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CN103242107A - Straw rotten organic sterilizing/weeding compound fertilizer - Google Patents

Straw rotten organic sterilizing/weeding compound fertilizer
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Publication number
CN103242107A
CN103242107ACN2013101975061ACN201310197506ACN103242107ACN 103242107 ACN103242107 ACN 103242107ACN 2013101975061 ACN2013101975061 ACN 2013101975061ACN 201310197506 ACN201310197506 ACN 201310197506ACN 103242107 ACN103242107 ACN 103242107A
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parts
compound fertilizer
bactericidal
stalk
extract
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CN2013101975061A
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Chinese (zh)
Inventor
刘浩川
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CHANGSHU RUNFENG AGRICULTURAL Co Ltd
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CHANGSHU RUNFENG AGRICULTURAL Co Ltd
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Abstract

The invention relates to a straw rotten organic sterilizing/weeding compound fertilizer. The invention is characterized in that the compound fertilizer is prepared from the following raw materials in parts by weight: 50-60 parts of straw, 1-15 parts of Stellera chamaejasme, 5-10 parts of humulus lupulus, 25-30 parts of pepper, 25-30 parts of Ginkgo biloba endocarp and the like. The compound fertilizer has the characteristics of farmland weed removal and broad-spectrum sterilization. Compared with the prior art, the preparation provided by the invention has the characteristics of favorable weeding effect, high environmental safety, low tendency of weed to generating chemical resistance and the like, and has wide application prospects.

Description

A kind of stalk organic bactericidal and herbicidal compound fertilizer that becomes thoroughly decomposed
Technical field
The invention belongs to the nuisanceless fertilizer technical field, relate to a kind of nuisanceless bactericidal and herbicidal compound fertilizer.
Background technology
Plant can run into various disease and pests in the occurring in nature process of growth, fungus disease particularly, its kind is many, and disease is serious, and for example gold disease, red gold disease, dark fund disease etc. are generally, comparatively to be difficult to the disease of preventing and treating in many farm crop generations, bring tremendous loss to agriculture production, mainly occur in the parts such as tender seedling, bud, the tip of crop, blade is withered when serious, curls, the browning look, withered.A large amount of chemical means that use are prevented and treated at present, yet domesticly mainly contain the unicity of methyl medication for many years and the singularity of pharmaceutical chemicals be used to the medicament of preventing and treating Powdery Mildew, be easy in use operator and ecotope be made serious harm, and have residual in a large number, easy-clear does not cause injury to edible people, and therefore country is own through banning use of highly toxic pesticide, greatly develop the green non-pollution vegetables, so be badly in need of developing low toxicity even nontoxic public nuisance-free agricultural chemicals.The annual a large amount of underproduction of farm crop that all cause of causing harm of farmland weed.Use chemical herbicide to remain the main means of present weed control, but because a large amount of and unreasonable use chemical herbicide have caused problems such as environmental pollution, pesticide residue and weeds resistance, be subjected to extensive concern.Therefore, exploitation is efficient, the new herbicides of low toxicity, low residue, becomes the problem that presses for solution.From plant, seek biologically active substance, and then the environmentally friendly agricultural chemicals of development of new, be the hot fields of current domestic and international research.
China is large agricultural country, and about 400,000,000 m2 of area take place the crop diseases and pest crop smothering throughout the year, and annual the need produced and used 800,000 tons in agricultural chemicals, and agricultural chemicals has become indispensable factor in the agriculture production.Being extensive use of of agricultural chemicals, though vital role has been played in production development, also occurred such as insect pest, disease the resistance problem, to the pollution of environment and in agricultural and animal products residual and accumulation problem, injure natural enemy, destroy balance of nature, cause insect rampant problem etc. again.This development to novel pesticide has proposed higher requirement.Especially entered since 21 century, along with the cry of people's uphold nature, protection environment, concern food safety is day by day surging, harmless boilogical agricultural chemicals industry and biological control area research have obtained rare opportunity to develop.
Seed of Chinese Soapberry (Sapindus mukurossi Gatren) is a kind of deciduous tree of Sapindaceae (Sapindaceae) Sapindus (Sapindus), originates on the south China Yangtze valley and South East Asia Mainland various places, India and Japan.Studies show that contain multiple secondary metabolite in the Seed of Chinese Soapberry, some have good biological activity, have been widely used in daily use chemicals, medicine and other fields.But not about the report of Seed of Chinese Soapberry extract weeding activity, be not the weedicide product of activeconstituents with Seed of Chinese Soapberry exosper extract more so far.Therefore, exploitation is the plant-sourced weedicide product of activeconstituents with the Seed of Chinese Soapberry extract, has vast market prospect.The plant pesticide that also has at present some to extract in the kuh-seng, but it is unreasonable to fill a prescription, effect is not ideal, is not suitable for suitability for industrialized production, and the fertilizer of prior art only has the trophic function of fertilizer at present, does not have the effect of killing plant insect.Market in urgent need is a kind of to be conducive to environment protection, effectively sterilization, and weeding, and can be fit to the big nuisanceless bactericidal and herbicidal compound of the plant fertilizer of producing.
Summary of the invention
The invention provides a kind of is the nuisanceless bactericidal and herbicidal compound fertilizer of main activeconstituents with Chinese medicine.
A kind of stalk organic bactericidal and herbicidal compound fertilizer that becomes thoroughly decomposed, it is obtained by the feedstock production of following parts by weight: stalk 50-60 part, Stellera chamaejasme L. 1-15 part, hops 5-10 part, Chinese prickly ash 25-30 part, ginkgo kind skin 25-30 part, Fructus Cnidii 26-30 part, Cortex Meliae 17-30 part, Rangooncreeper Fruit 16-25 part, Turkey-galls 1-15 part, Root of Pubescent Holly 5-15 part, matrine 5-10 part, Seed of Chinese Soapberry exosper 55-60 part, carbon ammonium 35-45 part, diammonium phosphate 20-30 part, Repone K 5-10 part, zinc sulfate 1-2 part, boric acid 1-2 part, manganous sulfate 5-10 part, medical stone powder 25-30 part, calcium stone flour 5-10 part, wilkinite 20-25 part, thiocarbamide 5-15 part, diatomite 10-20 part, ground phosphate rock 10-20 part, Sodium salts humic acids 5-15 part, 10~25 parts of proline(Pro), 15~20 parts of methionine(Met)s, 16~23 parts of glycine, 26~33 parts of Threonines, tyrosinase 15-15 part, water 10-20 part.
Get stalk in proportion, stir, the stacking fermentation; Stacking fermentation 10-20 days, when temperature reaches 65 ℃, turning 4 times, when temperature and normal temperature remained basically stable, complete ripeness fermented; With the fermentation complete ripeness the base-material airing or dry to water content≤10%; Get Stellera chamaejasme L., hops, Chinese prickly ash, ginkgo kind skin, Fructus Cnidii, Cortex Meliae, Rangooncreeper Fruit, Turkey-galls, Root of Pubescent Holly, matrine, Seed of Chinese Soapberry exosper according to described parts by weight, 70% alcohol reflux that at every turn adds 30 times of amounts of medicinal material total amount, reflux twice, each 3 hours, merge alcohol extract, relative density is 1.6 medicinal extract when 0.08Mpa, 60 ℃ are evaporated to 65 ℃, and spraying drying gets dry extract; After the medicinal extract that obtains is scattered in distilled water and the base-material of described fermentation complete ripeness mixes, add carbon ammonium, diammonium phosphate, Repone K, zinc sulfate, boric acid, manganous sulfate, medical stone powder, calcium stone flour, wilkinite, thiocarbamide, diatomite, ground phosphate rock, Sodium salts humic acids, proline(Pro), methionine(Met), glycine, Threonine, tyrosine by described prescription.
The application of described bactericidal and herbicidal compound fertilizer in control cereal class, fruit tree, vegetables.
Described crop is potato.
It is preferably obtained by the feedstock production of following parts by weight: 55 parts of stalks, 7 parts of Stellera chamaejasme L.s, 7 parts of hops, 27 parts in Chinese prickly ash, 27 parts of ginkgo kind skins, 27 parts of Fructus Cnidiis, 24 parts of Cortex Meliaees, 20 parts of Rangooncreeper Fruit, 8 parts in Turkey-galls, 8 parts of Root of Pubescent Holly, 8 parts of matrines, 60 parts of Seed of Chinese Soapberry exospers, 38 parts of carbon ammoniums, 27 parts of diammonium phosphate, 6 parts in Repone K, 1 part in zinc sulfate, 1 part of boric acid, 7 parts of manganous sulfates, 27 parts in medical stone powder, 8 parts of calcium stone flours, 23 parts of wilkinites, 9 parts of thiocarbamides, 16 parts in diatomite, 16 parts in ground phosphate rock, 9 parts of Sodium salts humic acidss, 12 parts of proline(Pro), 18 parts of methionine(Met)s, 19 parts of glycine, 29 parts of Threonines, 8 parts in tyrosine, 15 parts in water.
Bactericidal and herbicidal agent of the present invention can be used for broadcasting the preceding soil treatment of back seedling, prevents and kill off the sterilization idiocratic of farmland weed and wide spectrum.Compared with prior art, it is good, environmentally safe that formulation of the present invention has a herbicidal effect, and weeds characteristics such as be difficult for developing immunity to drugs have a extensive future.Formulation of the present invention is remarkable to the common disease-controlling effect of fruit, wheat, paddy rice and vegetables.Bactericidal and herbicidal agent of the present invention relatively safely to eyes, skin nonirritant, is low toxicity through bright its acute toxicity of day skin test checking to people and animals, easily decomposes in atmosphere and soil, and non-poisonous material is residual; Bactericidal and herbicidal agent of the present invention is little to the influence of farmland natural enemy, helps to keep ecotope, and is more friendly to environment, satisfies the production requirement of crop.
Embodiment
The present invention is described in further detail by the following examples, but should be appreciated that the present invention is not in following examples.
Embodiment 1: the become thoroughly decomposed preparation of organic bactericidal and herbicidal compound fertilizer of a kind of stalk
Will be separately traditional Chinese medicine ingredients air-dry, dry or in 40-60 ℃ of oven dry, pulverize.The feedstock production of getting following parts by weight obtains: it is obtained by the feedstock production of following parts by weight: stalk 50-60 part, Stellera chamaejasme L. 1-15 part, hops 5-10 part, Chinese prickly ash 25-30 part, ginkgo kind skin 25-30 part, Fructus Cnidii 26-30 part, Cortex Meliae 17-30 part, Rangooncreeper Fruit 16-25 part, Turkey-galls 1-15 part, Root of Pubescent Holly 5-15 part, matrine 5-10 part, Seed of Chinese Soapberry exosper 55-60 part, carbon ammonium 35-45 part, diammonium phosphate 20-30 part, Repone K 5-10 part, zinc sulfate 1-2 part, boric acid 1-2 part, manganous sulfate 5-10 part, medical stone powder 25-30 part, calcium stone flour 5-10 part, wilkinite 20-25 part, thiocarbamide 5-15 part, diatomite 10-20 part, ground phosphate rock 10-20 part, Sodium salts humic acids 5-15 part, 10~25 parts of proline(Pro), 15~20 parts of methionine(Met)s, 16~23 parts of glycine, 26~33 parts of Threonines, tyrosinase 15-15 part, water 10-20 part.
55 parts of stalks, 7 parts of Stellera chamaejasme L.s, 7 parts of hops, 27 parts in Chinese prickly ash, 27 parts of ginkgo kind skins, 27 parts of Fructus Cnidiis, 24 parts of Cortex Meliaees, 20 parts of Rangooncreeper Fruit, 8 parts in Turkey-galls, 8 parts of Root of Pubescent Holly, 8 parts of matrines, 60 parts of Seed of Chinese Soapberry exospers, 38 parts of carbon ammoniums, 27 parts of diammonium phosphate, 6 parts in Repone K, 1 part in zinc sulfate, 1 part of boric acid, 7 parts of manganous sulfates, 27 parts in medical stone powder, 8 parts of calcium stone flours, 23 parts of wilkinites, 9 parts of thiocarbamides, 16 parts in diatomite, 16 parts in ground phosphate rock, 9 parts of Sodium salts humic acidss, 12 parts of proline(Pro), 18 parts of methionine(Met)s, 19 parts of glycine, 29 parts of Threonines, 8 parts in tyrosine, 15 parts in water.
Get stalk in proportion, stir, the stacking fermentation; Stacking fermentation 10-20 days, when temperature reaches 65 ℃, turning 4 times, when temperature and normal temperature remained basically stable, complete ripeness fermented; With the fermentation complete ripeness the base-material airing or dry to water content≤10%; Get Stellera chamaejasme L., hops, Chinese prickly ash, ginkgo kind skin, Fructus Cnidii, Cortex Meliae, Rangooncreeper Fruit, Turkey-galls, Root of Pubescent Holly, matrine, Seed of Chinese Soapberry exosper according to described parts by weight, 70% alcohol reflux that at every turn adds 30 times of amounts of medicinal material total amount, reflux twice, each 3 hours, merge alcohol extract, relative density is 1.6 medicinal extract when 0.08Mpa, 60 ℃ are evaporated to 65 ℃, and spraying drying gets dry extract; After the medicinal extract that obtains is scattered in distilled water and the base-material of described fermentation complete ripeness mixes, add carbon ammonium, diammonium phosphate, Repone K, zinc sulfate, boric acid, manganous sulfate, medical stone powder, calcium stone flour, wilkinite, thiocarbamide, diatomite, ground phosphate rock, Sodium salts humic acids, proline(Pro), methionine(Met), glycine, Threonine, tyrosine by described prescription.
Embodiment 2: the become thoroughly decomposed bacteriostatic test effect of organic bactericidal and herbicidal compound fertilizer of a kind of stalk
Bactericidal and herbicidal fertilizer control paddy rice sclerotium disease, cucumber black heart, pears gray mold field control effectiveness test that the embodiment of the invention 1 makes:
3 processing are established in each test altogether, 4 repetitions, and each residential quarter area 10m2 carries out test design, wherein A according to the completely random design: the clear water blank; B: 800 times of diluent positive controls of compound derosal; C: 300 times of diluents of botanical pesticide of the present invention.Use medicine 4 times, interval 7d.
Investigation content and data processing: every residential quarter is selected 30 samples at random, 7d investigation before using medicine and after the 4th perfusion, record diseased plant number.Carry out the output investigation during results, the single receipts in every residential quarter, weighing separately.
Sickness rate (%)=(the total strain number of diseased plant number/investigation) * 100.
Prevention effect (%)=[(check plot sickness rate-treatment zone sickness rate)/check plot sickness rate] * 100.
Test-results shows that the inequality heteropole is remarkable between pesticide control paddy rice sclerotium disease of the present invention, cucumber black heart, pears gray mold and the clear water blank; Prevention effect on average reaches more than 75%, and control cucumber black heart is had positive effect, arrives 85%.
Embodiment 3: the become thoroughly decomposed controlling weeds test effect of organic bactericidal and herbicidal compound fertilizer of a kind of stalk
The stalk that the embodiment of the invention 1 makes the become thoroughly decomposed fertile control of organic bactericidal and herbicidal compound artemisiifolia, the bent grass of crawling, annual bluegrass and Bermuda grass field control effectiveness test:
3 processing are established in each test altogether, 4 repetitions, and each residential quarter area 10m2 carries out test design, wherein A according to the completely random design: the clear water blank; B: 800 times of diluent positive controls of compound derosal; C: 300 times of diluents of botanical pesticide of the present invention.Use medicine 4 times, interval 7d.
Investigation content and data processing: every residential quarter is selected 30 samples at random, 7d investigation before using medicine and after the 4th perfusion, record diseased plant number.Carry out the output investigation during results, the single receipts in every residential quarter, weighing separately.
Sickness rate (%)=(the total strain number of diseased plant number/investigation) * 100.
Prevention effect (%)=[(check plot sickness rate-treatment zone sickness rate)/check plot sickness rate] * 100.
Test-results shows that the inequality heteropole is remarkable between pesticide control artemisiifolia of the present invention, the bent grass of crawling, annual bluegrass and Bermuda grass and the clear water blank; Prevention effect on average reaches 76.1%, and control Bermuda grass, artemisiifolia are had positive effect, arrives 84.1%, 82.2%.
Embodiment 3: the manure trial effect of nuisanceless bactericidal and herbicidal compound fertilizer
Composite fertilizer of the present invention is all obtained positive effect through the field simultaneous test, mainly shows as follows: contain and enrich organic matter and humic acid, can improve Soil structure, vegetable soil promotes soil to build up fertility.With other fertilizer ratio such as nutrient such as grade, crop yield 26%.Formulation and the nutrition of coordination crop absorption stimulate and the regulation and control plant growth, reduce or the reduction crop pest, influence crop quality.Need not or reduce fertilizer amount, be beneficial to the protection environment.

Claims (4)

1. a stalk organic bactericidal and herbicidal compound fertilizer and preparation method thereof that becomes thoroughly decomposed is characterized in that it is obtained by the feedstock production of following parts by weight: stalk 50-60 part; Stellera chamaejasme L. 1-15 part, hops 5-10 part, Chinese prickly ash 25-30 part, ginkgo kind skin 25-30 part, Fructus Cnidii 26-30 part, Cortex Meliae 17-30 part, Rangooncreeper Fruit 16-25 part, Turkey-galls 1-15 part, Root of Pubescent Holly 5-15 part, matrine 5-10 part, Seed of Chinese Soapberry exosper 55-60 part, carbon ammonium 35-45 part, diammonium phosphate 20-30 part, Repone K 5-10 part, zinc sulfate 1-2 part, boric acid 1-2 part, manganous sulfate 5-10 part, medical stone powder 25-30 part, calcium stone flour 5-10 part, wilkinite 20-25 part, thiocarbamide 5-15 part, diatomite 10-20 part, ground phosphate rock 10-20 part, Sodium salts humic acids 5-15 part, 10~25 parts of proline(Pro), 15~20 parts of methionine(Met)s, 16~23 parts of glycine, 26~33 parts of Threonines, tyrosinase 15-15 part, water 10-20 part.
2. the preparation method of a kind of bactericidal and herbicidal agent according to claim 1 is characterized in that, it comprises the steps: to get in proportion stalk, stirs the stacking fermentation; Stacking fermentation 10-20 days, when temperature reaches 65 ℃, turning 4 times, when temperature and normal temperature remained basically stable, complete ripeness fermented; With the fermentation complete ripeness the base-material airing or dry to water content≤10%; Get Stellera chamaejasme L., hops, Chinese prickly ash, ginkgo kind skin, Fructus Cnidii, Cortex Meliae, Rangooncreeper Fruit, Turkey-galls, Root of Pubescent Holly, matrine, Seed of Chinese Soapberry exosper according to described parts by weight, 70% alcohol reflux that at every turn adds 30 times of amounts of medicinal material total amount, reflux twice, each 3 hours, merge alcohol extract, relative density is 1.6 medicinal extract when being evaporated to 65 ℃ through (0.08Mpa, 60 ℃), and spraying drying gets dry extract; After the medicinal extract that obtains is scattered in distilled water and the base-material of described fermentation complete ripeness mixes, add carbon ammonium, diammonium phosphate, Repone K, zinc sulfate, boric acid, manganous sulfate, medical stone powder, calcium stone flour, wilkinite, thiocarbamide, diatomite, ground phosphate rock, Sodium salts humic acids, proline(Pro), methionine(Met), glycine, Threonine, tyrosine by described prescription.
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Cited By (17)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
CN103478049A (en)*2013-10-152014-01-01苏州市相城区盛胡特种养殖专业合作社Method for feeding crayfishes by nano feeds
CN103613442A (en)*2013-11-082014-03-05苏州仁成生物科技有限公司Polyelement botanical bio-fertilizer and preparation method thereof
CN103626578A (en)*2013-11-082014-03-12苏州仁成生物科技有限公司Multielement microbial fertilizer produced by fermenting corn straw and preparation method thereof
CN104446989A (en)*2014-12-042015-03-25侨健新能源科技(苏州)有限公司High-performance compound fertilizer for kidney bean
CN104447116A (en)*2014-12-042015-03-25侨健新能源科技(苏州)有限公司High-performance composite fertilizer for cucumber
CN104447093A (en)*2014-12-042015-03-25侨健新能源科技(苏州)有限公司High-fertility high-survival rate compound fertilizer for brassica chinensis
CN105009895A (en)*2015-07-142015-11-04太仓市惠勤农场专业合作社Cultivation method of high-yield pollution-free tomatoes
CN105076262A (en)*2015-08-272015-11-25湖州旭龙生物化学有限公司Botanical herbicide
CN105103851A (en)*2015-08-032015-12-02太仓市家欣农场专业合作社Intercropping planting method for corns and salviae miltiorrhizae
CN105165302A (en)*2015-07-142015-12-23太仓市惠勤农场专业合作社High-quality and high-yield culture method for bitter gourds
CN105481560A (en)*2015-12-232016-04-13成都新柯力化工科技有限公司Multifunctional organic water soluble fertilizer resisting plant diseases and insect pests and preparation method thereof
CN105801208A (en)*2016-03-032016-07-27四川省眉山益稷农业科技有限公司Method for producing organic fertilizer by straw decomposition
CN105875670A (en)*2014-11-242016-08-24北京衡荣科技有限公司Botanical organic pesticide for preventing and treating soil diseases and insect pests
CN106172524A (en)*2016-06-302016-12-07固镇县华丰农业有限公司A kind of special pesticide of nuisanceless Caulis et Folium Brassicae capitatae
CN106588500A (en)*2016-12-232017-04-26庆阳敦博科技发展有限公司Method for producing biological organic fertilizer by utilizing pericarpium zanthoxyli seed meal
CN108033858A (en)*2017-12-192018-05-15河南省农业科学院园艺研究所A kind of dedicated clayey soil modifying agent of industrialized agriculture
CN108530177A (en)*2018-05-292018-09-14天津天丰泽田生物科技有限公司A kind of efficient and environment-friendly type fertilizer

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CN101323542A (en)*2008-07-282008-12-17李海涛Plant acid corrosion organic fertilizer
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Cited By (20)

* Cited by examiner, † Cited by third party
Publication numberPriority datePublication dateAssigneeTitle
CN103478049A (en)*2013-10-152014-01-01苏州市相城区盛胡特种养殖专业合作社Method for feeding crayfishes by nano feeds
CN103626578B (en)*2013-11-082015-12-09顾祥茂With polynary microbial fertilizer of maize straw fermentative production and preparation method thereof
CN103613442A (en)*2013-11-082014-03-05苏州仁成生物科技有限公司Polyelement botanical bio-fertilizer and preparation method thereof
CN103626578A (en)*2013-11-082014-03-12苏州仁成生物科技有限公司Multielement microbial fertilizer produced by fermenting corn straw and preparation method thereof
CN105875670A (en)*2014-11-242016-08-24北京衡荣科技有限公司Botanical organic pesticide for preventing and treating soil diseases and insect pests
CN104446989A (en)*2014-12-042015-03-25侨健新能源科技(苏州)有限公司High-performance compound fertilizer for kidney bean
CN104447116A (en)*2014-12-042015-03-25侨健新能源科技(苏州)有限公司High-performance composite fertilizer for cucumber
CN104447093A (en)*2014-12-042015-03-25侨健新能源科技(苏州)有限公司High-fertility high-survival rate compound fertilizer for brassica chinensis
CN105165302A (en)*2015-07-142015-12-23太仓市惠勤农场专业合作社High-quality and high-yield culture method for bitter gourds
CN105009895A (en)*2015-07-142015-11-04太仓市惠勤农场专业合作社Cultivation method of high-yield pollution-free tomatoes
CN105103851A (en)*2015-08-032015-12-02太仓市家欣农场专业合作社Intercropping planting method for corns and salviae miltiorrhizae
CN105076262A (en)*2015-08-272015-11-25湖州旭龙生物化学有限公司Botanical herbicide
CN105076262B (en)*2015-08-272018-04-10湖州旭龙生物化学有限公司A kind of botanical herbicides
CN105481560A (en)*2015-12-232016-04-13成都新柯力化工科技有限公司Multifunctional organic water soluble fertilizer resisting plant diseases and insect pests and preparation method thereof
CN105801208A (en)*2016-03-032016-07-27四川省眉山益稷农业科技有限公司Method for producing organic fertilizer by straw decomposition
CN106172524A (en)*2016-06-302016-12-07固镇县华丰农业有限公司A kind of special pesticide of nuisanceless Caulis et Folium Brassicae capitatae
CN106588500A (en)*2016-12-232017-04-26庆阳敦博科技发展有限公司Method for producing biological organic fertilizer by utilizing pericarpium zanthoxyli seed meal
CN108033858A (en)*2017-12-192018-05-15河南省农业科学院园艺研究所A kind of dedicated clayey soil modifying agent of industrialized agriculture
CN108033858B (en)*2017-12-192020-09-22河南省农业科学院园艺研究所 A special clay soil conditioner for facility agriculture
CN108530177A (en)*2018-05-292018-09-14天津天丰泽田生物科技有限公司A kind of efficient and environment-friendly type fertilizer

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