for drying the red or yellow or blue master batch. The bottom of the second drying tower 21 is provided with a second blanking valve 22 above a second outlet 24, so that whether the second material conveying mechanism 2 inputs red master batch or yellow master batch or blue master batch into the material mixing mechanism 4 can be controlled. The second metering pump 23 is arranged between the second blanking valve 22 and the second outlet 24, and after the second blanking valve 22 is opened, the second metering pump 23 works to meter the amount of the red master batch, the yellow master batch and the blue master batch which are input into the mixing mechanism 4 by the second material conveying mechanism 2.
In the present embodiment, the second metering pump 23 is a volumetric metering pump, and by varying the rotational speed, the master batch of accurate volume is transported into the mixing bin 41. The first material level sensor selects an infrared sensing material level instrument, and once the single-component master batch lacks materials before the second metering pump 23, the second metering pump 23 corresponding to the single-component master batch alarms for lacking materials, and then the screw stops running, and the spinning device stops, so that the accurate component proportioning is protected.
Specifically, once the single component master batch is starved before the second metering pump 23, the first level sensor transmits a signal to the control mechanism 6, the control mechanism 6 can control the alarm model to be played through the loudspeaker, and the screen is used for displaying the alarm content, so that a worker can clearly determine which component is starved, when the starved alarm occurs three times continuously within a specified time, the control mechanism 6 starts a skip equipment instruction to stop the whole spinning device, and the color of the produced polyester filament is ensured to be correct.
The spectrocolorimeter 5 according to the embodiment of the present application preferably uses a Color-Eye spectrocolorimeter, and operates by measuring reflected light or transmitted light in the entire spectrum and generating a visual curve for describing the Color on a specific substrate under specific illumination conditions. Color-Eye spectrophotometers are capable of accurately analyzing Color because they can measure the visible spectrum range from 360nm to 750nm in units of wavelengths of every 10nm and provide specular reflection element and transmission mode measurements. The optical principle utilized by Color-Eye spectrophotometers is scattering/8 ° (illumination/measurement), which design enables it to accurately measure various properties of Color, including hue, brightness and saturation. The reflectance curve of a white surface is a straight line and the reflectance is approximately between 90% and 100%. The reflectance curve of the black surface is flat and the reflectance is close to 0%. While the reflectivity of the other colors peaks over the wavelength range of the light that it reflects most. This measurement is based on the physical properties of the colors, and by analyzing the reflected or transmitted light, the spectrophotometer 5 can quantify the color differences, thereby helping the user to perform accurate color management and quality control.
In this embodiment, after analyzing and confirming the color number of the target production color sample, the spectrocolorimeter 5 inputs the color number information to the control mechanism 6, and the control mechanism 6 determines (automatically outputs) the blanking ratio of the color master batches of the three colors of red, yellow and blue according to the color number information, thereby controlling the rotation speed of the three second metering pumps 23 (volumetric metering pumps) and accurately calculating the blanking amount of each component. For example, the Color-Eye spectrophotometry detects a green No. 1 sample Color, the control mechanism 6 controls the blue master batch and the yellow master batch to be mixed according to a ratio of 1:1, the Color-Eye spectrophotometry detects a green No. 2 sample Color, the control mechanism 6 controls the blue master batch and the yellow master batch to be mixed according to a ratio of 1:1.5, the Color-Eye spectrophotometry detects a rose No. 1 sample Color, the control mechanism 6 controls the red master batch, the yellow master batch and the blue master batch to be mixed according to a ratio of 5:4:1, and the Color-Eye spectrophotometry detects a rose No. 2 sample Color, and the control mechanism 6 controls the red master batch, the yellow master batch and the blue master batch to be mixed according to a ratio of 6:3:1. And other different color ratios are not described here.
As shown in fig. 1, the third feed mechanism 3 includes a third drying tower 31 for drying the cleaning agent. The bottom of the third drying tower 31 is provided with a third discharging valve 32 above a third outlet 34, so that whether the third material conveying mechanism 3 inputs cleaning agent to the material mixing mechanism 4 can be controlled. The third metering pump 33 is disposed between the third discharging valve 32 and the third outlet 34, and after the third discharging valve 32 is opened, the third metering pump 33 works, so that the third feeding mechanism 3 can meter the amount of the cleaning agent fed into the mixing mechanism 4. When the third feeding mechanism 3 works, the three second discharging valves 22 are closed, the first discharging valve 15 and the third discharging valve 32 are opened, and the spinning main material and the cleaning agent are discharged according to a preset proportion.
When the screw rod is stopped for changing materials each time, the control mechanism 6 controls the three second discharging valves 22 and the three second metering pumps 23 to be closed, the first discharging valve 15, the first metering pump 16, the third discharging valve 32 and the third metering pump 33 are opened, the spinning main materials and the cleaning agent are discharged according to a preset proportion, and after the spinning main materials mixed with the cleaning agent pass through the screw rod, the pipeline, the dynamic mixer 45, the spinning box 7 and the fourth metering pump, the dye components in the spinning device are cleaned and taken away, so that the preparation is made for the next material with different colors. Through setting up control mechanism 6 and third feed mechanism 3, this spinning device can set for the procedure automatically and wash the pipeline, need not manual operation, convenient and fast.
In the present embodiment, the main component of the cleaning agent is a special resin material, and the cleaning agent is specially used for cleaning a plastic molding machine, and has high cleaning power and low residue. Its low residual properties benefit from its special molecular structure, making it very low in adhesion to metals, easily replaced by other resins, and thus reducing the residual properties. In addition, the cleaning agent is convenient to store and use, is safe and nontoxic, meets the environmental protection requirement, does not generate chemical reaction, has no corrosiveness and does not contain harmful substances. The cleaning agent mainly wets, permeates and swells degradation products, black spots, carbon deposition, color residues and other substances on the surface of the screw barrel by the action of the surfactant, thereby playing a role in cleaning. Sometimes, the combination of surfactant and grinding components (such as glass fiber, calcium carbonate and silicon dioxide) is adopted, and the pipeline is cleaned by utilizing the infiltration of the surfactant and the grinding action of inorganic filler.
The color master batch is a novel special colorant for high polymer materials and consists of three basic elements of pigment or dye, a carrier and an additive. The three-primary color masterbatch in the embodiment of the application is prepared from ACE dye, and the masterbatch has wide application in the field of plastic coloring and can improve the light resistance, weather resistance, electrical conductivity, antistatic effect and the like of plastics. Therefore, ACE dye has complete capability of being prepared into color master batches, and can meet the coloring requirements of different polymer products. In addition, ACE dye is a disperse dye, the molecular particle size of the dye is uniform, the speed is uniform and uniform during mixing diffusion, the color is not robbed, and the ACE dye is suitable for dyeing fabrics such as knitting, tatting polyester, polyester/cotton, polyester/wool, polyester/viscose and the like. Due to the requirements of the dyeing temperature and the dyeing time of the ACE dye and the stability of the ACE dye at high temperature, the ACE dye is very suitable for preparing color master batches. The three primary color master batch prepared by the ACE dye is selected, and the dispersion rate is consistent, the color is not robbed and the color is accurate during mixed coloring.
In particular, the spinning device may further comprise a mounting platform 8 for carrying part of the components of the spinning device.
It should be noted that, in the description of the present specification, the terms "first," "second," and the like are used for descriptive purposes only and to distinguish between similar objects, and there is no order of preference therebetween, nor should it be construed as indicating or implying relative importance. In addition, in the description of the present specification, unless otherwise indicated, the meaning of "a plurality" is two or more.
Any numerical value recited herein includes all values of the lower and upper values that are incremented by one unit from the lower value to the upper value, as long as there is a separation of at least two units between any lower value and any higher value. For example, if it is stated that the number of components or the value of a process variable (e.g., temperature, pressure, time, etc.) is from 1 to 90, preferably from 20 to 80, more preferably from 30 to 70, then the purpose is to explicitly list such values as 15 to 85, 22 to 68, 43 to 51, 30 to 32, etc. in this specification as well. For values less than 1, one unit is suitably considered to be 0.0001, 0.001, 0.01, 0.1. These are merely examples that are intended to be explicitly recited in this description, and all possible combinations of values recited between the lowest value and the highest value are believed to be explicitly stated in the description in a similar manner.
Unless otherwise indicated, all ranges include endpoints and all numbers between endpoints. "about" or "approximately" as used with a range is applicable to both endpoints of the range. Thus, "about 20 to 30" is intended to cover "about 20 to about 30," including at least the indicated endpoints.
All articles and references, including patent applications and publications, disclosed herein are incorporated by reference for all purposes. The term "consisting essentially of" describing a combination shall include the identified element, ingredient, component or step as well as other elements, ingredients, components or steps that do not substantially affect the essential novel features of the combination. The use of the terms "comprises" or "comprising" to describe combinations of elements, components, or steps herein also contemplates embodiments consisting essentially of such elements, components, or steps. By using the term "may" herein, it is intended that any attribute described as "may" be included is optional.
Multiple elements, components, parts or steps can be provided by a single integrated element, component, part or step. Alternatively, a single integrated element, component, part or step may be divided into separate plural elements, components, parts or steps. The disclosure of "a" or "an" to describe an element, component, section or step is not intended to exclude other elements, components, sections or steps.
It is to be understood that the above description is intended to be illustrative, and not restrictive. Many embodiments and many applications other than the examples provided will be apparent to those of skill in the art upon reading the above description. The scope of the present teachings should, therefore, be determined not with reference to the above description, but instead should be determined with reference to the appended claims, along with the full scope of equivalents to which such claims are entitled. The disclosures of all articles and references, including patent applications and publications, are incorporated herein by reference for the purpose of completeness. The omission of any aspect of the subject matter disclosed herein in the preceding claims is not intended to forego such subject matter, nor should the inventors regard such subject matter as not be considered to be part of the disclosed subject matter.