CN110219201B - Preparation method of basalt fiber paper - Google Patents

Abstract

The invention discloses a preparation method of basalt fiber paper, which comprises the steps of firstly, carrying out alkali treatment on basalt fiber slurry by adopting an alkali treatment agent to obtain alkali-treated basalt fiber, then carrying out acid treatment on the alkali-treated basalt fiber slurry by adopting an acid treatment agent to obtain acid-alkali-treated basalt fiber, adding a dispersing agent into the acid-alkali-treated basalt fiber slurry to be uniformly dispersed, then adding a mixture of an organic adhesive and an inorganic adhesive to be uniformly dispersed, diluting, carrying out inclined net forming and drying to obtain the basalt fiber paper. The basalt fiber paper prepared by the process has high strength and good toughness, can be used as a high-quality temperature-resistant flame-retardant material, and has a wide application field.

Description

Preparation method of basalt fiber paper

Technical Field

The invention relates to the technical field of pulping and papermaking, in particular to a preparation method of basalt fiber paper.

Background

The basalt fiber is a continuous fiber which is formed by melting basalt stone at 1450-1500 ℃ and drawing the basalt stone at high speed through a platinum-rhodium alloy wire drawing bushing. The basalt fiber is a new-appearing novel inorganic environment-friendly green high-performance fiber material, and is formed by quickly drawing basalt stone material consisting of oxides such as silicon dioxide, aluminum oxide, calcium oxide, iron oxide, titanium dioxide and the like through a bushing after the basalt stone material is melted at high temperature. The basalt continuous fiber has good stability, and also has various excellent performances of electrical insulation, corrosion resistance, combustion resistance, high temperature resistance and the like. In addition, the production process of the basalt fiber produces less waste and causes little pollution to the environment, and the waste product can be directly transferred into the ecological environment without any harm, so the basalt fiber is a real green and environment-friendly material. The basalt continuous fiber has been widely applied in various aspects such as fiber reinforced composite materials, friction materials, shipbuilding materials, heat insulation materials, automobile industry, high-temperature filter fabrics, protection fields and the like.

At present, basalt fiber composite materials are mainly applied on the basis of fabric structures, and there is also a technology for preparing fiber paper by mixing basalt fibers with other fibers, such as the Chinese patent with the publication number of 1948615. The fiber paper is prepared from basalt fiber, aramid fiber and polyphenylene sulfide fiber by a wet method. The synthetic fiber paper has the advantages of good mechanical property, good high temperature resistance, acid and alkali resistance, strong ultraviolet resistance, low hygroscopicity, better environment resistance, good insulating property, good high temperature filtering property, radiation resistance, good wave-transmitting property and the like.

On the one hand, however, because the basalt surface has better hydrophobicity, the affinity of the common inorganic fiber with water is poor, so that the fiber is difficult to disperse; on the other hand, the basalt fiber has low content of surface active groups, the fibers are difficult to form hydrogen bonds and other bonds, the formed paper has low strength and is difficult to form, and for the reasons, the related technology for independently preparing the basalt fiber into the thin paper-based material does not exist, so the application field and the precision of the basalt fiber are limited.

Disclosure of Invention

In order to solve the defects of the prior art, the invention aims to provide the preparation method of the basalt fiber paper, which can overcome the defects of difficult uniform dispersion of basalt fibers and low paper strength, so as to prepare the basalt fiber paper with high uniformity and high strength.

In order to achieve the purpose, the technical scheme of the invention is as follows:

the preparation method of the basalt fiber paper comprises the steps of firstly, carrying out alkali treatment on basalt fiber slurry by using an alkali treatment agent to obtain alkali-treated basalt fibers, then, carrying out acid treatment on the alkali-treated basalt fiber slurry by using an acid treatment agent to obtain acid-alkali-treated basalt fibers, adding a dispersing agent into the acid-alkali-treated basalt fiber slurry to be uniformly dispersed, then, adding a mixture of an organic adhesive and an inorganic adhesive to be uniformly dispersed, diluting, carrying out inclined net forming, and drying to obtain the basalt fiber paper.

According to the invention, the basalt fiber paper with high evenness and high strength is prepared by pretreating the basalt fiber with acid and alkali, improving the dispersibility of the basalt fiber and improving the strength of the basalt fiber under different use conditions by utilizing the bonding effect of the organic adhesive and the inorganic adhesive.

The second purpose of the invention is to provide the basalt fiber paper obtained by the preparation method.

The invention also aims to provide application of the basalt fiber paper in a temperature-resistant flame-retardant material.

The invention has the beneficial effects that:

the method has the advantages that alkali and acid are utilized to sequentially pretreat the basalt fiber, so that the dispersibility of the basalt fiber is improved, meanwhile, the bonding effect of the organic and inorganic adhesive is utilized to improve the strength of the basalt fiber under different using conditions, and the basalt fiber paper prepared by the method has high strength and good toughness, can be used as a high-quality temperature-resistant flame-retardant material, and is wide in application field.

Detailed Description

It should be noted that the following detailed description is exemplary and is intended to provide further explanation of the disclosure. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs.

It is noted that the terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of example embodiments according to the present application. As used herein, the singular forms "a", "an" and "the" are intended to include the plural forms as well, and it should be understood that when the terms "comprises" and/or "comprising" are used in this specification, they specify the presence of stated features, steps, operations, devices, components, and/or combinations thereof, unless the context clearly indicates otherwise.

As introduced in the background art, the defects of difficult uniform dispersion of basalt fibers and low paper strength exist in the prior art, and in order to solve the technical problems, the application provides a preparation method of basalt fiber paper.

The preparation method comprises the steps of firstly carrying out alkali treatment on basalt fiber slurry by adopting an alkali treatment agent to obtain basalt fibers after alkali treatment, then carrying out acid treatment on the basalt fiber slurry after alkali treatment by adopting an acid treatment agent to obtain basalt fibers after acid and alkali treatment, adding a dispersing agent into the basalt fiber slurry after acid and alkali treatment to disperse uniformly, then adding a mixture of an organic adhesive and an inorganic adhesive to disperse uniformly, diluting, carrying out inclined net forming and drying to obtain the basalt fiber paper.

According to the preparation method, the basalt fiber is pretreated by using acid and alkali, the dispersibility of the basalt fiber is improved, and meanwhile, the strength of the basalt fiber under different use conditions is improved by using the bonding effect of an organic adhesive and an inorganic adhesive, so that the basalt fiber paper with high evenness and high strength is prepared.

Preferably, the addition amount of the alkali treatment agent is 2 to 4% by mass of the basalt fiber. The alkali treating agent is sodium hydroxide. The effect of using sodium hydroxide is better.

Preferably, the addition amount of the acid treatment agent is 2-4% of the mass of the basalt fiber.

Preferably, the acid treatment agent is a mixture of hydrochloric acid, sulfuric acid and phosphoric acid. Further preferably, the mass ratio of the hydrochloric acid to the sulfuric acid to the phosphoric acid is 1:1: 1.

Preferably, the concentration of the slurry of basalt fiber in the acid treatment or alkali treatment is 2 to 5 mass%.

Preferably, after the acid treatment or the alkali treatment, the treated slurry is washed to be neutral.

Preferably, the treatment temperature of the acid treatment or the alkali treatment is 40-60 ℃, and the treatment time is 10-15 min. The stirring speed is 100-120 rpm.

Preferably, the addition amount of the dispersant is 0.1 to 0.3% of the mass of the basalt fiber.

Preferably, the dispersant is a mixture of sodium hexametaphosphate and polyethylene oxide. Sodium hexametaphosphate is an inorganic dispersant, and after various screens, better dispersants for basalt can be obtained by adopting sodium hexametaphosphate. Further preferably, the mass ratio of sodium hexametaphosphate to polyethylene oxide is 1: 1. The sodium hexametaphosphate can reduce the electrostatic acting force among fibers and is easy to disperse, good dispersion is realized, and the polyethylene oxide promotes the dispersion of the fibers by improving the viscosity of the system and simultaneously improves the stability of the dispersed fiber system. Experiments show that the proportion has the best effect.

Preferably, the organic adhesive is one or more of sodium carboxymethylcellulose, polyvinyl alcohol and polyacrylic acid. Further preferably, the organic adhesive is sodium carboxymethyl cellulose.

Preferably, the inorganic adhesive is one or more of water glass and alumina sol. Further preferably, the inorganic adhesive is a mixture of water glass and aluminum sol.

Preferably, the mass of the mixture of the organic adhesive and the inorganic adhesive is 20-40% of the mass of the basalt fiber.

Preferably, the mixture of the organic adhesive and the inorganic adhesive is sodium carboxymethylcellulose, and the mass ratio of the water glass to the alumina sol is 1:1: 1. The three adhesives screened are adhesives with good basalt fiber bonding property, the sodium carboxymethylcellulose plays a good bonding role at normal temperature, the sodium silicate and the alumina sol have poor bonding effect at normal temperature, but the bonding effect at high temperature is good, and the temperature resistance is good, so that the proportion is selected to obtain good bonding strength at normal temperature and high temperature.

Preferably, the mixture is diluted to 0.5 percent, then formed by using a wire screen with low concentration of 0.01 to 0.03 percent, and dried and formed at 105 ℃.

In another embodiment of the present application, there is provided basalt fiber paper obtained by the above-mentioned preparation method.

In a third embodiment of the application, an application of the basalt fiber paper in a temperature-resistant flame-retardant material is provided.

In order to make the technical solutions of the present application more clearly understood by those skilled in the art, the technical solutions of the present application will be described in detail below with reference to specific examples and comparative examples.

Example 1:

(1) after the basalt fibers are dispersed into slurry, the concentration of the slurry is 3%, the slurry is treated by using an alkali treatment agent sodium hydroxide, the addition amount of the sodium hydroxide is 2% of the mass of the basalt fibers, the treatment temperature is 40 ℃, the stirring speed is 100rpm, the treatment time is 10 minutes, and after the alkali treatment agent is used for treatment, the slurry is washed to be neutral.

(2) After the basalt fibers are dispersed into pulp, the concentration of the pulp is 3%, the pulp is treated by using an acid treatment agent, the addition amount of the acid treatment agent is 2% of the mass of the basalt fibers, the treatment temperature is 40 ℃, the stirring speed is 100rpm, the treatment time is 10 minutes, after the acid treatment agent is treated, the pulp is cleaned to be neutral, and the acid treatment agent is hydrochloric acid, sulfuric acid and phosphoric acid according to the mass ratio of 1:1:1 by mixing.

(3) After the basalt fibers are dispersed into slurry, the concentration of the slurry is 2%, the stirring speed is 150rpm, a dispersing agent is added for dispersion, the adding amount of the dispersing agent is 0.1% of the mass of the basalt fibers, and the mass ratio of the dispersing agent to the polyethylene oxide is 1:1, after dispersing for 30min uniformly, adding an adhesive accounting for 20% of the mass of the basalt fiber, continuously dispersing for 30min uniformly, diluting to 0.5%, forming by using an inclined wire with low concentration of 0.01%, and drying and forming at 105 ℃ to obtain the basalt fiber paper, wherein the adhesive is sodium carboxymethylcellulose, water glass and alumina sol, and the mass ratio of the adhesive is 1:1:1 to obtain the compound.

Example 2:

(1) after the basalt fibers are dispersed into slurry, the concentration of the slurry is 5%, the slurry is treated by using an alkali treatment agent sodium hydroxide, the addition amount of the sodium hydroxide is 3% of the mass of the basalt fibers, the treatment temperature is 50 ℃, the stirring speed is 110rpm, the treatment time is 13 minutes, and after the alkali treatment agent is used for treatment, the slurry is washed to be neutral.

(2) After the basalt fibers are dispersed into pulp, the concentration of the pulp is 5%, the pulp is treated by using an acid treatment agent, the addition amount of the acid treatment agent is 3% of the mass of the basalt fibers, the treatment temperature is 50 ℃, the stirring speed is 110rpm, the treatment time is 13 minutes, after the acid treatment agent is treated, the pulp is cleaned to be neutral, and the acid treatment agent is hydrochloric acid, sulfuric acid and phosphoric acid according to the mass ratio of 1:1:1 by mixing.

(3) After the basalt fibers are dispersed into slurry, the concentration of the slurry is 3%, the stirring speed is 130rpm, a dispersing agent is added for dispersion, the adding amount of the dispersing agent is 0.2% of the mass of the basalt fibers, and the mass ratio of the dispersing agent to the polyethylene oxide is 1:1, after dispersing for 30min uniformly, adding an adhesive accounting for 30% of the mass of the basalt fiber, continuously dispersing for 30min uniformly, diluting to 0.5%, forming by using an inclined wire at a low concentration of 0.03%, and drying and forming at 105 ℃ to obtain the basalt fiber paper, wherein the adhesive is sodium carboxymethylcellulose, water glass and alumina sol, and the mass ratio of the adhesive is 1:1:1 to obtain the compound.

Example 3:

(1) after the basalt fibers are dispersed into slurry, the concentration of the slurry is 6%, the slurry is treated by using an alkali treatment agent sodium hydroxide, the addition amount of the sodium hydroxide is 4% of the mass of the basalt fibers, the treatment temperature is 60 ℃, the stirring speed is 120rpm, the treatment time is 15 minutes, and after the alkali treatment agent is used for treatment, the slurry is washed to be neutral.

(2) After the basalt fibers are dispersed into pulp, the concentration of the pulp is 6%, the pulp is treated by using an acid treatment agent, the addition amount of the acid treatment agent is 4% of the mass of the basalt fibers, the treatment temperature is 60 ℃, the stirring speed is 120rpm, the treatment time is 15 minutes, after the acid treatment agent is treated, the pulp is cleaned to be neutral, and the acid treatment agent is hydrochloric acid, sulfuric acid and phosphoric acid according to the mass ratio of 1:1:1 by mixing.

(3) After the basalt fibers are dispersed into slurry, the concentration of the slurry is 5%, the stirring speed is 200rpm, a dispersing agent is added for dispersion, the adding amount of the dispersing agent is 0.3% of the mass of the basalt fibers, and the mass ratio of the dispersing agent to the polyethylene oxide is 1:1, after dispersing for 30min uniformly, adding an adhesive accounting for 40% of the mass of the basalt fiber, continuously dispersing for 30min uniformly, diluting to 0.5%, forming by using an inclined wire at a low concentration of 0.03%, and drying and forming at 105 ℃ to obtain the basalt fiber paper, wherein the adhesive is sodium carboxymethylcellulose, water glass and alumina sol, and the mass ratio of the adhesive is 1:1:1 to obtain the compound.

Example 4:

(1) after the basalt fibers are dispersed into slurry, the concentration of the slurry is 6%, the slurry is treated by using an alkali treatment agent sodium hydroxide, the addition amount of the sodium hydroxide is 4% of the mass of the basalt fibers, the treatment temperature is 60 ℃, the stirring speed is 120rpm, the treatment time is 15 minutes, and after the alkali treatment agent is used for treatment, the slurry is washed to be neutral.

(2) After the basalt fibers are dispersed into slurry, the concentration of the slurry is 5%, the stirring speed is 200rpm, a dispersing agent is added for dispersion, the adding amount of the dispersing agent is 0.3% of the mass of the basalt fibers, and the mass ratio of the dispersing agent to the polyethylene oxide is 1:1, after dispersing for 30min uniformly, adding an adhesive accounting for 40% of the mass of the basalt fiber, continuously dispersing for 30min uniformly, diluting to 0.5%, forming by using an inclined wire at a low concentration of 0.03%, and drying and forming at 105 ℃ to obtain the basalt fiber paper, wherein the adhesive is sodium carboxymethylcellulose, water glass and alumina sol, and the mass ratio of the adhesive is 1:1:1 to obtain the compound.

Example 5:

(1) after the basalt fibers are dispersed into pulp, the concentration of the pulp is 6%, the pulp is treated by using an acid treatment agent, the addition amount of the acid treatment agent is 4% of the mass of the basalt fibers, the treatment temperature is 60 ℃, the stirring speed is 120rpm, the treatment time is 15 minutes, after the acid treatment agent is treated, the pulp is cleaned to be neutral, and the acid treatment agent is hydrochloric acid, sulfuric acid and phosphoric acid according to the mass ratio of 1:1:1 by mixing.

(2) After the basalt fibers are dispersed into slurry, the concentration of the slurry is 5%, the stirring speed is 200rpm, a dispersing agent is added for dispersion, the adding amount of the dispersing agent is 0.3% of the mass of the basalt fibers, and the mass ratio of the dispersing agent to the polyethylene oxide is 1:1, after dispersing for 30min uniformly, adding an adhesive accounting for 40% of the mass of the basalt fiber, continuously dispersing for 30min uniformly, diluting to 0.5%, forming by using an inclined wire at a low concentration of 0.03%, and drying and forming at 105 ℃ to obtain the basalt fiber paper, wherein the adhesive is sodium carboxymethylcellulose, water glass and alumina sol, and the mass ratio of the adhesive is 1:1:1 to obtain the compound.

Example 6:

(1) after the basalt fibers are dispersed into slurry, the concentration of the slurry is 6%, the slurry is treated by using an alkali treatment agent sodium hydroxide, the addition amount of the sodium hydroxide is 4% of the mass of the basalt fibers, the treatment temperature is 60 ℃, the stirring speed is 120rpm, the treatment time is 15 minutes, and after the alkali treatment agent is used for treatment, the slurry is washed to be neutral.

(2) After the basalt fibers are dispersed into pulp, the concentration of the pulp is 6%, the pulp is treated by using an acid treatment agent, the addition amount of the acid treatment agent is 4% of the mass of the basalt fibers, the treatment temperature is 60 ℃, the stirring speed is 120rpm, the treatment time is 15 minutes, after the acid treatment agent is treated, the pulp is cleaned to be neutral, and the acid treatment agent is hydrochloric acid, sulfuric acid and phosphoric acid according to the mass ratio of 1:1:1 by mixing.

(3) After the basalt fibers are dispersed into slurry, the concentration of the slurry is 5%, the stirring speed is 200rpm, a dispersing agent is added for dispersion, the adding amount of the dispersing agent is 0.3% of the mass of the basalt fibers, and the mass ratio of the dispersing agent to the polyethylene oxide is 1:1, dispersing for 30min uniformly, adding an adhesive accounting for 40% of the mass of the basalt fiber, continuously dispersing for 30min uniformly, diluting to 0.5%, forming by using an inclined wire at a low concentration of 0.03%, and drying and forming at 105 ℃ to obtain the basalt fiber paper, wherein the adhesive is sodium carboxymethylcellulose.

Example 7:

(1) after the basalt fibers are dispersed into slurry, the concentration of the slurry is 6%, the slurry is treated by using an alkali treatment agent sodium hydroxide, the addition amount of the sodium hydroxide is 4% of the mass of the basalt fibers, the treatment temperature is 60 ℃, the stirring speed is 120rpm, the treatment time is 15 minutes, and after the alkali treatment agent is used for treatment, the slurry is washed to be neutral.

(2) After the basalt fibers are dispersed into pulp, the concentration of the pulp is 6%, the pulp is treated by using an acid treatment agent, the addition amount of the acid treatment agent is 4% of the mass of the basalt fibers, the treatment temperature is 60 ℃, the stirring speed is 120rpm, the treatment time is 15 minutes, after the acid treatment agent is treated, the pulp is cleaned to be neutral, and the acid treatment agent is hydrochloric acid, sulfuric acid and phosphoric acid according to the mass ratio of 1:1:1 by mixing.

(3) After the basalt fibers are dispersed into slurry, the concentration of the slurry is 5%, the stirring speed is 200rpm, a dispersing agent is added for dispersion, the adding amount of the dispersing agent is 0.3% of the mass of the basalt fibers, and the mass ratio of the dispersing agent to the polyethylene oxide is 1:1, after dispersing for 30min uniformly, adding an adhesive accounting for 40% of the mass of the basalt fiber, continuously dispersing for 30min uniformly, diluting to 0.5%, forming by using an inclined wire at a low concentration of 0.03%, and drying and forming at 105 ℃ to obtain the basalt fiber paper, wherein the adhesive is water glass and alumina sol, and the mass ratio of the adhesive is 1:1 to obtain the compound.

Examples fiber paper strength and temperature resistance data

The above description is only a preferred embodiment of the present application and is not intended to limit the present application, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, improvement and the like made within the spirit and principle of the present application shall be included in the protection scope of the present application.

Claims (16)

Translated fromChinese

1.一种玄武岩纤维纸的制备方法，其特征是，先采用碱处理剂对玄武岩纤维的浆液进行碱处理获得碱处理后的玄武岩纤维，再采用酸处理剂对碱处理后的玄武岩纤维的浆液进行酸处理获得酸碱处理后的玄武岩纤维，向酸碱处理后的玄武岩纤维的浆液添加分散剂分散均匀，然后添加有机胶黏剂与无机胶黏剂的混合物分散均匀后，稀释、斜网成型、干燥后即得玄武岩纤维纸；1. a preparation method of basalt fiber paper, it is characterized in that, first adopt alkali treatment agent to carry out alkali treatment to the slurries of basalt fiber to obtain the basalt fiber after alkali treatment, then adopt acid treatment agent to the slurry of basalt fiber after alkali treatment Perform acid treatment to obtain acid-base treated basalt fiber, add dispersant to the slurry of acid-base treated basalt fiber to disperse uniformly, then add a mixture of organic adhesive and inorganic adhesive to disperse uniformly, dilute and form an inclined net , After drying, basalt fiber paper is obtained;酸处理剂为盐酸、硫酸和磷酸的混合物；The acid treating agent is a mixture of hydrochloric acid, sulfuric acid and phosphoric acid;分散剂为六偏磷酸钠与聚氧化乙烯的混合物；The dispersant is a mixture of sodium hexametaphosphate and polyethylene oxide;有机胶黏剂为羧甲基纤维素钠、聚乙烯醇、聚丙烯酸中的一种或几种；The organic adhesive is one or more of sodium carboxymethyl cellulose, polyvinyl alcohol, and polyacrylic acid;无机胶黏剂为水玻璃、铝溶胶的一种或几种。The inorganic adhesive is one or more of water glass and aluminum sol.2.如权利要求1所述的制备方法，其特征是，碱处理剂的添加量为玄武岩纤维质量的2~4%。2. preparation method as claimed in claim 1 is characterized in that, the addition of alkali treatment agent is 2～4% of basalt fiber quality.3.如权利要求1所述的制备方法，其特征是，酸处理剂的添加量为玄武岩纤维质量的2~4%。3. preparation method as claimed in claim 1 is characterized in that, the addition of acid treatment agent is 2～4% of basalt fiber quality.4.如权利要求3所述的制备方法，其特征是，盐酸、硫酸和磷酸的质量比为1:1:1。4. preparation method as claimed in claim 3, is characterized in that, the mass ratio of hydrochloric acid, sulfuric acid and phosphoric acid is 1:1:1.5.如权利要求1所述的制备方法，其特征是，酸处理或碱处理中，玄武岩纤维的浆液的浆浓为2~5%质量分数。5. The preparation method according to claim 1, wherein in the acid treatment or the alkali treatment, the slurry concentration of the slurry of the basalt fiber is 2-5% by mass.6.如权利要求1所述的制备方法，其特征是，酸处理或碱处理后，需要将处理后的浆液洗涤至中性。6 . The preparation method according to claim 1 , wherein after acid treatment or alkali treatment, the treated slurry needs to be washed to neutrality. 7 .7.如权利要求1所述的制备方法，其特征是，酸处理或碱处理的处理温度为40~60℃，处理时间为10~15min。7. preparation method as claimed in claim 1 is characterized in that, the treatment temperature of acid treatment or alkali treatment is 40～60 ℃, and the treatment time is 10～15min.8.如权利要求1所述的制备方法，其特征是，分散剂的添加量为玄武岩纤维质量的0.1~0.3%。8. preparation method as claimed in claim 1 is characterized in that, the addition amount of dispersant is 0.1～0.3% of basalt fiber quality.9.如权利要求1所述的制备方法，其特征是，六偏磷酸钠与聚氧化乙烯的质量比为1:1。9. preparation method as claimed in claim 1 is characterized in that, the mass ratio of sodium hexametaphosphate and polyethylene oxide is 1:1.10.如权利要求1所述的制备方法，其特征是，有机胶黏剂为羧甲基纤维素钠。10. The preparation method of claim 1, wherein the organic adhesive is sodium carboxymethyl cellulose.11.如权利要求1所述的制备方法，其特征是，无机胶黏剂为水玻璃与铝溶胶的混合物。11. The preparation method of claim 1, wherein the inorganic adhesive is a mixture of water glass and aluminum sol.12.如权利要求1所述的制备方法，其特征是，有机胶黏剂与无机胶黏剂的混合物为羧甲基纤维素钠、水玻璃与铝溶胶的质量比为1:1:1。12. preparation method as claimed in claim 1, is characterized in that, the mixture of organic sizing agent and inorganic sizing agent is that the mass ratio of sodium carboxymethyl cellulose, water glass and aluminum sol is 1:1:1.13.如权利要求1所述的制备方法，其特征是，有机胶黏剂与无机胶黏剂的混合物的质量为玄武岩纤维质量的20~40%。13. The preparation method of claim 1, wherein the quality of the mixture of the organic adhesive and the inorganic adhesive is 20-40% of the quality of the basalt fiber.14.如权利要求1所述的制备方法，其特征是，稀释至0.5%，然后利用斜网低浓0.01%-0.03%成形，在105℃条件下干燥成形。14. The preparation method according to claim 1, characterized in that, after diluting to 0.5%, and then forming with a low concentration of 0.01%-0.03% using an inclined mesh, and drying and forming at 105°C.15.一种权利要求1~14任一所述的制备方法获得的玄武岩纤维纸。15. A basalt fiber paper obtained by the preparation method described in any one of claims 1 to 14.16.一种权利要求15所述的玄武岩纤维纸在耐温阻燃材料中的应用。16. An application of the basalt fiber paper according to claim 15 in a temperature-resistant and flame-retardant material.