Heat pump supercritical air energy storage systemTechnical Field
The invention belongs to the technical field of energy storage, relates to an air energy storage system, and particularly relates to an energy storage system based on heat pump circulation and supercritical air energy storage and generating electric energy by using the stored energy.
Background
In recent years, renewable energy sources are gradually becoming an important source of newly-increased electric power, and the power grid structure and the operation mode are changed significantly. With the increasing popularity of renewable energy sources (such as wind energy, solar energy, etc.), and the urgent demands of grid peaking, improving the reliability of the grid, and improving the quality of electrical energy, the importance of electrical energy storage systems is becoming increasingly prominent. The energy storage is an important component part and a key supporting technology of a smart power grid, a renewable energy high-occupancy energy system and an intelligent energy (hereinafter referred to as energy Internet) of the Internet+. The energy storage can provide various services such as peak shaving, frequency modulation, standby, black start, demand response support and the like for power grid operation, and is an important means for improving the flexibility, economy and safety of a traditional power system; the energy storage can obviously improve the level of the renewable energy sources such as wind, light and the like, supports distributed electric power and a microgrid, and is a key technology for pushing the main body energy source to replace from fossil energy sources to renewable energy sources; the energy storage can promote the open sharing and flexible transaction of energy production and consumption and realize multi-energy coordination, and is a core foundation for constructing the energy Internet, promoting the reform of an electric power system and promoting the development of new energy states.
Currently, the existing electric energy storage technology comprises pumping energy storage, compressed air energy storage, storage battery energy storage, superconducting magnetic energy, flywheel energy storage, super capacitor and the like. The energy storage in China presents a good situation of multiple development: the development of pumped storage is rapid; compressed air energy storage, flywheel energy storage, superconducting energy storage, super-capacitor, lead storage battery, lithium ion battery, sodium-sulfur battery, flow battery and other energy storage technologies are developed and applied rapidly; the heat storage, cold storage and hydrogen storage technologies have also been developed to some extent. The physical method energy storage represented by pumping energy storage, heat storage energy storage and compressed air energy storage is low in cost and large in energy storage capacity, is suitable for large-scale commercial application, and accounts for about 99.5% of the total energy storage in the world.
When the electric power system is in valley load, the water pump is driven by the motor to pump water in low reservoir to high reservoir through pipeline to consume a part of electric energy. When the peak load is on, the water in the high reservoir reversely runs the water pump and the motor through the pipeline to become the water turbine and the generator to generate electric energy for the user, so that the peak load reduction and valley filling functions are realized. The energy storage system of the water pumping power station has the advantages of mature and reliable technology, high efficiency (about 70%), large energy storage capacity and the like, and is widely used at present. However, the energy storage system of the water pumping power station needs special geographical conditions to build two reservoirs and dams, the construction period is long (generally about 7-15 years), and the initial investment is huge. More troublesome is that building large reservoirs can flood vegetation and even cities in large areas, ecological and immigration problems are caused, and therefore building water pumping power station energy storage systems is more and more limited.
In the traditional compressed air energy storage system, air is compressed and stored in an air storage chamber in the low electricity consumption valley, so that electric energy is converted into internal energy of the air to be stored; in the peak of electricity consumption, high-pressure air is released from the air storage chamber, enters the combustion chamber of the gas turbine to be combusted together with fuel, and then drives the turbine to generate electricity. The compressed air energy storage system has the advantages of large energy storage capacity, long energy storage period, high efficiency (50% -70%), relatively small unit investment and the like. However, the compressed air energy storage technology has low energy storage density, and has a difficulty in requiring a suitable place where compressed air can be stored, such as a sealed cave or abandoned mine, etc. Moreover, the compressed air energy storage system still relies on burning fossil fuel to provide a heat source, on one hand, the threat of gradual exhaustion and price rising of the fossil fuel is faced, and on the other hand, pollutants such as nitrides, sulfides, carbon dioxide and the like are still generated by burning the compressed air energy storage system, so that the compressed air energy storage system does not meet the requirements of green (zero emission) and renewable energy development.
In order to solve the main problems faced by the traditional compressed air energy storage system, in recent years, domestic and foreign scholars respectively develop researches on an advanced heat insulation compressed air energy storage system (AACAES), a ground compressed air energy storage system (SVCAES), a backheating compressed air energy storage system (AACAES) and an air steam combined cycle compressed air energy storage system (CASH) and the like, so that the compressed air energy storage system can basically avoid burning fossil fuel, but the energy density of the compressed air energy storage system is still low, and a large-sized air storage chamber is needed.
In recent years, liquid air energy storage systems and the like have been developed by students at home and abroad, and the energy storage density is higher due to the adoption of normal-pressure liquid air storage. However, the liquid air energy storage system has the problems of low system circulation efficiency, poor flexibility and the like.
Disclosure of Invention
Aiming at the defects and shortcomings in the existing air energy storage technology, the invention aims to provide a heat pump supercritical air energy storage system which has the characteristic of large energy storage density compared with the existing compressed air energy storage system and the like, has the characteristics of high energy storage efficiency and strong flexibility compared with the liquid air energy storage system, and can be suitable for being matched with various power stations.
In order to achieve the above purpose, the technical solution of the present invention is:
The heat pump supercritical air energy storage system comprises an air compressor unit, a heat storage heat exchanger, a cold storage heat exchanger, a liquid air storage tank, an air expansion unit, a heat pump circulating compressor unit, a heat pump circulating expansion unit and a low-temperature pump, and is characterized in that,
An air outlet of the heat pump cycle compressor unit is communicated with an air inlet of the heat pump cycle expansion unit through the heat storage heat exchanger, an air outlet of the heat pump cycle expansion unit is communicated with the air inlet of the heat pump cycle compressor unit through the cold storage heat exchanger, and a closed heat pump refrigerating and heating loop is formed among the heat pump cycle compressor unit, the heat storage heat exchanger, the heat pump cycle expansion unit and the cold storage heat exchanger through pipelines;
The air inlet of the air compressor unit is communicated with the atmosphere, the air outlet is sequentially communicated with the liquid air inlet at the top of the liquid air storage tank through the heat storage heat exchanger and the cold storage heat exchanger, an expansion valve is arranged on a pipeline communicated with the liquid air inlet at the top of the liquid air storage tank, a non-condensable gas exhaust port at the top of the liquid air storage tank is communicated with an exhaust pipeline through the cold storage heat exchanger, the exhaust pipeline is communicated with the atmosphere, and an energy storage air loop is formed among the air compressor unit, the heat storage heat exchanger, the cold storage heat exchanger and the liquid air storage tank through pipelines;
The liquid air outlet at the bottom of the liquid air storage tank is communicated with the air inlet of the air expansion unit through the low-temperature pump, the cold storage heat exchanger and the heat storage heat exchanger, the air outlet of the air expansion unit is communicated with the atmosphere, a control valve is arranged on a pipeline communicated with the inlet of the low-temperature pump, and an energy release and acting loop is formed among the liquid air storage tank, the low-temperature pump, the cold storage heat exchanger, the heat storage heat exchanger and the air expansion unit through pipelines.
The working process of the heat pump supercritical air energy storage system provided by the invention is as follows:
When the energy is stored, the control valve is closed, the power source drives the heat pump cycle compressor unit, the heat pump cycle gas working medium at normal temperature and low pressure is compressed to a high-temperature and high-pressure state, and then the temperature of the heat storage heat exchanger is reduced to normal temperature, and the heat storage heat exchanger stores high-temperature heat energy; the normal-temperature high-pressure heat pump cycle gas working medium is further converted into a low-temperature low-pressure state through the heat pump cycle expansion unit; the temperature of the low-temperature low-pressure heat pump circulating gas working medium is increased to normal temperature after passing through the cold accumulation heat exchanger, and meanwhile, low-temperature cold energy is transmitted to compressed air in an energy storage air loop; the normal-temperature low-pressure heat pump cycle gas working medium reenters the air inlet of the heat pump cycle compressor unit to participate in heat pump cycle;
When energy is stored, the power source drives the air compressor unit to compress air into high-pressure air; the temperature of the high-pressure air is reduced after passing through the heat storage heat exchanger, the high-pressure air further passes through the heat storage heat exchanger and then reaches a high-pressure low-temperature state, then the pressure is further reduced by the expansion valve to obtain high-pressure low-temperature liquid air and low-temperature non-condensable gas, and the liquid air and the low-temperature non-condensable gas are stored by the liquid air storage tank;
when energy is released, the control valve is opened, the pressure of the liquid air in the liquid air storage tank is raised to a low-temperature high-pressure state after passing through the low-temperature pump, then the liquid air flows through the cold storage heat exchanger, the low-temperature cold energy is recovered, the liquid air further flows through the heat storage heat exchanger to absorb heat energy, the heat energy is transferred to medium-temperature high-pressure air, and the medium-temperature high-pressure air is injected into the air expansion unit to expand and do work.
Preferably, the heat pump cycle gas working medium is one or a mixture of more of monoatomic molecular gas, diatomic molecular gas or polyatomic molecular gas.
The heat pump cycle gas working medium of the monoatomic molecular gas is one or two of helium and argon.
Preferably, the power source of the heat pump cycle compressor unit is a driving motor or a wind turbine; when the power source is a driving motor, one or more of electricity in low valley, nuclear power, wind power, solar power generation, water power or tidal power generation of the conventional power station are used as power sources.
Preferably, the air compression and cooling process also comprises air purification and purification to remove solid matters and impurity gases in the air; the air purification and purification device is integrated in the air compressor unit and the heat storage heat exchanger.
Preferably, the air compressor unit has a total pressure ratio between 36 and 340; when the compressor is a plurality of compressors, the compressors are in a coaxial serial connection mode or a split-shaft parallel connection mode; in the parallel form, each split shaft is in dynamic connection with the main drive shaft.
Preferably, the total expansion ratio of the air expansion unit is 38-340, and the exhaust of the final-stage expander is close to normal pressure; when the expansion machines are in a coaxial serial connection mode or a split-shaft parallel connection mode; in the parallel connection mode, each split shaft is in dynamic connection with the main driving shaft; the inlet air of each stage of expansion machine is heated by a heat storage heat exchanger.
Preferably, the heat pump cycle compressor unit has a total pressure ratio of between 5 and 40; when the compressor is a plurality of compressors, the compressors are in a coaxial serial connection mode or a split-shaft parallel connection mode; in the parallel form, each split shaft is in dynamic connection with the main drive shaft.
Preferably, the heat pump cycle expansion unit has a total expansion ratio of between 5 and 40; when the expansion machines are in a coaxial serial connection mode or a split-shaft parallel connection mode; in the parallel form, each split shaft is in dynamic connection with the main drive shaft.
Preferably, the air compressor unit is of the piston type, axial flow type, centrifugal type, screw type or hybrid type.
Preferably, the air expansion unit is piston type, axial flow type, centripetal type, screw type or mixed type.
Preferably, the heat pump cycle compressor unit is piston, axial flow, centrifugal, screw or hybrid.
Preferably, the heat pump cycle expansion unit is a piston type, an axial flow type, a centripetal type, a screw type or a hybrid type.
Preferably, the compressors and the expanders are respectively distributed on one driving shaft or a plurality of driving shafts.
Preferably, the heat pump cycle compressor unit and the heat pump cycle expansion unit are distributed on one driving shaft or a plurality of driving shafts connected through a gearbox.
Preferably, the heat storage type of the heat storage heat exchanger is one or more of sensible heat, latent heat or chemical reaction heat, and the heat exchange type of the heat storage heat exchanger is that high-pressure air directly contacts the heat storage material or exchanges heat with the heat storage material through a heat exchange surface; the heat accumulating medium is water, paraffin, biomass oil, inorganic crystalline hydrated salt, molten salt, metal and its alloy, organic acid, stone, rock or concrete and is stored inside heat insulating container.
Preferably, the cold accumulation form of the cold accumulation heat exchanger is one or a combination of sensible heat cold accumulation and solid-liquid phase change cold accumulation; the heat exchange mode is that the high-pressure liquid air is in direct contact heat exchange or indirect contact heat exchange with a cold accumulation medium in the cold accumulator; the sensible heat cold storage medium is one or more of sealing ice hockey, sha Danzi, concrete, aluminum tape reel or other metal substances; the solid-liquid phase change cold accumulation medium is one or more of ammonia and aqueous solution thereof, salt aqueous solution, alkanes, alkenes and their compounds, alcohols and aqueous solution thereof, and the cold accumulation medium is stored in an adiabatic container.
Preferably, the heat storage heat exchanger further comprises a heat exchanger for exchanging heat between the heat pump circulating gas and the compressed air, and the heat exchanger is in the form of one or more of a tube type, a tube fin type, a plate fin type or a plate type.
Preferably, the cold-storage heat exchanger further comprises a heat exchanger for exchanging heat between the heat pump circulating gas and the compressed air, and the heat exchanger is in the form of one or more of a tube type, a tube fin type, a plate fin type or a plate type.
Preferably, the heat pump supercritical air energy storage system further comprises a low-temperature heat exchanger for exchanging heat between the heat pump circulating gas loop and the compressed air heat exchange loop, wherein the heat exchanger is in the form of one or more of a tube type, a tube fin type, a plate fin type or a plate type.
Preferably, the low-temperature heat exchanger is mainly used for heat exchange between the energy storage air loop and the heat pump refrigerating and heating loop, an air outlet of the heat pump circulating expansion unit is sequentially communicated with an air inlet of the heat pump circulating compressor unit after passing through a cold side of the low-temperature heat exchanger and a cold storage heat exchanger, and an air outlet of the air compressor unit is sequentially communicated with a liquid air inlet at the top of the liquid air storage tank after passing through a hot side of the heat storage heat exchanger, the cold storage heat exchanger and the low-temperature heat exchanger.
Preferably, the air compressor unit and the air expansion unit are in the form of multistage series connection, and heat storage and heat release are carried out between stages through the heat storage heat exchanger.
Compared with the prior art, the heat pump supercritical air energy storage system has the remarkable technical advantages that: the air is compressed to a high-pressure state by using low-valley (low-price) electricity of a power station, the high-pressure air is cooled to a low-temperature state by using the stored cold energy and low-temperature cold energy obtained by heat pump circulation (heat energy obtained by heat pump circulation is stored at the same time), and the liquid air is obtained after depressurization; at the peak of electricity consumption, the high-pressure liquid air enters the cold accumulator after being pressurized by the low-temperature pump, absorbs heat to a normal-temperature high-pressure state, stores cold energy at the same time, further absorbs stored heat energy (including air compression heat and heat pump circulation heating), and then drives the generator to generate electricity through the expander. The heat pump supercritical air energy storage system has the advantages of high energy density, high efficiency, strong flexibility, suitability for power grid peak shaving and various renewable energy power stations, no generation of greenhouse gases and the like.
Drawings
FIG. 1 is a schematic diagram of a heat pump supercritical air energy storage system according to embodiment 1 of the present invention;
FIG. 2 is a schematic diagram of a heat pump supercritical air energy storage system according to embodiment 2 of the present invention;
FIG. 3 is a schematic diagram of a heat pump supercritical air energy storage system according to embodiment 3 of the present invention;
FIG. 4 is a schematic diagram of a heat pump supercritical air energy storage system according to embodiment 4 of the present invention;
Wherein,
The air compressor unit 1, the heat storage heat exchanger 2, the cold storage heat exchanger 3, the liquid air storage tank 4, the air expansion unit 5, the heat pump cycle compressor unit 6, the heat pump cycle expansion unit 7, the heat pump driving motor 8, the driving motor 9, the generator 10, the expansion valve 13, the control valve 17, the cryopump 19, the pipelines 11, 12, 14, 15, 16, 18, 20, 21, 22, 23, 24, 25, the atmosphere a and the cryogenic heat exchanger 30.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention will be further described in detail below by referring to the accompanying drawings and examples. It should be noted that the implementation manner not shown or described in the drawings is a manner known to those of ordinary skill in the art.
Example 1
As shown in fig. 1, an embodiment 1 of the heat pump supercritical air energy storage system of the present invention is shown. The heat pump supercritical air energy storage system comprises an air compressor unit 1, a heat storage heat exchanger 2, a cold storage heat exchanger 3, a liquid air storage tank 4, an air expansion unit 5, a heat pump circulating compressor unit 6, a heat pump circulating expansion unit 7 and a cryopump 19.
The air outlet of the heat pump cycle compressor unit 6 is communicated with the air inlet of the heat pump cycle expansion unit 7 through the heat storage heat exchanger 2, the air outlet of the heat pump cycle expansion unit 7 is communicated with the air inlet of the heat pump cycle compressor unit 6 through the cold storage heat exchanger 3, and a closed heat pump refrigerating and heating loop is formed among the heat pump cycle compressor unit 6, the heat storage heat exchanger 2, the heat pump cycle expansion unit 7 and the cold storage heat exchanger 3 through pipelines 22-25.
The air inlet A of the air compressor unit 1 is communicated with the atmosphere, the air outlet is communicated with a liquid air inlet at the top of the liquid air storage tank 4 through pipelines 11, 12 and 14 in sequence through the heat storage heat exchanger 2 and the cold storage heat exchanger 3, an expansion valve 13 is arranged on the pipeline 14 communicated with the liquid air inlet at the top of the liquid air storage tank 4, a non-condensable gas exhaust port at the top of the liquid air storage tank 4 is communicated with an exhaust pipeline 16 through a pipeline 15 through the cold storage heat exchanger 3, the exhaust pipeline 16 is communicated with the atmosphere, and an energy storage air loop is formed among the air compressor unit 1, the heat storage heat exchanger 2, the cold storage heat exchanger 3 and the liquid air storage tank 4 through pipelines.
The liquid air outlet at the bottom of the liquid air storage tank 4 is communicated with the air inlet of the air expansion unit 5 through pipelines 18 and 20-22 by a low-temperature pump 19, a cold accumulation heat exchanger 3 and a heat accumulation heat exchanger 2, the air outlet of the air expansion unit 5 is communicated with the atmosphere, a control valve 17 is arranged on the pipeline communicated with the inlet of the low-temperature pump 19, and an energy release and power generation loop is formed among the liquid air storage tank 4, the low-temperature pump 19, the cold accumulation heat exchanger 3, the heat accumulation heat exchanger 2 and the air expansion unit 5 through pipelines.
Further, the heat pump cycle compressor unit 6 and the heat pump cycle expansion unit 7 are coaxially arranged, and a common transmission shaft of the heat pump cycle compressor unit 6 and the heat pump cycle expansion unit 7 is fixedly connected with a heat pump driving motor 8.
Further, the input shaft of the air compressor unit 1 is fixedly connected with a driving motor 9, and the output shaft of the air expansion unit 5 is fixedly connected with a generator 10.
The working process of the heat pump supercritical air energy storage system provided by the invention is as follows:
When energy is stored, the heat pump driving motor 8 is utilized to drive the heat pump cycle compressor unit 6, and a certain amount of normal-temperature low-pressure heat pump cycle gas working medium is compressed to a high-temperature high-pressure state; the temperature of the gas entering the heat storage heat exchanger 2 through the pipeline 22 is reduced to the normal temperature, and meanwhile, the high-temperature heat energy is stored in the heat storage heat exchanger 2 and is changed into a normal temperature high-pressure heat pump cycle gas working medium; the normal-temperature high-pressure heat pump cycle gas working medium further enters the heat pump cycle expansion unit 7 through a pipeline 23 to be converted into a low-temperature low-pressure heat pump cycle gas working medium, and expansion work is generated to supplement the power consumption of the heat pump cycle compressor unit 6; the low-temperature low-pressure heat pump circulating gas working medium further enters the cold accumulation heat exchanger 3 through a pipeline 24, the temperature is raised to normal temperature, and meanwhile, the low-temperature cold energy is transferred to main path compressed air; the normal-temperature low-pressure heat pump cycle gas working medium is re-introduced into the air inlet of the heat pump cycle compressor unit 6 through the pipeline 25 to participate in heat pump cycle;
During energy storage, the low-valley (low-price) electric drive motor 9 drives the air compressor unit 1, air A enters the air compressor unit 1 to be compressed to a normal temperature and high pressure state, outlet air of the air compressor unit 1 enters the heat storage heat exchanger 2 through a pipeline 11, outlet air of the heat storage heat exchanger 2 falls to the normal temperature to enter the cold storage heat exchanger 3 through a pipeline 12, and the air is cooled to be close to or below a liquefaction temperature by a cold storage medium. The low-temperature high-pressure air discharged from the cold accumulation heat exchanger 3 is subjected to pressure reduction through an expansion valve 13 on a pipeline 14 to obtain liquid air and low-temperature non-condensable gas, and the liquid air and the low-temperature non-condensable gas are stored in a liquid air storage tank 4. The low-temperature non-condensable gas in the liquid air storage tank 4 enters the cold-storage heat exchanger 3 through a top pipeline 15, and residual cold energy is absorbed by the cold-storage heat exchanger 3 and then discharged into the atmosphere through a pipeline 16.
When releasing energy, the control valve 17 is opened, the liquid air in the liquid air storage tank 4 enters the low-temperature pump 19 through the pipeline 18, after the liquid air is pressurized to a certain pressure, the liquid air is conveyed to the cold-storage heat exchanger 3 through the pipeline 20 to exchange heat with a cold-storage medium and gasify, meanwhile, cold energy is recovered, high-pressure air which is discharged out of the cold-storage heat exchanger 3 enters the heat-storage heat exchanger 2 through the pipeline 21 to further heat, and the high-pressure air after the temperature rise is injected into the air expansion unit 5 through the pipeline 22 to expand and do work to drive the generator 10 to generate electricity.
During energy storage, the heat pump driving motor 8 drives the heat pump refrigerating and heating loop formed by the heat pump cycle compressor unit 6, the heat storage heat exchanger 2, the heat pump cycle expansion unit 7 and the cold storage heat exchanger 3 to work. The air compressor unit 1 works, the air expansion unit 5 is closed, the valve 13 is opened, the control valve 17 is closed, the heat storage heat exchanger 2 stores heat, the cold storage heat exchanger 3 releases cold energy, and the high-pressure air is cooled to be in a low-temperature liquid state. When the energy is released, the air compressor unit 1 is closed, the valve 13 is closed, and the control valve 17 is opened. The air expansion unit 5 works, the cold accumulation heat exchanger 3 recovers and stores cold energy, and meanwhile, the high-pressure liquid air is heated, so that heat energy is released, and the temperature of the high-pressure air is further improved.
Example 2
Fig. 2 is an embodiment 2 of a heat pump supercritical air energy storage system of the present invention, and the main structure of the heat pump supercritical air energy storage system is the same as that of embodiment 1, except that a low-temperature heat exchanger 30 is added to the heat pump refrigerating and heating loop and the energy storage air loop, the low-temperature heat exchanger 30 is mainly used for heat exchange between the energy storage air loop and the heat pump refrigerating and heating loop, the air outlet of the heat pump circulating expansion unit 7 is sequentially communicated with the air inlet of the heat pump circulating compressor unit 6 after passing through the cold side of the low-temperature heat exchanger 30 and the cold storage heat exchanger 3, and the air outlet of the air compressor unit 1 is sequentially communicated with the liquid air inlet at the top of the liquid air storage tank 4 after passing through the heat storage heat exchanger 2, the cold storage heat exchanger 3 and the hot side of the low-temperature heat exchanger 30.
During energy storage, the low-temperature cold energy generated by the heat pump refrigerating and heating loop is firstly exchanged to the low-temperature compressed air in the energy storage air loop through the low-temperature heat exchanger 30, and then the residual cold energy is released through the cold storage heat exchanger 3.
Example 3
Fig. 3 is an embodiment 3 of a heat pump supercritical air energy storage system according to the present invention, and the main structure of the heat pump supercritical air energy storage system is the same as that of embodiment 1, and the air compressor unit 1 and the air expansion unit 5 are both in a multi-stage series connection, and the heat storage and the heat release are performed between stages through the heat storage heat exchanger 3.
Example 4
Fig. 4 is an embodiment 4 of a heat pump supercritical air energy storage system according to the present invention, and the main structure thereof combines the structural features of embodiments 2 and 3, and the compressed air compressor unit 1 and the compressed air expansion unit 5 are both in a multi-stage series connection, and the heat storage and the heat release are performed by the heat storage heat exchanger 3 between stages. And a low-temperature heat exchanger 30 is added on the heat pump refrigerating and heating loop and the energy storage air loop, and the low-temperature heat exchanger 30 is mainly used for heat exchange between the energy storage air loop and the heat pump refrigerating and heating loop.
In addition, the specific embodiments described in the present specification may differ in terms of parts, shapes of components, names, and the like. All equivalent or simple changes of the structure, characteristics and principle according to the inventive concept are included in the protection scope of the present invention. Those skilled in the art may make various modifications or additions to the described embodiments or substitutions in a similar manner without departing from the scope of the invention as defined in the accompanying claims.