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Thorium heptaphosphide

From Wikipedia, the free encyclopedia
Thorium heptaphosphide
Identifiers
3D model (JSmol)
  • InChI=1S/7P.Th/q;;;4*-1;+4
    Key: LNJLDCGWEAURNN-UHFFFAOYSA-N
  • [Th+4].[P-].[P-].[P-].[P-].[P].[P].[P]
Properties
P7Th
Molar mass448.8540 g·mol−1
Appearanceblack rod-shaped crystals
Density4.93 g/cm3[1]
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Thorium heptaphosphide is a binaryinorganic compound ofthorium metal andphosphorus with the chemical formulaThP7.[2] This is the most phosphorus-rich binary compound of a tetravalent thorium.[3]

Synthesis

[edit]

Thorium heptaphosphide can be synthesized from the elements with addition of iodine at 830 K.[3][4]

Properties

[edit]

Thorium heptaphosphide forms black rod-shaped crystals oforthorhombic crystal system.[1][4] It decomposes toTh2P11 at 650 K in vacuo.[3]

References

[edit]
  1. ^ab"mp-28410: ThP7 (Orthorhombic, P2_12_12_1, 19)".Materials Project. Retrieved17 March 2024.
  2. ^Jahrbuch ... der Max-Planck-Gesellschaft zur Förderung der Wissenschaften (in German).Max-Planck-Gesellschaft zur Förderung der Wissenschaften. 1984. p. 599.ISBN 978-3-525-85390-0. Retrieved17 March 2024.
  3. ^abcVon Schnering, Hans-Georg; Vu, Dong (1 February 1986)."Thorium heptaphosphide ThP7".Journal of the Less Common Metals.116 (1):259–270.doi:10.1016/0022-5088(86)90234-1.ISSN 0022-5088. Retrieved17 March 2024.
  4. ^abBickel, Michael; Wedemeyer, Horst (17 April 2013).Th Thorium Supplement Volume C 8: Compounds with Si, P, As, Sb, Bi, and Ge.Springer Science & Business Media. p. 101.ISBN 978-3-662-06348-4. Retrieved17 March 2024.
Phosphides
Other compounds
Th(II)
Th(III)
Th(IV)
Binary phosphides
Ternary phosphides
Quaternary phosphides
Quinary phosphides
See also
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