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Zirconium(II) iodide

From Wikipedia, the free encyclopedia
Zirconium(II) iodide
Names
IUPAC name
diiodozirconium
Other names
Zirconium diiodide
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/2HI.Zr/h2*1H;/q;;+2/p-2
    Key: GODQOUBOGDKMGD-UHFFFAOYSA-L
  • [Zr](I)I
Properties
ZrI2
Appearancesolid
Melting point827
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Zirconium(II) iodide is an inorganicchemical compound with the chemical formulaZrI2.[1][2]

Synthesis

[edit]

Zirconium diiodide can be prepared from theZrI3 bydisproportionation at 360–390°. At higher temperatures, the diiodide disproportionates to the tetraiodide and metallic zirconium.[3]

References

[edit]
  1. ^"Zirconium(II) Iodide".American Elements. Retrieved19 July 2024.
  2. ^Mines, United States Bureau of (1984).Bulletin. U.S. Government Printing Office. p. 247. Retrieved19 July 2024.
  3. ^Clark, R. J. H.; Bradley, D. C.; Thornton, P. (12 March 2018).The Chemistry of Titanium, Zirconium and Hafnium: Pergamon Texts in Inorganic Chemistry.Elsevier. p. 433.ISBN 978-1-4831-5921-8. Retrieved19 July 2024.
Zr(II)
Zr(III)
Zr(IV)
Acids and complexes
Organozirconium(IV)
Salts and covalent derivatives of theiodide ion
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