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Thorium(IV) sulfide

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Thorium(IV) sulfide
Thorium(IV) sulfide
Thorium(IV) sulfide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.032.026Edit this at Wikidata
EC Number
  • 235-242-8
  • InChI=1S/2S.Th
  • [Th+4].[S-2].[S-2]
Properties
ThS2
Molar mass296.17 g/mol
Appearancedark brown crystals
Density7.3 g/cm3, solid
Melting point1,905 °C (3,461 °F; 2,178 K)
Structure[1]
PbCl2 type (orthorhombic)
Pnma (No. 62)
4
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound

Thorium(IV) sulfide (ThS2) is aninorganicchemical compound composed of onethorium atomionically bonded to two atoms ofsulfur. This salt is dark brown and has a melting point of 1905 °C. ThS2 adopts the sameorthorhombic lattice structure asPbCl2.[1][2][3]

References

[edit]
  1. ^abZachariasen, W. H. (1949-10-01). "Crystal chemical studies of the 5f-series of elements. X. Sulfides and oxysulfides".Acta Crystallographica.2 (5). International Union of Crystallography (IUCr):291–296.Bibcode:1949AcCry...2..291Z.doi:10.1107/s0365110x49000758.ISSN 0365-110X.
  2. ^Amoretti, G.; Calestani, G.; Giori, D. C. (1984-08-01)."The Refined Structure of ThS2 and the Implications on the Superposition Model Analysis of ThS2: Gd3+ Spin Hamiltonian Parameters".Zeitschrift für Naturforschung A.39 (8). Walter de Gruyter GmbH:778–782.doi:10.1515/zna-1984-0809.ISSN 1865-7109.
  3. ^Gerward, L.; Staun Olsen, J.; Benedict, U.; Abraham, H. C.; Hulliger, F. (1995). "High-pressure crystal structure of thorium disulfide and diselenide and uranium disulfide".High Pressure Research.13 (6). Informa UK Limited:327–333.Bibcode:1995HPR....13..327G.doi:10.1080/08957959508202585.ISSN 0895-7959.
Th(II)
Th(III)
Th(IV)
Sulfides(S2−)


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