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Tetraoxidane

From Wikipedia, the free encyclopedia
Tetraoxidane
Names
IUPAC name
Tetraoxidane
Other names
Hydroxyperoxide, dihydrogen tetroxide, diperoxide, bisperoxide
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/H2O4/c1-3-4-2/h1-2H
    Key: RSPISYXLHRIGJD-UHFFFAOYSA-N
  • OOOO
Properties
H2O4
Molar mass66.012 g·mol−1
Density1.8±0.1 g/cm3
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Tetraoxidane is an inorganic compound ofhydrogen andoxygen with the chemical formulaH2O4.[1][2][3] This is one of the unstablehydrogen polyoxides.[4]

Synthesis

[edit]

The compound is prepared by a chemical reaction betweenhydroperoxyl radicals (HOO•) at low temperatures:[5][6]

2 HOO• ⇌ H2O4

Physical properties

[edit]

This is the fourth member of the polyoxidanes. The first three arewater (oxidane),hydrogen peroxide (dioxidane), andtrioxidane. Tetraoxidane is more unstable than the previous compounds. The term "tetraoxidane" extends beyond the parent compound to several daughter compounds of the general formulaR2O4, where R can behydrogen,halogen, or variousinorganic andorganicmonovalent radicals. The two Rs together can be replaced by adivalent radical, soheterocyclic tetraoxidanes also exist.[7]

Ionization

[edit]

Tetraoxidaneautoionizes when in liquid form:

H2O4 ⇌ H+ + HO4
2 H2O4 ⇌ H3O+4 + HO4

See also

[edit]

References

[edit]
  1. ^Mckay, Daniel J.; Wright, James S. (1 February 1998)."How Long Can You Make an Oxygen Chain?".Journal of the American Chemical Society.120 (5):1003–1013.doi:10.1021/ja971534b.ISSN 0002-7863. Retrieved16 May 2023.
  2. ^"hydroxyperoxide". ChemScr. Retrieved15 May 2023.
  3. ^The Chemistry of Peroxides, Volume 3.John Wiley & Sons. 20 April 2015. p. 198.ISBN 978-1-118-41271-8. Retrieved15 May 2023.
  4. ^"Selected ATcT [1, 2] enthalpy of formation based on version 1.122 of the Thermochemical Network [3]". atct.anl.gov. Retrieved15 May 2023.
  5. ^Levanov, Alexander V.; Sakharov, Dmitri V.; Dashkova, Anna V.; Antipenko, Ewald E.; Lunin, Valeri V. (2011). "Synthesis of Hydrogen Polyoxides H2O4 and H2O3 and Their Characterization by Raman Spectroscopy".European Journal of Inorganic Chemistry.2011 (33):5144–5150.doi:10.1002/ejic.201100767.
  6. ^Möller, Detlev (19 February 2019).Fundamentals and Processes.Walter de Gruyter GmbH & Co KG. p. 276.ISBN 978-3-11-056126-5. Retrieved15 May 2023.
  7. ^Curutchet, Antton; Colinet, Pauline; Michel, Carine; Steinmann, Stephan N.; Le Bahers, Tangui (2020)."Two-sites are better than one: revisiting the OER mechanism on CoOOH by DFT with electrode polarization"(PDF).Physical Chemistry Chemical Physics.22 (13):7031–7038.Bibcode:2020PCCP...22.7031C.doi:10.1039/D0CP00281J.PMID 32195492.S2CID 213191538. Retrieved15 May 2023.
Alkali metal
(Group 1) hydrides
Alkaline (Group 2)
earth hydrides
Monohydrides
Dihydrides
Group 13
hydrides
Boranes
Alanes
Gallanes
Indiganes
Thallanes
Nihonanes(predicted)
  • NhH
  • NhH3
  • Nh2H6
  • NhH5
Group 14 hydrides
Hydrocarbons
Silanes
Silenes
Silynes
Germanes
Stannanes
Plumbanes
Flerovanes(predicted)
  • FlH
  • FlH2
  • FlH4
Pnictogen
(Group 15) hydrides
Azanes
Azenes
Phosphanes
Phosphenes
Arsanes
Stibanes
Bismuthanes
Moscovanes
Hydrogen
chalcogenides
(Group 16 hydrides)
Polyoxidanes
Polysulfanes
Selanes
Tellanes
Polanes
Livermoranes
Hydrogen halides
(Group 17 hydrides)
  • HF
  • HCl
  • HBr
  • HI
  • HAt
  • HTs(predicted)
  • Transition
    metal hydrides
    Lanthanide
    hydrides
    Actinide
    hydrides
    Exotic matter hydrides
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