CN102873949A - Manufacturing method of antiseptic flame-retarding static conductive composite coating for storage tank - Google Patents
Manufacturing method of antiseptic flame-retarding static conductive composite coating for storage tankDownload PDFInfo
- Publication number
- CN102873949A CN102873949ACN2012104120338ACN201210412033ACN102873949ACN 102873949 ACN102873949 ACN 102873949ACN 2012104120338 ACN2012104120338 ACN 2012104120338ACN 201210412033 ACN201210412033 ACN 201210412033ACN 102873949 ACN102873949 ACN 102873949A
- Authority
- CN
- China
- Prior art keywords
- storage tank
- coating
- composite coating
- retardation
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000576coating methodMethods0.000titleclaimsabstractdescription72
- 238000003860storageMethods0.000titleclaimsabstractdescription49
- 239000011248coating agentSubstances0.000titleclaimsabstractdescription47
- 230000003068static effectEffects0.000titleclaimsabstractdescription33
- 239000002131composite materialSubstances0.000titleclaimsabstractdescription29
- 230000002421anti-septic effectEffects0.000titleclaimsabstractdescription27
- 238000004519manufacturing processMethods0.000titleclaimsabstractdescription22
- 238000000034methodMethods0.000claimsabstractdescription21
- 238000006243chemical reactionMethods0.000claimsabstractdescription20
- 239000003822epoxy resinSubstances0.000claimsabstractdescription15
- 229920000647polyepoxidePolymers0.000claimsabstractdescription15
- 229920000877Melamine resinPolymers0.000claimsabstractdescription14
- 238000001914filtrationMethods0.000claimsabstractdescription14
- JDSHMPZPIAZGSV-UHFFFAOYSA-NmelamineChemical compoundNC1=NC(N)=NC(N)=N1JDSHMPZPIAZGSV-UHFFFAOYSA-N0.000claimsabstractdescription14
- 238000005406washingMethods0.000claimsabstractdescription12
- XLYOFNOQVPJJNP-UHFFFAOYSA-NwaterSubstancesOXLYOFNOQVPJJNP-UHFFFAOYSA-N0.000claimsabstractdescription11
- 238000001291vacuum dryingMethods0.000claimsabstractdescription10
- WQYSXVGEZYESBR-UHFFFAOYSA-Nthiophosphoryl chlorideChemical compoundClP(Cl)(Cl)=SWQYSXVGEZYESBR-UHFFFAOYSA-N0.000claimsabstractdescription8
- NINIDFKCEFEMDL-UHFFFAOYSA-NSulfurChemical compound[S]NINIDFKCEFEMDL-UHFFFAOYSA-N0.000claimsabstractdescription6
- 229910052717sulfurInorganic materials0.000claimsabstractdescription6
- 239000011593sulfurSubstances0.000claimsabstractdescription6
- 238000002360preparation methodMethods0.000claimsabstractdescription4
- 239000007787solidSubstances0.000claimsabstractdescription4
- 239000003063flame retardantSubstances0.000claimsdescription33
- RNFJDJUURJAICM-UHFFFAOYSA-N2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-trieneChemical compoundN=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1RNFJDJUURJAICM-UHFFFAOYSA-N0.000claimsdescription30
- HEMHJVSKTPXQMS-UHFFFAOYSA-MSodium hydroxideChemical group[OH-].[Na+]HEMHJVSKTPXQMS-UHFFFAOYSA-M0.000claimsdescription15
- 238000009503electrostatic coatingMethods0.000claimsdescription15
- 239000003795chemical substances by applicationSubstances0.000claimsdescription8
- 230000003750conditioning effectEffects0.000claimsdescription8
- 230000003292diminished effectEffects0.000claimsdescription5
- 241000370738ChlorionSpecies0.000claimsdescription4
- WGYKZJWCGVVSQN-UHFFFAOYSA-NpropylamineChemical compoundCCCNWGYKZJWCGVVSQN-UHFFFAOYSA-N0.000claimsdescription4
- 239000011247coating layerSubstances0.000claimsdescription3
- 239000006210lotionSubstances0.000claimsdescription3
- 239000002994raw materialSubstances0.000claimsdescription3
- 230000035484reaction timeEffects0.000claimsdescription3
- 238000004781supercoolingMethods0.000claimsdescription3
- 238000005260corrosionMethods0.000abstractdescription15
- 230000007797corrosionEffects0.000abstractdescription14
- 238000001816coolingMethods0.000abstractdescription3
- 239000005457ice waterSubstances0.000abstractdescription3
- TXBCBTDQIULDIA-UHFFFAOYSA-N2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diolChemical compoundOCC(CO)(CO)COCC(CO)(CO)COTXBCBTDQIULDIA-UHFFFAOYSA-N0.000abstract1
- 238000003912environmental pollutionMethods0.000abstract1
- 239000000047productSubstances0.000description13
- 230000007613environmental effectEffects0.000description9
- 239000000463materialSubstances0.000description6
- 239000007864aqueous solutionSubstances0.000description3
- 230000015572biosynthetic processEffects0.000description3
- 230000000694effectsEffects0.000description3
- 238000005755formation reactionMethods0.000description3
- IJGRMHOSHXDMSA-UHFFFAOYSA-NAtomic nitrogenChemical compoundN#NIJGRMHOSHXDMSA-UHFFFAOYSA-N0.000description2
- 229910000831SteelInorganic materials0.000description2
- 230000003487anti-permeability effectEffects0.000description2
- 239000007789gasSubstances0.000description2
- 229910052736halogenInorganic materials0.000description2
- 150000002367halogensChemical group0.000description2
- 239000010410layerSubstances0.000description2
- 239000002184metalSubstances0.000description2
- 239000003208petroleumSubstances0.000description2
- 239000012265solid productSubstances0.000description2
- 239000010959steelSubstances0.000description2
- 238000003756stirringMethods0.000description2
- VZGDMQKNWNREIO-UHFFFAOYSA-NtetrachloromethaneChemical compoundClC(Cl)(Cl)ClVZGDMQKNWNREIO-UHFFFAOYSA-N0.000description2
- OKTJSMMVPCPJKN-UHFFFAOYSA-NCarbonChemical compound[C]OKTJSMMVPCPJKN-UHFFFAOYSA-N0.000description1
- VEXZGXHMUGYJMC-UHFFFAOYSA-MChloride anionChemical compound[Cl-]VEXZGXHMUGYJMC-UHFFFAOYSA-M0.000description1
- 239000004593EpoxySubstances0.000description1
- VEXZGXHMUGYJMC-UHFFFAOYSA-NHydrochloric acidChemical compoundClVEXZGXHMUGYJMC-UHFFFAOYSA-N0.000description1
- 238000010521absorption reactionMethods0.000description1
- 239000007795chemical reaction productSubstances0.000description1
- 235000019504cigarettesNutrition0.000description1
- 239000008367deionised waterSubstances0.000description1
- 229910021641deionized waterInorganic materials0.000description1
- 238000010586diagramMethods0.000description1
- 239000000706filtrateSubstances0.000description1
- 238000000227grindingMethods0.000description1
- 229910052739hydrogenInorganic materials0.000description1
- 239000001257hydrogenSubstances0.000description1
- 229910000041hydrogen chlorideInorganic materials0.000description1
- IXCSERBJSXMMFS-UHFFFAOYSA-Nhydrogen chlorideSubstancesCl.ClIXCSERBJSXMMFS-UHFFFAOYSA-N0.000description1
- -1hydrogen halidesChemical class0.000description1
- 238000011835investigationMethods0.000description1
- 229910044991metal oxideInorganic materials0.000description1
- 150000004706metal oxidesChemical class0.000description1
- 229910052757nitrogenInorganic materials0.000description1
- 150000007524organic acidsChemical class0.000description1
- 231100000614poisonToxicity0.000description1
- 230000007096poisonous effectEffects0.000description1
- 239000002904solventSubstances0.000description1
Images
Landscapes
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
Abstract
Description
Technical field
The invention belongs to the composite coating technology field, particularly relate to a kind of antiseptic fire-retardation for storage tank and lead the manufacture method of static composite coating.
Background technology
At present, storage tank is requisite facility in oil storage, the transportation, the corrosivity of the oil product medium itself of storage and little in the tank, but in storing for a long time, transporting, moisture in the oil product can be deposited in tank bottom gradually, contains a large amount of CO in these water2, H2The materials such as S, chloride and organic acid, these material corrosivity are very strong, easily cause corrosion failure.At present tank bottom adopt with the epoxy static conducting coating as conduction matter such as graphite powder, conductive black, metal oxide, use a period of time after, the easy corrosion of storage tank bottom plate and perforation are found in investigation, and the phenomenon of boring a hole is general.In case storage tank corrosion perforation leakage of oil not only can affect the normal operation of production, causes huge economic loss, and environment is also caused certain pollution.In addition, oil is wildfire matter, therefore the anti-flammability of storage tank also receives increasing concern, former storage tank or do not use flame retardant coating, or the flame retardant coating that uses mostly is halogen-containing fire retardant, although flame retardant effect is better, there is in use thickness, discharges the shortcomings such as poisonous and corrosive hydrogen halides gas, hiding the technical problems such as secondary harm.
Summary of the invention
The present invention provides a kind of antiseptic fire-retardation for storage tank to lead the manufacture method of static composite coating for solving the technical problem that exists in the known technology.
The purpose of this invention is to provide a kind of storage tank antiseptic fire-retardation and lead the static composite coating, guarantee storage tank not corrosion perforation and leakage of oil, and make storage tank have good fire resistance, have surrounding environment pollution-freely, guarantee that the antiseptic fire-retardation that is used for storage tank of the characteristics such as petroleum storage and Transport Safety is led the manufacture method of static composite coating.
Storage tank antiseptic fire-retardation of the present invention is led the static composite coating, include storage tank bottom plate, solvent-free epoxy resin coating, environmental friendliness expansion type flame-retardant coatings and lead electrostatic coating and consist of, described storage tank bottom plate is identical with the storage tank bottom plate material of prior art, is steel material.Storage tank bottom plate is provided with the solvent-free epoxy resin coating through after the grinding process, is provided with the environmental friendliness expansion type flame-retardant coatings on the surface of solvent-free epoxy resin coating, is provided with on the surface of environmental friendliness expansion type flame-retardant coatings and leads electrostatic coating.
The antiseptic fire-retardation that the present invention is used for storage tank is led the technical scheme that the manufacture method of static composite coating takes:
A kind of antiseptic fire-retardation for storage tank is led the manufacture method of static composite coating, be characterized in: the storage tank bottom plate surface is provided with antiseptic fire-retardation and leads the static composite coating, is followed successively by from inside to outside solvent-free epoxy resin coating, expansion type flame-retardant coatings, leads electrostatic coating; Wherein, expansion type flame-retardant coatings is the sulfur-bearing expansion type flame-retardant coatings, and take bipentaerythrite, melamine and phosphorus thiochloride as raw material, preparation process may further comprise the steps:
(1) be that phosphorus thiochloride and the bipentaerythrite of 5.1-5.5:1 reacted 12-24 hour under 80-120 ° of C with mass ratio, after reaction finishes, behind supercooling, filtration under diminished pressure, with washing lotion washing three times, with filtration product vacuum drying 6-12 hour;
(2) step (1) products therefrom and water were reacted 0.5-1 hour under 80-100 ℃, then drip alkaline pH value conditioning agent, time for adding is 60-100 minute, be added dropwise to complete rear continuation reaction 60 minutes, add melamine, reaction temperature is 80-100 ℃, reaction time is 40-80 minute, after reaction finishes, remove chlorion with the frozen water washing, the filtration product vacuum drying is got Powdered faint yellow solid.
The manufacture method that the present invention leads the static composite coating for the antiseptic fire-retardation of storage tank can also adopt following technical measures:
Described antiseptic fire-retardation for storage tank is led the manufacture method of static composite coating, is characterized in: pH value conditioning agent is NaOH or propylamine, and dripping quantity is that the mol ratio of step ⑴ products therefrom and pH value conditioning agent is 1:2-2.5.The adjustable range of pH value is 6-7, is below or above this scope productive rate is descended.
Described antiseptic fire-retardation for storage tank is led the manufacture method of static composite coating, is characterized in: the addition of melamine is that the mol ratio of step ⑴ products therefrom and melamine is 1:2.
Described antiseptic fire-retardation for storage tank is led the manufacture method of static composite coating, is characterized in: the solvent-free epoxy resin coating layer thickness is 30-35 μ m, and expansion type flame-retardant coatings thickness is 15-25 μ m, and the thickness of leading electrostatic coating is 15-20 μ m.
Advantage and good effect that the present invention has are:
The antiseptic fire-retardation that is used for storage tank is led the manufacture method of static composite coating owing to having adopted the brand-new technical scheme of the present invention, and compared with prior art, the synthetic environment in the processing step of the present invention is the aqueous solution, need not to use flammable solvent and nitrogen protection.The synthetic environmental friendliness expansion type flame-retardant coatings that obtains of this technique, i.e. sulfur-bearing (S) expansion type flame-retardant coatings, fire resistance is high, belongs to Halogen, low cigarette, efficient environmental-protection flame-retardant coating.
Overall structure of the present invention is simple, and the solvent-free epoxy resin coating has high corrosion-resistant and anti-permeability performance as anti-corrosion insulating layer, plays the corrosion-resistant purpose, and can thoroughly isolate and lead electrostatic coating and storage tank bottom plate metal formation galvanic corrosion; The environmental friendliness expansion type flame-retardant coatings can play the purpose of highly effective flame-retardant, and pollution-free to surrounding environment in fire-retardant; The particular path of leading electrostatic coating can realize leading the purpose of static.Owing to being easy to when pin hole appears in surface of insulating layer detect, can realize the coating free of pinholes fully technically, stopped the problem of corrosion passage and galvanic corrosion.The prepared antiseptic fire-retardation of the present invention is led the static composite coating, has good anticorrosion and fire resistance, and is pollution-free to surrounding environment, and realizes leading the purpose of static.
Description of drawings
Fig. 1 is the manufacture method frame structure schematic diagram of leading the static composite coating for the antiseptic fire-retardation of storage tank.
Among Fig. 1,1-storage tank bottom plate, 2-solvent-free epoxy resin coating, 3-expansion type flame-retardant coatings, 4-lead electrostatic coating.
The specific embodiment
For further understanding summary of the invention of the present invention, Characteristic, hereby exemplify following examples, and cooperate accompanying drawing to be described in detail as follows:
A kind of antiseptic fire-retardation for storage tank is led the manufacture method of static composite coating, it is characterized in that: the storage tank bottom plate surface is provided with antiseptic fire-retardation and leads the static composite coating, is followed successively by from inside to outside solvent-free epoxy resin coating, expansion type flame-retardant coatings, leads electrostatic coating; Wherein, expansion type flame-retardant coatings is the sulfur-bearing expansion type flame-retardant coatings, and take bipentaerythrite, melamine and phosphorus thiochloride as raw material, preparation process may further comprise the steps:
(1) be that the phosphorus thiochloride of 5.1-5.5:1 and bipentaerythrite are 80-120 ℃ of lower reaction 12-24 hour, after reaction finishes, behind supercooling, filtration under diminished pressure, with washing lotion washing three times, with filtration product vacuum drying 6-12 hour with mass ratio;
(2) step (1) products therefrom and water were reacted 0.5 hour under 80-100 ℃, then drip alkaline pH value conditioning agent NaOH, transfer pH value 6-7, dripping quantity is that the mol ratio of step ⑴ products therefrom and pH value conditioning agent is 1:2-2.5; Time for adding is 60-100 minute, is added dropwise to complete rear continuation reaction 60 minutes, adds melamine, and the addition of melamine is that the mol ratio of step ⑴ products therefrom and melamine is 1:2; Reaction temperature is 80-100 ° of C, and the reaction time is 40-80 minute, after reaction finishes, removes chlorion with the frozen water washing, and the filtration product vacuum drying is got Powdered faint yellow solid.
The solvent-free epoxy resin coating layer thickness is 30-35 μ m, and expansion type flame-retardant coatings thickness is 15-25 μ m, and the thickness of leading electrostatic coating is 15-20 μ m.
The concrete manufacturing process of the present embodiment is described and is described as follows:
The storage tank antiseptic fire-retardation is led the static composite coating, includes storagetank bottom plate 1, solvent-freeepoxy resin coating 2, environmental friendliness expansion type flame-retardant coatings 3, leadselectrostatic coating 4 formations.Described storagetank bottom plate 1 is identical with the storage tank bottom plate material of prior art, is steel material; Described solvent-freeepoxy resin coating 2 is arranged on thetank bottom 1, has high corrosion-resistant and anti-permeability performance, plays the corrosion-resistant purpose, and can thoroughly isolate and lead electrostatic coating and storage tank bottom plate metal formation galvanic corrosion; Described environmental friendliness expansion type flame-retardant coatings 3 is arranged on the solvent-freeepoxy resin coating 2, can play the purpose of highly effective flame-retardant, and pollution-free to surrounding environment in fire-retardant; The describedelectrostatic coating 4 of leading is arranged on the environmental friendliness expansion type flame-retardant coatings 3, and the particular path of leadingelectrostatic coating 4 can realize leading the purpose of static.
Described environmental friendliness expansion type flame-retardant coatings, i.e. sulfur-bearing (S) expansion type flame-retardant coatings, implementation process is as follows:
Add bipentaerythrite 78g and phosphorus thiochloride 250mL in the 500mL there-necked flask, the mechanical agitator vigorous stirring is used in the oil bath that places 100 ° of C, reacts 24 hours, with the hydrogen chloride gas that produces in the NaOH aqueous solution absorption reaction.After reaction finishes, with ice-water bath cooling, filtration under diminished pressure, with the carbon tetrachloride washing, will leach at room temperature (20 ° of C) vacuum drying of thing 6 hours, obtain solid product (productive rate 78%).Go solid product to be dissolved in the there-necked flask of 500mL water, place the water-bath of 90 ° of C, then stirring reaction 0.5 hour drips 2mol/L NaOH aqueous solution 200ml, and time for adding 2 hours is added dropwise to complete and continues reaction 30 minutes.The melamine that then adds 50.4g reacted 2 hours.After reaction finishes, with ice-water bath cooling, filtration under diminished pressure, wash to the filtrate without till the chlorion with the ice deionized water.Filtration product vacuum drying in 60 ° of C was obtained end-product (productive rate 94%) in 8 hours.
The present embodiment is guaranteed storage tank not corrosion perforation and leakage of oil, and makes storage tank have good fire resistance, and is pollution-free to surrounding environment, guarantees petroleum storage and Transport Safety, has described good effect.
Claims (4)
1. an antiseptic fire-retardation that is used for storage tank is led the manufacture method of static composite coating, it is characterized in that: the storage tank bottom plate surface is provided with antiseptic fire-retardation and leads the static composite coating, is followed successively by from inside to outside solvent-free epoxy resin coating, expansion type flame-retardant coatings, leads electrostatic coating; Wherein, expansion type flame-retardant coatings is the sulfur-bearing expansion type flame-retardant coatings, and take bipentaerythrite, melamine and phosphorus thiochloride as raw material, preparation process may further comprise the steps:
(1) be that phosphorus thiochloride and the bipentaerythrite of 5.1-5.5:1 reacted 12-24 hour under 80-120 ° of C with mass ratio, after reaction finishes, behind supercooling, filtration under diminished pressure, with washing lotion washing three times, with filtration product vacuum drying 6-12 hour;
(2) step (1) products therefrom and water were reacted 0.5-1 hour under 80-100 ° of C, then drip alkaline pH value conditioning agent, time for adding is 60-100 minute, be added dropwise to complete rear continuation reaction 60 minutes, add melamine, reaction temperature is 80-100 ° of C, reaction time is 40-80 minute, after reaction finishes, remove chlorion with the frozen water washing, the filtration product vacuum drying is got Powdered faint yellow solid.
2. the antiseptic fire-retardation for storage tank according to claim 1 is led the manufacture method of static composite coating, it is characterized in that:
PH value conditioning agent is NaOH or propylamine, and dripping quantity is that the mol ratio of step ⑴ products therefrom and pH value conditioning agent is 1:2-2.5.
3. the antiseptic fire-retardation for storage tank according to claim 1 is led the manufacture method of static composite coating, it is characterized in that:
The addition of melamine is that the mol ratio of step ⑴ products therefrom and melamine is 1:2.
4. according to claim 1,2,3 or 4 described antiseptic fire-retardations for storage tank are led the manufacture method of static composite coating, it is characterized in that: the solvent-free epoxy resin coating layer thickness is 30-35 μ m, expansion type flame-retardant coatings thickness is 15-25 μ m, and the thickness of leading electrostatic coating is 15-20 μ m.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210412033.8ACN102873949B (en) | 2012-10-24 | 2012-10-24 | Manufacturing method of antiseptic flame-retarding static conductive composite coating for storage tank |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210412033.8ACN102873949B (en) | 2012-10-24 | 2012-10-24 | Manufacturing method of antiseptic flame-retarding static conductive composite coating for storage tank |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102873949Atrue CN102873949A (en) | 2013-01-16 |
| CN102873949B CN102873949B (en) | 2015-02-04 |
Family
ID=47475568
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210412033.8AExpired - Fee RelatedCN102873949B (en) | 2012-10-24 | 2012-10-24 | Manufacturing method of antiseptic flame-retarding static conductive composite coating for storage tank |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102873949B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107738844A (en)* | 2017-10-11 | 2018-02-27 | 沈阳拓界材料科技有限公司 | A kind of steel storage tank |
| US20220340357A1 (en)* | 2018-09-05 | 2022-10-27 | Christos Haritou | Wall Structure Monitoring System |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1152012A (en)* | 1995-12-15 | 1997-06-18 | 中国人民解放军海军后勤技术装备研究所 | Fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint |
| JP2004168829A (en)* | 2002-11-18 | 2004-06-17 | Yaskawa Electric Corp | Epoxy resin composition and vacuum equipment using the same |
| CN101474907A (en)* | 2009-01-08 | 2009-07-08 | 深圳市赛凌节能新材料科技有限公司 | Multifunctional composite coating of oil gas storage tank and preparation method thereof |
| CN101974167A (en)* | 2010-10-22 | 2011-02-16 | 天津工业大学 | Intumescent flame retardant and synthesis method thereof |
| CN102417765A (en)* | 2011-11-28 | 2012-04-18 | 兰州石化职业技术学院 | Preparation method of double-component chlorosulfonated polyethylene heavy-duty anticorrosive static conductive coating |
| CN202323033U (en)* | 2011-11-11 | 2012-07-11 | 天津亿利科能源科技发展股份有限公司 | Submarine pipeline armillary sacrificial anode |
- 2012
- 2012-10-24CNCN201210412033.8Apatent/CN102873949B/ennot_activeExpired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1152012A (en)* | 1995-12-15 | 1997-06-18 | 中国人民解放军海军后勤技术装备研究所 | Fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint |
| JP2004168829A (en)* | 2002-11-18 | 2004-06-17 | Yaskawa Electric Corp | Epoxy resin composition and vacuum equipment using the same |
| CN101474907A (en)* | 2009-01-08 | 2009-07-08 | 深圳市赛凌节能新材料科技有限公司 | Multifunctional composite coating of oil gas storage tank and preparation method thereof |
| CN101974167A (en)* | 2010-10-22 | 2011-02-16 | 天津工业大学 | Intumescent flame retardant and synthesis method thereof |
| CN202323033U (en)* | 2011-11-11 | 2012-07-11 | 天津亿利科能源科技发展股份有限公司 | Submarine pipeline armillary sacrificial anode |
| CN102417765A (en)* | 2011-11-28 | 2012-04-18 | 兰州石化职业技术学院 | Preparation method of double-component chlorosulfonated polyethylene heavy-duty anticorrosive static conductive coating |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107738844A (en)* | 2017-10-11 | 2018-02-27 | 沈阳拓界材料科技有限公司 | A kind of steel storage tank |
| US20220340357A1 (en)* | 2018-09-05 | 2022-10-27 | Christos Haritou | Wall Structure Monitoring System |
| US12269244B2 (en)* | 2018-09-05 | 2025-04-08 | Christos Haritou | Wall structure monitoring system |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102873949B (en) | 2015-02-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Qian et al. | Cations coordination‐regulated reversibility enhancement for aqueous Zn‐ion battery | |
| TW437113B (en) | Non-aqueous electrolyte secondary cell | |
| CN104746081B (en) | Functionalization imidazole ion liquid corrosion inhibiter and its preparation method and application | |
| Yusuf et al. | Synthesis and structures of divalent Co, Ni, Zn and Cd complexes of mixed dichalcogen and dipnictogen ligands with corrosion inhibition properties: experimental and computational studies | |
| CN107556796B (en) | A kind of preparation method of lightweight calcium phosphate zinc anti-corrosion paint | |
| CN104610794A (en) | Phosphor-nitrogen intumescent flame retardant, and synthetic method and applications thereof | |
| JP2006307339A (en) | Corrosion prevention method for metal material, high corrosion resistance metal material and method for producing the same | |
| CN102392674A (en) | Compounded latex retardant for preventing coal spontaneous combustion and preparation method thereof | |
| CN106189366A (en) | An a kind of step in-situ synthesis of organo-mineral complexing anti-corrosion paint | |
| CN105177561A (en) | Aluminum or aluminum alloy protection chromium-free passivation solution, preparation method and aluminum or aluminum alloy surface protection method thereof | |
| CN105295646A (en) | Acid-resisting, wear-resisting and corrosion-resisting flexible ceramic coating composition and preparing method thereof | |
| Altwaiq et al. | Sodium lignosulfonate as a friendly-environment corrosion inhibitor for zinc metal in acidic media | |
| CN102873949B (en) | Manufacturing method of antiseptic flame-retarding static conductive composite coating for storage tank | |
| CN103254736A (en) | Polyaniline powder paint with acid-resistant self-repair function and preparation method thereof | |
| CN108314951A (en) | A kind of preparation method of steel structure aqueous anti-corrosion fire resistant coating material | |
| CN112592637B (en) | New energy automobile power battery box shell fireproof and corrosion-resistant coating and preparation method and application thereof | |
| CN102690545B (en) | Electric equipment moisture resistance, corrosion resistance and insulation protection agent and preparation method thereof | |
| Zunita et al. | Investigation of corrosion inhibition activity of 3-butyl-2, 4, 5-triphenylimidazole and 3-butyl-2-(2-butoxyphenyl)-4, 5-diphenylimidazole toward carbon steel in 1% NaCl solution | |
| CN101717608B (en) | Conductive anti-corrosion coating of electric power grounding grid and preparation method thereof | |
| CN105694667A (en) | Thick-layered thermal-insulated anticorrosion epoxy paint | |
| CN107986662A (en) | A kind of hydrotalcite intercalation 2- amino -5- sulfydryls -1,3,4- thiadiazoles corrosion inhibitor and its application | |
| CN104762009B (en) | Nano modified polyurethane flame-retardant waterproof coating and preparation method thereof | |
| CN108084990A (en) | A kind of inorganic anti-corrosion pigment with warning function | |
| CN104341612A (en) | Phosphorus and nitrogen flame retardant and preparation method thereof | |
| CN107988601A (en) | A kind of hydrotalcite intercalation 5- methyl isophthalic acids, 3,4,-thiadiazoles -2- sulfydryls corrosion inhibitor and its application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | Denomination of invention:Manufacturing method of antiseptic flame-retarding static conductive composite coating for storage tank Effective date of registration:20151123 Granted publication date:20150204 Pledgee:Pudong Shanghai Development Bank Limited by Share Ltd. Tianjin branch Pledgor:E-TECH ENERGY TECHNOLOGY DEVELOPMENT Corp. Registration number:2015120000074 | |
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right | Date of cancellation:20170217 Granted publication date:20150204 Pledgee:Pudong Shanghai Development Bank Limited by Share Ltd. Tianjin branch Pledgor:E-TECH ENERGY TECHNOLOGY DEVELOPMENT Corp. Registration number:2015120000074 | |
| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | Denomination of invention:Manufacturing method of antiseptic flame-retarding static conductive composite coating for storage tank Effective date of registration:20170303 Granted publication date:20150204 Pledgee:Pudong Shanghai Development Bank Limited by Share Ltd. Tianjin branch Pledgor:E-TECH ENERGY TECHNOLOGY DEVELOPMENT Corp. Registration number:2017120000006 | |
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right | Date of cancellation:20180510 Granted publication date:20150204 Pledgee:Pudong Shanghai Development Bank Limited by Share Ltd. Tianjin branch Pledgor:E-TECH ENERGY TECHNOLOGY DEVELOPMENT Corp. Registration number:2017120000006 | |
| PE01 | Entry into force of the registration of the contract for pledge of patent right | Denomination of invention:Manufacturing method of antiseptic flame-retarding static conductive composite coating for storage tank Effective date of registration:20180611 Granted publication date:20150204 Pledgee:Pudong Shanghai Development Bank Limited by Share Ltd. Tianjin branch Pledgor:E-TECH ENERGY TECHNOLOGY DEVELOPMENT Corp. Registration number:2018120000018 | |
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right | Date of cancellation:20190521 Granted publication date:20150204 Pledgee:Pudong Shanghai Development Bank Limited by Share Ltd. Tianjin branch Pledgor:E-TECH ENERGY TECHNOLOGY DEVELOPMENT Corp. Registration number:2018120000018 | |
| PE01 | Entry into force of the registration of the contract for pledge of patent right | Denomination of invention:Manufacturing method of antiseptic flame-retarding static conductive composite coating for storage tank Effective date of registration:20190612 Granted publication date:20150204 Pledgee:Pudong Shanghai Development Bank Limited by Share Ltd. Tianjin branch Pledgor:E-TECH ENERGY TECHNOLOGY DEVELOPMENT Corp. Registration number:2019120000021 | |
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right | Date of cancellation:20191210 Granted publication date:20150204 Pledgee:Pudong Shanghai Development Bank Limited by Share Ltd. Tianjin branch Pledgor:E-TECH ENERGY TECHNOLOGY DEVELOPMENT Corp. Registration number:2019120000021 | |
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | Denomination of invention:Manufacturing method of antiseptic flame-retarding static conductive composite coating for storage tank Effective date of registration:20191218 Granted publication date:20150204 Pledgee:Pudong Shanghai Development Bank Limited by Share Ltd. Tianjin branch Pledgor:E-TECH ENERGY TECHNOLOGY DEVELOPMENT Corp. Registration number:Y2019120000025 | |
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee | Granted publication date:20150204 Termination date:20211024 |