Liquid helium retainskinetic energy and does not freeze regardless of temperature at standard atmospheric pressure due to zero-point energy. When cooled below itsLambda point, it exhibits properties ofsuperfluidity.
The notion of a zero-point energy is also important forcosmology, and physics currently lacks a full theoretical model for understanding zero-point energy in this context; in particular, the discrepancy between theorized and observed vacuum energy in the universe is a source of major contention.[4] Yet according to Einstein's theory ofgeneral relativity, any such energy would gravitate, and the experimental evidence from theexpansion of the universe,dark energy and theCasimir effect shows any such energy to be exceptionally weak. One proposal that attempts to address this issue is to say that thefermion field has a negative zero-point energy, while theboson field has positive zero-point energy and thus these energies somehow cancel out each other.[5][6] This idea would be true ifsupersymmetry were an exactsymmetry of nature; however, theLarge Hadron Collider atCERN has so far found no evidence to support it. Moreover, it is known that if supersymmetry is valid at all, it is at most abroken symmetry, only true at very high energies, and no one has been able to show a theory where zero-point cancellations occur in the low-energy universe we observe today.[6] This discrepancy is known as thecosmological constant problem and it is one of the greatestunsolved mysteries in physics. Many physicists believe that "the vacuum holds the key to a full understanding of nature".[7]
The termzero-point energy (ZPE)is a translation from the GermanNullpunktsenergie.[8] Sometimes used interchangeably with it are the termszero-point radiation andground state energy. The termzero-point field (ZPF) can be used when referring to a specific vacuum field, for instance theQED vacuum which specifically deals withquantum electrodynamics (e.g., electromagnetic interactions between photons, electrons and the vacuum) or theQCD vacuum which deals withquantum chromodynamics (e.g.,color charge interactions between quarks, gluons and the vacuum). A vacuum can be viewed not as empty space but as the combination of all zero-point fields. Inquantum field theory this combination of fields is called the vacuum state, and its associated zero-point energy is called thevacuum energy.
Inclassical mechanics allparticles can be thought of as having someenergy made up of theirpotential energy andkinetic energy.Temperature, for example, arises from the intensity of random particle motion caused by kinetic energy (known asBrownian motion). As temperature is reduced toabsolute zero, it might be thought that all motion ceases and particles come completely to rest. In fact, however, kinetic energy is retained by particles even at the lowest possible temperature. The random motion corresponding to this zero-point energy never vanishes; it is a consequence of theuncertainty principle ofquantum mechanics.[citation needed]
Zero-point radiation continually imparts random impulses on anelectron, so that it never comes to a complete stop. Zero-point radiation gives theoscillator an average energy equal to the frequency of oscillation multiplied by one-half of thePlanck constant.
The uncertainty principle states that no object can ever have precise values of position and velocity simultaneously. The total energy of a quantum mechanical object (potential and kinetic) is described by itsHamiltonian which also describes the system as a harmonic oscillator, orwave function, that fluctuates between various energy states (seewave-particle duality). All quantum mechanical systems undergo fluctuations even in their ground state, a consequence of theirwave-like nature. The uncertainty principle requires every quantum mechanical system to have a fluctuating zero-point energy greater than the minimum of its classicalpotential well. This results in motion even at absolute zero. For example,liquid helium does not freeze under atmospheric pressure regardless of temperature due to its zero-point energy.
Given the equivalence of mass and energy expressed byAlbert Einstein'sE =mc2, any point inspace that contains energy can be thought of as having mass to create particles. Modern physics has developed quantum field theory (QFT) to understand the fundamental interactions between matter and forces; it treats every single point of space as aquantum harmonic oscillator. According to QFT the universe is made up of matter fields, whose quanta arefermions (i.e.leptons and quarks), and force fields, whose quanta arebosons (e.g.photons andgluons). All these fields have zero-point energy.[2] Recent experiments support the idea that particles themselves can be thought of as excited states of the underlyingquantum vacuum, and that all properties of matter are merely vacuum fluctuations arising from interactions of the zero-point field.[9]
The idea that "empty" space can have an intrinsic energy associated with it, and that there is no such thing as a "true vacuum" is seemingly unintuitive. It is often argued that the entire universe is completely bathed in the zero-point radiation, and as such it can add only some constant amount to calculations. Physical measurements will therefore reveal only deviations from this value.[10] For many practical calculations zero-point energy is dismissed by fiat in the mathematical model as a term that has no physical effect. Such treatment causes problems however, as in Einstein's theory ofgeneral relativity the absolute energy value of space is not an arbitrary constant and gives rise to thecosmological constant. For decades most physicists assumed that there was some undiscovered fundamental principle that will remove the infinite zero-point energy (discussed further below) and make it completely vanish. If the vacuum has no intrinsic, absolute value of energy it will not gravitate. It was believed that as the universe expands from the aftermath of theBig Bang, the energy contained in any unit of empty space will decrease as the total energy spreads out to fill the volume of the universe;galaxies and all matter in the universe should begin to decelerate. This possibility was ruled out in 1998 by the discovery that the expansion of the universe is not slowing down but is in fact accelerating, meaning empty space does indeed have some intrinsic energy. The discovery ofdark energy is best explained by zero-point energy, though it still remains a mystery as to why the value appears to be so small compared to the huge value obtained through theory – thecosmological constant problem.[5]
Zero-point energy evolved from historical ideas about thevacuum. ToAristotle the vacuum wasτὸ κενόν, "the empty"; i.e., space independent of body. He believed this concept violated basic physical principles and asserted thatthe elements offire,air,earth, andwater were not made of atoms, but were continuous. To theatomists the concept of emptiness had absolute character: it was the distinction between existence and nonexistence.[21] Debate about the characteristics of the vacuum were largely confined to the realm ofphilosophy, it was not until much later on with the beginning ofthe renaissance, thatOtto von Guericke invented the first vacuum pump and the first testable scientific ideas began to emerge. It was thought that a totally empty volume of space could be created by simply removing all gases. This was the first generally accepted concept of the vacuum.[22]
Late in the 19th century, however, it became apparent that the evacuated region still containedthermal radiation. The existence of theaether as a substitute for a true void was the most prevalent theory of the time. According to the successfulelectromagnetic aether theory based uponMaxwell'selectrodynamics, this all-encompassing aether was endowed with energy and hence very different from nothingness. The fact that electromagnetic and gravitational phenomena were transmitted in empty space was considered evidence that their associated aethers were part of the fabric of space itself. However Maxwell noted that for the most part these aethers weread hoc:
To those who maintained the existence of a plenum as a philosophical principle, nature's abhorrence of a vacuum was a sufficient reason for imagining an all-surrounding aether ... Aethers were invented for the planets to swim in, to constitute electric atmospheres and magnetic effluvia, to convey sensations from one part of our bodies to another, and so on, till a space had been filled three or four times with aethers.[23]
Moreever, the results of theMichelson–Morley experiment in 1887 were the first strong evidence that the then-prevalent aether theories were seriously flawed, and initiated a line of research that eventually led tospecial relativity, which ruled out the idea of a stationary aether altogether. To scientists of the period, it seemed that a true vacuum in space might be created by cooling and thus eliminating all radiation or energy. From this idea evolved the second concept of achieving a real vacuum: cool a region of space down to absolute zero temperature after evacuation. Absolute zero was technically impossible to achieve in the 19th century, so the debate remained unsolved.
In 1900,Max Planck derived the average energyε of a singleenergy radiator, e.g., a vibrating atomic unit, as a function of absolute temperature:[24]whereh is thePlanck constant,ν is thefrequency,k is theBoltzmann constant, andT is the absolutetemperature. The zero-point energy makes no contribution to Planck's original law, as its existence was unknown to Planck in 1900.[25]
The concept of zero-point energy was developed byMax Planck in Germany in 1911 as a corrective term added to a zero-grounded formula developed in his original quantum theory in 1900.[26]
In 1912, Max Planck published the first journal article to describe the discontinuous emission of radiation, based on the discrete quanta of energy.[27] In Planck's "second quantum theory" resonators absorbed energy continuously, but emitted energy in discrete energy quanta only when they reached the boundaries of finite cells in phase space, where their energies became integer multiples ofhν. This theory led Planck to his new radiation law, but in this version energy resonators possessed a zero-point energy, the smallest average energy a resonator could take on. Planck's radiation equation contained a residual energy factor, onehν/2, as an additional term dependent on the frequencyν, which was greater than zero (whereh is the Planck constant). It is therefore widely agreed that "Planck's equation marked the birth of the concept of zero-point energy."[28] In a series of papers from 1911 to 1913,[29] Planck found the average energy of an oscillator to be:[26][30]
Einstein's official 1921 portrait after receiving the Nobel Prize in Physics
Soon, the idea of zero-point energy attracted the attention of Albert Einstein and his assistantOtto Stern.[31] In 1913 they published a paper that attempted to prove the existence of zero-point energy by calculating thespecific heat of hydrogen gas and compared it with the experimental data. However, after assuming they had succeeded, they retracted support for the idea shortly after publication because they found Planck's second theory may not apply to their example. In a letter toPaul Ehrenfest of the same year Einstein declared zero-point energy "dead as a doornail".[32] Zero-point energy was also invoked byPeter Debye,[33] who noted that zero-point energy of the atoms of acrystal lattice would cause a reduction in the intensity of the diffracted radiation inX-ray diffraction even as the temperature approached absolute zero. In 1916Walther Nernst proposed that empty space was filled with zero-pointelectromagnetic radiation.[34] With the development of general relativity Einstein found the energy density of the vacuum to contribute towards a cosmological constant in order to obtain static solutions to his field equations; the idea that empty space, or the vacuum, could have some intrinsic energy associated with it had returned, with Einstein stating in 1920:
There is a weighty argument to be adduced in favour of the aether hypothesis. To deny the aether is ultimately to assume that empty space has no physical qualities whatever. The fundamental facts of mechanics do not harmonize with this view ... according to the general theory of relativity space is endowed with physical qualities; in this sense, therefore, there exists an aether. According to the general theory of relativity space without aether is unthinkable; for in such space there not only would be no propagation of light, but also no possibility of existence for standards of space and time (measuring-rods and clocks), nor therefore any space-time intervals in the physical sense. But this aether may not be thought of as endowed with the quality characteristic of ponderable media, as consisting of parts which may be tracked through time. The idea of motion may not be applied to it.[35][36]
Heisenberg, 1924
Kurt Bennewitz [de] andFrancis Simon (1923),[37] who worked atWalther Nernst's laboratory in Berlin, studied the melting process of chemicals at low temperatures. Their calculations of the melting points ofhydrogen,argon andmercury led them to conclude that the results provided evidence for a zero-point energy. Moreover, they suggested correctly, as was later verified by Simon (1934),[38][39] that this quantity was responsible for the difficulty in solidifying helium even at absolute zero. In 1924Robert Mulliken[40] provided direct evidence for the zero-point energy of molecular vibrations by comparing the band spectrum of10BO and11BO: the isotopic difference in the transition frequencies between the ground vibrational states of two different electronic levels would vanish if there were no zero-point energy, in contrast to the observed spectra. Then just a year later in 1925,[41] with the development ofmatrix mechanics inWerner Heisenberg's article "Quantum theoretical re-interpretation of kinematic and mechanical relations" the zero-point energy was derived from quantum mechanics.[42]
In 1913Niels Bohr had proposed what is now called theBohr model of the atom,[43][44][45] but despite this it remained a mystery as to why electrons do not fall into their nuclei. According to classical ideas, the fact that an accelerating charge loses energy by radiating implied that an electron should spiral into the nucleus and that atoms should not be stable. This problem of classical mechanics was nicely summarized byJames Hopwood Jeans in 1915: "There would be a very real difficulty in supposing that the (force) law1/r2 held down to the zero values ofr. For the force between two charges at zero distance would be infinite; we should have charges of opposite sign continually rushing together and, when once together, no force would be adequate to separate them. [...] Thus the matter in the universe would tend to shrink into nothing or to diminish indefinitely in size."[46] The resolution to this puzzle came in 1926 whenErwin Schrödinger introduced theSchrödinger equation.[47] This equation explained the new, non-classical fact that an electron confined to be close to a nucleus would necessarily have a large kinetic energy so that the minimum total energy (kinetic plus potential) actually occurs at some positive separation rather than at zero separation; in other words, zero-point energy is essential for atomic stability.[48]
In 1926,Pascual Jordan[49] published the first attempt to quantize the electromagnetic field. In a joint paper withMax Born andWerner Heisenberg he considered the field inside a cavity as a superposition of quantum harmonic oscillators. In his calculation he found that in addition to the "thermal energy" of the oscillators there also had to exist an infinite zero-point energy term. He was able to obtain the same fluctuation formula that Einstein had obtained in 1909.[50] However, Jordan did not think that his infinite zero-point energy term was "real", writing to Einstein that "it is just a quantity of the calculation having no direct physical meaning".[51] Jordan found a way to get rid of the infinite term, publishing a joint work with Pauli in 1928,[52] performing what has been called "the first infinite subtraction, or renormalisation, in quantum field theory".[53]
Paul Dirac, 1933
Building on the work of Heisenberg and others,Paul Dirac's theory of emission and absorption (1927)[54] was the first application of the quantum theory of radiation. Dirac's work was seen as crucially important to the emerging field of quantum mechanics; it dealt directly with the process in which "particles" are actually created:spontaneous emission.[55] Dirac described the quantization of theelectromagnetic field as an ensemble ofharmonic oscillators with the introduction of the concept ofcreation and annihilation operators of particles. The theory showed that spontaneous emission depends upon the zero-point energy fluctuations of the electromagnetic field in order to get started.[56][57] In a process in which a photon is annihilated (absorbed), the photon can be thought of as making a transition into the vacuum state. Similarly, when a photon is created (emitted), it is occasionally useful to imagine that the photon has made a transition out of the vacuum state. In the words of Dirac:[54]
The light-quantum has the peculiarity that it apparently ceases to exist when it is in one of its stationary states, namely, the zero state, in which its momentum and therefore also its energy, are zero. When a light-quantum is absorbed it can be considered to jump into this zero state, and when one is emitted it can be considered to jump from the zero state to one in which it is physically in evidence, so that it appears to have been created. Since there is no limit to the number of light-quanta that may be created in this way, we must suppose that there are an infinite number of light quanta in the zero state ...
Contemporary physicists, when asked to give a physical explanation for spontaneous emission, generally invoke the zero-point energy of the electromagnetic field. This view was popularized byVictor Weisskopf who in 1935 wrote:[58]
From quantum theory there follows the existence of so called zero-point oscillations; for example each oscillator in its lowest state is not completely at rest but always is moving about its equilibrium position. Therefore electromagnetic oscillations also can never cease completely. Thus the quantum nature of the electromagnetic field has as its consequence zero point oscillations of the field strength in the lowest energy state, in which there are no light quanta in space ... The zero point oscillations act on an electron in the same way as ordinary electrical oscillations do. They can change the eigenstate of the electron, but only in a transition to a state with the lowest energy, since empty space can only take away energy, and not give it up. In this way spontaneous radiation arises as a consequence of the existence of these unique field strengths corresponding to zero point oscillations. Thus spontaneous radiation is induced radiation of light quanta produced by zero point oscillations of empty space
This view was also later supported byTheodore Welton (1948),[59] who argued that spontaneous emission "can be thought of as forced emission taking place under the action of the fluctuating field". This new theory, which Dirac coinedquantum electrodynamics (QED), predicted a fluctuating zero-point or "vacuum" field existing even in the absence of sources.
Throughout the 1940s improvements inmicrowave technology made it possible to take more precise measurements of the shift of the levels of ahydrogen atom, now known as the Lamb shift,[60] and measurement of themagnetic moment of the electron.[61] Discrepancies between these experiments and Dirac's theory led to the idea of incorporatingrenormalisation into QED to deal with zero-point infinities. Renormalization was originally developed byHans Kramers[62] and alsoVictor Weisskopf (1936),[63] and first successfully applied to calculate a finite value for the Lamb shift byHans Bethe (1947).[64] As per spontaneous emission, these effects can in part be understood with interactions with the zero-point field.[65][11] But in light of renormalisation being able to remove some zero-point infinities from calculations, not all physicists were comfortable attributing zero-point energy any physical meaning, viewing it instead as a mathematical artifact that might one day be eliminated. InWolfgang Pauli's 1945Nobel lecture[66] he made clear his opposition to the idea of zero-point energy stating "It is clear that this zero-point energy has no physical reality".
Hendrik Casimir (1958)
In 1948Hendrik Casimir[67][68] showed that one consequence of the zero-point field is an attractive force between two uncharged, perfectly conducting parallel plates, the so-called Casimir effect. At the time, Casimir was studying the properties ofcolloidal solutions. These are viscous materials, such as paint and mayonnaise, that contain micron-sized particles in a liquid matrix. The properties of such solutions are determined byVan der Waals forces – short-range, attractive forces that exist between neutral atoms and molecules. One of Casimir's colleagues, Theo Overbeek, realized that the theory that was used at the time to explain Van der Waals forces, which had been developed byFritz London in 1930,[69][70] did not properly explain the experimental measurements on colloids. Overbeek therefore asked Casimir to investigate the problem. Working withDirk Polder, Casimir discovered that the interaction between two neutral molecules could be correctly described only if the fact that light travels at a finite speed was taken into account.[71] Soon afterwards after a conversation withBohr about zero-point energy, Casimir noticed that this result could be interpreted in terms of vacuum fluctuations. He then asked himself what would happen if there were two mirrors – rather than two molecules – facing each other in a vacuum. It was this work that led to his prediction of an attractive force between reflecting plates. The work by Casimir and Polder opened up the way to a unified theory of van der Waals and Casimir forces and a smooth continuum between the two phenomena. This was done by Lifshitz (1956)[72][73][74] in the case of plane paralleldielectric plates. The generic name for both van der Waals and Casimir forces is dispersion forces, because both of them are caused by dispersions of the operator of the dipole moment.[75] The role of relativistic forces becomes dominant at orders of a hundred nanometers.
In 1951Herbert Callen and Theodore Welton[76] proved the quantumfluctuation-dissipation theorem (FDT) which was originally formulated in classical form byNyquist (1928)[77] as an explanation for observedJohnson noise in electric circuits.[78] The fluctuation-dissipation theorem showed that when something dissipates energy, in an effectively irreversible way, a connected heat bath must also fluctuate. The fluctuations and the dissipation go hand in hand; it is impossible to have one without the other. The implication of FDT being that the vacuum could be treated as a heat bath coupled to a dissipative force and as such energy could, in part, be extracted from the vacuum for potentially useful work.[79] FDT has been shown to be true experimentally under certain quantum, non-classical, conditions.[80][81][82]
In 1963 theJaynes–Cummings model[83] was developed describing the system of atwo-level atom interacting with a quantized field mode (i.e. the vacuum) within an optical cavity. It gave nonintuitive predictions such as that an atom's spontaneous emission could be driven by field of effectively constant frequency (Rabi frequency). In the 1970s experiments were being performed to test aspects of quantum optics and showed that the rate of spontaneous emission of an atom could be controlled using reflecting surfaces.[84][85] These results were at first regarded with suspicion in some quarters: it was argued that no modification of a spontaneous emission rate would be possible, after all, how can the emission of a photon be affected by an atom's environment when the atom can only "see" its environment by emitting a photon in the first place? These experiments gave rise tocavity quantum electrodynamics (CQED), the study of effects of mirrors and cavities on radiative corrections. Spontaneous emission can be suppressed (or "inhibited")[86][87] or amplified. Amplification was first predicted by Purcell in 1946[88] (thePurcell effect) and has been experimentally verified.[89] This phenomenon can be understood, partly, in terms of the action of the vacuum field on the atom.[90]
Zero-point energy is fundamentally related to the Heisenberg uncertainty principle.[91] Roughly speaking, the uncertainty principle states that complementary variables (such as a particle's position andmomentum, or a field's value and derivative at a point in space) cannot simultaneously be specified precisely by any given quantum state. In particular, there cannot exist a state in which the system simply sits motionless at the bottom of its potential well, for then its position and momentum would both be completely determined to arbitrarily great precision. Therefore, the lowest-energy state (the ground state) of the system must have a distribution in position and momentum that satisfies the uncertainty principle, which implies its energy must be greater than the minimum of the potential well.
The uncertainty principle tells us thatmaking theexpectation values of the kinetic andpotential terms above satisfy
The expectation value of the energy must therefore be at least
whereω =√k/m is theangular frequency at which the system oscillates.
A more thorough treatment, showing that the energy of the ground state actually saturates this bound and is exactlyE0 =V0 +ħω/2, requires solving for the ground state of the system.
The zero-point energyE =ħω/2 causes the ground-state of a harmonic oscillator to advance its phase (color). This has measurable effects when several eigenstates are superimposed.
The idea of a quantum harmonic oscillator and its associated energy can apply to either an atom or a subatomic particle. In ordinary atomic physics, the zero-point energy is the energy associated with theground state of the system. The professional physics literature tends to measure frequency, as denoted byν above, usingangular frequency, denoted withω and defined byω = 2πν. This leads to a convention of writing the Planck constanth with a bar through its top (ħ) to denote the quantityh/2π. In these terms, an example of zero-point energy is the aboveE =ħω/2 associated with the ground state of the quantum harmonic oscillator. In quantum mechanical terms, the zero-point energy is theexpectation value of the Hamiltonian of the system in the ground state.
If more than one ground state exists, they are said to bedegenerate. Many systems have degenerate ground states. Degeneracy occurs whenever there exists aunitary operator which acts non-trivially on a ground state andcommutes with the Hamiltonian of the system.
According to thethird law of thermodynamics, a system at absolute zero temperature exists in its ground state; thus, itsentropy is determined by the degeneracy of the ground state. Many systems, such as a perfectcrystal lattice, have a unique ground state and therefore have zero entropy at absolute zero. It is also possible for the highest excited state to have absolute zero temperature for systems that exhibitnegative temperature.
Thewave function of the ground state of aparticle in a one-dimensional well is a half-periodsine wave which goes to zero at the two edges of the well. The energy of the particle is given by:whereh is thePlanck constant,m is the mass of the particle,n is the energy state (n = 1 corresponds to the ground-state energy), andL is the width of the well.
In quantum field theory (QFT), the fabric of "empty" space is visualized as consisting offields, with the field at every point in space and time being a quantum harmonic oscillator, with neighboring oscillators interacting with each other. According to QFT the universe is made up of matter fields whosequanta are fermions (e.g.electrons and quarks), force fields whose quanta are bosons (i.e. photons and gluons) and a Higgs field whose quantum is theHiggs boson. The matter and force fields have zero-point energy.[2] A related term iszero-point field (ZPF), which is the lowest energy state of a particular field.[92] The vacuum can be viewed not as empty space, but as the combination of all zero-point fields.
In QFT the zero-point energy of the vacuum state is called the vacuum energy and the average expectation value of the Hamiltonian is called the vacuum expectation value (also called condensate or simply VEV). The QED vacuum is a part of the vacuum state which specifically deals with quantum electrodynamics (e.g. electromagnetic interactions between photons, electrons and the vacuum) and the QCD vacuum deals withquantum chromodynamics (e.g.color charge interactions between quarks, gluons and the vacuum). Recent experiments advocate the idea that particles themselves can be thought of as excited states of the underlyingquantum vacuum, and that all properties of matter are merely vacuum fluctuations arising from interactions with the zero-point field.[9]
Each point in space makes a contribution ofE =ħω/2, resulting in a calculation of infinite zero-point energy in any finite volume; this is one reasonrenormalization is needed to make sense of quantum field theories. Incosmology, the vacuum energy is one possible explanation for the cosmological constant[18] and the source of dark energy.[19][20]
Scientists are not in agreement about how much energy is contained in the vacuum. Quantum mechanics requires the energy to be large asPaul Dirac claimed it is, like asea of energy. Other scientists specializing inGeneral Relativity require the energy to be small enough forcurvature of space to agree with observedastronomy. The Heisenberg uncertainty principle allows the energy to be as large as needed to promote quantum actions for a brief moment of time, even if the average energy is small enough to satisfy relativity and flat space. To cope with disagreements, the vacuum energy is described as avirtual energypotential of positive and negative energy.[93]
The oldest and best known quantized force field is theelectromagnetic field.Maxwell's equations have been superseded by quantum electrodynamics (QED). By considering the zero-point energy that arises from QED it is possible to gain a characteristic understanding of zero-point energy that arises not just through electromagnetic interactions but in allquantum field theories.
In the quantum theory of the electromagnetic field, classical wave amplitudesα andα* are replaced by operatorsa anda† that satisfy:
The classical quantity|α|2 appearing in the classical expression for the energy of a field mode is replaced in quantum theory by the photon number operatora†a. The fact that:implies that quantum theory does not allow states of the radiation field for which the photon number and a field amplitude can be precisely defined, i.e., we cannot have simultaneous eigenstates fora†a anda. The reconciliation of wave and particle attributes of the field is accomplished via the association of a probability amplitude with a classical mode pattern. The calculation of field modes is entirely classical problem, while the quantum properties of the field are carried by the mode "amplitudes"a† anda associated with these classical modes.
The zero-point energy of the field arises formally from the non-commutativity ofa anda†. This is true for any harmonic oscillator: the zero-point energyħω/2 appears when we write the Hamiltonian:
It is often argued that the entire universe is completely bathed in the zero-point electromagnetic field, and as such it can add only some constant amount to expectation values. Physical measurements will therefore reveal only deviations from the vacuum state. Thus the zero-point energy can be dropped from the Hamiltonian by redefining the zero of energy, or by arguing that it is a constant and therefore has no effect on Heisenberg equations of motion. Thus we can choose to declare by fiat that the ground state has zero energy and a field Hamiltonian, for example, can be replaced by:[10]without affecting any physical predictions of the theory. The new Hamiltonian is said to benormally ordered (or Wick ordered) and is denoted by a double-dot symbol. The normally ordered Hamiltonian is denoted:HF, i.e.:
In other words, within the normal ordering symbol we can commutea anda†. Since zero-point energy is intimately connected to the non-commutativity ofa anda†, the normal ordering procedure eliminates any contribution from the zero-point field. This is especially reasonable in the case of the field Hamiltonian, since the zero-point term merely adds a constant energy which can be eliminated by a simple redefinition for the zero of energy. Moreover, this constant energy in the Hamiltonian obviously commutes witha anda† and so cannot have any effect on the quantum dynamics described by the Heisenberg equations of motion.
However, things are not quite that simple. The zero-point energy cannot be eliminated by dropping its energy from the Hamiltonian: When we do this and solve the Heisenberg equation for a field operator, we must include the vacuum field, which is the homogeneous part of the solution for the field operator. In fact we can show that the vacuum field is essential for the preservation of the commutators and the formal consistency of QED. When we calculate the field energy we obtain not only a contribution from particles and forces that may be present but also a contribution from the vacuum field itself i.e. the zero-point field energy. In other words, the zero-point energy reappears even though we may have deleted it from the Hamiltonian.[94]
From Maxwell's equations, the electromagnetic energy of a "free" field i.e. one with no sources, is described by:
We introduce the "mode function"A0(r) that satisfies theHelmholtz equation:wherek =ω/c and assume it is normalized such that:
We wish to "quantize" the electromagnetic energy of free space for a multimode field. The field intensity of free space should be independent of position such that|A0(r)|2 should be independent ofr for each mode of the field. The mode function satisfying these conditions is:wherek ·ek = 0 in order to have the transversality condition∇ ·A(r,t) satisfied for the Coulomb gauge[dubious –discuss] in which we are working.
To achieve the desired normalization we pretend space is divided into cubes of volumeV =L3 and impose on the field the periodic boundary condition:or equivalentlywheren can assume any integer value. This allows us to consider the field in any one of the imaginary cubes and to define the mode function:which satisfies the Helmholtz equation, transversality, and the "box normalization":whereek is chosen to be a unit vector which specifies the polarization of the field mode. The conditionk ·ek = 0 means that there are two independent choices ofek, which we callek1 andek2 whereek1 ·ek2 = 0 ande2 k1 =e2 k2 = 1. Thus we define the mode functions:in terms of which the vector potential becomes[clarification needed]:or:whereωk =kc andakλ,a† kλ are photon annihilation and creation operators for the mode with wave vectork and polarizationλ. This gives the vector potential for a plane wave mode of the field. The condition for(kx,ky,kz) shows that there are infinitely many such modes. The linearity of Maxwell's equations allows us to write:for the total vector potential in free space. Using the fact that:we find the field Hamiltonian is:
This is the Hamiltonian for an infinite number of uncoupled harmonic oscillators. Thus different modes of the field are independent and satisfy the commutation relations:
Clearly the least eigenvalue forHF is:
This state describes the zero-point energy of the vacuum. It appears that this sum is divergent – in fact highly divergent, as putting in the density factorshows. The summation becomes approximately the integral:for high values ofv. It diverges proportional tov4 for largev.
There are two separate questions to consider. First, is the divergence a real one such that the zero-point energy really is infinite? If we consider the volumeV is contained by perfectly conducting walls, very high frequencies can only be contained by taking more and more perfect conduction. No actual method of containing the high frequencies is possible. Such modes will not be stationary in our box and thus not countable in the stationary energy content. So from this physical point of view the above sum should only extend to those frequencies which are countable; a cut-off energy is thus eminently reasonable. However, on the scale of a "universe" questions of general relativity must be included. Suppose even the boxes could be reproduced, fit together and closed nicely by curving spacetime. Then exact conditions for running waves may be possible. However the very high frequency quanta will still not be contained. As per John Wheeler's "geons"[95] these will leak out of the system. So again a cut-off is permissible, almost necessary. The question here becomes one of consistency since the very high energy quanta will act as a mass source and start curving the geometry.
This leads to the second question. Divergent or not, finite or infinite, is the zero-point energy of any physical significance? The ignoring of the whole zero-point energy is often encouraged for all practical calculations. The reason for this is that energies are not typically defined by an arbitrary data point, but rather changes in data points, so adding or subtracting a constant (even if infinite) should be allowed. However this is not the whole story, in reality energy is not so arbitrarily defined: in general relativity the seat of the curvature of spacetime is the energy content and there the absolute amount of energy has real physical meaning. There is no such thing as an arbitrary additive constant with density of field energy. Energy density curves space, and an increase in energy density produces an increase of curvature. Furthermore, the zero-point energy density has other physical consequences e.g. the Casimir effect, contribution to the Lamb shift, or anomalous magnetic moment of the electron, it is clear it is not just a mathematical constant or artifact that can be cancelled out.[96]
The vacuum state of the "free" electromagnetic field (that with no sources) is defined as the ground state in whichnkλ = 0 for all modes(k,λ). The vacuum state, like all stationary states of the field, is an eigenstate of the Hamiltonian but not the electric and magnetic field operators. In the vacuum state, therefore, the electric and magnetic fields do not have definite values. We can imagine them to be fluctuating about their mean value of zero.[citation needed]
In a process in which a photon is annihilated (absorbed), we can think of the photon as making a transition into the vacuum state. Similarly, when a photon is created (emitted), it is occasionally useful to imagine that the photon has made a transition out of the vacuum state.[54] An atom, for instance, can be considered to be "dressed" by emission and reabsorption of "virtual photons" from the vacuum. The vacuum state energy described byΣkλħωk/2 is infinite. We can make the replacement:the zero-point energy density is:or in other words the spectral energy density of the vacuum field:
The zero-point energy density in the frequency range fromω1 toω2 is therefore:
This can be large even in relatively narrow "low frequency" regions of the spectrum. In the optical region from 400 to 700 nm, for instance, the above equation yields around 220erg/cm3.
We showed in the above section that the zero-point energy can be eliminated from the Hamiltonian by the normal ordering prescription. However, this elimination does not mean that the vacuum field has been rendered unimportant or without physical consequences. To illustrate this point we consider a linear dipole oscillator in the vacuum. The Hamiltonian for the oscillator plus the field with which it interacts is:
This has the same form as the corresponding classical Hamiltonian and the Heisenberg equations of motion for the oscillator and the field are formally the same as their classical counterparts. For instance the Heisenberg equations for the coordinatex and the canonical momentump =mẋ +eA/c of the oscillator are:or:since the rate of change of the vector potential in the frame of the moving charge is given by the convective derivative
For nonrelativistic motion we may neglect the magnetic force and replace the expression formẍ by:
Above we have made the electric dipole approximation in which the spatial dependence of the field is neglected. The Heisenberg equation forakλ is found similarly from the Hamiltonian to be:in the electric dipole approximation.
In deriving these equations forx,p, andakλ we have used the fact that equal-time particle and field operators commute. This follows from the assumption that particle and field operators commute at some time (say,t = 0) when the matter-field interpretation is presumed to begin, together with the fact that a Heisenberg-picture operatorA(t) evolves in time asA(t) =U†(t)A(0)U(t), whereU(t) is the time evolution operator satisfying
Alternatively, we can argue that these operators must commute if we are to obtain the correct equations of motion from the Hamiltonian, just as the corresponding Poisson brackets in classical theory must vanish in order to generate the correct Hamilton equations. The formal solution of the field equation is:and therefore the equation forȧkλ may be written:whereand
It can be shown that in theradiation reaction field, if the massm is regarded as the "observed" mass then we can take
The total field acting on the dipole has two parts,E0(t) andERR(t).E0(t) is the free or zero-point field acting on the dipole. It is the homogeneous solution of the Maxwell equation for the field acting on the dipole, i.e., the solution, at the position of the dipole, of the wave equationsatisfied by the field in the (source free) vacuum. For this reasonE0(t) is often referred to as the "vacuum field", although it is of course a Heisenberg-picture operator acting on whatever state of the field happens to be appropriate att = 0.ERR(t) is the source field, the field generated by the dipole and acting on the dipole.
Using the above equation forERR(t) we obtain an equation for the Heisenberg-picture operator that is formally the same as the classical equation for a linear dipole oscillator:whereτ =2e2/3mc3. in this instance we have considered a dipole in the vacuum, without any "external" field acting on it. the role of the external field in the above equation is played by the vacuum electric field acting on the dipole.
Classically, a dipole in the vacuum is not acted upon by any "external" field: if there are no sources other than the dipole itself, then the only field acting on the dipole is its own radiation reaction field. In quantum theory however there is always an "external" field, namely the source-free or vacuum fieldE0(t).
According to our earlier equation forakλ(t) the free field is the only field in existence att = 0 as the time at which the interaction between the dipole and the field is "switched on". The state vector of the dipole-field system att = 0 is therefore of the formwhere|vac⟩ is the vacuum state of the field and|ψD⟩ is the initial state of the dipole oscillator. The expectation value of the free field is therefore at all times equal to zero:sinceakλ(0)|vac⟩ = 0. however, the energy density associated with the free field is infinite:
The important point of this is that the zero-point field energyHF does not affect the Heisenberg equation forakλ since it is a c-number or constant (i.e. an ordinary number rather than an operator) and commutes withakλ. We can therefore drop the zero-point field energy from the Hamiltonian, as is usually done. But the zero-point field re-emerges as the homogeneous solution for the field equation. A charged particle in the vacuum will therefore always see a zero-point field of infinite density. This is the origin of one of the infinities of quantum electrodynamics, and it cannot be eliminated by the trivial expedient dropping of the termΣkλħωk/2 in the field Hamiltonian.
The free field is in fact necessary for the formal consistency of the theory. In particular, it is necessary for the preservation of the commutation relations, which is required by the unitary of time evolution in quantum theory:
We can calculate[z(t),pz(t)] from the formal solution of the operator equation of motion
Using the fact thatand that equal-time particle and field operators commute, we obtain:
For the dipole oscillator under consideration it can be assumed that the radiative damping rate is small compared with the natural oscillation frequency, i.e.,τω0 ≪ 1. Then the integrand above is sharply peaked atω =ω0 and:the necessity of the vacuum field can also be appreciated by making the small damping approximation inand
Without the free fieldE0(t) in this equation the operatorx(t) would be exponentially dampened, and commutators like[z(t),pz(t)] would approach zero fort ≫1/τω2 0. With the vacuum field included, however, the commutator isiħ at all times, as required by unitarity, and as we have just shown. A similar result is easily worked out for the case of a free particle instead of a dipole oscillator.[97]
What we have here is an example of a "fluctuation-dissipation elation". Generally speaking if a system is coupled to a bath that can take energy from the system in an effectively irreversible way, then the bath must also cause fluctuations. The fluctuations and the dissipation go hand in hand we cannot have one without the other. In the current example the coupling of a dipole oscillator to the electromagnetic field has a dissipative component, in the form of the zero-point (vacuum) field; given the existence of radiation reaction, the vacuum field must also exist in order to preserve the canonical commutation rule and all it entails.
The spectral density of the vacuum field is fixed by the form of the radiation reaction field, or vice versa: because the radiation reaction field varies with the third derivative ofx, the spectral energy density of the vacuum field must be proportional to the third power ofω in order for[z(t),pz(t)] to hold. In the case of a dissipative force proportional toẋ, by contrast, the fluctuation force must be proportional to in order to maintain the canonical commutation relation.[97] This relation between the form of the dissipation and the spectral density of the fluctuation is the essence of the fluctuation-dissipation theorem.[76]
The fact that the canonical commutation relation for a harmonic oscillator coupled to the vacuum field is preserved implies that the zero-point energy of the oscillator is preserved. it is easy to show that after a few damping times the zero-point motion of the oscillator is in fact sustained by the driving zero-point field.[98]
The QCD vacuum is the vacuum state of quantum chromodynamics (QCD). It is an example of anon-perturbative vacuum state, characterized by a non-vanishingcondensates such as thegluon condensate and thequark condensate in the complete theory which includes quarks. The presence of these condensates characterizes the confined phase ofquark matter. In technical terms, gluons arevectorgauge bosons that mediatestrong interactions of quarks in quantum chromodynamics (QCD). Gluons themselves carry the color charge of the strong interaction. This is unlike the photon, which mediates theelectromagnetic interaction but lacks an electric charge. Gluons therefore participate in the strong interaction in addition to mediating it, making QCD significantly harder to analyze than QED (quantum electrodynamics) as it deals withnonlinear equations to characterize such interactions.
The potential for the Higgs field, plotted as function ofϕ0 andϕ3. It has aMexican-hat orchampagne-bottle profile at the ground.
The Standard Model hypothesises a field called the Higgs field (symbol:ϕ), which has the unusual property of a non-zero amplitude in its ground state (zero-point) energy after renormalization; i.e., a non-zero vacuum expectation value. It can have this effect because of its unusual "Mexican hat" shaped potential whose lowest "point" is not at its "centre". Below a certain extremely high energy level the existence of this non-zero vacuum expectationspontaneously breakselectroweakgauge symmetry which in turn gives rise to the Higgs mechanism and triggers the acquisition of mass by those particles interacting with the field. The Higgs mechanism occurs whenever a charged field has a vacuum expectation value. This effect occurs because scalar field components of the Higgs field are "absorbed" by the massive bosons as degrees of freedom, and couple to the fermions via Yukawa coupling, thereby producing the expected mass terms. The expectation value ofϕ0 in the ground state (the vacuum expectation value or VEV) is then⟨ϕ0⟩ =v/√2, wherev =|μ|/√λ. The measured value of this parameter is approximately246 GeV/c2.[99] It has units of mass, and is the only free parameter of the Standard Model that is not a dimensionless number.
The Higgs mechanism is a type ofsuperconductivity which occurs in the vacuum. It occurs when all of space is filled with a sea of particles which are charged and thus the field has a nonzero vacuum expectation value. Interaction with the vacuum energy filling the space prevents certain forces from propagating over long distances (as it does in a superconducting medium; e.g., in theGinzburg–Landau theory).
Zero-point energy has many observed physical consequences.[11] It is important to note that zero-point energy is not merely an artifact of mathematical formalism that can, for instance, be dropped from a Hamiltonian by redefining the zero of energy, or by arguing that it is a constant and therefore has no effect on Heisenberg equations of motion without latter consequence.[100] Indeed, such treatment could create a problem at a deeper, as of yet undiscovered, theory.[101] For instance, in general relativity the zero of energy (i.e. the energy density of the vacuum) contributes to a cosmological constant of the type introduced by Einstein in order to obtain static solutions to his field equations.[102] The zero-point energy density of the vacuum, due to all quantum fields, is extremely large, even when we cut off the largest allowable frequencies based on plausible physical arguments. It implies a cosmological constant larger than the limits imposed by observation by about 120 orders of magnitude. This "cosmological constant problem" remains one of the greatest unsolved mysteries of physics.[103]
A phenomenon that is commonly presented as evidence for the existence of zero-point energy in vacuum is the Casimir effect, proposed in 1948 byDutchphysicistHendrik Casimir, who considered the quantized electromagnetic field between a pair of grounded, neutral metal plates. The vacuum energy contains contributions from all wavelengths, except those excluded by the spacing between plates. As the plates draw together, more wavelengths are excluded and the vacuum energy decreases. The decrease in energy means there must be a force doing work on the plates as they move.
Early experimental tests from the 1950s onwards gave positive results showing the force was real, but other external factors could not be ruled out as the primary cause, with the range of experimental error sometimes being nearly 100%.[104][105][106][107][108] That changed in 1997 with Lamoreaux[109] conclusively showing that the Casimir force was real. Results have been repeatedly replicated since then.[110][111][112][113]
In 2009, Munday et al.[114] published experimental proof that (as predicted in 1961[115]) the Casimir force could also be repulsive as well as being attractive. Repulsive Casimir forces could allow quantum levitation of objects in a fluid and lead to a new class of switchable nanoscale devices with ultra-low static friction.[116]
An interesting hypothetical side effect of the Casimir effect is theScharnhorst effect, a hypothetical phenomenon in which light signals travel slightlyfaster thanc between two closely spaced conducting plates.[117]
The quantum fluctuations of the electromagnetic field have important physical consequences. In addition to the Casimir effect, they also lead to a splitting between the twoenergy levels2S1/2 and2P1/2 (interm symbol notation) of thehydrogen atom which was not predicted by theDirac equation, according to which these states should have the same energy. Charged particles can interact with the fluctuations of the quantized vacuum field, leading to slight shifts in energy;[118] this effect is called the Lamb shift.[119] The shift of about4.38×10−6 eV is roughly10−7 of the difference between the energies of the 1s and 2s levels, and amounts to 1,058 MHz in frequency units. A small part of this shift (27 MHz ≈ 3%) arises not from fluctuations of the electromagnetic field, but from fluctuations of the electron–positron field. The creation of (virtual) electron–positron pairs has the effect of screening the Coulomb field and acts as a vacuum dielectric constant. This effect is much more important in muonic atoms.[120]
The fine-structure constant is the coupling constant of quantum electrodynamics (QED) determining the strength of the interaction between electrons and photons. It turns out that the fine-structure constant is not really a constant at all owing to the zero-point energy fluctuations of the electron-positron field.[121] The quantum fluctuations caused by zero-point energy have the effect of screening electric charges: owing to (virtual) electron-positron pair production, the charge of the particle measured far from the particle is far smaller than the charge measured when close to it.
The Heisenberg inequality whereħ =h/2π, andΔx,Δp are the standard deviations of position and momentum states that:
It means that a short distance implies large momentum and therefore high energy i.e. particles of high energy must be used to explore short distances. QED concludes that the fine-structure constant is an increasing function of energy. It has been shown that at energies of the order of theZ0 boson rest energy,mzc2 ≈ 90 GeV, that:rather than the low-energyα ≈1/137.[122][123] The renormalization procedure of eliminating zero-point energy infinities allows the choice of an arbitrary energy (or distance) scale for definingα. All in all,α depends on the energy scale characteristic of the process under study, and also on details of the renormalization procedure. The energy dependence ofα has been observed for several years now in precision experiment in high-energy physics.
Light coming from the surface of a strongly magneticneutron star (left) becomes linearly polarised as it travels through the vacuum.
In the presence of strong electrostatic fields it is predicted that virtual particles become separated from the vacuum state and form real matter.[citation needed] The fact that electromagnetic radiation can be transformed into matter and vice versa leads to fundamentally new features in quantum electrodynamics. One of the most important consequences is that, even in the vacuum, the Maxwell equations have to be exchanged by more complicated formulas. In general, it will be not possible to separate processes in the vacuum from the processes involving matter since electromagnetic fields can create matter if the field fluctuations are strong enough. This leads to highly complex nonlinear interaction – gravity will have an effect on the light at the same time the light has an effect on gravity. These effects were first predicted by Werner Heisenberg andHans Heinrich Euler in 1936[124] and independently the same year by Victor Weisskopf who stated: "The physical properties of the vacuum originate in the "zero-point energy" of matter, which also depends on absent particles through the external field strengths and therefore contributes an additional term to the purely Maxwellian field energy".[125][126] Thus strong magnetic fields vary the energy contained in the vacuum. The scale above which the electromagnetic field is expected to become nonlinear is known as theSchwinger limit. At this point the vacuum has all the properties of abirefringent medium, thus in principle a rotation of the polarization frame (theFaraday effect) can be observed in empty space.[127][128]
Both Einstein's theory of special and general relativity state that light should pass freely through a vacuum without being altered, a principle known asLorentz invariance. Yet, in theory, large nonlinear self-interaction of light due to quantum fluctuations should lead to this principle being measurably violated if the interactions are strong enough. Nearly all theories ofquantum gravity predict that Lorentz invariance is not an exact symmetry of nature. It is predicted the speed at which light travels through the vacuum depends on its direction, polarization and the local strength of the magnetic field.[129] There have been a number of inconclusive results which claim to show evidence of aLorentz violation by finding a rotation of the polarization plane of light coming from distant galaxies.[130] The first concrete evidence for vacuum birefringence was published in 2017 when a team ofastronomers looked at the light coming from the starRX J1856.5-3754,[131] the closest discoveredneutron star toEarth.[132]
Roberto Mignani at theNational Institute for Astrophysics inMilan who led the team ofastronomers has commented that "When Einstein came up with the theory of general relativity 100 years ago, he had no idea that it would be used for navigational systems. The consequences of this discovery probably will also have to be realised on a longer timescale."[133] The team found that visible light from the star had undergone linear polarisation[clarification needed] of around 16%. If the birefringence had been caused by light passing throughinterstellar gas or plasma, the effect should have been no more than 1%. Definitive proof would require repeating the observation at other wavelengths and on other neutron stars. AtX-ray wavelengths the polarization from the quantum fluctuations should be near 100%.[134] Although notelescope currently exists that can make such measurements, there are several proposed X-ray telescopes that may soon be able to verify the result conclusively such as China'sHard X-ray Modulation Telescope (HXMT) and NASA's Imaging X-ray Polarimetry Explorer (IXPE).
In the late 1990s it was discovered that very distantsupernovae were dimmer than expected suggesting that the universe's expansion was accelerating rather than slowing down.[136][137] This revived discussion that Einstein's cosmological constant, long disregarded by physicists as being equal to zero, was in fact some small positive value. This would indicate empty space exerted some form ofnegative pressure or energy.
There is no natural candidate for what might cause what has been called dark energy but the current best guess is that it is the zero-point energy of the vacuum, but this guess is known to be off by 120orders of magnitude.[138]
TheEuropean Space Agency'sEuclid telescope, launched on 1 July 2023, will map galaxies up to 10 billion light years away.[139] By seeing how dark energy influences their arrangement and shape, the mission will allow scientists to see if the strength of dark energy has changed. If dark energy is found to vary throughout time it would indicate it is due toquintessence, where observed acceleration is due to the energy of ascalar field, rather than the cosmological constant. No evidence of quintessence is yet available, but it has not been ruled out either. It generally predicts a slightly slower acceleration of the expansion of the universe than the cosmological constant. Some scientists think that the best evidence for quintessence would come from violations of Einstein'sequivalence principle andvariation of the fundamental constants in space or time.[140] Scalar fields are predicted by theStandard Model of particle physics andstring theory, but an analogous problem to the cosmological constant problem (or the problem of constructing models ofcosmological inflation) occurs:renormalization theory predicts that scalar fields should acquire large masses again due to zero-point energy.
The mechanism for inflation is unclear, it is similar in effect to dark energy but is a far more energetic and short lived process. As with dark energy the best explanation is some form of vacuum energy arising from quantum fluctuations. It may be that inflation causedbaryogenesis, the hypothetical physical processes that produced anasymmetry (imbalance) betweenbaryons and antibaryons produced in thevery early universe, but this is far from certain.
Paul S. Wesson examined the cosmological implications of assuming that zero-point energy is real.[142] Among numerous difficulties,general relativity requires that such energy not gravitate, so it cannot be similar to electromagnetic radiation.
There has been a long debate[143] over the question of whether zero-point fluctuations of quantized vacuum fields are "real" i.e. do they have physical effects that cannot be interpreted by an equally valid alternative theory?Schwinger, in particular, attempted to formulate QED without reference to zero-point fluctuations via his "source theory".[144] From such an approach it is possible to derive the Casimir Effect without reference to a fluctuating field. Such a derivation was first given by Schwinger (1975)[145] for a scalar field, and then generalized to the electromagnetic case by Schwinger, DeRaad, and Milton (1978).[146] in which they state "the vacuum is regarded as truly a state with all physical properties equal to zero".Jaffe (2005)[147] has highlighted a similar approach in deriving the Casimir effect stating "the concept of zero-point fluctuations is a heuristic and calculational aid in the description of the Casimir effect, but not a necessity in QED."
Milonni has shown the necessity of the vacuum field for the formal consistency of QED.[148] Modern physics does not know any better way to construct gauge-invariant, renormalizable theories than with zero-point energy and they would seem to be a necessity for any attempt at aunified theory.[149]Nevertheless, as pointed out by Jaffe, "noknown phenomenon, including the Casimir effect, demonstrates that zero point energies are "real""[147]
The mathematical models used inclassical electromagnetism, quantum electrodynamics (QED) and theStandard Model all view theelectromagnetic vacuum as a linear system with no overall observable consequence. For example, in the case of the Casimir effect, Lamb shift, and so on these phenomena can be explained by alternative mechanisms other than action of the vacuum by arbitrary changes to the normal ordering of field operators. See thealternative theories section. This is a consequence of viewing electromagnetism as a U(1) gauge theory, which topologically does not allow the complex interaction of a field with and on itself.[150] In higher symmetry groups and in reality, the vacuum is not a calm, randomly fluctuating, largely immaterial and passive substance, but at times can be viewed as a turbulent virtualplasma that can have complex vortices (i.e.solitons vis-à-vis particles),entangled states and a rich nonlinear structure.[151] There are many observed nonlinear physical electromagnetic phenomena such asAharonov–Bohm (AB)[152][153] and Altshuler–Aronov–Spivak (AAS) effects,[154]Berry,[155] Aharonov–Anandan,[156] Pancharatnam[157] and Chiao–Wu[158] phase rotation effects,Josephson effect,[159][160]Quantum Hall effect,[161] theDe Haas–Van Alphen effect,[162] theSagnac effect and many other physically observable phenomena which would indicate that the electromagnetic potential field has real physical meaning rather than being a mathematical artifact[163] and therefore an all encompassing theory would not confine electromagnetism as a local force as is currently done, but as a SU(2) gauge theory or higher geometry. Higher symmetries allow for nonlinear, aperiodic behaviour which manifest as a variety of complex non-equilibrium phenomena that do not arise in the linearised U(1) theory, such as multiple stable states, symmetry breaking, chaos andemergence.[164]
What are called Maxwell's equations today, are in fact a simplified version of the original equations reformulated byHeaviside,FitzGerald,Lodge andHertz. The original equations usedHamilton's more expressivequaternion notation,[165] a kind ofClifford algebra, which fully subsumes the standard Maxwell vectorial equations largely used today.[166] In the late 1880s there was a debate over the relative merits of vector analysis and quaternions. According to Heaviside the electromagnetic potential field was purely metaphysical, an arbitrary mathematical fiction, that needed to be "murdered".[167] It was concluded that there was no need for the greater physical insights provided by the quaternions if the theory was purely local in nature. Local vector analysis has become the dominant way of using Maxwell's equations ever since. However, this strictly vectorial approach has led to a restrictive topological understanding in some areas of electromagnetism, for example, a full understanding of the energy transfer dynamics inTesla's oscillator-shuttle-circuit can only be achieved in quaternionic algebra or higher SU(2) symmetries.[168] It has often been argued that quaternions are not compatible with special relativity,[169] but multiple papers have shown ways of incorporating relativity.[170][171][172][173]
A good example of nonlinear electromagnetics is in high energy dense plasmas, wherevortical phenomena occur which seemingly violate thesecond law of thermodynamics by increasing the energy gradient within the electromagnetic field and violateMaxwell's laws by creating ion currents which capture and concentrate their own and surrounding magnetic fields. In particularLorentz force law, which elaborates Maxwell's equations is violated by these force free vortices.[174][175][176] These apparent violations are due to the fact that the traditional conservation laws in classical and quantum electrodynamics (QED) only display linear U(1) symmetry (in particular, by the extendedNoether theorem,[177]conservation laws such as thelaws of thermodynamics need not always apply todissipative systems,[178][179] which are expressed in gauges of higher symmetry). The second law of thermodynamics states that in a closed linear system entropy flow can only be positive (or exactly zero at the end of a cycle). However, negative entropy (i.e. increased order, structure or self-organisation) can spontaneously appear in an open nonlinear thermodynamic system that is far from equilibrium, so long as this emergent order accelerates the overall flow of entropy in the total system. The 1977Nobel Prize in Chemistry was awarded to thermodynamicistIlya Prigogine[180] for his theory of dissipative systems that described this notion. Prigogine described the principle as "order through fluctuations"[181] or "order out of chaos".[182] It has been argued by some that all emergent order in the universe from galaxies, solar systems, planets, weather, complex chemistry, evolutionary biology to even consciousness, technology and civilizations are themselves examples of thermodynamic dissipative systems; nature having naturally selected these structures to accelerate entropy flow within the universe to an ever-increasing degree.[183] For example, it has been estimated that human body is 10,000 times more effective at dissipating energy per unit of mass than the sun.[184]
One may query what this has to do with zero-point energy. Given the complex and adaptive behaviour that arises from nonlinear systems considerable attention in recent years has gone into studying a new class ofphase transitions which occur at absolute zero temperature. These are quantum phase transitions which are driven by EM field fluctuations as a consequence of zero-point energy.[185] A good example of a spontaneous phase transition that are attributed to zero-point fluctuations can be found insuperconductors. Superconductivity is one of the best known empirically quantified macroscopic electromagnetic phenomena whose basis is recognised to be quantum mechanical in origin. The behaviour of the electric and magnetic fields under superconductivity is governed by theLondon equations. However, it has been questioned in a series of journal articles whether the quantum mechanically canonised London equations can be given a purely classical derivation.[186] Bostick,[187][188] for instance, has claimed to show that the London equations do indeed have a classical origin that applies to superconductors and to some collisionless plasmas as well. In particular it has been asserted that theBeltrami vortices in the plasma focus display the same pairedflux-tube morphology asType II superconductors.[189][190] Others have also pointed out this connection, Fröhlich[191] has shown that the hydrodynamic equations of compressible fluids, together with the London equations, lead to a macroscopic parameter ( = electric charge density / mass density), without involving eitherquantum phase factors or the Planck constant. In essence, it has been asserted that Beltrami plasma vortex structures are able to at least simulate the morphology ofType I andType II superconductors. This occurs because the "organised" dissipative energy of the vortex configuration comprising the ions and electrons far exceeds the "disorganised" dissipative random thermal energy. The transition from disorganised fluctuations to organised helical structures is a phase transition involving a change in the condensate's energy (i.e. the ground state or zero-point energy) butwithout any associated rise in temperature.[192] This is an example of zero-point energy having multiple stable states (seeQuantum phase transition,Quantum critical point,Topological degeneracy,Topological order[193]) and where the overall system structure is independent of a reductionist or deterministic view, that "classical" macroscopic order can also causally affect quantum phenomena. Furthermore, the pair production of Beltrami vortices has been compared to the morphology of pair production of virtual particles in the vacuum.
Physicists overwhelmingly reject any possibility that the zero-point energy field can be exploited to obtain useful energy (work) or uncompensated momentum; such efforts are seen as tantamount toperpetual motion machines.[citation needed]
Nevertheless, the allure of free energy has motivated such research, usually falling in the category offringe science. As long ago as 1889 (before quantum theory or discovery of the zero point energy)Nikola Tesla proposed that useful energy could be obtained from free space, or what was assumed at that time to be an all-pervasiveaether.[194] Others have since claimed to exploit zero-point or vacuum energy with a large amount ofpseudoscientific literature causing ridicule around the subject.[195][196] Despite rejection by the scientific community, harnessing zero-point energy remains an interest of research, particularly in the US where it has attracted the attention of major aerospace/defence contractors and theU.S. Department of Defense as well as in China, Germany, Russia and Brazil.[195][197]
A common assumption is that theCasimir force is of little practical use; the argument is made that the only way to actually gain energy from the two plates is to allow them to come together (getting them apart again would then require more energy), and therefore it is a one-use-only tiny force in nature.[195] In 1984Robert Forward published work showing how a "vacuum-fluctuation battery" could be constructed; the battery can be recharged by making the electrical forces slightly stronger than the Casimir force to reexpand the plates.[198]
In 1999, Pinto, a former scientist atNASA'sJet Propulsion Laboratory at Caltech in Pasadena, published inPhysical Review histhought experiment (Gedankenexperiment) for a "Casimir engine". The paper showed that continuous positive net exchange of energy from the Casimir effect was possible, even stating in the abstract "In the event of no other alternative explanations, one should conclude that major technological advances in the area of endless, by-product free-energy production could be achieved."[199]
Garret Moddel atUniversity of Colorado has highlighted that he believes such devices hinge on the assumption that the Casimir force is anonconservative force, he argues that there is sufficient evidence (e.g. analysis by Scandurra (2001)[200]) to say that the Casimir effect is a conservative force and therefore even though such an engine can exploit the Casimir force for useful work it cannot produce more output energy than has been input into the system.[201]
In 2008,DARPA solicited research proposals in the area of Casimir Effect Enhancement (CEE). The goal of the program is to develop new methods to control and manipulate attractive and repulsive forces at surfaces based on engineering of the Casimir force.[202]
A 2008 patent by Haisch and Moddel[203] details a device that is able to extract power from zero-point fluctuations using a gas that circulates through a Casimir cavity. A published test of this concept by Moddel[204] was performed in 2012 and seemed to give excess energy that could not be attributed to another source. However it has not been conclusively shown to be from zero-point energy and the theory requires further investigation.[205]
In 1951Callen and Welton[76] proved the quantumfluctuation-dissipation theorem (FDT) which was originally formulated in classical form byNyquist (1928)[77] as an explanation for observedJohnson noise[78] in electric circuits. Fluctuation-dissipation theorem showed that when something dissipates energy, in an effectively irreversible way, a connected heat bath must also fluctuate. The fluctuations and the dissipation go hand in hand; it is impossible to have one without the other. The implication of FDT being that the vacuum could be treated as a heat bath coupled to a dissipative force and as such energy could, in part, be extracted from the vacuum for potentially useful work.[79] Such a theory has met with resistance: Macdonald (1962)[206] and Harris (1971)[207] claimed that extracting power from the zero-point energy to be impossible, so FDT could not be true. Grau and Kleen (1982)[208] and Kleen (1986),[209] argued that the Johnson noise of a resistor connected to an antenna must satisfy Planck's thermal radiation formula, thus the noise must be zero at zero temperature and FDT must be invalid. Kiss (1988)[210] pointed out that the existence of the zero-point term may indicate that there is a renormalization problem—i.e., a mathematical artifact—producing an unphysical term that is not actually present in measurements (in analogy with renormalization problems of ground states in quantum electrodynamics). Later, Abbott et al. (1996) arrived at a different but unclear conclusion that "zero-point energy is infinite thus it should be renormalized but not the 'zero-point fluctuations'".[211] Despite such criticism, FDT has been shown to be true experimentally under certain quantum, non-classical conditions. Zero-point fluctuations can, and do, contribute towards systems which dissipate energy.[80] A paper by Armen Allahverdyan and Theo Nieuwenhuizen in 2000 showed the feasibility of extracting zero-point energy for useful work from a single bath, without contradicting thelaws of thermodynamics, by exploiting certain quantum mechanical properties.[81]
There have been a growing number of papers showing that in some instances the classical laws of thermodynamics, such as limits on the Carnot efficiency, can be violated by exploiting negative entropy of quantum fluctuations.[82][212][213][214][215][216][217][218][219][220]
Despite efforts to reconcile quantum mechanics and thermodynamics over the years, their compatibility is still an open fundamental problem. The full extent that quantum properties can alter classical thermodynamic bounds is unknown[221]
The use of zero-point energy for space travel is speculative and does not form part of the mainstream scientific consensus. A completequantum theory of gravitation (that would deal with the role of quantum phenomena like zero-point energy) does not yet exist. Speculative papers explaining a relationship between zero-point energy and gravitational shielding effects have been proposed,[16][222][223][224] but the interaction (if any) is not yet fully understood. According to thegeneral theory of relativity, rotating matter can generate a new force of nature, known as the gravitomagnetic interaction, whose intensity is proportional to the rate of spin.[225] In certain conditions the gravitomagnetic field can be repulsive. In neutron stars for example, it can produce a gravitational analogue of theMeissner effect, but the force produced in such an example is theorized to be exceedingly weak.[226]
In 1963Robert Forward, a physicist and aerospace engineer atHughes Research Laboratories, published a paper showing how within the framework of general relativity "anti-gravitational" effects might be achieved.[227] Since all atoms havespin, gravitational permeability may be able to differ from material to material. A strongtoroidal gravitational field that acts against the force of gravity could be generated by materials that havenonlinear properties that enhance time-varying gravitational fields. Such an effect would be analogous to the nonlinear electromagnetic permeability of iron, making it an effective core (i.e. the doughnut of iron) in a transformer, whose properties are dependent on magnetic permeability.[228][229][230] In 1966Dewitt[231] was first to identify the significance of gravitational effects in superconductors. Dewitt demonstrated that a magnetic-type gravitational field must result in the presence offluxoid quantization. In 1983, Dewitt's work was substantially expanded by Ross.[232]
From 1971 to 1974 Henry William Wallace, a scientist atGE Aerospace was issued with three patents.[233][234][235] Wallace usedDewitt's theory to develop an experimental apparatus for generating and detecting a secondary gravitational field, which he named the kinemassic field (now better known as the gravitomagnetic field). In his three patents, Wallace describes three different methods used for detection of the gravitomagnetic field – change in the motion of a body on a pivot, detection of a transverse voltage in a semiconductor crystal, and a change in the specific heat of a crystal material having spin-aligned nuclei. There are no publicly available independent tests verifying Wallace's devices. Such an effect if any would be small.[236][237][238][239][240][241] Referring to Wallace's patents, aNew Scientist article in 1980 stated "Although the Wallace patents were initially ignored as cranky, observers believe that his invention is now under serious but secret investigation by the military authorities in the USA. The military may now regret that the patents have already been granted and so are available for anyone to read."[242] A further reference to Wallace's patents occur in an electric propulsion study prepared for theAstronautics Laboratory atEdwards Air Force Base which states: "The patents are written in a very believable style which include part numbers, sources for some components, and diagrams of data. Attempts were made to contact Wallace using patent addresses and other sources but he was not located nor is there a trace of what became of his work. The concept can be somewhat justified on general relativistic grounds since rotating frames of time varying fields are expected to emit gravitational waves."[243]
In 1986 theU.S. Air Force's then Rocket Propulsion Laboratory (RPL) atEdwards Air Force Base solicited "Non Conventional Propulsion Concepts" under a small business research and innovation program. One of the six areas of interest was "Esoteric energy sources for propulsion, including the quantum dynamic energy of vacuum space..." In the same yearBAE Systems launched "Project Greenglow" to provide a "focus for research into novel propulsion systems and the means to power them".[197][244]
In 1988Kip Thorne et al.[245] published work showing how traversablewormholes can exist in spacetime only if they are threaded by quantum fields generated by some form ofexotic matter that hasnegative energy. In 1993 Scharnhorst and Barton[117] showed thatthe speed of a photon will be increased if it travels between two Casimir plates, an example of negative energy. In the most general sense, the exotic matter needed to create wormholes would share the repulsive properties of theinflationary energy, dark energy or zero-point radiation of the vacuum.[246]
In 1992Evgeny Podkletnov[247] published a heavily debated[248][249][250][251] journal article claiming a specific type of rotating superconductor could shield gravitational force. Independently of this, from 1991 to 1993Ning Li and Douglas Torr published a number of articles[252][253][254] about gravitational effects in superconductors. One finding they derived is the source ofgravitomagnetic flux in atype II superconductor material is due tospin alignment of the lattice ions. Quoting from their third paper: "It is shown that the coherent alignment of lattice ion spins will generate a detectable gravitomagnetic field, and in the presence of a time-dependent applied magnetic vector potential field, a detectable gravitoelectric field." The claimed size of the generated force has been disputed by some[255][256] but defended by others.[257][258] In 1997 Li published a paper attempting to replicate Podkletnov's results and showed the effect was very small, if it existed at all.[259] Li is reported to have left the University of Alabama in 1999 to found the companyAC Gravity LLC.[260] AC Gravity was awarded aU.S. Department of Defense grant for $448,970 in 2001 to continue anti-gravity research. The grant period ended in 2002 but no results from this research were made public.[261]
In 2002Phantom Works,Boeing's advanced research and development facility inSeattle, approachedEvgeny Podkletnov directly. Phantom Works was blocked by Russian technology transfer controls. At this time Lieutenant General George Muellner, the outgoing head of the Boeing Phantom Works, confirmed that attempts by Boeing to work with Podkletnov had been blocked by Russian government, also commenting that "The physical principles – and Podkletnov's device is not the only one – appear to be valid... There is basic science there. They're not breaking the laws of physics. The issue is whether the science can be engineered into something workable".[262]
Froning and Roach (2002)[263] put forward a paper that builds on the work of Puthoff, Haisch and Alcubierre. They used fluid dynamic simulations to model the interaction of a vehicle (like that proposed by Alcubierre) with the zero-point field. Vacuum field perturbations are simulated by fluid field perturbations and the aerodynamic resistance of viscous drag exerted on the interior of the vehicle is compared to the Lorentz force exerted by the zero-point field (a Casimir-like force is exerted on the exterior by unbalanced zero-point radiation pressures). They find that the optimized negative energy required for an Alcubierre drive is where it is a saucer-shaped vehicle withtoroidal electromagnetic fields. The EM fields distort the vacuum field perturbations surrounding the craft sufficiently to affect the permeability and permittivity of space.
In 2009, Giorgio Fontana and Bernd Binder presented a new method to potentially extract the Zero-point energy of the electromagnetic field and nuclear forces in the form ofgravitational waves.[264] In the spheron model of the nucleus,[265] proposed by the two times Nobel laureateLinus Pauling,dineutrons are among the components of this structure. Similarly to adumbbell put in asuitable rotational state, but with nuclear mass density, dineutrons are nearly ideal sources of gravitational waves at X-ray and gamma-ray frequencies. The dynamical interplay, mediated by nuclear forces, between the electrically neutral dineutrons and the electrically charged core nucleus is the fundamental mechanism by which nuclear vibrations can be converted to a rotational state of dineutrons with emission of gravitational waves. Gravity and gravitational waves are well described by General Relativity, that is not a quantum theory, this implies that there is no Zero-point energy for gravity in this theory, therefore dineutrons will emit gravitational waves like any other known source of gravitational waves. In Fontana and Binder paper, nuclear species with dynamical instabilities, related to the Zero-point energy of the electromagnetic field and nuclear forces, and possessing dineutrons, will emit gravitational waves. In experimental physics this approach is still unexplored.
In 2014NASA'sEagleworks Laboratories announced that they had successfully validated the use of aQuantum Vacuum Plasma Thruster which makes use of the Casimir effect for propulsion.[266][267][268] In 2016 a scientific paper by the team of NASA scientists passed peer review for the first time.[269] The paper suggests that the zero-point field acts aspilot-wave and that the thrust may be due to particles pushing off the quantum vacuum. While peer review doesn't guarantee that a finding or observation is valid, it does indicate that independent scientists looked over the experimental setup, results, and interpretation and that they could not find any obvious errors in the methodology and that they found the results reasonable. In the paper, the authors identify and discuss nine potential sources of experimental errors, including rogue air currents, leaky electromagnetic radiation, and magnetic interactions. Not all of them could be completely ruled out, and further peer-reviewed experimentation is needed in order to rule out these potential errors.[270]
^Nernst, Walther (1916). "Über einen Versuch, von quantentheoretischen Betrachtungen zur Annahme stetiger Energieänderungen zurückzukehren" [On an attempt to return from quantum-theoretical considerations to the assumption of constant energy changes].Verhandlungen der Deutschen Physikalischen (in German).18:83–116.
^Einstein, Albert (1920).Äther und Relativitäts-Theorie [Aether and relativity theory] (in German). Berlin: Springer.
^Jordan, P.; Pauli, W. (1928). "Zur Quantenelektrodynamik ladungsfreier Felder" [On the quantum electrodynamics of charge-free fields].Zeitschrift für Physik (in German).47 (3):151–173.Bibcode:1928ZPhy...47..151J.doi:10.1007/BF02055793.S2CID120536476.
^Weinberg, Steven (1977). "The Search for Unity: Notes for a History of Quantum Field Theory".Daedalus.106 (4):17–35.JSTOR20024506.
^Yokoyama, H.; Ujihara, K. (1995).Spontaneous emission and laser oscillation in microcavities. Boca Raton: CRC Press. p. 6.ISBN978-0-8493-3786-4.OCLC832589969.
^Weisskopf, Viktor (1935). "Probleme der neueren Quantentheorie des Elektrons" [Problems of the new quantum theory of the electron].Naturwissenschaften (in German).23 (37):631–637.Bibcode:1935NW.....23..631W.doi:10.1007/BF01492012.S2CID6780937.
^Eisenschitz, R. & London, F. (1930). "Über das Verhältnis der Van der Waalsschen Kräfte zu den homöopolaren Bindungskräften" [On the relationship of van der Waals forces to homeopolar binding forces].Zeitschrift für Physik (in German).60 (7–8):491–527.Bibcode:1930ZPhy...60..491E.doi:10.1007/BF01341258.S2CID125644826.
^Lifshitz, E. M. (1954). "The Theory of Molecular Attractive Forces between Solids".Journal of Experimental Theoretical Physics USSR.29:94–110.
^Lifshitz, E. M. (1956). "The theory of molecular Attractive Forces between Solids".Soviet Physics.2 (1):73–83.
^Derjaguin, B. V.; Abrikosova, I. I.; Lifshitz, E. M. (1956). "Direct measurement of molecular attraction between solids separated by a narrow gap".Quarterly Reviews, Chemical Society.10 (3):295–329.doi:10.1039/qr9561000295.
^Jaynes, E. T.; Cummings, F. W. (1963). "Comparison of quantum and semiclassical radiation theories with application to the beam maser".Proceedings of the IEEE.51 (1):89–109.Bibcode:1963IEEEP..51...89J.doi:10.1109/PROC.1963.1664.
^Derjaguin, B. V.; Abrikosova, I. I.; Lifshitz, E. M. (1956). "Direct measurement of molecular attraction between solids separated by a narrow gap".Quarterly Reviews, Chemical Society.10 (3):295–329.doi:10.1039/QR9561000295.
^Hunklinger, S.; Geisselmann, H.; Arnold, W. (1972). "A Dynamic Method for Measuring the Van der Waals Forces between Macroscopic Bodies".Rev. Sci. Instrum.43 (4):584–587.Bibcode:1972RScI...43..584H.doi:10.1063/1.1685696.
^Van Blokland, Peter H. G. M.; Overbeek, J. Theodoor G. (1978). "Van der Waals forces between objects covered with a chromium layer".J. Chem. Soc., Faraday Trans. 1.74:2637–2651.doi:10.1039/F19787402637.
^Aitchison, Ian; Hey, Anthony (2012).Gauge Theories in Particle Physics: A Practical Introduction: Volume 1: From Relativistic Quantum Mechanics to QED (4th ed.). CRC Press. p. 343.ISBN978-1-4665-1299-3.
^Quigg, C (1998). Espriu, D; Pich, A (eds.).Advanced School on Electroweak Theory: Hadron Colliders, the Top Quark, and the Higgs Sector. World Scientific. p. 143.ISBN978-981-4545-14-3.
^Tyson, Neil deGrasse and Donald Goldsmith (2004),Origins: Fourteen Billion Years of Cosmic Evolution, W. W. Norton & Company, pp. 84–85.
^Wesson, Paul S. "Cosmological constraints on the zero-point electromagnetic field." Astrophysical Journal, Part 1 (ISSN 0004-637X), vol. 378, Sept. 10, 1991, p. 466-470. Research supported by NSERC. 378 (1991): 466-470.
^Pancharatnam, S. (1956). "Generalized theory of interference, and its applications".Proceedings of the Indian Academy of Sciences.44 (5):247–262.doi:10.1007/BF03046050.S2CID118184376.
^De Haas, W. J.; Van Alphen, P. M. (1930). "The dependance of the susceptibility of diamagnetic metals upon the field".Proc. Netherlands R. Acad. Sci.33: 1106.
^Josephs, H. J. (1959). "The Heaviside papers found at Paignton in 1957".Proceedings of the IEE, Part C: Monographs.106 (9): 70.doi:10.1049/pi-c.1959.0012.
^Nicolis, G.; Prigogine, I. (1977).Self-organization in Nonequilibrium Systems: From Dissipative Structures to Order Through Fluctuations. Wiley-Blackwell.ISBN978-0-471-02401-9.
^Prigogine, Ilya; Stengers, Isabelle (1984).Order out of Chaos. Flamingo.ISBN978-0-00-654115-8.
^Gleick, James (1987).Chaos: Making a New Science (1998 ed.). Vintage. p. 308.ISBN978-0-7493-8606-1.
^Bostick, W. (1985)."The Morphology of the Electron"(PDF).International Journal of Fusion Energy.3 (1):9–52.Archived(PDF) from the original on 3 April 2016. Retrieved22 May 2020.
^Henriques, Carlos (2014).Study of atomic energy shifts induced by Casimir cavities (Thesis for: MS). Advisors: Fernandes, Luis & Amaro, F.doi:10.13140/RG.2.1.4297.1608.
^Boukobza, E.; Ritsch, H. (2013). "Breaking the Carnot limit without violating the second law: A thermodynamic analysis of off-resonant quantum light generation".Physical Review A.87 (6) 063845.Bibcode:2013PhRvA..87f3845B.doi:10.1103/PhysRevA.87.063845.
^Podkletnov, Evgeny; Modanese, Giovanni (2001). "Impulse Gravity Generator Based on Charged YBa2Cu3O7−y Superconductor with Composite Crystal Structure".arXiv:physics/0108005.
^Cravens, D. L. (1990)."Electric Propulsion Study: Final Report"(PDF).Contract F04611-88-C-0014, Astronautics Laboratory (AFSC), Air Force Space Technology Center, Space Systems Division, Air Force Systems Command, Edwards AFB, CA. Archived fromthe original(PDF) on 12 August 2011. Retrieved26 October 2016.
^Allen, J. E. (2005). "Aeronautics-1903; aerospace-2003; ? ? 2103".Proceedings of the Institution of Mechanical Engineers, Part G: Journal of Aerospace Engineering.219 (3):235–260.doi:10.1243/095441005X30252.S2CID110771631.
^Rounds, Frederic N. (1998). "Anomalous Weight Behavior in YBa2Cu3O7 Compounds at Low Temperature".Proc. NASA Breakthrough Propulsion Phys. Workshop.279: physics/9705043.arXiv:physics/9705043.Bibcode:1997physics...5043R.
^Harris, Edward G. (1999). "Comments on "Gravitoelectric-Electric Coupling via Superconductivity" by Douglas G. Torr and Ning Li".Foundations of Physics Letters.12 (2):201–208.doi:10.1023/A:1021621425670.S2CID115204136.
^Froning, H.; Roach, R. (2002). "Preliminary Simulations of Vehicle Interactions with the Quantum Vacuum by Fluid Dynamic Approximations".AIAA 38th Joint Propulsion Conference & Exhibit. p. 52236.doi:10.2514/6.2002-3925.ISBN978-1-62410-115-1.
Pilkington, M. (17 July 2003)."Zero Point Energy".The Guardian.Archived from the original on 7 February 2017.
Powell, C. S. (1994). "Unbearable Lightness: A New Theory May Explain Why Objects Tend to Stay Put".Scientific American.270 (5):30–31.doi:10.1038/scientificamerican0594-27.
Scott, W. B. (March 2004)."To the Stars"(PDF).Aviation Week & Space Technology. pp. 50–53. Archived fromthe original(PDF) on 26 February 2017. Retrieved25 October 2016.
Abbott, D.; Davis, B. R.; Phillips, N. J.; Eshraghian, K. (1996). "Simple derivation of the thermal noise formula using window-limited Fourier transforms and other conundrums".IEEE Transactions on Education.39 (1):1–13.Bibcode:1996ITEdu..39....1A.CiteSeerX10.1.1.129.5792.doi:10.1109/13.485226.
Goy, P.; Raimond, J. M.; Gross, M.; Haroche, S. (1983). "Observation of Cavity-Enhanced Single-Atom Spontaneous Emission".Physical Review Letters.50 (24):1903–1906.Bibcode:1983PhRvL..50.1903G.doi:10.1103/PhysRevLett.50.1903.
Planck, M. (1900). "Zur Theorie des Gesetzes der Energieverteilung im Normalspektrum".Verhandlungen der Deutschen Physikalischen Gesellschaft.2:237–245.
Planck, M. (1911). "Eine neue Strahlungshypothese".Verhandlungen der Deutschen Physikalischen Gesellschaft.13:138–148.
White, H.; March, P.; Lawrence, J.; Vera, J.; Sylvester, A.; Brady, D.; Bailey, P. (2016). "Measurement of Impulsive Thrust from a Closed Radio-Frequency Cavity in Vacuum".Journal of Propulsion and Power.33 (4):830–841.doi:10.2514/1.B36120.hdl:2060/20170000277.S2CID126303009.
Woods, R. C.; Cooke, S. G.; Helme, J.; Caldwell, C. H. (2001). "Gravity modification by high-temperature superconductors".AIAA 37th Joint Propulsion Conference and Exhibit.doi:10.2514/6.2001-3363.