Structure and synthesis

SF⁻
₃

References

1. ^^abMorton, J. R.; Preston, K. F.; Strach, S. J. (1978). "The EPR spectrum of SF₃ Trapped in SF₃BF₄ Crystals".The Journal of Chemical Physics.69 (4): 1392.Bibcode:1978JChPh..69.1392M.doi:10.1063/1.436766.
2. ^Deng, Jianming; Wang, Chaoyang; Li, Qian-shu; Xie, Yaoming; King, R. Bruce; Schaefer, Henry F. (2011). "Trifluorosulfane Ligand as an Analogue of the Nitrosyl Ligand: Highly Exothermic Fluorine Transfer Reactions from Sulfur to Metal in the Chemistry of SF₃ Metal Carbonyls of the First Row Transition Metals".Inorganic Chemistry.50 (7):2824–2835.doi:10.1021/ic101994k.PMID 21366337.
3. ^Irikura, Karl K. (1995)."Structure and thermochemistry of sulfur fluorides SF_n (n = 1–5) and their ionsSF⁺
   _n (n = 1–5)".The Journal of Chemical Physics.102 (13):5357–5367.Bibcode:1995JChPh.102.5357I.doi:10.1063/1.469263.
4. ^Woon, David E.; Dunning, Thom H. (2009)."Theory of Hypervalency: Recoupled Pair Bonding in SF_n (n = 1−6)".The Journal of Physical Chemistry A.113 (27):7915–7926.Bibcode:2009JPCA..113.7915W.doi:10.1021/jp901949b.PMID 19499905.
5. ^Cockman, Russell W.; Ebsworth, E. A. V.; Holloway, John H. (1987). "Complexes of iridium(III) containing the novel sulfur trifluoride ligand".Journal of the American Chemical Society.109 (7):2194–2195.Bibcode:1987JAChS.109.2194C.doi:10.1021/ja00241a055.
6. ^Gao, Xiaozhen; Li, Nan; King, R. Bruce (December 2014). "Formation of Difluorosulfane Complexes of the Third Row Transition Metals by Sulfur-to-Metal Fluorine Migration in Trifluorosulfane Metal Complexes: The Anomaly of Trifluorosulfane Iridium Tricarbonyl".Inorganic Chemistry.53 (23):12635–12642.doi:10.1021/ic502375q.PMID 25397720.