Detailed Description
The technical scheme of the invention is clearly and thoroughly described in the following with reference to the accompanying drawings. In the description of the present invention, it should be noted that, in the coordinate system XY provided herein, the X axis represents the length direction, and the Y axis represents the width direction. Also, it is noted that the terms "center", "longitudinal", "lateral", "length", "width", "thickness", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer", and the like, indicate orientations or positional relationships based on those shown in the drawings, and are only for convenience in describing and simplifying the description, but do not indicate or imply that the device or element referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus, should not be construed as limiting the invention.
In the description of the present specification, the description of the term "on the basis of the above-described embodiments" means that a specific feature, structure, material or characteristic described in connection with the embodiment or example is included in at least one preferred embodiment or preferred example of the present invention. Throughout this specification, the schematic representations of the terms used above do not necessarily refer to the same implementation or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
In order to further illustrate the present invention, the following examples are given to further illustrate the present invention.
The first aspect of the embodiments of the present invention provides a pole piece, which includes a current collector, the current collector includes a paste coating area and a blank foil area, which are sequentially arranged along a width direction, the paste coating area is provided with an active material layer, and the blank foil area is not provided with an active material layer;
the empty foil area comprises a glue-free area and a rubberizing area which are arranged along the width direction, no gummed paper is arranged in the glue-free area, gumming paper is arranged in the rubberizing area, and the rubberizing area is arranged on one side close to the paste coating area.
The pole pieces comprise a first pole piece and a second pole piece, the first pole piece and the second pole piece are both the pole pieces, the polarities of the first pole piece and the second pole piece are opposite, and the first pole piece can be a positive pole piece or a negative pole piece; correspondingly, the second pole piece is a negative pole piece or a positive pole piece. The active material layers arranged on the paste coating areas of the first pole piece and the second pole piece are different, if the first pole piece is a positive pole piece, the first active material layer arranged on the paste coating area of the first pole piece is a positive active material layer, and if the first pole piece is a negative pole piece, the first active material layer arranged on the paste coating area of the first pole piece is a negative active material layer; correspondingly, if the second pole piece is a negative pole piece, the second active material layer arranged in the paste coating area of the second pole piece is a negative pole active material layer, and if the second pole piece is a positive pole piece, the second active material layer arranged in the paste coating area of the second pole piece is a positive pole active material layer.
Specifically, referring to fig. 1 to 3, the first electrode sheet includes a firstcurrent collector 1, the firstcurrent collector 1 includes a firstpaste applying region 21 provided with a first active material layer (not labeled in the figures) and a firstempty foil region 3 provided with no first active material layer, and the firstpaste applying region 21 and the firstempty foil region 3 are sequentially arranged along a width direction of the firstcurrent collector 1; the firstempty foil area 3 comprises a first adhesive-free area and a first adhesive-pasting area (marked in the figure) which are arranged along the width direction, theadhesive paper 7 is not arranged in the first adhesive-free area, theadhesive paper 7 is arranged in the first adhesive-pasting area, and the first adhesive-pasting area is arranged on one side close to the first paste-coating area 21.
As shown in fig. 1, fig. 2 and fig. 4, the second electrode sheet includes a secondcurrent collector 4, the secondcurrent collector 4 includes asecond paste area 22 provided with a second active material layer (not shown in the figures) and a secondempty foil area 5 provided with no second active material layer, and thesecond paste area 22 and the secondempty foil area 5 are sequentially arranged along the width direction of the secondcurrent collector 4; the secondempty foil area 5 includes a second non-adhesive area and a second adhesive area (both marked in the figure) arranged along the width direction, the second non-adhesive area is not provided withadhesive paper 7, the second adhesive area is provided withadhesive paper 7, and the second adhesive area is arranged on one side close to thesecond pasting area 22.
In the embodiment of the invention, the adhesive paper is arranged on the empty foil area of the pole piece, and the empty foil area after being pasted with the adhesive paper has a certain thickness, so that the thickness difference between the empty foil area and the paste coating area can be reduced or eliminated, the surface of the battery cell prepared by winding or laminating the pole piece can be smoother, and the problem of poor flatness of the surface of the battery cell due to the large thickness difference between the whole pole lug plane and the whole battery cell is solved, so that the problems of potential safety hazard and influence on the storage performance and the cycle performance of the battery due to the deformation of an external aluminum-plastic film shell can be effectively avoided; in addition, one side edge of the pole piece is a glue-free area without adhesive paper, so that a thin welding surface is formed after the subsequent electric core is subjected to rubbing treatment, the welding difficulty is reduced, the welding success rate is improved, and the welding firmness is also improved.
On the basis of the above embodiment, the thickness of the first pasting region is the same as that of thefirst pasting region 21, and the thickness of the second pasting region is the same as that of thesecond pasting region 22, so that the thickness of the firstempty foil region 3 and the thickness of thefirst pasting region 21 after pasting the adhesive paper are the same, and the thickness of the secondempty foil region 5 and the thickness of thesecond pasting region 22 are the same, so that the thickness of the surface of the battery cell made by winding or laminating the first pole piece and the second pole piece is the same, the surface of the battery cell is kept flat, the problem of uneven surface of the battery cell due to the fact that the thickness of the whole pole lug plane is not the same as that of the whole battery cell is avoided, the surface of the external aluminum-plastic film shell is also guaranteed to be flat, and the aluminum-plastic film shell is prevented from deforming.
In this embodiment, the firstcurrent collector 1 and the secondcurrent collector 4 are one or more metal foils such as an aluminum foil, a copper foil, a nickel foil, a gold foil, or a platinum foil, and preferably, the firstcurrent collector 1 is an aluminum foil, and the secondcurrent collector 4 is a copper foil.
The length of theadhesive paper 7 is not greater than the lengths of the first and secondempty foil areas 3 and 5, that is, the length of theadhesive paper 7 is less than or equal to the lengths of the first and secondempty foil areas 3 and 5, theadhesive paper 7 may be continuously disposed on the first and/or secondempty foil areas 3 and 5, or may be disposed on the first and/or secondempty foil areas 3 and 5 in sections, that is, theadhesive paper 7 is disposed at intervals along the length direction in the first adhesive area of the firstempty foil area 3, and the area where theadhesive paper 7 is not disposed is located between the twoadhesive papers 7, and/or theadhesive paper 7 is disposed at intervals along the length direction in the second adhesive area of the secondempty foil area 5, and the area where theadhesive paper 7 is not disposed is located between the twoadhesive papers 7. The embodiment of the present invention does not further limit this, as long as it can ensure that the length of theadhesive paper 7 is not greater than the lengths of the first and secondempty foil regions 3 and 5, and that the thickness of the first adhesive region is the same as the thickness of thefirst pasting region 21, and the thickness of the second adhesive region is the same as the thickness of thesecond pasting region 22.
Theadhesive paper 7 is arranged on one side surface of the firstempty foil area 3 or theadhesive paper 7 is arranged on two side surfaces of the firstempty foil area 3, theadhesive paper 7 is arranged on one side surface or two side surfaces of the firstempty foil area 3 and is related to the first active material layer arranged on one side surface or two side surfaces of the firstpaste coating area 21, if the first active material layer is arranged on one side surface of the firstpaste coating area 21, theadhesive paper 7 is arranged on one side surface of the firstempty foil area 3; if the firstpaste applying region 21 is provided with the first active material layer on both surfaces, theadhesive sheet 7 is provided on both surfaces of the firstempty foil region 3.
Theadhesive paper 7 is arranged on one side surface of the secondempty foil area 5 or theadhesive paper 7 is arranged on both side surfaces of the secondempty foil area 5, theadhesive paper 7 is arranged on one side surface or both side surfaces of the secondempty foil area 5 and is related to the second active material layer arranged on one side surface or both side surfaces of the secondpaste coating area 22, if the second active material layer is arranged on one side surface of the secondpaste coating area 22, theadhesive paper 7 is arranged on one side surface of the secondempty foil area 5; if the secondpaste applying region 22 is provided with the second active material layer on both surfaces, theadhesive sheet 7 is provided on both surfaces of the secondempty foil region 5.
Theadhesive paper 7 is disposed on one side surface or both side surfaces of the first and secondempty foil areas 3 and 5 in this embodiment, which is not further limited, and may be set by those skilled in the art according to the actual situation, but generally, the efficiency of disposing theadhesive paper 7 on one side surface of the first and secondempty foil areas 3 and 5 is higher than the efficiency of disposing theadhesive paper 7 on both side surfaces of the first and secondempty foil areas 3 and 5.
Adhesive tape 7 includes adhesive layer and substrate layer, and the substrate layer presss from both sides and establishes between two adhesive layers, and wherein, the substrate layer can provide the support, and the adhesive layer is used for distinguishing first rubberizing district and second rubberizing fixedly to the messenger is put the electric core of coiling or the superpose formation in turn by first pole piece and second pole piece superpose and can be fixed into wholly, prevents that electric core is loose to influence the performance of battery.
Wherein, the material of the adhesive layer comprises at least one of water glue, oil glue, hot melt adhesive, natural rubber, synthetic rubber and conductive swelling glue. On the basis of the above embodiment, the material of the adhesive layer includes conductive swelling glue.
The conductive swelling glue has good swelling performance (the volume expansion rate of the conductive swelling glue soaked in the electrolyte at 25 ℃ for 24 hours is more than or equal to 100%) and conductivity (the conductivity is more than or equal to 10)4S/m) of the adhesive. The conductive swelling glue can fix the battery core, so that the battery core is not loose, and has a swelling function in the electrolyte, and in the process of recycling the battery core, the conductive swelling glue can move relatively along with the volume expansion of the battery core and is always tightly adhered to the firstempty foil area 3 and the secondempty foil area 5, so that the constant expansion effect can be achieved according to the thickness of the battery core and the capacity of the electrolyte, and the phenomenon that welding points between the firstempty foil area 3 and the secondempty foil area 5 are broken or fall off due to the volume expansion of the battery core is effectively avoided; in addition, the conductive swelling glue has conductive performance, so that the propagation path of lithium ions can be shortened, the internal resistance of the battery is reduced, and the rate capability of the battery is enhanced.
Specifically, the conductive swelling glue comprises a swelling component and a conductive component, wherein the swelling component can expand in volume in the presence of electrolyte, and can be effectively filled between first rubberizing areas of the firsthollow foil area 3 and between second rubberizing areas of the secondhollow foil area 5, so that the thicknesses of all positions of the battery core are consistent, the conductive swelling glue can be ensured to have conductive performance, and the influence of an adhesive layer on the internal resistance of the battery is avoided.
Wherein the swelling component is at least one of polyurethane acrylate, epoxy acrylate and polyester acrylate. The swelling component has a proper volume expansion rate in the electrolyte and a certain conductive function, and after being compounded with the conductive component, the conductivity of the conductive swelling adhesive can be better improved, and the internal resistance of the battery is reduced.
The conductive component is at least one of an organic conductive component, metal powder and graphite powder, wherein the organic conductive component comprises at least one of epoxy resin, organic silicon resin, polyimide resin, phenolic resin, polyurethane and acrylic resin; the metal powder includes at least one of copper, aluminum, iron, nickel, zinc, silver, and gold.
In this embodiment, the mixing ratio of the swelling component and the conductive component in the conductive swelling adhesive is not further limited, and a person skilled in the art can mix the swelling component and the conductive component according to a specific lithium ion battery electrolyte, as long as the conductive swelling adhesive has good swelling performance and conductivity.
In this embodiment, the material of the substrate layer is not further limited, and those skilled in the art can select the substrate according to actual situations as long as the substrate can provide better support, and for example, the material of the substrate layer is at least one of cast polypropylene, uniaxially stretched polypropylene, biaxially stretched polypropylene, polyethylene, polyester fiber, and polyvinyl chloride.
The thickness of theadhesive tape 7 is not further limited in this embodiment, as long as it can be ensured that the thickness of theadhesive tape 7 is the same as that of the first active material layer, the thickness of theadhesive tape 7 is the same as that of the second active material layer, so that the thickness of the first pole piece at the first adhesive region is the same as that of thefirst paste region 21, and the thickness of the second pole piece at the second adhesive region is the same as that of thesecond paste region 22. However, in order to make the conductive swelling paste exert its swelling action and conductive action well, on the substrate of the above embodiment, the thickness of both adhesive layers is 1 μm to 3 μm, and more preferably, the thickness of both adhesive layers is 2 μm; the thickness of the substrate layer can be set according to actual conditions.
The distance between theadhesive tape 7 arranged on the first adhesive tape pasting area and the firstpaste coating area 21 is 0-0.5 mm, and the distance between theadhesive tape 7 arranged on the second adhesive tape pasting area and the secondpaste coating area 22 is 0-0.5 mm, so that theadhesive tape 7 can be prevented from overlapping with the firstpaste coating area 21 and the secondpaste coating area 22 to influence the thickness of the first pole piece and the second pole piece.
With reference to fig. 1 to 6, a second aspect of the embodiment of the present invention provides a battery cell, including: the diaphragm comprises a first pole piece, a second pole piece and adiaphragm 6 arranged between the first pole piece and the second pole piece, wherein the polarities of the first pole piece and the second pole piece are opposite, and the first pole piece and the second pole piece are both pole pieces of the first aspect.
In the battery core provided by the embodiment, the adhesive tapes are respectively arranged in the first empty foil area and the second empty foil area, the thickness of the first empty foil area after the adhesive tapes are pasted is the same as that of the first paste coating area, and the thickness of the second empty foil area after the adhesive tapes are pasted is the same as that of the second paste coating area, so that the thickness difference between the first empty foil area and the first paste coating area and the thickness difference between the second empty foil area and the second paste coating area can be reduced or eliminated, the surface of the battery core made by winding or laminating the pole pieces can be smoother, the problem that the flatness of the surface of the battery core is poor due to the large thickness difference between the whole pole lug plane and the whole battery core is solved, and therefore, the problems that the potential safety hazard is generated and the storage performance and the cycle performance of the battery are affected due to the deformation of an aluminum plastic film shell arranged outside can be effectively avoided; the battery cell formed by overlapping and winding or alternately overlapping the first pole piece and the second pole piece can be fixed into a whole by arranging the adhesive tape in the empty foil area of the pole pieces, so that the whole battery cell can be connected more tightly, and the battery cell is prevented from loosening to influence the performance of the battery cell; in addition, one side edge of the pole piece is a glue-free area without adhesive paper, so that a thin welding surface is formed after the subsequent electric core is subjected to rubbing treatment, the welding difficulty is reduced, the welding success rate is improved, and the welding firmness is also improved.
Specifically, the first pole piece, the second pole piece and thediaphragm 6 may be stacked and wound to form a cell, or the first pole piece, the second pole piece and thediaphragm 6 may be stacked alternately to form a cell, no matter which way the cell is formed, so as to avoid short circuit caused by contact between the positive electrode tab and the negative electrode tab during welding, on the basis of the above embodiment, the firstpaste applying region 21 and the secondpaste applying region 22 are overlapped to form thepaste applying region 2, and the firstempty foil region 3 and the secondempty foil region 5 are respectively disposed at two opposite ends of thepaste applying region 2.
Wherein, theadhesive tape 7 sets up between first rubberizing district and second rubberizing district in succession, promptly, theadhesive tape 7 sets up between first rubberizing district in succession, and theadhesive tape 7 sets up between the second rubberizing district in succession, and scribbles the both sides of theadhesive tape 7 ofcream district 2 one end and be first rubberizing district, scribble the both sides of theadhesive tape 7 of the other end ofcream district 2 and be the empty rubberizing district of second.
After the first pole piece, the second pole piece and thediaphragm 6 are stacked and wound or alternately stacked to form the battery core, the firstempty foil area 3 and the secondempty foil area 5 need to be flattened, and the flattening process is to press down the originally vertical firstempty foil area 3 and the secondempty foil area 5, so that the firstempty foil area 3 and the secondempty foil area 5 of each stacked and wound or alternately stacked layer are mutually contacted, on one hand, a connecting sheet can be better welded, and on the other hand, a better current collecting effect can be achieved. In order to avoid the influence of the gummedpaper 7 on the flow concentration effect, the firstempty foil area 3 and the secondempty foil area 5 which are convenient to flatten can play a better flow concentration effect, a thinner welding surface can be provided after flattening is also convenient, welding is facilitated, the first glue-free area is arranged on the firstempty foil area 3 of the first pole piece, and the second glue-free area is arranged on the secondempty foil area 5 of the second pole piece, so that subsequent flattening treatment is facilitated.
Specifically, as shown in fig. 6, the area of the firstempty foil area 3 to which theadhesive paper 7 is attached is a firstadhesive area 31, and the area of the firstempty foil area 3 to which theadhesive paper 7 is not attached is a firstnon-adhesive area 32; the area of the secondempty foil area 5 to which the gummedpaper 7 is pasted is a second gummedarea 51, and the area of the secondempty foil area 5 to which the gummedpaper 7 is not pasted is a secondnon-gummed area 52. When the cell is flattened, performing flattening treatment on a first adhesive-free area 32 and a second adhesive-free area 52 which are not provided withadhesive tapes 7 at two ends of the cell, wherein after the flattening treatment, the thickness of the first adhesive-free area 31 is the same as that of thepaste coating area 2, the thickness of the first adhesive-free area 32 is smaller than that of the first adhesive-coatedarea 31, and a first welding surface which is perpendicular to the first adhesive-coatedarea 31 is formed on the side surface of the first adhesive-free area 31 after the first adhesive-free area 32 is flattened; similarly, the thickness of the secondadhesive region 51 is the same as that of thepaste applying region 2, the thickness of the second adhesive-free region 52 is smaller than that of the secondadhesive region 51, and a second bonding surface perpendicular to the secondadhesive region 51 is formed on the side surface of the secondadhesive region 51 after the second adhesive-free region 52 is flattened. First face of weld and second face of weld set up at the relative both ends of electric core, and first face of weld and second face of weld are regarded as two faces of weld of electric core respectively for the welding connection piece. From this, handle through rubbing the level and form two weld faces at the both ends of electric core, need welded number of piles when can reducing laser welding, the distance that the energy needs the transmission shortens, has reduced the welded degree of difficulty, has improved welded success rate greatly, has also improved the firm degree of welded, also can avoid easily welding when the welded connection piece and wear damage pole piece and diaphragm to effectively avoid causing the self discharge risk that the little short circuit arouses.
The way of the kneading and flattening treatment in this embodiment is not further limited, and those skilled in the art can select mechanical kneading and ultrasonic kneading and flattening according to actual situations.
As shown in fig. 6, an inverted L-shaped first connectingplate 8 and an L-shaped second connecting plate 9 are further welded on the battery cell, wherein one end of the first connectingplate 8 is welded on the first welding surface, and the other end of the first connecting plate leads out the first pole piece from the battery cell to provide a contact point during charging and discharging; one end of the second connecting sheet 9 is welded on the second welding surface, and the other end of the second connecting sheet leads out the second pole piece from the battery cell to provide a contact point during charging and discharging.
In this embodiment, the shapes of the first connectingpiece 8 and the second connecting piece 9 may also be rectangular, T-shaped, or the like, and the shapes of the first connectingpiece 8 and the second connecting piece 9 may be the same or different, which is not further limited in this embodiment of the present invention, and those skilled in the art may select the connecting pieces according to actual situations.
It should be noted that, in the present embodiment, specific dimensions of the first connectingpiece 8 and the second connecting piece 9 are not further limited, and those skilled in the art can adjust the dimensions according to actual situations; in this embodiment, the first connectingpiece 8 and the second connecting piece 9 are made of metal, for example: one or more of aluminum, copper, nickel, gold or platinum.
The electric core in this embodiment still includes electrolyte and the casing that holds electric core, and the inside formation of casing holds the chamber, and electric core and electrolyte are located and hold the intracavity, and electric core and electrolyte encapsulate in the inside of casing.
The following describes, with reference to an example, a method for manufacturing a battery cell in an embodiment of the present invention, where the method for manufacturing a battery cell includes the following steps:
step S1, coating a first active material on a single-side surface of the firstcurrent collector 1 to form a firstpaste coating area 21 with a first active material layer, where the upper side of the firstpaste coating area 21 is a firstempty foil area 3 without the first active material layer, and the firstempty foil area 3 is a full tab of the first pole piece; coating a second active material on the surface of one side of a secondcurrent collector 4 to form a secondpaste coating area 22 with a second active material layer, wherein the upper side of the secondpaste coating area 22 is a secondempty foil area 5 without the second active material layer, and the secondempty foil area 5 is a full tab of a second pole piece;
step S2, attaching a gummedpaper 7 on the firstempty foil area 3 on the surface of one side of the firstcurrent collector 1 coated with the first active material layer to form a first gummedarea 31, wherein the width of the gummedpaper 7 is smaller than the width of the firstempty foil area 3, the distance between the gummedpaper 7 and the firstpaste coating area 21 is 0-0.5 mm, the thickness of the gummedpaper 7 is the same as that of the first active material layer, and the area of the firstempty foil area 3 not gummed paper is a firstnon-gummed area 32; pastingadhesive paper 7 on a secondempty foil area 5 on one side surface of the secondcurrent collector 4 coated with the second active material to form a secondadhesive area 51, wherein the width of theadhesive paper 7 is smaller than that of the secondempty foil area 5, the distance between theadhesive paper 7 and the secondpaste coating area 22 is 0-0.5 mm, the thickness of theadhesive paper 7 is the same as that of the second active material layer, and the area of the secondempty foil area 5 not pasted with the adhesive paper is a second adhesive-free area 52;
step S3, drying the first active material layer and the second active material layer, stacking the first pole piece, thediaphragm 6 and the second pole piece, overlapping the firstpaste coating area 21 and the secondpaste coating area 22 to form apaste coating area 2, respectively arranging the firstempty foil area 3 and the secondempty foil area 5 at two opposite ends of thepaste coating area 2, then winding along the length direction of the first pole piece and the second pole piece to form a battery cell, winding thepaste coating areas 2 together after winding, pasting the firstadhesive tape area 31 at one end of thepaste coating area 2 together throughadhesive paper 7, and pasting the secondadhesive tape area 51 at the other end of thepaste coating area 2 together throughadhesive paper 7;
step S4, performing kneading and flattening treatment on the firstnon-adhesive area 32 and the secondnon-adhesive area 52 which are respectively positioned at the two ends of the electric core by adopting mechanical kneading and flattening or ultrasonic kneading and flattening, and respectively forming two welding surfaces, wherein the two welding surfaces are respectively vertical to the firstadhesive area 31 and the secondnon-adhesive area 51, and the two welding surfaces are respectively positioned at the two ends of the electric core along the width direction;
and step S5, welding the inverted L-shaped first connectingpiece 8 and the L-shaped second connecting piece 9 on two welding surfaces respectively by laser welding to obtain the battery core.
The prepared battery core is subjected to the steps of packaging, shell punching, top sealing, side sealing, liquid injection, hot cold pressing, formation, clamp baking, secondary sealing, capacity grading and the like, so that the battery is obtained, the battery is a full-tab roll core soft package battery, the positive electrode and the negative electrode are symmetrically distributed at two ends of the battery, the roll core capacity of the battery is designed to be 3850mAh, and the thickness of the battery is 3.8 mm.
The effects of the battery cell in the embodiment of the present invention are described below with reference to specific tests and test effects.
Arranging three batteries with common adhesive tapes adhered to the empty foil area, wherein the adhesive layer of the common adhesive tapes is made of hot melt adhesive, and the materials are respectively referred to as a commonadhesive tape group 1, a commonadhesive tape group 2 and a commonadhesive tape group 3 in the following;
arranging three batteries with conductive swelling gummed paper stuck in the empty foil area, wherein the material of the adhesive layer of the conductive swelling gummed paper is conductive swelling glue, and the conductive swelling gummedpaper group 1, the conductive swelling gummedpaper group 2 and the conductive swelling gummedpaper group 3 are respectively referred to below;
three batteries without gummed paper pasted on the empty foil area are arranged, and are respectively referred to as acomparison group 1, acomparison group 2 and acomparison group 3 below.
The materials of the first pole piece and the second pole piece of the three groups of batteries and the first active material layer and the second active material layer are the same, and the winding modes of the first pole piece, the second pole piece and the diaphragm of the three groups of batteries are also the same, so that the difference is only whether the first empty foil area and the second empty foil area are pasted with adhesive paper or not and the type of the pasted adhesive paper.
After the battery is packaged for the second time, thecomparison group 1, thecomparison group 2 and thecomparison group 3 have obvious depressions at the tab welding positions, the appearance smoothness is poor, the attractiveness is low, the commonadhesive tape group 1, the commonadhesive tape group 2, the commonadhesive tape group 3, the conductive swellingadhesive tape group 1, the conductive swellingadhesive tape group 2 and the conductive swellingadhesive tape group 3 do not have depressions at the tab welding positions, the appearance smoothness is good, and the attractiveness is high.
In order to further verify the performances of the three groups of batteries, the three groups of batteries are subjected to a stability test and a cycle performance test respectively.
And (3) stability testing: after the battery is fully charged, the capacity retention rate and the recovery rate of the battery are tested after the battery is stored for 35 days at a high temperature of 60 ℃;
and (3) testing the stability: all three groups of batteries are charged with 3.85A current and discharged with 3.85A current, and the cycling is carried out for 400 weeks to obtain the capacity after the cycling.
After testing three groups of cells, the results shown in table 1 and fig. 7 were obtained.
Table 1 test results of each battery set
Fig. 7 is a graph comparing the cycles of three groups of cells. As can be seen from table 1 and fig. 7, after the plain adhesive tape and the conductive swelling adhesive tape are applied to the empty foil region of the battery cell for the planarization treatment, after the battery cell of the plain adhesive tape group (including the plain adhesive tape group 1, the plain adhesive tape group 2, and the plain adhesive tape group 3) and the conductive swelling adhesive tape group (including the conductive swelling adhesive tape group 1, the conductive swelling adhesive tape group 2, and the conductive swelling adhesive tape group 3) is stored at 60 ℃ in the full power state for 35 days, the capacity retention rates are all as high as 75% or more, and excellent stability is exhibited, while after the battery cell of the comparative group without the planarization treatment of the adhesive tape (including the comparative group 1, the comparative group 2, and the comparative group 3) is stored at 60 ℃ in the full power state for 35 days, the maximum value of the capacity retention rate is 10.6%, and extremely poor stability is exhibited; although the capacity recovery rates of the three groups of batteries are all more than 80%, it can be seen from fig. 7 that the capacity retention rate of the battery cell of the comparative group without the adhesive paper for the flatness treatment after 320 weeks of circulation is 80%, while the capacity retention rate of the battery cell adopting the conductive sol adhesive paper for the flatness treatment after 400 weeks of circulation is 94%, and the capacity retention rate is also obviously better than the capacity retention rate of the battery cell adopting the ordinary adhesive paper for the flatness treatment after 400 weeks of circulation, which is 92%.
From the above results, the storage performance and the cycling stability of the battery core without the adhesive paper for the leveling treatment are both worse than those of the battery core adopting the adhesive paper for the leveling treatment, because after the formation, the two vacuum air extractions are performed, the aluminum-plastic film in the empty foil area is deformed, the edges of the first pole piece, the second pole piece and the diaphragm are subjected to uneven external force exerted by the deformed aluminum-plastic film, the expansion deformation of the pole pieces is obvious after the long-time cycle, the service life of the pole pieces is reduced, the aluminum-plastic film exerts uneven external force on the positions after the expansion deformation, the diaphragm is easily punctured, and the tiny self-discharge in the battery is caused, the stored electric quantity is accumulated, and the stored electric quantity is continuously consumed, and the stability is poor; the storage performance and the circulation stability of the battery core subjected to flatness processing by adopting the conductive swelling adhesive tape are better than those of a battery subjected to flatness shaping processing by adopting common adhesive tape, because the conductive swelling adhesive can play a constant expansion effect according to the thickness of the battery core and the capacity of electrolyte after expansion, and the relative movement of pole pieces in the circulating charge-discharge process is restrained, so that the phenomenon that welding points between the first hollow foil areas and the second hollow foil areas are broken or fall off due to the volume expansion of the battery core is effectively avoided.
Although the present disclosure has been described above, the scope of the present disclosure is not limited thereto. Various changes and modifications may be effected therein by one of ordinary skill in the pertinent art without departing from the spirit and scope of the present disclosure, and these changes and modifications are intended to be within the scope of the present disclosure.