Z ~S~ 9 METHOD FOR TREATING GAS AND APPARATUS USED THEREFOR
FIELD OF THE INVENTION
The present invention relates to a method for treating a malodorous gas or gas containing a harmful component and an apparatus used therefor.
BACKGROUND OF THE INVENTION
Tradi.tionally, gases containing a malodorous component, harmful component, organic solvent, hydrocarbon vapor or the like (hereinafter referred to as the subject gas) have been treated by a number of methods, including the direct combustion method, in which the subject gas is oxidized at a high temperature of 600 to 1000C, the catalytic oxidation method, in which the subject gas is oxidized at relatively low ternperature in the presence of catalyst, the adsorption method, which uses an adsorbent such as activated charcoal, silica gel, activated alumina, activated clay or zeolite, and the absorption method, in which an absor-bent solution is used to physically or chemically absorb and eliminate malodorous and other undesirable components.
However, the direct combustion method requires much fuel and increases running cost when the combustible substance concentration in the subject gas is low. The catalytic oxidation method also requires much energy.for heating to raise a temperature of the entire subject gas when the oxidizable substance concentration in the subject gas is low. For these reasons, there has recently been ~.
~'~SS9~3 carried out the method in which the malodorous and combustible substance is once adsorbed to adsorbent and then desorbed with a small amount of heating gas to take it out as a concentrated cornbustible gas, which is then oxidatively decomposed in a separately installed catalytic reaction apparatus. In this case, however, cost is high and a large area Or installing space is required because two apparatuses are necessary, namely an apparatus for concentration by adsorption-desorption and a catalytic reaction apparatus. As for the adsorption method and the absorption method, either of them is unsatisfactory because the deactivated adsorbent or absorbent solution must be regenerated using a separate apparatus or disposed.
On the other hand, there have recently been investigated the direct ozonic oxidation method, in which ozone is used to oxidize malodorous components etc. in vapor phase at room temperature or at a temperature lower than that used for the conventional catalytic oxidation method, and the ozonic catalytic oxidation method, in which ozone and a catalyst are used in combination. These ozonic oxidation methods draw much attention as methods for treating the subject gas because they have many advantages; for example, the desired effect is obtained with only a trace amount of ozone, the starting material is air and is easy to supply, and a fungicidal effect is expected in addition to the oxidizing effect. However, even the ozonic catalytic oxidation method, which is appreciated as a method with ~: .
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excellent oxidative decomposition performance, can undergo degradation Or its oxidative decomposition performance due to accumulation of a high boiling, difficult-to-decompose compound such as phenol or a decomposition product thereof when treating them at room ternperature. Another problem is that even in the case of a compound which is treatable at room temperature, catalyst exchange or regeneration must be made in long term use since the oxidative decomposition performance declines due to accumulation of trace amounts of undecomposed components, though the oxidative decomposition performance can be kept intact in short term use.
SUMMARY OF THE INVENTI~N
Taking note of the background situation described above, the present inventors made investigations to develop a method for efficiently and economically advantageously treating the subject gas containing a malodorous component, harmful component, organic solvent, hydrocarbon vapor or the like. As a result, the inventors found that the adsorbable substances adsorbed to catalyst bed can be completely oxidized and decomposed by catalytic action and the catalyst bed can be regenerated at the same time by passing the subject gas through the catalyst bed to adsorb the adsorbable substances in the subject gas khereto and subsequently passing a high temperature reaction regenerating gas through the catalyst bed.
The inventors also found that more complete oxidization and -~t~9~) decomposition can be carried out by adding an ozone to the subject gas to decompose a part o~ the adsorbable substances in the subject gas by ozonic oxidation and then by passing the ozone-supplemented subject gas through the catalyst bed to adsorb the undecomposed adsorbable substances thereto and subsequently by passing a high temperature reaction regenerating gas. As a result catalyst bed exchange is unnecessary because the catalyst bed can be regenerated at the same time, and that the adsorbable substances in the subject gas can be continuously, efficiently and economically advantageously decomposed and removed because there is no need for a separate apparatus for regeneration. The inventors made further investigations based on these findings, and developed the present invention.
The reaction regenerating gas (hereinafter referred to as regenerating gas) means the reaction gas to decompose adsorbed substances and simultaneously regenerate the catalyst.
Accordingly, the present invention relates to a method for continuously treating a gas using an apparatus with a catalyst bed housed therein, in which the subject gas or ozone-supplemented subject gas is passed through the catalyst bed to adsorb the adsorbable substances in the subject gas and a regenerating gas is passed through the catalyst bed adsorbed by the adsorbable substances therein to react and decompose them and simultaneously regenerate the catalyst bed, characterized in that the regenerating portion to pass the regenerating gas therethrough constitutes a part of the .; .
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catalyst bed and the entire catalyst bed is regenerated while the regenerating portion periodically moves from portion to portion in the catalyst bed, and an apparatus used for this method.
BRIEF DESCRIPTION OF THE DRAWINGS
Figure 1 is a schematic diagram of a treating apparatus incorporating a square catalyst bed.
Figure 2 is a schematic diagram of a cross sectional view of Figure 1 on the A-A line (A) and the B-B line (B).
Figure 3 is a schematic diagram of a treating apparatus incorporating a circular catalyst bed.
Figure 4 is a schematic diagram of a cross sectional view of Figure 3 on the A-A line~
Figure 5 is a schematic diagram of a treating apparatus incorporating a square catalyst bed with partitions therein.
Figure 6 is a schematic diagram of a treating apparatus which incorporates a square catalyst bed and which uses an oxygen- or ozone-enriched gas.
Figure 7 is a schematic diagram of a cross sectional view of Figure 6 on the A-A line (A) and the B-B line (B).
Figure 8 is a schematic diagram of a treating apparatus which incorporates a circular catalyst bed and which uses an oxygen- or ozone-enriched gas.
Figure 9 is a schematic diagram of a cross sectional view of Figure 8 on the A-A line.
Figure 10 is a schematic diagram of a treating apparatus which incorporates a square catalyst bed with .
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Figure 11 is a schematic diagram of a treating apparatus incorporating a reversion pan.
Figure 12 shows a schematic diagram of a cross sectional view of Figure 11 on the A-A line (A) and a schematic diagram of the flow of regenerating gas on a cross portion of Figure 11 on the B-B line (B).
Figure 13 is a schematic diagram of a treating apparatus which incorporates a reversion pan and which uses an oxygen- or ozone-enriched gas.
Figure 14 shows a schematic diagram of a cross sectional view of Figure 13 on the A-A line (A) and a schematic diagram of the flow of regenerating gas and high concentration ozone and/or oxygen on a cross portion of Figure 13 on the B-B line (B)-Figure 15 is a schematic diagram of a treatinB apparatuswhich incorporates a reversion pan and the blowing slit for high concentration ozone and/or oxygen provided at the inside of said pan.
Figure 16 shows a schematic diagram of a cross sectional view of Figure 15 on the A-A line (A) and a schematic diagram of the flow of regenerating gas and hiBh concentration ozone and/or oxygen on a cross portion of Figure 15 on the B-B line (B)-The numerical symbols in these figures are as follows:1: chamber, 2: catalyst bed, 3: regenerating portion, 3a:
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subject gas inlet, 5: regenerating gas blower, 6: regenerating gas heater, 7: drivine mechanism, 8: timing belt, 9: timing pulley, 10: sealing, 11: bearing, 12: flexible tube, 13:
inlet Or high concentration ozone and/or oxygen, 13a:
blowing slit for high concentration ozone and/or oxygen, 13b: blowing portion o~ high concentration ozone and/or oxygen, 14: reversion portion of regenerating gas, 14a: reversion pan, 15: treated gas outlet.
DETAILED DESCRIPTION OF THE INVENTION
The treating method of the present invention is characterized in that a heated regenerating gas is passed through a part of catalyst bed to form a regenerating portion in the catalyst bed, and the adsorbable substances adsorbed thereto are decomposed and removed and the catalyst in the regenerating portion is regenerated at the same time. This regenerating portion is a section of the catalyst bed, where the heated regenerating gas is passing, and moves portion to portion in the catalyst bed sequentially and periodically.
The direction of motion may be rotational around the center of the catalyst bed when the catalyst bed is circular as seen from the direction of flow of the subject gas, or may be parallel to one side of the catalyst bed when the catalyst bed is square. The regenerating portion may be moved by the method in which the blowing hole for regenerating gas moves above the catalyst bed or by the method in which the blowing hole for regenerating gas is fixed and the catalyst bed is ~ ~ ' . ~ ... .
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moved.
The regenerating portion -thus formed by passing a hea~ed regenerating gas through catalyst bed moves sequentially all over the catalyst bed to uniformly regenerate the catalyst bed and then returns to the starting position.
The direction of flow of regenerating gas may be the same as the direction Or flow of the subject gas or may be opposite thereto.
When the direction of rlow of regenerating gas is opposite to the direction of flow of the subject gas, it is necessary to keep the flow rate of regenerating gas enough greater than the flow rate of the subject gas. In this case, the adsorbable substances adsorbed to the catalyst bed are desorbed while being heated and decomposed by the regenerating gas and once pass through the catalyst bed along with the regenerating gas and return to the opposite side, i.e., the subject gas inlet side, where they are mixed with the subject gas and again pass through the catalyst bed; therefore, this case is advantageous from the viewpoint of decomposition of adsorbable substances.
Moreover, in the method in which the reeenerating gas is blown to the catalyst bed in the direction opposite to the direction of the subject gas, when the regenerating gas is blown to the catalyst bed and passed through the catalyst bed, after which its flow direction is reversed to the same direction as the direction of flow of the subject gas by a reversion pan provided at the opposite side of the catalyst ' /~ . ': .. , ,.. ", 2~iS~
bed to the blowing hole for regenerating gas, which moves along with the blowing hole. A good effect is obtained because the adsorbable substances adsorbed to the catalyst bed can be more completely decomposed by passing again regenerating gas through the catalyst bed without being mixed with the subject gas and hence without decline in gas temperature.
Providing such a reversion pan is advantageous because it reduces the volume of regenerating gas used and makes it possible to decompose the adsorbable substances and regenerate the catalyst bed with high efficiency. The cross sectional area of the reversion pan is suitably 2 to 20 tiMes the cross sectional area of the blowing hole for regenerating gas. If it exceeds 20 times, no significant effect is obtained from reversion of regenerating gas.
The regenerating gas used is air, an exhaust gas resulting from decomposing treatment of adsorbable substances or a gas obtained by enriching these gases with ozone and/or oxygen which are each heated to 100 to 500C, preferably 150 to 400C. Temperatures under 100C do not offer complete decomposition of adsorbable substances; heating to over 500C
requires much fuel and does not offer a corresponding effect.
The degree of enrichment of ozone enriched and/or oxygen enriched gas is not less than 1 ppm for ozone, preferably 10 ppm to 5%, and not less than 22% for oxygen, preferably 23%
to 99%. It is possible to use high concentration ozone generated from ozone generator and high concentration oxygen .
, - l o --2~ i97 generated from cylinder or oxygen PSA (Pressure Swing Adsorption) apparatus.
It is economical to use a heated BaS as a regenerating gas and pass it through the regenerating portion as a part of the catalyst bed because it is unnecessary to heat the entire subject gas or the entire catalyst bed and it is possible to save heat energy for gas heating. When heated air or the exhaust gas resulting from decomposition and treatment of adsorbable substances is used as a regenerating gas in combination with ozone and/or oxygen, it is more effective and efficient to introduce the latter gas at high concentration to a position close to the catalyst bed through a feeding pipe and blow it to a part of the regenerating portion in the catalyst bed because the ozone and/or oxygen is blown to the catalyst bed while being kept at high concentration. Here, a position close to the catalyst bed means that the distance from the catalyst bed is normally not longer than about 30 mm, preferably not longer than 10 mm, and more preferably not longer than 5 mm.
Thus, in the present invention there are two methods for preparing ozone-enriched and/or oxygen-enriched gas as a regenerating gas; one is to previously mix air or the exhaust gas described above with ozone and/or oxygen, and another is to introduce the high concentration ozone and/or oxygen to the catalyst bed directly through a feeding pipe separately from the blowing of air or the exhaust gas.
When an ozone-enriched gas is used as a regenerating gas, ~, :
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. ~ , , 2~S97~3 better results are obtained by the method in which hi8h concentration ozone is introduced to a position close to the catalyst bed through a feeding pipe and blown at high concentration, since ozone is not thermally stable and can be decomposed upon heating to lose its effect.
When the regenerating gas is blown in the direction opposite to the direction of the subject gas, the position to which the high concentration ozone and/or oxygen is introduced through a feeding pipe may be on either of the regenerating gas side or the subject gas side, as long as it is close to the regenerating portion of the catalyst bed.
When a reversion pan which moves along with the blowing hole for reBenerating gas is provided to reverse the direction of the regenerating gas, the position to which the high concentration ozone and/or oxygen is introduced through a feeding pipe may be at the inside of the reversion pan.
The exhaust gas thus resulting from decomposing treatment of adsorbable substances is purged through the treated gas outlet.
With respect to the catalyst bed, it is advantageous for feeding the gas to use a catalyst bed comprising a honeycomb-like base carrylng a catalyst or a catalys~ bed comprising cells partitioned in parallel to the direction of flow of the ~as and filled with grains or balls of catalyst because the flow resistance is lowered.
A conventional oxidation catalyst is used in the catalyst bed. Examples of such catalysts include platinum, palladium, .
--l2-~ 97 cobalt, nickel, chromium, manganese, vanadium, tungsten, molybdenum, iron, lead, copper ancl oxides thereof.
These catalysts may be used singly or in combination.
Examples of adsorbable substances in the subject gas which can be treated by the present invention include malodorous compounds and harmful compounds, speci~ically sulfides such as methyl mercaptan, amines such as ammonia, methylamine, dimethylamine, trimethylamine, ethylamine, diethylamine, triethylamine, isobutylamine and pyridine, ketones such as methyl ethyl ketone and cyclohexanone, organic acids such as acetic acid, butyric acid and propionic acid, aldehydes such as formaldehyde, acetaldehyde and acrolein, phenols such as phenol and cresol and alcohols such as methanol and butanol.
The method for treating a gas of the present invention is applicable when the concentration of these malodorous compounds and harmful compounds in the subject gas ranges from O.l-to 500 ppm by volume.
The ~low volume, ~low rate, retention time in catalyst bed and other factors of the subject gas are determined as appropriate according to the kind and concentration of components in the subject gas. The same applies to regenerating gas. Also, when ozone is added to the subject gas berorehand, the ozone concentration is normally not less than 0.1 ppm and pre~erably not less than l ppm and is determined as appropriate according to the kind and concentration of components in the subject gas.
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The size of catalyst bed, the amount of catalyst used, the cycle of rotation, sliding and other motions of the blowing hole for regenerating gas and other factors are also determined as appropriate according to the flow volume and flow rate of the subject gas and the kind and concentration of components in the subject gas.
As stated above, the treating method of the present invention makes it possible to simultaneously and continuously perform decomposition of adsorbable substances in the subject gas and regeneration of the catalyst bed;
therefore, there is no need for catalyst bed exchange or separate apparatus for regeneration and thus efficient and continuous operation is possible.
Another mode of the present invention is an apparatus for treating the subject gas containing such a malodorous compound or harmful compound.
To explain the apparatus of the present invention, some examples thereof are given in Figures 1 through 16.
Figure 1 exemplifies the use of a square catalyst bed 2, in which the regenerating gas is blown to the catalyst bed 2 while moving the blowing hole for regenerating gas 3a above the regenerating portion 3 for sequential regeneration.
The regenerating gas transferred from the regenerating gas blower 5 passes through the movable flexible tube 12 and is blown to the catalyst bed 2 through the biowing hole for regenerating gas, while the blowing hole for regenerating gas 3a is periodically sliding left and right above the catalyst , i ' :.
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bed. Figure 2 is a schematic diagram of a cross sectional view of the treating apparatus of Figure 1 on the A-A line (Q), in which the sliding direction Or regenerating portion 3 which moves along with the blowing hole 3a is shown by arrow (~).
Figure 3 exemplifies the use of a circular catalyst bed 2, in which the blowing hole f'or regenerating gas 3a periodically rotates around the center of the catalyst bed 2 above the catalyst bed. The blowing hole for regenerating gas 3a covers partly the catalyst bed 2. The regenerating pcrtion 3 has a fan-like form as illustrated in the schematic diagram of a cross sectional view on the A-A line in Figure 4;
its size can be set at any level, but is normally 1/4 to 1/200, preferably 1/10 to 1/20 of the area of the catalyst bed, and its number of portion may be 1 or 2 or more. When the subject gas is supplied from lower part of the chamber 1 and flow f`rom lower to upper parts of the chamber, the directions of flows of the subject gas and regenerating gas are opposite to each other; in this case, to increase the flow rate of regenerating gas, the area of the blowing hole is set at normally 1/60 to 1/720, pref'erably 1/100 to 1/360 of the area of the catalyst bed.
Figure 5 exemplifies the use of a square catalyst bed 2, in which unlike the example of Figure 1, the catalyst bed 2 is configured with appropriately partitioned sections packed with grains or balls of catalyst. The blowing hole for regenerating gas 3a moves sequentially from section to section and returns to the starting position in a given cycle.
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2(~ 97~) Figures 6 through 10 exemplify the modification of Figures 1 through 5, in which an ozone- and/or oxygen-enriched gas is used for regenerating the catatyst. High concentration ozone and/or oxygen is introduced through those inlet 13 and transferred through a feeding pipe to a position close to the catalyst bed 2 of the regenerating portion and blown to the catalyst bed 2 through the blowing slit 13a for hi8h concentration ozone and/or oxygen. In this way, it becornes possible to feed high concentration of ozone and/or oxygen to ensure efficient progress of regeneration of the catalyst bed.
Figure 11 shows the method in which the direction of flow of regenerating gas is reversed by the reversion pan 14a which moves along with the blowing hole for regenerating gas 3a, after which the regenerating gas again passes through the catalyst bed 2.
Figure 12 A is a schematic diagram of a cross sectional view of Figure 11 on the A-A line; Figure 12 B is a schematic diagram of a cross sectional view of Figure 11 on the B-B line, which schematically shows the flow of regenerating gas.
Figure 13 exemplifies the modification of the example of Figure 11, in which high concentration ozone and/or oxygen is blown through the blowing slit 13a provided at the inside of the blowing hole for regenerating gas 3a.
Figure 14 A is a schematic diagram of a cross sectional view of Figure 13 on the A~A line; Figure 14 B is a schematic diagram of a cross sectional view of Figure 13 on the B-B line, .
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--l6-7~) which schematically shows the flows of regenerating gas and high concentration ozone and/or oxygen.
Figure 15 shows a modification of the example of Figure 11, in which high concentration ozone and/or oxygen is introduced from inlet 13 through a feeding pipe into the reversion pan 14a. The blo~1ing slit 13a provided at the inside of the reversion pan 1LIa.
Figure 16 A is a schematic diagram of a cross sectional view Or Figure 15 on the A-A line; Figure 16 B is a schematic diagram of a cross sectional view of Figure 15 on the B-B line, which schematically shows the flows of regenerating gas and hiBh concentration ozone and/or oxygen.
By carrying out the method for treating a gas of the present invention using the gas treating apparatus of the present invention, it is possible to continuously, efficiently and economically advantageously treat a gas containing a malodorous component, harmful component, organic solvent, hydrocarbon vapor or the like.
EXAMP~ES
The present invention is hereinafter described in more detail by means of the following examples.
Example 1 Gas treatment was carried out using the apparatus illustrated in Figure 1. A honeycomb catalyst carrying manganese oxide (MnO2/TiOz ~SiO2, produced by ~ippon Shokubai) was used to form a catalyst bed (square, 150 mm x 200 mm x 50 mm H, 210 cell/(inch)2), and room temperature air -, ~ .
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!, 2 ~ 3 containing 20 ppm pyridine as the subject eas was passed through the catalyst bed at a space velocity of 20000 (l/hr) to adsorb the pyridine thereto. To the catalyst bed which had adsorbed pyridine, regeneration air at 240C was blo~n at a flow volume of 1/10 of that of the subject gas through a blowing hole having an outlet cross section o~ 150 mm x 20 mm provided at 1 mm above the c~atalyst bed to decompose the adsorbable substance and regenerate the catalyst. The speed of motion of the blowing hole for regenerating air above the catalyst bed was 1 reciprocal sliding cycle per 2 hours.
The exhaust gas resulting from treatment was analyzed using a detecting tube; no pyridine was detected in the exhaust gas.
Example 2 Gas treatment was carried out using the apparatus illustrated in Figure 3. A honeycomb catalyst carrying manganese oxide (MnOz/TiO2 SiO2, produced by Nippon Shokubai) was used to form a catalyst bed (circular, 200 mm ~ .
x 50 mm H, 210 cell/(inch)2), and room temperature air containing 20 ppm phenol as the subject gas was passed through the catalyst bed at a space veloity of 20000 (l/hr) to adsorb the phenol thereto. To the catalyst bed which had adsorbed phenol, regeneration air at 330C was blown at a flow volume of 1/5 of that of the subject gas through a fan-shaped blowing hole having an outlet cross sectional radius of 100 mm and a central angle Or 36 provided at 1 mm above the catalyst bed to decompose the adsorbable substance and regenerate the catalyst. The speed of motion of the blowing , :, ; . ..
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hole ror regenerating air above the catalyst bed ~as 1 rotational cycle per 1.5 hours.
The exhaust gas resulting from treatment was analyzed using a detecting tube; no phenol was detected in the exhaust gas.
Example 3 Gas treatment was carried out using the apparatus illustrated in Figure 3. A honeycomb catalyst carrying platinum (0.2% Pt/Al203, produced by N. E. Chemcat) was used to ~orm a catalyst bed (circular, 200 mm ~ . x 50 mm H, 210 cell/(inch)2), and room temperature air containing 20 ppm acetic acid as the subject gas was passed through the catalyst bed at a space velocity of 20000 (1/hr) to adsorb the acetic acid thereto. To the catalyst bed which had adsorbed acetic acid, regeneration air at 300CC was blown at a flow volume of 1/5 of that of the subject gas through a fan-shaped blowing hole having an outlet cross sectional radius of lO0 mm and a central angle of 36 provided at 1 mm above the catalyst bed to decompose the adsorbable substance and regenerate the catalyst. The speed of motion o~ the blowing hole for regenerating air above the catalyst bed was l rotational cycle per 2.0 hours.
The exhaust gas resulting from treatment was analyzed by gas chromatography; no acetic acid was detected in the exhaust ~as.
Examples 4 through 5 ~ sing the apparatus illustrated in Figure l or 3, ozone was previously added to the subject gas containing an ..
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adsorbable substance listed in Table 1 to be a concentration shown in Table 1, followed by treatment under the conditions shown in Table 1. The exhaust gas resulting from treatment was analyzed using a detecting tube; no adsorbable substance was detected in the exhaust gas in any case.
Example 6 Gas treatment was carried out using the apparatus illustrated in Figure 5. A catalyst bed of 150 mm x 200 mm x 50 mm H was divided into 10 equal sections in parallel to the direction of flow of the subject gas. Each section was packed with 1350 ml of grains of alumina catalyst carrying platinum (2 mm ~ ,0.2% Pt/Al203, produced by N. E. Chemcat) to form a catalyst bed. Room temperature air containing 15 ppm propionic acid as the subject gas was passed through the catalyst bed at a space velocity of 20000 (l/hr) to adsorb the propionic acid thereto. To the catalyst bed which had adsorbed propionic acid, regenerating air at 300C was blown at a flow volume of 1/10 of that of the subject gas through a blowing hole having an outlet cross~section of 150 mm x 20 mm provided at 1 mm above the catalyst bed to decompose the adsorbable substance and regenerate the catalyst. The blowing hole for regenerating air was moved above the catalyst bed sequentially from section to section at a speed of 1 reciprocal cycle per hour.
The exhaust gas resulting from treatment was analyzed by gas chromatography; no propionic acid was detected in the exhaust gas.
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--- 2 t Example 7 The subject gas containing 20 ppm pyridine ~las treated in the same manner as in Example 1 except that ozone-enriched air containing ozone obtained by rnixing regenerating air with air containing 3000 ppm of ozone at a flow volume of 1/100 of that of regenerating air was used as a regenerating gas in place of the regenerating air usecl in Example 1, and that the regenerating gas had a temperature of` 200oc. The exhaust gas resulting from treatment was analyzed using a detecting tube;
no pyridine was detected in the exhaust gas.
Examples 8 through 11 Using the apparatus illustrated in Figure 1 or 3, the subject gas containing an adsorbable substance or the subject gas obtained by previously adding ozone thereto (listed in Table 2) was treated with an ozone- or oxygen-enriched regenerating gas under the treating conditions shown in Table 2 in the same manner as in Example 7. The exhaust gas resulting from treatment was analyzed by gas chromatography;
no adsorbable substance was detected in the exhaust gas in any case.
Example 12 Gas treatment was carried out using the apparatus illustrated in Figure 5. The subject gas containing 15 ppm propionic acid was treated in the same manner as in Example 6 except that oxygen-enriched air prepared by blowing 99% oxygen at a flow volume of 1~10 of that of the regenerating air was used as a regenerating gas in place of ;
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the regenerating air used in Example 6, and that the regenerating gas had a temperature Or 240C. The exhaust gas resulting from treatment was analyzed by gas chromatography; no propionic acid was detected in the exhaust gas.
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Example 13 Gas treatment was carried out using the apparatus illustrated in Figure 6. An adsorbable substance was decomposed by blowing regenerating air and introducing and blowing 3000 ppm ozone gas through a feeding pipe to a position 1 mm apart from the catalyst bed in place of the regeneratin8 ozone-enriched gas prepared by previously mixing ozone with regenerating air in Example 7. Using the apparatus described above and the same subject gas as in Example 7, the subject gas was treated in the same manner as in Example 7 except that the regenerating air had a temperature of 190C.
Ozone gas was blown through a blowing slit with a cross sectional area of 1/10 of the cross sectional area of the blowing hole for regenerating gas provided at the inside of the blowing hole for regenerating gas.
The exhaust gas resulting from treatment was analyzed using a detecting tube; no pyridine was detected in the exhaust gas.
Examples 111 through 17 Using the apparatus illustrated in Figure 6 or 8, the subject gas containing an adsorbable substance or the subject gas obtained by previously adding ozone thereto (listed in Table 3) was treated under the treating conditions shown in Table 3 in the same manner as in Example 13. An adsorbable substance was decomposed by blowing regenerating air and introducing and blowing ozone or oxygen gas through a feeding pipe to a position 1 mm apart from the catalyst bed. The !
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exhaust gas resulting from treatment was analyzed using a detecting tube or by gas chromatography; no adsorbable substance was detec~e~ in the exhaust gas in any case.
Example 18 Gas treatment was carried out using the apparatus illustrated in Figure 10. An adsorbable substance was decomposed by blowing regenerating air and introducine and blowing oxygen through a f`eeding pipe to a position 1 mm apart from the catalyst bed in place of the regenerating oxygen-enriched gas prepared by previously mixing oxygen with regenerating air in Example 12. Using the apparatus described above and the same subject gas as in Example 12, the subject gas containing 15 ppm propionic acid was treated in the same manner as in Example 12 except that the regeneratin~ air had a temperature of 230C.
Oxygen was blown through a blowing slit with a cross sectional area of 1/10 of the cross sectional area of the blowing hole for regenerating gas provided at the inside o~
the blowing hole for regenerating gas.
The exhaust gas resulting from treatment was analyzed by gas chromatography; no propionic acid was detected in the exhaust gas.
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Example l9 Gas treatment was carried out using an apparatus having the same mechanism as of the apparatus illustrated in Figure 3 except that the subject gas was flown from the lower part Or the chamber. A honeycomb catalyst carrying manganese oxide (MnOz/Ti02-SiO2, produced by Nippon Shokubai3 was used to form a catalyst bed (circular, 200 mm ~ . x 50 mm H, 210 cell/(inch)2), and room temperature air containing 20 ppm phenol as the subject gas was passed through the catalyst bed at a space velocity of 20000 (l/hr) to adsorb the phenol thereto. To the catalyst bed which had adsorbed phenol, the regenerating air at 330C was blown at a flow volume of l/5 of that of the subject gas in the direction opposite to the direction of the subject gas through a fan-shaped blowing hole having an outlet cross sectional radius of 100 mm and a central angle of 1.8 to decompose the adsorbable substance and regenerate the catalyst. The speed of motion of the blowing hole for regenerating air above the catalyst bed was 1 rotational cycle per 1.5 hours.
The exhaust gas resulting from treatment was analyzed using a detecting tube; no phenol was detected in the exhaust gas.
Example 20 The subject gas containing 20 ppm phenol was treated in the same manner as in Example 19 excep~ that ozone-enriched air containing ozone obtained by mixing regenerating air with air containing 3000 ppm of ozone at a flow volume of 1/200 of .... . :
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that of regenerating air was used as a regenerating gas in place of the regenerating air used in Example l9, and that the regenerating gas had a temperature of 250C. The exhaust gas resulting from treatment was analyzed using a detecting tube; no phenol was detected in the exhaust gas.
Example 21 Gas treatment was carried out USillg an apparatus having the same mechanism as of the apparatus illustrated in Figure 8 except that the subject gas was flown from the lower part of the chamber.
Phenol was decomposed by blowing regenerating air and introducing and blowing 3000 ppm ozone gas through a feeding pipe to a position l mm apart from the catalyst bed in place of the regenerating ozone-enriched gas prepared by previously mixing ozone with regenerating air in Example 20. Ozone gas was blown through a blowing slit with a cross sectional area of l/10 of the cross sectional area of the blowing hole for regenerating gas provided at the inside of the blowing hole for regenerating gas.
Using the apparatus and method described above, the subject gas containing 20 ppm phenol was treated in the same manner as in Example 20 except that the regenerating air had a temperature of 240~C.
The exhaust gas resulting from treatment was analyzed using a detecting tube; no phenol was detected in the exhaust gas.
Example 22 2 ~ ~9~
Gas treatment was carried out using the apparatus illustrated in Figure 11.
To the catalyst bed to which phenol had been adsorbed in Example 19, regeneration air at 330C was blown at a rlOw volume of 1/10 o~ that of the subject gas in the direction opposite to the direction of flow of the subject gas through a fan-shaped blowing hole having an outlet cross sectional radius of 100 mm and a central angle of 1.8 and the regenerating gas after passing through the catalyst bed was reversed by a fan-shaped reversion pan having a radius of 100 mm and a central angle of 18 to pass it in the same direction as the direction of flow of the subject gas, whereby the adsorbable substance was decomposed and the catalyst was regenerated. The subject gas containing 20 ppm phenol was treated in the same manner as in Example 19 except that the apparatus described above was used.
The exhausk gas resulting from treatment was analyzed using a detecting tube; no phenol was detected in the exhaust gas.
Example 23 The subject gas containing 20 ppm phenol was treated in the same manner as in Example 22 except that ozone-enriched air containing ozone obtained by mixing regenerating air with air containing 3000 ppm of ozone at a flow volume Or 1/200 of that of regenerating air was used as a regenerating gas in place of the regenerating air used in Example 22, and that the regenerating gas had a temperature ~ .
~ . ' , ' , ~ 7~
of 250C. The exhaust gas resulting from treatment was analyzed using a detecting tube; no phenol was detected in the exhaust gas.
Example 24 Gas treat~ent was carried out using the apparatus illustrated in Figure 13. An adsorbable substance was decomposed by blowing regeneratinK air and introducing and blowing 3000 ppm ozone gas through a feedinB pipe to a position 1 mm apart from the catalyst bed in place of the regenerating ozone~enriched gas prepared by previously mixing ozone with regenerating air in Example 23. Using the apparatus described above, the subject gas containing 20 ppm phenol was treated in the same manner as in Example 23 except that the regenerating air had a temperature of 240C.
Ozone gas was blown through a blowing slit with a cross sectional area of 1/10 of the cross sectional area of the blowing hole for regenerating gas provided at the inside of the blowing hole for regenerating gas.
The exhaust gas resulting from treatment was analyzed using a detecting tube; no phenol was detected in the exhaust gas.
Example 25 Gas treatment was carried out using the apparatus illustrated in Figure 15. The subject gas containing 20 ppm phenol was treated in the same manner as in Example 24 except that the blowing slit for ozone gas was provided at the inside of the reversion pan in place of providing it at the inside of , . :
,, , : - 31-2~5597~) the blowing hole for regenerati.ng gas in Example 24.
The exhaust gas resulting from treatment was analyzed using a detecting tube; no phenol was detected in the exhaust gas.
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