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Zirconium difluoride

From Wikipedia, the free encyclopedia
Zirconium difluoride
Names
IUPAC name
difluorozirconium
Other names
Zirconium(II) fluoride
Identifiers
3D model (JSmol)
ChemSpider
UNII
  • InChI=1S/2FH.Zr/h2*1H;/q;;+2/p-2
    Key: COSHNDIHSFYGTR-UHFFFAOYSA-L
  • F[Zr]F
Properties
ZrF2
Appearanceblack crystals
Density3.6 g/cm3
Melting point902
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Zirconium difluoride is an inorganicchemical compound with the chemical formulaZrF2.[1][2]

Synthesis

[edit]

Zirconium difluoride can be prepared by the action of atomic hydrogen on thin layers ofzirconium tetrafluoride, at a temperature of approximately 350 °C.[3][4]

Physical properties

[edit]

ZrF2 forms black crystals of theorthorhombic system, with unit cell parameters a = 0.409 nm, b = 0.491 nm, c = 0.656 nm.[3]

The compound readily ignites and burns to formzirconium dioxide.[3]

Chemical properties

[edit]

ZrF2 disproportionates when heated to 800 °C:[3]

2ZrF2 → ZrF4 + Zr

References

[edit]
  1. ^Meshri, Dayal T. (26 January 2001). "Fluorine Compounds, Inorganic, Zirconium".Kirk-Othmer Encyclopedia of Chemical Technology.Wiley.doi:10.1002/0471238961.2609180313051908.a01.ISBN 978-0-471-48494-3. Retrieved22 July 2024.
  2. ^Hawkins, Donald T. (6 December 2012).Binary Fluorides: Free Molecular Structures and Force Fields A Bibliography (1957–1975).Springer Science & Business Media. p. 77.ISBN 978-1-4684-6147-3. Retrieved22 July 2024.
  3. ^abcdMcTaggart, F. K.; Turnbull, A. G. (1964)."Zirconium difluoride".Australian Journal of Chemistry.17 (7):727–730.doi:10.1071/ch9640727.ISSN 1445-0038. Retrieved19 July 2024.
  4. ^Haupt, Axel (22 March 2021).Organic and Inorganic Fluorine Chemistry: Methods and Applications.Walter de Gruyter GmbH & Co KG.ISBN 978-3-11-065950-4. Retrieved22 July 2024.
Zr(II)
Zr(III)
Zr(IV)
Acids and complexes
Organozirconium(IV)
Salts and covalent derivatives of thefluoride ion
HF?HeF2
LiFBeF2BF
BF3
B2F4
+BO3
CF4
CxFy
+CO3
NF3
FN3
N2F2
NF
N2F4
NF2
?NF5
+N
+NO3
OF2
O2F2
OF
O3F2
O4F2
?OF4
F2Ne
NaFMgF2AlF
AlF3
SiF4P2F4
PF3
PF5
+PO4
S2F2
SF2
S2F4
SF3
SF4
S2F10
SF6
+SO4
ClF
ClF3
ClF5
?ArF2
?ArF4
KFCaF
CaF2
ScF3TiF2
TiF3
TiF4
VF2
VF3
VF4
VF5
CrF2
CrF3
CrF4
CrF5
?CrF6
MnF2
MnF3
MnF4
?MnF5
FeF2
FeF3
FeF4
CoF2
CoF3
CoF4
NiF2
NiF3
NiF4
CuF
CuF2
?CuF3
ZnF2GaF2
GaF3
GeF2
GeF4
AsF3
AsF5
Se2F2
SeF4
SeF6
+SeO3
BrF
BrF3
BrF5
KrF2
?KrF4
?KrF6
RbFSrF
SrF2
YF3ZrF2
ZrF3
ZrF4
NbF4
NbF5
MoF4
MoF5
MoF6
TcF4
TcF
5

TcF6
RuF3
RuF
4

RuF5
RuF6
RhF3
RhF4
RhF5
RhF6
PdF2
Pd[PdF6]
PdF4
?PdF6
Ag2F
AgF
AgF2
AgF3
CdF2InF
InF3
SnF2
SnF4
SbF3
SbF5
TeF4
?Te2F10
TeF6
+TeO3
IF
IF3
IF5
IF7
+IO3
XeF2
XeF4
XeF6
?XeF8
CsFBaF2 LuF3HfF4TaF5WF4
WF5
WF6
ReF4
ReF5
ReF6
ReF7
OsF4
OsF5
OsF6
?OsF
7

?OsF
8
IrF2
IrF3
IrF4
IrF5
IrF6
PtF2
Pt[PtF6]
PtF4
PtF5
PtF6
AuF
AuF3
Au2F10
?AuF6
AuF5•F2
Hg2F2
HgF2
?HgF4
TlF
TlF3
PbF2
PbF4
BiF3
BiF5
PoF2
PoF4
PoF6
AtF
?AtF3
?AtF5
RnF2
?RnF
4

?RnF
6
FrFRaF2 LrF3RfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
LaF3CeF3
CeF4
PrF3
PrF4
NdF2
NdF3
NdF4
PmF3SmF
SmF2
SmF3
EuF2
EuF3
GdF3TbF3
TbF4
DyF2
DyF3
DyF4
HoF3ErF3TmF2
TmF3
YbF2
YbF3
AcF3ThF2
ThF3
ThF4
PaF4
PaF5
UF3
UF4
UF5
UF6
NpF3
NpF4
NpF5
NpF6
PuF3
PuF4
PuF5
PuF6
AmF2
AmF3
AmF4
?AmF6
CmF3
CmF4
 ?CmF6
BkF3
BkF
4
CfF3
CfF4
EsF3
EsF4
?EsF6
FmMdF3No
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