Background technology
Dendrobium candidum is orchid family Dendrobium herbaceos perennial, is a kind of Chinese medicine plant being distributed in karst area,It gains the name because iron green is presented for epidermis, and rare for China's emphasis second class protection relates to danger plant.Dendrobium Sw is China's weightThe traditional Chinese medicine wanted, confirms according to pharmacology test, and dendrobium candidum is long-standing as the Chinese medicine being of illnesses and fitness.
Dendrobium candidum is rich in polysaccharide, dendrobine, free amino acid, vitamin (vitamin A, vitamin C, vitamin E), leafGreen element and various enzymes, not only can also stop blooding by oral absorption, dendrobium candidum, promote wound healing, can be used to repair outsideMultiple damaged skin.And facial mask is a kind of skin care item that are most common, being most just carrying, can apply or spread on the skin table of human body faceFace is temporarily isolating extraneous air and pollution, improves skin temperature, expands the pore of skin, promote the secretion of sweat gland with it is newly oldMetabolism, through attachment a period of time so that the nutrient being rich in facial mask is slowly absorbed by skin, then take off from, clean or retain,It plays and is conducive to product and accumulation that skin excludes epidermal cell metabolism to face skin colonization or cleaning actionOil substances make the cuticula of skin fill moisture, and then it is flexible to become soft and bright for skin.As it can be seen that dendrobium candidum faceThe great Research Prospects of film.
Active ingredient in the method extraction dendrobium candidum that generally use decocts at present, traditional decoction extracting method can be ledThe destruction of the active ingredients such as polysaccharide, vitamin, amino acid, organized enzyme in dendrobium candidum is caused, polysaccharide, dimension life in products obtained therefromElement, chlorophyll, free amino acid equal size are relatively low, greatly reduce the utilization rate of dendrobium candidum.
The Chinese patent of Publication No. CN104107151A discloses a kind of dendrobium candidum clay mask, it is characterised in that：It shouldDendrobium candidum clay mask includes the water that parts by weight are 38~43 parts；The dendrobium candidum ultrafine powder that parts by weight are 4~6 parts, shouldContain polysaccharide, chlorophyll, vitamin and protein in dendrobium candidum ultrafine powder；The glycerine that parts by weight are 6~9 parts；Parts by weightThe kaolin that number is 4~6 parts；The cetearyl glucoside that parts by weight are 1~2 part；The spermaceti that parts by weight are 3~5 partsStearyl alcohol；The dormant oil that parts by weight are 3~5 parts；Parts by weight are 2~4 parts of octanoic acid and the mixture of Triglyceride DDD, are somebody's turn to doThe weight ratio of octanoic acid and Triglyceride DDD is 1:2；Parts by weight be 2~4 parts polyglycerolmethacrylate, propylene glycol andThe weight ratio of Gantrez AN-119, the polyglycerolmethacrylate, propylene glycol and Gantrez AN-119 is 3:2:1；Parts by weightThe dimethyl silicone polymer that number is 2~4 parts；The mixture for the cetanol and ceteth -20 that parts by weight are 2~4 parts, shouldThe weight ratio of cetanol and ceteth -20 is 1:1；The Butyrospermum parkii that parts by weight are 4~6 parts；Parts by weight are 3~5The PEG-75 stearates of part, the mixture of ceteth -20 and stereth -20, PEG-75 stearates, the spermacetiThe weight ratio of alcohol polyethers -20 and stereth -20 is 1:1:2；The aloe barbadensis Miller leaf extract that parts by weight are 4~6 parts；The xanthans that parts by weight are 0.2~0.4 part；The dipotassium glycyrrhizinate that parts by weight are 0.4~0.6 part；Parts by weight be 0.3~0.5 part of allantoin；The CI77492 that parts by weight are 0.3~0.5 part；The CI77499 that parts by weight are 0.1~0.3 part；WeightMeasure the methyl hydroxybenzoate that number is 0.1~0.2 part；The Nipasol that parts by weight are 0.05~0.1 part；Parts by weight be 0.2~0.4 part of iodopropynyl butyl carbamate and the mixture of dimethyloldimethylhydantoin, the iodo propinylThe weight ratio of butyl carbamate and dimethyloldimethylhydantoin is 3:2.
The Chinese patent of Publication No. CN105596258A discloses a kind of dendrobium candidum jelly film surface film, by following qualityThe raw material of part is made：30~50 parts of macromolecule glue, 10~15 parts of water, 30~40 parts of moisturizer, dendrobium candidum extractant 50~60Part, 5~10 parts of bletilla striata extract, 2~5 parts of PORIA ALBA extract, 1~3 part of shrubby sophora extract, 4~8 parts of aloe extract, sea10~15 parts of algae extract, 5~8 parts of forsythia suspense extraction.Wherein, macromolecule glue is polyvinylpyridine, and moisturizer is collagen eggIn vain, matter acid, hyaluronic acid, glycerine, polyethylene glycol, hexylene glycol, polypropylene glycol, amino acid.
The Chinese patent of Publication No. CN105616286A discloses a kind of fresh juice facial mask formula of nearly dendrobium officinale,The weight of each raw material is as follows：Nearly 15~25 parts of wild fresh dendrobium candidum, 35~40 parts of water, 4~8 parts of 1,3-PD,4~8 parts of glycerine, 4~7 parts of trehalose, 4~7 parts of diglycerol, 3~6 parts of sorb (sugar) alcohol, 3~5 parts of rhamnose, 1,2- hexylene glycol3~5 parts, 2~4 parts of Sodium Hyaluronate, 2~4 parts of urea capsule, 2~3 parts of malt widow glucoside, 2~3 parts of xanthans, ethoxy2~3 parts of cellulose, 1~3 part of anhydro xylitol, 1~3 part of hydrogenated starch hydrolysate, 1~2 part of tamarind seed polysaccharide, butanediol 1~2 parts, 1~2 part of xylitol, 1~2 part of Tremella fructification extract, 0.5~0.8 part of EDETATE SODIUM, PPG-26- butylol polyethers-260.5~0.7 parts, PEG-400.5~0.7 part, 0.3~0.6 part of rilanit special, 0.3~0.5 part of glucose, caprylic/capric0.3~0.4 part of triglycerides, 0.3~0.4 part of ginseng root extract hydrogenate soft phosphatidase 0 .2~0.4 part, cholesterine 0.2~0.4Part, 0.1~0.2 part of parahydroxyacet-ophenone, 0.05~0.2 part of essence.
The Chinese patent of Publication No. CN105748303A discloses a kind of dendrobium candidum small-molecular peptides facial mask, including facial maskCloth and Essence, which is characterized in that the Essence by following mass fraction at being grouped as：Water 84.05, carbomer 0.1,Glycerine 6.0, dendrobium candidum small-molecular peptides 1, polyethylene glycol -321.0, xanthan gum 0.03, EDTA-2Na0.02, glycine betaine 1.0,1,3- butanediols 4.0, beta glucan 1.0, Chondrus crispus 1.0, triethanolamine 0.1, Cremophor RH40 0.3, essence0.1, iodopropynyl butyl carbamate 0.18 and dimethyloldimethylhydantoin 0.12.Located in advance using normal temperature high voltageDendrobium candidum is managed, high degree of dispersion dendrobium candidum pretreatment fluid is obtained；Iron sheet is obtained with compound enzymatic treatment dendrobium candidum pretreatment fluidStem of noble dendrobium small-molecular peptides enzymolysis liquid；The dendrobium candidum small-molecular peptides lysate of acquisition is purified, dendrobium candidum small molecule is obtainedPeptide.
The Chinese patent of Publication No. CN106038396A discloses a kind of dendrobium candidum facial mask preparation method, including followingStep：By dipropylene glycol, glycerine, double-PEG-15 methyl ether dimethicones, honey, Cremophor RH40 and thirdGlycol, collagen are mixed and heated to 85 DEG C, maintain 30min sterilizings, obtain to obtain oil phase；By methacrylaldehyde/acrylic copolymer, hydroxylEthyl cellulose, allantoin are added to the water, and are heated with stirring to 90~100 DEG C, maintain 30min sterilizings, are cooled to 85 DEG C, obtainWater phase；Oil phase is added to stirring and emulsifying in water phase and obtains base-material；When dropping to 40~45 DEG C at a temperature of base-material, by filtered ironPhthalein urea is added in base-material in skin stem of noble dendrobium extract liquor, iodopropynyl butyl carbamate and dihydroxymethyl dimethyl second, is continuedStirring and emulsifying 20min, then emulsifying 5min is carried out with homogenizer, Rosa Damascana is added, stirs evenly, stands cooling 12~24Hour at cream, stops stirring, and cooling obtains dendrobium candidum facial mask.
The Chinese patent of Publication No. CN106176340A discloses a kind of facemask powder prepared by dendrobium candidum slag, and step is such asUnder：(1) by raw material proportioning will be put into after the drying of dendrobium candidum slag, Radix Salviae Miltiorrhizae and pseudo-ginseng air-stream type ultrafine pulverizer be crushed to 600~800 mesh, obtain mixed powder；(2) mixed powder of the ultra-fine bamboo charcoal powder of charge ratio, honey powder, talcum powder and step (1) is put into blenderStirring is uniformly mixed for 10~20 minutes, obtains facemask powder；(3) facemask powder of step (2) is sieved with 100 mesh sieve；(4) by step (3) mistakeThe facemask powder of sieve is put into microwave disinfection equipment, and control temperature is sterilized 3~5 minutes at 70~85 DEG C；(5) by step (4) sterilizationFacemask powder is quantitatively attached in aluminium foil bag, obtains facemask powder, air drying storage.
The Chinese patent of Publication No. CN106377476A discloses a kind of dendrobium candidum Biofibre facial mask and making sideMethod, including each component that parts by weight are following：50-60 parts of water, acrylic acid (ester) class/isodecyl vinyl acetate cross-linked polymer 0.1-1Part, 1-1.5 parts of xanthans, 5-10 parts of glycerine, 8-12 parts of propylene glycol, 0.05-0.15 parts of Sodium Hyaluronate, hydrolysis Scleroglucan0.1-0.5 parts, 1.5-2.0 parts of panthenol, 1-10 parts of glycine betaine, 1,2- 0.5-1 parts of hexylene glycol, 0.5-1 parts of parahydroxyacet-ophenone, essence0.1-0.5 parts of propylhomoserin, composition A：0.5-1.5 parts, composition B：0.1-0.5 parts, Bacillus acidi lactici/bear's weed tunning carriesTake 0.5-1.5 parts of object, 1-10 parts of ethoxy urea, 0.1-1 parts of PEG/PPG-14/7 dimethyl ethers, 1-5 parts of carbohydrate isomer,1-10 parts of dendrobium candidum extract, 0.1-0.5 parts of component C, 0.05-0.15 parts of essence, Cremophor RH40 0.1-0.5Part, 0.1-0.2 parts of biological fiber membrane material.
The Chinese patent of Publication No. CN106389270A discloses a kind of anti-aging dendrobium candidum facial mask of whitening, featureIt is, raw material includes by weight：It is 10-30 parts of composite extract, 5-15 parts of grape seed ultramicro-farina, tea powder 3-5 parts ultra-fine, poly-30-45 parts of vinyl alcohol, 3-20 parts of chitosan, 0.5-3 parts of volcanic slurry, 2-8 parts of pearl powder, 1-5 parts of amber powder, illite powder 2-8 parts, 0.5-2 parts of vitamin, 0.5-2 parts of JINHUAKUIZI oil, 2-5 parts of flores aurantii essential oil, 2-5 parts of lemon, Geranium Essential 6-8Part, 3-5 parts of shea butter, 5-12 parts of sodium carboxymethylcellulose, 3-10 parts of propylene glycol, 2-8 parts of ethyl alcohol, methyl hydroxybenzoate 0.1-0.5 part, bis- 0.1-0.9 parts of galloyl maple sugar esters of 2,6-, 50-70 parts of water；Wherein, the composite extract is according to following workIt is prepared by skill：By weight by 5-15 parts of dendrobium candidum, 5-15 parts of hairyvein agrimony, 3-12 parts of pawpaw, 3-15 parts of persimmon leaf, black fungus3-20 parts, 3-12 parts of cordyceps sinensis, 2-15 parts of seaweed, 2-10 parts of rice, 1-5 parts of mung bean, 2-10 parts of litchi rind, leaves of hyacinth 3-15 parts, 1-8 parts of blackberry seed, 1-3 parts of carrot be added in ethyl alcohol, wherein the weight of ethyl alcohol be dendrobium candidum, hairyvein agrimony, pawpaw,Persimmon leaf, black fungus, cordyceps sinensis, seaweed, rice, mung bean, litchi rind, leaves of hyacinth, blackberry seed, carrot total weight 0.5-1.5 times, it is warming up to 55-65 DEG C, the microwave abstracting 20-35min under the power of 500-600W, extract liquor is through 0.45 μm of miillpore filterFiltering, it is then concentrated, be dried to obtain the composite extract.
The Chinese patent of Publication No. CN107126399A discloses a kind of tencel facial mask of the ingredient containing dendrobium candidum, specialSign is, is formulated by tetra- kinds of component raw materials of A, B, C and D：Component A：30-45 parts of pure water, 2-5 parts of glycerine, 1,2- penta0.3-0.5 parts of glycol, 0.2-0.6 parts of 1,2- hexylene glycols, 0.05-0.1 parts of EDETATE SODIUM, 0.12-0.15 parts of methyl hydroxybenzoate；B groupsPoint：1-10 parts of 1,3- propylene glycol, 0.1-0.6 parts of xanthans, 0.1-1 parts of Tremella fructification extract, hydroxyethyl cellulose 0.06-0.08 part, 0.01-0.1 parts of Sodium Hyaluronate；Component C：0.5-1 parts of trehalose, carbohydrate isomer/pure water/citric acid/lemon0.1-0.3 parts of lemon acid sodium compound, dendrobium candidum extract/pure water/2-8 parts of butanediol compound, the extraction of saccharomycete lysis objectObject/water/1-3 parts of Phenoxyethanol compound, 0.5-2 parts of Gotu Kola P.E, 0.06-0.08 parts of dipotassium glycyrrhizinate, Phenoxyethanol0.1-0.5 parts, -11 0.05-2 parts of hexapeptide, 0.1-0.5 parts of calcium pantothenate, 0.1-0.2 parts of xanthans, 0.1-1 parts of urea, pungent glycol0.1-0.25 parts, 0.06-0.08 parts of magnesium lactate, 0.1-0.25 parts of Sensiva SC50,0.02-0.05 parts of potassium chloride, potassium lactate0.02-0.05 parts, 0.02-0.05 parts of magnesium chloride, 0.5-2 parts of glucose；D components：0-0.04 parts of essence, PEG-40 hydrogenated castorsIt is 0.06-0.09 parts oily.
The Chinese patent of Publication No. CN107260576A discloses a kind of facial mask congealed fat containing Dendrobium officinale polysaccharide bodyPreparation method comprises the steps of：Step is 1.：Sieving is placed into heat after being smashed by disintegrating machine after dendrobium candidum is freeze-driedIt extracts 3-6 times in water, by centrifuging and taking liquid and is filtered, then reduced vacuum is concentrated into the 1/10 of original volume, after alcohol precipitationIt is spare that Dendrobium officinale polysaccharide is obtained by centrifugation and after frozen drying；Step is 2.：Dendrobium candidum spends raw material freezingIt is dry to be weighed, fed after sieving by disintegrating machine grinding and sieving, after then extracting essential oil condensation by steam distillationIt is discrete that obtain dendrobium candidum flower essential oil finished product spare；Step is 3.：By predetermined weight proportioning laruyl alcohol sulfosuccinate disodium,Lauric alcohol sodium sulfovinate, wheaten starch, paraffin, glycerine, titanium dioxide and distilled water are sent into the emulsification of homogeneous emulsifying machine essence matter, mixConjunction is emulsified into semi-finished product for standby；Step is 4.：By the fibroin of predetermined weight proportioning, marine algae extract, aloe extract, Ye LvElement, cuke extract, Ganodenna Lucidum P.E, fiddlehead dish root extract, extractive of olive growing leaves, poplar flower extract, anise seedExtract, camellia oil extract, ginkgo biloba p.e, beta glucan, cocounut oil acyl isethionic acid ester sodium, shea butter, step are 1.The Dendrobium officinale polysaccharide of middle extraction, step 2. in the dendrobium candidum flower essential oil finished product that extracts, the essence obtained in adding step 3.Semi-finished product after matter emulsion reaction, mixing by high-speed stirred after heating the heating of stirred tank and are penetrated final in a mold after standingMolding；Step is 5.：Finished product after ejection formation is prevented to carry out air drying in hothouse.
The Chinese patent of Publication No. CN107157892A discloses a kind of dendrobium candidum clay mask for repairing acne printPreparation method, include the following steps：S1：Extract dendrobium candidum extract：Take the fresh dendrobium candidum stem 150-180 after cleaningPart plus 6-8 times of water impregnate 0.5-1h, and heating and refluxing extraction 1-2h, filtrate decompression is condensed into paste, spare；S2：Extract tea treeMushroom Thick many candies：It takes 100-140 parts of agrocybe plus 8-10 times of water to be placed in extraction vessel, extraction vessel is placed in and presets temperatureFor in 50 DEG C of thermostat water baths, 6-8h, filtering are extracted in water bath with thermostatic control, filtrate decompression is distilled to the 1/10 of former extracting solution, be placed in-It is freezed at 4 DEG C for 24 hours, then is placed in freeze drier and is freeze-dried for 24 hours, it is spare；S3：Extract carambola Thick many candies：Take carambola70-100 parts add 8-10 times of water to be placed in extraction vessel, and extraction vessel is placed in and presets the thermostat water bath that temperature is 50 DEG CIn, 6-8h, filtering are extracted in water bath with thermostatic control, and filtrate decompression distills to the 1/10 of former extracting solution, is placed at -4 DEG C and freezes for 24 hours, then setIt is freeze-dried in freeze drier for 24 hours, it is spare；S4：Extract Lonicera confusa extract：Take 80-110 parts of Honeysuckle flower plus 5-8Times water is placed in supersonic extractors, and set temperature is 30-50 DEG C, time 20-40min, filtering, and filtrate is spare；S5：By followingParts by weight weigh component：50-80 parts of tea polyphenols, 50-70 parts of mung bean mud, 20-30 parts of bamboo charcoal fiber, 100-140 parts of algae clay, hydroxyl5-8 parts of yl benzoic acid ester；S6：Take tea polyphenols, hydroxybenzoate, agrocybe Thick many candies made from bamboo charcoal fiber and step S2,Carambola Thick many candies made from step S3 are added in mung bean mud and stir evenly, and obtain mixture A；S7：Take iron sheet stone made from step S1Lonicera confusa extract made from dry measure used in former times extract, step S4 and algae clay heating, are stirred, cooling, obtain mixture B；S8：By step S6Mixture A and the mixture B of step S7 be placed in blender, stir evenly, add alkali to adjust pH to 6-7, add water to configuration amount,Continue to stir, sterilizing, it is filling to get.
Invention content
It is poor for there are enriching yin moisturizings in existing dendrobium candidum mask product, water lock ability is weaker, active material is oxidizable,The problems such as shelf-life is shorter, the present invention provide a kind of dendrobium candidum mask product of low adhesion, product are made to have during skin careThere is the features such as enriching yin moisturizing and water lock ability are strong, active material is not oxidizable, long shelf-life.
Therefore, first purpose of the invention is to provide a kind of dendrobium candidum mask product, take dendrobium candidum extract 50~10~15 parts of 70 parts, 15~25 parts of Rhizoma Atractylodis Macrocephalae bletilla water extract, 15~30 parts of chitosan and moisturizer.
In a specific embodiment, wherein each material composition is formed with following parts by weight：Take dendrobium candidum extract15 parts of 60 parts, 20 parts of Rhizoma Atractylodis Macrocephalae bletilla water extract, 25 parts of chitosan and moisturizer.
Second purpose of the invention is to provide a kind of preparation method of dendrobium candidum mask product, and step includes：
10~20 parts of chitosan is taken, is added in 2% acetum, non-woven fabrics or stretch fabric or fibre is directly laid in after dissolvingOn the plain film of dimension, vacuum drying makes its water content be reduced to 15% hereinafter, obtaining composite membrane A；5~10 parts of Rhizoma Atractylodis Macrocephalae bletilla water extract is taken to addEnter water to be dissolved, 30~40 parts of dendrobium candidum extract is added, adds 10~15 parts of moisturizer, is stirred uniformly, directlyIt connects and is laid on release film, vacuum drying makes its water content be reduced to 10~15%, obtains composite membrane B；Rhizoma Atractylodis Macrocephalae bletilla water under remainderExtract is added water and is dissolved, and remaining dendrobium candidum extract is added, adds remaining chitosan solution, is stirred uniformly,It is directly poured on composite membrane B, vacuum drying makes its water content be reduced to 60~75%, then is overlapped with the chitosan face of composite membrane ATogether, 10~30min of ultrasonication is saved backup using vacuum packaging.
The weight kg ratios of above-mentioned plus water amount L and be dissolved in substance are 15~25：1.
The thickness of above-mentioned composite membrane is no more than 1.5cm.
Above-mentioned chitosan selects deacetylation to reach 90% or more, and application method is that 2% acetic acid is first added and dissolve to matchThe chitosan-acetic acid solution of mass volume ratio 1%~15% is made.
Above-mentioned moisturizer can directly from market buy water-keeping material, can also worked materials, using various plant polyosesSuch as starch, be added acrylic acid and crosslinking agent and catalyst carry out polymerization acquisition, specific method with reference to CN105640797A orThe method that CN107500930A is provided carries out.
Third purpose of the present invention is to provide a kind of preparation method of dendrobium candidum extract, and it is used for dendrobium candidumIn mask product, step includes：
(1) dry dendrobium candidum is crushed, a certain amount of water is added is stirred and be heated to 70~85 DEG C, heat preservation 20~After 80min, 6000rpm~9000rpm centrifuges 10~20min, obtains supernatant, goes to precipitate.
(2) supernatant is concentrated under reduced pressure into the 1/20-1/50 of original volume at 50~65 DEG C, adds 95% ethyl alcohol extremelyFinal concentration reaches 75% or more, alcohol precipitation 10-20h, and the ceramic membrane filter that progress membrane aperture is 0.22 μm is primary, obtains filter residue and dryingAs precipitate II, as Dendrobium officinale polysaccharide.
In one embodiment, volume L and the dendrobium candidum weight kg ratios that water is added described in step (1) be 3~5：1.
4th purpose of the invention is to provide a kind of preparation method of Rhizoma Atractylodis Macrocephalae bletilla water extract, and it is used for dendrobium candidumIn mask product, step includes：
A crushes dry Rhizoma Atractylodis Macrocephalae and bletilla, a certain amount of water is added is stirred and be heated to 70~85 DEG C, and heat preservation 20~After 80min, 6000rpm~9000rpm centrifuges 10~20min, obtains supernatant, goes to precipitate, wherein Rhizoma Atractylodis Macrocephalae and bletilla weight kg ratiosIt is 1~3：1.
Supernatant is concentrated to dryness at 50~65 DEG C as Rhizoma Atractylodis Macrocephalae Pseudobulbus Bletillae (Rhizoma Bletillae) extract by B.
In one embodiment, the volume L and Rhizoma Atractylodis Macrocephalae and bletilla mixture weight kg ratios of water are added described in step AIt is 3~5：1.
Technique effect
1, it makes full use of polysaccharides of traditional Chinese medicine and chitosan to form film and skin contact, water is supplemented convenient for going deep into skin bottomPoint, enhance skin moisture-retaining capacity, moisture content in skin can be made to keep appropriate, improves skin cell metabolism, conditioning fleshSkin microcirculation, and water lock while moisturizing promote skin to restore good barrier function, effectively reduce water loss, lockFirmly moisture keeps 24 hours long-acting water profits, to enhance skin moisturizing degree, elasticity and suppleness, careful nourishing skin, flesh of releivingSkin drying and itch so that the natural regulating power of skin is restored；Prevent the leaching of microorganism outside further through chitosanDye.
2, the oxidation rate of water extract is slowed down to the iris action of air by chitosan, can be effectively caught after applicationMoisture needed for skin reinforces moisturizing, and maintenance fiber desalinates wrinkle, promotes elasticity of skin and degree of compacting, and repairs skin barrier work(Can, make skin smooth, softness and high resilience.