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CN106316691A - Polynucleotide zinc humid acid synergistic fertilizer and preparing method thereof - Google Patents

Polynucleotide zinc humid acid synergistic fertilizer and preparing method thereof
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Publication number
CN106316691A
CN106316691ACN201610715199.5ACN201610715199ACN106316691ACN 106316691 ACN106316691 ACN 106316691ACN 201610715199 ACN201610715199 ACN 201610715199ACN 106316691 ACN106316691 ACN 106316691A
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China
Prior art keywords
acid
poly
fertilizer
zinc
transported
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CN201610715199.5A
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Chinese (zh)
Inventor
张培升
常国锋
李春雷
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Shijiazhuang Zhongjia Fertilizer Co Ltd
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Shijiazhuang Zhongjia Fertilizer Co Ltd
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Priority to CN201610715199.5ApriorityCriticalpatent/CN106316691A/en
Publication of CN106316691ApublicationCriticalpatent/CN106316691A/en
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Abstract

The invention discloses a polynucleotide zinc humid acid synergistic fertilizer, prepared from, by weight, 88- 95 parts of compound fertilizer, 5- 12 parts of polynucleotide zinc humic acid synergist. The polynucleotide zinc humic acid synergist does not change due function of the humic acid. The humic acid is mainly composed of elements such as carbon, hydrogen, oxygen, nitrogen, sulfur, and contains functional groups such as phenolic hydroxyl group, hydroxyl group, quinone hydroxyl group, alcohol group, sulfonic acid group, and amine group. Humic acid is added into the fertilizer, which can increase the content of organic matter in the soil, enhance the growth and respiration of the crop root system, improve the root activity of the crop, promote the nutrient uptake through the foliar and root, inhibit the enzyme in the soil or promote the role of enzyme production, and can enhance the crop resistance, improve the quality of crop products, and compound fertilizer with the compound fertilizer fertilizer effect is fully utilized.

Description

A kind of poly-nuclear zinc corruption acid enhanced fertilizer and compound method thereof
Technical field
The present invention relates to technical field of fertilizers, be specially a kind of poly-nuclear zinc corruption acid enhanced fertilizer and compound method thereof.
Background technology
Compound fertilizer by chemical method or mixed method make containing any two in crop alimentary elemental nitrogen, phosphorus, potassium orThe chemical fertilizer of three kinds, compound fertilizer has purposes widely in current agricultural production, but improves making full use of of compound fertilizer's fertilizer efficiencyBeing our problem of always studying, we need the problem constantly studied especially in poly-nuclear zinc corruption acid application in compound fertilizer.
Summary of the invention
It is an object of the invention to provide a kind of poly-nuclear zinc corruption acid enhanced fertilizer and compound method thereof, to solve above-mentioned backgroundThe problem proposed in technology.
For achieving the above object, the present invention provides following technical scheme: a kind of poly-nuclear zinc corruption acid enhanced fertilizer, its raw material is pressedWeight portion is as follows: compound fertilizer's 88-95 part, poly-nuclear zinc corruption acid synergist 5-12 part.
Preferably, described compound fertilizer can be nitrogen phosphorus binary compound fertilizer, binary compound fertilizer containing nitrogen and potassium and N P and K tri compoundFertile.
Preferably, described poly-nuclear zinc corruption acid synergist is to utilize natural high-quality humic acids through adding microbial bacteria respectivelyAgent (salt tolerance lichengermium, salt tolerance bacillus subtilis) configuration forms.
The compound method of a kind of poly-nuclear zinc corruption acid enhanced fertilizer that the present invention also provides for, comprises the steps:
S1, the preparation of poly-nuclear zinc corruption acid synergist:
(1), add salt tolerance lichengermium and 10 kilograms according to every 1 ton of natural humic acid, be metered into one-levelIn fermentation tank, then it is sufficiently stirred for, adds humic-acid-type substances per ton and add water according to 200 kilograms, after being sufficiently stirred for, constant 65Degree celsius temperature bottom fermentation 20 hours, then be transported in second order fermentation tank, after being sufficiently stirred under constant 90 degree celsius temperature, send outFerment 40 hours, after being then passed through centrifuge dewatering, is transported in drying machine be dried, and the most communicated band is transported to coolerCool down, be transported to after cooling in rotary drum coating machine, meanwhile, add 50 according to the humic acids containing lichengermium agent per tonKilogram zinc sulfate, is carried out fully with the humic-acid-type substances containing lichengermium agent in measuring belt enters into rotary drum coating machineMixing, after enter into quantitative package in metering packaging machine, be packaged into 50 kilograms of packagings, both must contain lichengermium agent and contain sulfurThe humic acids of acid zinc;
(2), add 10 kilograms of bacillus subtilis according to natural humic acid per ton, be transported in one grade fermemtation tank enter through meteringRow stirring, then according to humic acids per ton adds 200 kg of water, after being sufficiently stirred for, at constant 75 degree celsius temperature bottom fermentations 20Hour, then be transported in second order fermentation tank, after being sufficiently stirred under constant 100 degree celsius temperature, ferment 40 hours, be then passed throughAfter centrifuge dewatering, being transported in drying machine be dried, the most communicated band is transported to cooler and cools down, defeated after coolingDeliver in rotary drum coating machine, meanwhile, add 50 kilograms of zinc sulfate according to the humic acids containing bacillus subtilis agent per ton, through metering skinBe brought in rotary drum coating machine and be sufficiently mixed with the humic-acid-type substances containing bacillus subtilis agent, after enter into metering bagQuantitative package in installation, is packaged into 50 kilograms of packagings, both must contain bacillus subtilis agent, humic-acid-type substances containing zinc sulfate;
Two kinds of methods all can prepare poly-nuclear zinc corruption acid synergist;
S2, by formulated poly-nuclear zinc corruption acid synergist and the sufficient mix and blend of compound fertilizer, it is thus achieved that poly-nuclear zinc corruption acidEnhanced fertilizer.
Described one grade fermemtation tank and second order fermentation tank volume are 10 cubic metres, and with agitating device.
Described drying machine model is 2.2 meters × 22 meters.
Described cooler model is 2 meters × 18 meters.
Compared with prior art, the invention has the beneficial effects as follows: the poly-nuclear zinc corruption acid synergist that the present invention prepares, notChanging the due effect of humic acids, humic-acid-type substances is mainly elementary composition by carbon, hydrogen, oxygen, nitrogen, sulfur etc., is a kind of multivalence phenolicAromatic compound and the polymer of nitrogen compound, have acidity, hydrophilic, ion exchangeable, and molecular weight can reach several ten thousand and arrivesMillions of units.Containing several functions groups such as phenolic hydroxyl group, hydroxyl, quinone hydroxyl, alcohol radical, sulfonic group, amidos.Humic-acid-type substances addsIt is added in fertilizer, the content of soil with organic matter can be increased, growth and the Repiration of crop root can be strengthened, improve and makeThing improving activity of root system, promotes Nutrient Absorption by blade face and root, has suppression to the various enzymes in soil or promotes what enzyme generatedEffect, and the resistance of crop can be strengthened, improve crop product quality.Generally, humic acid fertilizer can improve nitrogenFertile utilization rate about 6% to 15%, can improve the utilization rate about 7% of P elements, it is possible to improve the utilization rate of potassium element.This is speciallyThe poly-nuclear zinc corruption acid synergist of profit, i.e. contains the humic acids of high-quality, adds again microbial bacterial agent, and lichengermium agent is at fertilizerIn there is promotion plant growth, stimulate crop root to grow, improve the nitrogen fixing capacity of plant, reduce the nitrification and denitrification of nitrogenous fertilizerEffect, reduces the content of nitrate, it is possible to reduces pesticide residues, improves crop quality.Bacillus subtilis agent has in fertilizerHave strengthen crop resistance against diseases, the synthesis of multiple enzyme in involved in plant body, owing to bacillus subtilis is bred rapidly in soil,Spore is big, and spore is many, can effectively suppress the breeding of pernicious bacteria in soil, improve P in soil H-number, improve edaphic condition, is beneficial toThe growth of crop.Application in recent years shows, bacillus subtilis can also be effectively improved nitrogen, phosphorus, potassium, calcium, magnesium sulfur etc. in fertilizerThe absorption of element and utilization, promote the nutrition release of mineral.The poly-nuclear zinc corruption acid synergist of the present invention also added zinc sulfate,Can be that crop supplements zinc element.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with specific embodiment, to thisInvention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, notFor limiting the present invention.
Embodiment 1
A kind of poly-nuclear zinc corruption acid enhanced fertilizer, its raw material is as follows: nitrogen phosphorus binary compound fertilizer 95 parts, and poly-nuclear zinc is rottenAcid synergist 5 parts.
Described compound fertilizer can be nitrogen phosphorus binary compound fertilizer, binary compound fertilizer containing nitrogen and potassium and N P and K NPK.
Described poly-nuclear zinc corruption acid synergist is to utilize natural high-quality humic acids through adding microbial bacterial agent (salt tolerant respectivelyProperty lichengermium, salt tolerance bacillus subtilis) configuration form.
The compound method of a kind of poly-nuclear zinc corruption acid enhanced fertilizer that the present invention also provides for, comprises the steps:
S1, the preparation of poly-nuclear zinc corruption acid synergist:
(1), add salt tolerance lichengermium and 10 kilograms according to every 1 ton of natural humic acid, be metered into one-levelIn fermentation tank, then it is sufficiently stirred for, adds humic-acid-type substances per ton and add water according to 200 kilograms, after being sufficiently stirred for, constant 65Degree celsius temperature bottom fermentation 20 hours, then be transported in second order fermentation tank, after being sufficiently stirred under constant 90 degree celsius temperature, send outFerment 40 hours, after being then passed through centrifuge dewatering, is transported in drying machine be dried, and the most communicated band is transported to coolerCool down, be transported to after cooling in rotary drum coating machine, meanwhile, add 50 according to the humic acids containing lichengermium agent per tonKilogram zinc sulfate, is carried out fully with the humic-acid-type substances containing lichengermium agent in measuring belt enters into rotary drum coating machineMixing, after enter into quantitative package in metering packaging machine, be packaged into 50 kilograms of packagings, both must contain lichengermium agent and contain sulfurThe humic acids of acid zinc;
(2), add 10 kilograms of bacillus subtilis according to natural humic acid per ton, be transported in one grade fermemtation tank enter through meteringRow stirring, then according to humic acids per ton adds 200 kg of water, after being sufficiently stirred for, at constant 75 degree celsius temperature bottom fermentations 20Hour, then be transported in second order fermentation tank, after being sufficiently stirred under constant 100 degree celsius temperature, ferment 40 hours, be then passed throughAfter centrifuge dewatering, being transported in drying machine be dried, the most communicated band is transported to cooler and cools down, defeated after coolingDeliver in rotary drum coating machine, meanwhile, add 50 kilograms of zinc sulfate according to the humic acids containing bacillus subtilis agent per ton, through metering skinBe brought in rotary drum coating machine and be sufficiently mixed with the humic-acid-type substances containing bacillus subtilis agent, after enter into metering bagQuantitative package in installation, is packaged into 50 kilograms of packagings, both must contain bacillus subtilis agent, humic-acid-type substances containing zinc sulfate;
Two kinds of methods all can prepare poly-nuclear zinc corruption acid synergist;
S2, by formulated poly-nuclear zinc corruption acid synergist and the sufficient mix and blend of compound fertilizer, it is thus achieved that poly-nuclear zinc corruption acidEnhanced fertilizer.
Described one grade fermemtation tank and second order fermentation tank volume are 10 cubic metres, and with agitating device.
Described drying machine model is 2.2 meters × 22 meters.
Described cooler model is 2 meters × 18 meters.
Embodiment 2
A kind of poly-nuclear zinc corruption acid enhanced fertilizer, its raw material is as follows: binary compound fertilizer containing nitrogen and potassium 93 parts, and poly-nuclear zinc is rottenAcid synergist 7 parts.
Described compound fertilizer can be nitrogen phosphorus binary compound fertilizer, binary compound fertilizer containing nitrogen and potassium and N P and K NPK.
Described poly-nuclear zinc corruption acid synergist is to utilize natural high-quality humic acids through adding microbial bacterial agent (salt tolerant respectivelyProperty lichengermium, salt tolerance bacillus subtilis) configuration form.
The compound method of a kind of poly-nuclear zinc corruption acid enhanced fertilizer that the present invention also provides for, comprises the steps:
S1, the preparation of poly-nuclear zinc corruption acid synergist:
(1), add salt tolerance lichengermium and 10 kilograms according to every 1 ton of natural humic acid, be metered into one-levelIn fermentation tank, then it is sufficiently stirred for, adds humic-acid-type substances per ton and add water according to 200 kilograms, after being sufficiently stirred for, constant 65Degree celsius temperature bottom fermentation 20 hours, then be transported in second order fermentation tank, after being sufficiently stirred under constant 90 degree celsius temperature, send outFerment 40 hours, after being then passed through centrifuge dewatering, is transported in drying machine be dried, and the most communicated band is transported to coolerCool down, be transported to after cooling in rotary drum coating machine, meanwhile, add 50 according to the humic acids containing lichengermium agent per tonKilogram zinc sulfate, is carried out fully with the humic-acid-type substances containing lichengermium agent in measuring belt enters into rotary drum coating machineMixing, after enter into quantitative package in metering packaging machine, be packaged into 50 kilograms of packagings, both must contain lichengermium agent and contain sulfurThe humic acids of acid zinc;
(2), add 10 kilograms of bacillus subtilis according to natural humic acid per ton, be transported in one grade fermemtation tank enter through meteringRow stirring, then according to humic acids per ton adds 200 kg of water, after being sufficiently stirred for, at constant 75 degree celsius temperature bottom fermentations 20Hour, then be transported in second order fermentation tank, after being sufficiently stirred under constant 100 degree celsius temperature, ferment 40 hours, be then passed throughAfter centrifuge dewatering, being transported in drying machine be dried, the most communicated band is transported to cooler and cools down, defeated after coolingDeliver in rotary drum coating machine, meanwhile, add 50 kilograms of zinc sulfate according to the humic acids containing bacillus subtilis agent per ton, through metering skinBe brought in rotary drum coating machine and be sufficiently mixed with the humic-acid-type substances containing bacillus subtilis agent, after enter into metering bagQuantitative package in installation, is packaged into 50 kilograms of packagings, both must contain bacillus subtilis agent, humic-acid-type substances containing zinc sulfate;
Two kinds of methods all can prepare poly-nuclear zinc corruption acid synergist;
S2, by formulated poly-nuclear zinc corruption acid synergist and the sufficient mix and blend of compound fertilizer, it is thus achieved that poly-nuclear zinc corruption acidEnhanced fertilizer.
Described one grade fermemtation tank and second order fermentation tank volume are 10 cubic metres, and with agitating device.
Described drying machine model is 2.2 meters × 22 meters.
Described cooler model is 2 meters × 18 meters.
Embodiment 3
A kind of poly-nuclear zinc corruption acid enhanced fertilizer, its raw material is as follows: N P and K NPK 88 parts, poly-nuclear zincRotten acid synergist 12 parts.
Described compound fertilizer can be nitrogen phosphorus binary compound fertilizer, binary compound fertilizer containing nitrogen and potassium and N P and K NPK.
Described poly-nuclear zinc corruption acid synergist is to utilize natural high-quality humic acids through adding microbial bacterial agent (salt tolerant respectivelyProperty lichengermium, salt tolerance bacillus subtilis) configuration form.
The compound method of a kind of poly-nuclear zinc corruption acid enhanced fertilizer that the present invention also provides for, comprises the steps:
S1, the preparation of poly-nuclear zinc corruption acid synergist:
(1), add salt tolerance lichengermium and 10 kilograms according to every 1 ton of natural humic acid, be metered into one-levelIn fermentation tank, then it is sufficiently stirred for, adds humic-acid-type substances per ton and add water according to 200 kilograms, after being sufficiently stirred for, constant 65Degree celsius temperature bottom fermentation 20 hours, then be transported in second order fermentation tank, after being sufficiently stirred under constant 90 degree celsius temperature, send outFerment 40 hours, after being then passed through centrifuge dewatering, is transported in drying machine be dried, and the most communicated band is transported to coolerCool down, be transported to after cooling in rotary drum coating machine, meanwhile, add 50 according to the humic acids containing lichengermium agent per tonKilogram zinc sulfate, is carried out fully with the humic-acid-type substances containing lichengermium agent in measuring belt enters into rotary drum coating machineMixing, after enter into quantitative package in metering packaging machine, be packaged into 50 kilograms of packagings, both must contain lichengermium agent and contain sulfurThe humic acids of acid zinc;
(2), add 10 kilograms of bacillus subtilis according to natural humic acid per ton, be transported in one grade fermemtation tank enter through meteringRow stirring, then according to humic acids per ton adds 200 kg of water, after being sufficiently stirred for, at constant 75 degree celsius temperature bottom fermentations 20Hour, then be transported in second order fermentation tank, after being sufficiently stirred under constant 100 degree celsius temperature, ferment 40 hours, be then passed throughAfter centrifuge dewatering, being transported in drying machine be dried, the most communicated band is transported to cooler and cools down, defeated after coolingDeliver in rotary drum coating machine, meanwhile, add 50 kilograms of zinc sulfate according to the humic acids containing bacillus subtilis agent per ton, through metering skinBe brought in rotary drum coating machine and be sufficiently mixed with the humic-acid-type substances containing bacillus subtilis agent, after enter into metering bagQuantitative package in installation, is packaged into 50 kilograms of packagings, both must contain bacillus subtilis agent, humic-acid-type substances containing zinc sulfate;
Two kinds of methods all can prepare poly-nuclear zinc corruption acid synergist;
S2, by formulated poly-nuclear zinc corruption acid synergist and the sufficient mix and blend of compound fertilizer, it is thus achieved that poly-nuclear zinc corruption acidEnhanced fertilizer.
Described one grade fermemtation tank and second order fermentation tank volume are 10 cubic metres, and with agitating device.
Described drying machine model is 2.2 meters × 22 meters.
Described cooler model is 2 meters × 18 meters.
The poly-nuclear zinc corruption acid enhanced fertilizer of the present invention, shows through substantial amounts of application experiment, can be effectively improved the profit of fertilizerBy rate, strengthening disease-resistant, the drought resisting of crop, waterlogging-resistant ability, enhance the resistance of crop, general crop can be planted continuously, anti-Heavily meet batch effect notable.Show through great many of experiments, under the plantation of general field crop, can improve the utilization rate 20% of nitrogen element withOn, improve P elements utilization rate more than 10%, improve potassium element utilization rate more than 12%, it is possible to improve crop to calcium, magnesium,Multiple moderate-element and the absorptions of trace element such as sulfur, zinc, ferrum, boron, molybdenum, significantly enhance the resistance against diseases of crop, and effectivelyImprove the effect of soil, make loosing soil fertile.Due to, China's humic acids is widely distributed, substantial amounts, the price of humic acidsCheap, lichengermium agent and bacillus subtilis agent have also been formed industrialization, and price comparison is cheap, according to side of the present inventionMethod, the fertilizer of prepared poly-nuclear zinc corruption acid enhanced fertilizer contrast same amount, per ton only increase about 120 yuan of costs, be beneficial to promoteWith utilization, and the dose of about 20%-30% can be reduced, not result in the underproduction, through great many of experiments, reducing doseIn the case of 20%, amount of increase in production is more than 6%.This patent is that one is beneficial to be applied to promote in field of fertilizer production, again may be usedTo reduce dose, reduce the effective approach of carbon emission.The Fertilizer application amount of China, about at 100,000,000 tons, is that agricultural area source is dirtyThe main source of dye, if reducing by the dose of 10%, it is possible to a large amount of pollution of area source reducing agricultural, reduces the substantial amounts of energyConsume and substantial amounts of carbon emission.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme andInventive concept equivalent or change in addition, all should contain within protection scope of the present invention.

Claims (7)

(1), add salt tolerance lichengermium and 10 kilograms according to every 1 ton of natural humic acid, be metered into one grade fermemtationIn tank, then it is sufficiently stirred for, adds humic-acid-type substances per ton and add water according to 200 kilograms, after being sufficiently stirred for, constant 65 CelsiusFerment 20 hours at a temperature of degree, then be transported in second order fermentation tank, after being sufficiently stirred under constant 90 degree celsius temperature, fermentation 40Hour, after being then passed through centrifuge dewatering, it being transported in drying machine be dried, the most communicated band is transported to cooler to be carried outCooling, is transported to after cooling in rotary drum coating machine, meanwhile, adds 50 kilograms according to the humic acids containing lichengermium agent per tonZinc sulfate, fully mixes with the humic-acid-type substances containing lichengermium agent in measuring belt enters into rotary drum coating machineClose, after enter into quantitative package in metering packaging machine, be packaged into 50 kilograms of packagings, both must contain lichengermium agent and contain sulphuric acidThe humic acids of zinc;
(2), add 10 kilograms of bacillus subtilis according to natural humic acid per ton, be transported in one grade fermemtation tank stir through meteringMix, then according to humic acids per ton adds 200 kg of water, after being sufficiently stirred for, constant 75 degree celsius temperature bottom fermentation 20 hours,It is transported to again in second order fermentation tank, after being sufficiently stirred under constant 100 degree celsius temperature, ferments 40 hours, be then passed through being centrifugedAfter machine dehydration, being transported in drying machine be dried, the most communicated band is transported to cooler and cools down, and is transported to after coolingIn rotary drum coating machine, meanwhile, add 50 kilograms of zinc sulfate according to the humic acids containing bacillus subtilis agent per ton, enter through measuring beltEnter in rotary drum coating machine and be sufficiently mixed with the humic-acid-type substances containing bacillus subtilis agent, after enter into metering packaging machineMiddle quantitative package, is packaged into 50 kilograms of packagings, both must contain bacillus subtilis agent, humic-acid-type substances containing zinc sulfate;
CN201610715199.5A2016-08-242016-08-24Polynucleotide zinc humid acid synergistic fertilizer and preparing method thereofPendingCN106316691A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
CN109748762A (en)*2019-03-152019-05-14河北中仁化肥集团有限公司A kind of amino acid polymerization potassium enhanced fertilizer

Citations (2)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
CN101774854A (en)*2010-01-152010-07-14袁新华Biological organic compound fertilizer
CN103011952A (en)*2012-11-302013-04-03山东农大肥业科技有限公司Manufacturing method of high-concentration biological compound fertilizer

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
CN101774854A (en)*2010-01-152010-07-14袁新华Biological organic compound fertilizer
CN103011952A (en)*2012-11-302013-04-03山东农大肥业科技有限公司Manufacturing method of high-concentration biological compound fertilizer

Cited By (1)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
CN109748762A (en)*2019-03-152019-05-14河北中仁化肥集团有限公司A kind of amino acid polymerization potassium enhanced fertilizer

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