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Tetraiodine nonoxide

From Wikipedia, the free encyclopedia
Tetraiodine nonoxide
Identifiers
3D model (JSmol)
  • InChI=1S/I4O9/c5-1(6)11-4(12-2(7)8)13-3(9)10
    Key: IQQBBNVVZPXURM-UHFFFAOYSA-N
  • O=I(=O)OI(OI(=O)=O)OI(=O)=O
Properties
I4O9
Molar mass651.609 g·mol−1
Appearancelight yellow solid[1]
Melting point75 °C (decomposes)[1]
reacts
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Tetraiodine nonoxide is aniodine oxide with the chemical formula I4O9.

Preparation

[edit]

Tetraiodine nonoxide can be produced by reactingozone andiodine incarbon tetrachloride at −78 °C:[2][3]

2 I2 + 9 O3 → I4O9 + 9 O2

It can also be produced by heatingiodic acid andphosphoric acid together:[4]

8 HIO3 → 2 I4O9 + 4 H2O + O2

Properties

[edit]

Tetraiodine nonoxide is a light yellow solid that can easilyhydrolyze. It decomposes above 75 °C:[2]

4 I4O9 → 6 I2O5 + 2 I2 + 3 O2

Likediiodine tetroxide, tetraiodine nonoxide contains both I(III) and I(V), anddisproportionate toiodate andiodide under alkaline conditions:[2]

3 I4O9 + 12 HO → I + 11 IO3 + 6 H2O

It reacts with water to form iodic acid and iodine:[3]

4 I4O9 + 9 H2O → 18 HIO3 + I2

References

[edit]
  1. ^abPerry, Dale L. (2011).Handbook of Inorganic Compounds. Boca Raton, FL. p. 500.ISBN 978-1-4398-1462-8.OCLC 759865801.{{cite book}}: CS1 maint: location missing publisher (link)
  2. ^abcHolleman, A. F.; Nils, Wiberg; Wiberg, Egon (2019).Lehrbuch der anorganischen Chemie (in German). Berlin. p. 443.ISBN 978-3-11-083817-6.OCLC 1102802853.{{cite book}}: CS1 maint: location missing publisher (link)
  3. ^abGarg, Ragni; Singh, Randhir (2015).Inorganic Chemistry. New Delhi: McGraw-Hill Education.ISBN 978-1-259-06285-8.OCLC 965462199.
  4. ^Brauer, Georg (1963).Handbook of Preparative Inorganic Chemistry V1. Burlington: Elsevier Science. p. 331.ISBN 978-0-323-16127-5.OCLC 843200092.{{cite book}}:ISBN / Date incompatibility (help)
Iodine(−I)
Iodine(I)
Iodine(II)
Iodine(III)
Iodine(IV)
Iodine(V)
Iodine(VII)
Mixed oxidation states
+1 oxidation state
+2 oxidation state
+3 oxidation state
+4 oxidation state
+5 oxidation state
+6 oxidation state
+7 oxidation state
+8 oxidation state
Related
Oxides are sorted byoxidation state.Category:Oxides
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