技术领域technical field
本发明属于烟用调香技术领域，具体涉及一种能淡化卷烟搭口胶燃烧时所产生的不良气味，改善卷烟香气的香精。同时，本发明还涉及该香精的制备方法和使用方法。The invention belongs to the technical field of flavoring for cigarettes, and in particular relates to an essence capable of diluting the bad smell produced when cigarette lapping glue is burned and improving the aroma of cigarettes. At the same time, the invention also relates to a preparation method and a use method of the essence.
背景技术Background technique
随着人们经济生活水平的不断提高以及对香烟消费理念的逐步变化，中高档烟越来越受到广大烟民的喜爱。因此，如何将低、中档烟向中、高档次提升日益成为广大烟草研究人员关注的焦点问题。众所周知，提高卷烟档次的核心技术就是增加烟草本香，目前已有大量的工作者开展了烟丝、烟梗、薄片加香加料方法研究，并取得了一定的成果。但是现阶段，传统的烟丝、烟梗、薄片加香加料方法已经很难在原有技术上有大的突破，其中相当一部分的原因归结于烟用粘合剂的干扰。其实，烟用粘合剂作为卷烟重要的辅料之一，对于卷烟抽吸品质的影响意义重大。它们一般是由基料、固化剂、稀释剂、增塑剂、填料、偶联剂以及其它辅助材料组成。不同用途的粘合剂对于卷烟的抽吸品质有着不同程度的影响，这其中，直接参与卷烟燃烧的搭口胶对于卷烟的抽吸品质影响最大。在搭口胶的燃烧过程中，会产生苯、甲苯、二甲苯、正己烷、丙酮、乙酸乙酯等挥发性物质，不仅影响卷烟抽吸品质而且会对人体造成危害。因此，针对烟用粘合剂，特别是搭口胶开展去除不良化学气息的技术研究意义重大。With the continuous improvement of people's economic and living standards and the gradual change in the concept of cigarette consumption, medium and high-end cigarettes are more and more popular among smokers. Therefore, how to upgrade low- and middle-grade cigarettes to medium and high-grade cigarettes has increasingly become the focus of attention of tobacco researchers. As we all know, the core technology to improve the grade of cigarettes is to increase the original aroma of tobacco. At present, a large number of workers have carried out research on the method of adding flavoring to shredded tobacco, tobacco stems, and thin slices, and have achieved certain results. But at the present stage, the traditional method of flavoring shredded tobacco, tobacco stems, and flakes has been difficult to make a major breakthrough in the original technology, and a considerable part of the reason is attributed to the interference of tobacco adhesives. In fact, as one of the important auxiliary materials of cigarettes, tobacco adhesives have a great influence on the smoking quality of cigarettes. They are generally composed of base materials, curing agents, diluents, plasticizers, fillers, coupling agents and other auxiliary materials. Adhesives of different uses have varying degrees of influence on the smoking quality of cigarettes, among which the lap glue that directly participates in the burning of cigarettes has the greatest influence on the smoking quality of cigarettes. During the burning process of lap glue, volatile substances such as benzene, toluene, xylene, n-hexane, acetone, and ethyl acetate will be produced, which not only affect the smoking quality of cigarettes but also cause harm to human body. Therefore, it is of great significance to carry out technical research on removing bad chemical smells for cigarette adhesives, especially lapping glue.
发明内容Contents of the invention
本发明的目的在于针对现有技术的不足，提供一种卷烟搭口胶用香精，将其应用于卷烟，以淡化搭口胶燃烧时所产生的不良气味，改善卷烟香气。The purpose of the present invention is to address the deficiencies in the prior art, to provide a flavor for cigarette lapping glue, which is applied to cigarettes to reduce the bad smell produced when the lapping glue is burned, and to improve the aroma of cigarettes.
本发明的另一目的在于提供一种制备所述香精的方法。Another object of the present invention is to provide a method for preparing the essence.
本发明的目的还在于提供所述香精的使用方法。The object of the present invention is also to provide a method for using the essence.
本发明的目的通过以下技术方案予以实现。The purpose of the present invention is achieved through the following technical solutions.
除非另有说明，本发明所采用的百分数均为重量百分数。Unless otherwise stated, the percentages used in the present invention are all percentages by weight.
一种卷烟搭口胶用香精，由下述重量份的原料制成：云南烟叶提取物25份，圆柚酮3份，烟草增香基25份，玫瑰精油2份，二氢猕猴桃内酯3份，β-大马酮2份和溶剂40份。An essence for cigarette lapping gum, made of the following raw materials in parts by weight: 25 parts of Yunnan tobacco leaf extract, 3 parts of narone, 25 parts of tobacco flavoring base, 2 parts of rose essential oil, 3 parts of dihydroactinolactone Parts, 2 parts of β-damascenone and 40 parts of solvent.
其中，所述的云南烟叶提取物由下述重量份的原料制成：大理C3F 20份，玉溪C2F 10份，玉溪X2F 30份，楚雄C2F 20份和昆明C2F 20份。Wherein, the Yunnan tobacco leaf extract is made of the following raw materials in parts by weight: 20 parts of DaliC3F , 10 parts of Yuxi C2F, 30 parts of Yuxi X2F, 20 parts of Chuxiong C2F and 20 parts of Kunming C2F.
所述的烟草增香基由巨豆三烯酮、乙位突厥酮、津巴布韦烟叶提取物、3，4-二甲基环戊烯醇酮和乙位紫罗兰酮混合复配而成。The tobacco aroma-enhancing base is formed by mixing macrostigmatrienone, ethylturkone, Zimbabwean tobacco leaf extract, 3,4-dimethylcyclopentenolone and ethylionone.
所述的溶剂选自丙二醇、三乙酸甘油酯、乙醇中的一种或几种。The solvent is selected from one or more of propylene glycol, glycerol triacetate and ethanol.
制备上述卷烟搭口胶用香精的方法，包括以下步骤：The method for preparing the above-mentioned essence for cigarette lapping glue may further comprise the steps:
1、原料预处理：称取所述的云南烟叶，洗净、去泥沙后置于80±2℃下鼓风干燥3h，控制含水率在5％～10％，烘干后的烟叶立即粉碎至过120目～150目筛，备用；1. Pretreatment of raw materials: Weigh the above-mentioned Yunnan tobacco leaves, wash and remove the sediment, and then place them in blast-drying at 80±2°C for 3 hours, control the moisture content at 5% to 10%, and crush the dried tobacco leaves immediately Pass through a sieve of 120 mesh to 150 mesh, and set aside;
2、乙醇回流提取：用5倍叶重的75％乙醇，80℃回流提取3次，每次1h，过滤后得到云南烟叶酊剂；2. Ethanol reflux extraction: use 75% ethanol with 5 times the leaf weight, reflux extraction at 80°C for 3 times, each time for 1 hour, and obtain Yunnan tobacco leaf tincture after filtration;
3、树脂的预处理：在装柱之前，吸附树脂用稀氯化钠和碳酸钠溶液处理，水洗，以除去痕量的防腐剂和残留的单体化合物；3. Resin pretreatment: Before loading the column, the adsorption resin is treated with dilute sodium chloride and sodium carbonate solution, and washed with water to remove traces of preservatives and residual monomer compounds;
4、过柱精制：云南烟叶酊剂上柱至接近饱和，分别用6倍树脂体积的水和3倍20％乙醇洗脱，接着用60％乙醇洗脱烟叶有效成分，再经真空浓缩，冷冻干燥后得到云南烟叶提取物；4. Column refining: Yunnan tobacco leaf tincture is applied to the column until it is nearly saturated, then eluted with 6 times the resin volume of water and 3 times 20% ethanol, and then eluted the active ingredients of the tobacco leaves with 60% ethanol, then concentrated in vacuum and freeze-dried After obtaining the Yunnan tobacco leaf extract;
5、称取云南烟叶提取物25份，圆柚酮3份，烟草增香基25份，玫瑰精油2份，二氢猕猴桃内酯3份，β-大马酮2份和溶剂40份混合均匀，即得到所需的卷烟搭口胶用香精。5. Weigh 25 parts of Yunnan tobacco leaf extract, 3 parts of pomelo ketone, 25 parts of tobacco flavoring base, 2 parts of rose essential oil, 3 parts of dihydroactinolactone, 2 parts of β-damascenone and 40 parts of solvent and mix evenly , that is, to obtain the required essence for cigarette lapping gum.
该卷烟搭口胶用香精的使用方法：将搭口胶置于带有搅拌装置和冷凝器的聚合釜中，升温至90±2℃，搅拌搭口胶至匀质，降温至75℃，按搭口胶重量的0.5～2.0％分别加入乳化剂和消泡剂，继续降温至50℃，而后逐滴加入所述香精，添加量为搭口胶用量的0.01～0.05％，并以120rpm的转速开始搅拌，搅拌过程中保持恒温恒湿，香精加完后继续保持搅拌1h，加入乙酸调节pH值至6，搅拌0.5h后出胶。The method of using the essence for cigarette lapping glue: put the lapping glue in a polymerization kettle with a stirring device and a condenser, heat up to 90±2°C, stir the lapping glue until homogeneous, cool down to 75°C, press Add emulsifier and defoamer respectively at 0.5-2.0% of the weight of the glue, continue to cool down to 50°C, and then add the essence drop by drop. Start stirring, keep constant temperature and humidity during the stirring process, continue to stir for 1 hour after the essence is added, add acetic acid to adjust the pH value to 6, and stir for 0.5 hours to produce glue.
所述的乳化剂优选为辛基苯酚聚氧乙烯(10)醚。The emulsifier is preferably octylphenol polyoxyethylene (10) ether.
所述的消泡剂优选为庚醇。Described defoamer is preferably heptanol.
香精的添加量优选为搭口胶总量的0.04％。The added amount of essence is preferably 0.04% of the total amount of the mouth glue.
相对于现有技术，本发明具有如下优点：Compared with the prior art, the present invention has the following advantages:
1、烟用辅料加香技术目前在烟用粘合剂领域尚无应用。本发明创新性的开发出一种新型复合香精，该香精与常规搭口胶掺配后，可明显提高卷烟的烟草本香，谐调卷烟的各种香气，使烟香更自然、细腻、柔和和飘逸。1. At present, the flavoring technology of tobacco accessories has not been applied in the field of tobacco adhesives. The present invention innovatively develops a new type of composite flavor, which can significantly improve the tobacco aroma of cigarettes after blending with conventional lapping glue, and harmonize various aromas of cigarettes, making the aroma of cigarettes more natural, delicate, soft and mellow elegant.
2、云南烟叶提取物中含有较多的烟草致香成分，如巨豆三烯酮、甲位突厥酮、乙位突厥酮、甲基环戊烯醇酮、二氢乙酸香芹酯、法尼烯等。这些致香成分能起到增加烟草本香、谐调烟香的作用。2. Yunnan tobacco leaf extract contains more tobacco aroma components, such as macrostigmatrienone, methyl-turkone, ethyl-turkone, methylcyclopentenolone, carvyl dihydroacetate, farnesyl ene etc. These aroma-inducing components can increase the original aroma of tobacco and harmonize the aroma of tobacco.
3、经仪器分析检测后发现，该添加剂中的一些重要致香成分在卷烟烟气中的转移率较高。如乙位大马酮，它在卷烟烟气中的转移率高达30％。3. After instrumental analysis and detection, it is found that some important aroma components in the additive have a high transfer rate in cigarette smoke. Such as damascenone, its transfer rate in cigarette smoke is as high as 30%.
4、国内目前所生产的高速卷烟胶有效粘合速度可以达到6000支/分，经过本项加香加料技术处理后的卷烟胶，其粘合效率没有任何程度的降低。4. The effective bonding speed of the high-speed cigarette adhesive currently produced in China can reach 6000 sticks/minute, and the adhesive efficiency of the cigarette adhesive processed by this flavoring and feeding technology does not decrease to any extent.
5、本发明制备方法简便，成本低廉，可应用于大规模工业化生产。5. The preparation method of the present invention is simple and low in cost, and can be applied to large-scale industrial production.
具体实施方式Detailed ways
下面通过实施例对本发明做进一步的说明，但它们不是对本发明的限定。The present invention will be further described below by way of examples, but they are not limitation of the present invention.
实施例1Example 1
制备卷烟搭口胶用香精。将云南烟叶，洗净、去泥沙后置于80±2℃下鼓风干燥3h，控制含水率在7％，烘干后的烟叶立即采用机械粉碎处理至过130目筛。用5倍叶重的75％乙醇，80℃回流提取3次，每次1h，过滤后得到云南烟叶酊剂。在装柱之前，吸附树脂用稀氯化钠和碳酸钠溶液处理、水洗，以除去痕量的防腐剂和残留的单体化合物。云南烟叶酊剂上柱至接近饱和，分别用6倍树脂体积的水和3倍20％乙醇洗脱，接着用60％乙醇洗脱烟叶有效成分，再经真空浓缩，冷冻干燥后得到云南烟叶提取物。将巨豆三烯酮、乙位突厥酮、津巴布韦烟叶提取物、3，4-二甲基环戊烯醇酮和乙位紫罗兰酮混合均匀制得烟草增香基备用。称取云南烟叶提取物25份，圆柚酮3份，烟草增香基25份，玫瑰精油2份，二氢猕猴桃内酯3份，β-大马酮2份和丙二醇40份混合均匀，制得所需的搭口胶用香精。Essence for preparing cigarette lapping gum. Tobacco leaves from Yunnan were washed and desilted, and then placed in blast-drying at 80±2°C for 3 hours to control the moisture content at 7%. After drying, the tobacco leaves were immediately pulverized by machinery until they passed through a 130-mesh sieve. Use 75% ethanol which is 5 times the weight of the leaf, reflux extraction at 80°C for 3 times, each time for 1 hour, and filter to obtain Yunnan tobacco leaf tincture. Before packing, the adsorbent resin is treated with dilute sodium chloride and sodium carbonate solution and washed with water to remove traces of preservatives and residual monomeric compounds. Yunnan Tobacco Leaf Tincture was applied to the column until it was nearly saturated, and then eluted with 6 times the resin volume of water and 3 times 20% ethanol, and then eluted with 60% ethanol to elute the active ingredients of the tobacco leaves, then concentrated in vacuum and freeze-dried to obtain Yunnan Tobacco Leaf Extract . Tobacco flavoring base is prepared by uniformly mixing macrostigmatrienone, ethyl turkone, Zimbabwean tobacco leaf extract, 3,4-dimethylcyclopentenolone and ethyl ionone. Weigh 25 parts of Yunnan tobacco leaf extract, 3 parts of pomelo ketone, 25 parts of tobacco flavoring base, 2 parts of rose essential oil, 3 parts of dihydroactinolactone, 2 parts of β-damascenone and 40 parts of propylene glycol and mix evenly to prepare Get the flavor you need for the mouth glue.
实施例2Example 2
重复实施例1，有以下不同点：烟叶干燥至含水率5％，粉碎至过120目筛。溶剂为三乙酸甘油酯。Repeat Example 1, with the following differences: the tobacco leaves are dried to a moisture content of 5%, and pulverized to cross a 120 mesh sieve. The solvent is glycerol triacetate.
实施例3Example 3
重复实施例1，有以下不同点：烟叶干燥至含水率10％，粉碎至过150目筛。溶剂为乙醇。Repeat Example 1, with the following differences: the tobacco leaves are dried to a moisture content of 10%, and pulverized to cross a 150 mesh sieve. The solvent is ethanol.
应用实施例1Application Example 1
将搭口胶置于带有搅拌装置和冷凝器的聚合釜中，升温至90±2℃，搅拌搭口胶至匀质，降温至75℃，加入占搭口胶重量1％的辛基苯酚聚氧乙烯(10)醚和1％的庚醇，继续降温至50℃，而后逐滴加入实施例1所得香精，添加量为搭口胶用量的0.04％，并以120rpm的转速开始搅拌，搅拌过程中保持恒温恒湿，香精加完后继续保持搅拌1h，加入乙酸调节pH值至6，搅拌0.5h后出胶。Put the lapping glue in a polymerization kettle with a stirring device and a condenser, raise the temperature to 90±2°C, stir the lapping glue until homogeneous, cool down to 75°C, and add octylphenol accounting for 1% of the lapping glue weight Polyoxyethylene (10) ether and 1% heptanol, continue to cool down to 50 ℃, then add the essence gained in Example 1 dropwise, the addition is 0.04% of the amount of glue, and start stirring at a speed of 120rpm, stirring Keep constant temperature and humidity during the process, continue to stir for 1 hour after adding the essence, add acetic acid to adjust the pH value to 6, and stir for 0.5 hours to produce glue.
感官评分Sensory score
将加香后的搭口胶应用于红云集团云烟的生产，搭口胶加入量参照高速卷烟胶行业加入量标准进行。针对加香后的卷烟产品按照评吸标准进行评吸试验。评吸小组由十位卷烟感官评价专家组成，选用盲评方式进行感官评价并打分。The flavored lapping glue is applied to the production of Yunyan of Hongyun Group, and the amount of lapping glue is added according to the standard of high-speed cigarette glue industry. Smoking test is carried out for the flavored cigarette products according to the smoking evaluation standard. The smoking evaluation team is composed of ten cigarette sensory evaluation experts, who use the blind evaluation method to conduct sensory evaluation and score.
仪器检测Instrument testing
选用高温裂解气相色谱-质谱法对加香前后搭口胶裂解成分进行分析检测。具体的分析方法是，取一定量样品放入热裂解仪的裂解专用石英管中，然后置于热裂解仪的裂解头的加热丝中，裂解头插入自制的玻璃容器中，分别在400℃和700℃的裂解温度下进行热裂解。热裂解完毕后，分别用固相微萃取头于70℃下富集热裂解产物20min，然后把萃取头插入气相色谱高温汽化室(温度为240℃)中解吸附，解吸附时间为2min，最后，热裂解产物进入气相色谱/质谱(GC/MS)进行分离和鉴定。分析条件为：热裂解条件为在大气环境中进行有氧裂解，其中大气温度为30℃。GC/MS条件为：进样口温度：240℃；载气：He，1mL/min；升温程序：50℃(保持1min)--5℃/min--100℃(保持1min)--8℃/min--260℃(保持1min)；GC-MS接口温度：280℃；离子源(EI)温度：250℃；电离能量：70eV；质量扫描范围：35～455amu。应用NIST98标准谱库进行检索。经分析检测后发现，巨豆三烯酮、甲位突厥酮、乙位突厥酮、甲基环戊烯醇酮、二氢乙酸香芹酯、法尼烯、甲酸甲酯、吡啶、丙醇、2-甲基吡嗪、糠醛、糠醇、环戊-2-烯-1，4-二酮、乙酸异丙酯、2，6-二甲基吡嗪、乙基吡嗪、2，3-二甲基吡嗪、乙烯基吡嗪、糠酸、5-甲基糠醛、2，4，5-三甲基噻唑、4-(N，N-二甲氨基)吡啶、1-甲基吡嗪-2-甲醛、2-乙烯基-6-甲基吡嗪、吡咯-2-甲醛、苯甲醇、2，3-二氢-(1H)吲哚、苯乙醛、苯乙醇、麦芽酚、二乙氧基甲烷、戊酸丙酯、二聚丙二醇、硫氰酸甲酯、烟碱、2-(2’-呋喃基)-5-甲基吡嗪、6-氯甲基-2-甲基吡嗪、新植二烯等重要的致香成分，在含量上均有不同程度的提高。其中，添加剂β-大马酮的转移率达到30％。因此，所加香精对卷烟的香气具有较大的贡献。The pyrolysis gas chromatography-mass spectrometry was used to analyze and detect the cracking components of the gum before and after flavoring. The specific analysis method is to take a certain amount of sample and put it into the pyrolysis special quartz tube of the pyrolysis instrument, then place it in the heating wire of the pyrolysis head of the pyrolysis apparatus, and insert the pyrolysis head into a self-made glass container, respectively, at 400 ° C and Thermal cracking is carried out at a cracking temperature of 700°C. After the pyrolysis was completed, the pyrolysis products were enriched at 70°C for 20 minutes with the solid-phase microextraction head, and then the extraction head was inserted into the high-temperature vaporization chamber of the gas chromatography (at a temperature of 240°C) for desorption. The desorption time was 2 minutes, and finally , the pyrolysis products were separated and identified by gas chromatography/mass spectrometry (GC/MS). The analysis conditions are as follows: the thermal cracking condition is aerobic cracking in an atmospheric environment, wherein the atmospheric temperature is 30°C. GC/MS conditions are: inlet temperature: 240°C; carrier gas: He, 1mL/min; heating program: 50°C (hold for 1min)--5°C/min--100°C (hold for 1min)--8°C /min--260°C (hold for 1min); GC-MS interface temperature: 280°C; ion source (EI) temperature: 250°C; ionization energy: 70eV; mass scanning range: 35～455amu. The NIST98 standard spectral library was used for searching. After analysis and detection, it was found that macrostigmatrienone, methyl-turkone, ethyl-turkone, methylcyclopentenolone, carvyl dihydroacetate, farnesene, methyl formate, pyridine, propanol, 2-Methylpyrazine, furfural, furfuryl alcohol, cyclopent-2-ene-1,4-dione, isopropyl acetate, 2,6-dimethylpyrazine, ethylpyrazine, 2,3-di Methylpyrazine, vinylpyrazine, furoic acid, 5-methylfurfural, 2,4,5-trimethylthiazole, 4-(N,N-dimethylamino)pyridine, 1-methylpyrazine- 2-Formaldehyde, 2-vinyl-6-methylpyrazine, pyrrole-2-carbaldehyde, benzyl alcohol, 2,3-dihydro-(1H)indole, phenylacetaldehyde, phenylethyl alcohol, maltol, diethyl Oxymethane, propyl valerate, dipropylene glycol, methyl thiocyanate, nicotine, 2-(2'-furyl)-5-methylpyrazine, 6-chloromethyl-2-methylpyrazine The content of important aroma components such as azine and neophytadiene has been increased to varying degrees. Among them, the transfer rate of the additive β-Damascenone reaches 30%. Therefore, the added essence has a greater contribution to the aroma of cigarettes.
感官打分结果表明，加香后的产品在香气上评分增加1.2。The sensory scoring results showed that the aroma score of the flavored product increased by 1.2.
应用实施例2Application Example 2
加入实施例2所得香精，添加量为搭口胶用量的0.01％。将加香后的搭口胶应用于红云集团红山茶卷烟的生产。感官打分结果表明，加香后的产品在香气上评分增加1.4。Add the gained essence of embodiment 2, and the addition is 0.01% of the mouth glue consumption. The flavored lap gum was applied to the production of Hongyun Group Hongshancha cigarettes. The sensory scoring results showed that the aroma score of the flavored product increased by 1.4.
应用实施例3Application Example 3
加入实施例3所得香精，添加量为搭口胶用量的0.05％。将加香后的搭口胶应用于石林卷烟的生产，感官打分结果表明，加香后的产品在香气上评分增加1.3。Add the gained essence of embodiment 3, and the addition is 0.05% of the mouth glue consumption. The flavored lapping gum was applied to the production of Shilin cigarettes, and the sensory scoring results showed that the aroma score of the flavored product increased by 1.3.
应用实施例4Application Example 4
重复应用实施例1，有以下不同点：将加香后的搭口胶应用于红云集团小熊猫卷烟的生产。感官打分结果表明，加香后的产品在香气上评分增加1.5。The repeated application of Example 1 has the following differences: the flavored lapping glue is applied to the production of red panda cigarettes of Hongyun Group. The sensory scoring results showed that the aroma score of the flavored product increased by 1.5.
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100946582ACN101586057B (en) | 2009-06-25 | 2009-06-25 | Essence for cigarette lap adhesive and preparation and use methods thereof |
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100946582ACN101586057B (en) | 2009-06-25 | 2009-06-25 | Essence for cigarette lap adhesive and preparation and use methods thereof |
| Publication Number | Publication Date |
|---|---|
| CN101586057A CN101586057A (en) | 2009-11-25 |
| CN101586057Btrue CN101586057B (en) | 2011-10-05 |
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009100946582AActiveCN101586057B (en) | 2009-06-25 | 2009-06-25 | Essence for cigarette lap adhesive and preparation and use methods thereof |
| Country | Link |
|---|---|
| CN (1) | CN101586057B (en) |
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102304426B (en)* | 2011-03-17 | 2013-04-17 | 广州市澳键丰泽生物科技有限公司 | Formula of rose fragrance tobacco flavoring essence |
| CN102242072B (en)* | 2011-05-12 | 2013-02-27 | 江南大学 | Screening of β-damascenone-producing strains in Chinese liquor brewing by flavor-directed technology and its application |
| CN102488323A (en)* | 2011-12-13 | 2012-06-13 | 云南瑞升烟草技术（集团）有限公司 | Tobacco absolute emulsification preparation and application thereof to tobacco leaves |
| CN102586020B (en)* | 2012-02-23 | 2013-08-21 | 上海烟草集团有限责任公司 | Separation method of weak acidic aromatic components in cigarette mainstream smoke, and its application |
| CN102759588B (en)* | 2012-07-16 | 2014-05-07 | 上海烟草集团有限责任公司 | Method for separating and preparing key acid flavor components in cigarette mainstream smoke and application of key acid volatile components |
| CN103923579B (en)* | 2014-04-24 | 2016-05-18 | 川渝中烟工业有限责任公司 | Vanilla fragrance overlapping glue essence for cigarette |
| CN104818115B (en)* | 2015-03-24 | 2018-05-18 | 云南中烟工业有限责任公司 | A kind of liquid essence with burnt fragrant and sweet style and features and its application in cigarette |
| CN104804870B (en)* | 2015-03-24 | 2018-06-12 | 云南中烟工业有限责任公司 | The liquid essence and its application in cigarette that a kind of perfume quantity and aroma quality protrude |
| CN104804869B (en)* | 2015-03-24 | 2018-03-09 | 云南中烟工业有限责任公司 | A kind of liquid essence with fresh and sweet fragrant style and features and its application in cigarette |
| CN105831802B (en)* | 2016-05-31 | 2017-06-16 | 湖北中烟工业有限责任公司 | One kind is used for agilawood cigarette overlapping glue agalloch eaglewood essence and its preparation method and application |
| CN106036998A (en)* | 2016-07-18 | 2016-10-26 | 江苏浩丰生物科技有限公司 | Blast bead capable of making up for deficiencies in cigarette fragrance and moist sense and preparation method of blast bead |
| CN106520369A (en)* | 2016-11-18 | 2017-03-22 | 湖北中烟工业有限责任公司 | Essence for cigarette lap adhesive and use method thereof |
| CN109280579A (en)* | 2018-07-27 | 2019-01-29 | 内蒙古昆明卷烟有限责任公司 | The milk sweet tea type essence of cigarette overlapping glue cordyceps sinensis feature and its application and preparation method |
| CN109055008A (en)* | 2018-07-27 | 2018-12-21 | 内蒙古昆明卷烟有限责任公司 | Cigarette connects the milk sweet tea type essence and its application and preparation method of mouth glue cordyceps sinensis feature |
| CN112080235A (en)* | 2020-08-27 | 2020-12-15 | 重庆中烟工业有限责任公司 | Method for improving taste of cigarette lap adhesive |
| CN113088391A (en)* | 2021-04-14 | 2021-07-09 | 云南中烟工业有限责任公司 | Glutinous rice flavor type essence for cigarette and cigarette containing essence |
| CN117547059A (en)* | 2023-12-11 | 2024-02-13 | 江苏中烟工业有限责任公司 | Reconstituted tobacco essential oil with Zimbabwe tobacco style, and preparation method and application thereof |
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1217167A (en)* | 1997-10-09 | 1999-05-26 | 日本烟草产业株式会社 | Method for producing tobacco fragrant products |
| CN1532257A (en)* | 2003-03-23 | 2004-09-29 | 范明星 | Poisonless high speed cigarette overlapping glue |
| CN101215449A (en)* | 2008-01-07 | 2008-07-09 | 红云烟草(集团)有限责任公司 | Function cigarette overlapping glue and preparation method thereof |
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1217167A (en)* | 1997-10-09 | 1999-05-26 | 日本烟草产业株式会社 | Method for producing tobacco fragrant products |
| CN1532257A (en)* | 2003-03-23 | 2004-09-29 | 范明星 | Poisonless high speed cigarette overlapping glue |
| CN101215449A (en)* | 2008-01-07 | 2008-07-09 | 红云烟草(集团)有限责任公司 | Function cigarette overlapping glue and preparation method thereof |
| Title |
|---|
| 尹俊林等.卷烟搭口胶现状和发展.《中国胶粘剂》.2005,第14卷(第10期),43-46.* |
| Publication number | Publication date |
|---|---|
| CN101586057A (en) | 2009-11-25 |
| Publication | Publication Date | Title |
|---|---|---|
| CN101586057B (en) | Essence for cigarette lap adhesive and preparation and use methods thereof | |
| CN104041935B (en) | A kind of extracting method of electronic cigarette Chinese style flue-cured tobacco odor type style tobacco juice | |
| CN104983064B (en) | A kind of tobacco juice for electronic smoke and its preparation method | |
| CN106263013B (en) | A kind of high fragrance tobacco extract, preparation method and applications | |
| JP7338063B2 (en) | Method for producing tar extract from waste cigarette butts and its use in cigarettes | |
| CN105077570B (en) | A kind of tobacco leaf extract pyrolysis product, its preparation method and its application | |
| CN111035055B (en) | Method for extracting tar aroma components in cigarette butts and application of tar aroma components in cigarettes | |
| CN114009826A (en) | A kind of heating cigarette wick material and preparation method thereof | |
| CN115505458B (en) | Tobacco essence with strong fragrance style | |
| CN116491684A (en) | Heating non-combustion fuming material | |
| CN114794528B (en) | A preparation method and application of a tobacco full-component heat-reactive fragrance for heating cigarettes | |
| CN105996122A (en) | Cigarette filter stick for reducing cigarette aldehyde substances | |
| CN103386292B (en) | A kind of adsorbent that reduces nitrosamine burst size in cigarette mainstream flue gas | |
| CN105029700A (en) | Plant composite glycerol triacetate extract and application thereof in cigarettes | |
| CN101633822A (en) | Additive capable of removing bad smell in cigarette lapping glue and its preparation and use method | |
| CN109259292B (en) | Tobacco baked fragrant reconstituted tobacco and preparation method thereof | |
| CN114052283B (en) | Abelmoschus manihot bead-blasting essence and preparation method and application thereof | |
| CN102499433A (en) | Application of suberenol extract in cigarette flavoring additive | |
| CN105029699A (en) | Mint glycerol triacetate extract and application thereof in cigarette | |
| CN113349415B (en) | Preparation of low-temperature fraction for improving smoking quality and application of low-temperature fraction in heating cigarettes | |
| CN116286186A (en) | A jujube scorched-sweet spice that reduces harmful components burned and absorbed, and its preparation method and application | |
| CN107486161A (en) | A kind of adsorbent for heavy metal and its application | |
| CN107616544A (en) | Fragrant line agalloch eaglewood essence and its application in a kind of ramuscule filter stick | |
| CN112075661A (en) | A kind of preparation method of persimmon leaf flavonoids cigarette filter rod | |
| CN112056613A (en) | A kind of preparation method of gardenia fragrant cigarette filter rod |
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |