技术领域Technical Field
本发明涉及面料加工技术领域，具体为一种节能环保阻燃面料的染整工艺。The invention relates to the technical field of fabric processing, in particular to a dyeing and finishing process for energy-saving, environmentally friendly and flame-retardant fabrics.
背景技术Background technique
由于公共场所大量使用易燃可燃材料致使火灾不断发生，造成群死群伤，给人民生命和财产安全造成极大的损失。Due to the extensive use of flammable and combustible materials in public places, fires continue to occur, causing mass deaths and injuries, and causing great losses to people’s lives and property safety.
目前，传统的阻燃面料在阻燃耐久性和安全环保等方面存在严重不足，遇火燃烧时烟雾大，极限氧指数很少达到或高于28％。例如中国专利CN2014107615492公开了一种阻燃PET/PTT/TPEE复合纤维，其组分按质量百分数配比为：PET35％-64％、PTT20％-30％、TPEE5％-15％、阻燃剂6％-10％、阻燃协效剂2％-5％、相容剂2％-4％、抗氧剂0.1％-0.5％、成核剂0.1％-1％、润滑剂0.1％-1％，所述阻燃剂为聚苯基膦酸二苯砜酯，所述阻燃协效剂为三氧化二锑；上述面料通过添加的阻燃剂，虽然使得面料具有了一定的阻燃效果，但是极限氧指数较低，阻燃性能一般，无法满足现有商业中对面料阻燃性能的要求；并且，上述面料通过采用现有的染整工艺进行染色后，面料不易得到良好的收缩，导致生产的面料弹性不足。因此目前面料存在的阻燃性能一般，并且染整后弹性较差的问题成为了生产中的难题，为了解决此问题，使得面料具有优异的阻燃性，并且染整后弹性优良，找到该类产品的一种加工工艺来解决上述问题显得尤为重要。At present, traditional flame-retardant fabrics have serious deficiencies in flame-retardant durability, safety and environmental protection. They produce a lot of smoke when burned in fire, and the limiting oxygen index rarely reaches or exceeds 28%. For example, Chinese patent CN2014107615492 discloses a flame retardant PET/PTT/TPEE composite fiber, whose components are proportioned by mass percentage as follows: PET 35%-64%, PTT 20%-30%, TPEE 5%-15%, flame retardant 6%-10%, flame retardant synergist 2%-5%, compatibilizer 2%-4%, antioxidant 0.1%-0.5%, nucleating agent 0.1%-1%, lubricant 0.1%-1%, the flame retardant is polyphenylphosphonic acid diphenyl sulfone ester, and the flame retardant synergist is antimony trioxide; the above fabric has a certain flame retardant effect by adding flame retardant, but the limiting oxygen index is low and the flame retardant performance is general, which cannot meet the flame retardant performance requirements of fabrics in existing business; and after the above fabric is dyed by adopting the existing dyeing and finishing process, the fabric is not easy to shrink well, resulting in insufficient elasticity of the produced fabric. Therefore, the current flame retardancy of fabrics is average, and the problem of poor elasticity after dyeing and finishing has become a difficult problem in production. In order to solve this problem and make the fabric have excellent flame retardancy and excellent elasticity after dyeing and finishing, it is particularly important to find a processing technology for this type of product to solve the above problems.
发明内容Summary of the invention
本发明的目的在于提供一种节能环保阻燃面料的染整工艺，解决了现有技术中面料阻燃性不足以及染整后弹性较差的问题，加工后的面料，不仅可以很好的满足商业上对面料阻燃性的要求，而且染整后的面料弹性好，尺寸稳定。The purpose of the present invention is to provide a dyeing and finishing process for energy-saving, environmentally friendly and flame-retardant fabrics, which solves the problems of insufficient flame retardancy of fabrics and poor elasticity after dyeing and finishing in the prior art. The processed fabrics can not only meet the commercial requirements for flame retardancy of fabrics, but also have good elasticity and stable dimensions after dyeing and finishing.
为实现上述目的，本发明提供如下技术方案：To achieve the above object, the present invention provides the following technical solutions:
一种节能环保阻燃面料的染整工艺，包括轧酶、煮漂、烧毛、定型、阻燃整理、染色以及后整理；A dyeing and finishing process for energy-saving and environmentally friendly flame-retardant fabrics, including enzyme padding, scouring and bleaching, singeing, shaping, flame-retardant finishing, dyeing and post-finishing;
所述轧酶具体操作如下：将面料放入轧退浆酶液中进行二浸二轧处理，然后进行上卷，调整张力控制收缩门幅在10-15％，上卷完成后用塑料薄膜包裹好，以6-15r/min的速度匀速转动1-5h；The specific operation of the rolling enzyme is as follows: the fabric is placed in the rolling enzyme solution for double dipping and double rolling treatment, and then rolled up, the tension is adjusted to control the shrinkage width to 10-15%, and after the rolling is completed, it is wrapped with a plastic film and rotated at a constant speed of 6-15r/min for 1-5h;
所述煮漂具体操作如下：将经过轧酶处理后的面料经90-96℃热水洗后放入漂液中进行二浸二轧，取出经70-75℃汽蒸40-60min，再经90-96℃热水洗以及冷水洗，烘干后即可；The specific operation of the scouring and bleaching is as follows: the fabric treated with the padding enzyme is washed with hot water at 90-96°C, then put into the bleaching liquid for double dipping and double padding, taken out and steamed at 70-75°C for 40-60 minutes, then washed with hot water at 90-96°C and cold water, and then dried;
所述烧毛具体操作如下：采用一正一反的方法对面料进行烧毛处理，烧毛时天然气的流量为0.5-1.3m3/h，车速为100-120m/min；The singeing operation is as follows: the fabric is singed by using a forward and reverse method, the flow rate of natural gas during singeing is 0.5-1.3m3 /h, and the vehicle speed is 100-120m/min;
所述定型具体操作如下：在温度170-180℃条件下，控制车速30-50m/min，定型时间15-30s；The specific operation of the shaping is as follows: at a temperature of 170-180°C, the vehicle speed is controlled at 30-50m/min, and the shaping time is 15-30s;
所述阻燃整理具体操作如下：The specific operation of the flame retardant finishing is as follows:
1)将待染整的面料以1：80-130的浴比加入到去离子水中，经超声清洗后晾干，备用，将一定量的复合阻燃颗粒超声分散到去离子水中，得到分散液，再将KH-570加入到分散液中，超声处理后，得到整理液；1) Add the fabric to be dyed and finished into deionized water at a bath ratio of 1:80-130, clean it with ultrasound and then dry it for later use, disperse a certain amount of composite flame retardant particles into deionized water by ultrasound to obtain a dispersion, then add KH-570 into the dispersion, and after ultrasound treatment, obtain a finishing solution;
所述整理液中，复合阻燃颗粒的浓度为10-30g/L，KH-570的浓度为10-20g/L；In the finishing liquid, the concentration of the composite flame retardant particles is 10-30 g/L, and the concentration of KH-570 is 10-20 g/L;
2)将晾干后的面料以1：80-130的浴比加入到整理液中，放置在40-80℃水浴恒温震荡器中，以100-180r/min持续震荡20-40min，将面料取出后用去离子水对面料进行反复冲洗，置于60-80℃烘箱中干燥5-15min即可；2) Add the dried fabric to the finishing liquid at a bath ratio of 1:80-130, place it in a 40-80℃ water bath constant temperature oscillator, and continue to oscillate at 100-180r/min for 20-40min. After taking out the fabric, rinse it repeatedly with deionized water, and place it in a 60-80℃ oven to dry for 5-15min.
所述染色具体操作如下：采用染色设备，将定型后的面料和水加入到染色设备中，并控制染色液的组成为：活性染料1-8％，元明粉40-80g/L，液碱0.5-1.0g/L，纯碱4-8g/L，浴中宝1.2-1.8g/L以及其余为水，对面料进行染色；The specific dyeing operation is as follows: using a dyeing device, adding the shaped fabric and water into the dyeing device, and controlling the composition of the dyeing liquid to be: 1-8% of active dye, 40-80g/L of sodium sulfate, 0.5-1.0g/L of liquid alkali, 4-8g/L of soda ash, 1.2-1.8g/L of Yuzhongbao and the rest of water, dyeing the fabric;
所述后处理具体操作如下：包括定型机定型、砂洗以及汽蒸定型；The specific operation of the post-processing is as follows: including shaping by a shaping machine, sand washing and steaming shaping;
其中定型机定型温度为120-130℃；The setting temperature of the setting machine is 120-130℃;
其中砂洗在气流砂洗机中进行，温度为70-90℃，时间50-80min；The sand washing is carried out in an air flow sand washing machine at a temperature of 70-90°C for 50-80 minutes;
其中汽蒸定型温度为135-155℃。The steam setting temperature is 135-155℃.
更进一步，所述轧退浆酶液包括宽温退浆酶和渗透剂；Furthermore, the pad desizing enzyme solution includes a wide temperature desizing enzyme and a penetrant;
所述漂液包括NaOH 15-20g/L、H2O28-13g/L、Na2CO3 13-18g/L、低温练漂剂3-7g/L、稳定剂2-5g/L、螯合剂2-6g/L；The bleaching liquid includes NaOH 15-20g/L, H2 O2 8-13g/L, Na2 CO3 13-18g/L, low temperature scouring agent 3-7g/L, stabilizer 2-5g/L, chelating agent 2-6g/L;
所述烧毛处理中，火口与面料的距离为6-10mm，保持布面温度不高于180℃，且在火口上方安装冷水辊筒，火口后面吹风，落布温度保持在50℃以下，织物的门幅收缩不超过2％。In the singeing treatment, the distance between the burner and the fabric is 6-10mm, the temperature of the fabric surface is kept no higher than 180°C, a cold water roller is installed above the burner, air is blown behind the burner, the temperature of the falling fabric is kept below 50°C, and the width of the fabric shrinks no more than 2%.
更进一步，所述染色工艺中，面料在染色前先在40-60℃的处理液中进行处理，其中，浴比1：10-30，处理液包含辛醇、醋酸和水，并且辛醇占比为1-3％，醋酸占比为1.5-3.5％，pH值为3-4，浸渍处理10-30min。Furthermore, in the dyeing process, the fabric is treated in a treatment liquid at 40-60°C before dyeing, wherein the bath ratio is 1:10-30, the treatment liquid comprises octanol, acetic acid and water, and the octanol accounts for 1-3%, the acetic acid accounts for 1.5-3.5%, the pH value is 3-4, and the immersion treatment is 10-30 minutes.
更进一步，所述染色具体操作如下：将处理液浸渍处理后的面料和水进到溢流喷射染色机中，加入配方量的浴中宝，保持温度25-30℃，转3-7min，然后升温至35-40℃，加入配方量的活性染料，转12-20min后，再加入配方量的元明粉，转13-18min后，加入配方量的纯碱，转12-15min后，加入配方量的液碱，转30-40min，结束染色，排出染色液，将面料取出后进行水洗、烘干；Furthermore, the dyeing is specifically performed as follows: the fabric treated by the treatment liquid immersion and water are put into the overflow jet dyeing machine, a formula amount of Yuzhongbao is added, the temperature is maintained at 25-30°C, the temperature is rotated for 3-7 minutes, and then the temperature is raised to 35-40°C, a formula amount of reactive dye is added, the temperature is rotated for 12-20 minutes, and then a formula amount of glauber's salt is added, the temperature is rotated for 13-18 minutes, and then a formula amount of soda ash is added, the temperature is rotated for 12-15 minutes, and then a formula amount of liquid alkali is added, the temperature is rotated for 30-40 minutes, the dyeing is terminated, the dyeing liquid is discharged, and the fabric is taken out and washed and dried;
更进一步，所述复合阻燃颗粒得制备方法：Furthermore, the preparation method of the composite flame retardant particles is:
1)将盐酸加入到离心管中，并在磁力搅拌下加入氟化锂和碳铝钛，逐渐升温至35-45℃后，在油浴锅中反应20-30h，离心后用去离子水反复洗涤，经真空干燥，得到碳化钛颗粒；1) Add hydrochloric acid to a centrifuge tube, and add lithium fluoride and carbon aluminum titanium under magnetic stirring, gradually heat to 35-45° C., react in an oil bath for 20-30 hours, centrifuge, repeatedly wash with deionized water, and vacuum dry to obtain titanium carbide particles;
2)将碳化钛颗粒进行表面处理，得到预处理碳化钛颗粒，加入到乙醇溶液中，经超声处理后加入正硅酸乙酯，在60-70℃下搅拌30-50min，再加入的氨水继续搅拌5-10h，抽滤后用无水乙醇进行反复洗涤，将得到的产物真空干燥后，得到复合碳化钛颗粒；2) Surface-treating titanium carbide particles to obtain pretreated titanium carbide particles, adding them to an ethanol solution, adding ethyl orthosilicate after ultrasonic treatment, stirring at 60-70° C. for 30-50 min, adding ammonia water and continuing stirring for 5-10 h, filtering and repeatedly washing with anhydrous ethanol, and vacuum drying the obtained product to obtain composite titanium carbide particles;
3)将复合碳化钛颗粒、吡咯溶液以及植酸加入到容器中，超声处理后得到悬浮液，然后将过硫酸铵溶解于去离子水中，并将其逐滴加入到上述悬浮液中，在氮气气氛下反应4-10h，再将硝酸镍溶液逐滴加入到上述溶液中并反应2-6h，通过抽滤、去离子水和乙醇反复洗涤，将得到的产物真空干燥，得到复合阻燃颗粒。3) adding composite titanium carbide particles, pyrrole solution and phytic acid into a container, obtaining a suspension after ultrasonic treatment, then dissolving ammonium persulfate in deionized water, and adding it dropwise into the suspension, reacting for 4-10 hours under a nitrogen atmosphere, then adding nickel nitrate solution dropwise into the solution and reacting for 2-6 hours, filtering, repeatedly washing with deionized water and ethanol, and vacuum drying the obtained product to obtain composite flame retardant particles.
更进一步，步骤1)中，所述盐酸的质量分数为36-38％；Furthermore, in step 1), the mass fraction of the hydrochloric acid is 36-38%;
所述盐酸、氟化锂、碳铝钛的用量比为200-1000mL：15-30g：10-25g；The usage ratio of hydrochloric acid, lithium fluoride, carbon aluminum titanium is 200-1000mL: 15-30g: 10-25g;
所述碳铝钛400-800目。The carbon aluminum titanium is 400-800 mesh.
更进一步，步骤2)中，预处理碳化钛颗粒、乙醇溶液、正硅酸乙酯、氨水的用量比例为2-6g：250-400mL：15-40mL：5-10mL；Furthermore, in step 2), the ratio of the pretreated titanium carbide particles, the ethanol solution, the tetraethyl orthosilicate, and the ammonia water is 2-6 g: 250-400 mL: 15-40 mL: 5-10 mL;
所述氨水的质量分数为25-30％。The mass fraction of the ammonia water is 25-30%.
更进一步，步骤2)中，所述碳化钛颗粒的表面处理方法如下：Furthermore, in step 2), the surface treatment method of the titanium carbide particles is as follows:
将3-10g聚乙烯吡咯烷酮溶于500-1000mL去离子水中，加入5-15g碳化钛颗粒，在25-30℃以及260-320W条件下超声处理5-15min，将得到的混合液在常温下，以300-500r/min机械搅拌1-3h，再用去离子水反复洗涤和抽滤后，在60-80℃烘箱中干燥10-15h，即可得到预处理碳化钛颗粒。Dissolve 3-10g of polyvinyl pyrrolidone in 500-1000mL of deionized water, add 5-15g of titanium carbide particles, and ultrasonically treat for 5-15min at 25-30°C and 260-320W. Stir the obtained mixture mechanically at 300-500r/min for 1-3h at room temperature, repeatedly wash and filter with deionized water, and dry in an oven at 60-80°C for 10-15h to obtain pretreated titanium carbide particles.
更进一步，步骤3)中，所述复合碳化钛颗粒、吡咯烷酮、植酸、过硫酸铵、去离子水以及硝酸镍溶液的用量比例为0.2-1.0g：0.4-2.0g：5-10g：0.7-1.5g：50-100mL：60-120mL；Furthermore, in step 3), the ratio of the composite titanium carbide particles, pyrrolidone, phytic acid, ammonium persulfate, deionized water and nickel nitrate solution is 0.2-1.0 g: 0.4-2.0 g: 5-10 g: 0.7-1.5 g: 50-100 mL: 60-120 mL;
所述硝酸镍的质量浓度为1-3％。The mass concentration of the nickel nitrate is 1-3%.
更进一步，步骤3)中，所述复合碳化钛颗粒在使用前还进行的预处理，具体操作如下：Furthermore, in step 3), the composite titanium carbide particles are pretreated before use, and the specific operation is as follows:
1)按照复合碳化钛颗粒质量百分数的25-35％量取KH-570，加入到体积比为1：1的无水乙醇与去离子水混合液中，控制KH-570与混合液的体积比为1：8-15，用稀盐酸将溶液pH调整为3-4，磁力搅拌反应1-3h后，KH-570水解；1) taking KH-570 according to 25-35% of the mass percentage of the composite titanium carbide particles, adding it to a mixture of anhydrous ethanol and deionized water in a volume ratio of 1:1, controlling the volume ratio of KH-570 to the mixture to be 1:8-15, adjusting the pH of the solution to 3-4 with dilute hydrochloric acid, and reacting with magnetic stirring for 1-3 hours to hydrolyze KH-570;
2)将复合碳化钛颗粒加入到积比为1：1的无水乙醇与去离子水混合液中进行分散，将分散好的复合碳化钛颗粒以及水解后的KH-570加入到容器中，水浴加热至75-85℃，机械搅拌2-6h，将得到的产物冷却至室温后进行高速离心，用去离子水和乙醇反复洗涤后，真空干燥后即可。2) Add the composite titanium carbide particles to a mixture of anhydrous ethanol and deionized water in a volume ratio of 1:1 for dispersion, add the dispersed composite titanium carbide particles and the hydrolyzed KH-570 into a container, heat in a water bath to 75-85°C, mechanically stir for 2-6 hours, cool the obtained product to room temperature and perform high-speed centrifugation, repeatedly wash with deionized water and ethanol, and then vacuum dry.
更进一步，步骤2)中，所述复合碳化钛颗粒与混合液的质量体积比为1：10-30g/mL。Furthermore, in step 2), the mass volume ratio of the composite titanium carbide particles to the mixed liquid is 1:10-30 g/mL.
与现有技术相比，本发明的有益效果是：Compared with the prior art, the present invention has the following beneficial effects:
1.本发明中，采用聚合反应和自组装技术，以复合碳化钛颗粒、硝酸镍、植酸、吡咯作为原料，合成植酸镍修饰的聚吡咯包裹的复合阻燃颗粒，并通过将面料浸入到由复合阻燃颗粒和KH-570组成的整理液中，从而使得复合阻燃颗粒可以通过KH-570与面料纤维发生交联反应，从而粘附在面料表面，在面料表面形成一层有复合阻燃颗粒构建成的阻燃层，由于复合阻燃颗粒为较为光滑的整体结构，并且缝隙较少，因此形成的阻燃层具有很好的致密性，使得面料在燃烧过程中可以形成完整的致密的的炭层，不仅可以阻挡热量的释放，从而抑制了热释放的速率，并且还可以抑制小分子物质的逸出，起到抑烟的效果，从而可以有效的减少面料在燃烧时热量和烟气的产生，使得面料具有了优良的阻燃性能以及抑烟性能。1. In the present invention, polymerization reaction and self-assembly technology are adopted, composite titanium carbide particles, nickel nitrate, phytic acid, and pyrrole are used as raw materials to synthesize composite flame retardant particles wrapped with polypyrrole modified by phytic acid nickel, and the fabric is immersed in a finishing liquid composed of the composite flame retardant particles and KH-570, so that the composite flame retardant particles can undergo a cross-linking reaction with the fabric fibers through KH-570, thereby adhering to the fabric surface, and forming a flame retardant layer constructed with the composite flame retardant particles on the fabric surface. Since the composite flame retardant particles have a relatively smooth overall structure and fewer gaps, the flame retardant layer formed has good density, so that the fabric can form a complete and dense carbon layer during the combustion process, which can not only block the release of heat, thereby inhibiting the rate of heat release, but also inhibit the escape of small molecules, thereby achieving a smoke suppression effect, thereby effectively reducing the generation of heat and smoke when the fabric is burned, so that the fabric has excellent flame retardant and smoke suppression properties.
2.本发明中，在碳化钛颗粒表面原位生长纳米二氧化硅粒子，以提高碳化钛颗粒在水中的分散性，从而使得形成的复合碳化钛颗粒在悬浮液中可以形成稳定的分散体系，从而有利于提高植酸镍修饰的聚吡咯在复合碳化钛颗粒表面的包覆效果，并且在燃烧过程中，形成的二氧化硅覆盖物隔离层可以起到强化炭化过程，达到提高面料燃烧后所形成的炭层的包覆致密性，促成了面料具有更高的阻燃等级，从而使得后续制备的复合阻燃颗粒具有更加优异的阻燃性能，从而可以进一步提高面料的阻燃效果，而且，二氧化硅与KH-570形成的-Si-O-键极易断裂，断裂之后可以捕捉面料燃烧时产生的自由基，阻止燃烧链式反应的进行，达到降低热释放和烟气生成的目的；同时，通过对制备的复合碳化钛颗粒还进行预处理，利用KH-570对复合碳化钛颗粒进行表面改性，有助于提高其界面结合力，从而使得植酸镍修饰的聚吡咯可以牢固的包覆在复合碳化钛颗粒表面，从而有助于提高后续制备的复合阻燃颗粒的稳定性，从而使得面料表面形成的阻燃层结构稳定，可以长久在粘附在面料上，起到长久高效的阻燃效果。2. In the present invention, nano-silicon dioxide particles are in-situ grown on the surface of titanium carbide particles to improve the dispersibility of titanium carbide particles in water, so that the formed composite titanium carbide particles can form a stable dispersion system in the suspension, which is beneficial to improve the coating effect of nickel phytate-modified polypyrrole on the surface of the composite titanium carbide particles, and during the combustion process, the formed silicon dioxide covering isolation layer can strengthen the carbonization process, thereby improving the coating density of the carbon layer formed after the fabric is burned, and promoting the fabric to have a higher flame retardant grade, so that the composite flame retardant particles prepared subsequently have more excellent flame retardant properties, thereby further improving the flame retardant effect of the fabric, and the silicon dioxide The -Si-O- bond formed by silicon carbide and KH-570 is very easy to break. After breaking, it can capture the free radicals generated when the fabric burns, prevent the combustion chain reaction from proceeding, and achieve the purpose of reducing heat release and smoke generation; at the same time, by pre-treating the prepared composite titanium carbide particles and using KH-570 to modify the surface of the composite titanium carbide particles, it helps to improve its interfacial bonding strength, so that the polypyrrole modified with nickel phytate can be firmly coated on the surface of the composite titanium carbide particles, which helps to improve the stability of the subsequently prepared composite flame retardant particles, so that the flame retardant layer formed on the surface of the fabric has a stable structure and can adhere to the fabric for a long time, achieving a long-lasting and efficient flame retardant effect.
3.本发明中所述的染整工艺，面料进行处理后，不仅手感柔软，弹性好，而且面料表面构建的阻燃层是由大量复合阻燃颗粒之间相互嵌插形成的连续相整体，在赋予面料阻燃性的同时，使得面料具有优良的尺寸稳定性，提高了面料的强度，使得面料不易发生破损，从而使得面料经久耐用。3. The dyeing and finishing process described in the present invention not only makes the fabric soft and elastic after being processed, but also the flame retardant layer constructed on the surface of the fabric is a continuous phase formed by a large number of composite flame retardant particles interlocked with each other. While giving the fabric flame retardancy, the fabric has excellent dimensional stability, improves the strength of the fabric, makes the fabric less likely to be damaged, and thus makes the fabric durable.
具体实施方式Detailed ways
下面将对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其它实施例，都属于本发明保护的范围。The technical solutions in the embodiments of the present invention are described clearly and completely below. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of them. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.
实施例1Example 1
一种节能环保阻燃面料的染整工艺，包括轧酶、煮漂、烧毛、定型、阻燃整理、染色以及后整理；A dyeing and finishing process for energy-saving and environmentally friendly flame-retardant fabrics, including enzyme padding, scouring and bleaching, singeing, shaping, flame-retardant finishing, dyeing and post-finishing;
所述轧酶具体操作如下：将面料放入轧退浆酶液中进行二浸二轧处理，然后进行上卷，调整张力控制收缩门幅在10％，上卷完成后用塑料薄膜包裹好，以6r/min的速度匀速转动1h；The specific operation of the rolling enzyme is as follows: the fabric is placed in the rolling enzyme solution for double dipping and double rolling treatment, and then rolled up, the tension is adjusted to control the shrinkage width to 10%, and after the rolling is completed, it is wrapped with a plastic film and rotated at a constant speed of 6r/min for 1h;
其中，轧退浆酶液包括宽温退浆酶HS-380(开来化工)5g/L和渗透剂JFC2g/L；Among them, the pad desizing enzyme solution includes wide temperature desizing enzyme HS-380 (Kailai Chemical) 5g/L and penetrant JFC 2g/L;
所述煮漂具体操作如下：将经过轧酶处理后的面料经90℃热水洗后放入漂液中进行二浸二轧，取出经70℃汽蒸40min，再经90℃热水洗以及冷水洗，烘干后即可；The specific operation of the scouring and bleaching is as follows: the fabric treated with the padding enzyme is washed with hot water at 90°C, then put into the bleaching liquid for double dipping and double padding, taken out and steamed at 70°C for 40 minutes, then washed with hot water at 90°C and cold water, and then dried;
其中，漂液包括NaOH 15g/L、H2O28g/L、Na2CO3 13g/L、低温练漂剂DF-106(杨天化工)3g/L、稳定剂DM-1408(德美化工)2g/L、螯合剂DM-8108(德美化工)2g/L；The bleaching liquid includes NaOH 15g/L, H2 O2 8g/L, Na2 CO3 13g/L, low-temperature scouring agent DF-106 (Yangtian Chemical) 3g/L, stabilizer DM-1408 (Demei Chemical) 2g/L, chelating agent DM-8108 (Demei Chemical) 2g/L;
所述烧毛具体操作如下：采用一正一反的方法对面料进行烧毛处理，烧毛时天然气的流量为0.5m3/h，车速为100m/min；火口与面料的距离为6mm，保持布面温度不高于180℃，且在火口上方安装冷水辊筒，火口后面吹风，落布温度保持在50℃以下，织物的门幅收缩不超过2％；The singeing operation is as follows: the fabric is singed by a method of one positive and one negative, the flow rate of natural gas during singeing is0.5m3 /h, the speed is 100m/min; the distance between the burner and the fabric is 6mm, the temperature of the fabric surface is kept no higher than 180℃, and a cold water roller is installed above the burner, and air is blown behind the burner, the temperature of the falling fabric is kept below 50℃, and the width of the fabric shrinks no more than 2%;
所述定型具体操作如下：在温度170℃条件下，控制车速30m/min，定型时间15s；The specific operation of the shaping is as follows: under the condition of temperature 170°C, the vehicle speed is controlled to 30m/min, and the shaping time is 15s;
所述阻燃整理具体操作如下：The specific operation of the flame retardant finishing is as follows:
1)将待染整的面料以1：80的浴比加入到去离子水中，经超声清洗后晾干，备用，将一定量的复合阻燃颗粒加入到去离子水中，200W超声分散10min，得到分散液，再将KH加入到分散液中，继续超声处理10min，得到整理液；1) Add the fabric to be dyed and finished into deionized water at a bath ratio of 1:80, clean it with ultrasound and then dry it for later use, add a certain amount of composite flame retardant particles into deionized water, and disperse it with ultrasound at 200W for 10 minutes to obtain a dispersion, then add KH into the dispersion, and continue ultrasound treatment for 10 minutes to obtain a finishing solution;
所述整理液中，复合阻燃颗粒的浓度为10g/L，KH-570的浓度为10g/L；In the finishing liquid, the concentration of the composite flame retardant particles is 10 g/L, and the concentration of KH-570 is 10 g/L;
2)将晾干后的面料以1：80的浴比加入到整理液中，放置在40℃水浴恒温震荡器中，以100r/min持续震荡20min，将面料取出后用去离子水对面料进行反复冲洗，置于60℃烘箱中干燥5min即可；2) Add the dried fabric to the finishing liquid at a bath ratio of 1:80, place it in a 40℃ water bath constant temperature oscillator, and oscillate continuously at 100r/min for 20min. After taking out the fabric, rinse it repeatedly with deionized water, and dry it in a 60℃ oven for 5min.
所述染色具体操作如下：将定型后的面料先在40℃的处理液中进行处理，其中，浴比1：10，处理液包含辛醇、醋酸和水，并且辛醇占比为1％，醋酸占比为1.5％，pH值为3，浸渍处理10min，取出织物，采用溢流喷射染色机，浴比控制为1：20，染色液的组成为：活性染料1％，元明粉40g/L，液碱0.5g/L，纯碱4g/L，浴中宝1.2g/L以及其余为水，染色过程如下，将面料和水进到溢流喷射染色机中，加入配方量的浴中宝，保持温度25℃，转3min，然后升温至35℃，加入配方量的活性染料，转12min后，再加入配方量的元明粉，转13min后，加入配方量的纯碱，转12min后，加入配方量的液碱，转30min，结束染色，排出染色液，将面料取出后进行水洗、烘干；The dyeing is specifically performed as follows: the shaped fabric is first treated in a treatment solution at 40°C, wherein the bath ratio is 1:10, the treatment solution comprises octanol, acetic acid and water, and the octanol accounts for 1%, the acetic acid accounts for 1.5%, the pH value is 3, the immersion treatment is 10 minutes, the fabric is taken out, an overflow jet dyeing machine is used, the bath ratio is controlled to be 1:20, the composition of the dyeing solution is: 1% active dye, 40g/L sodium sulfate, 0.5g/L liquid alkali, 4g/L soda ash, 1.2g/L Yuzhongbao and the rest is water, the dyeing process is as follows: the fabric and water are put into the overflow jet dyeing machine, the formula amount of Yuzhongbao is added, the temperature is maintained at 25°C, the temperature is turned for 3 minutes, and then the temperature is raised to 35°C, the formula amount of active dye is added, after turning for 12 minutes, the formula amount of sodium sulfate is added, after turning for 13 minutes, the formula amount of soda ash is added, after turning for 12 minutes, the formula amount of liquid alkali is added, the dyeing is terminated, the dyeing solution is discharged, and the fabric is taken out for water washing and drying;
所述后处理具体操作如下：经过水洗、烘干后的面料，经离心脱水机脱水后，手工开幅经定型机烘干，温度120℃，车速40m/min，烘干后在平缸进行柔软加工，再经定型机定型，温度125℃，车速35m/min；之后，将面料送入气流砂洗机，在传动导轮带动下，面料在机内循环，并被喷射气流拍打，温度为70℃，时间50min，循环面料速300m/min；最后一步整理工序是汽蒸定型，定型布速45m/min，温度135℃。The specific operation of the post-treatment is as follows: the washed and dried fabrics are dehydrated by a centrifugal dehydrator, manually opened and dried by a setting machine at a temperature of 120°C and a speed of 40m/min. After drying, they are softened on a flat cylinder and then set by a setting machine at a temperature of 125°C and a speed of 35m/min. After that, the fabrics are sent to an air flow sand washing machine. Driven by a transmission guide wheel, the fabrics circulate in the machine and are beaten by a jet of air at a temperature of 70°C, a time of 50min, and a circulating fabric speed of 300m/min. The last finishing process is steam setting, with a setting cloth speed of 45m/min and a temperature of 135°C.
所述复合阻燃颗粒得制备方法：The preparation method of the composite flame retardant particles:
1)量取200mL质量分数为36％的盐酸加入到离心管中，在磁力搅拌下加入15g氟化锂和10g粒径为400目的碳铝钛，逐渐升温至35℃后，在油浴锅中反应20h，经5000r/min离心处理10min后，用去离子水反复洗涤，在50℃真空烘箱中干燥5h，得到碳化钛颗粒；1) 200 mL of 36% hydrochloric acid was added to a centrifuge tube, 15 g of lithium fluoride and 10 g of carbon aluminum titanium with a particle size of 400 mesh were added under magnetic stirring, the temperature was gradually raised to 35° C., the mixture was reacted in an oil bath for 20 h, centrifuged at 5000 r/min for 10 min, repeatedly washed with deionized water, and dried in a vacuum oven at 50° C. for 5 h to obtain titanium carbide particles;
2)称取2g经过表面处理后得到的预处理碳化钛颗粒，加入到250mL乙醇溶液中，在25℃以及260W条件下超声处理10min，加入15mL正硅酸乙酯，在60℃下搅拌30min，再加入5mL质量分数为25％的氨水，继续搅拌5h，抽滤后用无水乙醇进行反复洗涤，将得到的产物在50℃真空烘箱中干燥10h，得到复合碳化钛颗粒；2) Weigh 2 g of the pretreated titanium carbide particles obtained after surface treatment, add them to 250 mL of ethanol solution, ultrasonically treat them at 25° C. and 260 W for 10 min, add 15 mL of ethyl orthosilicate, stir at 60° C. for 30 min, then add 5 mL of 25% ammonia water, continue stirring for 5 h, filter and repeatedly wash with anhydrous ethanol, and dry the obtained product in a vacuum oven at 50° C. for 10 h to obtain composite titanium carbide particles;
3)将0.2g复合碳化钛颗粒、0.4-g吡咯溶液以及5g植酸加入到容器中，在200W下超声处理20min，得到悬浮液，然后将0.7g过硫酸铵溶解于50mL去离子水中，并将其逐滴加入到上述悬浮液中，在氮气气氛下反应4h，再将60mL质量浓度为1％的硝酸镍溶液逐滴加入到上述溶液中并反应2h，通过抽滤、去离子水和乙醇反复洗涤，将得到的产物在60℃下真空干燥箱中干燥20h，得到复合阻燃颗粒。3) 0.2 g of composite titanium carbide particles, 0.4 g of pyrrole solution and 5 g of phytic acid were added to a container, and ultrasonically treated at 200 W for 20 min to obtain a suspension, and then 0.7 g of ammonium persulfate was dissolved in 50 mL of deionized water and added dropwise to the above suspension, and reacted for 4 h under a nitrogen atmosphere, and then 60 mL of a 1% nickel nitrate solution was added dropwise to the above solution and reacted for 2 h, and the product was dried in a vacuum drying oven at 60 ° C for 20 h by suction filtration, deionized water and ethanol repeated washing to obtain composite flame retardant particles.
所述碳化钛颗粒的表面处理方法如下：The surface treatment method of the titanium carbide particles is as follows:
将3g聚乙烯吡咯烷酮溶于500mL去离子水中，加入5g碳化钛颗粒，在25℃以及260W条件下超声处理5min，将得到的混合液在常温下，以300r/min机械搅拌1h，再用去离子水反复洗涤和抽滤后，在60℃烘箱中干燥10h，即可得到预处理碳化钛颗粒。3 g of polyvinyl pyrrolidone was dissolved in 500 mL of deionized water, 5 g of titanium carbide particles were added, and ultrasonic treatment was performed at 25 ° C and 260 W for 5 min. The obtained mixture was mechanically stirred at 300 r/min at room temperature for 1 h, and then repeatedly washed and filtered with deionized water, and dried in an oven at 60 ° C for 10 h to obtain pretreated titanium carbide particles.
所述复合碳化钛颗粒在使用前还进行的预处理，具体操作如下：The composite titanium carbide particles are also pretreated before use, and the specific operation is as follows:
1)按照复合碳化钛颗粒质量百分数的25％量取KH-570，加入到体积比为1：1的无水乙醇与去离子水混合液中，控制KH-570与混合液的体积比为1：8，用稀盐酸将溶液pH调整为3，磁力搅拌反应1h后，KH-570水解；1) KH-570 was measured according to 25% of the mass percentage of the composite titanium carbide particles, and added to a mixture of anhydrous ethanol and deionized water in a volume ratio of 1:1, and the volume ratio of KH-570 to the mixture was controlled to be 1:8, and the pH of the solution was adjusted to 3 with dilute hydrochloric acid. After magnetic stirring for 1 hour, KH-570 was hydrolyzed;
2)将复合碳化钛颗粒加入到积比为1：1的无水乙醇与去离子水混合液中，控制复合碳化钛颗粒与混合液的质量体积比为1：10g/mL，200W超声分散1h，将分散好的复合碳化钛颗粒以及水解后的KH-570加入到容器中，水浴加热至75℃，以100r/min机械搅拌2h，将得到的产物冷却至室温后以6000r/min高速离心3min，用去离子水和乙醇反复洗涤后，在60℃条件下真空干燥15h即可。2) Add the composite titanium carbide particles to a mixture of anhydrous ethanol and deionized water in a volume ratio of 1:1, control the mass volume ratio of the composite titanium carbide particles to the mixture to be 1:10 g/mL, and ultrasonically disperse at 200 W for 1 hour. Add the dispersed composite titanium carbide particles and the hydrolyzed KH-570 to the container, heat to 75°C in a water bath, and mechanically stir at 100 r/min for 2 hours. After cooling the product to room temperature, centrifuge it at 6000 r/min for 3 minutes, wash it repeatedly with deionized water and ethanol, and then vacuum dry it at 60°C for 15 hours.
实施例2Example 2
本实施例所提供的节能环保阻燃面料的染整工艺和实施例1大致相同，其主要区别在于，所用原料的具体配比不同，具体为：The dyeing and finishing process of the energy-saving, environmentally friendly and flame-retardant fabric provided in this embodiment is substantially the same as that in Embodiment 1, the main difference being that the specific proportions of the raw materials used are different, specifically:
所述轧酶具体操作中，将面料放入轧退浆酶液中进行二浸二轧处理，然后进行上卷，调整张力控制收缩门幅在12％，上卷完成后用塑料薄膜包裹好，以10r/min的速度匀速转动3h；In the specific operation of the rolling enzyme, the fabric is placed in the rolling desizing enzyme solution for double dipping and double rolling treatment, and then rolled up, the tension is adjusted to control the shrinkage width at 12%, and after the rolling is completed, it is wrapped with a plastic film and rotated at a constant speed of 10r/min for 3h;
所述煮漂具体操作中，将经过轧酶处理后的面料经95℃热水洗后放入漂液中进行二浸二轧，取出经72℃汽蒸50min，再经95℃热水洗以及冷水洗，烘干后即可；In the specific operation of scouring and bleaching, the fabric treated with the rolling enzyme is washed with hot water at 95°C and then put into the bleaching liquid for double immersion and double rolling, taken out and steamed at 72°C for 50 minutes, then washed with hot water at 95°C and cold water, and then dried;
所述烧毛具体操作中，采用一正一反的方法对面料进行烧毛处理，烧毛时天然气的流量为0.8m3/h，车速为110m/min；In the singeing operation, the fabric is singed by using a forward and reverse method, the flow rate of natural gas during singeing is 0.8m3 /h, and the vehicle speed is 110m/min;
所述定型具体操作中，在温度175℃条件下，控制车速40m/min，定型时间25s；In the specific shaping operation, the vehicle speed is controlled at 40 m/min and the shaping time is 25 s at a temperature of 175°C.
所述染色具体操作如下：将定型后的面料先在50℃的处理液中进行处理，其中，浴比1：20，处理液包含辛醇、醋酸和水，并且辛醇占比为2％，醋酸占比为2.5％，pH值为3.5，浸渍处理20min，取出织物，采用溢流喷射染色机，浴比控制为1：25，染色过程如下，将面料和水进到溢流喷射染色机中，加入配方量的浴中宝，保持温度30℃，转5min，然后升温至40℃，加入配方量的活性染料，转15min后，再加入配方量的元明粉，转16min后，加入配方量的纯碱，转13min后，加入配方量的液碱，转35min，结束染色，排出染色液，将面料取出后进行水洗、烘干；The dyeing is specifically performed as follows: the shaped fabric is first treated in a treatment solution at 50°C, wherein the bath ratio is 1:20, the treatment solution comprises octanol, acetic acid and water, and the octanol accounts for 2%, the acetic acid accounts for 2.5%, the pH value is 3.5, the immersion treatment is performed for 20 minutes, the fabric is taken out, and an overflow jet dyeing machine is used, the bath ratio is controlled to be 1:25, and the dyeing process is as follows: the fabric and water are put into the overflow jet dyeing machine, a formula amount of Yuzhongbao is added, the temperature is maintained at 30°C, the temperature is rotated for 5 minutes, and then the temperature is raised to 40°C, a formula amount of active dye is added, after rotating for 15 minutes, a formula amount of glauber powder is added, after rotating for 16 minutes, a formula amount of soda ash is added, after rotating for 13 minutes, a formula amount of liquid alkali is added, the dyeing is terminated, the dyeing solution is discharged, and the fabric is taken out for water washing and drying;
所述后处理具体操作如下：经过水洗、烘干后的面料，经离心脱水机脱水后，手工开幅经定型机烘干，温度123℃，车速40m/min，烘干后在平缸进行柔软加工，再经定型机定型，温度127℃，车速35m/min；之后，将面料送入气流砂洗机，在传动导轮带动下，面料在机内循环，并被喷射气流拍打，温度为80℃，时间70min，循环面料速500m/min；最后一步整理工序是汽蒸定型，定型布速46m/min，温度145℃。The specific operation of the post-treatment is as follows: the fabric after washing and drying is dehydrated by a centrifugal dehydrator, manually opened and dried by a setting machine at a temperature of 123°C and a speed of 40m/min, softened on a flat cylinder after drying, and then set by a setting machine at a temperature of 127°C and a speed of 35m/min; thereafter, the fabric is sent to an air flow sand washing machine, driven by a transmission guide wheel, the fabric circulates in the machine and is beaten by a jet air flow at a temperature of 80°C, a time of 70min, and a circulating fabric speed of 500m/min; the last step of the finishing process is steam setting, with a setting cloth speed of 46m/min and a temperature of 145°C.
实施例3Example 3
本实施例所提供的节能环保阻燃面料的染整工艺和实施例1大致相同，其主要区别在于，所用原料的具体配比不同，具体为：The dyeing and finishing process of the energy-saving, environmentally friendly and flame-retardant fabric provided in this embodiment is substantially the same as that in Embodiment 1, the main difference being that the specific proportions of the raw materials used are different, specifically:
所述轧酶具体操作如下：将面料放入轧退浆酶液中进行二浸二轧处理，然后进行上卷，调整张力控制收缩门幅在15％，上卷完成后用塑料薄膜包裹好，以15r/min的速度匀速转动5h；The specific operation of the rolling enzyme is as follows: the fabric is placed in the rolling enzyme solution for double dipping and double rolling treatment, and then rolled up, the tension is adjusted to control the shrinkage width at 15%, and after the rolling is completed, it is wrapped with a plastic film and rotated at a constant speed of 15r/min for 5h;
其中，轧退浆酶液包括宽温退浆酶HS-380(开来化工)5g/L和渗透剂JFC2g/L；Among them, the pad desizing enzyme solution includes wide temperature desizing enzyme HS-380 (Kailai Chemical) 5g/L and penetrant JFC 2g/L;
所述煮漂具体操作如下：将经过轧酶处理后的面料经96℃热水洗后放入漂液中进行二浸二轧，取出经75℃汽蒸60min，再经96℃热水洗以及冷水洗，烘干后即可；The specific operation of the scouring and bleaching is as follows: the fabric treated with the padding enzyme is washed with hot water at 96°C, then put into the bleaching liquid for double dipping and double padding, taken out and steamed at 75°C for 60 minutes, then washed with hot water at 96°C and cold water, and then dried;
所述烧毛具体操作如下：采用一正一反的方法对面料进行烧毛处理，烧毛时天然气的流量为1.3m3/h，车速为120m/min；The singeing operation is as follows: the fabric is singed by using a forward and reverse method, the flow rate of natural gas during singeing is 1.3m3 /h, and the vehicle speed is 120m/min;
所述定型具体操作如下：在温度180℃条件下，控制车速50m/min，定型时间30s；The specific operation of the shaping is as follows: under the condition of temperature 180°C, the vehicle speed is controlled to 50m/min, and the shaping time is 30s;
所述阻燃整理具体操作如下：The specific operation of the flame retardant finishing is as follows:
1)将待染整的面料以1：130的浴比加入到去离子水中，经超声清洗后晾干，备用，将一定量的复合阻燃颗粒加入到去离子水中，400W超声分散30min，得到分散液，再将KH-570加入到分散液中，继续超声处理30min，得到整理液；1) Add the fabric to be dyed and finished into deionized water at a bath ratio of 1:130, clean it with ultrasound and then dry it for later use, add a certain amount of composite flame retardant particles into deionized water, and disperse it with ultrasound at 400W for 30 minutes to obtain a dispersion, then add KH-570 into the dispersion, and continue ultrasound treatment for 30 minutes to obtain a finishing solution;
所述整理液中，复合阻燃颗粒的浓度为30g/L，KH-570的浓度为20g/L；In the finishing liquid, the concentration of the composite flame retardant particles is 30 g/L, and the concentration of KH-570 is 20 g/L;
2)将晾干后的面料以1：130的浴比加入到整理液中，放置在80℃水浴恒温震荡器中，以180r/min持续震荡40min，将面料取出后用去离子水对面料进行反复冲洗，置于80℃烘箱中干燥15min即可；2) Add the dried fabric to the finishing liquid at a bath ratio of 1:130, place it in an 80℃ water bath constant temperature oscillator, and oscillate at 180r/min for 40min. After taking out the fabric, rinse it repeatedly with deionized water, and dry it in an 80℃ oven for 15min.
所述染色具体操作如下：将定型后的面料先在60℃的处理液中进行处理，其中，浴比1：30，处理液包含辛醇、醋酸和水，并且辛醇占比为1-3％，醋酸占比为3.5％，pH值为4，浸渍处理30min，取出织物，采用溢流喷射染色机，浴比控制为1：30，染色过程如下，将面料和水进到溢流喷射染色机中，加入配方量的浴中宝，保持温度30℃，转7min，然后升温至40℃，加入配方量的活性染料，转20min后，再加入配方量的元明粉，转18min后，加入配方量的纯碱，转15min后，加入配方量的液碱，转40min，结束染色，排出染色液，将面料取出后进行水洗、烘干；The dyeing is specifically performed as follows: the shaped fabric is first treated in a treatment solution at 60°C, wherein the bath ratio is 1:30, the treatment solution comprises octanol, acetic acid and water, and the octanol accounts for 1-3%, the acetic acid accounts for 3.5%, the pH value is 4, the immersion treatment is performed for 30 minutes, the fabric is taken out, and an overflow jet dyeing machine is used, the bath ratio is controlled to be 1:30, and the dyeing process is as follows: the fabric and water are put into the overflow jet dyeing machine, a formula amount of Yuzhongbao is added, the temperature is maintained at 30°C, the temperature is rotated for 7 minutes, and then the temperature is raised to 40°C, a formula amount of active dye is added, after rotating for 20 minutes, a formula amount of glauber powder is added, after rotating for 18 minutes, a formula amount of soda ash is added, after rotating for 15 minutes, a formula amount of liquid alkali is added, the dyeing is terminated, the dyeing solution is discharged, and the fabric is taken out for water washing and drying;
所述后处理具体操作如下：经过水洗、烘干后的面料，经离心脱水机脱水后，手工开幅经定型机烘干，温度125℃，车速40m/min，烘干后在平缸进行柔软加工，再经定型机定型，温度130℃，车速35m/min；之后，将面料送入气流砂洗机，在传动导轮带动下，面料在机内循环，并被喷射气流拍打，温度为90℃，时间80min，循环面料速700m/min；最后一步整理工序是汽蒸定型，定型布速50m/min，温度155℃。The specific operation of the post-treatment is as follows: the fabric after washing and drying is dehydrated by a centrifugal dehydrator, manually opened and dried by a setting machine at a temperature of 125°C and a speed of 40m/min. After drying, it is softened on a flat cylinder and then set by a setting machine at a temperature of 130°C and a speed of 35m/min; thereafter, the fabric is sent to an air flow sand washing machine, driven by a transmission guide wheel, the fabric circulates in the machine and is beaten by a jet air flow at a temperature of 90°C, a time of 80min, and a circulating fabric speed of 700m/min; the last step of the finishing process is steam setting, with a setting cloth speed of 50m/min and a temperature of 155°C.
对比例1：本对比例所提供的节能环保阻燃面料的染整工艺和实施例1大致相同，其主要区别在于：碳化钛颗粒未进行表面处理。Comparative Example 1: The dyeing and finishing process of the energy-saving, environmentally friendly and flame-retardant fabric provided in this comparative example is substantially the same as that of Example 1, with the main difference being that the titanium carbide particles are not surface treated.
对比例2：本对比例所提供的节能环保阻燃面料的染整工艺和实施例1大致相同，其主要区别在于：碳化钛颗粒表面未进行原位生长二氧化硅。Comparative Example 2: The dyeing and finishing process of the energy-saving, environmentally friendly and flame-retardant fabric provided in this comparative example is substantially the same as that of Example 1, with the main difference being that silicon dioxide is not grown in situ on the surface of the titanium carbide particles.
对比例3：本对比例所提供的节能环保阻燃面料的染整工艺和实施例1大致相同，其主要区别在于：复合碳化钛颗粒在实用前未进行预处理。Comparative Example 3: The dyeing and finishing process of the energy-saving, environmentally friendly and flame-retardant fabric provided in this comparative example is substantially the same as that of Example 1, with the main difference being that the composite titanium carbide particles are not pretreated before use.
对照组：本对比例所提供的节能环保阻燃面料的染整工艺和实施例1大致相同，其主要区别在于：选用市售的聚苯基膦酸二苯砜酯替代本发明中的复合阻燃颗粒。Control group: The dyeing and finishing process of the energy-saving and environmentally friendly flame-retardant fabric provided in this comparative example is substantially the same as that in Example 1, the main difference being that commercially available polyphenylphosphonic acid diphenyl sulfone ester is used to replace the composite flame-retardant particles in the present invention.
测试实验1：Test experiment 1:
面料断裂强力测试，参照GB/T39231-2013，纺织品织物拉伸性能测定Fabric breaking strength test, refer to GB/T39231-2013, Determination of tensile properties of textile fabrics
面料撕破强力测试，参照GB/T39171-2009，纺织品织物撕破性能测定Fabric tear strength test, refer to GB/T39171-2009, Determination of tear properties of textile fabrics
面料弹性和回复性能测试，参照ASTMD3107-2003，织物弹性回复率/定载荷伸长率的测试规定。Fabric elasticity and recovery performance test, refer to ASTMD3107-2003, fabric elastic recovery rate/constant load elongation test regulations.
采用上述测试方法，对实施例1-3提供的面料进行性能测试，测试结果如下表所示：The above test method was used to perform performance tests on the fabrics provided in Examples 1-3. The test results are shown in the following table:
表1Table 1
从上表可以看出，本发明中的面料经染整后，不仅手感柔软，弹性好，而且面料具有优良的尺寸稳定性，提高了面料的强度，使得面料不易发生破损，从而使得面料经久耐用。It can be seen from the above table that after dyeing and finishing, the fabric of the present invention is not only soft to the touch and has good elasticity, but also has excellent dimensional stability, which improves the strength of the fabric and makes the fabric less likely to be damaged, thereby making the fabric durable.
测试实验2：Test experiment 2:
对实施例1-3、对比例1-3以及对照组提供的面料进行阻燃性能测试，测试结果下表所示：The flame retardant properties of the fabrics provided by Examples 1-3, Comparative Examples 1-3 and the control group were tested, and the test results are shown in the following table:
表2Table 2
从上表可以看出，本发明中的面料，具有了优良的阻燃性能以及抑烟性能，并且面料表面构建的阻燃层，结构稳定，不易脱落，使得面料可以具有长久高效的阻燃效果。It can be seen from the above table that the fabric of the present invention has excellent flame retardant properties and smoke suppression properties, and the flame retardant layer constructed on the surface of the fabric has a stable structure and is not easy to fall off, so that the fabric can have a long-lasting and efficient flame retardant effect.
在本说明书的描述中，参考术语“一个实施例”、“示例”、“具体示例”等的描述意指结合该实施例或示例描述的具体特征、结构、材料或者特点包含于本发明的至少一个实施例或示例中。在本说明书中，对上述术语的示意性表述不一定指的是相同的实施例或示例。而且，描述的具体特征、结构、材料或者特点可以在任何的一个或多个实施例或示例中以合适的方式结合。In the description of this specification, the description with reference to the terms "one embodiment", "example", "specific example", etc. means that the specific features, structures, materials or characteristics described in conjunction with the embodiment or example are included in at least one embodiment or example of the present invention. In this specification, the schematic representation of the above terms does not necessarily refer to the same embodiment or example. Moreover, the specific features, structures, materials or characteristics described can be combined in any one or more embodiments or examples in a suitable manner.
以上公开的本发明优选实施例只是用于帮助阐述本发明。优选实施例并没有详尽叙述所有的细节，也不限制该发明仅为所述的具体实施方式。显然，根据本说明书的内容，可作很多的修改和变化。本说明书选取并具体描述这些实施例，是为了更好地解释本发明的原理和实际应用，从而使所属技术领域技术人员能很好地理解和利用本发明。本发明仅受权利要求书及其全部范围和等效物的限制。The preferred embodiments of the present invention disclosed above are only used to help illustrate the present invention. The preferred embodiments do not describe all the details in detail, nor do they limit the invention to the specific implementation methods described. Obviously, many modifications and changes can be made according to the content of this specification. This specification selects and specifically describes these embodiments in order to better explain the principles and practical applications of the present invention, so that those skilled in the art can understand and use the present invention well. The present invention is limited only by the claims and their full scope and equivalents.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116175720B (en)* | 2023-02-23 | 2024-08-09 | 江苏名天木业有限公司 | Waterproof flame-retardant wood composite floor and preparation method thereof |
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105220460A (en)* | 2015-11-13 | 2016-01-06 | 长兴县三星纺织有限公司 | The silk fabric that a kind of crease-resistant drapability is good |
| CN107059384A (en)* | 2016-12-28 | 2017-08-18 | 无为竟成服饰有限公司 | A kind of dyeing and finishing technology of polyester-cotton blend interwoven fabric |
| CN110527323A (en)* | 2019-07-15 | 2019-12-03 | 华南理工大学 | A kind of nano hybridization filler and preparation method thereof using the preparation of electrostatic self-assembled method |
| CN110670341A (en)* | 2019-10-25 | 2020-01-10 | 四川意龙科纺集团有限公司 | Continuous dyeing and finishing process for CVC/T400 interwoven fabric |
| CN112927950A (en)* | 2021-01-25 | 2021-06-08 | 安徽大学 | Preparation method and application of biaxial tension flexible energy storage device |
| CN113047058A (en)* | 2021-03-10 | 2021-06-29 | 安徽禾臣新材料有限公司 | Damping cloth with good wear resistance and preparation method thereof |
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11319251B2 (en)* | 2019-01-29 | 2022-05-03 | Qilu University Of Technology | Nickel-coated hexagonal boron nitride nanosheet composite powder, preparation and high performance composite ceramic cutting tool material |
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105220460A (en)* | 2015-11-13 | 2016-01-06 | 长兴县三星纺织有限公司 | The silk fabric that a kind of crease-resistant drapability is good |
| CN107059384A (en)* | 2016-12-28 | 2017-08-18 | 无为竟成服饰有限公司 | A kind of dyeing and finishing technology of polyester-cotton blend interwoven fabric |
| CN110527323A (en)* | 2019-07-15 | 2019-12-03 | 华南理工大学 | A kind of nano hybridization filler and preparation method thereof using the preparation of electrostatic self-assembled method |
| CN110670341A (en)* | 2019-10-25 | 2020-01-10 | 四川意龙科纺集团有限公司 | Continuous dyeing and finishing process for CVC/T400 interwoven fabric |
| CN112927950A (en)* | 2021-01-25 | 2021-06-08 | 安徽大学 | Preparation method and application of biaxial tension flexible energy storage device |
| CN113047058A (en)* | 2021-03-10 | 2021-06-29 | 安徽禾臣新材料有限公司 | Damping cloth with good wear resistance and preparation method thereof |
| Title |
|---|
| 碳化钛 含镍杂化物对聚氨酯阻燃性能的影响研究;邱纹汐等;《安全与环境工程》;20220331;第29卷(第2期);第24页第1.1节、第1.2.1和1.2.2节、第25页第2.2节、第29页左栏最后一段以及右栏第3部分结论* |
| Publication number | Publication date |
|---|---|
| CN114645450A (en) | 2022-06-21 |
| Publication | Publication Date | Title |
|---|---|---|
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