Summary of the invention
The present invention solves the technical problem of: it can not be into one for the antifreeze viscous effect of traditional antifreeze stick coating of shock resistanceThe problem of step improves, provides a kind of antifreeze stick coating of shock resistance.
In order to solve the above-mentioned technical problem, the technical scheme adopted by the invention is that:
A kind of antifreeze stick coating of shock resistance, is made of the raw material of following parts by weight:
40~60 parts of aqueous acrylic emulsion
8~10 parts of ethyl orthosilicate
5~8 parts of methyltriethoxysilane
100~120 parts of dehydrated alcohol
5~8 parts of deionized water
Modified 8~10 parts of additive
5~8 parts of emulsifier
5~8 parts of carbomer
Phosphatidase 3~5 part
5~8 parts of glycoprotein
3~5 parts of ammonium hydroxide
2~3 parts of starch
2~3 parts of albumen powder
2~3 parts of whisker
The preparation process of the antifreeze stick coating of shock resistance are as follows: each raw material is weighed by raw material composition, by methyltriethoxysilane,Dehydrated alcohol, deionized water are stirred, and are subsequently added into aqueous acrylic emulsion, modified additive, emulsifier, carbomer, phosphorusEthyl orthosilicate is then added dropwise in rouge, glycoprotein, starch, albumen powder, whisker, is subsequently added into ammonium hydroxide, is stirred to get anti-impactHit antifreeze stick coating.
The aqueous acrylic emulsion solid content is 50~60%.
The preparation process of the modified additive are as follows: according to parts by weight, by 20~30 parts of rice hull celluloses, 2~3 parts of natural pondsLiquid, 1~2 part of glucose solution, 30~50 parts of water mixed fermentations are filtered, freezing, ball milling, cross the sieve of 280 mesh, dry, at high temperatureReason, cooling is to get modified additive.
The emulsifier is alkyl phenol polyoxyethylene ether, high-carbon fatty alcohol polyoxyethylene ether, cocinic acid, fatty acid or twoAny one in ethanol amine.
The carbomer is Acritamer 940, any one in carbomer 934 or Carbopol 941.
The phosphatide is protein, phospholipid, any one in soybean lecithin or peanut phosphatide.
The glycoprotein is pig blood albumin, bovine serum albumin, any one in sheep blood serum albumen or horse serum albumen.
The starch is any one in glutinous rice starch, cornstarch, starch from sweet potato, potato starch or wheaten starchKind.
The albumen powder is soyabean protein powder, casoid flour, any one in PURE WHEY or Fed Protein Powder of Pea Insteal.
The whisker is calcium carbonate crystal whisker, any one in potassium titanate crystal whisker or aluminium borate whisker.
The beneficial effects of the present invention are:
(1) present invention is by addition carbomer, ethyl orthosilicate, glycoprotein and ammonium hydroxide, during the preparation process, firstly, carbomerIt can interact with the glycoprotein in system, form physical entanglement, and can be with the residual sugar base shape on glycoprotein oligonucleotide chainAt hydrogen bond, stronger mucous gels reticular structure is generated, then passes through and ethyl orthosilicate is added, in ethyl orthosilicate and systemWater reaction generates nano silica, nano silica is once generated in system, i.e., is inhaled by the carbomer with active groupIt is attached, it effectively avoids the nano silica nucleus generated from continuing to grow up, is in always so that generating the silica that hydrolysis obtainsNanoscale, then by the way that ammonium hydroxide is added, ammonium hydroxide makes carboxylic ions on carbomer strand, due to mutually arranging between like chargesReprimand, so that carbomer carries, nano silica is good to be dispersed in system, after using this product, curing of coatings, due toNano silica in system good can be dispersed in system surface, on the one hand, so that the mechanical property of system is mentionedIt rises, on the other hand, so that the roughness on system surface further decreases, so that the mechanical snap power of ice and painting interlayer reduces, makesThe shock peel strength for obtaining ice reduces, so that the antifreeze viscous effect of system is further promoted；
(2) present invention is by adding modified additive, firstly, during the preparation process, by rice hull cellulose, and biogas slurry, glucose solution,Water mixed fermentation, by fermentation, using the organic matter in microorganism decomposition rice hull cellulose, so that interfibrous interface bond strengthFurther decline, so that interfibrous gap is further widened, enables moisture is good to penetrate into system, thenBy liquid nitrogen frozen, so that form ice crystal between fiber, be then passed through ball milling, the rupture of ice crystal so that fibrocyte ruptures,So that fiber splits into the whisker of micro/nano level, it is then passed through charing, so that the rice hull cellulose of micro/nano level carbonizes, due to rice huskFiber surface contains siliceous, internal organic matter and shrinks in carbonization process, and the contraction of extraneous siliceous obstruction fiber,From the raw helix-coil of fibrous crystal beard and hair for making micro/nano level, in use, due to the fiber of spiral helicine micro/nano levelMechanical snap can occur between whisker, so that the mechanical property of system gets a promotion, in addition, during the high temperature treatment process,A large amount of tar can be generated, tar can penetrate into the interface bond strength between modified fibre and matrix, so that systemMechanical property further promoted.
Specific embodiment
According to parts by weight, by 20~30 parts of rice hull celluloses, 2~3 parts of biogas slurries, 1~2 part of mass fraction is 0.3~0.5 timesGlucose solution, 30~50 parts of water are placed in fermentation cauldron, are 30~35 DEG C in temperature, revolving speed is 100~200r/min conditionUnder, it is stirred fermentation 3~5 days, obtains fermentation mixed liquor, then fermentation mixed liquor is filtered, obtain filter cake, filter cake is then placed in liquidIt is freezed in nitrogen, obtains frozen block, frozen block is then placed in ball milling in ball mill, crossed the sieve of 280 mesh, ball milling material is obtained, then by ballAbrasive material is placed in baking oven, dry to constant weight under the conditions of temperature is 105~110 DEG C, dry ball abrasive material is obtained, then by dry ballAbrasive material is placed in tube furnace, and nitrogen is filled with into furnace with 60~90mL/min rate, under the conditions of temperature is 800~850 DEG C,After 1~2h of high-temperature process, room temperature is down to get modified additive with furnace；According to parts by weight, 40~60 parts aqueous third are successively takenOlefin(e) acid lotion, 8~10 parts of ethyl orthosilicates, 5~8 parts of methyltriethoxysilane, 100~120 parts of dehydrated alcohols, 5~8 parts are goneIonized water, 8~10 parts of modified additives, 5~8 parts of emulsifiers, 5~8 parts of carbomers, 3~5 parts of phosphatide, 5~8 parts of glycoprotein and 3The ammonium hydroxide that~5 parts of mass fractions are 20 ~ 30%, 2~3 parts of starch, 2~3 parts of albumen powders, 2~3 parts of whiskers, by methyl triethoxySilane, dehydrated alcohol, deionized water are placed in batch mixer, under the conditions of revolving speed is 400~600r/min, it is stirred 40~60min, is then added aqueous acrylic emulsion into batch mixer, modified additive, emulsifier, carbomer, phosphatide, glycoprotein,Starch, albumen powder, whisker are stirred 40~60min, then into batch mixer under the conditions of revolving speed is 400~600r/minEthyl orthosilicate is added dropwise, under the conditions of revolving speed is 400~600r/min, is stirred 40~60min, then adds into batch mixerEnter the ammonium hydroxide that mass fraction is 20 ~ 30%, under the conditions of revolving speed is 400~600r/min, is stirred 40~60min to get anti-Impact antifreeze stick coating.The aqueous acrylic emulsion solid content is 50~60%.The emulsifier is alkylphenol-polyethenoxyAny one in ether, high-carbon fatty alcohol polyoxyethylene ether, cocinic acid, fatty acid or diethanol amine.The carbomer is cardAny one in wave nurse 940, carbomer 934 or Carbopol 941.The phosphatide is protein, phospholipid, soybean lecithin or peanut phosphorusAny one in rouge.The glycoprotein is pig blood albumin, bovine serum albumin, appointing in sheep blood serum albumen or horse serum albumenIt anticipates one kind.
According to parts by weight, by 30 parts of rice hull celluloses, 3 parts of biogas slurries, the glucose solution that 2 parts of mass fractions are 0.5 times, 50Part water is placed in fermentation cauldron, is 35 DEG C in temperature, under the conditions of revolving speed is 200r/min, is stirred fermentation 5 days, must ferment mixingLiquid, then fermentation mixed liquor is filtered, filter cake is obtained, then filter cake is placed in liquid nitrogen and is freezed, obtains frozen block, then sets frozen blockThe ball milling in ball mill, cross 280 mesh sieve, obtain ball milling material, then ball milling material be placed in baking oven, in temperature be 110 DEG C of conditionsUnder, it is dry to constant weight, dry ball abrasive material is obtained, then dry ball abrasive material is placed in tube furnace, and with 90mL/min rate to furnaceIt is inside filled with nitrogen, under the conditions of temperature is 850 DEG C, after high-temperature process 2h, is down to room temperature with furnace to get modified additive；By weightNumber meter is measured, 60 parts of aqueous acrylic emulsions, 10 parts of ethyl orthosilicates, 8 parts of methyltriethoxysilane, 120 parts of nothings are successively takenWater-ethanol, 8 parts of deionized waters, 10 parts of modified additives, 8 parts of emulsifiers, 8 parts of carbomers, 5 parts of phosphatide, 8 parts of glycoprotein, 5 parts of matterThe ammonium hydroxide that score is 20 ~ 30% is measured, 3 parts of starch, 3 parts of albumen powders, 3 parts of whiskers, by methyltriethoxysilane, dehydrated alcohol is goneIonized water is placed in batch mixer, under the conditions of revolving speed is 600r/min, is stirred 60min, water is then added into batch mixerProperty acrylic emulsion, modified additive, emulsifier, carbomer, phosphatide, glycoprotein, starch, albumen powder, whisker is in revolving speedUnder the conditions of 600r/min, be stirred 60min, ethyl orthosilicate be then added dropwise into batch mixer, in revolving speed be 600r/min itemUnder part, be stirred 60min, then into batch mixer be added mass fraction be 20 ~ 30% ammonium hydroxide, in revolving speed be 600r/minUnder the conditions of, 60min is stirred to get the antifreeze stick coating of shock resistance.The aqueous acrylic emulsion solid content is 60%.It is describedEmulsifier is alkyl phenol polyoxyethylene ether.The carbomer is Acritamer 940.The phosphatide is protein, phospholipid.The glycoproteinFor pig blood albumin.
According to parts by weight, by 30 parts of rice hull celluloses, 3 parts of biogas slurries, the glucose solution that 2 parts of mass fractions are 0.5 times, 50Part water is placed in fermentation cauldron, is 35 DEG C in temperature, under the conditions of revolving speed is 200r/min, is stirred fermentation 5 days, must ferment mixingLiquid, then fermentation mixed liquor is filtered, filter cake is obtained, then filter cake is placed in liquid nitrogen and is freezed, obtains frozen block, then sets frozen blockThe ball milling in ball mill, cross 280 mesh sieve, obtain ball milling material, then ball milling material be placed in baking oven, in temperature be 110 DEG C of conditionsUnder, it is dry to constant weight, dry ball abrasive material is obtained, then dry ball abrasive material is placed in tube furnace, and with 90mL/min rate to furnaceIt is inside filled with nitrogen, under the conditions of temperature is 850 DEG C, after high-temperature process 2h, is down to room temperature with furnace to get modified additive；By weightNumber meter is measured, 60 parts of aqueous acrylic emulsions, 8 parts of methyltriethoxysilane, 120 parts of dehydrated alcohols, 8 parts of deionizations are successively takenWater, 10 parts of modified additives, 8 parts of emulsifiers, 8 parts of carbomers, 5 parts of phosphatide, 8 parts of glycoprotein, 5 parts of mass fractions are 20 ~ 30%Ammonium hydroxide, 3 parts of starch, 3 parts of albumen powders, 3 parts of whiskers, by methyltriethoxysilane, dehydrated alcohol, deionized water is placed in batch mixerIn, under the conditions of revolving speed is 600r/min, it is stirred 60min, aqueous acrylic emulsion is then added into batch mixer, it is modifiedAdditive, emulsifier, carbomer, phosphatide, glycoprotein, starch, albumen powder, whisker, under the conditions of revolving speed is 600r/min, stirring60min is mixed, the ammonium hydroxide that mass fraction is 20 ~ 30% is then added into batch mixer, under the conditions of revolving speed is 600r/min, is stirredMixing 60min is mixed to get the antifreeze stick coating of shock resistance.The aqueous acrylic emulsion solid content is 60%.The emulsifier is alkaneBase phenol polyethenoxy ether.The carbomer is Acritamer 940.The phosphatide is protein, phospholipid.The glycoprotein is Swine serum eggIt is white.
According to parts by weight, 60 parts of aqueous acrylic emulsions, 10 parts of ethyl orthosilicates, 8 parts of methyl triethoxies are successively takenSilane, 120 parts of dehydrated alcohols, 8 parts of deionized waters, 8 parts of emulsifiers, 8 parts of carbomers, 5 parts of phosphatide, 8 parts of glycoprotein, 5 parts of qualityThe ammonium hydroxide that score is 20 ~ 30%, 3 parts of starch, 3 parts of albumen powders, 3 parts of whiskers, by methyltriethoxysilane, dehydrated alcohol, go fromSub- water is placed in batch mixer, under the conditions of revolving speed is 600r/min, is stirred 60min, is then added into batch mixer aqueousAcrylic emulsion, emulsifier, carbomer, phosphatide, glycoprotein, starch, albumen powder, whisker, under the conditions of revolving speed is 600r/min,It is stirred 60min, ethyl orthosilicate is then added dropwise into batch mixer, under the conditions of revolving speed is 600r/min, is stirredThe ammonium hydroxide that mass fraction is 20 ~ 30% is then added in 60min into batch mixer, and under the conditions of revolving speed is 600r/min, stirring is mixed60min is closed to get the antifreeze stick coating of shock resistance.The aqueous acrylic emulsion solid content is 60%.The emulsifier is alkyl phenolPolyoxyethylene ether.The carbomer is Acritamer 940.The phosphatide is protein, phospholipid.The glycoprotein is pig blood albumin.
According to parts by weight, by 30 parts of rice hull celluloses, 3 parts of biogas slurries, the glucose solution that 2 parts of mass fractions are 0.5 times, 50Part water is placed in fermentation cauldron, is 35 DEG C in temperature, under the conditions of revolving speed is 200r/min, is stirred fermentation 5 days, must ferment mixingLiquid, then fermentation mixed liquor is filtered, filter cake is obtained, then filter cake is placed in liquid nitrogen and is freezed, obtains frozen block, then sets frozen blockThe ball milling in ball mill, cross 280 mesh sieve, obtain ball milling material, then ball milling material be placed in baking oven, in temperature be 110 DEG C of conditionsUnder, it is dry to constant weight, dry ball abrasive material is obtained, then dry ball abrasive material is placed in tube furnace, and with 90mL/min rate to furnaceIt is inside filled with nitrogen, under the conditions of temperature is 850 DEG C, after high-temperature process 2h, is down to room temperature with furnace to get modified additive；By weightNumber meter is measured, 60 parts of aqueous acrylic emulsions, 10 parts of ethyl orthosilicates, 8 parts of methyltriethoxysilane, 120 parts of nothings are successively takenWater-ethanol, 8 parts of deionized waters, 10 parts of modified additives, 8 parts of emulsifiers, 5 parts of phosphatide, 8 parts of glycoprotein, 5 parts of mass fractions are 20~ 30% ammonium hydroxide, 3 parts of starch, 3 parts of albumen powders, 3 parts of whiskers, by methyltriethoxysilane, dehydrated alcohol, deionized water is placed inIn batch mixer, under the conditions of revolving speed is 600r/min, it is stirred 60min, aqueous acrylamide yogurt is then added into batch mixerLiquid, modified additive, emulsifier, phosphatide, glycoprotein, starch, albumen powder, whisker, under the conditions of revolving speed is 600r/min, stirring60min is mixed, ethyl orthosilicate is then added dropwise into batch mixer, under the conditions of revolving speed is 600r/min, is stirred 60min,Then the ammonium hydroxide that mass fraction is 20 ~ 30% is added into batch mixer, under the conditions of revolving speed is 600r/min, is stirred60min is to get the antifreeze stick coating of shock resistance.The aqueous acrylic emulsion solid content is 60%.The emulsifier is poly- for alkyl phenolEthylene oxide ether.The phosphatide is protein, phospholipid.The glycoprotein is pig blood albumin.
According to parts by weight, by 30 parts of rice hull celluloses, 3 parts of biogas slurries, the glucose solution that 2 parts of mass fractions are 0.5 times, 50Part water is placed in fermentation cauldron, is 35 DEG C in temperature, under the conditions of revolving speed is 200r/min, is stirred fermentation 5 days, must ferment mixingLiquid, then fermentation mixed liquor is filtered, filter cake is obtained, then filter cake is placed in liquid nitrogen and is freezed, obtains frozen block, then sets frozen blockThe ball milling in ball mill, cross 280 mesh sieve, obtain ball milling material, then ball milling material be placed in baking oven, in temperature be 110 DEG C of conditionsUnder, it is dry to constant weight, dry ball abrasive material is obtained, then dry ball abrasive material is placed in tube furnace, and with 90mL/min rate to furnaceIt is inside filled with nitrogen, under the conditions of temperature is 850 DEG C, after high-temperature process 2h, is down to room temperature with furnace to get modified additive；By weightNumber meter is measured, 60 parts of aqueous acrylic emulsions, 10 parts of ethyl orthosilicates, 8 parts of methyltriethoxysilane, 120 parts of nothings are successively takenWater-ethanol, 8 parts of deionized waters, 10 parts of modified additives, 8 parts of emulsifiers, 8 parts of carbomers, 8 parts of glycoprotein, 5 parts of mass fractions are20 ~ 30% ammonium hydroxide, 3 parts of starch, 3 parts of albumen powders, 3 parts of whiskers, by methyltriethoxysilane, dehydrated alcohol, deionized water is setIn batch mixer, under the conditions of revolving speed is 600r/min, it is stirred 60min, water soluble acrylic acid is then added into batch mixerLotion, modified additive, emulsifier, carbomer, glycoprotein, starch, albumen powder, whisker, under the conditions of revolving speed is 600r/min,It is stirred 60min, ethyl orthosilicate is then added dropwise into batch mixer, under the conditions of revolving speed is 600r/min, is stirredThe ammonium hydroxide that mass fraction is 20 ~ 30% is then added in 60min into batch mixer, and under the conditions of revolving speed is 600r/min, stirring is mixed60min is closed to get the antifreeze stick coating of shock resistance.The aqueous acrylic emulsion solid content is 60%.The emulsifier is alkyl phenolPolyoxyethylene ether.The carbomer is Acritamer 940.The glycoprotein is pig blood albumin.
According to parts by weight, by 30 parts of rice hull celluloses, 3 parts of biogas slurries, the glucose solution that 2 parts of mass fractions are 0.5 times, 50Part water is placed in fermentation cauldron, is 35 DEG C in temperature, under the conditions of revolving speed is 200r/min, is stirred fermentation 5 days, must ferment mixingLiquid, then fermentation mixed liquor is filtered, filter cake is obtained, then filter cake is placed in liquid nitrogen and is freezed, obtains frozen block, then sets frozen blockThe ball milling in ball mill, cross 280 mesh sieve, obtain ball milling material, then ball milling material be placed in baking oven, in temperature be 110 DEG C of conditionsUnder, it is dry to constant weight, dry ball abrasive material is obtained, then dry ball abrasive material is placed in tube furnace, and with 90mL/min rate to furnaceIt is inside filled with nitrogen, under the conditions of temperature is 850 DEG C, after high-temperature process 2h, is down to room temperature with furnace to get modified additive；By weightNumber meter is measured, 60 parts of aqueous acrylic emulsions, 10 parts of ethyl orthosilicates, 8 parts of methyltriethoxysilane, 120 parts of nothings are successively takenWater-ethanol, 8 parts of deionized waters, 10 parts of modified additives, 8 parts of emulsifiers, 8 parts of carbomers, 5 parts of phosphatide, 5 parts of mass fractions are 20~ 30% ammonium hydroxide, 3 parts of starch, 3 parts of albumen powders, 3 parts of whiskers, by methyltriethoxysilane, dehydrated alcohol, deionized water is placed inIn batch mixer, under the conditions of revolving speed is 600r/min, it is stirred 60min, aqueous acrylamide yogurt is then added into batch mixerLiquid, modified additive, emulsifier, carbomer, phosphatide, starch, albumen powder, whisker, under the conditions of revolving speed is 600r/min, stirring60min is mixed, ethyl orthosilicate is then added dropwise into batch mixer, under the conditions of revolving speed is 600r/min, is stirred 60min,Then the ammonium hydroxide that mass fraction is 20 ~ 30% is added into batch mixer, under the conditions of revolving speed is 600r/min, is stirred60min is to get the antifreeze stick coating of shock resistance.The aqueous acrylic emulsion solid content is 60%.The emulsifier is poly- for alkyl phenolEthylene oxide ether.The carbomer is Acritamer 940.The phosphatide is protein, phospholipid.
According to parts by weight, by 30 parts of rice hull celluloses, 3 parts of biogas slurries, the glucose solution that 2 parts of mass fractions are 0.5 times, 50Part water is placed in fermentation cauldron, is 35 DEG C in temperature, under the conditions of revolving speed is 200r/min, is stirred fermentation 5 days, must ferment mixingLiquid, then fermentation mixed liquor is filtered, filter cake is obtained, then filter cake is placed in liquid nitrogen and is freezed, obtains frozen block, then sets frozen blockThe ball milling in ball mill, cross 280 mesh sieve, obtain ball milling material, then ball milling material be placed in baking oven, in temperature be 110 DEG C of conditionsUnder, it is dry to constant weight, dry ball abrasive material is obtained, then dry ball abrasive material is placed in tube furnace, and with 90mL/min rate to furnaceIt is inside filled with nitrogen, under the conditions of temperature is 850 DEG C, after high-temperature process 2h, is down to room temperature with furnace to get modified additive；By weightNumber meter is measured, 60 parts of aqueous acrylic emulsions, 10 parts of ethyl orthosilicates, 8 parts of methyltriethoxysilane, 120 parts of nothings are successively takenWater-ethanol, 8 parts of deionized waters, 10 parts of modified additives, 8 parts of emulsifiers, 8 parts of carbomers, 5 parts of phosphatide, 8 parts of glycoprotein, 3 parts of shallow lakesPowder, 3 parts of albumen powders, 3 parts of whiskers, by methyltriethoxysilane, dehydrated alcohol, deionized water is placed in batch mixer, in revolving speedUnder the conditions of 600r/min, it is stirred 60min, aqueous acrylic emulsion, modified additive, cream are then added into batch mixerAgent, carbomer, phosphatide, glycoprotein, starch, albumen powder, whisker are stirred under the conditions of revolving speed is 600r/minEthyl orthosilicate is then added dropwise in 60min into batch mixer, under the conditions of revolving speed is 600r/min, is stirred 60min, stirs60min is mixed to get the antifreeze stick coating of shock resistance.The aqueous acrylic emulsion solid content is 60%.The emulsifier is alkylPhenol polyethenoxy ether.The carbomer is Acritamer 940.The phosphatide is protein, phospholipid.The glycoprotein is pig blood albumin.
Comparative example: according to parts by weight, successively taking 60 parts of aqueous acrylic emulsions, 8 parts of methyltriethoxysilane, and 120Part dehydrated alcohol, 8 parts of deionized waters, 8 parts of emulsifiers, 3 parts of starch, 3 parts of albumen powders, 3 parts of whiskers, by methyltriethoxy silaneAlkane, dehydrated alcohol, deionized water are placed in batch mixer, in revolving speed be 600r/min under the conditions of, be stirred 60min, then toBe added aqueous acrylic emulsion in batch mixer, modified additive, emulsifier, starch, albumen powder, whisker, in revolving speed be 600r/Under the conditions of min, it is stirred 60min, under the conditions of revolving speed is 600r/min, it is antifreeze viscous to get shock resistance to be stirred 60minCoating.The aqueous acrylic emulsion solid content is 60%.The emulsifier is alkyl phenol polyoxyethylene ether.
Example 1 to the antifreeze stick coating of the resulting shock resistance of example 7 and comparative example product are subjected to performance detection, it is specific to detectMethod is as follows:
1. using L9(34) type normal orthogonal test table tested, use tangential peel strength for measurement index, numerical value is got overIt is small better.
According to GB/T1732(" paint film impact resistance measuring method ") national standard, shock resistance is carried out using heavy impactorTest.Coating is coated on Q235 steel plate first, thickness control is in 3mm, to its after curing completely, with 2kg weight in differenceCoating is impacted in vertical drop in height, carries out coating impact and passes through test, investigates the impact resistance of coating, carry out 5 timesParallel test is averaged.
Specific testing result is as shown in table 1:
The specific testing result of the antifreeze stick coating of 1 shock resistance of table
By 1 testing result of table it is found that the antifreeze stick coating of shock resistance of technical solution of the present invention preparation has excellent antifreeze viscous effectThe characteristics of fruit and mechanical property, has broad prospects in the development of building material technology industry.