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Ytterbium(III) sulfide

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Ytterbium(III) sulfide
Names
Other names
Ytterbium sulfide, diytterbium trisulfide, ytterbium sesquisulfide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.031.704Edit this at Wikidata
EC Number
  • 234-888-8
  • InChI=1S/S.Yb
    Key: QHGZBASAVJOMNS-UHFFFAOYSA-N
  • [Yb].[S]
Properties
S3Yb2
Molar mass442.27 g·mol−1
Appearanceyellow crystals
Density6.02 g/cm3
insoluble
Structure
rhombic
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Ytterbium(III) sulfide is a binaryinorganic compound ofytterbium andsulfur with the chemical formulaYb2S3. It is a yellow solid of rhombic symmetry, and cell parameters a = 0.678 nm, b = 0.995 nm, c = 0.361 nm.[1]

Synthesis

[edit]

Ytterbium(III) sulfide can be produced by treating metallic ytterbium with sulfur:

2Sm + 3S → Sm2S3

Once prepared, ytterbium(III) sulfide can be purified bychemical vapor transport usingiodine.[2]

Ytterbium(III) sulfide can also be prepared by treating the sulfate withhydrogen sulfide at elevated temperatures:[3]

Yb2(SO4)3 + 12 H2S → Yb2S3 + 12 H2O + 12 S

References

[edit]
  1. ^El Fadli, Z.; Lemoine, P.; Guittard, M.; Tomas, A. (19 August 2010)."ChemInform Abstract: Structure of the Ytterbium Sulfide Yb2S3".ChemInform.25 (23): no.doi:10.1002/chin.199423005. Retrieved4 April 2023.
  2. ^A. W. Sleight and D. P. Kelly (1973), Aaron Wold and John K. Ruff (ed.),Rare-earth Sesquisulfides, Ln2S3, Inorganic Syntheses, vol. 14, McGraw-Hill Book Company, Inc., pp. 152–155
  3. ^K. Wetzel (1963). "Lanthanum Sulfides". In G. Brauer (ed.).Handbook of Preparative Inorganic Chemistry, 2nd Ed. Vol. 2. NY, NY: Academic Press. p. 1153.
Yb(II)
Yb(III)
Other
Sulfides(S2−)
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