技术领域technical field
本发明涉及一种花露水技术领域，特别是涉及一种无醇驱蚊花露水及其制备方法。The invention relates to the technical field of toilet water, in particular to an alcohol-free mosquito repellent toilet water and a preparation method thereof.
背景技术Background technique
夏季，为了避免蚊虫叮咬，常常需要在身体上涂上驱蚊花露水。In summer, in order to avoid mosquito bites, it is often necessary to smear mosquito repellent toilet water on the body.
一般市售驱蚊花露水配方以1%-3%的香精，70%-75%的酒精，5%的避蚊胺（DEET），15%-20%的去离子水为主。目前的驱蚊花露水主要存在下述问题：Generally, the formula of commercially available mosquito repellent toilet water is based on 1%-3% essence, 70%-75% alcohol, 5% DEET, and 15%-20% deionized water. Present mosquito repellent toilet water mainly has the following problems:
1、避蚊胺是世界上广泛使用的昆虫驱避剂，应用历史已达40余年。实践证明DEET是最有效的广谱驱避剂。但是，避蚊剂使用不当会出现毒性问题，尤其是高浓度重复使用，研究结果表明在高剂量条件下，试验动物出现运动失调、震颤、惊厥等。1. DEET is an insect repellent widely used in the world, and its application history has reached more than 40 years. Practice has proved that DEET is the most effective broad-spectrum repellent. However, improper use of mosquito repellent will cause toxicity problems, especially high-concentration repeated use. Research results show that under high-dose conditions, experimental animals have ataxia, tremors, convulsions, etc.
2、市售花露水由于含有大量的乙醇，致使使用花露水会有诸如加速皮肤水分流失.令皮肤干燥、容易老化、产生皱纹等副作用。特别是对肌肤柔嫩的婴幼儿刺激更为突出。2. Commercially available toilet water contains a large amount of ethanol, so the use of toilet water will have side effects such as accelerating skin moisture loss, making skin dry, prone to aging, and producing wrinkles. Especially for infants with tender skin, the stimulation is more prominent.
3、市售花露水由于含有大量的乙醇，有发生火灾等的潜在危害。3. Commercially available toilet water contains a large amount of ethanol, which has potential hazards such as fire.
发明内容Contents of the invention
本发明的目的是针对现有技术中存在的技术缺陷，而提供一种不使用避蚊胺，使用安全的无醇驱蚊花露水。The object of the present invention is to aim at the technical defects existing in the prior art, and provide a kind of alcohol-free mosquito repellent toilet water that does not use DEET and is safe to use.
本发明的另一个目的是提供一种工艺简单，成本低的无醇驱蚊花露水的制备方法。Another object of the present invention is to provide a method for preparing alcohol-free mosquito repellent toilet water with simple process and low cost.
为实现本发明的目的所采用的技术方案是：The technical scheme adopted for realizing the purpose of the present invention is:
一种无醇驱蚊花露水，包括基液和具有驱蚊功效的植物精油，所述基液为天然植物水蒸气蒸馏液；所述植物精油为基液体积的0.25%～2.5%。An alcohol-free mosquito repellent toilet water comprises a base liquid and a plant essential oil with mosquito repelling effect, the base liquid is a natural plant water vapor distillate; the plant essential oil is 0.25% to 2.5% of the volume of the base liquid.
还包括适量的乳化剂或/和防腐剂。Appropriate amounts of emulsifiers or/and preservatives are also included.
所述植物精油为桂叶油、椒样薄荷油、柠檬草油、薄荷醇、石菖蒲油、白兰叶油、山苍子油、柠檬桉油、香叶醇、松油醇、芳樟醇、石竹烯、柠檬醛、香叶油、香茅醛、香茅醇、丁香叶油、橙叶油、香叶油中的至少一种。The plant essential oils are bay leaf oil, peppermint oil, lemongrass oil, menthol, calamus oil, brandy leaf oil, litsea cubeba oil, lemon eucalyptus oil, geraniol, terpineol, linalool, At least one of caryophyllene, citral, geranium oil, citronellal, citronellol, clove oil, orange leaf oil, and geranium oil.
所述天然植物水蒸气蒸馏液为天然植物花或叶的水蒸气蒸馏液。The natural plant steam distillate is the steam distillate of natural plant flowers or leaves.
所述乳化剂为可用于化妆品的乳化剂。The emulsifier is an emulsifier that can be used in cosmetics.
所述基液为板栗花蒸馏液，所述植物精油由薄荷醇、芳樟醇和松油醇组成，所述防腐剂为三氯生（DP-300）。The base liquid is chestnut flower distillate, the plant essential oil is composed of menthol, linalool and terpineol, and the preservative is triclosan (DP-300).
优选每100mL板栗花蒸馏液中加入薄荷醇0.75～1.5g，香叶醇1～2ml，芳樟醇0.25～0.75ml，松油醇0.25～0.75ml，乳化剂10～16g和0.05～0.1g的三氯生。It is preferred to add 0.75-1.5 g of menthol, 1-2 ml of geraniol, 0.25-0.75 ml of linalool, 0.25-0.75 ml of terpineol, 10-16 g of emulsifier and 0.05-0.1 g of per 100 mL of chestnut flower distillate. Triclosan.
所述乳化剂为吐温-20或PEG-40氢化蓖麻油，所述吐温-20为10～14g，所述PEG-40氢化蓖麻油为12～16g。The emulsifier is Tween-20 or PEG-40 hydrogenated castor oil, the Tween-20 is 10-14g, and the PEG-40 hydrogenated castor oil is 12-16g.
一种无醇驱蚊花露水的制备方法，包括下述步骤：A preparation method of alcohol-free mosquito repellent toilet water, comprising the steps of:
（1）将板栗花与水按照质量比为1∶5～1∶10的比例进行蒸馏得到板栗花蒸馏液，蒸馏条件为：蒸汽压力为0.02～0.04Mpa，蒸馏时间为2～3h；(1) Distill the chestnut flower and water according to the mass ratio of 1:5-1:10 to obtain the chestnut flower distillate, the distillation conditions are: steam pressure 0.02-0.04Mpa, distillation time 2-3h;
（2）向上述每100ml蒸馏液中加入薄荷醇0.75-1.5g、香叶醇1～2ml、芳樟醇0.25～0.75ml、松油醇0.25～0.75ml、乳化剂10～16g和三氯生0.05～0.1g进行混合，得到无醇驱蚊花露水。(2) Add menthol 0.75-1.5g, geraniol 1-2ml, linalool 0.25-0.75ml, terpineol 0.25-0.75ml, emulsifier 10-16g and triclosan to each 100ml of distillate above 0.05-0.1 g are mixed to obtain alcohol-free mosquito repellent toilet water.
与现有技术相比，本发明的有益效果是：Compared with prior art, the beneficial effect of the present invention is:
1、本发明的花露水采用植物水蒸气蒸馏液、天然植物水浸提液，添加了驱蚊精油成分，在满足驱蚊要求的情况下，作用温和，无副作用，避免了乙醇对皮肤的伤害。1. The toilet water of the present invention adopts plant steam distillate and natural plant water extract, and adds mosquito repellent essential oil components. When meeting the requirements of mosquito repellent, it has mild effect, no side effects, and avoids the damage of ethanol to the skin.
2、本发明的花露水驱蚊成分为天然植物成分，不含乙醇，无毒副作用，使用更安全无刺激，尤其适合儿童、妇女、对乙醇过敏者。2. The mosquito repellent composition of the toilet water of the present invention is a natural plant component, does not contain ethanol, has no toxic and side effects, is safer to use and has no irritation, and is especially suitable for children, women, and those who are allergic to ethanol.
3、本发明的花露水用水蒸气蒸馏液和乳化剂代替乙醇，成为无醇产品，可以减少乙醇的刺鼻气味，使整体效果更温和，安全。3. The toilet water of the present invention replaces ethanol with steam distillate and emulsifier to become an alcohol-free product, which can reduce the pungent smell of ethanol and make the overall effect more mild and safe.
4、本发明的花露水不仅可以保留原有植物花等的香气成分，另一方面通过添加薄荷醇、香叶醇、芳樟醇、松油醇强化原液精油成分，大大加强了植物花等蒸馏水的驱蚊作用，通过植物花蒸馏液与精油成分的协同作用，得到持久高效的趋避作用。4. The toilet water of the present invention can not only retain the aroma components of the original plant flowers, etc., but also strengthen the essential oil components of the stock solution by adding menthol, geraniol, linalool, and terpineol, which greatly strengthens the aroma of distilled water such as plant flowers. Mosquito repellent effect, through the synergistic effect of plant flower distillate and essential oil components, a long-lasting and efficient repellent effect is obtained.
5、本发明的花露水采用板栗花蒸馏液为基液，添加了薄荷醇、香叶醇、芳樟醇、松油醇、乳化剂等组成无醇驱蚊花露水，通过各组分和合理配比，在满足驱蚊要求的情况下，作用温和，无副作用，避免了乙醇对皮肤的伤害。5. The toilet water of the present invention adopts the distilled liquid of chestnut flower as the base liquid, adds menthol, geraniol, linalool, terpineol, emulsifiers, etc. to form alcohol-free mosquito repellent toilet water, through each component and reasonable proportioning , in the case of meeting the mosquito repellent requirements, the effect is mild, without side effects, and avoids the damage of ethanol to the skin.
6、本发明的制备方法工艺简单，成本低，能够保留板栗花中的功效成分。6. The preparation method of the present invention has simple process and low cost, and can retain the functional ingredients in chestnut flowers.
具体实施方式Detailed ways
以下结合具体实施例对本发明作进一步详细说明。The present invention will be described in further detail below in conjunction with specific examples.
实施例1Example 1
以河北省唐山迁西县晚期板栗花为原料，固液比为1∶6，蒸汽压力0.04Mpa，蒸馏时间2.5h，获得板栗花蒸馏液。取100ml板栗花蒸馏液，加入薄荷醇1g，香叶醇1.5ml，芳樟醇0.25ml，松油醇0.25ml，PEG-40氢化蓖麻油15g和DP-3000.1g，得到板栗花无醇驱蚊花露水。Chestnut flower distillate was obtained from the late chestnut flower in Qianxi County, Tangshan, Hebei Province, with a solid-liquid ratio of 1:6, a steam pressure of 0.04Mpa, and a distillation time of 2.5h. Take 100ml of chestnut flower distillate, add 1g of menthol, 1.5ml of geraniol, 0.25ml of linalool, 0.25ml of terpineol, 15g of PEG-40 hydrogenated castor oil and 0.1g of DP-3000 to get chestnut flower alcohol-free mosquito repellent toilet water.
功效测试efficacy test
1、驱蚊时间的比较：1. Comparison of mosquito repellent time:
按照GB/17322.10—1998的方法，选用江苏白蚊伊蚊为试虫，分别以隆力奇驱蚊花露水和蒸馏水为阳、阴性对照组，对板栗花蒸馏液和本发明的板栗花无醇驱蚊花露水驱蚊效果进行测定。实验结果显示各处理组的驱蚊时间：蒸馏水为0h，板栗花蒸馏液为0.08h，本发明实施例1的花露水为2.5h，隆力奇花露水为2h。本发明的板栗花无醇驱蚊花露水不仅具有板栗花的特有清香气味，而且其驱蚊效果也非常显著。驱蚊时间远远长于板栗花蒸馏液和空白组，并且强于隆力奇驱蚊花露水。According to the method of GB/17322.10-1998, select Aedes albopictus Jiangsu as the test insect, take Longliqi mosquito repellent toilet water and distilled water as positive and negative control groups respectively, to chestnut flower distillate and chestnut flower non-alcoholic mosquito repellent toilet water of the present invention Mosquito repellent effect was measured. The experimental results show that the mosquito repelling time of each treatment group is: 0h for distilled water, 0.08h for chestnut flower distillate, 2.5h for the toilet water of Example 1 of the present invention, and 2h for Longliqi toilet water. The chestnut flower alcohol-free mosquito repelling toilet water not only has the unique fragrance of chestnut flowers, but also has a very remarkable mosquito repelling effect. Mosquito repelling time is much longer than chestnut flower distillate and blank group, and stronger than Longliqi mosquito repellent toilet water.
2、驱蚊效果比较：2. Comparison of mosquito repellent effect:
选用江苏白纹伊蚊、广东白纹伊蚊、天津白纹伊蚊，以及淡色库蚊和中华按蚊为试虫，采用GB/17322.10—1998的方法，测定实施例1所得板栗花无醇驱蚊花露水的驱蚊效果。测定结果：江苏白纹伊蚊2.5h，广东白纹伊蚊2.25h，天津白纹伊蚊2.5h，淡色库蚊3.5h，中华按蚊3h。因此，本发明的产品对不同地区的多种蚊种均具有明显的趋避作用。Select Aedes albopictus Jiangsu, Aedes albopictus Guangdong, Aedes albopictus Tianjin, Culex palustris and Anopheles sinensis as test insects, adopt the method of GB/17322.10-1998, measure the chestnut flower obtained in embodiment 1 without alcohol repellent Mosquito repellent effect of mosquito toilet water. Determination results: Jiangsu Aedes albopictus 2.5h, Guangdong Aedes albopictus 2.25h, Tianjin Aedes albopictus 2.5h, Culex palustris 3.5h, Anopheles sinensis 3h. Therefore, the product of the present invention has obvious repelling effects on various mosquito species in different regions.
3、稀释后效果：3. Effect after dilution:
将本发明实施例1所得板栗花无醇花露水分别稀释2倍、3倍、5倍、10倍进行驱蚊试验，试虫为江苏白蚊伊蚊。实验结果为：板栗花无醇花露水原液为2.5小时，稀释2倍为1.5小时，稀释3倍为1小时，稀释5倍为0.25小时，稀释10倍为0.1小时。随着稀释倍数不断增加驱蚊时间不断减小。在将原液稀释2-3倍，仍然具有很强的驱蚊功效（1-1.5小时）。The chestnut flower alcohol-free toilet water obtained in Example 1 of the present invention was diluted 2 times, 3 times, 5 times, and 10 times respectively to carry out a mosquito repellent test, and the test insect was Aedes albopictus Jiangsu. The experimental results are as follows: the stock solution of chestnut flower alcohol-free toilet water is 2.5 hours, diluted 2 times is 1.5 hours, diluted 3 times is 1 hour, diluted 5 times is 0.25 hours, diluted 10 times is 0.1 hours. As the dilution factor increased, the repellent time decreased continuously. After diluting the original solution 2-3 times, it still has a strong mosquito repellent effect (1-1.5 hours).
实施例2Example 2
以河北省唐山迁西县晚期板栗花为原料，固液比为1∶6，蒸汽压力0.04Mpa，蒸馏时间2.5h，获得板栗花蒸馏液。取100ml板栗花蒸馏液，加入薄荷醇0.75g，香叶醇1.5ml，芳樟醇0.5ml，松油醇0.5ml，PEG-40氢化蓖麻油13g和DP-3000.05g，得到板栗花无醇驱蚊花露水。选择江苏白纹伊蚊为受试对象，按照GB/17322.10—1998的方法进行驱蚊试验，驱蚊时间为2h。Chestnut flower distillate was obtained from the late chestnut flower in Qianxi County, Tangshan, Hebei Province, with a solid-liquid ratio of 1:6, a steam pressure of 0.04Mpa, and a distillation time of 2.5h. Take 100ml of chestnut flower distillate, add 0.75g of menthol, 1.5ml of geraniol, 0.5ml of linalool, 0.5ml of terpineol, 13g of PEG-40 hydrogenated castor oil and 0.05g of DP-3000 to obtain alcohol-free repellent of chestnut flower. Mosquito toilet water. Aedes albopictus in Jiangsu was selected as the subject, and the mosquito repellent test was carried out according to the method of GB/17322.10-1998, and the mosquito repellent time was 2 hours.
实施例3Example 3
以河北省唐山迁西县晚期板栗花为原料，固液比为1∶6，蒸汽压力0.04Mpa，蒸馏时间2.5h，获得板栗花蒸馏液。取100ml板栗花蒸馏液，加入薄荷醇0.75g，香叶醇2ml，芳樟醇0.75ml，松油醇0.75ml，PEG-40氢化蓖麻油14g和DP-3000.06g，得到板栗花无醇驱蚊花露水。选择江苏白纹伊蚊为受试对象按照GB/17322.10—1998的方法进行驱蚊试验，驱蚊时间为1.75h。Chestnut flower distillate was obtained from the late chestnut flower in Qianxi County, Tangshan, Hebei Province, with a solid-liquid ratio of 1:6, a steam pressure of 0.04Mpa, and a distillation time of 2.5h. Take 100ml of chestnut flower distillate, add 0.75g of menthol, 2ml of geraniol, 0.75ml of linalool, 0.75ml of terpineol, 14g of PEG-40 hydrogenated castor oil and 0.06g of DP-3000 to get chestnut flower alcohol-free mosquito repellent toilet water. Select Jiangsu Aedes albopictus as the subject to carry out the mosquito repellent test according to the method of GB/17322.10-1998, and the mosquito repellent time is 1.75h.
实施例4Example 4
以河北省唐山迁西县晚期板栗花为原料，固液比为1∶6，蒸汽压力0.02Mpa，蒸馏时间2.5h，获得板栗花蒸馏液。取100ml板栗花蒸馏液，加入薄荷醇1g，香叶醇1.5ml，芳樟醇0.75ml，松油醇0.25ml，PEG-40氢化蓖麻油15g和DP-3000.07g，得到板栗花无醇驱蚊花露水。按照GB/17322.10—1998的方法对江苏白纹伊蚊进行驱蚊试验，驱蚊时间为2.5h。Chestnut flower distillate was obtained from late chestnut flower in Qianxi County, Tangshan, Hebei Province, with solid-liquid ratio of 1:6, steam pressure of 0.02Mpa, and distillation time of 2.5h. Take 100ml of chestnut flower distillate, add 1g of menthol, 1.5ml of geraniol, 0.75ml of linalool, 0.25ml of terpineol, 15g of PEG-40 hydrogenated castor oil and 0.07g of DP-3000 to get chestnut flower alcohol-free mosquito repellent toilet water. According to the method of GB/17322.10-1998, the mosquito repellent test was carried out on Aedes albopictus in Jiangsu, and the mosquito repellent time was 2.5h.
实施例5Example 5
以河北省唐山迁西县晚期板栗花为原料，固液比为1∶6，蒸汽压力0.04Mpa，蒸馏时间2.5h，获得板栗花蒸馏液。取100ml板栗花蒸馏液，加入薄荷醇1.5g，香叶醇1.5ml，芳樟醇0.25ml，松油醇0.75ml，PEG-40氢化蓖麻油16g和DP-3000.1g，得到板栗花无醇驱蚊花露水。按照GB/17322.10—1998的方法对江苏白纹伊蚊进行驱蚊试验，驱蚊时间为1.5h。Chestnut flower distillate was obtained from the late chestnut flower in Qianxi County, Tangshan, Hebei Province, with a solid-liquid ratio of 1:6, a steam pressure of 0.04Mpa, and a distillation time of 2.5h. Take 100ml of chestnut flower distillate, add 1.5g of menthol, 1.5ml of geraniol, 0.25ml of linalool, 0.75ml of terpineol, 16g of PEG-40 hydrogenated castor oil and 0.1g of DP-3000 to obtain alcohol-free repellent of chestnut flower. Mosquito toilet water. According to the method of GB/17322.10-1998, the mosquito repellent test was carried out on Aedes albopictus in Jiangsu, and the mosquito repellent time was 1.5h.
实施例6Example 6
以河北省唐山迁西县晚期板栗花为原料，固液比为1∶6，蒸汽压力0.04Mpa，蒸馏时间2.5h，获得板栗花蒸馏液。取100ml板栗花蒸馏液，加入薄荷醇1g，香叶醇1.5ml，芳樟醇0.25ml，松油醇0.25ml，吐温-2012g和DP-3000.09g，得到板栗花无醇驱蚊花露水。按照GB/17322.10—1998的方法进行驱蚊试验，驱蚊时间为2.5h。Chestnut flower distillate was obtained from the late chestnut flower in Qianxi County, Tangshan, Hebei Province, with a solid-liquid ratio of 1:6, a steam pressure of 0.04Mpa, and a distillation time of 2.5h. Take 100ml of chestnut flower distillate, add menthol 1g, geraniol 1.5ml, linalool 0.25ml, terpineol 0.25ml, Tween-2012g and DP-3000.09g to obtain chestnut flower alcohol-free mosquito repellent toilet water. The mosquito repellent test was carried out according to the method of GB/17322.10-1998, and the mosquito repellent time was 2.5h.
实施例7Example 7
以河北省唐山迁西县晚期板栗花为原料，蒸汽压力0.04Mpa，蒸馏时间2.5h，固液比分别为1:5,1:6，1:7,1:8,1:9,1:10获得板栗花蒸馏液。分别取100ml各种固液比所得的板栗花蒸馏液，加入薄荷醇1g，香叶醇1.5ml，芳樟醇0.25ml，松油醇0.25ml，吐温-2014g和DP-3000.1g，得到板栗花无醇驱蚊花露水。按照GB/17322.10—1998的方法对江苏白纹伊蚊进行驱蚊试验，驱蚊时间分别为2.5h,2.5h,2.48h,2.48h,2.46h,2.45h。The late chestnut flower of Qianxi County, Tangshan, Hebei Province is used as raw material, the steam pressure is 0.04Mpa, the distillation time is 2.5h, and the solid-liquid ratio is 1:5, 1:6, 1:7, 1:8, 1:9, 1: 10 Obtain chestnut flower distillate. Take 100ml of chestnut flower distillate obtained by various solid-to-liquid ratios, add 1g of menthol, 1.5ml of geraniol, 0.25ml of linalool, 0.25ml of terpineol, Tween-2014g and DP-3000.1g to obtain chestnut Flower alcohol-free mosquito repellent toilet water. According to the method of GB/17322.10-1998, the mosquito repellent test was carried out on Jiangsu Aedes albopictus, and the mosquito repellent time was 2.5h, 2.5h, 2.48h, 2.48h, 2.46h, 2.45h.
实施例8Example 8
以河北省唐山迁西县晚期板栗花为原料，固液比为1∶6，蒸馏时间2.5h，蒸汽压力分别为0.02,0.03,0.04,0.05Mpa，获得板栗花蒸馏液。分别取100ml各种蒸汽压力得到的板栗花蒸馏液，加入薄荷醇1g，香叶醇1.5ml，芳樟醇0.25ml，松油醇0.25ml，PEG-40氢化蓖麻油15g和DP-3000.1g，得到板栗花无醇驱蚊花露水。按照GB/17322.10—1998的方法对江苏白纹伊蚊进行驱蚊试验，驱蚊时间分别为2.46h,2.47h,2.5h，2.5h。Chestnut flower distillates were obtained from late chestnut flowers in Qianxi County, Tangshan, Hebei Province, with a solid-to-liquid ratio of 1:6, distillation time of 2.5 hours, and vapor pressures of 0.02, 0.03, 0.04, and 0.05 Mpa, respectively. Take 100ml of chestnut flower distillate obtained by various steam pressures, add menthol 1g, geraniol 1.5ml, linalool 0.25ml, terpineol 0.25ml, PEG-40 hydrogenated castor oil 15g and DP-3000.1g, Get Chestnut Blossom Alcohol-Free Mosquito Repellent Toilet Water. According to the method of GB/17322.10-1998, the mosquito repellent test was carried out on Jiangsu Aedes albopictus, and the mosquito repellent time was 2.46h, 2.47h, 2.5h, 2.5h.
实施例9Example 9
以河北省唐山迁西县晚期板栗花为原料，固液比为1∶6，蒸汽压力0.04Mpa，蒸馏时间分别为2，2.5，3h，按照实施例8分别加入精油和进行驱蚊实验，驱蚊时间分别为2.48h,2.5h，2.47h。With chestnut flower in the late stage of Qianxi County, Tangshan, Hebei Province as raw material, the solid-liquid ratio is 1: 6, the steam pressure is 0.04Mpa, and the distillation time is respectively 2, 2.5, and 3h. The mosquito time is 2.48h, 2.5h, 2.47h respectively.
本发明的板栗花无醇花露水中不含驱蚊胺和乙醇，能够避免驱蚊胺和乙醇对身体的危害，而具有更持久的驱蚊效果。作用温和，无副作用，避免了乙醇对皮肤的伤害。The chestnut flower alcohol-free toilet water of the present invention does not contain repellent amine and ethanol, can avoid the harm of repellent amine and ethanol to the body, and has a longer-lasting mosquito repellent effect. Mild action, no side effects, avoiding the damage of ethanol to the skin.
以上所述仅是本发明的优选实施方式，应当指出的是，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。The above is only a preferred embodiment of the present invention, it should be pointed out that, for those of ordinary skill in the art, without departing from the principle of the present invention, some improvements and modifications can also be made, these improvements and Retouching should also be regarded as the protection scope of the present invention.
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310728932.3ACN103690449B (en) | 2013-12-17 | 2013-12-17 | Without alcohol mosquito-repellent perfume and preparation method thereof |
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310728932.3ACN103690449B (en) | 2013-12-17 | 2013-12-17 | Without alcohol mosquito-repellent perfume and preparation method thereof |
| Publication Number | Publication Date |
|---|---|
| CN103690449A CN103690449A (en) | 2014-04-02 |
| CN103690449Btrue CN103690449B (en) | 2015-09-16 |
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310728932.3AExpired - Fee RelatedCN103690449B (en) | 2013-12-17 | 2013-12-17 | Without alcohol mosquito-repellent perfume and preparation method thereof |
| Country | Link |
|---|---|
| CN (1) | CN103690449B (en) |
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105520020B (en)* | 2015-12-10 | 2018-06-05 | 迁西县板栗产业研究发展中心 | Chinese Chestnut health beverages and its instructions of taking |
| CN106172472B (en)* | 2016-07-07 | 2019-03-26 | 平阳县小鸽工艺品厂 | A kind of environmental protection mosquitocide composition and its mosquito killing liquid and mosquito eradication packet that are prepared into |
| CN108477243A (en)* | 2018-02-07 | 2018-09-04 | 黄珊珊 | A kind of pest repellant, insecticides |
| WO2020042095A1 (en)* | 2018-08-30 | 2020-03-05 | 江苏奇力康皮肤药业有限公司 | Alcohol-free bacteriostatic florida water and preparation method therefor |
| CN111345299A (en)* | 2018-12-24 | 2020-06-30 | 上海碧珈圣科技有限公司 | Composition and application thereof |
| CN110063341A (en)* | 2019-06-03 | 2019-07-30 | 青岛尚芳环境科技有限公司 | A kind of culicifuge |
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101906353A (en)* | 2010-08-03 | 2010-12-08 | 河北科技大学 | A kind of extraction method and application of chestnut flower essential oil |
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103404539A (en)* | 2013-07-19 | 2013-11-27 | 施健 | Mosquito repellent composition |
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101906353A (en)* | 2010-08-03 | 2010-12-08 | 河北科技大学 | A kind of extraction method and application of chestnut flower essential oil |
| Title |
|---|
| 林翔云.芳香疗法和芳香养生.《香味世界》.2011,* |
| Publication number | Publication date |
|---|---|
| CN103690449A (en) | 2014-04-02 |
| Publication | Publication Date | Title |
|---|---|---|
| CN103690449B (en) | Without alcohol mosquito-repellent perfume and preparation method thereof | |
| CN102835428B (en) | Essential oil mosquito repellent | |
| CN104958774A (en) | Air purification plant composition and making method thereof | |
| CN105707139B (en) | Natural anticorrosion composition | |
| CN104094977A (en) | Composition with insect-expelling sterilization disinfection effects and application thereof | |
| KR101711050B1 (en) | Natural antibacterial composition and spray device including the same | |
| CN104295054A (en) | A health-care floor made of tourmaline compounded with natural extracts | |
| CN106310906A (en) | Indoor air deodorant having sterilizing function and preparation method thereof | |
| CN104041539A (en) | Low-toxicity harmless pesticide | |
| CN101906353A (en) | A kind of extraction method and application of chestnut flower essential oil | |
| CN103520059A (en) | Botanical mosquito repellent and preparation method thereof | |
| CN105475390A (en) | Plant culicifuge | |
| CN106265097A (en) | A kind of mosquito-eliminating wet tissue and preparation method thereof | |
| CN105475370A (en) | Air disinfectant | |
| CN105396166A (en) | Liquid air freshener | |
| CN104367529A (en) | Mosquito repellent floral water for purifying air and preparation method of mosquito repellent floral water | |
| CN108219945A (en) | A kind of flower water essential oil and all-scent type flower water essential oil | |
| CN102988233A (en) | Floral water for children | |
| CN102614092A (en) | Mosquito driving ointment and preparation method thereof | |
| CN103655276A (en) | Aromatic insect repellent perfume | |
| KR101898060B1 (en) | Natural aroma essential oil water soluble composition for humidifier disinfectant and the method of manufaturing the same | |
| CN103861141A (en) | Formula and preparation of quick and safe aldehyde-removing air freshener, as well as using method thereof | |
| CN110178861A (en) | A kind of natural essential oil culicifuge | |
| CN106172520A (en) | Mosquito-repellent water | |
| CN105794861B (en) | A kind of Pure natural plant essential oil culicifuge and preparation method thereof |
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee | Granted publication date:20150916 Termination date:20161217 |