技术领域technical field
本发明涉及一种利用绿茶茶叶提取物制备的电子烟烟液，属于电子烟制备领域。The invention relates to an electronic cigarette liquid prepared by using green tea extract, and belongs to the field of electronic cigarette preparation.
背景技术Background technique
随着国际烟草控制框架公约的逐步实施和人们健康意识的逐渐增强，传统卷烟销售市场受到强大冲击。为了应对市场的变化和消费者的需求，一类低危害的新型烟草制品受到了国内外各大烟草企业的高度关注和广泛研究。其中，电子烟作为新型烟草制品中一类重要产品，是将含有或不含烟碱溶液雾化成微粒，直接被消费者吸入。电子烟由于采取雾化方式生成烟雾感觉，不产生焦油和CO，同时几乎不产生二手烟危害，被视为无公害的戒烟产品或烟草替代品。近些年来特别是在欧美发达国家表现出强劲的发展趋势，数据表明世界电子烟销售总额近三年来年均增速高达40％。其中仅在美国市场，2013年电子烟销售总额已超过10亿美元，比2012年增长了近一倍。With the gradual implementation of the International Tobacco Control Framework Convention and the gradual enhancement of people's health awareness, the traditional cigarette sales market has been greatly impacted. In response to changes in the market and the needs of consumers, a new class of low-harm tobacco products has received great attention and extensive research from major tobacco companies at home and abroad. Among them, electronic cigarettes, as an important category of new tobacco products, atomize solutions containing or not containing nicotine into particles, which are directly inhaled by consumers. E-cigarettes are regarded as pollution-free smoking cessation products or tobacco substitutes because they use atomization to generate a sense of smoke, do not produce tar and CO, and produce almost no second-hand smoke hazards. In recent years, especially in developed countries in Europe and the United States, there has been a strong development trend. Data show that the world's total e-cigarette sales have grown at an average annual rate of 40% in the past three years. Among them, in the US market alone, the total sales of e-cigarettes in 2013 exceeded 1 billion US dollars, nearly double that of 2012.
电子烟巨大的市场潜力激发各大烟草企业和个人的广泛兴趣和深入研究。目前已有的雾化技术可以产生较好的雾化效果，给电子烟吸食者以吞云吐雾的感受，但是在口感、香气上与传统卷烟相比却是差强人意。改善电子烟烟液配方是目前电子烟研究的重中之重，是烟草企业在电子烟行业立足和发展的核心技术。The huge market potential of e-cigarettes has stimulated extensive interest and in-depth research among major tobacco companies and individuals. At present, the existing atomization technology can produce better atomization effect, giving e-cigarette smokers the feeling of puffing, but compared with traditional cigarettes in terms of taste and aroma, it is not satisfactory. Improving the formula of e-cigarette liquid is the top priority of e-cigarette research at present, and it is the core technology for tobacco companies to gain a foothold and develop in the e-cigarette industry.
为了能在最大程度上模拟传统卷烟的香气、香味和口感，目前最为普遍的解决方案是在烟液中添加烟草提取物。烟草提取技术主要包括水蒸气蒸馏、溶剂萃取、同时蒸馏法、酶解萃取法、超临界萃取法、分子蒸馏法等不同手段组合提取烟草中致香成分。通过提取获得的烟草精油与雾化剂、烟用香精按一定配比混合得到电子烟烟液，但评吸结果表明通过这种途径获得的烟液虽然含有一定的烟草本香，但是口感和香味丰富程度与传统卷烟相比还有较大差距。究其原因可能是：一方面不同萃取手段萃取效率不一样，部分烟草致香成分无法较高效率的转移至萃取液中；另一方面，烟草未经燃烧过程，提取液中缺乏经过裂解产生的香气成分。为了进一步弥补烟草提取液的不足，寻找一种与烟草具有类似性质的植物，经过调香、配方改进，制备香气丰富且特征明显的电子烟烟液。In order to simulate the aroma, aroma and taste of traditional cigarettes to the greatest extent, the most common solution at present is to add tobacco extracts to the e-liquid. Tobacco extraction technology mainly includes steam distillation, solvent extraction, simultaneous distillation, enzymatic extraction, supercritical extraction, molecular distillation and other methods to extract aroma components in tobacco. Tobacco essential oil obtained by extraction is mixed with atomizer and tobacco essence in a certain proportion to obtain e-cigarette liquid, but the evaluation results show that although the e-liquid obtained through this method contains a certain amount of tobacco aroma, the taste and aroma are not Compared with traditional cigarettes, there is still a big gap in the richness. The reason may be: on the one hand, different extraction methods have different extraction efficiencies, and some tobacco aroma components cannot be transferred to the extract with high efficiency; on the other hand, the tobacco has not been burned, and the extract lacks cracking aroma components. In order to further make up for the shortage of tobacco extract, a plant with similar properties to tobacco was found, and after flavoring and formula improvement, an e-cigarette liquid with rich aroma and distinctive characteristics was prepared.
茶叶与烟草是现在人们生活不可或缺的两大类消费品。两者具有众多相似之处，如茶叶的香型与烟草类似，茶叶中含有的香味物质与烟草相似。同时，茶叶又含有自身特殊的致香和保健成分，如儿茶素、咖啡因、丰富的矿物质、维生素及其他有效成分黄酮醇类、皂素等。将烟草提取液与茶叶提取液按一定比例混合制备成电子烟液，不仅可以补充烟草香气浓度不足的缺点，使香气成分更加丰富；同时茶叶萃取液中含有许多有效成分可以缓解或抑制烟草带来的危害。据报道茶叶中茶多酚的应用研究已有很多方面，包括抗癌、抗氧化和延缓衰老、抗菌和抗病毒、降血脂、油脂抗氧化作用、色素保护作用、除臭剂、防龋作用、抑制动脉粥样硬化等多种功能。茶多酚已成为医药、食品界开发的热点。烟辛辣而又芬芳，茶津甜而又幽香，一起使用可相得益彰。Tea and tobacco are two major categories of consumer goods that are now indispensable to people's lives. The two have many similarities, such as the aroma of tea is similar to tobacco, and the aroma substances contained in tea are similar to tobacco. At the same time, tea contains its own special fragrance-causing and health-care ingredients, such as catechins, caffeine, rich minerals, vitamins, and other effective ingredients such as flavonols and saponins. Mixing tobacco extract and tea extract in a certain proportion to prepare e-cigarette liquid can not only make up for the shortcomings of insufficient tobacco aroma concentration, but also enrich the aroma components; at the same time, tea extract contains many active ingredients that can alleviate or inhibit tobacco. hazards. It is reported that the application research of tea polyphenols in tea has many aspects, including anti-cancer, anti-oxidation and anti-aging, anti-bacterial and anti-virus, lowering blood fat, anti-oxidation of oil, pigment protection, deodorant, anti-caries, Inhibition of atherosclerosis and other functions. Tea polyphenols have become a hot spot in the field of medicine and food. The smoke is spicy and fragrant, and the tea is sweet and fragrant, and they can complement each other when used together.
茶树因遗传特性、生长环境、地理状况及发酵过程等不同，使得茶叶中的化学成分及含量、茶叶品质和香型都存在一定差异。绿茶属不发酵茶，是以适宜茶树新梢为原料，经杀青、揉捻、干燥等典型工艺过程制成的茶叶。其干茶色泽和冲泡后的茶汤、叶底以绿色为主调，故名绿茶。绿茶较多的保留了鲜叶内的天然物质，其中茶多酚、咖啡碱保留鲜叶的85％以上，叶绿素保留50％左右，维生素损失也较少，从而形成了绿茶“清汤绿叶，滋味收敛性强”的特点。最新科学研究结果表明，绿茶中保留的天然物质成分，对防衰老、防癌、抗癌、杀菌、消炎等均有特殊效果，为其他茶类所不及。中国绿茶香高味长，品质优异，且造型独特，按其干燥和杀青方法的不同，一般分为炒青、烘青、晒青和蒸青绿茶。代表性的品类包括：西湖龙井、黄山毛峰、洞庭碧螺春、顾渚紫笋、桂平西山茶、太平猴魁、庐山云雾、六安瓜片、蒙顶茶、信阳毛尖、平水珠茶、雁荡毛峰、涌溪火青、都匀毛尖等。研究分析结果表明绿茶的主要香气成分为:芳樟醇及其氧化物、水杨酸甲酯、香叶醇、己酸-顺-3-乙己烯酯、丁香烯、法呢烯、橙花叔醇、茉莉酮酸甲酯、6,10,14-三甲基十五烷酮及邻苯二甲酸二丁酯等。Due to differences in genetic characteristics, growth environment, geographical conditions and fermentation process of tea trees, there are certain differences in the chemical composition and content of tea leaves, tea quality and aroma. Green tea is a non-fermented tea, which is made from suitable new shoots of tea trees through typical processes such as greening, rolling, and drying. Its dry tea color and brewed tea paste and the bottom of the leaves take green as the main tone, hence the name green tea. Green tea retains more natural substances in fresh leaves, among which tea polyphenols and caffeine retain more than 85% of fresh leaves, chlorophyll retains about 50%, and vitamin loss is less, thus forming green tea "clear soup and green leaves, with astringent taste". strong" feature. The latest scientific research results show that the natural substances retained in green tea have special effects on anti-aging, anti-cancer, anti-cancer, sterilization, anti-inflammatory, etc., which are beyond the reach of other teas. Chinese green tea has a high aroma, high quality, and unique shape. According to different drying and greening methods, it is generally divided into fried green tea, baked green tea, sun-dried green tea and steamed green tea. Representative categories include: West Lake Longjing, Huangshan Maofeng, Dongting Biluochun, Guzhu Zisun, Guiping Xishan Tea, Taiping Houkui, Lushan Yunwu, Lu'an Guapian, Mengding Tea, Xinyang Maojian, Pingshui Pearl Tea, Yandang Maofeng , Yongxi Huoqing, Duyun Maojian, etc. The results of research and analysis show that the main aroma components of green tea are: linalool and its oxides, methyl salicylate, geraniol, hexanoic acid-cis-3-ethylhexyl ester, clovene, farnesene, tertiary neroli Alcohol, methyl jasmonate, 6,10,14-trimethylpentadecanone and dibutyl phthalate, etc.
发明内容Contents of the invention
本发明的目的在于一种利用绿茶茶叶提取物制备的电子烟烟液，以改善现有电子烟烟液口感不佳，香气不足等缺点。通过超临界萃取提取不同品种的绿茶茶叶，之后将其与对应的烟草提取物混合，辅以合适的烟用香精香料和雾化剂，可以制备得到香气丰富、口感舒适的电子烟烟液。The object of the present invention is an electronic cigarette liquid prepared by using green tea leaf extract, so as to improve the disadvantages of the existing electronic cigarette liquid such as poor taste and insufficient aroma. Different types of green tea leaves are extracted by supercritical extraction, and then mixed with corresponding tobacco extracts, supplemented with appropriate tobacco flavors and atomizers, and e-cigarette liquids with rich aroma and comfortable taste can be prepared.
本发明是通过以下技术方案实现的：The present invention is achieved through the following technical solutions:
一种利用绿茶茶叶提取物制备的电子烟烟液，包括以下重量份的原料组分：An electronic cigarette liquid prepared by using green tea leaf extract, comprising the following raw material components in parts by weight:
优选的，所述电子烟烟液，包括以下重量份的原料组分：Preferably, the e-cigarette liquid includes the following raw material components in parts by weight:
最优选的，所述电子烟烟液，包括以下重量份的原料组分：Most preferably, the e-cigarette liquid includes the following raw material components in parts by weight:
优选的，所述烟草提取物为清香型烤烟、马里兰烟或香料烟的一种或多种的烟叶经提取制得的浓缩液。Preferably, the tobacco extract is a concentrated liquid obtained by extracting one or more tobacco leaves of fresh-flavor flue-cured tobacco, Maryland tobacco or oriental tobacco.
优选的，所述烟草提取物的提取方法为：取烟叶干燥，冷却至室温，粉碎得烟末；取所得烟末，加提取溶剂进行超声萃取，然后静置沉降、过滤、浓缩即得烟草提取物。Preferably, the extraction method of the tobacco extract is as follows: take the tobacco leaves and dry them, cool them to room temperature, and pulverize them to obtain tobacco powder; take the obtained tobacco powder, add an extraction solvent for ultrasonic extraction, and then leave it to settle, filter, and concentrate to obtain the tobacco extract. thing.
优选的，所述干燥的温度是30～80℃，干燥的时间为1～9h。Preferably, the drying temperature is 30-80° C., and the drying time is 1-9 hours.
更优选的，所述干燥在40℃干燥3h。More preferably, the drying is performed at 40° C. for 3 hours.
优选的，所述烟末的平均粒径大小为40～100目；更优选为40～60目。Preferably, the average particle size of the tobacco powder is 40-100 mesh; more preferably 40-60 mesh.
优选的，所述提取溶剂为水或乙醇。Preferably, the extraction solvent is water or ethanol.
优选的，烟末和提取溶剂的料液质量比为1:2～5，更优选为1:2.5～3.5；最优选为1：3。Preferably, the mass ratio of the tobacco powder to the extraction solvent is 1:2-5, more preferably 1:2.5-3.5; most preferably 1:3.
优选的，所述超声萃取的温度为30～60℃，时间为2～5h；更优选的，超声萃取的温度为45～55℃，时间为3.5～4.5h。Preferably, the temperature of the ultrasonic extraction is 30-60°C, and the time is 2-5h; more preferably, the temperature of the ultrasonic extraction is 45-55°C, and the time is 3.5-4.5h.
优选的，所述静置沉降的时间为不少于4h。Preferably, the time for standing and settling is not less than 4 hours.
优选的，所述浓缩为在50～90℃条件下的减压浓缩，更优选为60～80℃。Preferably, the concentration is concentration under reduced pressure at 50-90°C, more preferably at 60-80°C.
优选的，所述烟草提取物的制备方法为：取烤烟烟叶在40℃烘箱中干燥3h，冷却至室温后，粉碎，得40～100目烤烟烟末；称取100g烟末，加入300mL去离子水，于45～55℃条件下超声提取4h，之后静置沉降4h，砂芯漏斗过滤得滤液，60～80℃减压旋蒸浓缩至3mL，即得烟草提取物。Preferably, the preparation method of the tobacco extract is as follows: take flue-cured tobacco leaves and dry them in an oven at 40°C for 3 hours, cool to room temperature, and then pulverize them to obtain 40-100 mesh flue-cured tobacco powder; weigh 100g of tobacco powder, add 300mL of deionized Water, ultrasonically extracted at 45-55°C for 4 hours, then left to settle for 4 hours, filtered through a sand core funnel to obtain the filtrate, concentrated to 3 mL by rotary evaporation at 60-80°C to obtain tobacco extract.
优选的，所述烟用香精选自乙基香兰素、乙酸苄酯、糠醛、β-大马酮、β-二氢大马酮、巨豆三烯酮、二氢猕猴桃内酯、丁二酸二甲酯、2，6，6-三甲基-2-环己烯-1，4-二酮、2-羟基-3，5，5-三甲基-2-环己烯酮、香叶基丙酮、β-紫罗兰酮、苯甲醇、棕榈酸、异戊酸、2-甲基戊酸、吲哚、吡啶、3-乙酰基吡啶、2，3，5-三甲基吡嗪中的一种或多种的组合。Preferably, the incense for tobacco is selected from ethyl vanillin, benzyl acetate, furfural, β-damascenone, β-dihydrodamascenone, macrostigmatrienone, dihydroactinolactone, butyl Dimethyl diacid, 2,6,6-trimethyl-2-cyclohexene-1,4-dione, 2-hydroxy-3,5,5-trimethyl-2-cyclohexenone, Geranyl acetone, β-ionone, benzyl alcohol, palmitic acid, isovaleric acid, 2-methylpentanoic acid, indole, pyridine, 3-acetylpyridine, 2,3,5-trimethylpyrazine one or a combination of more.
优选的，以烟用香精总重为100％计，所述烟用香精为以下几种配方(重量百分比)：Preferably, based on the total weight of the tobacco flavor as 100%, the tobacco flavor has the following formulations (percentage by weight):
配方一：8％β-大马酮、5％β-二氢大马酮、13％巨豆三烯酮、24％β-紫罗兰酮、9％乙基香兰素、7％乙酸苄酯、5％糠醛、5％苯甲醇、4％棕榈酸、12％二氢猕猴桃内酯、8％丁二酸二甲酯。将上述组分在漩涡振荡器上混合均匀既得。Formula 1: 8% β-Damascenone, 5% β-Damascenone, 13% macrostigmatrienone, 24% β-ionone, 9% ethyl vanillin, 7% benzyl acetate, 5% Furfural, 5% Benzyl Alcohol, 4% Palmitic Acid, 12% Dihydroactinolactone, 8% Dimethyl Succinate. Mix the above components uniformly on a vortex shaker.
配方二：15％β-大马酮、3％吲哚、15％巨豆三烯酮、5％2，3，5-三甲基吡嗪、8％乙基香兰素、4％棕榈酸、9％二氢猕猴桃内酯、2％丁二酸二甲酯、15％香叶基丙酮、9％β-紫罗兰酮、15％苯甲醇。将上述组分在漩涡振荡器上混合均匀。Formula 2: 15% β-Damascenone, 3% indole, 15% macrostigmatrienone, 5% 2,3,5-trimethylpyrazine, 8% ethyl vanillin, 4% palmitic acid , 9% dihydroactinolactone, 2% dimethyl succinate, 15% geranyl acetone, 9% β-ionone, 15% benzyl alcohol. Mix the above components homogeneously on a vortex shaker.
优选的，所述绿茶茶叶提取物为西湖龙井、碧螺春、黄山毛峰、庐山云雾、湄潭翠芽、蒙顶甘露、竹叶青、信阳毛尖、六安瓜片、雁荡毛峰、涌溪火青、平水珠茶、顾渚紫笋、桂平西山茶、恩施玉露、都匀毛尖和太平猴魁等绿茶茶叶的一种或多种的提取物。Preferably, the green tea extracts are West Lake Longjing, Biluochun, Huangshan Maofeng, Lushan Yunwu, Meitan Cuiya, Mengding Ganlu, Zhuyeqing, Xinyang Maojian, Lu'an Guapian, Yandang Maofeng, Yongxi Huoqing, Pingshui One or more extracts of green tea leaves such as pearl tea, Guzhu purple bamboo shoots, Guiping Xishan tea, Enshi Yulu, Duyun Maojian and Taiping Houkui.
优选的，所述绿茶茶叶提取物的提取方法为：取绿茶茶叶干燥后粉碎，然后进行超临界萃取获得绿茶茶叶提取物。Preferably, the extraction method of the green tea leaf extract is as follows: the green tea leaves are dried, crushed, and then subjected to supercritical extraction to obtain the green tea leaf extract.
优选的，所述绿茶茶叶提取物的提取方法为：取绿茶茶叶干燥后粉碎，绿茶然后进行超临界CO2萃取获得绿茶茶叶提取物。Preferably, the extraction method of the green tea leaf extract is as follows: the green tea leaves are dried and crushed, and the green tea is then subjected to supercritical CO2 extraction to obtain the green tea leaf extract.
优选的，干燥后茶叶水分重量百分比小于20％，更优的干燥后茶叶水分重量百分比小于10％；Preferably, the water weight percentage of the dried tea leaves is less than 20%, more preferably the water weight percentage of the dried tea leaves is less than 10%;
优选的，所述绿茶茶叶粉碎粒度为10～70目，更优选为25目。Preferably, the crushed particle size of the green tea leaves is 10-70 mesh, more preferably 25 mesh.
优选的，所述超临界CO2萃取的萃取压力为10～50MPa；更优选的萃取压力为25MPa。Preferably, the extraction pressure of the supercritical CO2 extraction is 10-50 MPa; more preferably, the extraction pressure is 25 MPa.
优选的，所述超临界CO2萃取的萃取温度为10～60℃；更优的萃取温度为45℃。Preferably, the extraction temperature of the supercritical CO2 extraction is 10-60°C; a more optimal extraction temperature is 45°C.
优选的，所述超临界CO2萃取的萃取时间为1～10h；更优选的萃取时间为3h。Preferably, the extraction time of the supercritical CO2 extraction is 1-10 h; more preferably, the extraction time is 3 h.
本发明对所述电子烟烟液的制备方法没有特殊的限制，可直接将各个组分按设定比例混合均匀即既得。The present invention has no special limitation on the preparation method of the e-cigarette liquid, and the components can be directly mixed evenly according to the set ratio.
本发明还公开了前述电子烟烟液在制备电子烟中的应用。The present invention also discloses the application of the aforementioned electronic cigarette liquid in the preparation of electronic cigarettes.
与现有技术相比，本发明具有以下有益效果：Compared with the prior art, the present invention has the following beneficial effects:
(1)本发明利用超临界二氧化碳提取手段得到绿茶茶叶的精油成分，最大程度的保持了绿茶本香。(1) The present invention utilizes supercritical carbon dioxide extraction means to obtain the essential oil components of green tea leaves, which keeps the original fragrance of green tea to the greatest extent.
(2)本发明通过将绿茶提取液与烟草提取液混合，使得电子烟烟液香气更加丰富，香味更加协调，在一定程度上解决了电子烟烟液香气和口味不足的缺点。(2) The invention mixes the green tea extract with the tobacco extract to make the e-cigarette liquid richer in aroma and more harmonious in aroma, and to a certain extent solves the shortcomings of insufficient aroma and taste of the e-cigarette liquid.
(3)本发明电子烟烟液由于采取雾化方式生成烟雾感觉，不产生焦油和CO，同时不产生二手烟危害。(3) The e-cigarette liquid of the present invention does not produce tar and CO, and does not produce second-hand smoke hazards because it adopts an atomization method to generate a smog sensation.
(4)本发明电子雾化剂添加含多种有效成分的绿茶茶叶精油，具有防衰老、防癌、抗癌、杀菌、消炎等均有特殊效果。(4) The electronic atomizer of the present invention is added with green tea leaf essential oil containing various active ingredients, and has special effects such as anti-aging, anti-cancer, anti-cancer, sterilization, and anti-inflammatory.
(5)本发明提供的电子烟液中的溶剂和烟用香精均为食品级，对吸食者无害。(5) The solvent and tobacco essence in the electronic cigarette liquid provided by the present invention are both food grade and harmless to smokers.
具体实施方式Detailed ways
以下通过特定的具体实例说明本发明的技术方案。应理解，本发明提到的一个或多个方法步骤并不排斥在所述组合步骤前后还存在其他方法步骤或在这些明确提到的步骤之间还可以插入其他方法步骤；还应理解，这些实施例仅用于说明本发明而不用于限制本发明的范围。而且，除非另有说明，各方法步骤的编号仅为鉴别各方法步骤的便利工具，而非为限制各方法步骤的排列次序或限定本发明可实施的范围，其相对关系的改变或调整，在无实质变更技术内容的情况下，当亦视为本发明可实施的范畴。The technical solutions of the present invention are illustrated below through specific examples. It should be understood that one or more method steps mentioned in the present invention do not exclude that there are other method steps before and after the combined steps or other method steps can be inserted between these explicitly mentioned steps; it should also be understood that these The examples are only for illustrating the present invention and are not intended to limit the scope of the present invention. Moreover, unless otherwise stated, the numbering of each method step is only a convenient tool for identifying each method step, and is not intended to limit the sequence of each method step or limit the scope of the present invention. The change or adjustment of its relative relationship is in In the case of no substantive change in the technical content, it shall also be regarded as the applicable scope of the present invention.
实施例1Example 1
制备烟草提取物：取清香型烤烟样品在40℃烘箱中干燥3h，冷却至室温后，粉碎至40～100目。称取100g烟末置于1L的锥形瓶中，加入300mL去离子水，于50±5℃条件下超声萃取4h，之后静置沉降4h，砂芯漏斗过滤得滤液，70±10℃减压旋蒸浓缩至3mL，即得烟草提取物。Tobacco extract preparation: Take a sample of fresh-flavor flue-cured tobacco and dry it in an oven at 40°C for 3 hours, cool it down to room temperature, and crush it to 40-100 mesh. Weigh 100g of tobacco powder into a 1L Erlenmeyer flask, add 300mL of deionized water, conduct ultrasonic extraction at 50±5°C for 4 hours, then let it settle for 4 hours, filter it with a sand core funnel to obtain the filtrate, and depressurize at 70±10°C Concentrate to 3mL by rotary evaporation to obtain tobacco extract.
制备西湖龙井茶叶提取物：称西湖龙井茶叶100g，干燥至含水量为8％，经粉碎机磨碎为20-30目粉末，装入1L的萃取釜中，控制萃取压力为25MPa，萃取温度为50℃，调节超临界CO2的流量为25L/h，萃取时间为3h。经萃取后溶解有提取物的超临界流体通过节流阀减压，进入分离釜中变为气体，提取物在分离釜中析出，收集于接收瓶中即得西湖龙井茶叶提取物。Preparation of West Lake Longjing tea extract: weigh 100g of West Lake Longjing tea leaves, dry to 8% water content, grind to 20-30 mesh powder through a pulverizer, put into a 1L extraction kettle, control the extraction pressure to be 25MPa, and the extraction temperature is 50°C, adjust the flow rate of supercritical CO2 to 25L/h, and the extraction time to 3h. After extraction, the supercritical fluid in which the extract is dissolved is decompressed through the throttle valve, and enters the separation kettle to become a gas. The extract is precipitated in the separation kettle and collected in the receiving bottle to obtain the West Lake Longjing tea extract.
制备电子烟烟液：取以下重量份的组分：烟草提取物18份，烟用香精8份，西湖龙井茶叶提取物18份，甘油20份，食用酒精3份，丙二醇70份。将各组分漩涡振荡器上混合均匀即得电子烟烟液。Preparation of e-cigarette liquid: take the following components in parts by weight: 18 parts of tobacco extract, 8 parts of tobacco essence, 18 parts of West Lake Longjing tea extract, 20 parts of glycerin, 3 parts of edible alcohol, and 70 parts of propylene glycol. Mix the components evenly on a vortex oscillator to obtain the e-cigarette liquid.
其中，以烟用香精总重为100％计，烟用香精配方为：8％β-大马酮、5％β-二氢大马酮、13％巨豆三烯酮、24％β-紫罗兰酮、9％乙基香兰素、7％乙酸苄酯、5％糠醛、5％苯甲醇、4％棕榈酸、12％二氢猕猴桃内酯、8％丁二酸二甲酯。将上述组分在漩涡振荡器上混合均匀既得。Among them, based on the total weight of the tobacco flavor as 100%, the formula of the tobacco flavor is: 8% β-Damascenone, 5% β-Damascenone, 13% macrostigmatrienone, 24% β-violet Ketones, 9% ethyl vanillin, 7% benzyl acetate, 5% furfural, 5% benzyl alcohol, 4% palmitic acid, 12% dihydroactinolactone, 8% dimethyl succinate. Mix the above components uniformly on a vortex shaker.
将得到的电子烟烟液进行评吸，结果如表2所示。The obtained e-cigarette liquid was smoked, and the results are shown in Table 2.
实施例2Example 2
制备烟草提取物：取马里兰烟烟叶样品在40℃烘箱中干燥3h，冷却至室温后，粉碎至40～100目。称取100g烟末置于1L的锥形瓶中，加入300mL乙醇，于50±5℃条件下超声提取4h，之后静置沉降4h，砂芯漏斗过滤得滤液，70±10℃减压旋蒸浓缩至3mL，即得烟草提取物。Tobacco extract preparation: Maryland tobacco leaf samples were dried in an oven at 40°C for 3 hours, cooled to room temperature, and crushed to 40-100 mesh. Weigh 100g of tobacco powder and place it in a 1L Erlenmeyer flask, add 300mL of ethanol, ultrasonically extract at 50±5°C for 4h, then let it settle for 4h, filter it with a sand core funnel to obtain the filtrate, and rotate it under reduced pressure at 70±10°C Concentrate to 3mL to obtain the tobacco extract.
制备碧螺春茶叶提取物：称取碧螺春茶叶100g，干燥至含水量为5％，经粉碎机磨碎为20-30目粉末，装入1L的萃取釜中，控制萃取压力为25MPa，萃取温度为50℃，调节超临界CO2的流量为25L/h，萃取时间为3h。经萃取后溶解有提取物的超临界流体通过节流阀减压，进入分离釜中变为气体，提取物在分离釜中析出，收集于接收瓶中即得碧螺春茶叶提取物。Preparation of Biluochun tea extract: Weigh 100g of Biluochun tea leaves, dry to a water content of 5%, grind them into 20-30 mesh powder through a pulverizer, put them into a 1L extraction kettle, control the extraction pressure to 25MPa, and the extraction temperature to 50 °C, adjust the flow rate of supercritical CO2 to 25L/h, and the extraction time to 3h. After extraction, the supercritical fluid in which the extract is dissolved is decompressed through the throttle valve, and enters the separation kettle to become a gas. The extract is precipitated in the separation kettle and collected in the receiving bottle to obtain the Biluochun tea extract.
制备电子烟烟液，取以下重量份的组分：烟草提取物5份，烟用香精10份，碧螺春茶叶提取物25份，食用甘油25份，食用酒精2份，丙二醇60份。将各组分漩涡振荡器上混合均匀即得电子烟烟液。To prepare e-cigarette liquid, take the following components by weight: 5 parts of tobacco extract, 10 parts of tobacco essence, 25 parts of Biluochun tea extract, 25 parts of edible glycerin, 2 parts of edible alcohol, and 60 parts of propylene glycol. Mix the components evenly on a vortex oscillator to obtain the e-cigarette liquid.
其中，以烟用香精总重100％计，烟用香精配方为：15％β-大马酮、3％吲哚、15％巨豆三烯酮、5％2，3，5-三甲基吡嗪、8％乙基香兰素、4％棕榈酸、9％二氢猕猴桃内酯、2％丁二酸二甲酯、15％香叶基丙酮、9％β-紫罗兰酮、15％苯甲醇；将上述组分在漩涡振荡器上混合均匀。Among them, based on 100% of the total weight of tobacco flavor, the formula of tobacco flavor is: 15% β-damascenone, 3% indole, 15% macrostigmatrienone, 5% 2,3,5-trimethyl Pyrazine, 8% ethyl vanillin, 4% palmitic acid, 9% dihydroactinolactone, 2% dimethyl succinate, 15% geranyl acetone, 9% beta-ionone, 15% benzene Methanol; mix the above components homogeneously on a vortex shaker.
将得到的电子烟烟液进行评吸，结果如表2所示。The obtained e-cigarette liquid was smoked, and the results are shown in Table 2.
实施例3Example 3
制备烟草提取物：取香料烟烟叶样品在40℃烘箱中干燥3h，冷却至室温后，粉碎至40～100目的烟末。称取100g烟末置于1L的锥形瓶中，加入300mL去离子水，于50±5℃条件下超声提取4h，之后静置沉降4h，砂芯漏斗过滤得滤液，减压旋蒸浓缩至3mL，即得烟草提取物。Tobacco extract preparation: oriental tobacco leaf samples were dried in an oven at 40° C. for 3 hours, cooled to room temperature, and crushed to 40-100 mesh tobacco powder. Weigh 100g of tobacco powder and place it in a 1L Erlenmeyer flask, add 300mL of deionized water, conduct ultrasonic extraction at 50±5°C for 4 hours, then let it settle for 4 hours, filter through a sand core funnel to obtain the filtrate, and concentrate it by rotary evaporation under reduced pressure to 3mL to obtain the tobacco extract.
制备信阳毛尖和都匀毛尖茶叶提取物：称取信阳毛尖50g、都匀毛尖茶叶50g，干燥至含水量为15％，经粉碎机磨碎为20-30目粉末，装入1L的萃取釜中，控制萃取压力为25MPa，萃取温度为50℃，调节超临界CO2的流量为25L/h，萃取时间为3h。经萃取后溶解有提取物的超临界流体通过节流阀减压，进入分离釜中变为气体，提取物在分离釜中析出，收集于接收瓶中即得信阳毛尖和都匀毛尖茶叶提取物。Preparation of Xinyang Maojian and Duyun Maojian tea extracts: Weigh 50g of Xinyang Maojian and 50g of Duyun Maojian tea leaves, dry them until the water content is 15%, grind them into 20-30 mesh powders with a grinder, and put them into a 1L extraction kettle , control the extraction pressure to 25MPa, the extraction temperature to 50°C, adjust the flow rate of supercritical CO2 to 25L/h, and the extraction time to 3h. After extraction, the supercritical fluid in which the extract is dissolved is decompressed through the throttle valve and enters the separation kettle to become a gas. The extract is precipitated in the separation kettle and collected in the receiving bottle to obtain Xinyang Maojian and Duyun Maojian tea extracts. .
本实施例中的电子烟烟液的组成及各组分重量百分比为：烟草提取物25份，烟用香精3份，信阳毛尖和都匀毛尖茶叶提取物7份，甘油10份，食用酒精4份，丙二醇75份。将各组分漩涡振荡器上混合均匀即得电子烟烟液。The composition and weight percentage of the e-cigarette liquid in this example are: 25 parts of tobacco extract, 3 parts of tobacco essence, 7 parts of Xinyang Maojian and Duyun Maojian tea extracts, 10 parts of glycerin, 4 parts of edible alcohol Parts, 75 parts of propylene glycol. Mix the components evenly on a vortex oscillator to obtain the e-cigarette liquid.
其中，烟用香精配方同实施例2。Wherein, the essence formula for tobacco is the same as that in Example 2.
将得到的电子烟烟液进行评吸，结果如表2所示。The obtained e-cigarette liquid was smoked, and the results are shown in Table 2.
实施例4Example 4
制备烟草提取物：取质量比为1:1的烤烟和香料烟烟叶样品在40℃烘箱中干燥3h，冷却至室温后，粉碎至40～100目的烟末。称取100g烟末置于1L的锥形瓶中，加入300mL去离子水，于50±5℃条件下超声提取4h，之后静置沉降4h，砂芯漏斗过滤得滤液，减压旋蒸浓缩至3mL，即得烟草提取物。Tobacco extract preparation: Take flue-cured tobacco and oriental tobacco leaf samples with a mass ratio of 1:1, dry them in an oven at 40°C for 3 hours, cool to room temperature, and grind them to 40-100 mesh tobacco powder. Weigh 100g of tobacco powder and place it in a 1L Erlenmeyer flask, add 300mL of deionized water, conduct ultrasonic extraction at 50±5°C for 4 hours, then let it settle for 4 hours, filter through a sand core funnel to obtain the filtrate, and concentrate it by rotary evaporation under reduced pressure to 3mL to obtain the tobacco extract.
制备黄山毛峰茶叶提取物：称取黄山毛峰茶叶100g，干燥至含水量为5％，经粉碎机磨碎为20-30目粉末，装入1L的萃取釜中，控制萃取压力为25MPa，萃取温度为50℃，调节超临界CO2的流量为25L/h，萃取时间为3h。经萃取后溶解有提取物的超临界流体通过节流阀减压，进入分离釜中变为气体，提取物在分离釜中析出，收集于接收瓶中即得黄山毛峰茶叶提取物。Preparation of Huangshan Maofeng tea extract: Weigh 100g of Huangshan Maofeng tea leaves, dry to a water content of 5%, grind to 20-30 mesh powder through a pulverizer, put into a 1L extraction kettle, control the extraction pressure to 25MPa, The extraction temperature was 50°C, the flow rate of supercritical CO2 was adjusted to 25L/h, and the extraction time was 3h. After extraction, the supercritical fluid in which the extract is dissolved is decompressed through the throttle valve, and enters the separation kettle to become gas, and the extract is precipitated in the separation kettle, and collected in the receiving bottle to obtain the Huangshan Maofeng tea extract.
制备电子烟烟液，取以下重量份的组分：烟草提取物2份，烟用香精8份，黄山毛峰茶叶提取物30份，甘油30份，食用酒精5份，丙二醇50份。将各组分漩涡振荡器上混合均匀即得电子烟烟液。To prepare e-cigarette liquid, take the following components by weight: 2 parts of tobacco extract, 8 parts of tobacco essence, 30 parts of Huangshan Maofeng tea extract, 30 parts of glycerin, 5 parts of edible alcohol, and 50 parts of propylene glycol. Mix the components evenly on a vortex oscillator to obtain the e-cigarette liquid.
其中，烟用香精配方同实施例1。Wherein, the formula of flavoring essence for tobacco is the same as that in Example 1.
将制得的电子烟烟液进行评吸，评吸效果见表2。The prepared e-cigarette liquid was smoked, and the smoking effect is shown in Table 2.
实施例5Example 5
本实施例中的电子烟烟液包括以下重量份的组分：烟草提取物30份，烟用香精1份，太平猴魁茶叶提取物2份，甘油5份，食用酒精5份，丙二醇80份。The e-cigarette liquid in this embodiment includes the following components by weight: 30 parts of tobacco extract, 1 part of tobacco essence, 2 parts of Taiping Houkui tea extract, 5 parts of glycerin, 5 parts of edible alcohol, and 80 parts of propylene glycol .
其中烟草提取物成分以及提取方式、烟用香精配方同实施例4。Wherein the components of the tobacco extract, the extraction method, and the formulation of the flavoring essence for tobacco are the same as those in Example 4.
制备太平猴魁茶叶提取物：称取太平猴魁茶叶100g，干燥至含水量为5％，经粉碎机磨碎为20-30目粉末，装入1L的萃取釜中，控制萃取压力为25MPa，萃取温度为50℃，调节超临界CO2的流量为25L/h，萃取时间为3h。经萃取后溶解有提取物的超临界流体通过节流阀减压，进入分离釜中变为气体，提取物在分离釜中析出，收集于接收瓶中即得太平猴魁茶叶提取物；Preparation of Taiping Houkui tea extract: Weigh 100g of Taiping Houkui tea leaves, dry to a water content of 5%, grind into 20-30 mesh powder by a pulverizer, put into a 1L extraction kettle, control the extraction pressure to 25MPa, The extraction temperature was 50°C, the flow rate of supercritical CO2 was adjusted to 25L/h, and the extraction time was 3h. After extraction, the supercritical fluid in which the extract is dissolved is decompressed through the throttle valve, and enters the separation kettle to become a gas, and the extract is precipitated in the separation kettle, and collected in the receiving bottle to obtain the Taiping Houkui tea extract;
将各组分漩涡振荡器上混合均匀即得电子烟烟液。Mix the components evenly on a vortex oscillator to obtain the e-cigarette liquid.
对比例1Comparative example 1
本实施例中的电子烟烟液包含以下重量份的组分：烟草提取物18份，西湖龙井茶叶提取物3份，甘油20份，食用酒精3份，丙二醇70份。The electronic cigarette liquid in this embodiment contains the following components in parts by weight: 18 parts of tobacco extract, 3 parts of West Lake Longjing tea extract, 20 parts of glycerin, 3 parts of edible alcohol, and 70 parts of propylene glycol.
其中烟草提取物成分以及提取方式、烟草提取物成分以及提取方式同实施例1。The components of the tobacco extract and the extraction method, the components of the tobacco extract and the extraction method are the same as in Example 1.
将各组分漩涡振荡器上混合均匀即得电子烟烟液。Mix the components evenly on a vortex oscillator to obtain the e-cigarette liquid.
本发明将得到的电子烟烟液进行评吸，结果如表2所示，表2为本发明实施例和对比例得到的电子烟烟液的评吸结果。In the present invention, the obtained e-cigarette liquid is evaluated and smoked, and the results are shown in Table 2. Table 2 shows the results of the e-cigarette liquid obtained in the examples and comparative examples of the present invention.
对比例2Comparative example 2
本实施例中电子烟烟液包含以下重量份的组分：西湖龙井茶叶提取物18份，烟用香精8份，甘油20份，食用酒精3份，丙二醇70份。The e-cigarette liquid in this embodiment contains the following components in parts by weight: 18 parts of West Lake Longjing tea extract, 8 parts of tobacco essence, 20 parts of glycerin, 3 parts of edible alcohol, and 70 parts of propylene glycol.
其中西湖龙井茶叶提取物成分以及提取方式、烟用香精配方同实施例1。Wherein the composition of the West Lake Longjing tea extract, the extraction method, and the formula of the essence for tobacco are the same as those in Example 1.
将各组分漩涡振荡器上混合均匀即得电子烟烟液。Mix the components evenly on a vortex oscillator to obtain the e-cigarette liquid.
将得到的电子烟烟液进行评吸，结果如表2所示。The obtained e-cigarette liquid was smoked, and the results are shown in Table 2.
对比例3Comparative example 3
本实施例电子烟烟液包含以下重量份的组分：烟草提取物18份，烟用香精8份，甘油20份，食用酒精3份，丙二醇70份。The electronic cigarette liquid in this embodiment contains the following components in parts by weight: 18 parts of tobacco extract, 8 parts of tobacco essence, 20 parts of glycerin, 3 parts of edible alcohol, and 70 parts of propylene glycol.
其中烟草提取物成分以及提取方式、茶叶提取物成分以及提取方式同实施例4。The components and extraction methods of the tobacco extract, and the components and extraction methods of the tea extract are the same as in Example 4.
将各组分漩涡振荡器上混合均匀即得电子烟烟液。Mix the components evenly on a vortex oscillator to obtain the e-cigarette liquid.
将得到的电子烟烟液进行评吸，结果如表2所示。The obtained e-cigarette liquid was smoked, and the results are shown in Table 2.
将上述实施例1-5和对比例1-3中的电子烟烟液液添加到电子烟装置中分别进行感官效果评价。The e-cigarette liquids in the above-mentioned Examples 1-5 and Comparative Examples 1-3 were added to the electronic cigarette device to evaluate the sensory effect respectively.
感官效果评价方法包括以下步骤：The sensory effect evaluation method includes the following steps:
(1)设置了9个评价指标，包括刺激性、满足感、浓度、舒适度、特征风格、烟草香、香气质、香气量和发烟量，并根据各项评价指标对电子烟烟液感官质量的不同影响程度赋予不同分值。(1) Set up 9 evaluation indicators, including irritation, satisfaction, concentration, comfort, characteristic style, tobacco fragrance, aroma quality, aroma volume and smoke volume, and evaluate the sensory characteristics of e-cigarette liquid according to each evaluation index. Different degrees of impact on quality are assigned different points.
所述刺激性是指：吸入电子烟烟液经雾化产生的烟气对感觉器官包括口腔、喉部和鼻腔产生的不舒适感受。The irritation refers to the discomfort caused by inhaling the smoke produced by atomization of e-cigarette liquid on sensory organs, including the mouth, throat and nasal cavity.
所述满足感是指：电子烟烟液经雾化产生的烟气劲头、浓度及香韵对感觉器官上产生的综合感受。The sense of satisfaction refers to the comprehensive experience on the sensory organs of the strength, concentration and fragrance of the smoke produced by the atomization of the e-cigarette liquid.
所述浓度是指：电子烟烟液经雾化产生的烟气刚吸入口时口腔充盈程度的感受。The concentration refers to the feeling of mouth fullness when the smoke generated by the atomization of the e-cigarette liquid is just sucked into the mouth.
所述舒适度是指：电子烟烟液经雾化产生的烟气经吸入口腔及呼出后对口腔舒适程度的影响。The comfort level refers to the effect on the comfort level of the oral cavity after inhalation and exhalation of the smoke generated by the atomization of the e-cigarette liquid.
所述特征风格是指：一种电子烟烟液在愉悦感上区别于其他同类电子烟烟液的感官主要差异表现。The characteristic style refers to: the main sensory difference performance of an e-cigarette liquid in terms of pleasure that is different from other similar e-cigarette liquids.
所述烟草香是指：评吸过程中感官感觉到烟草本香的气息。The tobacco fragrance refers to: the smell of the original fragrance of tobacco is felt by the senses during the smoking process.
所述香气质是指：评吸过程中通过嗅觉和味觉感觉到令人愉悦气息的优劣程度。The aroma quality refers to: the quality of the pleasant smell is felt through the sense of smell and taste during the evaluation process.
所述香气量是指：评吸过程中通过口腔和鼻腔衡量令人愉悦气息量的多少。The amount of aroma refers to the amount of pleasant breath measured through the oral cavity and nasal cavity during the inhalation process.
所述发烟量是指：电子烟烟液经雾化产生烟气量的多少。The amount of smoke generated refers to the amount of smoke produced by the e-cigarette liquid through atomization.
(2)设置9人的评吸员，每人一份电子烟烟液感官质量评价表，采用暗评的评分方式，采用整体循环评吸法，对电子烟烟液进行抽吸，依据表1中9个感官质量评价指标评分值的含义，采用百分制评分法对电子烟烟液的感官质量进行综合评分，各项评价指标按五分、十分制或十五分制评分。电子烟烟液评价指标的评分值的具体含义见下表1：(2) Set up 9 e-cigarette smokers, each with a sensory quality evaluation form for e-cigarette liquid, adopt the scoring method of dark evaluation, and use the overall cycle evaluation method to smoke e-cigarette liquid, according to Table 1 The meaning of the score values of the 9 sensory quality evaluation indicators, the sensory quality of the e-cigarette liquid is comprehensively scored using the 100-point scoring method, and each evaluation indicator is scored on a five-point, ten-point or fifteen-point system. The specific meaning of the score value of the e-cigarette liquid evaluation index is shown in the following table 1:
表1电子烟烟液感官质量评价指标的评分值含义表Table 1 Score value meaning table of sensory quality evaluation index of e-cigarette liquid
(3)评价方法：根据表1中的评价指标和评分值，评吸员应对各评价指标进行感官质量评价，并记录其评价结果，评分值的最小计分单位为0.5。(3) Evaluation method: According to the evaluation indicators and scoring values in Table 1, the appraisers should evaluate the sensory quality of each evaluation index and record the evaluation results. The minimum scoring unit of the scoring value is 0.5.
(4)结果统计：所有评吸员的感官质量评价结果中去掉一个最低分和一个最高分，计算剩下有效的单项评价指标评分的算术平均值，结果保留两位小数，最后电子烟烟液的感官质量评价综合评分是计算各单项指标评分的算术平均值之和，得到总分，结果保留一位小数。(4) Results statistics: remove the lowest score and the highest score from the sensory quality evaluation results of all reviewers, calculate the arithmetic mean of the remaining effective single evaluation index scores, keep the results to two decimal places, and finally e-cigarette liquid The comprehensive score of the sensory quality evaluation is the sum of the arithmetic mean of each individual index score to obtain the total score, and one decimal place is reserved for the result.
将实施例1-5中制备的含白茶茶叶提取物的电子烟烟液和对比例1-3中制备的电子烟烟液添加在电子烟中进行感官质量评价。具体评价结果见表2，表2中各项评价指标的评分为9位评吸员有效评分的算术平均分。The e-cigarette liquid containing white tea leaf extract prepared in Examples 1-5 and the e-cigarette liquid prepared in Comparative Examples 1-3 were added to the electronic cigarette for sensory quality evaluation. The specific evaluation results are shown in Table 2. The scores of each evaluation index in Table 2 are the arithmetic mean scores of the effective scores of 9 reviewers.
表2电子烟烟液感官效果评价结果Table 2 Evaluation results of sensory effect of e-cigarette liquid
表2结果表明，上述实施例中电子烟烟液具体表现为抽吸时雾气浓厚，香气丰富，烟气清香，口感醇和，烟茶香协调，劲头适中，无明显刺激性。但所使用的茶叶类型、烟叶类型、提取物添加比例、烟用香精香料添加比例对所采用的9项指标产生不同影响；所用茶叶提取物还有保健之功效。The results in Table 2 show that the e-cigarette liquid in the above examples is characterized by thick mist, rich aroma, clear smoke, mellow taste, harmonious smoke and tea aroma, moderate strength, and no obvious irritation when inhaled. However, the type of tea leaves used, the type of tobacco leaves, the proportion of extracts added, and the proportions of tobacco flavors and fragrances used have different effects on the 9 indicators used; the tea extracts used also have health benefits.
以上所述，仅为本发明的较佳实施例，上述实施例仅例示性说明本发明的原理及其功效，而并非对本发明任何形式上和实质上的限制，应当指出，对于本技术领域的普通技术人员，在不脱离本发明方法的前提下，还将可以做出若干改进和补充，这些改进和补充也应视为本发明的保护范围。凡熟悉本专业的技术人员，在不脱离本发明的精神和范围的情况下，当可利用以上所揭示的技术内容而做出的些许更动、修饰与演变的等同变化，均为本发明的等效实施例；同时，凡依据本发明的实质技术对上述实施例所作的任何等同变化的更动、修饰与演变，均仍属于本发明的技术方案的范围内。The above is only a preferred embodiment of the present invention, and the above-described embodiment only illustrates the principle of the present invention and its effect, but is not any formal and substantial limitation of the present invention. It should be pointed out that for those in the technical field Those skilled in the art will be able to make some improvements and supplements without departing from the method of the present invention, and these improvements and supplements should also be regarded as the protection scope of the present invention. Those who are familiar with this field, without departing from the spirit and scope of the present invention, when they can use the technical content disclosed above to make some changes, modifications and equivalent changes of evolution, are all included in the present invention. Equivalent embodiments; at the same time, all changes, modifications and evolutions of any equivalent changes made to the above-mentioned embodiments according to the substantive technology of the present invention still belong to the scope of the technical solution of the present invention.
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410848828.2ACN104544549A (en) | 2014-12-31 | 2014-12-31 | Electronic cigarette smoke solution prepared through green tea leaf extract |
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410848828.2ACN104544549A (en) | 2014-12-31 | 2014-12-31 | Electronic cigarette smoke solution prepared through green tea leaf extract |
| Publication Number | Publication Date |
|---|---|
| CN104544549Atrue CN104544549A (en) | 2015-04-29 |
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410848828.2APendingCN104544549A (en) | 2014-12-31 | 2014-12-31 | Electronic cigarette smoke solution prepared through green tea leaf extract |
| Country | Link |
|---|---|
| CN (1) | CN104544549A (en) |
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038983A (en)* | 2015-06-17 | 2015-11-11 | 云南中烟工业有限责任公司 | Glycerol triacetate extract of Zimbabwe tobacco and application thereof to cigarettes |
| CN105559136A (en)* | 2015-12-30 | 2016-05-11 | 立场电子科技发展（上海）有限公司 | Method for preparing electronic cigarette juice fragrance from green tea enzyme |
| CN106037012A (en)* | 2016-07-18 | 2016-10-26 | 福建中烟工业有限责任公司 | Electronic cigarette liquid |
| CN106398867A (en)* | 2016-09-27 | 2017-02-15 | 湖北中烟工业有限责任公司 | Preparation method of Maryland tobacco extract and application thereof to cigarettes |
| CN110419765A (en)* | 2019-08-12 | 2019-11-08 | 四川三联新材料有限公司 | A kind of preparation method and preparation facilities of electronic cigarette tobacco tar |
| CN110819461A (en)* | 2019-11-27 | 2020-02-21 | 安徽香杰香精科技有限公司 | Method for extracting cool fragrant liquid |
| CN110952374A (en)* | 2018-09-27 | 2020-04-03 | 浙江中烟工业有限责任公司 | A kind of green tea fragrant cigarette paper without industrial preservatives and preparation method thereof |
| CN111671133A (en)* | 2020-06-22 | 2020-09-18 | 福建中烟工业有限责任公司 | A tea-flavored flue-cured tobacco-flavored electronic cigarette liquid |
| WO2021046923A1 (en)* | 2019-09-12 | 2021-03-18 | 深圳雾芯科技有限公司 | Flavor composition and e-cigarette liquid comprising same |
| CN115153081A (en)* | 2022-06-28 | 2022-10-11 | 深圳市艾普生物科技有限公司 | Herbal atomized liquid and preparation method thereof |
| CN117461876A (en)* | 2022-07-20 | 2024-01-30 | 比亚迪精密制造有限公司 | Electronic cigarette oil and preparation method thereof, electronic cigarette |
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11225731A (en)* | 1998-02-12 | 1999-08-24 | Japan Tobacco Inc | Improving agent for aroma and smoking taste of tobacco and improvement of the same |
| WO2002091866A1 (en)* | 2001-05-11 | 2002-11-21 | Thione International, Inc. | Glutathione, green tea, grape seed extract to neutralize tobacco free radicals |
| CN1994159A (en)* | 2006-12-15 | 2007-07-11 | 姜志荣 | Kidney-strengthening mind-refreshing tobacco liquid for electronic atomized cigarette |
| KR20120083738A (en)* | 2011-01-18 | 2012-07-26 | 주식회사태창물산 | Capsule containing extract of persimmon |
| CN102674628A (en)* | 2012-05-03 | 2012-09-19 | 波鹰(厦门)科技有限公司 | Sewage treatment and regeneration cyclic utilization device and sewage treatment and regeneration cyclic utilization method |
| CN102813278A (en)* | 2012-08-09 | 2012-12-12 | 深圳瀚星翔科技有限公司 | Mixed electronic cigarette tobacco liquid |
| CN102960852A (en)* | 2012-11-14 | 2013-03-13 | 湖北中烟工业有限责任公司 | Light-fragrance electronic cigarette atomized smoke solution and preparation method thereof |
| CN103932404A (en)* | 2014-04-15 | 2014-07-23 | 上海聚华科技股份有限公司 | Electronic cigarette with ultrasonic atomization function and tobacco liquid |
| CN103989244A (en)* | 2014-06-06 | 2014-08-20 | 山东中烟工业有限责任公司 | Chinese style flue-cured tobacco odor type electronic cigarette tobacco juice capable of improving smoking satisfaction sense |
| CN104068467A (en)* | 2014-07-01 | 2014-10-01 | 安徽中烟工业有限责任公司 | Electronic cigarette liquid rich in plant flavone |
| EP2818059A1 (en)* | 2012-02-24 | 2014-12-31 | Japan Tobacco Inc. | Manufacturing method for chewing tobacco material, and chewing tobacco material |
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11225731A (en)* | 1998-02-12 | 1999-08-24 | Japan Tobacco Inc | Improving agent for aroma and smoking taste of tobacco and improvement of the same |
| WO2002091866A1 (en)* | 2001-05-11 | 2002-11-21 | Thione International, Inc. | Glutathione, green tea, grape seed extract to neutralize tobacco free radicals |
| CN1994159A (en)* | 2006-12-15 | 2007-07-11 | 姜志荣 | Kidney-strengthening mind-refreshing tobacco liquid for electronic atomized cigarette |
| KR20120083738A (en)* | 2011-01-18 | 2012-07-26 | 주식회사태창물산 | Capsule containing extract of persimmon |
| EP2818059A1 (en)* | 2012-02-24 | 2014-12-31 | Japan Tobacco Inc. | Manufacturing method for chewing tobacco material, and chewing tobacco material |
| CN102674628A (en)* | 2012-05-03 | 2012-09-19 | 波鹰(厦门)科技有限公司 | Sewage treatment and regeneration cyclic utilization device and sewage treatment and regeneration cyclic utilization method |
| CN102813278A (en)* | 2012-08-09 | 2012-12-12 | 深圳瀚星翔科技有限公司 | Mixed electronic cigarette tobacco liquid |
| CN102960852A (en)* | 2012-11-14 | 2013-03-13 | 湖北中烟工业有限责任公司 | Light-fragrance electronic cigarette atomized smoke solution and preparation method thereof |
| CN103932404A (en)* | 2014-04-15 | 2014-07-23 | 上海聚华科技股份有限公司 | Electronic cigarette with ultrasonic atomization function and tobacco liquid |
| CN103989244A (en)* | 2014-06-06 | 2014-08-20 | 山东中烟工业有限责任公司 | Chinese style flue-cured tobacco odor type electronic cigarette tobacco juice capable of improving smoking satisfaction sense |
| CN104068467A (en)* | 2014-07-01 | 2014-10-01 | 安徽中烟工业有限责任公司 | Electronic cigarette liquid rich in plant flavone |
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038983A (en)* | 2015-06-17 | 2015-11-11 | 云南中烟工业有限责任公司 | Glycerol triacetate extract of Zimbabwe tobacco and application thereof to cigarettes |
| CN105559136A (en)* | 2015-12-30 | 2016-05-11 | 立场电子科技发展（上海）有限公司 | Method for preparing electronic cigarette juice fragrance from green tea enzyme |
| CN106037012A (en)* | 2016-07-18 | 2016-10-26 | 福建中烟工业有限责任公司 | Electronic cigarette liquid |
| CN106037012B (en)* | 2016-07-18 | 2019-03-15 | 福建中烟工业有限责任公司 | An electronic cigarette liquid |
| CN106398867A (en)* | 2016-09-27 | 2017-02-15 | 湖北中烟工业有限责任公司 | Preparation method of Maryland tobacco extract and application thereof to cigarettes |
| CN110952374B (en)* | 2018-09-27 | 2022-07-01 | 浙江中烟工业有限责任公司 | A kind of green tea fragrant cigarette paper without industrial preservatives and preparation method thereof |
| CN110952374A (en)* | 2018-09-27 | 2020-04-03 | 浙江中烟工业有限责任公司 | A kind of green tea fragrant cigarette paper without industrial preservatives and preparation method thereof |
| CN110419765A (en)* | 2019-08-12 | 2019-11-08 | 四川三联新材料有限公司 | A kind of preparation method and preparation facilities of electronic cigarette tobacco tar |
| CN110419765B (en)* | 2019-08-12 | 2022-04-19 | 四川三联新材料有限公司 | Preparation method and preparation device of electronic cigarette tobacco tar |
| WO2021046923A1 (en)* | 2019-09-12 | 2021-03-18 | 深圳雾芯科技有限公司 | Flavor composition and e-cigarette liquid comprising same |
| CN110819461A (en)* | 2019-11-27 | 2020-02-21 | 安徽香杰香精科技有限公司 | Method for extracting cool fragrant liquid |
| CN111671133A (en)* | 2020-06-22 | 2020-09-18 | 福建中烟工业有限责任公司 | A tea-flavored flue-cured tobacco-flavored electronic cigarette liquid |
| CN115153081A (en)* | 2022-06-28 | 2022-10-11 | 深圳市艾普生物科技有限公司 | Herbal atomized liquid and preparation method thereof |
| CN117461876A (en)* | 2022-07-20 | 2024-01-30 | 比亚迪精密制造有限公司 | Electronic cigarette oil and preparation method thereof, electronic cigarette |
| Publication | Publication Date | Title |
|---|---|---|
| CN104544549A (en) | Electronic cigarette smoke solution prepared through green tea leaf extract | |
| CN103989245B (en) | The Chinese style flue-cured tobacco odor type tobacco juice for electronic smoke of the sweet soapy feeling in a kind of effective reduction oral cavity | |
| CN103989244B (en) | A kind of Chinese style tobacco juice for electronic smoke and preparation method thereof | |
| CN102304423B (en) | Fragrance-enhancing tobacco essence | |
| CN104544552A (en) | Electronic cigarette smoke solution prepared through oolong leaf extract | |
| CN104489911A (en) | Tobacco juice of electronic cigarette | |
| CN104489904A (en) | E-cigarette nicotine liquid with functions of relieving cough and reducing sputum | |
| CN104770863A (en) | Electronic cigarette smoke solution with herbal tea flavor | |
| CN102304428A (en) | Formula of tobacco flavoring essence with sweet fragrance | |
| CN104531356B (en) | Sweet fragrant additive and the electronic cigarette liquid with sweet perfume | |
| CN102304429B (en) | Formula of tobacco flavoring essence with pure and sweet fruit fragrance | |
| CN104544553A (en) | Fen-flavor electronic tobacco liquid | |
| CN104544543A (en) | Electronic cigarette smoke solution prepared through black tea leaf extract | |
| CN104489912A (en) | Strong-flavor electronic cigarette liquid | |
| CN104489903A (en) | E-cigarette nicotine liquid with function of tranquilizing by nourishing the heart | |
| CN102154060B (en) | Formula of tobacco additive essence of hami melon fragrance | |
| CN104544544A (en) | Electronic cigarette smoke solution prepared through white tea leaf extract | |
| CN104397871A (en) | Electronic cigarette liquid containing tea extracts and preparation method of electronic cigarette liquid containing tea extracts | |
| CN104489913A (en) | E-cigarette nicotine liquid with functions of heat clearing and fire removing | |
| CN104544554A (en) | Electronic cigarette smoke solution with blood fat decreasing function | |
| CN102304430B (en) | Formula of tobacco flavoring essence with sweet fragrance | |
| CN104544548A (en) | Electronic cigarette smoke solution prepared through yellow tea leaf extract | |
| CN104544546A (en) | Electronic cigarette smoke solution with appetite improving and digestion prompting functions | |
| CN102304427B (en) | Formula of fresh and sweet tobacco flavoring essence | |
| CN102161937A (en) | Formula of tobacco flavoring essence containing hops |
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | Application publication date:20150429 | |
| RJ01 | Rejection of invention patent application after publication |