Summary of the invention
The present invention organically combines chemical method, microbial method and physics method, combination is handled in sanitary sewage disposal and emulsifying liquid waste water, cultivate and activated sludge absorption by oily water separation, chemical demulsification, gravity separation, active sludge microorganism, carrying out process integrations such as anaerobic biological treatment and aerobic biological treatment again handles emulsifying liquid waste water, final emulsifying liquid waste water water outlet reaches emission request or reuse water requirement, this invention, by rational combination, the absorption property running cost that makes full use of active sludge is low, treatment effect is good, and sludge quantity is few.
Implementation method of the present invention is as follows:
At first sanitary sewage and emulsifying liquid waste water are introduced different equalizing tank sanitary sewage equalizing tank 1 and emulsifying liquid waste water equalizing tank 3 respectively.
A sanitary sewage part enters in the aerobic biochemical process sanitary sewage disposal unit 2 carries out biochemical treatment, and main purpose is to carry out active sludge microorganism to cultivate, and a sanitary sewage part enters emulsion anaerobic biological treatment unit 8.
4 pairs of emulsifying liquid waste waters carry out oily water separation to emulsifying liquid waste water in the oily water separation unit, oily substance enters 12 pairs of waste oil of oil storage unit and collects, emulsifying liquid waste water through oily water separation enters breakdown of emulsion and solid-liquid separation unit 5, the clear liquid of breakdown of emulsion and solid-liquid separation unit enters pH adjustment unit 6, the emulsifying liquid waste water of adjusting through pH enters activated sludge absorption processing unit 7, the emulsifying liquid waste water clear liquid of handling through activated sludge absorption enters anaerobic biological treatment unit 8, clear liquid after anaerobic biological treatment enters aerobe processing unit 9, and the clear liquid after aerobe is handled enters discharging pond 10.
The mud that aerobic biochemical process sanitary sewage disposal unit 2, breakdown of emulsion and solid-liquid separation unit 5, activated sludge absorption processing unit 7, anaerobic biological treatment unit 8, aerobe processing unit 9 produce enters mud and concentrates anddewatering unit 11.
Innovative point of the present invention mainly contains as follows:
1, carrying out active domestic sludge with sanitary sewage cultivates, utilize the domestic sludge that produces in the sanitary sewage disposal process that the pollution substance of emulsifying liquid waste water is carried out adsorption treatment, the active sludge that produces in nutritive substance in the ingenious use sanitary sewage and the sanitary sewage disposal process.
2, use heat treated and add milk of lime and polyacrylamide PAM combination at emulsion breakdown of emulsion and solid-liquid separation link, do not use coagulating agent such as polymerize aluminum chloride or bodied ferric sulfate, sludge quantity is few, good effect of separating solid from liquid during precipitation.
3, the present invention has organically combined chemical method, microbial method and physics method, ingenious combination by technology, moving on the basis cheaply, the solid mud oleaginousness that produces is low, need not dispose, and make emulsifying liquid waste water reach the emission request of three grades of emission standards of GB8978-1996 " integrated wastewater discharge standard " according to danger wastes.
Embodiment
The present invention will be further described below in conjunction with drawings and Examples.
As shown in Figure 1, at first sanitary sewage and emulsifying liquid waste water are introduced different equalizing tank sanitary sewage equalizing tank 1 and emulsifying liquid waste water equalizing tank 3 respectively, introduce the water yield of sanitary sewage and the water yield of emulsifying liquid waste water and can be controlled in certain proportional range, promptly the water yield ratio of the water yield of sanitary sewage and emulsifying liquid waste water generally should be greater than 2: 1.
A sanitary sewage part enters in the aerobic biochemical process sanitary sewage disposal unit 2 carries out biochemical treatment, the sanitary sewage amount that enters this processing unit is determined according to the treatment capacity of emulsifying liquid waste water, the water yield of control sanitary sewage is more than 1 times of activated sludge absorption processing unit 7 emulsifying liquid waste water flooding quantitys, this processing unit is common domestic sewage treatment process, can be that sequencing batch active sludge also can be other sewage activated sludge method commonly used, sanitary sewage is handled through aeration and biological, the sanitary sewage chemical oxygen demand COD is reduced to below the 100mg/l by influent concentration, this processing unit main purpose is to carry out active sludge microorganism to cultivate, the active sludge excess sludge of cultivating all enters activated sludge absorption processing unit 7, for the activated sludge absorption processing unit provides active sludge.A sanitary sewage part enters emulsion anaerobic biological treatment unit 8, and the sanitary sewage water yield that enters emulsion anaerobic biological treatment unit 8 is to enter more than 0.5 times of this unitary emulsifying liquid waste water amount.
4 pairs of emulsifying liquid waste waters carry out oily water separation to emulsifying liquid waste water in the oily water separation unit, oily substance enters 12 pairs of waste oil of oil storage unit and collects, emulsifying liquid waste water through oily water separation enters breakdown of emulsion and solid-liquid separation unit 5, in emulsion breakdown of emulsion and solid-liquid separation unit 5 during breakdown of emulsion, in emulsion, add the milk of lime of calcium hydroxide preparation, it is 100mg/l-2000mg/l that calcium hydroxide gets consumption, more than the pH regulator to 10; Clear liquid after the solid-liquid separation enters pH adjustment unit 6 afterwards, utilize hydrochloric acid or sulfuric acid that pH is adjusted into 6-9, the emulsifying liquid waste water of adjusting through pH enters activated sludge absorption processing unit 7, in activated sludge absorption processing unit 7 by aerobic biochemical process sanitary sewage disposal unit 2 in the row active sludge and the emulsion of coming stir, alr mode can be a pneumatic blending, waterpower stirs or mechanical stirring, reaction times is 5 minutes-120 minutes, reaction is after solid-liquid separation, the emulsifying liquid waste water clear liquid enters anaerobic biological treatment unit 8, mix with the sanitary sewage that enters anaerobic biological treatment unit 8 and to carry out anaerobic biological treatment, clear liquid after anaerobic biological treatment enters aerobe processing unit 9, emulsion clear liquid COD concentration after aerobe is handled is reduced to below the 500mg/l, reach the emission request of three grades of emission standards of GB8978-1996 " integrated wastewater discharge standard ", the waste water that reaches emission request enters discharging pond 10.
The mud that aerobic biochemical process sanitary sewage disposal unit 2, breakdown of emulsion and solid-liquid separation unit 5, activated sludge absorption processing unit 7, anaerobic biological treatment unit 8, aerobe processing unit 9 produce enters mud and concentrates anddewatering unit 11, and the sewage backflow that mud concentrates anddewatering unit 11 produces is handled to aerobic biochemical process sanitary sewage disposal unit 2.
Specific embodiment
Embodiment 1
Wuxi City mechanical fitting manufacturing enterprise workshop produces emulsifying liquid waste water in process of production, this emulsifying liquid waste water COD15780mg/l, pH6.7, mineral oil content 1200mg/l, the water yield is 0.8 ton/day, for handling emulsifying liquid waste water, other utilizes 1.6 tons/day in this enterprise's daily life sewage, sanitary sewage water-quality COD 326mg/l, pH6.9, wherein sanitary sewage enters in the aerobic biochemical process sanitary sewage disposal unit 2 0.8 ton/day, enters in the anaerobic biological treatment unit 8 0.8 ton/day.Emulsion water quality after oily water separation is COD7636mg/l, at breakdown of emulsion and solid-liquid separation unit calcium hydroxide consumption is 1000mg/l, be heated to 50 ℃, 10 minutes stirring reaction time, by the time during normal temperature, add PAM10mg/l, 10 minutes stirring reaction time, through precipitating 1 hour, supernatant C OD reduces to 3105mg/l, clear liquid enters pH adjustment unit 6, utilize hydrochloric acid that pH is adjusted into 6-9, supernatant liquor enters in the activated sludge absorption processing unit 7, mixes with the active sludge of coming in, adopted aeration agitation 10 minutes, precipitate that supernatant C OD reduces to 2427mg/l after 1 hour, supernatant liquor enters in the anaerobic biological treatment unit 8, mixes with sanitary sewage in entering anaerobic biological treatment unit 8, hydraulic detention time is 16 hours, supernatant C OD will be 849mg/l, and supernatant liquor enters aerobe processing unit 9, hydraulic detention time 8 hours, COD will be 384mg/l, reach the emission request of three grades of emission standards of GB8978-1996 " integrated wastewater discharge standard ".
Embodiment 2
Wuxi City mechanical fitting manufacturing enterprise workshop produces emulsifying liquid waste water in process of production, this emulsifying liquid waste water COD15780mg/l, pH6.7, mineral oil content 1200mg/l, the water yield is 0.8 ton/day, for handling emulsifying liquid waste water, other utilizes 3.2 tons/day in this enterprise's daily life sewage, sanitary sewage water-quality COD 326mg/l, pH6.9, wherein sanitary sewage enters in the aerobic biochemical process sanitary sewage disposal unit 2 1.6 tons/day, enters in the anaerobic biological treatment unit 8 1.6 tons/day.Emulsion water quality after oily water separation is COD7636mg/l, at breakdown of emulsion and solid-liquid separation unit calcium hydroxide consumption is 1000mg/l, be heated to 50 ℃, 10 minutes stirring reaction time, by the time during normal temperature, add PAM5mg/l, 10 minutes stirring reaction time, through precipitating 1 hour, supernatant C OD reduces to 3105mg/l, clear liquid enters pH adjustment unit 6, utilize sulfuric acid that pH is adjusted into 6-9, supernatant liquor enters in the activated sludge absorption processing unit 7, mixes with the active sludge of coming in, adopted aeration agitation 10 minutes, precipitate that supernatant C OD reduces to 1873mg/l after 1 hour, supernatant liquor enters in the anaerobic biological treatment unit 8, mixes with sanitary sewage in entering anaerobic biological treatment unit 8, hydraulic detention time is 16 hours, supernatant C OD will be 464mg/l, and supernatant liquor enters aerobe processing unit 9, hydraulic detention time 8 hours, COD will be 237mg/l, reach the emission request of three grades of emission standards of GB8978-1996 " integrated wastewater discharge standard ".
Embodiment 3
Wuxi City mechanical fitting manufacturing enterprise workshop produces emulsifying liquid waste water in process of production, this emulsifying liquid waste water COD15780mg/l, pH6.7, mineral oil content 1200mg/l, the water yield is 0.8 ton/day, for handling emulsifying liquid waste water, other utilizes 3.2 tons/day in this enterprise's daily life sewage, sanitary sewage water-quality COD 326mg/l, pH6.9, wherein sanitary sewage enters in the aerobic biochemical process sanitary sewage disposal unit 2 1.6 tons/day, enters in the anaerobic biological treatment unit 8 1.6 tons/day.Emulsion water quality after oily water separation is COD7636mg/l, at breakdown of emulsion and solid-liquid separation unit calcium hydroxide consumption is 1000mg/l, 30 minutes stirring reaction time, by the time during normal temperature, add PAM15mg/l, 10 minutes stirring reaction time, through staticly settling 2 hours, supernatant C OD reduces to 2971mg/l, and clear liquid enters pH adjustment unit 6, utilizes hydrochloric acid that pH is adjusted into 6-9, supernatant liquor enters in the activated sludge absorption processing unit 7, mix with the active sludge of coming in, adopted aeration agitation 10 minutes, precipitate that supernatant C OD reduces to 1646mg/l after 1 hour, supernatant liquor enters in the anaerobic biological treatment unit 8, mix with the sanitary sewage in entering anaerobic biological treatment unit 8, hydraulic detention time is 16 hours, and supernatant C OD will be 495mg/l, supernatant liquor enters aerobe processing unit 9, hydraulic detention time 8 hours, COD will be 325mg/l, reach the emission request of three grades of emission standards of GB8978-1996 " integrated wastewater discharge standard ".
Embodiment 4
Wuxi City mechanical fitting manufacturing enterprise workshop produces emulsifying liquid waste water in process of production, this emulsifying liquid waste water COD15780mg/l, pH6.7, mineral oil content 1200mg/l, the water yield is 0.8 ton/day, for handling emulsifying liquid waste water, other utilizes 3.2 tons/day in this enterprise's daily life sewage, sanitary sewage water-quality COD 326mg/l, pH6.9, wherein sanitary sewage enters in the aerobic biochemical process sanitary sewage disposal unit 2 1.6 tons/day, enters in the anaerobic biological treatment unit 8 1.6 tons/day.Emulsion water quality after oily water separation is COD7636mg/l, at breakdown of emulsion and solid-liquid separation unit calcium hydroxide consumption is 2000mg/l, 10 minutes stirring reaction time, by the time during normal temperature, add PAM50mg/l, 10 minutes stirring reaction time, through precipitating 1 hour, supernatant C OD reduces to 2651mg/l, and clear liquid enters pH adjustment unit 6, utilizes sulfuric acid that pH is adjusted into 6-9, supernatant liquor enters in the activated sludge absorption processing unit 7, mix with the active sludge of coming in, adopted aeration agitation 10 minutes, precipitate that supernatant C OD reduces to 1873mg/l after 1 hour, supernatant liquor enters in the anaerobic biological treatment unit 8, mix with the sanitary sewage in entering anaerobic biological treatment unit 8, hydraulic detention time is 16 hours, and supernatant C OD will be 464mg/l, supernatant liquor enters aerobe processing unit 9, hydraulic detention time 8 hours, COD will be 237mg/l, reach the emission request of three grades of emission standards of GB8978-1996 " integrated wastewater discharge standard ".
Embodiment 5
Wuxi City mechanical fitting manufacturing enterprise workshop produces emulsifying liquid waste water in process of production, this emulsifying liquid waste water COD15780mg/l, pH6.7, mineral oil content 1200mg/l, the water yield is 0.8 ton/day, for handling emulsifying liquid waste water, other utilizes 3.2 tons/day in this enterprise's daily life sewage, sanitary sewage water-quality COD 326mg/l, pH6.9, wherein sanitary sewage enters in the aerobic biochemical process sanitary sewage disposal unit 2 1.6 tons/day, enters in the anaerobic biological treatment unit 8 1.6 tons/day.Emulsion water quality after oily water separation is COD7636mg/l, at breakdown of emulsion and solid-liquid separation unit calcium hydroxide consumption is 500mg/l, 10 minutes stirring reaction time, by the time during normal temperature, add PAM20mg/l, 10 minutes stirring reaction time, through precipitating 1 hour, supernatant C OD reduces to 2651mg/l, and clear liquid enters pH adjustment unit 6, utilizes hydrochloric acid that pH is adjusted into 6-9, supernatant liquor enters in the activated sludge absorption processing unit 7, mix with the active sludge of coming in, adopted aeration agitation 10 minutes, precipitate that supernatant C OD reduces to 1382mg/l after 1 hour, supernatant liquor enters in the anaerobic biological treatment unit 8, mix with the sanitary sewage in entering anaerobic biological treatment unit 8, hydraulic detention time is 10 hours, and supernatant C OD will be 978mg/l, supernatant liquor enters aerobe processing unit 9, hydraulic detention time 6 hours, COD will be 409mg/l, reach the emission request of three grades of emission standards of GB8978-1996 " integrated wastewater discharge standard ".
Embodiment 6
Wuxi City mechanical fitting manufacturing enterprise workshop produces emulsifying liquid waste water in process of production, this emulsifying liquid waste water COD15780mg/l, pH6.7, mineral oil content 1200mg/l, the water yield is 0.8 ton/day, for handling emulsifying liquid waste water, other utilizes 8.0 tons/day in this enterprise's daily life sewage, sanitary sewage water-quality COD 326mg/l, pH6.9, wherein sanitary sewage enters in the aerobic biochemical process sanitary sewage disposal unit 2 5.6 tons/day, enters in the anaerobic biological treatment unit 8 2.4 tons/day.Emulsion water quality after oily water separation is COD7636mg/l, at breakdown of emulsion and solid-liquid separation unit calcium hydroxide consumption is 100mg/l, 10 minutes stirring reaction time, by the time during normal temperature, add PAM5mg/l, 10 minutes stirring reaction time, through precipitating 1 hour, supernatant C OD reduces to 2651mg/l, and clear liquid enters pH adjustment unit 6, utilizes hydrochloric acid that pH is adjusted into 6-9, supernatant liquor enters in the activated sludge absorption processing unit 7, mix with the active sludge of coming in, adopted aeration agitation 10 minutes, precipitate that supernatant C OD reduces to 1582mg/l after 1 hour, supernatant liquor enters in the anaerobic biological treatment unit 8, mix with the sanitary sewage in entering anaerobic biological treatment unit 8, hydraulic detention time is 10 hours, and supernatant C OD will be 477mg/l, supernatant liquor enters aerobe processing unit 9, hydraulic detention time 6 hours, COD will be 305mg/l, reach the emission request of three grades of emission standards of GB8978-1996 " integrated wastewater discharge standard ".
Embodiment 7
Wuxi City mechanical fitting manufacturing enterprise workshop produces emulsifying liquid waste water in process of production, this emulsifying liquid waste water COD15780mg/l, pH6.7, mineral oil content 1200mg/l, the water yield is 0.8 ton/day, for handling emulsifying liquid waste water, other utilizes 8.0 tons/day in this enterprise's daily life sewage, sanitary sewage water-quality COD 326mg/l, pH6.9, wherein sanitary sewage enters in the aerobic biochemical process sanitary sewage disposal unit 24 tons/day, enters in the anaerobic biological treatment unit 84 tons/day.Emulsion water quality after oily water separation is COD7636mg/l, at breakdown of emulsion and solid-liquid separation unit calcium hydroxide consumption is 500mg/l, 10 minutes stirring reaction time, by the time during normal temperature, add PAM2mg/l, 10 minutes stirring reaction time, through precipitating 1 hour, supernatant C OD reduces to 2651mg/l, and clear liquid enters pH adjustment unit 6, utilizes hydrochloric acid that pH is adjusted into 6-9, supernatant liquor enters in the activated sludge absorption processing unit 7, mix with the active sludge of coming in, adopted aeration agitation 10 minutes, precipitate that supernatant C OD reduces to 1382mg/l after 1 hour, supernatant liquor enters in the anaerobic biological treatment unit 8, mix with the sanitary sewage in entering anaerobic biological treatment unit 8, hydraulic detention time is 10 hours, and supernatant C OD will be 327mg/l, supernatant liquor enters aerobe processing unit 9, hydraulic detention time 6 hours, COD will be 185mg/l, reach the emission request of three grades of emission standards of GB8978-1996 " integrated wastewater discharge standard ".
Embodiment 8
Wuxi City mechanical fitting manufacturing enterprise workshop produces emulsifying liquid waste water in process of production, this emulsifying liquid waste water COD15780mg/l, pH6.7, mineral oil content 1200mg/l, the water yield is 0.8 ton/day, for handling emulsifying liquid waste water, other utilizes 8.0 tons/day in this enterprise's daily life sewage, sanitary sewage water-quality COD 326mg/l, pH6.9, wherein sanitary sewage enters in the aerobic biochemical process sanitary sewage disposal unit 2 6.4 tons/day, enters in the anaerobic biological treatment unit 8 1.6 tons/day.Emulsion water quality after oily water separation is COD7636mg/l, at breakdown of emulsion and solid-liquid separation unit calcium hydroxide consumption is 500mg/l, 10 minutes stirring reaction time, by the time during normal temperature, add PAM2mg/l, 10 minutes stirring reaction time, through precipitating 1 hour, supernatant C OD reduces to 2651mg/l, and clear liquid enters pH adjustment unit 6, utilizes hydrochloric acid that pH is adjusted into 6-9, supernatant liquor enters in the activated sludge absorption processing unit 7, mix with the active sludge of coming in, adopted aeration agitation 10 minutes, precipitate that supernatant C OD reduces to 1497mg/l after 1 hour, supernatant liquor enters in the anaerobic biological treatment unit 8, mix with the sanitary sewage in entering anaerobic biological treatment unit 8, hydraulic detention time is 10 hours, and supernatant C OD will be 346mg/l, supernatant liquor enters aerobe processing unit 9, hydraulic detention time 6 hours, COD will be 198mg/l, reach the emission request of three grades of emission standards of GB8978-1996 " integrated wastewater discharge standard ".