A kind of high-temperature stable soap base type facial cleaning cream and preparation method thereofTechnical field
The invention discloses a kind of facial cleaning cream, is a kind of high-temperature stable soap base type facial cleaning cream specifically, the present invention also public affairsThe preparation method of the soap base type facial cleaning cream is opened, has belonged to chemical product technical field.
Background technology
Soap base type facial cleaning cream is with soap base as primary vehicle and the facial milk cleanser system of foaming agent, is that in recent years daily use chemicals line is non-One of the product that washes one's face of permanent current row, its foaming power is good, and foaming abundancy is fine and smooth, and decontamination is clean thoroughly easily to be rinsed well with rear, is givenThe clean salubrious sense of skin, in addition its pearly-lustre toothpaste-like outward appearance seem very noble, the beautiful great kindness for obtaining consumer and producer.
The soap base type facial cleaning cream brand circulated on market is very more, and such as High Tier Brand has the bright whitening clean skin of Estee LauderBreast, Shiseido thoroughly the bright profit facial cleaning cream of white U.S.'s flesh, Aupres time lock soft facial cleaning cream, the solidifying essence washing cream of Kosé Avenir book on Chinese herbal medicine,The solidifying face of He Lianna is oozed white moisturizing facial milk cleanser etc., and popular brand has live charcoal deep layer facial milk cleanser, Nivea silk of Mentholatum man soft and gracefulWhite facial milk cleanser, the net face facial milk cleanser of Ponds Korea Spro's sheet, herborist man's bodyguard equilibrium facial milk cleanser etc..So many brand business's production and sales soapFavorable rating of the visible consumer of face cleaning product of matrix system to such product.
Although the appearance of soap base type facial cleaning cream has had many years, Soap-base facial cleanser is because of its manufacturing process and formulaComplexity, the research of domestic Management of Cosmetics Enterprises to such product seems deep not enough, grasp not enough thoroughly, according to existing at presentThe analysis of the facial cleaning cream product that the domestic enterprise that can be seen in society is produced, the facial cleaning cream product that most enterprises are producedAll without the performance indications that can reach same kind of products at abroad, especially high-temperature stability this aspect grasp not enough intoIt is ripe.The high temperature of soap base system facial cleaning cream shows as two kinds on market：The first state is most commonly seen, and 40-45 DEG C is placed liquefaction pointLayer, recovers to return to normal after room temperature, and upper strata is very hard pearly-lustre shape solid, the next solid without pearly-lustre or semisolid,This pyrometric scale is most commonly seen currently on the market.The advantage of this state is that knot cream point is relatively low, and mastic is softer, low temperature (5-10 DEG C)Shi Buhui becomes very hard, and such use feeling is relatively good, is easily opened mastic, has the disadvantage in transportation if meeting with fortiesThe high temperature of degree, mastic can go bad layering.Second is the ability liquid after even 55 DEG C higher than 48 DEG C with domestic some products as representativeChange layering, recover to return to normal after room temperature, upper strata is very hard pearly-lustre shape solid, the next solid without pearly-lustre or partly solidBody, this pyrometric scale is also relatively conventional currently on the market.The advantage of this state is that knot cream point is high, is met with transportation highTemperature, mastic also undergoes no deterioration layering, and high-temperature stability is relatively trusted.It is determined that being that mastic is harder, become during low temperature (5-10 DEG C)Very hard, mastic is difficult to be dissolved opening, or even can not extrude during winter.
The content of the invention
For above-mentioned deficiency, the present invention provides a kind of high-temperature stable, cost performance height, and foaming abundancy moistens not tight after washingSoap-base facial cleanser.
To solve above-mentioned technical problem, first technical scheme that the present invention is provided is such：
A kind of high-temperature stable soap base type facial cleaning cream, is made up of the component of following weight percentage ratio：Stearic acid 10～30%, the moonCinnamic acid 2～10%, myristic acid 5～10%, castor oil hydrogenated 0.5～2%, glyceryl stearate 0.25～1.5%, PEG-100 stearates 0.25～1.5%, potassium hydroxide 2～10%, glycerol 5～20%, Propylene Glycol 1～10%, EDETATE SODIUM 0～1%, preservative 0～1%, essence 0～1%, hydroxypropyl methyl cellulose 0.1～1%, balance of water.
Further, a kind of above-mentioned high-temperature stable soap base type facial cleaning cream, is made up of the component of following weight percentage ratio：FirmlyFat acid 15～25%, lauric acid 4～8%, myristic acid 6～9%, castor oil hydrogenated 1～1.5%；Glyceryl stearate 0.25～1.5%, PEG-100 stearate 0.25～1.5%, potassium hydroxide 4～8%, glycerol 10～15%, Propylene Glycol 3～7%,EDETATE SODIUM 0.2～0.8%, preservative 0.2～0.8%, essence 0.2～0.8%, hydroxypropyl methyl cellulose 0.1～1%,Balance of water.
Another technical scheme that the present invention is provided is to provide the preparation method of the high-temperature stable soap base type facial cleaning cream, the partyMethod comprises the steps successively：
1) each component is weighed；
2) by step 1) water that weighs is added to water phase pot, then potassium hydroxide is added to the water into dissolving, then again successively plusEnter EDETATE SODIUM, glycerol, Propylene Glycol, stir, be heated to 75 DEG C, obtain A phases, it is standby；
3) by stearic acid, lauric acid, myristic acid, castor oil hydrogenated, glyceryl stearate, PEG-100 stearates are thrownEnter in emulsifying pot and be stirred and heated to 75 DEG C, obtain B phases, it is standby；
4) stirring of emulsifying pot is opened, B phase components is quickly pumped in A phase components, and add hydroxypropyl methyl fineDimension element, keeps stable system, and saponification 30～60 minutes are incubated at 80 DEG C -90 DEG C；
5) cooling water stirring cooling is opened, preservative and essence is added when cooling to less than 45 DEG C, continue to stir to bodyTying is paste body shape, is then stirred for 30 minutes discharging.
Compared with prior art, because castor oil hydrogenated has more-OH in the technical scheme that the present invention is provided, GuBlow point is higher, can reduce dissolubility of the fatty acid potassium salt under soap base system high temperature state (45-50 DEG C) so as to noLayering, while can play a part of to assign ester as oils and fatss, moistens not tight after washing user, hydroxypropyl methyl cellulose can be withSuspension of the non-saponified fat acid in system is improved, while foam enhancing can be played a part of and adjusted rear skin sense, glyceryl stearate are washedAcid and PEG-100 stearates can be with the unsaponified fatty acids of emulsifying so as to which will not float precipitation, so that soap base is in high temperature barIt is stable in properties under part, it is not stratified；Fatty acid reacts the work for generating fatty acid potassium salt (soap base) so as to play cleaning with potassium hydroxideWith glycerol can be with disperse fat acid potassium salt；Propylene Glycol can dissolve disperse fat acid potassium salt；EDETATE SODIUM is as chelating agen and surelyDetermine agent；Preservative plays in the basic conditions antiseptical effect；Essence covers the fragrance that base material taste gives product pleasure, eachComponent synergism, so as to ensure the soap base under the high temperature conditions in steady statue, the not stratified water outlet at 45-60 DEG C, and hasThere is good moisturizing to assign fat effect, improve skin and wash rear defat, tight feeling.
Specific embodiment
The claim of the present invention is described in further detail with reference to the mode of specific embodiment, but not structureInto any limitation of the invention, the modification of anyone limited number of time for being made within the scope of the invention as claimed, still at thisWithin bright right.
Embodiment 1
A kind of high-temperature stable soap base type facial cleaning cream that the present invention is provided, is made up per 100g of following weight array point：Hard FatSour 30g, lauric acid 2g, myristic acid 10g, castor oil hydrogenated 0.5g；Glyceryl stearate 1.5g, PEG-100 stearate1.5g, potassium hydroxide 2g, glycerol 20g, Propylene Glycol 1g, EDETATE SODIUM 1g, essence 1g, hydroxypropyl methyl cellulose 0.1g, surplusFor water.
Embodiment 2
A kind of high-temperature stable soap base type facial cleaning cream that the present invention is provided, is made up per 100g of following weight array point：Hard FatSour 10g, lauric acid 10g, myristic acid 5g, castor oil hydrogenated 2g；Glyceryl stearate 0.25g, PEG-100 stearate0.25g, potassium hydroxide 10g, glycerol 5g, Propylene Glycol 10g, preservative 1g, hydroxypropyl methyl cellulose 1g, balance of water.
Embodiment 3
A kind of high-temperature stable soap base type facial cleaning cream that the present invention is provided, is made up per 100g of following weight array point：Hard FatSour 15g, lauric acid 8g, myristic acid 6g, castor oil hydrogenated 1.5g；Glyceryl stearate 0.5g, PEG-100 stearate0.5g, potassium hydroxide 8g, glycerol 10g, Propylene Glycol 7g, EDETATE SODIUM 0.2g, preservative 0.8g, essence 0.2g, hydroxypropyl methylCellulose 1g, balance of water.
Embodiment 4
A kind of high-temperature stable soap base type facial cleaning cream that the present invention is provided, is made up per 100g of following weight array point：Hard FatSour 20g, lauric acid 6g, myristic acid 7g, castor oil hydrogenated 1.2g；Glyceryl stearate 0.75g, PEG-100 stearate0.75g, potassium hydroxide 6g, glycerol 12g, Propylene Glycol 5g, EDETATE SODIUM 0.5g, preservative 0.5g, essence 0.5g, hydroxypropyl methylCellulose 0.61g, balance of water.
Embodiment 5
A kind of high-temperature stable soap base type facial cleaning cream that the present invention is provided, is made up per 100g of following weight array point：Hard FatSour 25g, lauric acid 4g, myristic acid 9g, castor oil hydrogenated 1g；Glyceryl stearate 1.0g, PEG-100 stearate 1.0g,Potassium hydroxide 4g, glycerol 15g, Propylene Glycol 3g, EDETATE SODIUM 0.8g, preservative 0.2g, essence 0.8g, hydroxypropyl methyl cellulose0.1g, balance of water.
In order to prove the beneficial effect of the high-temperature stable soap base type facial cleaning cream of present invention offer, offer of the present invention is given belowHigh-temperature stable soap base type facial cleaning cream detection data.
1st, reagent
The screening operation of 1.1 soap base high-temperature stable raw materials：
The selection of raw material：The sample in comparative example 1 to comparative example 3 is configured using same method, is surveyed after sample preparation successTest agent observes state of the sample at 5 DEG C and sensation on probation in 40 DEG C, 45 DEG C, 50 DEG C of stability.
The testing result of sample stability
Performance during high-temperature sample can be divided into following state：
A. there is pearly-lustre not stratified；B is without pearly-lustre but not stratified；C. it is layered after melting and stratified proportional is big；D. it is layered after meltingBut lower stratum proportion is little.
Comparative example 1
Castor oil hydrogenated, SF-1 is replaced to replace hydroxypropyl methyl cellulose, tween 20 to replace glycerol stearate with stearic acidEster (and) PEG-100 stearates, other components and proportion it is consistent with embodiment 4.Comparative example 2
Castor oil hydrogenated, hydroxyethyl cellulose is replaced to replace hydroxypropyl methyl cellulose, HR-S1 to replace with cetearyl alcoholGlyceryl stearate (and) PEG-100 stearates, other components and proportion it is consistent with embodiment 4.
Comparative example 3
Castor oil hydrogenated, SF-1 is replaced to replace hydroxypropyl methyl cellulose, HR-S1 to replace glyceryl stearate with monoglyceride(and) PEG-100 stearates, other components and proportion it is consistent with embodiment 4.Comparative example 4
Commercially available prod.
The high-temperature sample state verification table of table 1.
| Sample | 40℃ | 45℃ | 50℃ | 5 DEG C using sensation |
| Embodiment 1 | A | A | A | Foaming is fast, and bubble diminishes, and mastic is soft, without sensation of dryness during flushing. |
| Embodiment 2 | A | A | A | Foaming is fast, and bubble diminishes, and mastic is soft, without sensation of dryness during flushing. |
| Embodiment 3 | A | A | A | Foaming is fast, and bubble diminishes, and mastic is soft, without sensation of dryness during flushing. |
| Embodiment 4 | A | A | A | Foaming is fast, and bubble diminishes, and mastic is soft, without sensation of dryness during flushing. |
| Embodiment 5 | A | A | A | Foaming is fast, and bubble diminishes, and mastic is soft, without sensation of dryness during flushing. |
| Comparative example 1 | A | D | D | Bubble very little, foaming is difficult, rinses dry and astringent |
| Comparative example 2 | A | D | D | Foam is little, rinses dry and astringent |
| Comparative example 3 | A | D | D | Bubble very little, foaming is difficult, rinses dry and astringent |
| Comparative example 4 | A | B | C | Foaming hands over fast, and bubble diminishes, and has slight astringent sense during flushing. |
As can be seen from the above table, the formula property stable in properties under the high temperature conditions that the present invention is provided, and sample is in low temperatureWhen table it is functional, soft foam is enriched, and pearly-lustre becomes fine and smooth, without sensation of dryness during flushing.