Movatterモバイル変換


[0]ホーム

URL:


Jump to content
WikipediaThe Free Encyclopedia
Search

Thorium(IV) hydroxide

From Wikipedia, the free encyclopedia
The topic of this articlemay not meet Wikipedia'sgeneral notability guideline. Please help to demonstrate the notability of the topic by citingreliable secondary sources that areindependent of the topic and provide significant coverage of it beyond a mere trivial mention. If notability cannot be shown, the article is likely to bemerged,redirected, ordeleted.
Find sources: "Thorium(IV) hydroxide" – news ·newspapers ·books ·scholar ·JSTOR
(September 2024) (Learn how and when to remove this message)
Thorium(IV) hydroxide
Names
IUPAC name
Thorium(IV) hydroxide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.034.097Edit this at Wikidata
EC Number
  • 237-522-5
  • InChI=1S/4H2O.Th/h4*1H2;/q;;;;+4/p-4
    Key: SFKTYEXKZXBQRQ-UHFFFAOYSA-J
  • [OH-].[OH-].[OH-].[OH-].[Th+4]
Properties
Th(OH)4
Molar mass300.07
Appearancewhite solid[1]
Related compounds
Otheranions
thorium dioxide
thorium nitrate
Othercations
cerium(IV) hydroxide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Thorium(IV) hydroxide is aninorganic compound with achemical formula Th(OH)4.

Production

[edit]

Thorium(IV) hydroxide can be produced by reacting alkali metal hydroxides likesodium hydroxide andpotassium hydroxide and soluble thorium salts, such asthorium nitrate.[1][2][3]

Reactions

[edit]

New thorium(IV) hydroxide is soluble in acid but its solubility will decrease when older.[1]

At above 470 °C, thorium(IV) hydroxide will continuously decompose and producethorium dioxide:[3]

Th(OH)4 → ThO2 + 2 H2O

Thorium(IV) hydroxide reacts withcarbon dioxide gas. Under ambient conditions this produces the hydrated oxide carbonate ThOCO3·xH2O, and under higher pressure this producesthorium carbonate hemihydrate (Th(CO3)2·½H2O).[4][3][5]

References

[edit]
  1. ^abc《无机化合物制备手册》.朱文祥 主编.化学工业出版社. P143. 【III-251】氢氧化钍(thorium hydroxide)
  2. ^Gayer, K. H.; Leider, H. (1 Dec 1954). "The Solubility of Thorium Hydroxide in Solutions of Sodium Hydroxide and Perchloric Acid at 25°".Journal of the American Chemical Society.76 (23):5938–5940.doi:10.1021/ja01652a012.
  3. ^abcWickleder et al., pp. 70–7
  4. ^H. Ehrhardt, H. Seidel, H. Schweer (March 1980)."Hochdrucksynthesen einiger Carbonate mit überkritischem CO2".Zeitschrift für anorganische und allgemeine Chemie (in German).462 (1):185–198.doi:10.1002/zaac.19804620121.ISSN 0044-2313. Retrieved2019-11-23.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  5. ^Wickleder et al., pp. 101–115
Th(II)
Th(III)
Th(IV)

Bibliography

[edit]
Retrieved from "https://en.wikipedia.org/w/index.php?title=Thorium(IV)_hydroxide&oldid=1299998927"
Categories:
Hidden categories:

[8]ページ先頭

©2009-2026 Movatter.jp