Full-automatic ozone water makerTechnical Field
The invention relates to the technical field of water electrolysis equipment, in particular to a full-automatic ozone water manufacturing machine.
Background
The ozone water is manufactured by two methods of electric air shock and electrolytic water, the electric air shock method generates a large amount of ozone gas after one-time air shock, then the gas is dissolved into the water by means of gas mixing and the like to quickly obtain a large amount of ozone water with higher concentration, but the concentration of the ozone water cannot be monitored, so that the feedback effect is not achieved, and meanwhile, low-concentration or trace ozone water cannot be manufactured in real time. The electrolyzed water can be used to obtain oxidation products such as hydrogen peroxide, ozone, hypochlorous acid (residual chlorine in water), etc. People disinfect the water body and the surrounding environment through the oxidation products. The water electrolysis device usually only has one anode and one cathode or a plurality of electrode plates, but the electrode plates are mutually conducted and can be regarded as one electrode, so that the module is only switched on and off in two stages, and the concentration of the oxidation product can be controlled only by controlling the current between the anode and the cathode. The control of the oxide concentration in the electrolyzed water is necessary, and the required power is different due to different water use scenes, so that the existing ozone water electrolysis equipment has the following problems:
1. the concentration is not adjustable: the concentration of the oxide is too high in the existing electrolysis device due to the unadjustable concentration, so that the oxidation damage is generated to the surrounding environment; the concentration of the oxide is too low to achieve the disinfection effect at high flow; and when the flow is low, large current is adopted to heat and wear the electrode plates, so that the aging and scaling of the electrode plates are accelerated;
2. it is difficult to control the oxide concentration by adjusting the voltage and current of the electrolyzer: in the actual research and development process, because the current is in dynamic change all the time, even if the current is operated in a current constant-current mode, the slope of voltage to current is changed, and the slopes of scale, water flow speed and power supply fluctuation are also larger, so that relatively large current change is brought by slight voltage change, and the control of the oxide concentration by adjusting the voltage and the current of the electrolysis device is difficult. As the time of use increases, scaling between the electrodes can cause the oxide yield to decrease for the same current;
3. mounting and dismounting are irreversible: because inside fastening and waterproof have higher requirement, so inside most can be sealed with glue or adopt silica gel in the current electrolysis module, so can't not harm and disassemble, unpack apart moreover and will not recover.
4. The ozone concentration of the water discharged by the water electrolysis technology is uneven, the ozone concentration is relatively low at a large flow rate, and the ozone concentration is relatively high at a low flow rate. Ozone water with specific concentration can not be manufactured, ozone concentration feedback information is lacked, trace ozone water can not be manufactured, the ozone water can not be used as it is, and ozone gas leakage and nitrogen oxide harm exist.
Therefore, a fully automatic ozone water producing machine capable of stably electrolyzing and producing oxides with different concentrations is required.
Disclosure of Invention
One of the purposes of the invention is to provide a full-automatic ozone water maker, a bypass water supply pipe is arranged in parallel at one side of a main water supply pipe, and the high-precision flow sensor in the main water supply pipe is matched with a one-way valve and a high-flow sensor in the bypass water supply pipe to meet the requirements of starting high-flow equipment and low-flow equipment; meanwhile, the ozone module with controllable electrolytic power is combined with a water flow sensor, so that the concentration of ozone is kept consistent under the conditions of high flow and low flow. And the electrodes at both sides of the electrode assembly are made of different materials, and different electrolytic products are generated when the different materials are used as anodes, so that the ozone water maker has various modes.
In order to realize the purpose of the invention, the technical scheme adopted by the invention is as follows:
a full automatic ozone water producing machine comprising:
the water path system comprises a water inlet pipe, a water outlet pipe, a main water feeding pipe and a bypass water feeding pipe, wherein the main water feeding pipe comprises a first water inlet end and a first water outlet end, the bypass water feeding pipe comprises a second water inlet end and a second water outlet end, the water inlet pipe comprises a third water inlet end and a third water outlet end, the water outlet pipe comprises a fourth water inlet end and a fourth water outlet end, the second water inlet end and the first water inlet end are connected with the third water outlet end of the water inlet pipe through a three-way joint, and the second water outlet end and the first water outlet end are connected with the fourth water inlet end through a three-way joint, so that the main water feeding pipe and the bypass water feeding pipe are arranged between the water inlet pipe and the water outlet pipe; the main water supply pipe and the bypass water supply pipe are arranged in parallel, and both the main water supply pipe and the bypass water supply pipe can be communicated with the water inlet pipe and the water outlet pipe;
the sensor module comprises a large-flow sensor, a one-way valve and a high-precision flow sensor, the high-precision flow sensor is arranged in the main water supply pipe between a first water inlet end and a first water outlet end, the large-flow sensor and the one-way valve are arranged in the bypass water supply pipe, and the one-way valve is used for enabling water flow to the second water outlet end from a second water inlet end in a one-way mode;
the electrolytic module is arranged on the water inlet pipe or the water outlet pipe and comprises an electrolytic cavity, an electrode assembly and electrode pins, a water inlet and a water outlet are respectively formed in two ends of the electrolytic cavity, an electrolytic tank for water circulation is arranged in the electrolytic cavity, and an assembly hole is formed in the wall of the electrolytic cavity; the electrode assembly is arranged in the electrolytic cell and is used for electrolyzing water flowing in the electrolytic cell, the electrode assembly comprises at least one first electrode, at least two second electrodes and a proton exchange membrane arranged between the first electrode and the second electrode, the electrode pins comprise a first group of electrode pins and a second group of electrode pins, the first group of electrode pins are connected with the first electrode, and the second group of electrode pins are connected with the second electrode;
the monitoring module comprises one or two of an ozone concentration detector and an ORP value tester, and the ozone concentration detector and the ORP value tester are arranged at the downstream of the electrolysis module and are used for monitoring the ozone concentration and the ORP value in the ozone water;
the central controller is used for collecting data information transmitted by the sensor module, the electrolysis module and the monitoring module, the central controller can be used for controlling the start and stop of the electrolysis module, and the central controller is further provided with a display and regulation module which is used for setting corresponding ozone concentration to control the electrolysis strength of the electrolysis module.
The display and regulation module is provided with a key or a control panel for displaying the ozone concentration and the ORP value and regulating the water quality condition numerical value, the water quality condition is fed back to the central controller through the two water quality detection instruments of the ozone concentration detector and the ORP detector, the electrolysis capacity of the electrolysis module is regulated through regulating the key or the control panel on the display and regulation module, the specific ozone concentration is low, the current is increased or the conduction quantity of the second electrode is increased, and the ozone concentration is high, the current is reduced or the conduction quantity of the second electrode is reduced so that the water quality is maintained at the specified numerical value.
The full-automatic ozone water maker in the embodiment further comprises a cleaning module, the cleaning module comprises a cleaning water pipe, an electromagnetic valve, a three-way joint, a water storage tank and a water pump, two ends of the cleaning water pipe are respectively connected with the water inlet pipe and the water outlet pipe, the water storage tank and the water pump are arranged on the cleaning water pipe, the electromagnetic valve is arranged in the cleaning water pipe, descaling liquid is stored in the water storage tank, the electromagnetic valve is opened, the water pump is used for conveying the descaling liquid in the water storage tank to the waterway system, and the main water supply pipe, the bypass water supply pipe and the electrolysis module are washed.
The cleaning module is in a closed state during operation of the electrolysis module.
Preferably, the monitoring module further comprises a TDS detector, the TDS detector is electrically connected with the central controller, and the TDS detector is arranged at the downstream of the electrolysis module and used for detecting the water quality in the electrolyzed water.
The TDS detector is used for detecting the total amount of various soluble mineral salts in water, including inorganic salts and organic matters. By detecting the total amount of soluble mineral salts, the total mineralization of the water quality of the electrolyzed ozone water can be analyzed. The central controller collects a TDS value of the electrolyzed water fed back by the TDS detector, the TDS value can be displayed on the display and adjustment module, the TDS set value can be adjusted by the display and adjustment module, the automatic cleaning time is found by combining the monitored current information of the electrolysis module, when the detected TDS value is larger than the set value or the monitored current information of the electrolysis module is smaller under the condition of normal water flow (generally caused by electrode fouling or damage), the central controller sends an instruction to close a third water inlet end of the water inlet pipe and a fourth water outlet end of the water outlet pipe, open an electromagnetic valve in the cleaning module, and sequentially convey the descaling liquid in the water storage tank to the water inlet pipe, the main water inlet pipe, the bypass water inlet pipe, the water outlet pipe and the electrolysis module positioned on the water inlet pipe or the water outlet pipe through the water pump and finally flow back to the cleaning water pipe, and completing the circulating cleaning to realize the automatic cleaning of the waterway system and the electrolysis module.
Preferably, the device also comprises an alarm module, wherein the alarm module compares the ozone concentration value detected by the ozone concentration detector with a preset concentration, compares the ORP value detected by the ORP value tester with a preset value, and alarms when the concentration is lower than the preset value. And meanwhile, when the current information of the electrolysis module is monitored to be reduced to a set value under the condition of normal water flow, the alarm module is started to give an alarm, wherein the condition is generally caused by electrode fouling or damage.
Preferably, the inner side wall of the first electrode and the inner side wall of the second electrode are oppositely arranged, the plurality of second electrodes are arranged at intervals and independently, and a conductive film is plated on the substrate of one or both of the first electrode and the second electrode, and is a conductive diamond coating; the first group of electrode pins comprise electrode pins with the number larger than or equal to that of the first electrodes, the second group of electrode pins comprise electrode pins with the number larger than or equal to that of the second electrodes, the electrode pins penetrate through the assembly holes to be connected with a power supply, and the first electrodes and the second electrodes at different positions are connected through the electrode pins, so that different opposite electrifying areas are formed between the first electrodes and the second electrodes, and the working capacitance and resistance of the electrode assembly are changed. When the area of the opposite current is larger, the capacitance is larger, and the resistance is smaller.
Preferably, the electrode pin and the electrode assembly are connected by bonding or abutting.
Preferably, the electrode pin is an elastic conductive clip, the elastic conductive clip connected with the first electrode is in contact with the conductive film on the first electrode, and the elastic conductive clip connected with the second electrode is in contact with the conductive film on the second electrode.
Preferably, the electrode pins are fastening rod members, the fastening rod members include a first group of fastening rod members and a second group of fastening rod members, which are oppositely arranged, the first group of fastening rod members includes fastening rod members greater than or equal to the number of the first electrodes, the second group of fastening rod members includes fastening rod members greater than or equal to the number of the second electrodes, one end of the fastening rod members in the first group of fastening rod members passes through the assembly holes into the electrolytic bath and abuts against the outer side wall of the first electrodes, and one end of the fastening rod members in the second group of fastening rod members passes through the assembly holes into the electrolytic bath and abuts against the outer side wall of the second electrodes, so that the fastening rod members clamp and fix the electrode assembly in the electrolytic bath. The tightness of the first group of fastening rod pieces and the tightness of the second group of fastening rod pieces on the second electrode and the first electrode are adjusted to enable the two electrodes to be always kept clamped, so that the proton exchange membrane between the second electrode and the first electrode is ensured to be clamped, and the influence caused by the enlargement of the gap between the first electrode and the second electrode when water is electrolyzed is avoided. The fastening member is sleeved with a waterproof rubber ring, the waterproof rubber ring is sleeved at one end, far away from the electrolytic cavity, of the fastening member, the waterproof rubber ring is matched with one end of the fastening member to seal the assembly hole, and the waterproof rubber ring can play a role in sealing a connection gap between the fastening member and the assembly hole and is used for preventing water from seeping out of the assembly hole.
Preferably, the fastening rod pieces are metal conductor rod pieces, the first group of fastening rod pieces are connected with the positive pole of the power supply through a lead, and the second group of fastening rod pieces are connected with the negative pole of the power supply through a lead.
Preferably, the electrode assembly further comprises a tightness adjusting piece, a pressing piece and a pressing cover, mounting cavities communicated with the assembling holes are formed in two sides of an electrolytic cell of the electrolytic cavity, and the two ends of the electrolytic cavity are respectively provided with one pressing cover for sealing the mounting cavities;
the electrode pin comprises a first rod body, a second rod body and a clamping rod body arranged between the first rod body and the second rod body, the diameter of the clamping rod body is larger than that of the assembling hole, the first rod body penetrates through the assembling hole to be abutted against the first electrode or the second electrode, the clamping rod body and the second rod body are arranged in the mounting cavity, a spring is sleeved on the second rod body, one end of the spring is abutted against the end face of the clamping rod body, and the other end of the spring is abutted against the inner side of the gland;
still set up the fixed part on the electrolysis cavity, set up first connection chamber on the fixed part set up on the gland and be close to the second of electrolysis cavity is connected the chamber and is close to the third of the gland outside is connected the chamber, the fixed part is worn to establish on the second connects the chamber, the second connect the chamber with the third connects the chamber intercommunication, just the fixed part with gland dress matches the back first connection chamber with the chamber intercommunication is connected to the third, it is equipped with the preforming still to paste on the lateral wall of gland, set up on the clamp plate in the central mounting hole at center and with the side mounting hole, the elasticity regulating part passes the central mounting hole the third connect the chamber and the second connect the chamber will the gland with the electrolysis cavity links together.
According to the arrangement, the distance between the gland and the electrolytic cavity is adjusted by adjusting the assembling depth of the tightness adjusting piece, and then the compression amount of the spring between the clamping rod body and the gland is adjusted, so that the pressing force of the electrode pin on the electrode assembly is adjusted.
Preferably, the slack adjuster is a screw or a bolt.
Preferably, the press cover is further provided with a through hole communicated with the side opening hole, so that the first electrode or the second electrode in the motor assembly extends out of the mounting cavity, the through hole and the side mounting hole and is connected with a power supply.
Preferably, the fixing part is arranged at the central position outside the two side walls of the electrolytic cavity, so that the connection stress of the gland and the electrolytic cavity is balanced, and the connection stability and the subsequent adjustment stability are ensured.
Preferably, the electrode assembly includes one first electrode and at least two rows of second electrodes, the number of the second electrodes in each row is at least two, the second electrodes in each row are arranged along the length direction of the first electrode, and each second electrode is connected to one electrode pin.
Preferably, the electrode assembly comprises one first electrode and two second electrodes, the two second electrodes are arranged at intervals, and the sum of the areas of the sides, facing the first electrode, of the two second electrodes is smaller than or equal to the area of the side, facing the second electrode, of the first electrode.
Preferably, the electrode assembly includes at least two rows of first electrodes and at least two rows of second electrodes, the number of the first electrodes in each row is at least one, the number of the second electrodes in each row is at least one, and each first electrode is disposed opposite to one or more second electrodes.
Preferably, each of the first electrodes is disposed opposite to all or a part of the plurality of second electrodes. With such an arrangement, it is possible to obtain as high a facing area gradient as possible with as few electrodes as possible, thereby enabling the electrode assembly to obtain a larger number of current regulation gradients.
Preferably, the electrode pin is an inert metal. Due to the characteristics of the inert metal, the second electrode cannot be dissolved in the electrolytic process, and elements such as a silica gel rubber piece for fixing and the like are not arranged in the electrolytic cell, so that the service life of the whole ozone water generator is greatly prolonged. Meanwhile, if the electrode pin is a fastening rod piece, the fastening rod piece can facilitate the leading-in of a later-stage wire, a weldable wire can be led out in a mode that the lead is clamped on the fastening rod piece through a clamp, or the weldable wire is led out in a mode that the wire is wound on the fastening rod piece, or the weldable wire is led out in a mode that the wire is arranged on the fastening rod piece in a penetrating mode, so that the first fastening rod piece is connected with the positive pole of a power supply, and the second fastening rod piece is connected with the negative pole of the power supply.
More preferably, the electrode pin is a titanium contact post.
Preferably, the substrate of the first electrode and the second electrode is one or more of inert metal and stainless steel.
More preferably, the first electrode is a titanium sheet, the second electrode is a BDD electrode sheet, and the PEM membrane is arranged between the titanium sheet and the BDD electrode sheet, wherein the area of the titanium sheet is larger than the sum of the areas of the BDD electrodes. The first electrode is connected with the positive electrode of a power supply through an electrode pin, the first electrode is an anode, and oxygen-enriched water is electrolyzed; if the second electrode is connected with the positive electrode of the power supply through the electrode pin, the second electrode is the anode, meanwhile, the first electrode is connected with the negative electrode of the power supply, and the electrolyzed ozone water is ozone water.
Preferably, a current monitor is connected to the electrode assembly and used for monitoring the current of the electrode assembly. The first electrode and the second electrode at different positions are connected in the electrode assembly according to the electrode pins, so that the electrode assembly forms a plurality of combined electrodes, different combined currents are formed, and when the current monitor monitors that the combined current of the electrode assembly is smaller than a threshold value, other electrodes in the electrode assembly are started, so that the next combined electrode is started in a progressive mode. The service life of the whole module is prolonged, and the single normal service life time of the electrolysis module is prolonged. So as to overcome the problem that the single combination in the prior art only has the longest service life of 300-500h at a time in a more extreme working mode and can not meet the requirement of the national standard of more than or equal to 1000 h.
More preferably, the potential of the electrode pin is controlled by using an encoder, an MCU, or the like.
Preferably, the electrolytic cell further comprises a shell and an upper closing plate, wherein the shell is provided with an installation cavity for accommodating the electrolytic cavity, one end of the shell is connected with the upper closing plate, and the upper closing plate is arranged at the water inlet and used for closing the water inlet.
Preferably, the conductive film is a conductive diamond coating.
Preferably, the check valve is an electromagnetic valve, and the electromagnetic valve is used for controlling the water inlet flow in the bypass water supply pipe.
Preferably, the precision range of the high-precision flow sensor is 5 ml/min-50 ml/min.
Preferably, the precision range of the high-precision flow sensor is 20 ml/min-50 ml/min.
Preferably, the opening flow of the one-way valve is 50 ml/min-100 ml/min, and the precision direction of the large-flow sensor is 50 ml/min-100 ml/min.
The invention has the beneficial effects that:
1. the invention can be used for preparing ozone, can also be added with other electrolytes to prepare other disinfectants, or can be used for directly electrolyzing water to produce oxygen-enriched water, hydrogen-enriched water and the like, a bypass water supply pipe is arranged in parallel at one side of a main water supply pipe, a high-precision flow sensor in the main water supply pipe is matched with a one-way valve and a large-flow sensor in the bypass water supply pipe, and high-precision low starting flow and large-flow water flow output are obtained at the same time, so that the starting of high-flow equipment and low-flow equipment is met, and meanwhile, the flow information transmitted back by the high-precision flow sensor and the large-flow sensor is judged so as to control the conduction number of the second electrode, change the electrolysis area, achieve the purpose of controlling the electrolysis intensity by controlling the conduction number of the second electrode, and achieve the purpose of obtaining ozone water with the same concentration under the condition of adapting to different water yields;
2. the fastening rod piece can still adjust the distance between the gland and the electrode cavity by adjusting the tightness adjusting piece after the electrolytic module is installed, so that the pressure of the spring on the electrode pin is adjusted, and the tightness between the first electrode and the second electrode in the electrode assembly is further adjusted;
3. the first electrode and the second electrode at different positions are connected through the electrode pins, so that the electrode assembly forms various combined electrodes, and the effect of controlling the electrical characteristics of the electrolytic assembly is achieved by changing the difference value of the opposite areas between the electrode plates; different positive areas are achieved by giving different electric potentials to different electrode plates, voltage is further controlled to obtain finer electrolytic current, different combined currents are formed, so that the electrode assembly is controlled to achieve multi-gradient current, transition from small current to large current under the same voltage is achieved, stable electrolysis of water is achieved to generate oxides with different concentrations, power is controlled more conveniently, the requirement on a high-quality power supply is eliminated, and more use scenes are adapted. When the current monitor monitors that the combined current of the electrode assembly is smaller than the threshold value, other electrodes in the electrode assembly are started, so that the next combined electrode is started in a progressive mode, the service life of the whole module is prolonged, and the single normal service life time of the electrolysis module is prolonged. So as to overcome the problem that the single longest service life of the prior art is only 300-500h in a relatively extreme working mode by using a single combination and can not meet the requirement that the national standard is more than or equal to 1000 h;
4. in the aspect of practicability, compared with the problems that the requirement of the steady current on the power supply is high and the power supply generates heat seriously when the voltage is changed in the prior art, the invention can reduce the requirement of the power supply on the voltage control capability, only needs one constant voltage source and a central control circuit, and does not need to be provided with a constant current chip.
Drawings
Fig. 1 is a schematic block diagram of a fully automatic ozone water producing machine 1;
FIG. 2 is a schematic view showing a structure of a fully automatic ozone water producing machine;
FIG. 3 is a schematic view showing the structure of an electrolysis module in a fully automatic ozone water producing machine;
FIG. 4 is a schematic view showing a structure of an electrolytic module removing case in a fully automatic ozone water producing machine;
FIG. 5 is an exploded view of FIG. 4;
FIG. 6 is a front view of FIG. 4;
FIG. 7 is a cross-sectional view taken along A-A of FIG. 6;
FIG. 8 is a front view of FIG. 4;
FIG. 9 is a cross-sectional view taken along line B-B of FIG. 8;
FIG. 10 is a structural view of an electrode assembly ofembodiment 4 in a fully automatic ozone water producing machine;
FIG. 11 is a structural view of an electrode assembly inembodiment 5 of a fully automatic ozone water producing machine;
reference numerals:
1. a main water supply pipe; 11. a high precision flow sensor; 2. a bypass water supply pipe; 21. a one-way valve; 22. a high flow sensor; 3. a water inlet pipe; 4. a three-way joint; 5. a water outlet pipe; 6. an electrolysis module; 61. an electrolysis chamber; 611. an electrolytic cell; 612. a mounting cavity; 613. a water outlet; 614. a water inlet; 615. an installation part; 6151. a first connection chamber; 616. a cathode water outlet pipe; 617. an anode water outlet pipe; 62. an electrode assembly; 621. a first electrode; 622. a second electrode; 63. an electrode pin; 631. a first set of electrode pins; 632. a second group of electrode pins; 6331. a first rod body; 6332. clamping the rod body; 6333. a second rod body; 64. a gland; 641. a second connection chamber; 642. a third connecting cavity; 643. a through hole; 65. tabletting; 651. a central mounting hole; 66. a slack adjuster; 67. a spring; 68. a housing; 69. an upper closure cap; 4. an upper closing plate; 7. a water storage tank; 8. and (4) a water pump.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
It should be noted that, if directional indication is involved in the embodiment of the present invention, the directional indication is only used for explaining the relative positional relationship, the motion situation, and the like between the components in a certain posture, and if the certain posture is changed, the directional indication is changed accordingly. In addition, if there is a description of "first", "second", etc. in an embodiment of the present invention, the description of "first", "second", etc. is for descriptive purposes only and is not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated.
As shown in fig. 1 and 2, a full automatic ozone water maker includes:
the water path system comprises a water inlet pipe 3, a water outlet pipe 5, a main water feeding pipe 1 and a bypass water feeding pipe 2, wherein the main water feeding pipe 1 comprises a first water inlet end and a first water outlet end, the bypass water feeding pipe 2 comprises a second water inlet end and a second water outlet end, the water inlet pipe 3 comprises a third water inlet end and a third water outlet end, the water outlet pipe 5 comprises a fourth water inlet end and a fourth water outlet end, the second water inlet end and the first water inlet end are connected with the third water outlet end of the water inlet pipe 3 through a three-way joint 4, and the second water outlet end and the first water outlet end are connected with the fourth water inlet end through a three-way joint 4, so that the main water feeding pipe 1 and the bypass water feeding pipe 2 are arranged between the water inlet pipe 3 and the water outlet pipe 5; the arrangement is such that the main water supply pipe 1 and the bypass water supply pipe 2 are arranged in parallel, and both the main water supply pipe 1 and the bypass water supply pipe 2 can be communicated with the water inlet pipe 3 and the water outlet pipe 5;
the sensor module comprises a large-flow sensor 22, a one-way valve 21 and a high-precision flow sensor 11, the high-precision flow sensor 11 is arranged in the main water supply pipe 1 between a first water inlet end and a first water outlet end, the large-flow sensor 22 and the one-way valve 21 are arranged in the bypasswater supply pipe 2, and the one-way valve 21 is used for enabling water flow to the second water outlet end from a second water inlet end in a one-way mode;
theelectrolysis module 6 is mounted on thewater inlet pipe 3 or thewater outlet pipe 5, theelectrolysis module 6 comprises anelectrolysis cavity 61, anelectrode assembly 62 and electrode pins 63, awater inlet 614 and awater outlet 613 are respectively arranged at two ends of theelectrolysis cavity 61, anelectrolysis bath 611 for supplying water to circulate is arranged in theelectrolysis cavity 61, and an assembly hole is arranged on the cavity wall of theelectrolysis cavity 61; theelectrode assembly 62 is installed in theelectrolytic cell 611, theelectrode assembly 62 is used for electrolyzing water circulating in theelectrolytic cell 611, theelectrode assembly 62 comprises at least onefirst electrode 621, at least twosecond electrodes 622, and a proton exchange membrane arranged between thefirst electrode 621 and thesecond electrode 622, the electrode pins 63 comprise a first group of electrode pins 631 and a second group of electrode pins 632, the first group of electrode pins 631 is connected with thefirst electrode 621, and the second group of electrode pins 632 is connected with thesecond electrode 622;
a monitoring module including one or both of an ozone concentration detector and an ORP value tester, which are disposed downstream of theelectrolysis module 6 for monitoring the ozone concentration and the ORP value in the ozone water;
the central controller is used for collecting data information transmitted by the sensor module, theelectrolysis module 6 and the monitoring module, the central controller can be used for controlling the start and stop of theelectrolysis module 6, and the central controller is also provided with a display and regulation module which is used for setting corresponding ozone concentration to control the electrolysis strength of theelectrolysis module 6.
The display and adjustment module is provided with a key or a control panel for displaying the ozone concentration and the ORP value and adjusting the water quality condition value, the water quality condition is fed back to the central controller through the two water quality detection instruments of the ozone concentration detector and the ORP detector, the electrolysis capacity of theelectrolysis module 6 is adjusted through adjusting the key or the control panel on the display and adjustment module, the specific ozone concentration is low, the current is increased or the conduction number of thesecond electrode 622 is increased, and the ozone concentration is high, the current is reduced or the conduction number of thesecond electrode 622 is reduced, so that the water quality is maintained at the specified value.
As shown in fig. 2, the full-automatic ozone water maker further comprises a cleaning module, wherein the cleaning module comprises a cleaning water pipe, an electromagnetic valve, a three-way joint 4, a water storage tank 7 and awater pump 8, two ends of the cleaning water pipe are respectively connected with thewater inlet pipe 3 and thewater outlet pipe 5, the water storage tank 7 and thewater pump 8 are arranged on the cleaning water pipe, the electromagnetic valve is arranged in the cleaning water pipe, descaling liquid is stored in the water storage tank 7, the descaling liquid in the water storage tank 7 is conveyed to the waterway system by opening the electromagnetic valve, and the main water conveying pipe 1, the bypasswater conveying pipe 2 and theelectrolysis module 6 are washed.
The cleaning module is in a closed state during operation of theelectrolysis module 6.
Preferably, the monitoring module further comprises a TDS detector, the TDS detector is electrically connected with the central controller, and the TDS detector is arranged at the downstream of theelectrolysis module 6 and used for detecting the water quality in the electrolyzed water.
The TDS detector is used for detecting the total amount of various soluble mineral salts in water, including inorganic salts and organic matters. By detecting the total amount of soluble mineral salts, the total mineralization of the water quality of the electrolyzed ozone water can be analyzed. The central controller collects a TDS value of the electrolyzed water fed back by the TDS detector, the TDS value can be displayed on the display and adjustment module, the TDS set value can be adjusted by the display and adjustment module, the monitored current information of theelectrolysis module 6 is combined to find an automatic cleaning occasion, when the detected TDS value is larger than the set value or the monitored current information of theelectrolysis module 6 is smaller under the condition of normal water flow (generally caused by electrode scale deposition or damage), the central controller sends an instruction to close a third water inlet end of thewater inlet pipe 3 and a fourth water outlet end of thewater outlet pipe 5 and open an electromagnetic valve in the cleaning module, the descaling solution in the water storage tank 7 is sequentially conveyed to thewater inlet pipe 3, the main water conveying pipe 1, the bypasswater conveying pipe 2, thewater outlet pipe 5 and theelectrolysis module 6 on thewater inlet pipe 3 or thewater outlet pipe 5 through thewater pump 8, and finally, the water flows back to the cleaning water pipe to complete the circular cleaning so as to realize the automatic cleaning of the water path system and theelectrolysis module 6.
The full-automatic ozone water producing machine also comprises an alarm module, wherein the alarm module is used for comparing the ozone concentration value detected by the ozone concentration detector with the preset concentration and comparing the ORP value detected by the ORP value tester with the preset value, and alarming when the concentration is lower than the preset value. Meanwhile, when the current information of theelectrolysis module 6 is monitored to be reduced to a set value under the condition of normal water flow, the alarm module is started to give an alarm, and the condition is generally caused by electrode fouling or damage.
As shown in fig. 3 to 9, in theelectrode assembly 62, the inner sidewall of thefirst electrode 621 and the inner sidewall of thesecond electrode 622 are oppositely disposed, the plurality ofsecond electrodes 622 are independently disposed at intervals, and a conductive film is plated on the substrate of one or both of thefirst electrode 621 and thesecond electrode 622; the first group of electrode pins 631 comprises electrode pins 63 with the number larger than or equal to that of thefirst electrodes 621, the second group of electrode pins 632 comprises electrode pins 63 with the number larger than or equal to that of thesecond electrodes 622, the electrode pins 63 penetrate through the assembly holes to be connected with a power supply, and thefirst electrodes 621 and thesecond electrodes 622 at different positions are connected through the electrode pins 63, so that different opposite electrifying areas are formed between thefirst electrodes 621 and thesecond electrodes 622, and further the working capacitance and the resistance of theelectrode assembly 62 are changed. When the area of the opposite current is larger, the capacitance is larger, and the resistance is smaller.
Theelectrode pin 63 and theelectrode assembly 62 are connected by bonding or abutting.
Preferably, the electrode pins 63 are fastening rods, the fastening rods include a first group of fastening rods and a second group of fastening rods, the first group of fastening rods includes fastening rods with the number greater than or equal to that of thefirst electrodes 621, the second group of fastening rods includes fastening rods with the number greater than or equal to that of thesecond electrodes 622, and the electric potential of the electrode pins 63 is controlled by using an encoder, an MCU, or the like. The first electrode 62121 and the second electrode 62222 at different positions are connected through theelectrode pin 63, so that theelectrode assembly 622 forms various combined electrodes, and the effect of controlling the electrical characteristics of the electrolytic assembly is achieved by changing the difference of the facing areas between the electrode plates; different positive areas are achieved by giving different electric potentials to different electrode plates, voltage is further controlled to obtain finer electrolytic current, different combined currents are formed, so that theelectrode assembly 622 is controlled to achieve multi-gradient current, transition from small current to large current under the same voltage is achieved, and stable electrolysis of water is achieved to generate oxides with different concentrations.
One end of the fastening bar of the first group of fastening bars passes through the fitting hole into theelectrolytic bath 611 and abuts on the outer sidewall of thefirst electrode 621, and one end of the fastening bar of the second group of fastening bars passes through the fitting hole into theelectrolytic bath 611 and abuts on the outer sidewall of thesecond electrode 622, so that the fastening bars clamp and fix theelectrode assembly 62 in theelectrolytic bath 611. The tightness of the first group of fastening rod pieces and the tightness of the second group of fastening rod pieces on thesecond electrode 622 and thefirst electrode 621 are adjusted to enable the two electrodes to be always clamped, so that the proton exchange membrane between thesecond electrode 622 and thefirst electrode 621 is ensured to be clamped, and the gap between thefirst electrode 621 and thesecond electrode 622 cannot be enlarged to generate influence when water is electrolyzed. Waterproof rubber ring is established to the cover on the fastening member, waterproof rubber ring cover is established the fastening member is kept away from the one end ofelectrolysis cavity 61, waterproof rubber ring cooperation the one end of fastening member is sealed the pilot hole, waterproof rubber ring can play the effect of sealing fastening member and pilot hole joint gap for prevent that water from following ooze in the pilot hole.
The fastening rod pieces are metal conductor rod pieces, the first group of fastening rod pieces are connected with the positive pole of the power supply through a lead, and the second group of fastening rod pieces are connected with the negative pole of the power supply through a lead.
As shown in fig. 5-9, theelectrode assembly 62 further includes aslack adjuster 66, apressing plate 65, and apressing cover 64, and theslack adjuster 66 is a screw or a bolt. Mountingcavities 612 communicated with the assembling holes are arranged on two sides of anelectrolytic tank 611 of theelectrolytic cavity 61, and two ends of theelectrolytic cavity 61 are respectively provided with onegland 64 for sealing the mountingcavities 612;
theelectrode pin 63 comprises a first rod body 6331, a second rod body 6333 and a clamping rod body 6332 arranged between the first rod body 6331 and the second rod body 6333, the diameter of the clamping rod body 6332 is larger than that of the assembly hole, the first rod body 6331 penetrates through the assembly hole and thefirst electrode 621 or thesecond electrode 622 in butt joint, the clamping rod body 6332 and the second rod body 6333 are arranged in theinstallation cavity 612, aspring 67 is sleeved on the second rod body 6333, one end of thespring 67 is in butt joint with the end face of the clamping rod body 6332, and the other end of thespring 67 is in butt joint with the inner side of thegland 64;
theelectrolytic cavity 61 is further provided with a fixing part, the fixing part is provided with a first connectingcavity 6151, thegland 64 is provided with a second connectingcavity 641 close to theelectrolytic cavity 61 and a third connectingcavity 642 close to the outer side of thegland 64, the fixing portion is disposed on thesecond connection cavity 641 in a penetrating manner, thesecond connection cavity 641 is communicated with thethird connection cavity 642, and the first connectingcavity 6151 is communicated with the third connectingcavity 642 after the fixing part is assembled and matched with thegland 64, the outer side wall of thegland 64 is also provided with apressing plate 65, the pressing plate is provided with acentral mounting hole 651 in the center, the inner walls of the first connectingcavity 6151 and the third connectingcavity 642 are provided with internal threads, theelastic member 66 passes through thecentral mounting hole 651, the third connectingcavity 642 and the second connectingcavity 641 to connect thepressing cover 64 and theelectrolysis chamber 61 together.
Theelectrolysis cavity 61 is further provided with a cathodewater outlet pipe 616 and an anodewater outlet pipe 617, which are respectively communicated with the cathode cavity and the anode cavity of theelectrolysis bath 611, so as to respectively discharge cathode water and anode water, thewater outlet 613 on theelectrolysis cavity 61 can also be provided with a separated cathode water outlet and an anode water outlet, and the anode water outlet and the cathode water outlet are communicated with thewater inlet pipe 3 or thewater outlet pipe 5 through different pipelines.
In this way, the distance between thepressing cover 64 and theelectrolytic chamber 61 is adjusted by adjusting the assembling depth of theelastic adjusting piece 66, and the compression amount of thespring 67 between the clamping rod 6332 and thepressing cover 64 is further adjusted, so as to adjust the pressing force of theelectrode pin 63 on theelectrode assembly 62. The fastening rod of the invention can adjust the distance between thegland 64 and the electrode cavity by adjusting thetightness adjusting piece 66 after theelectrolytic module 6 is installed, thereby adjusting the pressure of thespring 67 on theelectrode pin 63 and further adjusting the tightness between thefirst electrode 621 and thesecond electrode 622 in theelectrode assembly 62;
thegland 64 is further provided with a throughhole 643 communicated with the mountingcavity 612, so that thefirst electrode 621 or thesecond electrode 622 in the motor assembly extends out of the mountingcavity 612 and the throughhole 643 to be in contact connection with thepressing sheet 65, and further is connected with a power supply through thepressing sheet 65. The fixing part is arranged at the central position of the outer sides of the two side walls of theelectrolytic cavity 61, so that the connection stress of thegland 64 and theelectrolytic cavity 61 is balanced, and the connection stability and the subsequent adjustment stability are ensured.
Preferably, in this embodiment, theelectrode assembly 62 includes onefirst electrode 621 and twosecond electrodes 622, a sum of areas of sides of the twosecond electrodes 622 facing thefirst electrode 621 is smaller than or equal to an area of a side of thefirst electrode 621 facing thesecond electrode 622, theelectrode pin 63 is a fastening rod, the first group of fastening rods includes one fastening rod or two fastening rods, and if one fastening rod is provided, the fastening rod abuts against a central position of thefirst electrode 621, so that a supporting force applied by the fastening rod to thefirst electrode 621 is concentrated on the center, and clamping and fixing of thefirst electrode 621 and thesecond electrode 622 is ensured. If two fastening rods are provided, the two fastening rods are symmetrically disposed on two sides of the center of thefirst electrode 621 and abut against thefirst electrode 621.
Each of thefirst electrodes 621 is disposed opposite to all or a part of the plurality ofsecond electrodes 622. With this arrangement, it is possible to obtain as high a facing area gradient as possible with as few electrodes as possible, thereby allowing theelectrode assembly 62 to obtain a greater number of current regulation gradients.
Theelectrode pin 63 is an inert metal. Due to the characteristics of the inert metal, thesecond electrode 622 cannot be dissolved in the electrolysis process, and meanwhile, elements such as a silica gel rubber part for fixing and the like are not arranged in theelectrolytic bath 611, so that the service life of the whole ozone water generator is greatly prolonged. Meanwhile, if theelectrode pin 63 is a fastening rod piece, the fastening rod piece can facilitate the leading-in of a later-stage wire, a weldable wire can be led out in a mode that the lead is clamped on the fastening rod piece through a clamp, or the weldable wire is led out in a mode that the wire is wound on the fastening rod piece, or the weldable wire is led out in a mode that the wire is arranged on the fastening rod piece in a penetrating mode, so that the first fastening rod piece is connected with the positive pole of a power supply, and the second fastening rod piece is connected with the negative pole of the power supply.
Theelectrode pin 63 is a titanium contact post. The substrate of thefirst electrode 621 and thesecond electrode 622 is one or more of inert metal and stainless steel. Preferably, thefirst electrode 621 is a titanium sheet, thesecond electrode 622 is a BDD electrode sheet, and a PEM membrane is disposed between the titanium sheet and the BDD electrode sheet, wherein the area of the titanium sheet is larger than the sum of the areas of the BDD electrodes. Thefirst electrode 621 is connected with the positive electrode of the power supply through theelectrode pin 63, and thefirst electrode 621 is an anode and electrolyzed oxygen-enriched water; if thesecond electrode 622 is connected to the positive electrode of the power supply through theelectrode pin 63, thesecond electrode 622 is an anode, and thefirst electrode 621 is connected to the negative electrode of the power supply, so that the electrolyzed ozone water is obtained.
A current monitor is connected to theelectrode assembly 62 and is used to monitor the current of theelectrode assembly 62. Thefirst electrode 621 and thesecond electrode 622 in different positions are connected in theelectrode assembly 62 according to theelectrode pin 63, so that theelectrode assembly 62 forms a plurality of combined electrodes, and further forms different combined currents, when the current monitor monitors that the combined current of theelectrode assembly 62 is smaller than a threshold value, other electrodes in theelectrode assembly 62 are started, and then the next combined electrode is started in a progressive manner.
The potential of theelectrode pin 63 is controlled by using an encoder, an MCU, or the like. When the current monitor detects that the combined current of theelectrode assembly 62 is less than the threshold value, other electrodes in theelectrode assembly 62 are activated, so that the next combined electrode is activated in a progressive manner, thereby prolonging the service life of the whole module and prolonging the service life of theelectrolysis module 6 in a single normal use. So as to overcome the problem that the single combination in the prior art only has the longest service life of 300-500h at a time in a more extreme working mode and can not meet the requirement of the national standard of more than or equal to 1000 h.
Theelectrolysis module 6 further comprises ashell 68 and anupper closing plate 4, wherein theshell 68 is provided with aninstallation cavity 612 for accommodating theelectrolysis cavity 61, one end of theshell 68 is connected with theupper closing plate 4, and theupper closing plate 4 is arranged at thewater inlet 614 and used for closing thewater inlet 614.
The one-way valve 21 in the sensor module, which is located in the bypasswater supply pipe 2, is an electromagnetic valve, and the electromagnetic valve is used for controlling the water inlet flow in the bypasswater supply pipe 2. The precision range of the high-precision flow sensor 11 is 5 ml/min-50 ml/min. In the embodiment, the precision range of the high-precision flow sensor 11 is preferably 20ml/min to 50 ml/min. The opening flow of the one-way valve 21 is 50 ml/min-100 ml/min, and the precision direction of the large-flow sensor 22 is 50 ml/min-200 ml/min. Within the range, when the bypasswater supply pipe 2 reaches the opening flow value, the valve is opened, so that the bypasswater supply pipe 2 circulates, and the waterway starting device outputs large-flow water flow.
Thecheck valve 21 is used to prevent the water flow from the second water outlet end to the second water inlet end, so that the water flow can only flow from the second water inlet end to the second water outlet end. The bypasswater supply pipe 2 is provided with thecheck valve 21, so that the water flowing into the second water inlet end from the first water inlet end is blocked by thecheck valve 21, and a part of the water is forced to flow from the first water inlet end to the first water outlet end of the main water supply pipe 1 and flows through the high-precision flow sensor 11, so as to drive the high-precision flow sensor 11 to output a signal.
The bypasswater supply pipe 2 and the main water supply pipe 1 are arranged in parallel. The setting can make main flow pipe 1 the same withbypass flow pipe 2's rivers direction, thereby can not make rivers turn to and produce other resistances, sets up the volume that can save water route starting drive more simultaneously like this for the device is more portable and lower to installation space's requirement.
The opening flow of thecheck valve 21 and the large-precision flow sensor is larger than the maximum flow value of the high-precision flow sensor 11. Set up like this and when making the low flow that needs, the flow of rivers is always in highaccuracy flow sensor 11's response within range to make rivers only can enter into main flow pipe 1, and thecheck valve 21 ofbypass flow pipe 2 can not open, thereby make highaccuracy flow sensor 11 can give central controller with low flow signal transmission, be convenient for adjust the size of electric current inelectrolysis module 6, the circular telegram quantity ofsecond electrode 622 promptly. When high flow is needed, the flow of water flow exceeds the upper limit value of the high-precision flow sensor 11, and when the flow reaches the opening flow of thecheck valve 21, thecheck valve 21 is opened, and thecheck valve 21 and the high-flow sensor 22 send out signals at the same time, so that the high-flow signal is transmitted to the central controller, and the adjustment of the current in theelectrolysis module 6 is facilitated.
As shown in fig. 3, the electrode assembly includes one first electrode a and two second electrodes B and C, the two second electrodes B and C are arranged at intervals, and the sum of the areas of the sides of the two second electrodes B and C facing the first electrode is smaller than the area of the side of the first electrode facing the second electrode. The current of the electrolytic cell is controlled by controlling the area, arrangement and applied potential of the electrode plates, so that the ozone production power is controlled. Table 1 below shows the currents formed by the first electrode a and the various combined electrodes of the two second electrodes B and C:
table 1: current test data with three electrodes arranged for different combinations
As can be seen from table 1, the length, width, height and size of the first electrode a is 25mm × 7.8mm × 1.1mm, the length, width, height and size of the second electrode B is 15mm × 7.8mm × 1.1mm, the length, width, height and size of the second electrode C is 8mm × 7.8mm × 1.1mm, when the first electrode a is grounded, the first electrode a is the negative electrode of the electrode assembly, the second electrode B is suspended, the second electrode C is connected to the positive electrode of the power supply, the formed combined electrode is an AB combined electrode, the facing area of the first electrode a and the second electrode C is 7.8mm × 8mm, and the current in the electrolytic cell is measured to be 0.8A;
when the first electrode A is grounded, the first electrode A is the negative electrode of the electrode assembly, the second electrode C is suspended, and the second electrode B is connected with the positive electrode of the power supply, the formed combined electrode is an AC combined electrode, the facing area of the first electrode A and the second electrode B is 7.8mm x 15mm, and the current measured in theelectrolytic cell 11 is 1.5A;
when the second electrode B and the second electrode C are grounded, the second electrode B and the second electrode C are jointly combined into a negative electrode of an electrode assembly, the first electrode A is connected with a positive electrode of a power supply, the formed combined electrode is an ABC combined electrode, the facing area of the first electrode A, the second electrode B and the second electrode C is 7.8mm x 23mm, and the current measured in theelectrolytic cell 11 is 2A;
when the first electrode A is suspended, the second electrode C is grounded, the second electrode C is the cathode of the electrode assembly, the second electrode B is connected with the anode of the power supply, the formed combined electrode is a BC combined electrode, the facing area of the second electrode B and the second electrode C is 7.8mm x 1.1mm, and the current in the electrolytic cell is measured to be 0.1A; the current discharged from the electrode assembly is minimized.
According to the data, various combined electrodes can be obtained by connecting different electrode plates, for example, when the water flow is 50ml/min at low flow, the pin with the lowest starting current is matched, and when the water flow is 2L/min at high flow, the pin with the highest starting current is matched, so that the problem of uneven concentration is solved, the dynamic balance of heat dissipation and heating is improved, the electrode works in a proper environment, and the service life of the electrode is prolonged.
Example 2
This embodiment will be described only for differences from the above-described embodiment, and the remaining technical features are the same as those of the above-described embodiment. In this example, theelectrode pin 63 is an elastic conductive clip, the elastic conductive clip connected to thefirst electrode 621 contacts with a conductive film on thefirst electrode 621, and the elastic conductive clip connected to thesecond electrode 622 contacts with a conductive film on thesecond electrode 622.
Example 3
This embodiment will be described only for differences from the above-described embodiment, and the remaining technical features are the same as those of the above-described embodiment. In this embodiment, it is preferable that the fastening rod is a threaded fastening rod, the assembly hole is a threaded hole, and the fastening rod is in threaded connection with the assembly hole.
Example 4
This embodiment will be described only for differences from the above-described embodiment, and the remaining technical features are the same as those of the above-described embodiment. As shown in fig. 10, in this embodiment, theelectrode assembly 62 includes onefirst electrode 621 and at least two rows ofsecond electrodes 622, the number of the second electrodes in each row is at least two, thesecond electrodes 622 in each row are arranged along the length direction of thefirst electrode 621, and eachsecond electrode 622 is connected to oneelectrode pin 63.
Example 5
This embodiment will be described only for differences from the above-described embodiment, and the remaining technical features are the same as those of the above-described embodiment. As shown in fig. 11, theelectrode assembly 62 in this embodiment includes at least two rows offirst electrodes 621 and at least two rows ofsecond electrodes 622, the number of thefirst electrodes 621 in each row is at least one, the number of thesecond electrodes 622 in each row is at least one, and eachfirst electrode 621 is disposed opposite to one or moresecond electrodes 622.
Each of thefirst electrodes 621 is disposed opposite to all or a part of the plurality ofsecond electrodes 622. With this arrangement, it is possible to obtain as high a facing area gradient as possible with as few electrodes as possible, thereby allowing theelectrode assembly 62 to obtain a greater number of current regulation gradients.
Variations and modifications to the above-described embodiments may occur to those skilled in the art, which fall within the scope and spirit of the above description. Therefore, the present invention is not limited to the specific embodiments disclosed and described above, and some modifications and variations of the present invention should fall within the scope of the claims of the present invention. Furthermore, although specific terms are employed herein, they are used in a generic and descriptive sense only and not for purposes of limitation.