技术领域Technical field
本发明涉及宠物洗护品领域，具体涉及一种防脱宠物洗护凝胶组合物及其制备方法。The invention relates to the field of pet care products, and in particular to an anti-shedding pet care gel composition and a preparation method thereof.
背景技术Background technique
随着生活水平不断提高，家庭饲养宠物数量不断增加。由于宠物大多毛发浓密，又喜欢在草丛泥地穿梭翻滚，使其容易携带和滋生蚊虫、虱子、跳蚤及螨虫等病原体，加上自身的体味，身上容易沾染各种细菌，这对宠物和主人的健康存在很大的隐患。因此，对宠物进行清洁时不仅要洗净宠物皮毛上的尘土污垢，而且还要实现驱虫、祛除异味以及抗菌抑菌的目的。因此宠物的卫生护理一直是比较关注的问题。现有技术中开发了不同品类的宠物香波，但是往往在清洗时，需要涂覆宠物香波后进行长久的揉搓以提升宠物香波的去污能力，而且在清洗时会导致比较严重的脱毛。As living standards continue to improve, the number of pets kept in households continues to increase. Because most pets have thick hair and like to roll around in grass and mud, they are prone to carry and breed pathogens such as mosquitoes, lice, fleas, and mites. In addition, coupled with their own body odor, their bodies are easily contaminated with various bacteria, which is harmful to pets and their owners. There are huge health risks. Therefore, when cleaning pets, we must not only wash away the dust and dirt on the pet's fur, but also achieve the purposes of repelling insects, removing odors, and antibacterial and antibacterial effects. Therefore, the health care of pets has always been a matter of concern. Different types of pet shampoos have been developed in the prior art. However, when cleaning, it is often necessary to apply pet shampoo and then rub it for a long time to improve the decontamination ability of the pet shampoo, and it will cause serious hair loss during cleaning.
发明内容Contents of the invention
本发明的目的在于克服现有技术存在的不足之处而提供一种防脱宠物洗护凝胶组合物及其制备方法。The object of the present invention is to overcome the shortcomings of the prior art and provide an anti-shedding pet care gel composition and a preparation method thereof.
为实现上述目的，本发明采取的技术方案为：一种防脱宠物洗护组合物，所述防脱宠物洗护凝胶组合物包括以下重量百分比的组分：8％～12％的辛基十二烷醇、1％～4％的PEG-40氢化蓖麻油、2％～4％的丙三醇、3％～5％的马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物、5％～10％的银杏叶提取物、0.3％～1％的烟酰胺、0.3％～0.8％维生素E、0.1％～0.5％的芳香精油、0.1％～0.25％的抑菌螨组分、pH调节剂和余量的去离子水。In order to achieve the above object, the technical solution adopted by the present invention is: an anti-shedding pet care gel composition, the anti-shedding pet care gel composition includes the following components by weight percentage: 8% to 12% octyl Dodecanol, 1% to 4% PEG-40 hydrogenated castor oil, 2% to 4% glycerol, 3% to 5% maleic anhydride-styrene-sodium methacrylate sulfonate polymer, 5% to 10% Ginkgo leaf extract, 0.3% to 1% nicotinamide, 0.3% to 0.8% vitamin E, 0.1% to 0.5% aromatic essential oil, 0.1% to 0.25% antibacterial mite component, pH conditioner and balance deionized water.
上述的防脱宠物洗护组合物中，辛基十二烷醇、氢化蓖麻油、丙三醇、马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物以辛基十二烷醇作为主要的油相，和氢化蓖麻油、丙三醇以及作为主要表面活性剂的马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物混合均质后，形成微乳体系，微乳油均一、透明，能够负载银杏叶提取物、烟酰胺、维生素E、芳香精油、抑菌螨组分等功效成分，负载功效成分的微乳油分散在水系中，平均粒径在20～80nm，多分散性系数(PDI)在0.3以下，微乳粒径均一，其作为防脱宠物洗护组合物，将该防脱宠物洗护组合物轻柔涂覆至宠物身体，由于微乳粒径小，均一，能够更好的、更均匀的分布在宠物身体表面，而且微乳可以将宠物身体表面的油污、糖类、蛋白质等溶解，起到去污效果，且微乳粒径小，均一，直接冲洗即具有良好的去污效果，冲洗无残留，避免了宠物洗涤剂使用时的反复揉搓，减少了宠物的不适和脱毛。In the above-mentioned anti-shedding pet care composition, octyldodecanol, hydrogenated castor oil, glycerin, maleic anhydride-styrene-sodium methacrylate sulfonate polymer are mainly composed of octyldodecanol. The oil phase is mixed and homogenized with hydrogenated castor oil, glycerol and maleic anhydride-styrene-sodium methacrylate sulfonate polymer as the main surfactant to form a microemulsion system. The microemulsion is uniform and transparent. It can load functional ingredients such as ginkgo leaf extract, nicotinamide, vitamin E, aromatic essential oils, and antibacterial mite components. The microemulsifiable oil loaded with functional ingredients is dispersed in the water system, with an average particle size of 20 to 80 nm and a polydispersity coefficient (PDI). ) below 0.3, the microemulsion particle size is uniform, and it can be used as an anti-shedding pet care composition. The anti-shedding pet care composition is gently applied to the pet's body. Since the microemulsion particle size is small and uniform, it can better , more evenly distributed on the surface of the pet's body, and the microemulsion can dissolve oil, sugar, protein, etc. on the surface of the pet's body to achieve a decontamination effect. The particle size of the microemulsion is small and uniform, and it has good decontamination properties when rinsed directly. It has a stain-free effect and no residue after washing, which avoids repeated rubbing when using pet detergent and reduces pet discomfort and hair loss.
优选地，所述抑菌螨组分为麝香草酚、山梨酸和二氯海英中的一种或多种。Preferably, the antibacterial mite component is one or more of thymol, sorbic acid and dichlorohydantoin.
上述防脱宠物洗护组合物中的抑菌螨组分对虱子、跳蚤、螨虫、癣菌等具有抑菌和除螨效果。The antibacterial and mite component in the above-mentioned anti-shedding pet care composition has antibacterial and mite-removing effects on lice, fleas, mites, ringworm, etc.
优选地，所述防脱宠物洗护组合物为微乳组合物，所述防脱宠物洗护组合物中微乳的平均粒径为20～80nm。Preferably, the anti-shedding pet care composition is a microemulsion composition, and the average particle size of the microemulsion in the anti-shedding pet care composition is 20 to 80 nm.
优选地，所述防脱宠物洗护组合物为微乳组合物，所述防脱宠物洗护组合物中微乳的平均粒径为20～40nm。Preferably, the anti-shedding pet care composition is a microemulsion composition, and the average particle size of the microemulsion in the anti-shedding pet care composition is 20 to 40 nm.
优选地，所述防脱宠物洗护组合物中微乳粒径的多分散性系数为0.12～0.18。Preferably, the polydispersity coefficient of the microemulsion particle size in the anti-shedding pet care composition is 0.12 to 0.18.
上述的防脱宠物洗护组合物为微乳组合物具有更好的去污效果和防脱毛效果。The above-mentioned anti-hair loss pet care composition is a microemulsion composition and has better decontamination effect and anti-hair loss effect.
优选地，所述防脱宠物洗护组合物的微乳组合物的制备方法包括步骤：Preferably, the preparation method of the microemulsion composition of the anti-shedding pet care composition includes the steps:
(1)将辛基十二烷醇、PEG-40氢化蓖麻油、丙三醇、马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物按照重量比均质混匀；(1) Homogenously mix octyldodecanol, PEG-40 hydrogenated castor oil, glycerin, maleic anhydride-styrene-sodium methacrylate sulfonate polymer according to weight ratio;
(2)将银杏叶提取物、烟酰胺、维生素E、芳香精油、抑菌螨组分加入步骤(1)得到的均质混合物中，均质混匀；(2) Add ginkgo leaf extract, nicotinamide, vitamin E, aromatic essential oils, and antibacterial mite components to the homogeneous mixture obtained in step (1), and mix evenly;
(3)于30～38℃下，在步骤(2)得到均质混合物处于搅拌状态下滴加去离子水。(3) At 30 to 38°C, add deionized water dropwise while stirring the homogeneous mixture obtained in step (2).
优选地，所述马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物的化学结构如式Ⅰ所示：Preferably, the chemical structure of the maleic anhydride-styrene-sodium methacrylate sulfonate polymer is as shown in Formula I:
其中，m、n、p均为大于0的自然数，7％≤p/(m+n+p)≤12％，10％≤n/(m+n+p)≤13.5％，所述马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物的分子量为4000～10000。Among them, m, n and p are all natural numbers greater than 0, 7%≤p/(m+n+p)≤12%, 10%≤n/(m+n+p)≤13.5%, the Malay The molecular weight of the acid anhydride-styrene-sodium methacrylate sulfonate polymer is 4,000 to 10,000.
上述的防脱宠物洗护组合物具有更优异的去污能力。The above-mentioned anti-shedding pet cleaning and care composition has more excellent stain removal ability.
优选地，所述pH调节剂调节所述防脱宠物洗护组合物的pH为6.5～7，所述pH调节剂为柠檬酸、酒石酸。Preferably, the pH adjuster adjusts the pH of the anti-shedding pet care composition to 6.5-7, and the pH adjuster is citric acid or tartaric acid.
上述的防脱宠物洗护组合物以柠檬酸、酒石酸作pH调节剂调节pH为6.5～7，性能温和，刺激性更小。The above-mentioned anti-shedding pet care composition uses citric acid and tartaric acid as pH regulators to adjust the pH to 6.5-7, has mild performance and less irritation.
优选地，所述芳香精油为为薰衣草精油、柠檬精油、玫瑰精油、茶树精油、洋甘菊精油、茉莉花精油、天竺葵精油、迷迭香精油、薄荷精油中的一种或数种。Preferably, the aromatic essential oil is one or more of lavender essential oil, lemon essential oil, rose essential oil, tea tree essential oil, chamomile essential oil, jasmine essential oil, geranium essential oil, rosemary essential oil, and peppermint essential oil.
上述的防脱宠物洗护组合物中添加精油，具有除臭的效果，气味淡，减少了宠物经常舔毛导致的毛上粘黏口中的臭味物质。The above-mentioned anti-shedding pet care composition is added with essential oils, which has a deodorizing effect, has a light smell, and reduces the odorous substances in the pet's mouth caused by frequent licking of fur.
优选地，所述防脱宠物洗护凝胶组合物包括以下重量百分比的组分：9％～11％的辛基十二烷醇、1.5％～3％的PEG-40氢化蓖麻油、2.5％～3.5％的丙三醇、3.5％～4.5％的马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物、5％～10％的银杏叶提取物、0.3％～1％的烟酰胺、0.3％～0.8％维生素E、0.1％～0.5％的芳香精油、0.1％～0.25％的抑菌螨组分、pH调节剂和余量的去离子水。Preferably, the anti-shedding pet care gel composition includes the following components by weight: 9% to 11% octyldodecanol, 1.5% to 3% PEG-40 hydrogenated castor oil, 2.5% ~3.5% glycerol, 3.5% ~ 4.5% maleic anhydride-styrene-sodium methacrylate sulfonate polymer, 5% ~ 10% Ginkgo leaf extract, 0.3% ~ 1% nicotinamide, 0.3% to 0.8% vitamin E, 0.1% to 0.5% aromatic essential oil, 0.1% to 0.25% antibacterial mite component, pH adjuster and the balance deionized water.
上述的防脱宠物洗护凝胶组合物在组分重量符合上述比例时，具有更好的去污效果和防脱毛效果。The above-mentioned pet hair loss prevention gel composition has better decontamination effect and hair loss prevention effect when the component weight meets the above ratio.
本发明还提供上述任一所述防脱宠物洗护组合物的制备方法，所述制备方法包括以下步骤：The present invention also provides a method for preparing any of the above-mentioned anti-shedding pet care compositions, and the preparation method includes the following steps:
(1)将辛基十二烷醇、PEG-40氢化蓖麻油、丙三醇、马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物按照重量比均质混匀；(1) Homogenously mix octyldodecanol, PEG-40 hydrogenated castor oil, glycerin, maleic anhydride-styrene-sodium methacrylate sulfonate polymer according to weight ratio;
(2)将银杏叶提取物、烟酰胺、维生素E、芳香精油、抑菌螨组分加入步骤(1)得到的均质混合物中，均质混匀；(2) Add ginkgo leaf extract, nicotinamide, vitamin E, aromatic essential oils, and antibacterial mite components to the homogeneous mixture obtained in step (1), and mix evenly;
(3)于30～38℃下，在步骤(2)得到均质混合物处于搅拌状态下滴加去离子水。(3) At 30 to 38°C, add deionized water dropwise while stirring the homogeneous mixture obtained in step (2).
本发明的有益效果在于：本发明提供了一种防脱宠物洗护凝胶组合物及其制备方法，本发明的防脱宠物洗护组合物中，辛基十二烷醇、氢化蓖麻油、丙三醇、马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物以辛基十二烷醇作为主要的油相，和氢化蓖麻油、丙三醇以及作为主要表面活性剂的马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物混合均质后，形成微乳体系，微乳油均一、透明，能够负载银杏叶提取物、烟酰胺、维生素E、芳香精油、抑菌螨组分等功效成分，负载功效成分的微乳油分散在水系中，平均粒径在20～80nm，多分散性系数(PDI)在0.3以下，微乳粒径均一，其作为防脱宠物洗护组合物，将该防脱宠物洗护组合物轻柔涂覆至宠物身体，由于微乳粒径小，均一，能够更好的、更均匀的分布在宠物身体表面，而且微乳可以将宠物身体表面的油污、糖类、蛋白质等溶解，起到去污效果，且微乳粒径小，均一，直接冲洗即具有良好的去污效果，冲洗无残留，避免了宠物洗涤剂使用时的反复揉搓，减少了宠物的不适和脱毛。The beneficial effects of the present invention are: the invention provides an anti-shedding pet care gel composition and a preparation method thereof. In the anti-shedding pet care composition of the present invention, octyldodecanol, hydrogenated castor oil, Glycerin, maleic anhydride-styrene-sodium methacrylate sulfonate polymer uses octyldodecanol as the main oil phase, and hydrogenated castor oil, glycerol and maleic anhydride as the main surfactant - After the styrene-sodium methacrylate sulfonate polymer is mixed and homogenized, a microemulsion system is formed. The microemulsion is uniform and transparent, and can load ginkgo leaf extract, nicotinamide, vitamin E, aromatic essential oils, antibacterial mite components, etc. Functional ingredients, microemulsions loaded with functional ingredients are dispersed in the water system, the average particle size is between 20 and 80nm, the polydispersity coefficient (PDI) is below 0.3, and the microemulsion particle size is uniform. It can be used as an anti-shedding pet care composition. The anti-shedding pet care composition is gently applied to the pet's body. Due to the small and uniform particle size of the microemulsion, it can be better and more evenly distributed on the surface of the pet's body, and the microemulsion can remove oil, dirt, and sugar on the surface of the pet's body. It dissolves bacteria, proteins, etc. to achieve a decontamination effect, and the microemulsion particle size is small and uniform. It has a good decontamination effect when rinsed directly. There is no residue after rinsing, which avoids repeated rubbing when using pet detergent and reduces pets' pain. Discomfort and hair loss.
具体实施方式Detailed ways
为更好的说明本发明的目的、技术方案和优点，下面将结合具体实施例对本发明作进一步说明。In order to better explain the purpose, technical solutions and advantages of the present invention, the present invention will be further described below with reference to specific embodiments.
实施例1Example 1
作为本发明实施例的一种防脱宠物洗护组合物，所述防脱宠物洗护凝胶组合物包括以下重量百分比的组分：10％的辛基十二烷醇、2.5％的PEG-40氢化蓖麻油、3％的丙三醇、4％的马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物、8％的银杏叶提取物、0.5％的烟酰胺、0.3％％维生素E、0.2％的茉莉花精油；还包括0.5％麝香草酚、0.5％山梨酸和0.3％二氯海英的作为抑菌螨组分和余量的去离子水，柠檬酸作为pH调节剂，调节pH为6.7；As an anti-shedding pet care composition according to an embodiment of the present invention, the anti-shedding pet care gel composition includes the following components by weight: 10% octyldodecanol, 2.5% PEG- 40 hydrogenated castor oil, 3% glycerin, 4% maleic anhydride-styrene-sodium methacrylate sulfonate polymer, 8% ginkgo leaf extract, 0.5% niacinamide, 0.3% vitamin E , 0.2% jasmine essential oil; also includes 0.5% thymol, 0.5% sorbic acid and 0.3% dichlorohyperin as antibacterial mite components and the balance of deionized water, citric acid as a pH regulator to adjust the pH is 6.7;
马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物的化学结构如式Ⅰ所示：The chemical structure of maleic anhydride-styrene-sodium methacrylate sulfonate polymer is shown in Formula I:
其中，m、n、p均为大于0的自然数，7％≤p/(m+n+p)≤12％，10％≤n/(m+n+p)≤13.5％。Among them, m, n and p are all natural numbers greater than 0, 7%≤p/(m+n+p)≤12%, 10%≤n/(m+n+p)≤13.5%.
本实施例中的马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物的制备方法如下：The preparation method of the maleic anhydride-styrene-sodium methacrylate sulfonate polymer in this embodiment is as follows:
(1)将一半配置好的过硫酸钾水溶液、十二硫醇加入三口瓶中，过硫酸钾质量浓度为5％，十二硫醇的质量分数为5％；(1) Add half of the prepared potassium persulfate aqueous solution and dodecyl mercaptan into a three-necked bottle. The mass concentration of potassium persulfate is 5% and the mass fraction of dodecyl mercaptan is 5%;
(2)加入马来酸酐滴加几滴氢氧化钠溶液加热至马来酸酐全部溶解；(2) Add maleic anhydride and add a few drops of sodium hydroxide solution and heat until the maleic anhydride is completely dissolved;
(3)设定好搅拌转速、蠕动泵转速控制滴加速率，向三口瓶中滴加另一半配置好的5％过硫酸钾水溶液、甲基丙烯磺酸钠水溶液、苯乙烯单体，搅拌继续升温至90℃反应1小时；(3) Set the stirring speed and peristaltic pump speed to control the dripping rate, add the other half of the prepared 5% potassium persulfate aqueous solution, sodium methacrylate sulfonate aqueous solution, and styrene monomer dropwise into the three-necked flask, and continue stirring. Raise the temperature to 90°C and react for 1 hour;
(4)搅拌速率不变的条件下冷却至室温，滴加氢氧化钠溶液调节pH至12，得到马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物；(4) Cool to room temperature while keeping the stirring rate constant, add sodium hydroxide solution dropwise to adjust the pH to 12, and obtain a maleic anhydride-styrene-sodium methacrylate sulfonate polymer;
其中，马来酸酐、甲基丙烯磺酸钠、苯乙烯的用量的摩尔比例为78:10:12。Among them, the molar ratio of maleic anhydride, sodium methacrylate sulfonate, and styrene is 78:10:12.
经液相排阻色谱检测，马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物的分子量在4800～6500之间，粘度检测为48mPa.s。After detection by liquid phase exclusion chromatography, the molecular weight of the maleic anhydride-styrene-sodium methacrylate sulfonate polymer was between 4800 and 6500, and the viscosity was detected as 48 mPa.s.
本实施例防脱宠物洗护组合物的制备方法包括步骤：The preparation method of the anti-shedding pet care composition in this embodiment includes the steps:
(1)将辛基十二烷醇、PEG-40氢化蓖麻油、丙三醇、马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物按照重量比均质混匀；(1) Homogenously mix octyldodecanol, PEG-40 hydrogenated castor oil, glycerin, maleic anhydride-styrene-sodium methacrylate sulfonate polymer according to weight ratio;
(2)将银杏叶提取物、烟酰胺、维生素E、芳香精油、抑菌螨组分加入步骤(1)得到的均质混合物中，均质混匀；(2) Add ginkgo leaf extract, nicotinamide, vitamin E, aromatic essential oils, and antibacterial mite components to the homogeneous mixture obtained in step (1), and mix evenly;
(3)于35℃下，在步骤(2)得到均质混合物处于搅拌状态下滴加去离子水。(3) At 35°C, add deionized water dropwise while stirring the homogeneous mixture obtained in step (2).
实施例2Example 2
作为本发明实施例的一种防脱宠物洗护组合物，本实施例与实施例1的唯一区别为：As an anti-shedding pet care composition according to an embodiment of the present invention, the only difference between this embodiment and Example 1 is:
所述防脱宠物洗护凝胶组合物包括以下重量百分比的组分：10％的辛基十二烷醇、2.5％的PEG-40氢化蓖麻油、3％的丙三醇、3％的马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物、8％的银杏叶提取物、0.5％的烟酰胺、0.3％％维生素E、0.2％的茉莉花精油；还包括0.5％麝香草酚、0.5％山梨酸和0.3％二氯海英的作为抑菌螨组分和余量的去离子水，柠檬酸作为pH调节剂，调节pH为6.7。The anti-shedding pet care gel composition includes the following components by weight: 10% octyldodecanol, 2.5% PEG-40 hydrogenated castor oil, 3% glycerin, 3% horseradish Lenic anhydride-styrene-sodium methacrylate sulfonate polymer, 8% Ginkgo leaf extract, 0.5% nicotinamide, 0.3% vitamin E, 0.2% jasmine essential oil; also includes 0.5% thymol, 0.5 % sorbic acid and 0.3% dichlorohydanine are used as antibacterial mite components and the balance is deionized water, and citric acid is used as a pH adjuster to adjust the pH to 6.7.
实施例3Example 3
作为本发明实施例的一种防脱宠物洗护组合物，本实施例与实施例1的唯一区别为：As an anti-shedding pet care composition according to an embodiment of the present invention, the only difference between this embodiment and Example 1 is:
所述防脱宠物洗护凝胶组合物包括以下重量百分比的组分：10％的辛基十二烷醇、2.5％的PEG-40氢化蓖麻油、3％的丙三醇、5％的马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物、8％的银杏叶提取物、0.5％的烟酰胺、0.3％％维生素E、0.2％的茉莉花精油；还包括0.5％麝香草酚、0.5％山梨酸和0.3％二氯海英的作为抑菌螨组分和余量的去离子水，柠檬酸作为pH调节剂，调节pH为6.7。The anti-shedding pet care gel composition includes the following components by weight: 10% octyldodecanol, 2.5% PEG-40 hydrogenated castor oil, 3% glycerin, 5% horseradish Lenic anhydride-styrene-sodium methacrylate sulfonate polymer, 8% Ginkgo leaf extract, 0.5% nicotinamide, 0.3% vitamin E, 0.2% jasmine essential oil; also includes 0.5% thymol, 0.5 % sorbic acid and 0.3% dichlorohydanine are used as antibacterial mite components and the balance is deionized water, and citric acid is used as a pH adjuster to adjust the pH to 6.7.
实施例4Example 4
作为本发明实施例的一种防脱宠物洗护组合物，本实施例与实施例1的唯一区别为：As an anti-shedding pet care composition according to an embodiment of the present invention, the only difference between this embodiment and Example 1 is:
所述防脱宠物洗护凝胶组合物包括以下重量百分比的组分：9％的辛基十二烷醇、2.5％的PEG-40氢化蓖麻油、3％的丙三醇、4％的马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物、8％的银杏叶提取物、0.5％的烟酰胺、0.3％％维生素E、0.2％的茉莉花精油；还包括0.5％麝香草酚、0.5％山梨酸和0.3％二氯海英的作为抑菌螨组分和余量的去离子水，柠檬酸作为pH调节剂，调节pH为6.7。The anti-shedding pet care gel composition includes the following components by weight: 9% octyldodecanol, 2.5% PEG-40 hydrogenated castor oil, 3% glycerol, 4% horse oil. Lenic anhydride-styrene-sodium methacrylate sulfonate polymer, 8% Ginkgo leaf extract, 0.5% nicotinamide, 0.3% vitamin E, 0.2% jasmine essential oil; also includes 0.5% thymol, 0.5 % sorbic acid and 0.3% dichlorohydanine are used as antibacterial mite components and the balance is deionized water, and citric acid is used as a pH adjuster to adjust the pH to 6.7.
实施例5Example 5
作为本发明实施例的一种防脱宠物洗护组合物，本实施例与实施例1的唯一区别为：As an anti-shedding pet care composition according to an embodiment of the present invention, the only difference between this embodiment and Example 1 is:
所述防脱宠物洗护凝胶组合物包括以下重量百分比的组分：11％的辛基十二烷醇、2.5％的PEG-40氢化蓖麻油、3％的丙三醇、4％的马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物、8％的银杏叶提取物、0.5％的烟酰胺、0.3％％维生素E、0.2％的茉莉花精油；还包括0.5％麝香草酚、0.5％山梨酸和0.3％二氯海英的作为抑菌螨组分和余量的去离子水，柠檬酸作为pH调节剂，调节pH为6.7。The anti-shedding pet care gel composition includes the following components by weight: 11% octyldodecanol, 2.5% PEG-40 hydrogenated castor oil, 3% glycerol, 4% horse oil. Lenic anhydride-styrene-sodium methacrylate sulfonate polymer, 8% Ginkgo leaf extract, 0.5% nicotinamide, 0.3% vitamin E, 0.2% jasmine essential oil; also includes 0.5% thymol, 0.5 % sorbic acid and 0.3% dichlorohydanine are used as antibacterial mite components and the balance is deionized water, and citric acid is used as a pH adjuster to adjust the pH to 6.7.
实施例6Example 6
作为本发明实施例的一种防脱宠物洗护组合物，本实施例与实施例1的唯一区别为：As an anti-shedding pet care composition according to an embodiment of the present invention, the only difference between this embodiment and Example 1 is:
所述防脱宠物洗护凝胶组合物包括以下重量百分比的组分：10％的辛基十二烷醇、2.5％的PEG-40氢化蓖麻油、2％的丙三醇、4％的马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物、8％的银杏叶提取物、0.5％的烟酰胺、0.3％％维生素E、0.2％的茉莉花精油；还包括0.5％麝香草酚、0.5％山梨酸和0.3％二氯海英的作为抑菌螨组分和余量的去离子水，柠檬酸作为pH调节剂，调节pH为6.7。The anti-shedding pet care gel composition includes the following components by weight: 10% octyldodecanol, 2.5% PEG-40 hydrogenated castor oil, 2% glycerol, 4% horseradish Lenic anhydride-styrene-sodium methacrylate sulfonate polymer, 8% Ginkgo leaf extract, 0.5% nicotinamide, 0.3% vitamin E, 0.2% jasmine essential oil; also includes 0.5% thymol, 0.5 % sorbic acid and 0.3% dichlorohydanine are used as antibacterial mite components and the balance is deionized water, and citric acid is used as a pH adjuster to adjust the pH to 6.7.
实施例7Example 7
作为本发明实施例的一种防脱宠物洗护组合物，本实施例与实施例1的唯一区别为：As an anti-shedding pet care composition according to an embodiment of the present invention, the only difference between this embodiment and Example 1 is:
所述防脱宠物洗护凝胶组合物包括以下重量百分比的组分：11％的辛基十二烷醇、2.5％的PEG-40氢化蓖麻油、4％的丙三醇、4％的马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物、8％的银杏叶提取物、0.5％的烟酰胺、0.3％％维生素E、0.2％的茉莉花精油；还包括0.5％麝香草酚、0.5％山梨酸和0.3％二氯海英的作为抑菌螨组分和余量的去离子水，柠檬酸作为pH调节剂，调节pH为6.7。The anti-shedding pet care gel composition includes the following components by weight: 11% octyldodecanol, 2.5% PEG-40 hydrogenated castor oil, 4% glycerin, 4% horseradish Lenic anhydride-styrene-sodium methacrylate sulfonate polymer, 8% Ginkgo leaf extract, 0.5% nicotinamide, 0.3% vitamin E, 0.2% jasmine essential oil; also includes 0.5% thymol, 0.5 % sorbic acid and 0.3% dichlorohydanine are used as antibacterial mite components and the balance is deionized water, and citric acid is used as a pH adjuster to adjust the pH to 6.7.
对比例1Comparative example 1
作为本发明对比例的一种防脱宠物洗护组合物，本对比例与实施例1的唯一区别为：不包含丙三醇，组分重量由去离子水替换。As an anti-shedding pet care composition as a comparative example of the present invention, the only difference between this comparative example and Example 1 is that it does not contain glycerol, and the component weight is replaced by deionized water.
对比例2Comparative example 2
作为本发明对比例的一种防脱宠物洗护组合物，本对比例与实施例1的唯一区别为：不包含氢化蓖麻油，组分重量由去离子水替换。As an anti-shedding pet care composition as a comparative example of the present invention, the only difference between this comparative example and Example 1 is that it does not contain hydrogenated castor oil, and the component weight is replaced by deionized water.
对比例3Comparative example 3
作为本发明对比例的一种防脱宠物洗护组合物，本对比例与实施例1的唯一区别为：不包含辛基十二烷醇，组分重量由去离子水替换。As an anti-shedding pet care composition as a comparative example of the present invention, the only difference between this comparative example and Example 1 is that it does not contain octyldodecanol, and the component weight is replaced by deionized water.
对比例4Comparative example 4
作为本发明对比例的一种防脱宠物洗护组合物，本对比例与实施例1的唯一区别为：不包含马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物，组分重量由去离子水替换。As an anti-shedding pet care composition as a comparative example of the present invention, the only difference between this comparative example and Example 1 is that it does not contain maleic anhydride-styrene-sodium methacrylate sulfonate polymer, and the weight of the components is: Replace with deionized water.
对比例5Comparative example 5
作为本发明对比例的一种防脱宠物洗护组合物，本对比例与实施例1的唯一区别为：由十二烷基磺酸钠替换马来酸酐-苯乙烯-甲基丙烯磺酸钠聚合物。As a comparative example of an anti-shedding pet care composition of the present invention, the only difference between this comparative example and Example 1 is that sodium dodecyl sulfate replaces sodium maleic anhydride-styrene-methacrylene sulfonate. polymer.
实验方法experimental method
一、微乳粒径及粒径分布的检测。1. Detection of microemulsion particle size and particle size distribution.
利用Zetasizer-nano-zs90测防脱宠物洗护组合物的微乳粒径分布，结果如表1所示。Zetasizer-nano-zs90 was used to measure the microemulsion particle size distribution of the anti-shedding pet care composition. The results are shown in Table 1.
表1防脱宠物洗护组合物的微乳粒径分布Table 1 Microemulsion particle size distribution of anti-shedding pet care composition
二、去污能力2. Decontamination ability
参照GB/T13174-2021，用光学白度法测定实施例1-7、对比例1-5分别对JB-02蛋白污布、JB-03皮脂污布的去污能力。将污布裁剪成6×6cm的方片，每组试片至少有4片，用于一个样品去污性能的测定，用白度计在457nm下测定污布洗涤前后的白度值。Referring to GB/T13174-2021, the optical whiteness method was used to measure the decontamination ability of Examples 1-7 and Comparative Examples 1-5 on JB-02 protein stain cloth and JB-03 sebum stain cloth respectively. Cut the dirty cloth into 6×6cm square pieces. Each set of test pieces has at least 4 pieces, which are used to measure the decontamination performance of one sample. Use a whiteness meter to measure the whiteness value of the dirty cloth before and after washing at 457nm.
洗前白度以试片正反两面各取两个点(处于同一面的两点呈中心对称)，测定白度，以4片试片的平均白度值作为该试片的洗前白度，记作F1。Pre-wash whiteness: Take two points on each side of the test piece (the two points on the same side are centrally symmetrical) to measure the whiteness. The average whiteness value of the four test pieces is used as the pre-wash whiteness of the test piece. , recorded as F1.
称取3g样品，用250mg/kg的硬水溶解并定容至1000mL。Weigh 3g of sample, dissolve it in 250mg/kg hard water and adjust the volume to 1000mL.
预热立式去污试验机至30±1℃，将配制好的洗涤剂投入到洗涤实验缸中，加入污布，注意布片不能重叠在一起，启动搅拌，搅拌速度为5r/min，洗涤时间为10min。取出洗涤过的污布，用去离子水冲洗干净后置于搪瓷盘中自然晾干。取洗涤并晾干的污布，按照洗前白度的测定方法，测定洗后白度，记作F2；Preheat the vertical decontamination testing machine to 30±1℃, put the prepared detergent into the washing experimental tank, add dirty cloth, be careful that the cloth pieces cannot overlap each other, start stirring, the stirring speed is 5r/min, and wash The time is 10min. Take out the washed dirty cloth, rinse it with deionized water and place it in an enamel plate to dry naturally. Take the washed and dried dirty cloth and measure the whiteness after washing according to the method for measuring the whiteness before washing, and record it as F2;
污布的去污值(R)可以由下式表示：The stain removal value (R) of dirty cloth can be expressed by the following formula:
R＝∑(F2-F1)/n；式中，F1指代试片洗涤之前的光谱反射率(％)；F2指代洗涤之后的光谱反射率(％)；n为每组试片的有效数量。R=∑(F2-F1)/n; in the formula, F1 refers to the spectral reflectance (%) of the test piece before washing; F2 refers to the spectral reflectance (%) after washing; n is the effective value of each group of test pieces. quantity.
P＝R/R0，其中R0为立白洗洁精(生产许可号粤XK16-114-00011)在相同条件下的去污能力。P=R/R0, where R0 is the decontamination ability of Liby dishwashing liquid (Production License No. Guangdong XK16-114-00011) under the same conditions.
表2防脱宠物洗护组合物的去污能力Table 2 Decontamination ability of anti-shedding pet care compositions
由表1、表2的结果可知，本发明的防脱宠物洗护组合物能够形成均匀的，平均粒径在20～35nm范围内微乳，在几乎不搅拌、不揉搓的时候，也具有高效的去污能力，能够更好的、更均匀的分布在宠物身体表面，而且微乳可以将宠物身体表面的油污、糖类、蛋白质等溶解，起到去污效果，且微乳粒径小，均一，直接冲洗即具有良好的去污效果，冲洗无残留，避免了宠物洗涤剂使用时的反复揉搓，在不揉搓的条件下即具有高效的去污能力，通过避免反复揉搓减少了宠物的不适和脱毛。It can be seen from the results in Table 1 and Table 2 that the anti-shedding pet care composition of the present invention can form a uniform microemulsion with an average particle size in the range of 20 to 35 nm, and has high efficiency even when there is almost no stirring or rubbing. The decontamination ability of the microemulsion can be better and more evenly distributed on the surface of the pet's body, and the microemulsion can dissolve oil, sugar, protein, etc. on the surface of the pet's body to achieve a decontamination effect, and the microemulsion has a small particle size. Uniform and direct rinsing, it has a good decontamination effect. There is no residue when rinsing, which avoids repeated rubbing when using pet detergent. It has efficient decontamination ability without rubbing, and reduces pet discomfort by avoiding repeated rubbing. and hair removal.
最后所应当说明的是，以上实施例仅用以说明本发明的技术方案而非对本发明保护范围的限制，尽管参照较佳实施例对本发明作了详细说明，本领域的普通技术人员应当理解，可以对本发明的技术方案进行修改或者等同替换，而不脱离本发明技术方案的实质和范围。Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention and do not limit the protection scope of the present invention. Although the present invention has been described in detail with reference to the preferred embodiments, those of ordinary skill in the art should understand that The technical solution of the present invention may be modified or equivalently substituted without departing from the essence and scope of the technical solution of the present invention.
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| CN202310963331.4ACN117180145A (en) | 2023-08-01 | 2023-08-01 | Anti-drop pet washing and caring composition and preparation method thereof |
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| CN103554362A (en)* | 2013-10-18 | 2014-02-05 | 中国科学院广州化学研究所 | Maleic anhydride copolymer dispersing agent as well as preparation method and application thereof |
| CN116421505A (en)* | 2023-06-09 | 2023-07-14 | 广州汇芬生物科技有限公司 | Antibacterial mite-killing nanoemulsion for pets and preparation method thereof |
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103554362A (en)* | 2013-10-18 | 2014-02-05 | 中国科学院广州化学研究所 | Maleic anhydride copolymer dispersing agent as well as preparation method and application thereof |
| CN116421505A (en)* | 2023-06-09 | 2023-07-14 | 广州汇芬生物科技有限公司 | Antibacterial mite-killing nanoemulsion for pets and preparation method thereof |
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