Summary of the invention
The invention discloses oil shale in-situ vertical shaft pressure break chemistry method for destructive distillation and technique, fundamentally solved above-mentioned shortcoming and problem that underground mining, destructive distillation on the ground bring.
the method of shale oil gas is extracted in oil shale in-situ vertical shaft pressure break chemistry disclosed by the invention destructive distillation, and its technical solution is as follows:
According to oil shale layer situation, the pressure break of drilling on the ground burning well and several mouthfuls of derivation recovery wells are to subterranean oil shale layer, and deriving recovery well is honeycombed layout centered by pressure break burning well; In pressure break burning well, set up pressure break chamber, oil shale layer is carried out to pressure break; In pressure break burning well, inject oil shale layer high-pressure medium (air, water, quartz sand), in oil shale layer, pressure break goes out the crack of some 1-3mm, and in crack, blind upholder (quartz sand), sets up gas channel; In pressure break burning well, set up combustion chamber, to combustion chamber, inject inflammable gas and combustion-supporting gas, ignited flammable gas makes inflammable gas burn in combustion chamber bottom (combustiblematerials in light fluid shale), oil shale layer is heated to 550 ~ 600 ℃, realize resinous shale heating destructive distillation, drive and carry shale oil, gas; Shale oil, gas are derived ground by gas channel and derivation recovery well; In oil shale layer, by vertical shaft, pass into last bituminous matter and fixed carbon generation oxidizing reaction after oxygenant and oil shale distillation, the heat energy of generation, as the thermal source of follow-up destructive distillation, is realized the underground original position continuous carbonization of resinous shale and is extracted shale oil, gas; Shale oil, the gas of deriving ground are separated through ground gas-liquid separation device, and separated shale oil is delivered to product tank storage and sold; Combustible gas is delivered to gas power generator and is used for generating electricity.
realize oil shale in-situ vertical shaft pressure break chemistry of the present invention destructive distillation and extract the technique of shale oil gas method, comprise the following steps:
1) according to oil shale layer, distribute, move towards, selected pressure break burning well and derivation recovery well particular location, the pressure break of drilling on the ground burning well and derivation recovery well are to subterranean oil shale layer, pressure break burning well drilling depth should be as the criterion not penetrate oil shale layer, deriving recovery well should be as the criterion to penetrate oil shale layer, and described derivation recovery well is honeycombed layout centered by pressure break burning well;
2) in pressure break burning well, set up pressure break chamber, take out well casing, by pressure break burning well, to oil shale layer, inject high-pressure medium, oil shale layer pressure break is gone out to the crack of some 1-3mm, blind upholder quartz sand, sets up gas channel, and concrete steps are as follows:
1. drifting and well-flushing;
2. in pit shaft, be lowered to waterpower sleeve pipe shower nozzle;
3. closed casing and crag space, make oil shale layer form the pressure break space of sealing;
4. adopt waterpower sleeve pipe shower nozzle to carry out hydraulic jet perforation to oil shale layer, the mortar that first pumps into base fluid (water) and sand-carrying agent 20 ~ 35% carries out the cutting stage, when sand-carrying agent is during apart from nozzle 250m left and right, promote rapidly pump speed to guarantee to obtain the required enough pressure reduction (55 ~ 80MPa) of cutting perforation;
5. after abrasive perforating 2-3min, spray orifice detritus is replaced;
6. pump into again crosslinked guanidine glue and sand (ratio 20 ~ 30:40 ~ 60) to increase expansion dynamics;
7. open flow after pressing, sand washing support fracturing gap;
8. to filling liquid temporary plugging agent in pit shaft;
9. on, carry drilling tool, above carry drilling tool to design attitude, 3. one deck under pressure break, repeat ~ 6. walk.
3) at pressure break burning well, set up combustion chamber,
1. well-flushing, goes out ground by the sand water extraction in pressure break burning well,
2. pressure break burning well head is added to 0.5m Sealed casing pipe under oil shale layer, utilizes swelling agent closed casing and borehole wall space;
3. in pressure break burning well, install combustible gas and air input pipe and electronic ignition system additional, sealing well head, forms combustion chamber at resinous shale interval;
4. by combustible gas transfer lime, to combustion chamber, carry LPG and air; Utilize electronic ignition system to light combustible gas;
5. after light fluid shale, to oil shale layer, heat to 550 ~ 600 ℃, recording derives recovery well and comes temperature degree to reach 200 ℃, stops for combustible gas, drives and carries part shale oil, gas is derived recovery well to ground gas and oil separating plant by gas channel;
4) continue to inject high-pressure air in well, make in oil shale layer remaining bituminous matter and fixed carbon generation oxidizing reaction after destructive distillation, under hot conditions, carry out oxidizing reaction, produce new inflammable gas (drive simultaneously and carry shale oil, gas) by gas channel and derive recovery well and derive ground;
5) shale oil on derivation ground, gas are through the separation of ground gas-liquid separation device, and the shale oil separating is delivered to product tank storage and sold;
6) inflammable gas separating through gas-liquid separation device is delivered to gas power generator and is used for generating electricity.
Described derivation recovery well is six mouthfuls and is honeycombed layout.
Described high-pressure medium is selected from: air, water or mortar.
Described oxygenant is selected from: air or oxygen rich gas.
Described waterpower sleeve pipe shower nozzle, is mainly comprised of upper centralizer, spray gun, check valve, lower centralizer, screen casing, guide shoe, and the surface of spray gun is provided with nozzle, and one end of spray gun is communicated with sleeve pipe by short circuit, and the other end is communicated with screen casing by check valve; The outside cover of short circuit has upper centralizer; On the tube wall of screen casing, be evenly distributed with some sieve apertures, lower centralizer is enclosed within on screen casing, and guide shoe is fixed on the top of screen casing.
positively effect of the present invention is:utilize the underground in-situ extraction shale oil of resinous shale, by the chemical heat intensive treatment process of pressure break chemistry destructive distillation shale oil gas, removed a large amount of exploitations to oil shale mine, the environmental pollution of having avoided destructive distillation on the ground to bring from.The 2nd, utilize remaining bituminous matter after destructive distillation, fixed carbon, realized underground continuous carbonization, heat is self-sufficient.The 3rd, the process of chemical heat intensive treatment, is not single physical heating treating processes, neither underground spontaneous combustion treating processes, and in reaction process, rock inner pore progressively increases, and it is applicable to most oil shale formations.The present invention has less investment, operation cost is low, environmental pollution is little, resource utilization is high and the advantage such as produce oil aerogenesis instant effect.
Embodiment
By specific embodiment, describe below the beneficial effect of implementation process of the present invention and generation in detail, be intended to help reader to understand better essence of the present invention and feature, not as restriction that can practical range to this case.
embodiment 1
In conjunction with Fuyu County--ridge, Changchun oil shale mine is as implementing base, and Fuyu County---ridge, Changchun oil shale resources total reserves is 452.74 hundred million tons.Resinous shale average grade 5.53%, total resources that can commercial exploitation is 18,000,000,000, buried depth 160-800m, top board and base plate are beige shale, oil shale layer mean thickness 5m.
As shown in Figure 1, according to oil shale layer, distribute, move towards, selected pressure break burning well and derivation recovery well particular location, beat a bite pressure break burning well 1(well head diameter 200mm) and six mouthfuls of derivation recovery well 2(well head diameter 200mm) by subterranean strata 7 (380 meters apart from ground) to subterraneanoil shale layer 6; Shown in 2, pressure break burning well 1 is positioned at center by reference to the accompanying drawings, derives recovery well 2 for six mouthfuls and centered by pressure break burning well 1, is honeycombed distribution; The pressure break of drilling on the ground burning well and derivation recovery well are to subterranean oil shale layer, pressure break burning well drilling depth should be as the criterion not penetrate oil shale layer, deriving recovery well should be as the criterion to penetrate oil shale layer, and described derivation recovery well is honeycombed layout centered by pressure break burning well.
2) in pressure break burning well, set up pressure break chamber, take out well casing, by pressure break burning well, to oil shale layer, inject high-pressure medium, oil shale layer pressure break is gone out to the crack of some 1-3mm, blind upholder quartz sand, sets up gas channel, and concrete steps are as follows:
1. drifting and well-flushing;
2. in pit shaft, be lowered to waterpower sleeve pipe shower nozzle;
3. closed casing and crag space, make oil shale layer form the pressure break space of sealing;
4. adopt waterpower sleeve pipe shower nozzle to carry out hydraulic jet perforation tooil shale layer 6; in pressure break burning well 1, bymaterial conveyor 9, byfrac tank 13, tooil shale layer 6, inject base fluid (water) and sand-carrying agent (20 ~ 35% mortars) (cutting stage); when sand-carrying agent is during apart from nozzle 250m left and right; promote rapidly pump speed to guarantee that obtaining the required enough pressure reduction (55 ~ 80MPa) of cutting perforation goes out 1-3mm crack 12 byoil shale layer 6 pressure breaks
5. after abrasive perforating 2-3min, will spray empty detritus and replace;
6. the maximum pump speed allowing according to design annular space discharge capacity or annular space top pressure pumps into guanidine matrix liquid by annular space, according to design, by pumping into of oil pipe, is cross-linked guanidine glue and sand (increasing expansion dynamics);
7. open flow after pressing, remaining quartz sand becomes blind upholder, forms many gas channels 8, and many gas channels 8 collect and are communicated with derivation recovery well 2;
8. to filling liquid temporary plugging agent in pit shaft;
9. on, carry drilling tool, above carry drilling tool to design attitude, proceed upper strata fracturing process refracturing, until the whole pressure breaks of oil shale layer are complete.
3) at pressure break burning well, set up combustion chamber,
The first step, well-flushing, goes out ground by the sand water extraction in well,
Second step, well head is added to 0.5m Sealed casing pipe under oil shale layer, utilizes swelling agent closed casing and borehole wall space;
The 3rd step installs combustible gas and air input pipe and electronic ignition system additional in well, and sealing well head, forms combustion chamber at resinous shale interval;
The 4th step, LPG hold-upvessel 14 andoxygenant tank 15 add LPG and air by pressure break burning well 1 tooil shale layer 6 bymaterial conveyor 9, utilize electronic ignition system to light combustible gas;
The 6th step, after light fluid shale, heats to 550 ~ 600 ℃ tooil shale layer 6, and recording derives recovery well 2 and come temperature degree to reach 200 ℃, stops for combustible gas, drives and carries part shale oil, gas is derivedrecovery wells 2 to ground gas and oil separating plant 3 by gas channel 8;
By pass into contained bituminous matter and fixed carbon generation oxidizing reaction after oxygenant and oil shale distillation inoil shale layer 6, the heat energy of generation is as the thermal source of follow-up destructive distillation, laddering destructive distillation later stage resinous shale, and shale oil, the gas of generation pass through
4) bymaterial conveyor 9, byoxygenant tank 15, continued to the interior injection high-pressure air (air: 1000m of pressure break burning well 13/ hour), make inoil shale layer 6 remaining bituminous matter and fixed carbon after destructive distillation under hot conditions, carry out oxidizing reaction, produce new inflammable gas (drive simultaneously and carry shale oil, gas), by gas channel 8, by deriving recovery well 2 derivation ground, enter into gas-liquid separation device 3 again, realize underground in-situ extraction shale oil, gas;
5) shale oil on derivation ground, gas are through 3 separation of ground gas-liquid separation device, and the shale oil separating is delivered to product tank 4 storages byoil well pump 11 and sold.
6) inflammable gas separating through gas-liquid separation device 3 is delivered to gas power generator 5 bydispatch machine 10 and is used for generating electricity.
embodiment 2
In conjunction with front Guo's oil shale mine as implementing base, mining area total area 675.5km2,61.72 hundred million tons of total resources, 49.4 hundred million tons of exploitable resources amounts, resinous shale average grade 5%, buried depth 160-800m, top board and base plate are beige shale, oil shale layer mean thickness 6m.
As shown in Figure 1, according to oil shale layer, distribute, move towards, selected pressure break burning well and derivation recovery well particular location, beat a bite pressure break burning well 1(well head diameter 200mm) and six mouthfuls of derivation recovery well 2(well head diameter 200mm) by subterranean strata 7 (380 meters apart from ground) to subterraneanoil shale layer 6; Shown in 2, pressure break burning well 1 is positioned at center by reference to the accompanying drawings, derives recovery well 2 for six mouthfuls and centered by pressure break burning well 1, is honeycombed distribution; The pressure break of drilling on the ground burning well and derivation recovery well are to subterranean oil shale layer, pressure break burning well drilling depth should be as the criterion not penetrate oil shale layer, deriving recovery well should be as the criterion to penetrate oil shale layer, and described derivation recovery well is honeycombed layout centered by pressure break burning well.
2) in pressure break burning well, set up pressure break chamber, take out well casing, by pressure break burning well, to oil shale layer, inject high-pressure medium, oil shale layer pressure break is gone out to the crack of some 1-3mm, blind upholder quartz sand, sets up gas channel, and concrete steps are as follows:
1. drifting and well-flushing;
2. in pit shaft, be lowered to waterpower sleeve pipe shower nozzle;
3. closed casing and crag space, make oil shale layer form the pressure break space of sealing;
4. adopt waterpower sleeve pipe shower nozzle to carry out hydraulic jet perforation tooil shale layer 6, in pressure break burning well 1, bymaterial conveyor 9, byfrac tank 13, tooil shale layer 6, inject base fluid (water) and sand-carrying agent (20 ~ 35% mortars) (cutting stage), when sand-carrying agent is during apart from nozzle 250m left and right, promote rapidly pump speed to guarantee that obtaining the required enough pressure reduction (55 ~ 80MPa) of cutting perforation goes out 1-3mm crack 12 byoil shale layer 6 pressure breaks;
5. after abrasive perforating 2-3min, will spray empty detritus and replace;
6. the maximum pump speed allowing according to design annular space discharge capacity or annular space top pressure pumps into guanidine matrix liquid by annular space, according to design, by pumping into of oil pipe, is cross-linked guanidine glue and sand (increasing expansion dynamics);
7. open flow after pressing, remaining quartz sand becomes blind upholder, forms many gas channels 8, and many gas channels 8 collect and are communicated with derivation recovery well 2;
8. to filling liquid temporary plugging agent in pit shaft;
9. on, carry drilling tool, above carry drilling tool to design attitude, proceed upper strata fracturing process refracturing, until the whole pressure breaks of oil shale layer are complete.
3) at pressure break burning well, set up combustion chamber,
The first step, well-flushing, goes out ground by the sand water extraction in well,
Second step, well head is added to 0.5m Sealed casing pipe under oil shale layer, utilizes swelling agent closed casing and borehole wall space;
The 3rd step installs combustible gas and air input pipe and electronic ignition system additional in well, and sealing well head, forms combustion chamber at resinous shale interval;
The 4th step, LPG hold-upvessel 14 andoxygenant tank 15 add LPG and air by pressure break burning well 1 tooil shale layer 6 bymaterial conveyor 9, utilize electronic ignition system to light combustible gas;
The 6th step, after light fluid shale, heats to 550 ~ 600 ℃ tooil shale layer 6, and recording derives recovery well 2 and come temperature degree to reach 200 ℃, stops for combustible gas, drives and carries part shale oil, gas is derivedrecovery wells 2 to ground gas and oil separating plant 3 by gas channel 8;
By pass into contained bituminous matter and fixed carbon generation oxidizing reaction after oxygenant and oil shale distillation inoil shale layer 6, the heat energy of generation is as the thermal source of follow-up destructive distillation, laddering destructive distillation later stage resinous shale, and shale oil, the gas of generation pass through
4) bymaterial conveyor 9, byoxygenant tank 15, continued to the interior injection high-pressure air (air: 1000m of pressure break burning well 13/ hour), make inoil shale layer 6 remaining bituminous matter and fixed carbon after destructive distillation under hot conditions, carry out oxidizing reaction, produce new inflammable gas (drive simultaneously and carry shale oil, gas), by gas channel 8, by deriving recovery well 2 derivation ground, enter into gas-liquid separation device 3 again, realize underground in-situ extraction shale oil, gas;
The shale oil on derivation ground, gas are through 3 separation of ground gas-liquid separation device, and the shale oil separating is delivered to product tank 4 storages byoil well pump 11 and sold.
The inflammable gas separating through gas-liquid separation device 3 is delivered to gas power generator 5 bydispatch machine 10 and is used for generating electricity.
embodiment 3
According to Fig. 3, the waterpower sleeve pipe shower nozzle thatembodiment 1 ~ 2 relates to, mainly byupper centralizer 16,spray gun 17,check valve 19, lower centralizer 20,screen casing 22, guide shoe 23, sleeve pipe 23, short circuit 24, formed, wherein, the surface ofspray gun 17 is provided withnozzle 18, one end ofspray gun 17 is communicated with sleeve pipe 23 by short circuit 24, and the other end is communicated with screen casing 21 bycheck valve 19; The outside cover of short circuit 24 hasupper centralizer 16; On the tube wall of screen casing 21, be evenly distributed with some sieve apertures, lower centralizer 20 is enclosed within on screen casing 21, and guideshoe 22 is fixed on the top of screen casing 21.