A kind of suspension oil droplet makeup remover and preparation method thereofTechnical field
The invention belongs to daily chemicals fields, are related to a kind of makeup removal products, especially a kind of suspension oil droplet makeup remover and its preparationMethod.
Background technique
With the improvement of people's living standards, masses increasingly follow the fashion and beauty, the use of color make-up is also increasingly widerIt is general.With the rise of color make-up, demand of the people to makeup removal products is also more and more vigorous.After face makeup, if do not removed thoroughly,Remaining cosmetics or the various dirts of absorption can cause the clogging of pores of skin of face, and the skin that gets off for a long time cannot exhaleIt inhales, acne, acne and blackhead etc. can be caused to make us the skin problem of puzzlement.So makeup removing and makeup are same for skin nursingImportant, makeup removal products have become pith indispensable in daily skin nursing.
Commercially available low viscosity face makeup removal products, traditional has makeup remover and makeup remover, and appearance is all uniform liquid.In recent yearsCome the also popular double-deck make up remover, the Double-layer liquid that usually upper layer is oil, lower layer is water.
Makeup remover quality is salubrious, does not stimulate mildly, but ability of removing ornaments and formal dress is weaker.Makeup remover makeup removing ability is stronger, stillBecause it is with the characteristic of the molten oil of oil, the sebum film of human body itself can be also washed away while removal color make-up, long-time service is be easy to causeBarrier is impaired, and skin sense sticks greasy makeup remover when in use, makes people unhappy.The double-deck makeup remover in combination with makeup remover with unloadThe advantages of adornment water, makeup removing effect is better than makeup remover, when use the tender non-greasy of water salubriouser than makeup remover, and it is mild, non-stimulated, it is specialIt Shi Yongyu not the use of the sensitive parts such as eye and lip.But the double-deck makeup remover is in use process that there are several distinct disadvantages: 1,It must firmly be rocked before, some consumers may be because that the dynamics of rocking is inadequate, cause usage experience bad；2, oil, water two-phaseAfter shaking up can fast hierarchical, consumer is in the color make-up to more difficult removal, such as when waterproof eye-liner, mascara are removed ornaments and formal dress,It repeated multiple times need to shake up, the makeup removing time is longer, and makeup removal efficiency is low；3, water in the make up remover got when each use is not can guaranteeMutually as the ratio of oily phase, makeup removing effect is inconsistent when same bottle makeup remover being caused to use every time.
Summary of the invention
It is an object of the invention to good, the users that provides a kind of makeup removing effect in view of the deficiencies of the prior art mentioned aboveJust, and after do not stick it is greasy, to the inirritative makeup removal products of skin.
To achieve the above object, the technical scheme adopted by the invention is as follows: a kind of makeup remover of suspension oil droplet, including following matterMeasure the component of percentage composition: grease 5-20%, thickener 0.15-1.0%, the grease include silicone oil, vegetable oil, synthesizing esterAnd squalene extracting, in the silicone oil, vegetable oil, synthesizing ester and squalene extracting composition, the silicone oil, vegetable oil, conjunctionIt is synthesizing ester: silicone oil: vegetable oil: squalene extracting=(3.5~4): (3~3.5) at the mass ratio of esters and squalene extracting:(1~2): (1~1.5), the density of the grease are 0.9995~1.0100, and the synthesizing ester is Sucrose Acetate acid sucrose；The thickener is pectin and gellan gum.
Sucrose acetoisobutyrate is typically used as food additives, with various types grease good compatibility, relative density1.14-1.15 having wet dispersion force to pigment.In addition to adjusting oily phase density, its removal to color make-ups such as eye shadow, lipstick, foundation creamsAbility is very excellent.
Pectin is a kind of natural macromolecule amylose substance, usually with the pericarp of shaddock, lemon, citrus, apple etc. or fruitSlag is raw material, food additives obtained by extracted, purification, can be used as thickener, gelling agent, stabilizer, tissue forming agent.TogetherWhen, pectin has the function of autobalance pH, can form protective film in skin surface when it is applied to makeup remover, make facial fleshSkin is adjusted to normal acid-base balance state.After pectin is compounded with gellan gum according to special ratios, it is crosslinked the synergistic effect of generation,So that gellan gum has more excellent suspension stability；The stability of grease suspension can be effectively improved.
The makeup remover of suspension oil droplet, technical difficult points are the stability and makeup removing effect that oil droplet suspends, and greaseTwo phase densities are close, are the key factors that oil droplet can suspend.The grease density range that the combination matching obtains is in 0.9995-Between 1.0100, it is approximately equal to the density of water.
Mutually collocation is combination of the various types grease according to special ratios, product, silicone oil for vegetable oil system to the oilThe product of system and the product of dormant oil system have outstanding solvability, this is also to improve makeup removing effect key factor.IncreaseThick dose of addition can further increase stability, so that oil droplet preferably suspends.
Preferably, the density of the grease is 1.003.
Specifically, the silicone oil in the grease is at least one of following components: phenyl polymethyl siloxane, phenyl are poly-Trimethicone, the poly- trimethicone of diphenyl silicon phenyl, trimethyl pentaphenyltrisiloxane, diphenyl are poly-Dimethyl siloxane, ring five dimethyl silicone polymer, cyclohexasiloxane, dimethyl silicone polymer；Vegetable oil in the greaseFor at least one of following components: olive oil, Sweet Almond Oil, macadimia nut oil, white pond flower seed oil, rice bran oil, cottonseed oil, smallWheat germ oil, corn oil, jojoba oil, tea-seed oil；Squalene extracting in the grease is at least one of following components: liquidBody paraffin, Nexbase 2004, isomery hexadecane, isomery dodecane, Parleam, saualane.
The selection of grease and makeup removing effect are closely related, therefore it is most important to reasonably select grease.
Preferably, the grease includes Sucrose acetoisobutyrate, phenyl trimethicone, white pond flower seed oil, liquidBody paraffin, the mass ratio of each component are as follows: Sucrose acetoisobutyrate: phenyl trimethicone: white pond flower seed oil: liquid stoneWax=3.5:3:1:1.
Specifically, the mass ratio of the gellan gum and pectin is 1:0.2~0.6.Preferably, the gellan gum and pectinMass ratio is 1:0.5.
Through testing, when gellan gum and pectin mass ratio are 1:0.2~0.6, the suspension effect of oil droplet is good, if exceeding the modelIt encloses, suspension stability decline.
Further, the makeup remover further includes the component of following mass percentage: moisturizer 10-30%, preservative0.2-1%, surfactant 0.1-1%, electrolyte 0.05-0.2%, antioxidant 0.01-0.5%, pigment 0.001-0.3% and water surplus.
Specifically, the moisturizer includes at least one of following components: glycerol, diglycerol, dipropylene glycol, the third twoAlcohol, 1,3-BDO, PEG-6, isoprene；The preservative includes at least one of following components: Chlorphenesin, poly- ammoniaPropyl biguanides, parahydroxyacet-ophenone, imidazolidinyl urea, Phenoxyethanol, Sensiva SC50, pungent glycol, decoyl hydroximic acid；It is describedSurfactant include following components at least one of: PEG-7 glyceryl cocoate, poloxamer, PEG-6 caprylic/capricGlyceride；The electrolyte includes but is not limited to calcium chloride；The antioxidant includes at least one of following components: fourthHydroxy toluene, pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamate), tocopherol acetate；The pigment includes followingAt least one of component: solvent yellow 16, solvent green 3, German chamomile essential oil, Asian puccoon root extract, sunflower seed oil, kermesRed, lemon yellow, light green, brilliant blue.
Pigment assigns the better appearance of make up remover, and the pleasure of the senses of user can be improved.Wherein, solvent yellow 16 (i.e. CI12700), solvent green 3 (i.e. CI 61565), German chamomile essential oil, Asian puccoon root extract, sunflower seed oil are fat-soluble colorElement, famille rose, lemon yellow, light green, brilliant blue are water colo(u)r.
Preferably, the preservative is pungent glycol and Sensiva SC50；The surfactant is poloxamer；It is describedPigment is German chamomile essential oil.
Pungent glycol is skin emollient, wetting agent, and existing good moisturizer also has anti-corrosion function, can prevent water-basedBacterium and yeast are exceeded in formula, make an addition in product to play and assist moisturizing, softening and antibacterial application.Sensiva SC50 is toolThere is the moisturizer of antibacterial activity.
Poloxamer is polyoxyethylene poly-oxygen propylene aether block copolymer, is that a kind of novel macromolecule non-ionic surface is livingProperty agent；It is safe and non-stimulating, assist removal color make-up.
The main component of German chamomile essential oil includes german chamomile azulene, α-bisabol and sesquiterpene lactone, is had excellentAnti-inflammatory effects, on skin measles, itch, dry, exfoliant effect it is significant.In addition, being not necessarily to due to the presence of azuleneAddition pigment just can make oil mutually show graceful navy blue.De Gan is with slightly sweet spice taste, to calm equilibrium nerve systemSystem, eliminating anxiety also has good curative effect.
The present invention also provides the preparation methods of the makeup remover, and steps are as follows:
(1) water phase: main still is added in water, is added in room temperature water after thickener and moisturizer are premixed uniformly, agitating and heatingSufficiently to 80-85 DEG C of swelling, surfactant is then added to stir evenly, is cooled to 70-75 DEG C of addition electrolyte, is cooled to 50DEG C preservative is added stirs evenly, and standing is cooled to 30 DEG C or less and condenses into solid gum, uses homogenizer, speed 1000-2000rpm homogeneous 3-5min smashes solid gum for uniform fluid glue；
(2) oily phase: mixing each grease, antioxidant, and is heated to 75 DEG C with transparent up to dissolving, and is cooled to 40 DEG C ± 5DEG C, pigment is added, stirs evenly；
(3) finished product: under agitation, oily phase is added in main still water phase, until oil droplet suspension is in water phase, after stirring evenlyDischarging.
It is that can assemble to form double helix knot automatically between molecule after it is dissolved in water that gellan gum, which has the reason of levitation effect,Structure, and the addition of electrolyte have caused the polymerization crosslinking between double helix.Further assemble when double helix and forms three-dimensional netted knotStructure, hydrone, which is trapped, produces gelatin phenomenon.The fluid glue of traditional handicraft preparation is lasting stirring drop after electrolyte is addedTemperature is to gelling temp hereinafter, process and not formed tridimensional network, only provide suspending power by double-spiral structure at this time.And this hairIt is blended again after bright formation solid gel as fluid glue, the molecule hydrogen bond for forming tridimensional network still remains, molecule knotStructure is secured, this suspending power for allowing for system greatly improves.
The oil phase of the double-deck makeup remover can be steadily suspended in water phase by suspension oil droplet makeup remover of the present inventionIn, without rocking when use, no longer there is water-oil phase and takes uneven phenomenon, not only completely in grease uniform discharge when takingGround remains the advantages that double-deck makeup remover irritation is low, and skin sense is salubrious and makeup removing effect is good, also solves it in use processIn various inconvenience, greatly improve makeup removal efficiency；Oil of the invention, which is combined, further improves makeup removing effect, to variousColor make-up, the sunscreen product of type all have good removal effect；Completely new make up remover appearance can also be brought more to consumerPleasant makeup removing new experience.In addition, the present invention also provides the preparation method of the makeup remover, makeup remover production cost of the inventionLow, preparation process is not related to complicated technology, can be used for a large amount of steady productions makeup remover, provides quality-high and inexpensive unload for consumerComplete outfit for newlyweds selection.
Detailed description of the invention
Fig. 1 is using the embodiment of the present invention 1, embodiment 3, the makeup remover of comparative example 4 and typical bilayer make up remover to eyelashesThe makeup removing effect test result of cream.
Fig. 2 is using the embodiment of the present invention 1, embodiment 3, the makeup remover of comparative example 4 and typical bilayer make up remover to non-stickyThe red makeup removing effect test result of rim of a cup.
Fig. 3 is the embodiment of the present invention 4, the makeup remover of comparative example 5-8 to the makeup removing effect test result of mascara.
The makeup removing effect test result that Fig. 4 is the embodiment of the present invention 4, the makeup remover of comparative example 5-8 is red to non-sticky rim of a cup.
Specific embodiment
To better illustrate the object, technical solutions and advantages of the present invention, below in conjunction with specific embodiment to the present inventionIt is described further.
Embodiment 1
As a kind of embodiment of the invention, consisting of the component of following mass percentage: 20% isoprene,5% dipropylene glycol, 5% butanediol, 0.08% pectin, 0.16% gellan gum, 0.12% calcium chloride, 0.3% it is pungentGlycol, 0.2% Sensiva SC50,0.2% poloxamer, 8% Sucrose acetoisobutyrate, 2% the poly- front three of phenylRadical siloxane, 2% ring five dimethyl silicone polymer, 2% trimethyl pentaphenyltrisiloxane, 1% macadimia nut oil,1% white pond flower seed oil, 2% olive oil, 0.5% atoleine, 1% Nexbase 2004,0.5% saualane,0.3% tocopherol acetate, 0.02% German chamomile essential oil and water surplus.The preparation of makeup remover of the present inventionMethod, steps are as follows:
(1) water phase: main still is added in water, is added in room temperature water after thickener and moisturizer are premixed uniformly, agitating and heatingSufficiently to 80-85 DEG C of swelling, surfactant is then added to stir evenly, is cooled to 70-75 DEG C of addition electrolyte, is cooled to 50DEG C preservative is added stirs evenly, and standing is cooled to 30 DEG C or less and condenses into solid gum, uses homogenizer, speed 1000-2000rpm homogeneous 3-5min smashes solid gum for uniform fluid glue；
(2) oily phase: mixing each grease, antioxidant, and is heated to 75 DEG C with transparent up to dissolving, and is cooled to 40 DEG C ± 5DEG C, pigment is added, stirs evenly；
(3) finished product: under agitation, oily phase is added in main still water phase, until oil droplet suspension is in water phase, after stirring evenlyDischarging.
Embodiment 2
As a kind of embodiment of the invention, the preparation method of the makeup remover is same as Example 1, consisting of belowThe component of mass percentage: 20% dipropylene glycol, 5% butanediol, 0.05% pectin, 0.1% gellan gum, 0.05%Calcium chloride, 0.1% pungent glycol, 0.1% Sensiva SC50,0.1% poloxamer, 5.25% Sucrose Acetate acid sugarcaneSugar ester, 4.5% phenyl trimethicone, 1.5% white pond flower seed oil, 1.5% atoleine, 0.05% season pentaTetrol four (double-tert-butyl hydroxy hydrocinnamic acid) ester, 0.1% German chamomile essential oil and water surplus.
Embodiment 3
As a kind of embodiment of the invention, the preparation method of the makeup remover is same as Example 1, consisting of belowThe component of mass percentage: 10% isoprene, 10% dipropylene glycol, 10% butanediol, 0.2% pectin, 0.4%Gellan gum, 0.3% calcium chloride, 0.1% pungent glycol, 0.3% Sensiva SC50,0.2% poloxamer, 2%Sucrose acetoisobutyrate, 1% ring five dimethyl silicone polymer, 0.5% trimethyl pentaphenyltrisiloxane, 1% it is whitePond flower seed oil, 0.5% atoleine, 0.5% tocopherol acetate, 0.0001% German chamomile essential oil, Yi JishuiSurplus.
Embodiment 4
As a kind of embodiment of the invention, the preparation method of the makeup remover is same as Example 1, consisting of belowThe component of mass percentage: 15% isoprene, 15% dipropylene glycol, 0.072% pectin, 0.12% gellan gum,0.09% calcium chloride, 0.1% pungent glycol, 0.5% Sensiva SC50,0.2% poloxamer, 3.5% acetic acid are differentButyric acid sucrose ester, 1% phenyl trimethicone, 1% ring five dimethyl silicone polymer, 1% five phenyl of trimethylTrisiloxanes, 0.5% macadimia nut oil, 0.5% white pond flower seed oil, 0.5% atoleine, 0.5% Nexbase 2004,0.5% saualane, 0.1% tocopherol acetate, 0.3% German chamomile essential oil and water surplus.
Embodiment 5
As a kind of embodiment of the invention, the preparation method of the makeup remover is same as Example 1, consisting of belowThe component of mass percentage: 10% isoprene, 0.04% pectin, 0.2% gellan gum, 0.15% calcium chloride,0.2% pungent glycol, 0.2% Sensiva SC50,1% poloxamer, 3.5% Sucrose acetoisobutyrate, 3% benzeneThe poly- trimethicone of base, 1% macadimia nut oil, 1% saualane, 0.01% pentaerythrite four (double-tert-butyl hydroxy hydrogenChange cinnamic acid) ester, 0.2% tocopherol acetate, 0.2% German chamomile essential oil and water surplus.
Embodiment 6
As a kind of embodiment of the invention, the preparation method of the makeup remover is same as Example 1, consisting of belowThe component of mass percentage: 20% butanediol, 0.2% pectin, 0.8% gellan gum, 0.2% calcium chloride, 0.3%Pungent glycol, 0.2% Sensiva SC50,0.5% poloxamer, 2% Sucrose acetoisobutyrate, 0.25% ring five it is poly-Dimethyl siloxane, 1.5% trimethyl pentaphenyltrisiloxane, 0.5% macadimia nut oil, 0.5% white pond flower seed oil,0.5% atoleine, 0.25% Nexbase 2004,0.01% pentaerythrite four (double-tert-butyl hydroxy hydrocinnamoylAcid) ester, 0.05% German chamomile essential oil and water surplus.
Comparative example 1
As comparative example of the invention, the preparation method of the makeup remover is same as Example 1, consisting of following qualityThe component of percentage composition: 20% isoprene, 5% dipropylene glycol, 5% butanediol, 0.016% pectin, 0.16%Gellan gum, 0.12% calcium chloride, 0.3% pungent glycol, 0.2% Sensiva SC50,0.2% poloxamer, 8% secondSour isobutyric acid sucrose ester, 2% phenyl trimethicone, 2% ring five dimethyl silicone polymer, 2% trimethyl fivePhenyl trisiloxanes, 1% macadimia nut oil, 1% white pond flower seed oil, 2% olive oil, 0.5% atoleine, 1%Nexbase 2004,0.5% saualane, 0.3% tocopherol acetate, 0.02% German chamomile essential oil, Yi JishuiSurplus.
Comparative example 2
As a kind of comparative example of the invention, the composition of the makeup remover is same as Example 1, but makeup removing of the present inventionThe preparation method of water, steps are as follows:
(1) water phase: main still is added in water, is added in room temperature water after thickener and moisturizer are premixed uniformly, agitating and heatingSufficiently to 80-85 DEG C of swelling, surfactant is then added to stir evenly, is cooled to 70-75 DEG C of addition electrolyte, is cooled to 50DEG C preservative is added stirs evenly, and lasting stirring is cooled to 30 DEG C or less；
(2) oily phase: mixing each grease, antioxidant, and is heated to 75 DEG C with transparent up to dissolving, and is cooled to 40 DEG C ± 5DEG C, pigment is added, stirs evenly；
(3) finished product: under agitation, oily phase is added in main still water phase, until oil droplet suspension is in water phase, after stirring evenlyDischarging.
Comparative example 3
As a kind of comparative example of the invention, the preparation method of the makeup remover is same as Example 1, consisting of belowThe component of mass percentage: 20% isoprene, 5% dipropylene glycol, 5% butanediol, 0.08% pectin, 0.16%Gellan gum, 0.12% calcium chloride, 0.3% pungent glycol, 0.2% Sensiva SC50,0.2% poloxamer, 6%Sucrose acetoisobutyrate, 2% phenyl trimethicone, 2% ring five dimethyl silicone polymer, 2% trimethylPentaphenyltrisiloxane, 1% macadimia nut oil, 1% white pond flower seed oil, 2% olive oil, 0.5% atoleine,1% Nexbase 2004,0.5% saualane, 0.3% tocopherol acetate, 0.02% German chamomile essential oil, andWater surplus.
Comparative example 4
As a kind of comparative example of the invention, the preparation method of the makeup remover is same as Example 1, consisting of belowThe component of mass percentage: 20% isoprene, 5% dipropylene glycol, 5% butanediol, 0.08% pectin, 0.16%Gellan gum, 0.12% calcium chloride, 0.3% pungent glycol, 0.2% Sensiva SC50,0.2% poloxamer, 8%Caprylic/capric/amber acid glycerol three ester, 2% phenyl trimethicone, 2% ring five dimethyl silicone polymer, 2%Trimethyl pentaphenyltrisiloxane, 1% macadimia nut oil, 1% white pond flower seed oil, 2% olive oil, 0.5% liquidBody paraffin, 1% Nexbase 2004,0.5% saualane, 0.3% tocopherol acetate, 0.02% German chamomile essenceOil and water surplus.
Comparative example 5
As a kind of comparative example of the invention, the preparation method of the makeup remover is same as Example 1, consisting of belowThe component of mass percentage: 15% isoprene, 15% dipropylene glycol, 0.072% pectin, 0.12% gellan gum,0.09% calcium chloride, 0.1% pungent glycol, 0.5% Sensiva SC50,0.2% poloxamer, 4.5% phenyl are poly-Trimethicone, 1% ring five dimethyl silicone polymer, 1% trimethyl pentaphenyltrisiloxane, 0.5% Queensland nutOil, 0.5% white pond flower seed oil, 0.5% atoleine, 0.5% Nexbase 2004,0.5% saualane, 0.1%Tocopherol acetate, 0.3% German chamomile essential oil and water surplus.
Comparative example 6
As a kind of comparative example of the invention, the preparation method of the makeup remover is same as Example 1, consisting of belowThe component of mass percentage: 15% isoprene, 15% dipropylene glycol, 0.072% pectin, 0.12% gellan gum,0.09% calcium chloride, 0.1% pungent glycol, 0.5% Sensiva SC50,0.2% poloxamer, 3.5% acetic acid are differentButyric acid sucrose ester, 0.5% macadimia nut oil, 0.5% white pond flower seed oil, 3% olive oil, 0.5% atoleine,0.5% Nexbase 2004,0.5% saualane, 0.1% tocopherol acetate, 0.3% German chamomile essential oil, withAnd water surplus.
Comparative example 7
As a kind of embodiment of the invention, the preparation method of the makeup remover is same as Example 1, consisting of belowThe component of mass percentage: 15% isoprene, 15% dipropylene glycol, 0.072% pectin, 0.12% gellan gum,0.09% calcium chloride, 0.1% pungent glycol, 0.5% Sensiva SC50,0.2% poloxamer, 3.5% acetic acid are differentButyric acid sucrose ester, 1% phenyl trimethicone, 1% ring five dimethyl silicone polymer, 1% five phenyl of trimethylTrisiloxanes, 1.5% atoleine, 0.5% Nexbase 2004,0.5% saualane, 0.1% tocopherol acetate,0.3% German chamomile essential oil and water surplus.
Comparative example 8
As a kind of embodiment of the invention, the preparation method of the makeup remover is same as Example 1, consisting of belowThe component of mass percentage: 15% isoprene, 15% dipropylene glycol, 0.072% pectin, 0.12% gellan gum,0.09% calcium chloride, 0.1% pungent glycol, 0.5% Sensiva SC50,0.2% poloxamer, 3.5% acetic acid are differentButyric acid sucrose ester, 1% phenyl trimethicone, 1% ring five dimethyl silicone polymer, 1% five phenyl of trimethylTrisiloxanes, 0.5% macadimia nut oil, 0.5% white pond flower seed oil, 1.5% olive oil, 0.1% tocopherol acetate,0.3% German chamomile essential oil and water surplus.
Comparative example 9
As a kind of embodiment of the invention, the makeup remover is in addition to without pectin, remaining is at being grouped as and preparation methodIt is same as Example 3.
Comparative example 10
As a kind of embodiment of the invention, the makeup remover is in addition to without gellan gum, remaining is at being grouped as and preparation sideMethod is same as Example 6.
Comparative example 11
As a kind of embodiment of the invention, it is 0.04% containing mass percentage that the makeup remover, which is removed, which is free of pectin,Outside xanthan gum, remaining is at being grouped as and preparation method is same as Example 5.
One, product stability can be evaluated
Stability test: to embodiment 1-6, the product of comparative example 1-11 is tested.1 Sucrose Acetate acid sucrose of embodimentEster and silicone oil, vegetable oil, hydro carbons are 4:3:2:1 in mass ratio, measure density 1.007.3 Sucrose acetoisobutyrate of comparative example withSilicone oil, vegetable oil, hydro carbons are 3:3:2:1 in mass ratio, measure density 0.9982.Comparative example 4 is formulated referring to embodiment 1, stillSucrose acetoisobutyrate is substituted for caprylic/capric/amber acid glycerol three ester, measuring comparative example grease density is 0.9999.Comparative example 5-8 is the comparative example for being embodiment 4, and comparative example 5 does not contain Sucrose acetoisobutyrate, density 0.9999；ComparisonExample 6 does not contain silicone oil, density 1.0027；Comparative example 7 does not contain vegetable oil, density 1.0094；Comparative example 8 does not contain hydro carbonsGrease, density 0.9996.It is resisted cold (- 15 DEG C) to each embodiment, comparative example, the stability of heat-resisting (45 DEG C) examinationIt tests, experimentation is as follows:
A) it resists cold and tests:
Instrument: refrigerator, accuracy of temperature control ± 1 DEG C
Operation sequence: adjusting refrigerator arrive (- 15 ± 1) DEG C in advance, real sample is placed in refrigerator, is taken out after 3 months, restoresIt is observed after to room temperature.
B) heat-resistant experiment
Instrument: constant incubator, accuracy of temperature control ± 1 DEG C
Operation sequence: constant incubator is adjusted arrive (45 ± 1) DEG C in advance, real sample is placed in incubator, is taken after 3 monthsOut, restore to room temperature to observe.
Test result such as table 1.It is found by trimestral test, embodiment 1-6 uniformly stablizes without significant change, oil dropletGround is suspended in system.Comparative example 1 because thickener ratio adjustment, comparative example 2 because technique change, all cause water phase outstandingFloating stability dies down, and shows as oil droplet floating.The change of 3 grease ratio of comparative example causes relative density to become smaller, and oil droplet floats.It is rightThe change of 4 grease of ratio selection causes oily mutually compatibility to be deteriorated, and separates between the grease of miscella phase, the big oil of density occursSink, the small oil of density floats, and it is poor to stablize sex expression.It can be obtained by comparative example 5-8, under certain density, Sucrose Acetate acidSucrose ester plays a decisive role to the suspension for maintaining oil droplet, shows that single gellan gum or pectin are not enough to provide by comparative example 9,10Compounding can be crosslinked the enough suspending powers of generation according to a certain percentage for suspending power steady in a long-term, only the two.By comparative example11 as it can be seen that pectin, which is replaced with xanthan gum also, can make outstanding pearl stability decline.
1 stability test result of table
Two, the makeup removing performance evaluation of product
It in daily nursing, needs that facial color make-up and the anti-sweat sunscreen product of waterproof unload washing, color make-up is many kinds of, packetInclude a plurality of types of products such as foundation cream, sweet powder, lipstick, eye shadow, kermes, mascara；Color make-up product component is extremely complex.Wherein,Vanishing cream, suncream majority are silicon oil packed water formulations, usually contain a large amount of silicone oil and organic silicon film forming agent, contain titanium white simultaneouslyThe inorganic particles such as powder, iron oxide, zinc oxide, and in order to achieve the effect that docile, most powders are carried out using organosiliconSurface treatment；Containing plant components such as beeswax, Brazil wax, candelila waxes in lipstick, also containing hydrocarbons such as dormant oil, paraffinMatter；Kermes, eye shadow, mascara contain the ingredients such as pigment, color ingot, silicone oil and film forming agent.Because non-sticky rim of a cup is red and mascara formulationThe ingredients such as pigment, silicone oil, film forming agent, mineral oil, vegetable wax are usually contained, it is relatively more representative, therefore the present invention choosesIt carries out makeup removing performance test.
Respectively using embodiment 1, embodiment 3, embodiment 4, the suspension oil droplet make up remover of comparative example 4-8 carry out makeup removing andThe conventional double-deck make up remover carries out mascara and the red makeup removing effect test of non-sticky rim of a cup: taking that the not viscous rim of a cup of equivalent is red, mascaraIt is uniformly applied at arm, respectively takes 0.5g makeup removing water droplet will makeup removing after the cotton that on makeup removing cotton, will remove ornaments and formal dress applies 1min after adornment is dryCotton is wiped 3 times with same dynamics, observes makeup removing effect.Test result (A typical bilayer make up remover picture 1-4；B comparative example 4；CEmbodiment 3；D embodiment 1；1. comparative example 5；2. comparative example 6；3. comparative example 7；4. comparative example 8；5. embodiment 4).
By Fig. 1, Fig. 2 as it can be seen that embodiment makeup removing effect is preferable, the wherein highest embodiment of Sucrose acetoisobutyrate content1 makeup removing effect is best；Sucrose acetoisobutyrate equivalent is replaced with other esters by comparative example 4, and makeup removing ability is declined；CityIt sells the double-deck make up remover and there is the problems such as taking inconvenience, uneven, and makeup removing effect is most weak.
According to the similar principle that mixes, it just can be carried out and dissolve each other between the similar component of polarity, therefore can not only be unloaded by vegetable oilIt, only also can not the more kermes of removal toner content, eye shadow class by mineral oil except the color make-up or sun-proof class product of siliceous Chuck SteakProduct；Therefore the makeup removing effect for the makeup remover for lacking amount of grease in Fig. 3, Fig. 4 is remarkably decreased, only when grease is that acetic acid is differentThe makeup removing effect of the combination of butyric acid sucrose ester and silicone oil, vegetable oil, squalene extracting, makeup remover is most excellent.
The present invention dispersibility splendid to pigment, toner using Sucrose acetoisobutyrate, by itself and silicone oil, plantOil, squalene extracting be combined, thus the makeup removal products being prepared have it is easy to use, take uniformly, and can simultaneously removalVarious types of color make-ups, sunscreen product.
Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than protects to the present inventionThe limitation of range is protected, although the invention is described in detail with reference to the preferred embodiments, those skilled in the art shouldUnderstand, it can be with modification or equivalent replacement of the technical solution of the present invention are made, without departing from the essence of technical solution of the present inventionAnd range.