Movatterモバイル変換


[0]ホーム

URL:


CN113013154A - Integrated packaging tube shell for flat phased array antenna receiving and transmitting assembly - Google Patents

Integrated packaging tube shell for flat phased array antenna receiving and transmitting assembly
Download PDF

Info

Publication number
CN113013154A
CN113013154ACN202110183854.8ACN202110183854ACN113013154ACN 113013154 ACN113013154 ACN 113013154ACN 202110183854 ACN202110183854 ACN 202110183854ACN 113013154 ACN113013154 ACN 113013154A
Authority
CN
China
Prior art keywords
shell
layer
cavity
tube
radio frequency
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202110183854.8A
Other languages
Chinese (zh)
Other versions
CN113013154B (en
Inventor
刘俊超
杜明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Southwest Electronic Technology Institute No 10 Institute of Cetc
Original Assignee
Southwest Electronic Technology Institute No 10 Institute of Cetc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Southwest Electronic Technology Institute No 10 Institute of CetcfiledCriticalSouthwest Electronic Technology Institute No 10 Institute of Cetc
Priority to CN202110183854.8ApriorityCriticalpatent/CN113013154B/en
Publication of CN113013154ApublicationCriticalpatent/CN113013154A/en
Application grantedgrantedCritical
Publication of CN113013154BpublicationCriticalpatent/CN113013154B/en
Activelegal-statusCriticalCurrent
Anticipated expirationlegal-statusCritical

Links

Images

Classifications

Landscapes

Abstract

Translated fromChinese

本发明公开的一种平板相控阵天线收发组件一体化封装管壳,旨在解决收发组件工作时在狭小空间内的高效散热问题。本发明通过下述技术方案予以实现:管壳腔体被中间介质层分隔为管壳上腔和管壳下腔,射频芯片两边分布芯片电容,同时通过贯穿中间介质层的阵列散热通孔与相变材料层连通;射频芯片通过分布在沿管壳内壁介质层延伸至内埋腔底的印刷金属导线、金属导线上的印刷电阻、互连管壳上盖两边排列的线阵焊球,实现与天线网络的信号传输;射频芯片通过中间介质内阵列排布的散热通孔、与散热通孔连通填充在管壳下腔内的相变材料层,固联在管壳底端的管壳热沉实现与外界环境的热交换,完成一体化气密封装结构中的射频芯片在工作时的高效散热功能。

Figure 202110183854

The invention discloses an integrated package package of a flat-plate phased array antenna transceiver component, which aims to solve the problem of efficient heat dissipation in a narrow space when the transceiver component works. The invention is realized by the following technical scheme: the tube-shell cavity is divided into the tube-shell upper cavity and the tube-shell lower cavity by the intermediate medium layer, the chip capacitors are distributed on both sides of the radio frequency chip, and the array heat dissipation through holes passing through the intermediate medium layer and the phase The variable material layer is connected; the radio frequency chip is distributed with the printed metal wires extending along the inner wall of the shell and the dielectric layer to the bottom of the buried cavity, the printed resistors on the metal wires, and the linear array solder balls arranged on both sides of the upper cover of the interconnecting shell to achieve and The signal transmission of the antenna network; the RF chip is realized through the heat dissipation through holes arranged in an array in the intermediate medium, the phase change material layer filled in the lower cavity of the tube shell, and the heat sink of the tube shell fixed at the bottom of the tube shell. The heat exchange with the external environment completes the efficient heat dissipation function of the RF chip in the integrated hermetic packaging structure during operation.

Figure 202110183854

Description

Integrated packaging tube shell for flat phased array antenna receiving and transmitting assembly
Technical Field
The invention relates to a flat phased array antenna mainly used for communication and navigation functions in the aerospace field, in particular to an antenna transceiving component packaging tube shell which can be used as a structural component of a device carrier such as a transceiving component radio frequency chip and the like and also can be used as a functional component for interconnecting a device and an antenna network.
Background
The phased array antenna can carry out beam forming configuration on N antenna array elements, intelligently controls the amplitude and phase excitation of each independent antenna array element in the phased array antenna in an electronic mode, generates beams pointing to the required direction, and can carry out beam forming and beam scanning quickly without inertia under the condition that a physical structure is fixed and unchanged. The beam-forming design at the front end of the phased array antenna has very excellent performance, so that the integrated nest plate of the type is a mainstream scheme in large-scale phased array radar and satellite communication applications. Most of the traditional satellite communication antennas are mechanical parabolic antennas, which have high profile and heavy weight and need a servo system to provide antenna pointing variation. The electric scanning phased array antenna adopts the phase shifter to control the phase, does not need a mechanical structure, and has the advantages of low profile, easy conformality, light weight and the like, so the electric scanning phased array antenna is increasingly applied to the construction of space-based systems such as high-orbit broadband and low-orbit mobile satellites, and has wide application prospect in the fields of civil aviation/high-speed rail high-speed mobile communication, remote area maritime terminal broadband internet access, enterprise/government large data platform construction and the like which are developed at high speed nowadays. The core active function of the electric scanning phased array antenna is realized by the transceiving component, and meanwhile, the transceiving component is also the link with the highest cost ratio (60% -80%) in the electric scanning phased array antenna, the finest assembling process and the most complex flow, so that the performance of the transceiving component has decisive influence on the quality of the index of the active function of the electric scanning phased array antenna.
The digital phase shifter and the digital attenuator are important components of the phased array antenna receiving assembly. Since the phase shift accuracy and the attenuation accuracy directly affect the performance of the entire phased array antenna, a high-order digital phase shifter and a digital attenuator are inevitably selected. Assuming that the receiving component uses a 6-bit digital phase shifter and a 6-bit digital attenuator, the receiving component has 4096 (2)6×26) A phase-shift attenuation state. So much attenuated phase shiftThe state presents a significant challenge to the testing of the receiving component. When the existing transceiving component consisting of an active chip, a circuit board, a connector, a metal shell and a cover plate breaks down, due to the complex assembly process and the multiple types of used devices, the performance problems of each component and structure and the connection problems during mutual assembly need to be checked step by step, the problems are difficult to locate and the repair time is long. However, the existing transceiver module usually adopts an integrated scheme of packaging parts such as an active chip, a circuit board, a connector and the like in a metal shell, and the scheme needs to use a radio frequency connector to realize signal interconnection between the transceiver module and an antenna. Because a large number of radio frequency connectors are used, the manufacturing cost of the transceiving component is increased, extremely strict requirements are provided for the welding quality of the radio frequency connectors, and the assembly and repair difficulty of the transceiving component is increased. Therefore, in order to reduce the manufacturing cost of the transceiving component and improve the integration level of the transceiving component, a manufacturing scheme of the planar phased array antenna transceiving component is formed, wherein the active function of the transceiving component is made into a chip, and the chip-level device is integrally packaged. In the scheme, the chip-level device needs to be independently packaged and then attached to an antenna carrier plate with multiple functions such as an integrated antenna network and the like after being packaged. This requires that the package case not only has the structural function of carrying the chip-scale device and realizing the package thereof, but also has the functional function of realizing the signal interconnection between the chip-scale device and the antenna carrier. Meanwhile, the active functional chip of the transceiver module can produce a large amount of heat during working, and the active functional chip is packaged in a narrow packaging tube shell in the scheme, so that great difficulty is brought to the heat dissipation of the active functional chip, and therefore the packaging tube shell must have good heat dissipation characteristics and establish a heat dissipation channel between the active functional chip and the external environment.
The low temperature co-fired ceramic (LTCC) technology is a manufacturing technology for forming a multilayer interconnected substrate by performing processes of cavity punching, wiring, via metallization, lamination, co-firing, and the like on a green tape. Because the LTCC substrate has the excellent characteristics of low thermal expansion, low transmission loss and low dielectric loss, the LTCC substrate can meet the characteristic requirements of large current, high temperature resistance, high-frequency communication and the like, and is widely applied to the advanced fields of aerospace communication, microsystem integration and the like. In order to form a cavity structure in an LTCC substrate, many foreign researchers have made researches, for example, Tick T uses a pressure assisted sintering technology to fabricate a microwave waveguide cavity of a 160GHz waveguide antenna on an LTCC substrate, and when fabricating a cavity, an upper cover, an inner cavity, and a bottom of the cavity are formed by laminating, bonding, and sintering the three parts to form a 1.3mm × 0.615mm micro waveguide cavity. The research results provide technical bases for manufacturing the integrated packaging tube shell of the planar phased-array antenna transceiving component by using a low temperature co-fired ceramic (LTCC) technology.
Disclosure of Invention
Aiming at the problems in the prior art, the invention provides a packaging tube shell with integrated structure and function and good heat dissipation property according to the manufacturing requirements of a flat phased array antenna aiming at a transmitting and receiving assembly packaging body, wherein the transmitting and receiving assembly packaging body can be used as a structural member of a device carrier such as a transmitting and receiving assembly radio frequency chip and the like and can also be used as a device and an antenna network interconnection functional member.
The technical scheme adopted by the invention for solving the technical problems is as follows: the utility model provides a dull and stereotyped phased array antenna receiving and dispatching subassembly integration encapsulation tube, has arectangle tube cavity 1 through 4 encapsulation of tube upper cover and its solidantithetical couplet 8 on the heat sink of tube of bottom, its characterized in that: thetube shell cavity 1 is divided into a tube shellupper cavity 2 and a tube shell lower cavity 6 by an intermediate medium layer, aradio frequency chip 10 serving as a transceiving component and chip capacitors which are connected with theradio frequency chip 10 through bonding gold wires and symmetrically distributed on two sides of theradio frequency chip 10 are arranged in the middle of the step surface of the intermediate medium layer, theradio frequency chip 10 and the chip capacitors are connected with a connectingbonding pad 11 through the bonding gold wires and connected to a radio frequency transmission hole 12 embedded in the intermediate medium, and theradio frequency chip 10 is communicated with a phasechange material layer 7 through an array heat dissipation throughhole 9 penetrating through the intermediate medium layer; the middle medium layer is also embedded with aprinting metal lead 3 which extends along the side walls of the two sides and is connected with a lineararray welding ball 5, theprinting metal lead 3 extends to the bottom of the embedded cavity along the medium layer of the inner wall of the tube shell, theprinting resistors 13 which are symmetrically distributed on theprinting metal lead 3 and are arranged in the radiating throughholes 9, and the radio frequency chip realizes the signal transmission with the antenna network through the printing metal lead which is distributed along the medium layer of the inner wall of the tube shell and extends to the bottom of the embedded cavity, the printing resistors on the metal lead and the linear array welding balls which are arranged on the two sides of the; the radio frequency chip is communicated with a phasechange material layer 7 filled in a lower cavity 6 of the tube shell through radiating throughholes 9 arrayed in the middle medium layer, the bottom end of the tube shell is provided with a tubeshell heat sink 8 fixedly connected, the radio frequency chip is communicated with the radiating through holes through the radiating through holes arrayed in the middle medium layer and is filled in the lower cavity of the tube shell, and the tube shell heat sink fixedly connected to the bottom end of the tube shell realizes heat exchange with the external environment, so that the efficient radiating function of the radio frequency chip in the integrated airtight packaging structure during working is achieved.
Compared with the prior art, the invention has the following beneficial effects:
the invention adopts a rectangulartube shell cavity 1 which is packaged by a tube shellupper cover 4 and a tubeshell heat sink 8 which is fixedly connected with the bottom end of thetube shell cavity 1, thetube shell cavity 1 is divided into an uppertube shell cavity 2 and a lower tube shell cavity 6 by an intermediate medium layer, signal transmission of a radio frequency chip of a transceiving component and an antenna network is realized by a connectingbonding pad 11, a radio frequency transmission hole 12, an embedded printedmetal lead 3, a printedresistor 13 which is interconnected with the embedded printed metal lead, and a lineararray welding ball 5, the manufacturing problems of difficult welding and difficult repair of a radio frequency connector which are brought by using a large number of radio frequency connectors of the existing transceiving component are solved, and the repair performance of the transceiving component is improved while the manufacturing cost of the transceiving.
The size and weight are reduced. The invention realizes the structure and function integrated packaging of the whole transceiving component by installing a transceiving component radio frequency chip, a chip capacitor and a gold bonding wire on atube shell cavity 1 and a tube shellupper cavity 2, embedding a printed metal wire and a printed resistor in the tube shell, implanting a lineararray solder ball 5 on a tube shellupper cover 4, and sealing the tube shellupper cavity 2 and the tube shell lower cavity 6 by using the tube shellupper cover 4 and a tubeshell heat sink 8. Compared with the existing transceiver module, the transceiver module omits a metal shell, a metal cover plate for sealing the metal shell and a fastener, so that the volume and the weight of the transceiver module are reduced by more than 50%.
Thetube shell cavity 1 is connected with the tube shellupper cover 4 in a lead-tin welding mode to form sealing on the tube shellupper cavity 2; the tubeshell heat sink 8 is interconnected with thetube shell cavity 1 in a tin-silver welding mode to form sealing for the tube shell lower cavity 6; by sealing the upperpipe shell cavity 2 and the lower pipe shell cavity 6, the air-tight packaging of the whole pipe shell can be realized, and the environmental adaptability of the pipe shell under severe conditions such as damp heat, salt mist and the like is enhanced.
The heat dissipation capability is improved. The lower cavity 6 of thetube shell cavity 1 is filled with a phasechange material layer 7 for rapid heat dissipation, a large amount of heat generated by the radio frequency chip of the transceiver component during working can be conducted to the phasechange material layer 7 through the heat dissipation throughhole 9, the phase change material absorbs a large amount of heat by phase change when reaching a phase change temperature, so that the heat generated by the radio frequency chip of the transceiver component during working is conducted to the phasechange material layer 7 through the heat dissipation throughhole 9, the phase change material absorbs a large amount of heat by phase change when reaching the phase change temperature, and the heat is rapidly transferred from the radio frequency chip of the transceiver component to the phase change material, so that the. The phase-change material absorbs a large amount of heat and then exchanges heat with a tube-shell heat sink 8 made of diamond-copper, when the temperature of the phase-change material is lower than the phase-change temperature of the phase-change material, the phase-change material is changed again to release heat, and the heat is dissipated to the external environment through the diamond-copper heat sink. The upperpipe shell cavity 2 and the lower pipe shell cavity 6 in thepipe shell cavity 1 are manufactured by a sacrificial layer filling technology and a low-temperature co-fired ceramic technology, the filled sacrificial layer material can be filled in during lamination to avoid the cavity from excessively collapsing or deforming during lamination, and meanwhile, the sacrificial layer material can completely volatilize below 450 ℃ during sintering and does not form any residue in the cavity. The problem of the integrated manufacturing of dull and stereotyped phased array antenna receiving and dispatching subassembly tube structure and function integration and the high-efficient heat dissipation of receiving and dispatching subassembly radio frequency chip during operation in narrow and small space is solved.
The reworkability is improved. The invention adopts the printedmetal wire 3 embedded in the tube shell to be interconnected with the lineararray welding balls 5 arranged on two sides of theupper cover 4 of the tube shell, thus realizing the signal transmission with the antenna network; the radio frequency chip of the transceiving component is communicated to the phasechange material layer 7 filled in the lower cavity 6 of the tube shell through the heat dissipation throughholes 9 arrayed in the middle medium, and performs heat exchange with theheat sink 8 of the tube shell, so that the radio frequency chip of the transceiving component of the planar phased array antenna is integrally packaged in the airtight structure of thecavity 1 of the tube shell, and the function of efficient heat dissipation is performed during work. The lineararray welding balls 5 are embedded in theupper cover 4 of the tube shell, and the antenna carrier plate is interconnected by adopting an SMT (surface mount technology). When the flat phased array antenna breaks down, the receiving and sending assembly with problems can be accurately positioned through electrical testing, and the receiving and sending assembly with problems can be quickly replaced through the hot air repairing table. The problems that when the existing transceiving component composed of an active chip, a circuit board, a connector, a metal shell and a cover plate breaks down, performance problems of each component and structure and connection problems during mutual assembly need to be checked step by step due to the fact that the assembly process is complex and the types of used devices are multiple, positioning is difficult, and repair time is long are solved. Compared with the existing assembly mode of the transceiver assembly, the invention has the advantages of easier fault location and effectively improved repair performance.
The invention is applicable to receiving elements of different array sizes.
Drawings
FIG. 1 is a perspective view of an integrated package structure for a planar phased array antenna transceiver module according to the present invention;
FIG. 2 is a top view of FIG. 1;
fig. 3 is a flow chart of the fabrication of the cavity of the integrally packaged package of fig. 1;
in the figure: the structure comprises ashell cavity 1, a shellupper cavity 2, a printedmetal wire 3, a shellupper cover 4, a lineararray solder ball 5, a shell lower cavity 6, a phasechange material layer 7, ashell heat sink 8, a heat dissipation throughhole 9, a transceiver moduleradio frequency chip 10, aconnection pad 11, a radio frequency transmission hole 12 and a printedresistor 13.
Detailed Description
Refer to fig. 1 and 2. In the embodiments described below, a package with integrated planar phased-array antenna transceiver module has arectangular package cavity 1 packaged by a packageupper cover 4 and apackage heat sink 8 fixedly connected to the bottom end. Thetube shell cavity 1 is divided into a tube shellupper cavity 2 and a tube shell lower cavity 6 by an intermediate medium layer, aradio frequency chip 10 serving as a transceiving component and chip capacitors which are connected with theradio frequency chip 10 through bonding gold wires and symmetrically distributed on two sides of theradio frequency chip 10 are arranged in the middle of the step surface of the intermediate medium layer, theradio frequency chip 10 and the chip capacitors are connected with a connectingbonding pad 11 through the bonding gold wires and connected to a radio frequency transmission hole 12 embedded in the intermediate medium, and theradio frequency chip 10 is communicated with a phasechange material layer 7 through an array heat dissipation throughhole 9 penetrating through the intermediate medium layer; the middle medium layer is also embedded with aprinting metal lead 3 which extends along the side walls of the two sides and is connected with a lineararray welding ball 5, theprinting metal lead 3 extends to the bottom of the embedded cavity along the medium layer of the inner wall of the tube shell, theprinting resistors 13 which are symmetrically distributed on theprinting metal lead 3 and are arranged in the radiating throughholes 9, and the radio frequency chip realizes the signal transmission with the antenna network through the printing metal lead which is distributed along the medium layer of the inner wall of the tube shell and extends to the bottom of the embedded cavity, the printing resistors on the metal lead and the linear array welding balls which are arranged on the two sides of the; the radio frequency chip is communicated with a phasechange material layer 7 filled in a lower cavity 6 of the tube shell through radiating throughholes 9 arrayed in the middle medium layer, the bottom end of the tube shell is provided with a tubeshell heat sink 8 fixedly connected, the radio frequency chip is communicated with the radiating through holes through the radiating through holes arrayed in the middle medium layer and is filled in the lower cavity of the tube shell, and the tube shell heat sink fixedly connected to the bottom end of the tube shell realizes heat exchange with the external environment, so that the efficient radiating function of the radio frequency chip in the integrated airtight packaging structure during working is achieved.
The integrated packaging tube shell is divided into atube shell cavity 1, a tube shellupper cover 4 and a tubeshell heat sink 8. Thetube shell cavity 1 comprises a tube shellupper cavity 2 and a tube shell lower cavity 6, the tube shellupper cavity 2 is used for bonding a radio frequency chip, a chip capacitor and a gold bonding wire of the transceiver module, and the tube shell lower cavity 6 is mainly used for filling a phasechange material layer 7.
A printedmetal wire 3 and a printedresistor 13 are embedded in atube shell cavity 1, a lineararray solder ball 5 is embedded in a tube shellupper cover 4, and a radio frequency chip of a transceiving component can form signal interconnection with an antenna network on an antenna carrier plate through a connectingbonding pad 11, a radio frequency transmission hole 12, the embedded printedmetal wire 3, the printedresistor 13 interconnected with the embedded printed metal wire, and the lineararray solder ball 5. Theupper cover 4 of the tube shell is welded on thecavity 1 of the tube shell by a lead-tin welding process, and theupper cavity 2 of the tube shell is sealed. The tubeshell heat sink 8 is welded on thetube shell cavity 1 through a tin-silver welding process to complete the sealing of the tube shell lower cavity 6, and the phase change material layer is in close contact with the tube shell heat sink to establish a heat exchange channel between the phase change material layer and the external environment.
In an optional embodiment, the embedded printedmetal wire 3 and the passive printedresistor 13 are manufactured inside the tube shell by using a low-temperature co-fired ceramic technology, the embedded printed metal wire and the passive printed resistor are printed on a low-temperature co-fired ceramic chip through high-precision contraposition, and are formed by laminating, laminating and sintering together with the ceramic chip, and the signal interconnection between the radio frequency chip of the transceiver component in the packaging tube shell and the antenna network can be realized through the embedded printed metal wire, the passive printed resistor and the lineararray solder balls 5.
The lineararray solder ball 5 is Sn/Ag/Cu solder ball, the bottom of the solder ball is provided with a composite metal layer under a welding spot for enhancing the connection strength with the tube shell, and the composite metal layer consists of an Au layer used as an oxidation barrier layer, a Pd layer used as an adhesion and diffusion barrier layer and a Ni layer used as a solder wetting layer.
The phase-change material layer 7 is positioned in the lower cavity 6 of the tube shell, heat generated when the radio-frequency chip of the transceiver component works can be conducted to the phase-change material through the heat dissipation throughhole 9, and the phase-change material changes phase when the phase-change material exceeds the phase-change temperature of the phase-change material to absorb a large amount of heat. The phase-change material absorbs a large amount of heat and then exchanges heat with the tube-shell heat sink 8 made of diamond-copper, when the temperature of the phase-change material is lower than the phase-change temperature of the phase-change material, the phase-change material changes phase, the released heat is dissipated to the external environment through the diamond-copper heat sink, and therefore efficient heat dissipation of the radio frequency chip of the transceiver module during working is achieved.
See fig. 3. Thetube shell cavity 1 is mainly manufactured by combining a low-temperature co-fired ceramic process and a sacrificial layer technology. Firstly, cutting a raw porcelain strip into 8-inch × 8-inch standard porcelain pieces, tearing off a protective film on the back surface of the porcelain strip on a film tearing machine, and placing the porcelain strip in a constant temperature and humidity box for 24 hours to release the residual stress of the torn porcelain pieces. And then punching radio frequency holes and heat conducting holes on the ceramic chips by using a high-speed mechanical punching machine, and filling metal into the radio frequency holes and the heat conducting holes by using a printing hole filling mode. In order to reduce the manufacturing cost, the hole filling slurry uses a hole filling silver slurry. After the ceramic chip is filled, the ceramic chip is kept stand for 24 hours or dried in a vacuum oven at the temperature of 120 ℃ for 20 minutes so as to dry and solidify the filling silver paste. Printing the printed metal wires of each layer on the porcelain sheets of each layer through a printing silk screen tool by a printing machine according to a design drawing, and printing silver paste to reduce the manufacturing cost during printing. And standing the printed layers of the ceramic tiles for 4 hours to dry and solidify the printed metal wires. And then printing the printed resistor on the ceramic chip according to the design drawing, wherein the relative position of the metal line and the printed resistor needs to be noticed during printing, which has important influence on the resistance value of the internal printed resistor. After the printed resistance paste is dried, the positions of the upper cavity and the lower cavity of the tube shell in the ceramic chip are cut off by an ultraviolet laser cutting method, and the ceramic chip is laminated by an automatic laminating machine after the cutting off to form a ceramic chip laminated body.
Before the lamination of the tile laminate, a sacrificial layer filler is required. In the embodiment, the filling material is formed by casting the polypropylene carbonate composite material through a powder casting process, the sheet material can be softened at the temperature of 60-80 ℃, the softened sheet material can be cut into a regular shape by a hot cutting machine, and the thickness of the formed filling material is 0.04 mm.
After the sacrificial layer filling material block is manufactured, the upper cavity and the lower cavity of the ceramic chip laminated body are respectively filled, so that the cavity is prevented from deforming and collapsing in the laminating process. After the completion of the filling, the ceramic chip laminate was placed in a packaging bag, evacuated, and laminated and formed by hot water isostatic pressing. After the lamination, the ceramic tile laminate was sintered in a sintering furnace, and a sintered body was obtained after the sintering.
Because the metal on the surface of the sintered body is silver and cannot be used for subsequent gold wire bonding, the silver layer metal on the surface is replaced by a Ni/Pd/Au composite metal layer by adopting a chemical plating method, wherein the Au layer is used as an oxidation barrier layer, the Pd layer is used as an adhesion and diffusion barrier layer, and the Ni layer is used as a solder wetting layer. And obtaining thetube shell cavity 1 after the chemical plating is finished.
The phase-change material layer 7 of the present embodiment is made of a paraffin/graphite foam composite phase-change material. During preparation, the foam graphite is used as a reinforced heat-conducting framework structure, and a liquid-phase infiltration method is adopted to prepare the foam graphite by utilizing the good adsorption property of the graphite to paraffin. The thermal conductivity coefficient of the prepared paraffin/foam graphite composite phase-change material is about 6W/m.K, which is improved by about 20 times compared with that of pure paraffin, and the heat transfer enhancement effect is obvious. The prepared paraffin/foam graphite composite phase-change material is cut into a size matched with the lower cavity 6 of the tube shell in an ultraviolet laser cutting mode and filled into the lower cavity of the tube shell; and welding the tubeshell heat sink 8 at the bottom of thetube shell cavity 1 by using tin-silver solder to seal the lower cavity 6 of the tube shell.
In this embodimentIn the method, a radio frequency chip and a chip capacitor of a transceiving assembly are bonded in corresponding positions in anupper cavity 2 of a tube shell by conductive silver paste, and then a semi-automatic gold wire bonding machine is used for completing signal interconnection of the radio frequency chip of the transceiving assembly and the chip capacitor and the radio frequency chip of the transceiving assembly and a bonding pad in the tube shell by 25 microns. And after gold wire bonding is finished, welding theupper cover 4 of the tube shell on the top of thecavity 1 of the tube shell by adopting lead-tin solder Sn63Pb37 to finish sealing theupper cavity 2 of the tube shell. The welding temperature is set to 210 ℃ during welding so as to ensure that thelinear solder balls 5 are not melted. The lower cavity 6 of the tube shell and theupper cavity 2 of the tube shell are welded and sealed, so that the whole tube shell can be hermetically packaged, and the leakage rate is 1 multiplied by 10 through helium mass spectrum leakage detection test-6Pa.m3And/s, the air tightness standard is achieved, and the environmental adaptability of the transceiving component under severe conditions such as damp heat, salt mist and the like is effectively enhanced.
It should be understood that the specific examples described above are intended to be illustrative only and are not intended to be limiting, as any feature disclosed in the present invention may be replaced by alternative features serving the same, equivalent or similar purpose, unless expressly stated otherwise.

Claims (10)

Translated fromChinese
1.一种平板相控阵天线收发组件一体化封装管壳,具有一个通过管壳上盖(4)封装的矩形管壳腔体(1)及其固联在底端的管壳热沉(8),其特征在于:管壳腔体(1)被中间介质层分隔为管壳上腔(2)和管壳下腔(6),中间介质层台阶面的中部设有作为收发组件的射频芯片(10)和通过键合金丝与射频芯片(10)相连、并在射频芯片(10)两边对称分布的芯片电容,射频芯片(10)和芯片电容通过键合金丝与连接焊盘(11)相连,连接至内埋于中间介质内的射频传输孔(12),射频芯片(10)通过贯穿中间介质层的阵列散热通孔(9)连通相变材料层(7);中间介质层内还埋置有沿两边侧壁延伸与线阵焊球(5)相连的印刷金属导线(3),印刷金属导线(3)沿管壳内壁介质层延伸至内埋腔底,印刷金属导线(3)上有对称于散热通孔(9)排布的印刷电阻(13),射频芯片通过分布在沿管壳内壁介质层并延伸至内埋腔底的印刷金属导线、金属导线上的印刷电阻、互连管壳上盖两边排列的线阵焊球,实现与天线网络的信号传输;射频芯片同时通过中间介质层内阵列排布的散热通孔(9)与填充在管壳下腔(6)内的相变材料层(7)相连通,管壳底端有固联的管壳热沉(8),射频芯片通过中间介质内阵列排布的散热通孔、与散热通孔连通并填充在管壳下腔内的相变材料层、固联在管壳底端的管壳热沉实现与外界环境的热交换,完成处于一体化气密封装结构中的射频芯片在工作时的高效散热功能。1. A flat-plate phased array antenna transceiver component integrated packaging tube case, comprising a rectangular tube case cavity (1) encapsulated by an upper cover (4) of the tube case and a tube case heat sink (8) fixed at the bottom end ), characterized in that: the tube-shell cavity (1) is divided into a tube-shell upper cavity (2) and a tube-shell lower cavity (6) by an intermediate medium layer, and a radio frequency chip as a transceiver component is arranged in the middle of the stepped surface of the intermediate medium layer (10) and a chip capacitor connected to the radio frequency chip (10) by bonding wires and symmetrically distributed on both sides of the radio frequency chip (10), the radio frequency chip (10) and the chip capacitor are connected to the connection pad (11) by bonding wires connected to the radio frequency transmission hole (12) buried in the intermediate medium, the radio frequency chip (10) is connected to the phase change material layer (7) through the array heat dissipation through holes (9) passing through the intermediate medium layer; There are printed metal wires (3) extending along the side walls of both sides and connected to the linear array solder balls (5). There are printed resistors (13) arranged symmetrically to the heat dissipation through holes (9), and the radio frequency chip passes through the printed metal wires distributed along the dielectric layer of the inner wall of the tube shell and extended to the bottom of the buried cavity, the printed resistors on the metal wires, and interconnected The linear array solder balls arranged on both sides of the upper cover of the tube case realize signal transmission with the antenna network; the radio frequency chip simultaneously passes through the heat dissipation through holes (9) arranged in the array in the intermediate dielectric layer and the heat dissipation through holes (9) filled in the lower cavity (6) of the tube case. The phase-change material layer (7) is communicated with, and the bottom end of the tube shell is provided with a solid-connected tube-shell heat sink (8), and the radio frequency chip is connected to the heat-dissipating through holes through the heat-dissipating through holes arranged in an array in the intermediate medium, and is filled in the tube-shell The phase change material layer in the lower cavity and the shell heat sink fixed at the bottom of the shell realize heat exchange with the external environment, and complete the efficient heat dissipation function of the radio frequency chip in the integrated airtight packaging structure during operation.2.如权利要求1所述的平板相控阵天线收发组件一体化封装管壳,其特征在于:管壳腔体(1)包含管壳上腔(2)和管壳下腔(6),管壳上腔(2)用于粘接收发组件射频芯片、芯片电容和键合金丝,管壳下腔(6)填充相变材料层(7);管壳腔体(1)内埋印刷金属导线(3)及印刷电阻(13),管壳上盖(4)植有线阵焊球(5),收发组件射频芯片通过连接焊盘(11)、射频传输孔(12)、内埋印刷金属导线(3)及与其互联的印刷电阻(13)、线阵焊球(5)与天线载板上的天线网络形成信号互连。2. The integrated encapsulation casing of a flat-plate phased array antenna transceiver assembly as claimed in claim 1, characterized in that: the casing cavity (1) comprises an upper casing cavity (2) and a casing lower cavity (6), The upper cavity (2) of the tube shell is used for bonding the radio frequency chip, chip capacitor and bonding wire of the transceiver component, the lower cavity (6) of the tube shell is filled with the phase change material layer (7); the tube shell cavity (1) is embedded with printed metal Wires (3) and printed resistors (13), the upper cover (4) of the tube case is planted with wire array solder balls (5), and the radio frequency chip of the transceiver component is connected to the pad (11), the radio frequency transmission hole (12), and the embedded printed metal The wires (3), the interconnected printed resistors (13), the linear array solder balls (5) and the antenna network on the antenna carrier form signal interconnection.3.如权利要求1所述的平板相控阵天线收发组件一体化封装管壳,其特征在于:管壳上盖(4)通过铅锡焊接工艺焊接于管壳腔体(1),对管壳上腔(2)进行密封,管壳热沉(8)通过锡银焊接工艺焊接于管壳腔体(1),完成对管壳下腔(6)的密封,并使相变材料层(7)与管壳热沉紧密接触,建立相变材料层与外界环境的热交换通道。3. The integrated encapsulation tube casing of the flat-panel phased array antenna transceiver assembly according to claim 1, characterized in that: the casing upper cover (4) is welded to the casing cavity (1) by a lead-tin welding process, and the tube casing is welded to the tube casing cavity (1). The upper cavity (2) of the shell is sealed, and the shell heat sink (8) is welded to the shell cavity (1) by the tin-silver welding process, so as to complete the sealing of the lower cavity (6) of the shell, and make the phase change material layer ( 7) It is in close contact with the heat sink of the tube shell to establish a heat exchange channel between the phase change material layer and the external environment.4.如权利要求1所述的平板相控阵天线收发组件一体化封装管壳,其特征在于:利用低温共烧陶瓷技术在管壳内部制作了内埋印刷金属导线(3)和无源印刷电阻(13),内埋印刷金属导线和无源印刷电阻通过高精度对位印刷在低温共烧陶瓷瓷片上,随瓷片一起叠层、层压、烧结而成,通过内埋印刷金属导线、无源印刷电阻和线阵焊球(5)实现封装管壳内的收发组件射频芯片与天线网络的信号互连。4. The flat-panel phased array antenna transceiver assembly integrated package package as claimed in claim 1, characterized in that: using low temperature co-fired ceramic technology to make buried printed metal wires (3) and passive printing inside the package Resistor (13), embedded printed metal wires and passive printed resistors are printed on low-temperature co-fired ceramic tiles through high-precision alignment, laminated, laminated and sintered together with the ceramic tiles. The passive printed resistors and the linear array solder balls (5) realize the signal interconnection between the radio frequency chip of the transceiver component and the antenna network in the packaged tube case.5.如权利要求4所述的平板相控阵天线收发组件一体化封装管壳,其特征在于:线阵焊球(5)为Sn/Ag/Cu焊球,焊球底部具有增强与管壳连接强度的焊点下复合金属层,复合金属层由作为氧化阻挡层的Au层、作为粘附及扩散阻挡层的Pd层和作为焊料润湿层的Ni层组成。5. The integrated package package of a flat-panel phased array antenna transceiver assembly as claimed in claim 4, characterized in that: the linear array solder balls (5) are Sn/Ag/Cu solder balls, and the bottom of the solder balls has reinforcement and the package. The composite metal layer under the solder joint of the connection strength is composed of an Au layer as an oxidation barrier layer, a Pd layer as an adhesion and diffusion barrier layer, and a Ni layer as a solder wetting layer.6.如权利要求1所述的平板相控阵天线收发组件一体化封装管壳,其特征在于:相变材料层(7)位于管壳下腔(6)中,通过散热通孔(9)将收发组件射频芯片工作时产生的热量传导至相变材料,相变材料在超过其相变温度时发生相变,吸收大量热量,相变材料吸收大量热量后通过与金刚石-铜制成的管壳热沉(8)进行热交换,当相变材料温度低于其相变温度时发生相变,放出热量通过金刚石-铜热沉向外界环境散热,从而实现收发组件射频芯片工作时的高效散热。6. The integrated package package of flat-panel phased array antenna transceiver components as claimed in claim 1, characterized in that: the phase-change material layer (7) is located in the lower cavity (6) of the shell, and passes through the heat dissipation through hole (9) The heat generated by the radio frequency chip of the transceiver component is conducted to the phase change material. When the phase change material exceeds its phase change temperature, a phase change occurs and a large amount of heat is absorbed. After absorbing a large amount of heat, the phase change material passes through a tube made of diamond-copper. The shell heat sink (8) conducts heat exchange. When the temperature of the phase change material is lower than its phase change temperature, a phase change occurs, and the released heat is dissipated to the external environment through the diamond-copper heat sink, so as to achieve efficient heat dissipation when the radio frequency chip of the transceiver component works. .7.如权利要求1所述的平板相控阵天线收发组件一体化封装管壳,其特征在于:管壳腔体(1)通过低温共烧陶瓷工艺结合牺牲层技术制作而成,首先将生瓷带切制成8英寸×8英寸的标准瓷片,在撕膜机上撕去背面的保护膜,在恒温恒湿箱内放置24小时,以施放撕膜后瓷片的残余应力,随后用高速机械打孔机在瓷片上冲制射频孔和导热孔,并用印刷填孔方式对射频孔和导热孔进行金属填充,填孔浆料使用填孔银浆。7. The integrated package package of a flat-panel phased array antenna transceiver assembly as claimed in claim 1, wherein the shell cavity (1) is fabricated by a low-temperature co-fired ceramic process combined with a sacrificial layer technology. The ceramic tape was cut into a standard 8-inch x 8-inch tile, the protective film on the back was torn off on a film tearing machine, and placed in a constant temperature and humidity box for 24 hours to apply the residual stress of the tile after the film was peeled off, and then used at a high speed. The mechanical punching machine punches RF holes and thermal holes on the ceramic sheet, and fills the RF holes and thermal holes with metal by means of printing and filling, and the filling paste is filled with silver paste.8.如权利要求7所述的平板相控阵天线收发组件一体化封装管壳,其特征在于:瓷片填孔完成后静置24h或在真空烘箱中以120℃的温度烘干20分钟,以便填孔银浆干燥固化;然后按照设计图纸将各层的印刷金属导线用印刷机通过印刷丝网工装印制于各层瓷片上,将印刷后的各层瓷片静置4小时,使印刷的印刷金属导线干燥固化,接着按照设计图纸在瓷片上印刷印刷电阻,待印刷电阻浆料干燥后,用紫外激光切割方法将瓷片中管壳上腔和管壳下腔的位置切除,切除后再用自动叠片机将瓷片叠层形成瓷片叠层体。8. The integrated package package of the flat-panel phased array antenna transceiver assembly as claimed in claim 7, characterized in that: after filling the holes of the tile, let it stand for 24 hours or be dried in a vacuum oven at a temperature of 120°C for 20 minutes, In order to dry and solidify the hole-filling silver paste; then, according to the design drawings, the printed metal wires of each layer are printed on the ceramic sheets of each layer by a printing machine through a printing screen tool, and the printed ceramic sheets of each layer are allowed to stand for 4 hours to make the printing The printed metal wires are dried and solidified, and then printed resistors are printed on the tiles according to the design drawings. After the printed resistor paste is dried, the upper and lower cavities of the shell and the shell in the tiles are cut off by UV laser cutting. The ceramic sheets are then laminated to form a ceramic sheet laminated body by an automatic lamination machine.9.如权利要求8所述的平板相控阵天线收发组件一体化封装管壳,其特征在于:在瓷片叠层体层压前,制作牺牲层填充材料,填充材料由聚丙烯碳酸盐复合材料通过粉末流延工艺流延成形,该片状材料在60-80℃软化,软化后由热切机切割成规则形状,成形后的填充材料厚度为0.04mm。9 . The integrated package package of the flat-panel phased array antenna transceiver assembly as claimed in claim 8 , wherein: before the ceramic laminate is laminated, a sacrificial layer filling material is made, and the filling material is made of polypropylene carbonate. 10 . The composite material is cast and formed through a powder casting process. The sheet-like material is softened at 60-80° C., and is cut into a regular shape by a hot cutting machine after softening. The thickness of the formed filling material is 0.04 mm.10.如权利要求9所述的平板相控阵天线收发组件一体化封装管壳,其特征在于:牺牲层填充材料块制作完成后,分别填入瓷片叠层体的上腔和下腔,填充完成后,将瓷片叠层体放入封装袋中抽真空,用温水等静压方式层压成形,层压完成后,使用烧结炉对瓷片层压体进行烧结,烧结获得烧结体;采用化学镀的方法将表面的银层金属置换为Ni/Pd/Au的复合金属层,其中Au层作为氧化阻挡层、Pd层作为粘附及扩散阻挡层、Ni层作为焊料润湿层,化学镀完成后即获得管壳腔体(1)。10 . The integrated package package of the flat-panel phased array antenna transceiver assembly according to claim 9 , wherein after the sacrificial layer filling material block is fabricated, the upper cavity and the lower cavity of the ceramic laminate are respectively filled, After the filling is completed, the ceramic laminate is put into a packaging bag to be evacuated, and laminated and formed by isostatic pressing with warm water. After the lamination is completed, the ceramic laminate is sintered using a sintering furnace to obtain a sintered body; The silver layer metal on the surface is replaced by a composite metal layer of Ni/Pd/Au by electroless plating, wherein the Au layer is used as an oxidation barrier layer, the Pd layer is used as an adhesion and diffusion barrier layer, and the Ni layer is used as a solder wetting layer. After the plating is completed, the tube shell cavity (1) is obtained.
CN202110183854.8A2021-02-102021-02-10Integrated packaging tube shell of flat phased array antenna transceiver componentActiveCN113013154B (en)

Priority Applications (1)

Application NumberPriority DateFiling DateTitle
CN202110183854.8ACN113013154B (en)2021-02-102021-02-10Integrated packaging tube shell of flat phased array antenna transceiver component

Applications Claiming Priority (1)

Application NumberPriority DateFiling DateTitle
CN202110183854.8ACN113013154B (en)2021-02-102021-02-10Integrated packaging tube shell of flat phased array antenna transceiver component

Publications (2)

Publication NumberPublication Date
CN113013154Atrue CN113013154A (en)2021-06-22
CN113013154B CN113013154B (en)2023-08-18

Family

ID=76402258

Family Applications (1)

Application NumberTitlePriority DateFiling Date
CN202110183854.8AActiveCN113013154B (en)2021-02-102021-02-10Integrated packaging tube shell of flat phased array antenna transceiver component

Country Status (1)

CountryLink
CN (1)CN113013154B (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
CN113423198A (en)*2021-06-232021-09-21中国电子科技集团公司第二十九研究所Printed circuit board embedded with micro flat heat pipe and packaging method thereof
CN113851923A (en)*2021-10-192021-12-28北京大学东莞光电研究院Laser TO packaging structure
CN114121848A (en)*2021-10-272022-03-01中国电子科技集团公司第十三研究所Low-frequency high-power device metal ceramic tube shell package
CN114256175A (en)*2021-12-072022-03-29中国电子科技集团公司第二十九研究所 A tile-type TR component embedded in a microfluidic channel and its preparation method
CN115549721A (en)*2022-10-102022-12-30航天科工微电子系统研究院有限公司Miniaturized data chain radio frequency front end receiving and transmitting assembly and design method thereof
CN119552637A (en)*2025-01-242025-03-04中科优选新材料(浙江)有限公司 A high performance and high thermal conductivity composite phase change material and its preparation process and application
CN120033457A (en)*2025-02-252025-05-23瑞度(北京)电子技术有限公司 A low temperature ceramic phased array antenna and its manufacturing process

Citations (6)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
WO2012054642A1 (en)*2010-10-202012-04-26Peregrine Semiconductor CorporationMethod and apparatus for use in improving linearity of mosfets using an accumulated charge sink - harmonic wrinkle reduction
US20120212384A1 (en)*2011-02-172012-08-23International Business Machines CorporationIntegrated antenna for rfic package applications
CN105304577A (en)*2015-07-282016-02-03中国电子科技集团公司第十研究所Preparation method for multi-chip module heat dissipation packaging ceramic composite substrate
WO2016093933A1 (en)*2014-12-102016-06-16Raytheon CompanyVertical radio frequency module
WO2017049963A1 (en)*2015-09-212017-03-30福建中科芯源光电科技有限公司White-light led module having multiple heat flow channels and fabrication method therefor
US20170182165A1 (en)*2015-12-232017-06-29Rhode Island HospitalThermal accelerant compositions and methods of use

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
WO2012054642A1 (en)*2010-10-202012-04-26Peregrine Semiconductor CorporationMethod and apparatus for use in improving linearity of mosfets using an accumulated charge sink - harmonic wrinkle reduction
US20120212384A1 (en)*2011-02-172012-08-23International Business Machines CorporationIntegrated antenna for rfic package applications
WO2016093933A1 (en)*2014-12-102016-06-16Raytheon CompanyVertical radio frequency module
CN105304577A (en)*2015-07-282016-02-03中国电子科技集团公司第十研究所Preparation method for multi-chip module heat dissipation packaging ceramic composite substrate
WO2017049963A1 (en)*2015-09-212017-03-30福建中科芯源光电科技有限公司White-light led module having multiple heat flow channels and fabrication method therefor
US20170182165A1 (en)*2015-12-232017-06-29Rhode Island HospitalThermal accelerant compositions and methods of use

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
吕倩: "复合相变装置导热系数测试方法", 《电子机械工程》*

Cited By (10)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
CN113423198A (en)*2021-06-232021-09-21中国电子科技集团公司第二十九研究所Printed circuit board embedded with micro flat heat pipe and packaging method thereof
CN113423198B (en)*2021-06-232022-03-08中国电子科技集团公司第二十九研究所Printed circuit board embedded with micro flat heat pipe and packaging method thereof
CN113851923A (en)*2021-10-192021-12-28北京大学东莞光电研究院Laser TO packaging structure
CN114121848A (en)*2021-10-272022-03-01中国电子科技集团公司第十三研究所Low-frequency high-power device metal ceramic tube shell package
CN114121848B (en)*2021-10-272025-08-08中国电子科技集团公司第十三研究所 A metal ceramic tube package for low-frequency high-power devices
CN114256175A (en)*2021-12-072022-03-29中国电子科技集团公司第二十九研究所 A tile-type TR component embedded in a microfluidic channel and its preparation method
CN114256175B (en)*2021-12-072023-09-01中国电子科技集团公司第二十九研究所Tile type TR (transmitter-receiver) component embedded in micro-channel and preparation method thereof
CN115549721A (en)*2022-10-102022-12-30航天科工微电子系统研究院有限公司Miniaturized data chain radio frequency front end receiving and transmitting assembly and design method thereof
CN119552637A (en)*2025-01-242025-03-04中科优选新材料(浙江)有限公司 A high performance and high thermal conductivity composite phase change material and its preparation process and application
CN120033457A (en)*2025-02-252025-05-23瑞度(北京)电子技术有限公司 A low temperature ceramic phased array antenna and its manufacturing process

Also Published As

Publication numberPublication date
CN113013154B (en)2023-08-18

Similar Documents

PublicationPublication DateTitle
CN113013154B (en)Integrated packaging tube shell of flat phased array antenna transceiver component
US9153863B2 (en)Low temperature co-fired ceramic (LTCC) system in a package (SiP) configurations for microwave/millimeter wave packaging applications
KR102103196B1 (en)Multilayer electronics assembly and method for embedding electrical circuit components within a three dimensional module
US8536954B2 (en)Millimeter wave multi-layer packaging including an RFIC cavity and a radiating cavity therein
CN100533797C (en) Covering device in semiconductor package
JP5864601B2 (en) Low mass foam electrical structure
CN104332413A (en)3D assembling method for integrally integrating chips of T/R assembly
CN111785691A (en) A three-dimensional package shell structure of a radio frequency microsystem and a manufacturing method
CN112635444A (en)Three-dimensional stacked microsystem packaging assembly and manufacturing method thereof
US8209846B2 (en)Methods for producing large flat panel and conformal active array antennas
CN111769087B (en) A high-power GaN device heat dissipation and integrated integrated structure and manufacturing method
TW200408161A (en)Multilayer stripline radio frequency circuits and interconnection methods
US9899717B2 (en)Stacked low loss stripline circulator
KR101447325B1 (en)Heterogeneous chip integration with low loss interconnection through adaptive patterning
Thompson et al.Packaging of MMICs in multilayer LCP substrates
CN111698824B (en)Integrated interconnection structure of self-airtight packaging functional module and implementation method
CN102881602A (en)Integrating method of working temperature controllable multi-chip component
CN112349691A (en)Airtight high-heat-conductivity LCP packaging substrate, manufacturing method and multi-chip system-in-package structure
CN110961741A (en) A kind of LTCC substrate brazing method
CN112349700A (en)Airtight high heat conduction LCP packaging substrate and multi-chip system level packaging structure
Curran et al.Development and validation of a chip integration concept for multi-die GaAs front ends for phased arrays up to 60 GHz
CN104465607A (en)Leadless plane surface-mounted type microwave thin film hybrid integrated circuit and integration method thereof
BechtoldInnovation steps towards a novel and cost efficient LTCC packaging technology for high end applications
CN210489608U (en)Ceramic shell meeting Ka-band TR (transmitter-receiver) component packaging
CN112349685A (en)Six-layer wiring LCP packaging substrate, manufacturing method and multi-chip system-in-package structure

Legal Events

DateCodeTitleDescription
PB01Publication
PB01Publication
SE01Entry into force of request for substantive examination
SE01Entry into force of request for substantive examination
GR01Patent grant
GR01Patent grant

[8]ページ先頭

©2009-2025 Movatter.jp