CN115969715A - Radiation-proof composition, preparation method and application thereof - Google Patents

Abstract

The invention provides a radiation-proof composition which comprises the following raw materials in parts by weight: 1 to 20 parts of stannic oxide, 1 to 30 parts of titanium dioxide and 50 to 85 parts of nephrite powder. According to the invention, nephrite powder is used as a carrier, and the composition finally prepared by coating and combining tin dioxide and titanium dioxide has good radiation protection capability.

Description

Translated fromChinese

一种防辐射组合物、其制备方法和应用A kind of anti-radiation composition, its preparation method and application

技术领域technical field

本发明涉及化妆品技术领域，尤其是涉及一种防辐射组合物、其制备方法和应用。The invention relates to the technical field of cosmetics, in particular to a radiation protection composition, its preparation method and application.

背景技术Background technique

太阳辐射指到达地球表面的连续电磁辐射，太阳辐射的波长范围在0.2～3μm之间，涵盖紫外线、可见光、近红外线，在到达地球表面的太阳辐射中，长时间照射会引起皮肤晒黑、晒伤，甚至引发皮肤癌等问题。而紫外线是众所周知的危害之一，而太阳辐射中可见光占40％-50％，分成蓝光(400nm～500nm)、绿光(500nm～600nm)和红光(600～700nm)，其中蓝光是可见光中的高能量波段，对皮肤也能造成类似紫外线引起的皮肤损伤，包括引起皮肤光老化、造成氧化应激、损害皮肤屏障、促进皮肤持续性色素沉着、导致皮肤干燥等。除太阳光外，生活中各种数字设备(包括手机、笔记本电脑等)发出的蓝光，也会对皮肤产生不良影响。Solar radiation refers to the continuous electromagnetic radiation that reaches the earth's surface. The wavelength range of solar radiation is between 0.2 and 3 μm, covering ultraviolet rays, visible light, and near-infrared rays. Among the solar radiation that reaches the earth's surface, long-term exposure can cause skin tanning and tanning. injury, and even lead to problems such as skin cancer. Ultraviolet light is one of the well-known hazards, and visible light accounts for 40%-50% of solar radiation, which is divided into blue light (400nm-500nm), green light (500nm-600nm) and red light (600-700nm), wherein blue light is the visible light. The high-energy band of the UV rays can also cause skin damage similar to that caused by ultraviolet rays, including causing skin photoaging, causing oxidative stress, damaging the skin barrier, promoting persistent skin pigmentation, and causing skin dryness. In addition to sunlight, the blue light emitted by various digital devices in life (including mobile phones, laptops, etc.) can also have adverse effects on the skin.

因此，开发一种可以防辐射组合物是非常必要的。Therefore, it is very necessary to develop a radiation-proof composition.

发明内容Contents of the invention

有鉴于此，本发明要解决的技术问题在于提供一种组合物，本发明提供的组合物具有良好的防辐射效果。In view of this, the technical problem to be solved by the present invention is to provide a composition, which has good radiation protection effect.

本发明一种防辐射组合物，包括如下重量份的原料：A radiation protection composition of the present invention comprises the following raw materials in parts by weight:

二氧化锡1～20份，二氧化钛1～30份，软玉粉50～85份。1-20 parts of tin dioxide, 1-30 parts of titanium dioxide, 50-85 parts of nephrite jade powder.

优选的，包括如下重量份的原料：Preferably, the following raw materials are included in parts by weight:

二氧化锡5～20份，二氧化钛10～25份，软玉粉55～85份。5-20 parts of tin dioxide, 10-25 parts of titanium dioxide, 55-85 parts of nephrite jade powder.

优选的，包括如下重量份的原料：Preferably, the following raw materials are included in parts by weight:

二氧化锡8～18份，二氧化钛15～25份，软玉粉55～75份。8-18 parts of tin dioxide, 15-25 parts of titanium dioxide, and 55-75 parts of nephrite jade powder.

本发明提供了一种防辐射组合物的制备方法，包括如下步骤：The invention provides a preparation method of a radiation protection composition, comprising the steps of:

二氧化钛、二氧化锡和水混合，再加入软玉粉，混合研磨，干燥，粉碎，即得。Mix titanium dioxide, tin dioxide and water, add nephrite jade powder, mix and grind, dry and pulverize to obtain.

优选的，所述研磨为100～120r/min的速度下研磨6～8h；Preferably, the grinding is performed at a speed of 100-120 r/min for 6-8 hours;

所述干燥具体为100℃干燥；The drying is specifically drying at 100°C;

所述粉碎具体为气流粉碎后过100～200目筛。The pulverization is specifically jet pulverization and passing through a 100-200 mesh sieve.

本发明提供了上述技术方案所述的组合物在制备防辐射产品中的应用。The present invention provides the application of the composition described in the above technical solution in the preparation of radiation protection products.

本发明提供了一种防辐射产品，包括上述技术方案任意一项所述的组合物。The present invention provides a radiation protection product, comprising the composition described in any one of the above technical solutions.

优选的，所述防辐射产品包括散粉、粉饼、膏霜或乳液。Preferably, the radiation protection product includes loose powder, pressed powder, cream or lotion.

本发明提供了一种防辐射散粉，包括如下重量份的原料：The invention provides a kind of anti-radiation powder, comprising the following raw materials in parts by weight:

优选的，所述肤感调节剂包括硅石、聚甲基丙烯酸、尼龙或氮化硼中的一种或几种；Preferably, the skin feel modifier includes one or more of silica, polymethacrylic acid, nylon or boron nitride;

所述皮肤调理剂包括聚二甲基硅氧烷或角鲨烷。Such skin conditioning agents include dimethicone or squalane.

与现有技术相比，本发明提供了一种防辐射组合物，包括如下重量份的原料：二氧化锡1～20份，二氧化钛1～30份，软玉粉50～85份。本发明采用软玉粉作为载体，采用二氧化锡和二氧化钛包覆组合最终制备的组合物防辐射能力好。Compared with the prior art, the invention provides a radiation protection composition, which includes the following raw materials in parts by weight: 1-20 parts of tin dioxide, 1-30 parts of titanium dioxide, and 50-85 parts of nephrite jade powder. The invention adopts nephrite jade powder as a carrier, and adopts tin dioxide and titanium dioxide to coat and combine to finally prepare a composition with good radiation protection ability.

附图说明Description of drawings

图1为实施例1～3、对比例1～4的抗辐射效果对比图；Fig. 1 is the contrast figure of anti-radiation effect of embodiment 1～3, comparative example 1～4;

图2为实施例2/4和对比例7的防辐射结果图。Fig. 2 is the radiation protection result figure of embodiment 2/4 and comparative example 7.

具体实施方式Detailed ways

本发明提供了一种防辐射组合物、其制备方法和应用，本领域技术人员可以借鉴本文内容，适当改进工艺参数实现。特别需要指出的是，所有类似的替换和改动对本领域技术人员来说是显而易见的，它们都属于本发明保护的范围。本发明的方法及应用已经通过较佳实施例进行了描述，相关人员明显能在不脱离本发明内容、精神和范围内对本文的方法和应用进行改动或适当变更与组合，来实现和应用本发明技术。The invention provides a radiation protection composition, its preparation method and application, and those skilled in the art can learn from the content of this article and appropriately improve the process parameters to realize it. In particular, it should be pointed out that all similar substitutions and modifications are obvious to those skilled in the art, and they all belong to the protection scope of the present invention. The method and application of the present invention have been described through preferred embodiments, and relevant personnel can obviously make changes or appropriate changes and combinations to the method and application herein without departing from the content, spirit and scope of the present invention to realize and apply the present invention Invent technology.

本发明一种防辐射组合物，包括如下重量份的原料：A radiation protection composition of the present invention comprises the following raw materials in parts by weight:

二氧化锡1～20份，二氧化钛1～30份，软玉粉50～85份。1-20 parts of tin dioxide, 1-30 parts of titanium dioxide, 50-85 parts of nephrite jade powder.

本发明提供的防辐射组合物包括二氧化锡1～20重量份；更优选包括二氧化锡5～20重量份；最优选包括二氧化锡8～18重量份；特别优选包括二氧化锡10～16重量份。The anti-radiation composition provided by the present invention comprises 1～20 parts by weight of tin dioxide; more preferably comprises 5～20 parts by weight of tin dioxide; most preferably comprises 8～18 parts by weight of tin dioxide; particularly preferably comprises 10～20 parts by weight of tin dioxide 16 parts by weight.

本发明提供的防辐射组合物包括二氧化钛1～30重量份；优选包括10～25重量份；更优选包括15～25重量份；特别优选包括20～25重量份。The anti-radiation composition provided by the present invention includes 1-30 parts by weight of titanium dioxide; preferably 10-25 parts by weight; more preferably 15-25 parts by weight; especially preferably 20-25 parts by weight.

本发明提供的防辐射组合物包括软玉粉50～85重量份；优选包括软玉粉55～85重量份；更优选包括软玉粉55～75重量份；特别优选包括软玉粉60～70重量份。The anti-radiation composition provided by the present invention includes 50-85 parts by weight of nephrite jade powder; preferably includes 55-85 parts by weight of nephrite jade powder; more preferably includes 55-75 parts by weight of nephrite jade powder; particularly preferably includes 60-70 parts by weight of nephrite jade powder parts by weight.

在本发明其中一部分优选实施方式中，包括如下重量份的原料：In one of the preferred embodiments of the present invention, the following raw materials are included in parts by weight:

二氧化锡5～20份，二氧化钛10～25份，软玉粉55～85份。5-20 parts of tin dioxide, 10-25 parts of titanium dioxide, 55-85 parts of nephrite jade powder.

在本发明其中一部分优选实施方式中，包括如下重量份的原料：In one of the preferred embodiments of the present invention, the following raw materials are included in parts by weight:

二氧化锡8～18份，二氧化钛15～25份，软玉粉55～75份。8-18 parts of tin dioxide, 15-25 parts of titanium dioxide, and 55-75 parts of nephrite jade powder.

在本发明其中一部分优选实施方式中，包括如下重量份的原料：In one of the preferred embodiments of the present invention, the following raw materials are included in parts by weight:

二氧化锡10～16份，二氧化钛20～25份，软玉粉60～70份。10-16 parts of tin dioxide, 20-25 parts of titanium dioxide, 60-70 parts of nephrite jade powder.

在本发明其中一部分优选实施方式中，包括如下重量份的原料：In one of the preferred embodiments of the present invention, the following raw materials are included in parts by weight:

二氧化锡10～13份，二氧化钛22～25份，软玉粉62～68份。10-13 parts of tin dioxide, 22-25 parts of titanium dioxide, 62-68 parts of nephrite jade powder.

在本发明其中一个优选实施方式中，包括如下重量份的原料：In one of the preferred embodiments of the present invention, the following raw materials are included in parts by weight:

二氧化锡20份，二氧化钛20份，软玉粉60份。20 parts of tin dioxide, 20 parts of titanium dioxide, 60 parts of nephrite jade powder.

在本发明防辐射组合物的试验中，本发明采用二氧化锡、二氧化钛和云母粉替换本发明的组分，结果显示，本发明的组合物属于相互关联的整体技术方案，其效果优于对比例，本发明的二氧化锡、二氧化钛和软玉粉组合具有良好的防辐射效果，替换组分或者缺少组分导致效果降低、本发明提供了一种防辐射组合物的制备方法，包括如下步骤：In the test of the anti-radiation composition of the present invention, the present invention adopts tin dioxide, titanium dioxide and mica powder to replace the components of the present invention, and the results show that the composition of the present invention belongs to an interrelated overall technical scheme, and its effect is better than that of Ratio, the combination of tin dioxide, titanium dioxide and nephrite jade powder of the present invention has a good radiation protection effect, and replacement of components or lack of components leads to reduced effect. The invention provides a preparation method of radiation protection composition, comprising the following steps :

二氧化钛、二氧化锡和水混合，再加入软玉粉，混合研磨，干燥，粉碎，即得。Mix titanium dioxide, tin dioxide and water, add nephrite jade powder, mix and grind, dry and pulverize to obtain.

本发明提供的防辐射组合物的制备方法首先将二氧化钛、二氧化锡和水混合，混合液呈浓稠状。The preparation method of the anti-radiation composition provided by the invention firstly mixes titanium dioxide, tin dioxide and water, and the mixed liquid is thick.

再加入软玉粉，混合研磨，干燥，粉碎，即得。Then add nephrite jade powder, mix and grind, dry and pulverize.

本发明对于上述组分和配比已经有了清楚的描述，在此不再赘述。The present invention has clearly described the above-mentioned components and proportions, and will not repeat them here.

本发明所述研磨为100～120r/min的速度下研磨6～8h；所述干燥具体为100℃干燥；所述粉碎具体为气流粉碎后过100～200目筛。The grinding in the present invention is grinding at a speed of 100-120 r/min for 6-8 hours; the drying is specifically drying at 100° C.; the pulverizing is specifically jet pulverizing and passing through a 100-200 mesh sieve.

本发明提供了上述技术方案所述的组合物在制备防辐射产品中的应用。The present invention provides the application of the composition described in the above technical solution in the preparation of radiation protection products.

本发明提供了一种防辐射产品，包括上述技术方案任意一项所述的组合物。The present invention provides a radiation protection product, comprising the composition described in any one of the above technical solutions.

本发明所述防辐射产品包括散粉、粉饼、膏霜或乳液。The anti-radiation product of the present invention includes loose powder, pressed powder, cream or lotion.

本发明上述产品还包括化妆品领域常见的配料，本发明对此不进行限定。The above-mentioned products of the present invention also include common ingredients in the field of cosmetics, which are not limited in the present invention.

本发明提供了一种防辐射散粉，包括如下重量份的原料：The invention provides a kind of anti-radiation powder, comprising the following raw materials in parts by weight:

在本发明其中一部分优选实施方式中，所述防辐射散粉，包括如下重量份的原料：In some preferred embodiments of the present invention, the radiation-proof loose powder includes the following raw materials in parts by weight:

其中，所述肤感调节剂包括硅石、聚甲基丙烯酸、尼龙或氮化硼中的一种或几种。Wherein, the skin feeling modifier includes one or more of silica, polymethacrylic acid, nylon or boron nitride.

所述皮肤调理剂包括聚二甲基硅氧烷或角鲨烷。Such skin conditioning agents include dimethicone or squalane.

本发明还提供了一种防辐射散粉的制备方法，包括如下步骤：The present invention also provides a preparation method of anti-radiation loose powder, comprising the steps of:

将上述技术方案任意一项所述的组合物粉碎、分散，加入防腐剂、皮肤调理剂混合加热，粉碎。Pulverize and disperse the composition described in any one of the above technical solutions, add preservatives and skin conditioners, mix and heat, and pulverize.

本发明所述分散优选为在25000r/min的条件下，分散5秒，两次，直至均匀单一颜色的粉末。The dispersing in the present invention is preferably under the condition of 25000r/min, dispersing for 5 seconds twice, until the powder of uniform single color.

所述加热温度优选为80℃。The heating temperature is preferably 80°C.

得到粉末后，用环五聚二甲基硅氧烷溶剂稀释100倍得到标准溶液，漩涡振荡仪在500r/min条件下，均匀分散3min，取溶液使用分光光度仪测定辐射(在200nm-800nm条件下)透过数值。After the powder is obtained, it is diluted 100 times with a cyclopentasiloxane solvent to obtain a standard solution, and the vortex oscillator is uniformly dispersed for 3 minutes under the condition of 500r/min, and the solution is taken to measure the radiation using a spectrophotometer (under the condition of 200nm-800nm below) through the value.

本发明提供了一种防辐射组合物，包括如下重量份的原料：二氧化锡1～20份，二氧化钛1～30份，软玉粉50～85份。本发明采用软玉粉作为载体，采用二氧化锡和二氧化钛包覆组合最终制备的组合物防辐射能力好。The invention provides a radiation protection composition, which comprises the following raw materials in parts by weight: 1-20 parts of tin dioxide, 1-30 parts of titanium dioxide, and 50-85 parts of nephrite jade powder. The invention adopts nephrite jade powder as a carrier, and adopts tin dioxide and titanium dioxide to coat and combine to finally prepare a composition with good radiation protection ability.

为了进一步说明本发明，以下结合实施例对本发明提供的一种防辐射组合物、其制备方法和应用进行详细描述。In order to further illustrate the present invention, a radiation protection composition provided by the present invention, its preparation method and application are described in detail below in conjunction with examples.

实施例1Example 1

一种二氧化锡二氧化钛复合软玉粉材料制备，包括以下按重量份计的原料：二氧化锡10份，二氧化钛10份，软玉粉80份。A tin dioxide-titanium dioxide composite nephrite jade powder material is prepared, comprising the following raw materials in parts by weight: 10 parts of tin dioxide, 10 parts of titanium dioxide, and 80 parts of nephrite jade powder.

上述的二氧化锡二氧化钛复合软玉粉材料方法，包括以下步骤：The above-mentioned tin dioxide titanium dioxide composite nephrite jade powder material method comprises the following steps:

1)加入去离子水混合二氧化锡，二氧化钛，搅拌均匀，使得水与二氧化锡二氧化钛粉体混合后呈浓稠状。1) Add deionized water to mix tin dioxide and titanium dioxide, and stir evenly, so that the mixture of water and tin dioxide and titanium dioxide powder becomes thick.

2)再加入软玉粉，在150r/min的速度下研磨8h，然后在100℃下干燥至水分完全挥发，气流粉碎后通过100～200目筛网，得到最终复合材料。2) Add nephrite jade powder, grind at a speed of 150r/min for 8h, and then dry at 100°C until the water is completely evaporated, and pass through a 100-200 mesh screen after jet milling to obtain the final composite material.

实施例2Example 2

一种二氧化锡二氧化钛复合软玉粉材料制备，包括以下按重量份计的原料：二氧化锡20份，二氧化钛20份，软玉粉60份。A tin dioxide-titanium dioxide composite nephrite jade powder material is prepared, comprising the following raw materials in parts by weight: 20 parts of tin dioxide, 20 parts of titanium dioxide, and 60 parts of nephrite jade powder.

上述的二氧化锡二氧化钛复合软玉粉材料方法，包括以下步骤：The above-mentioned tin dioxide titanium dioxide composite nephrite jade powder material method comprises the following steps:

1)加入去离子水混合二氧化锡，二氧化钛，搅拌均匀，使得水与二氧化锡二氧化钛粉体混合后呈浓稠状。1) Add deionized water to mix tin dioxide and titanium dioxide, and stir evenly, so that the mixture of water and tin dioxide and titanium dioxide powder becomes thick.

2)再加入软玉粉，在150r/min的速度下研磨8h，然后在100℃下干燥至水分完全挥发，气流粉碎后通过100～200目筛网，得到最终复合材料。2) Add nephrite jade powder, grind at a speed of 150r/min for 8h, and then dry at 100°C until the water is completely evaporated, and pass through a 100-200 mesh screen after jet milling to obtain the final composite material.

实施例3Example 3

一种二氧化锡二氧化钛复合软玉粉材料制备，包括以下按重量份计的原料：二氧化锡20份，二氧化钛30份，软玉粉50份。The preparation of a tin dioxide-titanium dioxide composite nephrite jade powder material comprises the following raw materials in parts by weight: 20 parts of tin dioxide, 30 parts of titanium dioxide, and 50 parts of nephrite jade powder.

上述的二氧化锡二氧化钛复合软玉粉材料方法，包括以下步骤：The above-mentioned tin dioxide titanium dioxide composite nephrite jade powder material method comprises the following steps:

1)加入去离子水混合二氧化锡，二氧化钛，搅拌均匀，使得水与二氧化锡二氧化钛粉体混合后呈浓稠状。1) Add deionized water to mix tin dioxide and titanium dioxide, and stir evenly, so that the mixture of water and tin dioxide and titanium dioxide powder becomes thick.

2)再加入软玉粉，在150r/min的速度下研磨8h，然后在100℃下干燥至水分完全挥发，气流粉碎后通过100～200目筛网，得到最终复合材料。2) Add nephrite jade powder, grind at a speed of 150r/min for 8h, and then dry at 100°C until the water is completely evaporated, and pass through a 100-200 mesh screen after jet milling to obtain the final composite material.

对比例1Comparative example 1

同质量的纯二氧化钛，其余同实施例1。The pure titanium dioxide of same quality, all the other are with embodiment 1.

对比例2Comparative example 2

同质量的纯二氧化锡，其余同实施例1。The pure tin dioxide of same quality, all the other are with embodiment 1.

对比例3Comparative example 3

同质量的纯软玉粉，其余同实施例1。The pure nephrite jade powder of same quality, all the other are with embodiment 1.

对比例4Comparative example 4

一种二氧化锡二氧化钛复合云母材料制备，包括以下按重量份计的原料：二氧化锡20份，二氧化钛30份，云母粉50份A preparation of tin dioxide-titanium dioxide composite mica material, comprising the following raw materials in parts by weight: 20 parts of tin dioxide, 30 parts of titanium dioxide, 50 parts of mica powder

上述的二氧化锡二氧化钛复合云母粉材料方法，包括以下步骤：The above-mentioned tin dioxide-titanium dioxide composite mica powder material method comprises the following steps:

1)加入去离子水混合二氧化锡，二氧化钛，搅拌均匀，使得水与二氧化锡二氧化钛粉体混合后呈浓稠状。1) Add deionized water to mix tin dioxide and titanium dioxide, and stir evenly, so that the mixture of water and tin dioxide and titanium dioxide powder becomes thick.

2)再加入与软玉粉同粒径的云母粉，在150r/min的速度下研磨8h，然后在100℃下干燥至水分完全挥发，气流粉碎后通过100～200目筛网，得到最终复合材料。2) Add mica powder with the same particle size as nephrite jade powder, grind at a speed of 150r/min for 8 hours, then dry at 100°C until the water is completely evaporated, and pass through a 100-200 mesh screen after airflow crushing to obtain the final compound Material.

对比例5Comparative example 5

一种二氧化锡二氧化钛复合云母材料制备，包括以下按重量份计的原料：二氧化锡20份，二氧化钛20份，云母粉60份。A tin dioxide-titanium dioxide composite mica material is prepared, comprising the following raw materials in parts by weight: 20 parts of tin dioxide, 20 parts of titanium dioxide, and 60 parts of mica powder.

上述的二氧化锡二氧化钛复合云母粉材料方法，包括以下步骤：The above-mentioned tin dioxide-titanium dioxide composite mica powder material method comprises the following steps:

1)加入去离子水混合二氧化锡，二氧化钛，搅拌均匀，使得水与二氧化锡二氧化钛粉体混合后呈浓稠状。1) Add deionized water to mix tin dioxide and titanium dioxide, and stir evenly, so that the mixture of water and tin dioxide and titanium dioxide powder becomes thick.

2)再加入与软玉粉同粒径的云母粉，在150r/min的速度下研磨8h，然后在100℃下干燥至水分完全挥发，气流粉碎后通过100～200目筛网，得到最终复合材料。2) Add mica powder with the same particle size as nephrite jade powder, grind at a speed of 150r/min for 8 hours, then dry at 100°C until the water is completely evaporated, and pass through a 100-200 mesh screen after airflow crushing to obtain the final compound Material.

对比例6Comparative example 6

一种二氧化锡二氧化钛复合软玉粉材料制备，包括以下按重量份计的原料：二氧化锡30份，二氧化钛40份，软玉粉30份。A tin dioxide-titanium dioxide composite nephrite jade powder material is prepared, comprising the following raw materials in parts by weight: 30 parts of tin dioxide, 40 parts of titanium dioxide, and 30 parts of nephrite jade powder.

上述的二氧化锡二氧化钛复合软玉粉材料方法，包括以下步骤：The above-mentioned tin dioxide titanium dioxide composite nephrite jade powder material method comprises the following steps:

1)加入去离子水混合二氧化锡，二氧化钛，搅拌均匀，使得水与二氧化锡二氧化钛粉体混合后呈浓稠状。1) Add deionized water to mix tin dioxide and titanium dioxide, and stir evenly, so that the mixture of water and tin dioxide and titanium dioxide powder becomes thick.

2)再加入软玉粉，在150r/min的速度下研磨8h，然后在100℃下干燥至水分完全挥发，气流粉碎后通过100～200目筛网，得到最终复合材料。2) Add nephrite jade powder, grind at a speed of 150r/min for 8h, and then dry at 100°C until the water is completely evaporated, and pass through a 100-200 mesh screen after jet milling to obtain the final composite material.

验证例Verification example

实施例1～3、对比例1～5的结果如图1所述，图1为实施例1～3、对比例1～6的的抗辐射效果对比图；由图可以看出实施例2的抗辐射能力远优于对比例1～3，证明组合的效果优于未组合；而对比例4～5，可以看出软玉粉组合优于云母组合。而对比例6，可以看出优选比例的三者关系能增效防辐射的能力Embodiment 1～3, the result of comparative example 1～5 are as described in Figure 1, and Fig. 1 is the anti-radiation effect comparative figure of embodiment 1～3, comparative example 1～6; Can find out that embodiment 2 is as shown in the figure The anti-radiation ability is much better than that of Comparative Examples 1-3, which proves that the effect of combination is better than that of no combination; and Comparative Examples 4-5, it can be seen that the combination of nephrite jade powder is better than that of mica. And comparative example 6, it can be seen that the three relations of the preferred ratio can increase the radiation protection ability

实施例4Example 4

A)将实施例二3～20份，硅石、聚甲基丙烯酸、尼龙、氮化硼等肤感调节剂10～80份置于高速粉碎机中，在25000R/min的条件下，分散5秒，两次，直至均匀单一颜色的粉末A) Put 3-20 parts of Example 2, 10-80 parts of skin feeling modifiers such as silica, polymethacrylic acid, nylon, boron nitride, etc. into a high-speed pulverizer, and disperse for 5 seconds under the condition of 25000 R/min , twice, until a uniform single-color powder

B)将防腐剂1～2份，聚二甲基硅氧烷、角鲨烷等皮肤调理剂1～10份在80℃加热，之后倒入含有A的高速粉碎机中，在25000R/min的条件下，分散5秒，两次，直至均匀，无可见的油点为止。B) Heat 1 to 2 parts of preservatives, 1 to 10 parts of skin conditioning agents such as polydimethylsiloxane and squalane at 80°C, and then pour them into a high-speed pulverizer containing A. Under the same conditions, disperse for 5 seconds, twice, until it is uniform and there is no visible oil point.

C)用环五聚二甲基硅氧烷溶剂稀释100倍得到标准溶液，漩涡振荡仪在500r/min条件下，均匀分散3min，取溶液使用分光光度仪测定辐射(在200nm-800nm条件下)透过数值，记作样品一。C) Dilute 100 times with cyclopentasiloxane solvent to obtain a standard solution, vortex shaker under the condition of 500r/min, disperse evenly for 3min, take the solution and use a spectrophotometer to measure the radiation (under the condition of 200nm-800nm) The value passed through is recorded as sample 1.

对比例7Comparative example 7

A)将软玉粉3～20份，硅石、聚甲基丙烯酸、尼龙、氮化硼等肤感调节剂10～80份置于高速粉碎机中，在25000R/min的条件下，分散5秒，两次，直至均匀单一颜色的粉末A) Put 3-20 parts of nephrite jade powder, 10-80 parts of skin feeling modifiers such as silica, polymethacrylic acid, nylon, boron nitride, etc. into a high-speed pulverizer, and disperse for 5 seconds under the condition of 25000 R/min , twice, until a uniform single-color powder

B)将防腐剂1份，聚二甲基硅氧烷、角鲨烷等皮肤调理剂1～5份在80℃加热，之后倒入含有A的高速粉碎机中，在25000R/min的条件下，分散5秒，两次，直至均匀，无可见的油点为止。B) Heat 1 part of preservative, 1 to 5 parts of skin conditioning agents such as polydimethylsiloxane and squalane at 80°C, and then pour them into the high-speed pulverizer containing A, under the condition of 25000R/min , disperse for 5 seconds, twice, until uniform, no visible oil spots.

C)用环五聚二甲基硅氧烷溶剂稀释100倍得到标准溶液，漩涡振荡仪在500r/min条件下，均匀分散3min，取溶液使用分光光度仪测定辐射(在200nm-800nm条件下)透过数值，记作样品2。C) Dilute 100 times with cyclopentasiloxane solvent to obtain a standard solution, vortex shaker under the condition of 500r/min, disperse evenly for 3min, take the solution and use a spectrophotometer to measure the radiation (under the condition of 200nm-800nm) The transmission value is referred to as sample 2.

验证例2Verification example 2

实施例4和实施例2和对比例7的结果如图2所示，图2为实施例2/4和对比例7的防辐射结果图。从图2数据可以看出，实施例4(组合后的软玉粉)抵御辐射的能力远高于对比例7(未组合的软玉粉)，且实施例4即使在添加量为(3～20％)时依旧能维持像实施例2的抗辐射能力。The results of Example 4, Example 2 and Comparative Example 7 are shown in Figure 2, and Figure 2 is the radiation protection results of Example 2/4 and Comparative Example 7. As can be seen from the data in Fig. 2, the ability to resist radiation of Example 4 (nephrite jade powder after combination) is much higher than that of Comparative Example 7 (nephrite jade powder not combined), and even if the addition amount of Example 4 is (3～ 20%), still can maintain the radiation resistance like embodiment 2.

以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。The above is only a preferred embodiment of the present invention, it should be pointed out that, for those of ordinary skill in the art, without departing from the principle of the present invention, some improvements and modifications can also be made, and these improvements and modifications can also be made. It should be regarded as the protection scope of the present invention.

Claims (10)

Translated fromChinese

1.一种防辐射组合物，其特征在于，包括如下重量份的原料：1. a radiation protection composition, is characterized in that, comprises the raw material of following weight part:二氧化锡1～20份，二氧化钛1～30份，软玉粉50～85份。1-20 parts of tin dioxide, 1-30 parts of titanium dioxide, 50-85 parts of nephrite jade powder.2.根据权利要求1所述的组合物，其特征在于，包括如下重量份的原料：2. composition according to claim 1 is characterized in that, comprises the raw material of following weight portion:二氧化锡5～20份，二氧化钛10～25份，软玉粉55～85份。5-20 parts of tin dioxide, 10-25 parts of titanium dioxide, 55-85 parts of nephrite jade powder.3.根据权利要求1所述的组合物，其特征在于，包括如下重量份的原料：3. composition according to claim 1 is characterized in that, comprises the raw material of following weight portion:二氧化锡8～18份，二氧化钛15～25份，软玉粉55～75份。8-18 parts of tin dioxide, 15-25 parts of titanium dioxide, and 55-75 parts of nephrite jade powder.4.一种防辐射组合物的制备方法，其特征在于，包括如下步骤：4. A preparation method of radiation protection composition, is characterized in that, comprises the steps:二氧化钛、二氧化锡和水混合，再加入软玉粉，混合研磨，干燥，粉碎，即得。Mix titanium dioxide, tin dioxide and water, add nephrite jade powder, mix and grind, dry and pulverize to obtain.5.根据权利要求4所述的制备方法，其特征在于，所述研磨为100～120r/min的速度下研磨6～8h；5. The preparation method according to claim 4, characterized in that, the grinding is performed at a speed of 100-120 r/min for 6-8 hours;所述干燥具体为100℃干燥；The drying is specifically drying at 100°C;所述粉碎具体为气流粉碎后过100～200目筛。The pulverization is specifically jet pulverization and passing through a 100-200 mesh sieve.6.权利要求1～4任意一项所述的组合物在制备防辐射产品中的应用。6. The application of the composition according to any one of claims 1 to 4 in the preparation of radiation protection products.7.一种防辐射产品，其特征在于，包括权利要求1～4任意一项所述的组合物。7. A radiation protection product, characterized in that it comprises the composition according to any one of claims 1-4.8.根据权利要求8所述的防辐射产品，其特征在于，所述防辐射产品包括散粉、粉饼、膏霜或乳液。8. The radiation protection product according to claim 8, characterized in that, the radiation protection product comprises loose powder, pressed powder, cream or emulsion.9.一种防辐射散粉，其特征在于，包括如下重量份的原料：9. A radiation-proof loose powder, characterized in that it comprises the following raw materials in parts by weight:

10.根据权利要求9所述的防辐射散粉，其特征在于，所述肤感调节剂包括硅石、聚甲基丙烯酸、尼龙或氮化硼中的一种或几种；10. The anti-radiation loose powder according to claim 9, characterized in that, the skin feeling regulator comprises one or more of silica, polymethacrylic acid, nylon or boron nitride;所述皮肤调理剂包括聚二甲基硅氧烷或角鲨烷。Such skin conditioning agents include dimethicone or squalane.

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