To determine thevibrational spectroscopy of linear molecules, the rotation andvibration of linear molecules are taken into account to predict which vibrational (normal) modes are active in theinfrared spectrum and theRaman spectrum.

The location of amolecule in a 3-dimensional space can be described by the total number of coordinates. Eachatom is assigned a set ofx,y, andz coordinates and can move in all three directions.Degrees of freedom is the total number of variables used to define the motion of a molecule completely. ForN atoms in a molecule moving in 3-D space, there are 3N total motions because each atom has 3N degrees of freedom.^[1]

N atoms in a molecule have 3Ndegrees of freedom which constitutetranslations,rotations, andvibrations. Fornon-linear molecules, there are 3 degrees of freedom for translational (motion along the x, y, and z directions) and 3 degrees of freedom for rotational motion (rotations in R_x, R_y, and R_z directions) for each atom. Linear molecules are defined as possessing bond angles of 180°, so there are 3 degrees of freedom for translational motion but only 2 degrees of freedom for rotational motion because the rotation about its molecularaxis leaves the molecule unchanged.^[2] When subtracting the translational and rotational degrees of freedom, the degrees of vibrational modes is determined.

Number of degrees of vibrational freedom fornonlinear molecules: 3N-6

Number of degrees of vibrational freedom forlinear molecules: 3N-5^[3]

All 3N degrees of freedom havesymmetry relationships consistent with theirreducible representations of the molecule'spoint group.^[1] Alinear molecule is characterized as possessing abond angle of 180° with either a C_∞v or D_∞h symmetry point group. Each point group has acharacter table that represents all of the possible symmetry of that molecule. Specifically for linear molecules, the two character tables are shown below:

However, these two character tables have infinite number of irreducible representations, so it is necessary to lower the symmetry to a subgroup that has related representations whose characters are the same for the shared operations in the two groups. A property that transforms as one representation in a group will transform as its correlated representation in a subgroup. Therefore, C_∞v will be correlated to C_2v and D_∞h to D_2h. The correlation table for each is shown below:

Once the point group of the linear molecule is determined and the correlated symmetry is identified, all symmetry element operations associated to that correlated symmetry's point group are performed for each atom to deduce the reducible representation of the 3N Cartsian displacement vectors. From the right side of the character table, the non-vibrational degrees of freedom, rotational (R_x and R_y) and translational (x, y, and z), are subtracted:Γ_vib = Γ_3N - Γ_rot - Γ_trans. This yields theΓ_vib, which is used to find the correct normal modes from the original symmetry, which is either C_∞v or D_∞h, using the correlation table above. Then, each vibrational mode can be identified as either IR or Raman active.

Avibration will be active in the IR if there is a change in thedipole moment of the molecule and if it has the same symmetry as one of the x, y, z coordinates. To determine which modes are IR active, the irreducible representation corresponding to x, y, and z are checked with thereducible representation ofΓ_vib.^[4] An IR mode is active if the same irreducible representation is present in both.

Furthermore, a vibration will be Raman active if there is a change in thepolarizability of the molecule and if it has the same symmetry as one of the direct products of the x, y, z coordinates. To determine which modes are Raman active, the irreducible representation corresponding to xy, xz, yz, x², y², and z² are checked with the reducible representation ofΓ_vib.^[4] A Raman mode is active if the same irreducible representation is present in both.

Carbon Dioxide, CO₂

1. Assign point group: D_∞h

2. Determine group-subgroup point group: D_2h

3. Find the number of normal (vibrational) modes or degrees of freedom using the equation: 3n - 5 = 3(3) - 5 = 4

4. Derive reducible representation Γ_3N:

5. Decompose the reducible representation into irreducible components:

Γ_3N = A_g + B_2g + B_3g + 2B_1u + 2B_2u + 2B_3u

6. Solve for the irreducible representation corresponding to the normal modes with the subgroup character table:

Γ_3N = A_g + B_2g + B_3g + 2B_1u + 2B_2u + 2B_3u

Γ_rot = B_2g + B_3g

Γ_trans = B_1u + B_2u + B_3u

Γ_vib = Γ_3N - Γ_rot - Γ_trans

Γ_vib = A_g + B_1u + B_2u + B_3u

7. Use the correlation table to find the normal modes for the original point group:

v₁ = A_g = Σ⁺
_g

v₂ = B_1u = Σ⁺
_u

v₃ = B_2u = Π_u

v₄ = B_3u = Π_u

8. Label whether the modes are either IR active or Raman active:

v₁ = Raman active

v₂ = IR active

v₃ = IR active

v₄ = IR active

• Vibrational spectroscopy